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FROM OATC SUBJECT
mfucncs
TO
W. J. Boyle, Jr. - Springfield
co R. E.
April 13, 1972
G. M. D. L.
VINYL CHLORIDE SAFETY ASSOCIATION
G. W. W. B.
NOVEMBER 10-12, 1971 MEETING SUMMARY
R. L.
F. 'T.
W. F. Gabel
W. L. A. P.
J. J.
|^W. P.
Cummings Ellsworth Gendron Fletcher Howard - St. Miller - St. Molyneux Thomasino Torrenzano Uihlein Willis
Louis Louis
4
V
f
Highlights of the recent Rochester meeting of the Vinyl Chloride Safety Association are summarized in the order in which the topics were discussed. Items of particular interest to us are underlined.
BUSINESS MEETING
i
t
The present slate of officers were:
C. G. Thompson, Tenneco, Chairman M. G. Glenn, General Tire, Vice-Chairman (absent) S. J. Moll, Borden, Secretary H. E. Kling, American Chemical, Treasurer W. J. Boyle, Jr., Monsanto, Program Chairman
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The officers recommended against the V.C.3.A. associating with the S.P.E. or S.P.I. A motion was passed to keep the group an independent body.
New memberships include Norsk Hydro A.S. of Norway, Promociones Industriales, S.A., of Mexico, Shell Chemical of Deer Park, Texas, and Pittsburgh Plate Glass Industries, Inc.
Additional inquiries have been received from Farbewerke Hoeschst of West Germany and Montecatini Edison SPA of Milano, Italy.
A nominating committee proposed a new slate of officers. The slate was accepted and took office following the adjournment of this meeting, r
M. G. Glenn* General Tire, Chairman R. A. Asti, Stauffer, Vice-Chairman J. C. Flores, Great American, Treasurer J. R. Mehall, Hooker, Secretary H. G. Smith, Ethyl Corp., Program Chairman
The business meeting took only twenty minutes. Tha remainder of the meeting was turned over to W. J. Boyle,' Jr., who onesided over the agenda discussions of November 10 (A.M.), November 11 (A.M. and P.M.) and November 12 (A.M.)
011-1972-00004184
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Vinyl ^ilori* L'lgiUI PrtCfSJ binovilioiu Litifi&tior T.'Ufpc*t
<5C4J $810
RSV oooZ^1
VINYL CHLORIDE SAFETY ASSOCIATION NOVEMBER 10-12, 1971 MEETING SUMMARY
4/13/72 -15-
AOL Bone Disease
Airco and Conoco reported that an extensive x-ray program is now being undertaken with their central medical department to detect AOL in employes. Ten companies have an AOL program already. B. F. Goodrich has long been the leader in doing extensive employe analysis to detect AOL early. Europe has recently reported many cases of AOL in PVC plant employes. Originally thought to be caused by hand reactor cleaning, cases in lead operators and other non-cleaners now proves that AOL is caused Dy repeated exposure to low concentrations of vcm (50 ppmJ.
Bulk Truck Loading
Four companies use life lines on operators while loading and climbing on bulk trucks. Several companies expressed concern at the high injury potential of this operation.
d. Fisheye Control
*
Pantosote indicated that maintaining the oxygen level in the vapor space above incoming VCM tank cars below 100 ppm would" have a great effect on reducing ^isheyes.
Airco, Pantasote and Diamond Shamrock confirmed that once the oxygen level in the RVCM system was monitored and controlled to prevent polyperoxide formation, fisheyes improved considerably.
e- New Solution Fast Catalysts
Reference was made during the catalyst handling and storage discussions, that not only do the solution catalysts reduce the severe hazard of handling solid IPP, but give better conversion and cycles as well. No indication of which fast catalyst was made, however.
f. Shortstop Testing
Uniroyal is doing some testing to determine the effectiveness of isoprene in various concentrations and under different conditions as an emergency shortstop. Isoprene was reported at an earlier meeting to be the most effective sHortstop for PVC reactions. Uniroyal will make the test results available to the""Vinyl Chloride Safety Association in unpublished form at a future meeting.
:SV ,2 7 5 8
4/13/72.1 VCT2 RSV 2757-2759 011-1972-00004185
Page Number 002 Europe 1 Baggett, McCall & Burgess
RSV 0002756
VINYL CHLORIDE SAFI . ASSOCIATION NOVEMBER 10-12, 1971 MEETING SUMMARY
*/l3/72 -16-
g. Kettle Jacket Cleaning
One company commented that kettle jackets should be cleaned annually, since many years of scale may take several chemical cleanings before significant heat transfer can be recovered.
