Document oyDvkYNKg42nqJzxR6OmgJD

MATERIAL DATA SHEET C -- 2199 Experimental Eeat Stabilizer Morton Thiokol, lac. Carstab Division 2000 West Street Cincinnati, Ohio 4521: 1. PRODUCT IDENTIFICATION Emergency Phone No. General Information MSDS Reference No. Rev. Date 01/14/86 513-732-2213 513-733-21C0 2190 Rev. No. 1 Product name: C-210'J Experimental Heat Stabilizer Chemical name: Mir.tur-* Chemical family. Proprietary aikyitin hear stabilizer II. HAZARDOUS CONSTITUENTS CAS No. Chemical Experimental product of proprietary composition For R . D use only under appropriate technical supervision Hazard Data TIV tir.-sxi: 0.1 mg/m - Combustible III. PHYSICAL DATA Boiling point: VnDor pressure K;0 solubility Viscosity: >22C:C <1.0 mm TM 25 - C Insoluble Co cs e 22 ' 0 Melting point: Vapor density iair=l' fi volatiles by wt.: Specific gravity: Not applicable 4.5 6 e llo:c 1.00 3 25-C Appear oii.-r: Clear colorless la pale yellow Li.mid with s mercaptan odor r a::d enplcsicn hazard data Flash point (method used1 Fi.ur.mub l e limits in air : Ext mgr. mil mg media: Fir'.* fight.inr. procedures: Fir1' ^ exnlor, ion hazards: 100 F (Setaflasii - AS'IM 0:1273-78) UnJinown Carbon dioxide, water for. or toai:i Sel f-coiil ained breathing appurnrus with full facepiece in positive pressure mode and Impervious suit On burning, mav produce irritating or toxic vapors includinr, Ir'droi'arbotu;, orr.nnot ins and oxides of carbon and sulfur. D0 088987 c0NFTnfrNTTAl" C-21G9 Experimental Heat Stabilizer Fa.'ie 2 MSDS Here 01/l4/26~ Nc. 2IGD Morton Thiokol, Inc. Cars tab Division 512-722-2100 V. HEALTH HAZARD INFORMATION Health Hazara Data Eased on ani.ua! studies of similar products. No human exposure data. TLV: PEL: 0.1 mg tin/a , tin-skin 0.1 mg tin.m:, tin-skin LC50: Not determined LC30: Not determined Skin Irritation Index (rabbit): Not determined Eye Irritation Index (rabbit/: Not determined Effects of Over^xr.esur ? Inhalation: Skin contact: Skin absorption: Eye contact: Investicn: Chronic: May cause headache, nausea and/or irritation of throat (coughing;. May cause reddening of the skin (erythema), swelling (edema; and irritation (dermatitis). May cause shaking, loss of coordination, ataxia and hypersensitivity. No data available but good hygiene dictates avoiding any eve contact. May cause depression, excessive salivation, diarrhea, eye and nasal discharge. No data available. Targeted organs in acute toxicity test of similar products include kidneys. f Aid Procedures I a; a. r:. Ingest ton Flush with water for 15 minutes. Obtain medical art on rion. 'wash :a with scan and ware:-, iiomiivo uunramiunt *d clothing. Obtain medical ?r.t on me t was prole r.*yd r me. Remove to fr ?sh air. Obtain medical jti .:tn t on irritation develops. Obtain medical attention immediately. 00 085983 CONFrOFNTTAi. C-2ISS Experimental Heat Stabilize: ?a*f 2 0I/W/S6 Merton Thiokol, Inc. Carstab Division Oiu" ( VI. REACTIVITY DATA Stabiiitv of compound: Chessicni in cesnotibi'it*/: Decomposition products: Hazardous polymerization: Stable Coosa tibia with ether stable compounds. Hydrocarbcas, crganctir.s and oxides cf carbon and sulfur may be produced when burned. Will not occur. VII. SPILL CR LEAli PROCEDURES If material is spilled: Spills oav be removed with any absorbent: sand, sponge, cloth, paper, ecc. Use detergent with water for final cleanup. Wear prescribed protective equipment see section V.T"'. to nre,-*r.: vapor inhalation or shin contact. Wasre disposal method: Place absorbed material in an appropriate, closed container for disposal o: in accordance with local, state and federal regulations. Reportable quantities: Not applicable VIII. SPECIAL PROTECTION INFORMATION Ventilation requirements: Adequate to prevent vapor accumulation & keep below TLV/PEL. Equipment Respirui or If varors are irritating, wear NIOSH-appriyed cartridge respirator with organic vapor cartridges. Where iar.ga vapor I'cnoentrat ions are susoocted, w^ar NlOSu-annroved air-sunn lied breaching equipment. 11: iv-1,;: Saf '.-.-s and, or suf v. v \ Lr.r..and f nnebericed ginveu ihiei-i r.nnervi.ni:; suit or rubber anron 0859Q4 C0NrT^NTrAl C-21S3 Experimental Hear S cabilicer ?aa -4 :-S3S aefsrerca Mo. Elai} 01/14/26 Morton Thickol, Inc. Carszab Division 512-722-2100 Ik'. SPECIAL FEECALTIOMS Do net take internally. Store ir. cool, cry location. For industry use cnlv. keep away from children. U Kemove contaminated clothing immediately and launder before reuse. Contaminated shoes and gloves should be destroyed'. For MSDS information contact John L. Hanley, 513-733-2127. "To the best, of our knowledge the information contained herein is correct. Ail cir'niicuis ir.uv present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot jfuarnnr.eo that these arc the only u*d:; which exist. Final determination of suitabilitv of the chemical is the sole responsibility or id;-* or. doors of an'-' o::o::r.c:,..i should satisfv themselves that the enndi * r<'i:r end methods of use assure that the chemical is used safe!". xo :xj oh fit:-ta i ::;yh2:;x c:.