Document omwwK4rDBaKBpwp368Xb48z5o

ttf ---- ICXACO MATERIAL SAFETY DATA SHEET DntP I r.simd notion- 09/1G/93 09/ 19/99 NOTE: Read and understand Material Safety Data Sheet before hand)ing or disposing of product 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name: 08166 ISOBUTANE Chemical Name and/or Family or Description: Aliphatic Hydrocarbon Manufacturer's Name and Address: Texaco Refining and Marketing, Inc. P.O. Box 7812 Universal City, California 91608 Telephone Numbers: TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 GENERAL MSDS ASSISTANCE (914) 838-7204 TECHNICAL INFORMATION Fuels: (914) 838-7336; Lubrlcants/Antlfreezes: (800) 782-7852 Chemicals: (512) 459-6543; Additives- (713) 235-6278 Solvents: (800) 876-3738 2. COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FDR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS: CHRONIC HAZARDS (CARCINOGENIC, TERATOGENIC. MUTAGENIC. NEUROTOXIC. AND SENSITIZERS) ARE LISTED WHEN PRESENT AT 0.01% OR GREATER; ACUTE HAZARDS ARE LISTED WHEN PRESENT AT 1.0% OR GREATER AND NON-HAZARDCUS COMPONENTS ARP LISTED WHEN PRESENT AT 3.0% OR GREATER. THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE. OSHA Product and/or Component(s) Carcinogenic According to: _ I ARC _ NTP _ OTHER _ NONE X Composition: Chemical /Common Name * Isobutane (2-Methyl Propane) CAS No, Exposure Limit Range in % 75285 None Established 100.00 Product is hazardous according to OSHA (1910.1200) * Component(s) is hazardous according to OSHA or one or more state Right-to-Know laws. 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance and Odor: gas WARNING STATEMENT DANGER! EXTREMELY FLAMMABLE GAS GAS MAY CAUSE FLASH FIRE GAS REDUCES OXYGEN AVAILABLE FOR BREATHING MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE SUFFOCATION LIQUID MAY CAUSE FROSTBITE Health: F1ammab111ty: HMIS 2 4 React 1vity: Spec 1 a 1; 0 - Hea1th: 2 F1ammab11ity: 4 NFPA Reactivlty: Specia 1 . 0 - N.D. - Not Determined < - Less Than _________________ Page: 1 N.A. - Not Applicable > - Greater Than N . T. - Not Tested DO a 061806 CONFIDENTIAL I PRODUCT CODE: 08166 ' PRODUCT NAME: ISOBUTANE 3. HAZARD IDENTIFICATION <CONT) Date Issued: 09/16/93 Supersedes: 09/15/93 POTENTIAL HEALTH EFFECTS Primary Route of Exposure: Eff cts of Overexposure Acute Eyes: Eye contact with liquid (cold burns) EYE X product SKIN X or gas INHALATION X under pressure INGESTION - can cause frostbite Skin: No adverse effects expected from absorption of material through the skin. Skin contact with liquid product can cause frostbite (cold burns). Inhalation: Vapors or mist may cause irritation of the nose and throat, headache, nausea, vomiting, dizziness, drowsiness, euphoria, loss of coordination, and disorientation In poorly ventilated areas or confined spaces, unconsciousness and asphyxiation may result Ingestion: This material is a gas (cold burns) Gas or liouid under pressure may cause frostbite Sensitization Properties: Unknown. Chronic: No adverse effects anticipated Medical Conditions Aggravated by Exposure: There is no evidence that this product aggravates an existing medical conditlon Other Remarks: None 4. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of eyelids apart while flushing to rinse water. Get medical attention water for at least 15 entire surface of eye minutes. and lids Hold with Skin: In case of cold burn, immediately place affected area in and keep at this temperature until circulation returns. at tention. warm water (105 Get medical F) Ingestion: No emergency care anticipated temperature and pressure This material Is a gas at standard Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical attention. Other Instructions: None N.D. - Not Determined < - Less Than Page: 2 N.A. - Not Applicable > - Greater Than N.T. - Not Tested ^D A 061807 CONFlDFNrrAL PRODUCT CODE: 08166 PRODUCT NAMF : lSOFUIlANF *z Dote Issued: 09/16/93 6iiriornerlB 09/16/93 5. FIRE-FIGHTING MEASURES Ignition Temp. Degrees F.: N.D. Flammable Limits (%) Lower: 1^J3 Flash Point Degrees F. (Method): -181 F Upper- B 44 Recommended Fire Extinguishing Agents And Special Procedures: According to NFPA Guide, stop flow of gas, use water to cool fire-exposed containers and to protect personnel attempting shut off. Allow fire to burn out. Small fires may be extinguished with dry chemical or carbon dioxide. Wear self-contained breathing apparatus and protective clothing When handling, use non-sparking tools, ground and bond all containers. Unusual or Explosive Hazards: Explosive air-vapor mixtures may form. Danger! Readily forms explosive air-vapor mixtures: may release explosive vapors that travel, be ignited at remote locations, and flash back. Containers may explode in fire. Do not expose to heat, sparks, flame, static, or other sources of Ignition. When handling, use non-sparking tool, ground and bond all containers. 