WJB/rg
W, j. Boyle, Jr,'
011-1972-00004186
Vitryl Chlcride T5 Process
(5045 522 >850
Support
RSV 0002759
L
L'OftSSIViO
PROM
W. J. Boyle, Jr. - Springfield
OATS
Aoril 13, 1972
luucer VINYL CHLORIDE SAFETY ASSOCIATION NOVEMBER 10-12, 1971 MEETINGSUMMARY
RVUINCI
TO W. F. Gabel
co R. E. G. M. D. L. G. W. W. B.
R. L.
F. NT. W. L. A. P.
J. J. |j/. p.
Cummings Ellsworth Gendron Fletcher Howard - St
Miller - St Molyneux Thomasino Torrenzano Uihlein Willis
Louis Louis
Highlights of the recent Rochester meeting of the Vinyl Chloride Safety Association are summarized in the order in which the topics were discussed. Items of particular interest to us are underlined.
BUSINESS MEETING
The present slate of officers were:
C. G. Thompson, Tenneco, Chairman M. G. Glenn, General Tire, Vice-Chairman (absent) S. J. Moll, Borden, Secretary H. E. Kling, American Chemical, Treasurer W. J. Boyle, Jr., Monsanto, Program Chairman
The officers recommended against the V.C.3.A. associating with the S.P.E. or S.P.I. A motion was passed to keep the group an independent body.
New memberships include Norsk Hydro A.S. of Norway, Promociones Industriales, S.A., of Mexico, Shell Chemical of Deer Park, Texas, and Pittsburgh Plate Glass Industries, Inc.
Additional inquiries have been received from Farbewerke Hoeschst of West Germany and Montecat:_ni Edison SPA of Milano, Italy.
A nominating committee proposed a new slate of officers. The slate was accepted and took office following the adjournment of this meeting.
M. G. Glenn* General Tire, Chairman R. A. Asti, Stauffer, Vice-Chairman J. C. Flores, Great American, Treasurer J. R. Mehall, Hooker, Secretary H. G. Smith, Ethyl Corp., Program Chairman
The business meeting took only twenty minutes. Ths remainder of the meeting was turned over to W. J. Boyle, Jr. , who oresided over the agenda discussions of November 10 (A.M.), November 11 (A.M. and P.M.) and November 12 (A.M.)
RSV 00027^7
VINYL CHLORIDE SAFETY ASSOCIATION NOVEMBER 10-12, 1971 MEETING SUMMARY
4/13/72 -1S-
b. AOL Bone Disease
Airco and Conoco reported that an extensive x-ray program is now being undertaken with their central medical department to detect AOL in employes. Ten companies have an AOL program already. B. F. Goodrich has long been the leader in doing extensive employe analysis to detect AOL early. Europe has recently reported many cases of AOL in PVC plant employes. Originally thought to be caused by ~ hand reactor cleaning, cases in lead operators and other / non-cleaners now" proves that AOL is caused by repeated
exposure to low concentrations of VCM (50 ppm7.
c. Bulk Truck Loading
Four companies use life lines on operators while loading and climbing on bulk trucks. Several companies expressed concern at the high injury potential of this operation.
d. Fisheye Control
L; *
Pantosote indicated that maintaining the oxygen level in
the vapor space above incoming t/cm tank cars below 1QQ ppm
would have a great effect on reducing fisheyes.
~
Airco, Pantasote and Diamond Shamrock confirmed that once the oxygen level in the RVCM system was monitored and controlled to prevent polyperoxide formation, fisheyes improved considerably.
e. New Solution Fast Catalysts
Reference was made during the catalyst handling and storage discussions, that not only do the solution catalysts reduce the severe hazard of handling solid IPP, but give better conversion and cycles as well. No indication of which fast catalyst was made, however.
f. Shortstop Testing
Uniroyal is doing some testing to determine the effectiveness of isoprene in various concentrations and under different conditions as an emergency shortstop. Isoprene was reported at an earlier meeting to be the most effective shortstop for PVC reactions" Uniroyal will make the test results available to the Vinyl Chloride Safety Association in unpublished form at a future meeting.
RSV 0002758
VINYL CHLORIDE SAFI . ASSOCIATION . NOVEMBER 10-12, 1971 MEETING SUMMARY
4/13/72 -16-
g. Kettle Jacket Cleaning
One company commented that kettle jackets should be cleaned annually, since many years of scale may take several chemical cleanings before significant heat transfer can be recovered.
WJB/rg
W. j. Boyle, Jr
RSV 0002759