* lypLilJ. mel::a.:7..: .ihrv, r:7::7/c r?.;? a 'a.;: re u.;v:a::'::a . .;s i.. DO 085985 CONFIOFNTTAL MATERIAL SAFETY DATA SHEET C--2227 Experimental Weatherab1e Lubricant Morton Thiokol, Inc. Carstab Division 2000 West Street Cincinnati, Ohio 45215 I. PRODUCT IDENTIFICATION Emergency Phone No. General Information MSDS Reference No. Rev. Date 12/16/85 513-733-2218 513-733-2100 2227 Rev. No. 1 Product name: Experimental weatherable lubricant Chemical name: Confidential Chemical family: Confidential II. HAZARDOUS CONSTITUENTS CAS No. Chemical None currently known as defined by 29 CFR 1910.1200. Review this MSDS for precautionary and emergency measures. For research and developmental use only. Hazard Data III. PHYSICAL DATA Boiling point: Vapor pressure: H^O solubility: Viscosity: Not determined Not determined Insoluble Not applicable Melting point: Vapor density (air=l): \ volatiles by wt.: Specific gravity: 40-45C Not applicable Not determined 0.98 at 25=C Appear. & odor: White flake with mild odor IV. FIRE AND EXPLOSION HAZARD DATA Flash point (method used) Flammable limits in air : Extinguishing media: Fire fighting procedures: Fire & explosion hazards: Not determinedlash - ASTM D3278-78) Not applicable Carbon dioxide, water fog or foam Self-contained breathing apparatus with full facepiece in positive pressure mode and impervious suit On burning, may produce irritating or toxic vapors including: hydrocarbons and oxides of carbon. DO 085986 C0NFTDENTTA1 C-2227 Experimental Weatherable Lubricant Page 2 MSDS Reference No. 2227 12/16/85 Morton Thiokol, Inc Carstab Division 513-733-2100 V. HEALTH HAZARD INFORMATION Health Hazard Data TLV: None established PEL: None established LD50: Not determined LC50: Not determined Skin Irritation Index (rabbit): Not determined Eye Irritation Index (rabbit): Not determined Effects of Overexposure Inhalation: Skin contact: Skin absorption: Eye contact: Ingestion: Chronic: None currently known. None currently known. None currently known. None currently known. None currently known. None currently known. Emergency First Aid Procedures Eyes: Skin: Inhalation: . Ingestion: Flush with water for 15 minutes. Obtain medical attention. Wash immediately with soap and water. Remove contaminated clothing. Obtain medical attention if any irritation results. Remove to fresh air. Obtain medical attention if any irritation develops. Obtain medical attention. C-2227 Experimental Weatherable Lubricant Page 3 MSDS Reference No. 2227 12/16/85 Mort d Thiokol, Inc. Carstab Division 513-733-2100 VI. REACTIVITY DATA Stability of compound: Chemical incompatibility: Decomposition products: Hazardous polymerization: Stable Compatible with other stable compounds. Hydrocarbons and their decompostion products including oxides of carbon may be produced during fire. Will not occur. VII. SPILL OR LEAK PROCEDURES If '"ef'erial is spilled: Spills may be removed mechanically. Avoid dusting. Detergent and water may be used for final cleanup. Waste disposal method: Place material in an appropriate container for disposal of in accordance with local, state and federal regulations. Reportable quantities: Not applicable VIII. SPECIAL PROTECTION IN70H-1ATI0N Ventilation requirements: Use adequate ventilation to control dusting. Equipment Respiratory: If dust becomes irritating, wear a NIOSH-approved dust respirator with dust cartridge, or a NIOSH-approved air-supplied breathing apparatus may be used if necessary. Eye: Safety goggles (and/or safety glasses) and face shield Gloves: Use gloves to avoid skin contact. Other: Protective dust-proof clothing DO 085988 CONFTDFNTTAl C-2227 Experimental W atherable lubricant Page 4 MSDS Reference No. 2227 12/16/85 IX. SPECIAL PRECAUTIONS Do not take internally. Store in cool, dry location. For industry use only. Keep away from children. Morton Thiokol, Inc. Carstab Division 513-733-2100 For MSDS information contact John L. Hanley, 513-733-2127. "To the best of our knowledge the information contained herein is correct. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. Users of any chemical should satisfy themselves that the conditions and methods of use assure that the chemical is used safely. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFOffriATION REFERS." DO 085989 CONFTDFNTTAl MATERIAL SAFETY DATA SHEET C--2327 Lubricating Stabilizer Morton Thiokol, Inc. Carstab Products 2000 West Street Cincinnati, Ohio 45215 I. PRODUCT IDENTIFICATION Emergency Phone No. General Information MSDS Reference No. Rev. Date 06/29/87 513-733-2218 513-733-2100 2327 Rev. No. 1 Product name: C-2327 Experimental Lubricating Stabilizer Chemical name: Mixture Chemical family: PVC lubrLant & alkyltin mercaptide stabilizer HAZARDOUS CONSTITUENTS CAS No. 57583-35-4 Chemical Mixed methyltin mercaptoester sulfides <213* Hazard Data TLV tin-skin, 0.1 mg/m3 PHYSICAL DATA Boiling point: Vapor pressure: H2O solubility: Viscosity: >290C (decom.) <0,1 mm @ 25C Insoluble Not applicable Melting point: Vapor density (air=l): % volatiles by wt.: Specific gravity: 110C (d.p) Not applicable <1.0 e 110F 0.95 Appear. & odor: Off-white to li ght yellow powder with si ight mercaptan odor FIRE AND EXPLOSION HAZARD DATA Flash point (method used) Flammable limits in air : Extinguishing media: Fire fighting procedures: Fire & explosion hazards: 370F (Setaflash - ASTM D3278-78) Not applicable Dry chemical; carbon dioxide; water spray; foam Self-contained breathing apparatus with full facepiece in positive pressure mode and impervious suit On burning, may produce irritating or toxic vapors including hydrocarbons, organotins and oxides of carbon and sulfur. 00 085990 COn^tofNTTai C-2327 Lubricating Stabilizer Page 2 MSDS Reference No. 2327 06/29/87 Morton Thiokol, Inc. Carstab Products 513-733-2100 V. HEALTH HAZARD INFORMATION Health Hazard Data Based on animal studies of a similar organotin stabilizer @ 100% active. TLV: 0.1 mg tin/m^, tin-skin PEL: 0.1 mg tin/m^, tin-skin LD50: oral, 4700 mg/kg (rat) LC50; not determined Skin Irritation Index (rabbit): 1.04 (not primary irritant) Eye Irritation Index (rabbit): Not an eye irritant Effects of Overexposure Inhalation: Skin contact: Eye contact: Ingestion: Chronic: May cause headache, nausea and/or irritation of throat (coughing) or skin (itching). May cause reddening of the skin (erythema), swelling (edema) and irritation (dermatitis). May cause shaking, loss of coordination, ataxia and hypersensitivitj. Not an irritant (see ct'ove) but good hygiene dictates avoiding any eye contact. May cause depression, excessive salivation, diarrhea, eye and nasal discharge. No known human exposure data. The no-toxic effect level in the diet of rats was >5,000 ppm in a sub-chronic (90 day) toxicity study of a similar lubricating stabilizer product. Emergency First Aid Procedures Eyes: Skin: Inhalation: Ingestion: Flush with water for 15 minutes. Obtain medical attention. Wash immediately with soap and water. Remove contaminated clothing. Obtain medical attention if contact was prolonged or extensive. Remove to fresh air. Obtain medical attention if any irritation develops. Obtain medical attention immediately. DO 085991 CONFTDFNTTAL C-2327 lubricating Stabilizer Page 3 MSDS Reference No. 2327 06/29/87 Morton Thiokol, Inc. Carstab Products 513-733-2100 VI. REACTIVITY DATA Stability of compound: Chemical incompatibility: Decomposition products: Hazardous polymerization: Stable Can liberate hydrogen sulfide on contact with acids Hydrocarbons, organotins and oxides of carbon and sulfur may be produced when burned. Will not occur. VII. SPILL OR LEAK PROCEDURES If material is spilled: Spills may be removed mechanically. Avoid dusting. Use prescribed safety equipment. Detergent and water may be used bor final cleanup. Waste disposal method: Place material in an appropriate, closed container for disposal of in accordance with local, state and federal regulations. VIII. SPECIAL PROTECTION INFORMATION Ventilation requirements: Use adequate ventilation to prevent dust &, comply with TLV. Equipment Respiratory: If dusting conditions exist or vapors become irritating, wear a NIOSH-approved, air-suppliedbreathingapparatus. Eye: Safety goggles (and/or safety glasses) andface shield Gloves: Impervious gloves Other: Impervious suit DO 08599? CONFTDFNTT Al. C-2327 Lubricating Stabilizer Page 4 MSDS Reference No. 2327 06/29/87 IX. SPECIAL PRECAUTIONS Do not take internally. Store in cool, dry location. For industrial use only Wash thoroughly after handling. Morton Thiokol, Inc. Carstab Products 513-733-2100 "To the best of our knowledge the information contained herein is correct. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. Users of any chemical should satisfy themselves that the conditions and methods of use assure that the chemical is used safely. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFORMATION REFERS." 00 085990 CONFIDENTIAL