6. ACCIDENTAL RELEASE MEASURES (Transportation Spills Call: CHEMTREC (800) 424-9300) Pr cedures in Case of Accidental Release, Breakage or Leakage: Shut off flow of gas If possible. Isolate area. Keep upwind of leak. Water spray may be effective in dispersing vapors. Eliminate all sources of ignition. Keep people away. Stay upwind and warn of possible downwind explosion hazard. 7. HANDLING AND STORAGE Precautions to be Taken in Handling and Storage: Transport, handle, and store in accordance with OSHA Regulation 1910 106 and applicable DOT Regulations. Ground and bond shipping container, transfer line, and receiving container. Use spark-proof tools. Keep away from heat, sparks, flame and other sources of ignition. Material may be at elevated temperatures and/or pressures. Exercise due care when opening bleeders and sampling ports. Eye wash and safety shower should be available nearby when this product is handled or used. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection: Avoid eye contact. Chemical contact lenses. type goggles should be worn. Do not wear Skin Protection: Protective clothing such as uniforms, coveralls or lab coats should be worn. Launder or dry-clean when soiled. Gloves and boots resistant to chemicals and petroleum distillates required. Insulated gloves also required if contact with liquid-cooled product or equipment is expected. Respiratory Protection: Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated, use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. See below for applicable permissible concentrations. Page: 3 k 1 r> -- Vir>4 r>r + or'mtr'>eH MA -- M<-\ ^ nr, 1 i r-ih 1 n *1 * 1 -- * `T -- J < - Less Than > - Greater Than DO A 061808 C0NFTDFNTIA1 oRDDUCT CODE- 08166 PRODUCT NAME: ISOBUTANE B. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONT) ' '~ Date Issued' Supersedes: 09/16/93 09/15/93 Ventl1 at Ion: Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits, if applicable (see below), prevent accumuI atton of explosive air-gas mixtures, and avoid significant oxygen displacement. Oxygen levels should be at least 19.5% in confined spaces or other work areas (OSHA value). Exposure Limit for Total Product: None established for proouct. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor gas Boiling Point (Degrees F ) 10 4 Specific Gravity 0.5631 (H20=1) pH of undiluted product- N.A. Vapor Pressure 27.5C mmhg V i scosity N A 10. STABILITY AND REACTIVITY Percent VOC. 100 Vapor Density: 2.07 Solubility in Water: apprec Other: Air=1 This Material Reacts Violently With: (If others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These YY Comments : This product may contain up to 80 pDm benzene in raw natural gas. benzene detected in processed natural gas. No Products Evolved When Subjected to Heat or Combustion: Toxic levels of carbon monoxide, carbon dioxide, irritating ketones. OCCUR DO NOT OCCUR Hazardous Polymerizations: _X aldehydes and 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION ANIMAL TOXICITY DATA) Median Lethal Dose (LD50 LC50) (Species) Oral : believed to be > 5 g/kg (rat); practically non-toxic Inha1 at 1 on: No adverse effects In humans exposed to 250-IOOOppm/8 hrs./IO day Derma 1 : believed to be > 3 g/kg (rabbit); practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin: believed to be < O.5/8.0 (rabbit) no appreciable effect Eyes believed to be < 15/110 (rabbit); no appreciable effect Sens 111zation: N.D. Other: None 12. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user of the product to deter mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardous. ________ Page: 4 N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater Than DO A 061809 CONFIDENTIAL PRODUCT CODE: 08166 PRODUCT NAME: ISOBUTANE Date Issued: Supersedes: ilmiyhtoi'p nhil nht>w n ynmiiin I'nillnl Inn rom) I ny i It li 11 iu i >| ioi n l 11 h i. A |iul ohl Ini external radiation hazard exists at or near any pipe, valve or vessel containing a radon-enriched stream or containing internal deposits of radioactive material, due to the transmission of gamma radiation through its wall. Field studies in the literature and conducted by company personnel at selected sites, have not shown any conditions that subject workers to cumulative exposures in excess of general population limits. Equipment emitting gamma radiation should be presumed to be internally contaminated with alpha-emitting decay products which may be a hazard if inhaled or ingested. During maintenance operations that require the opening of contaminated process equipment, the flow of gas should be stopped and a four hour delay enforced to allow the gamma radiation to drop to back ground levels. Protective equipment E.G. coveralls, gloves and respirator (NIOSH/MSHA approved for high efficiency particulates and radionuclides, or supplied air) should be worn by personnel entering a vessel or working on contaminated process equipment to prevent skin contamination, ingestion or inhalation of any residue containing alpha radiation. Air borne contamination may be minimized by handling scale and/or contaminated materials in a wet state. 09/16/93 09/15/93 _ THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILTIY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY. PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. Tate: 09-16-93 jate Printed: 05-16-94 _ New X Revised. Supersedes: 09-15-93 Inquiries regarding MSDS should be directed Texaco Inc. Manager, Product Safety P.O. Box 509 Beacon, N.Y. 12508 to: PLEASE SEE NEXT PAGE FOR PRODUCT LABEL ____Page: 6 N.D. - Not Determined < - Less Than N. A. - Not Applicable > - Greater Than N.T. - Not Tested A 061820 CONFrOFNTTAI. PRODUCT CODE: 08166 PRODUCT NAME: ISORUTANF 16. PRODUCT LABEL Date Issued: 09/16/93 OQ/ 1F./B3 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT OB 166 ISUBUIANt DANGER! WARNING STATEMENT EXTREMELY FLAMMABLE GAS GAS MAY CAUSE FLASH FIRE GAS REDUCES OXYGEN AVAILABLE FOR BREATHING MAY CAUSE DIZZINESS AND DROWSINESS MAY CAUSE SUFFOCATION LIQUID MAY CAUSE FROSTBITE PRECAUTIONARY MEASURES KEEP AWAY FROM HEAT. SPARKS, AND FLAME KEEP CONTAINER CLOSED AVOID CONTACT WITH EYES, SKIN, AND CLOTHING USE WITH ADEQUATE VENTILATION DO NOT ENTER STORAGE AREAS UNLESS ADEQUATELY VENTILATED WEAR INSULATED GLOVES IF CONTACT WITH LIQUID COOLED EQUIPMENT IS EXPECTED FIRST AID INGESTION: No emergency care anticipated This material is a gas at standard temperature and pressure. INHALATION: Remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical attention EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and lids with water. Get medical attention SKIN CONTACT: In case of cold burn, immediately place affected area in warm water (105 F) and keep at this temperature until circulation returns. Get medical at tention. FIRE In case of fire, stop flow of gas; allow fire to burr. out. Use water to cool containers and protect personnel. Wear self-contained breathing apparatus (SCBA) . Extinguish small residual fires with dry chemical or C02 Chem i ca 1/Common Name CAS No___________________________________________ Range in % * Isobutane (2-Methyl Propane) 75285 100.00 Product is hazardous according to OSHA (1910.1200). * Component(s) is hazardous according to OSHA or one or more state Right-to-Know laws HMIS Health 2 Reactivity Flammability: 4 Special 0 National Fire Protection Association Health : 2 Reactivity : 0 Flammability: 4 Special DOT Proper Shipping Name- Liquefied Petroleum Gas DOT Hazardous Class :21 CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous If used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat Keep container closed and drum bungs In place. _____________ Page: 7 N.D. - Not Determined N.A. - Not Applicable < - Less Than > - Greater Than N.T. - Not Tested DO A 061811 CONFIDENTIAL PRODUCT CODE: 08166 PRODUCT NAME: ISOBUTANE 16. PRODUCT LABEL (CONT) Date Issued: 09/16/93 Supersedes: 09/15/93 Manufacturer's Name: Texaco Refining and Marketing, Inc. P.O. Box 7812 Universal City, California 9160B I DANSI'Uli IA I 1 UN EMERGENCY Company: (91-1) 031-3-100 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 ^0 A 06181? CONFTDFNTTAl.