Document omQqry0nEyRkk83g9NpOaNK83
:
AR 226 _ 08ST
TOXICITY TO AQUATIC PLANTS
IESTSUBS ~~ T0 A0 N0C 0E 0 Identity: A mixture containing perfluorooctanesulfonate, which may also be
referred to as PFOS, FC-95, or as a component of FC-603EF. "Octanesulfonic acid) (CAS # 2795-39-3).
Remarks: The 3M production lot number is not noted. The test sample is
FC-603EF. Current information indicates it is a mixture of 1.30% PFOS, 10%
diethylene glycol butyl ether, 54.15% water, 22.5% ethylene glycol, 2.6%
propanesultone foamer, 5% Alkylether sulfate, 0.1% N-(3-
Chloroally)hexaminium chloride, 0.9% Xanthan gum, 0.9% starch, 1.0%
triethanolamine, and 0.05% tolyl triazole.
~
The following summary applies a mixture with incompletely
characterized concentrationsof impurities. Data may notaccurately
reflect toxicity of the fluorochemical component of the test sample.
ME0 THOD0 : 0000000
Method: NS-EN ISO 10253, 1998: Water quality -- Marine algal growth
inhibition test
Type: Acute Static
GLP: No
Year completed: 2000
Species: Skeletonema costatum
Source: Strain NIVA
Research, Stavanger,
BACH, stock
Norway.
culture
maintained
at
RF
--Rogaland
Element basis: Estimate biomass by measuring fluorescence
Exposure period: 72 hours
Statistical Methods: Growth rates by Log linear regression on biomass
(fluorescence) vs. time, as described in NS-EN ISO 10253. Calculation of
NOEC done by single factor
Analytical monitoring: pH
ANOVA
followed
by
Bonferronis
procedure.
Test Conditions:
Algal Nutrient Medium: Filtered natural seawater (34 ppt salinity) from an
unpolluted site in Byfjord, Norway, enriched with nutrients according to ISO 10253 and recommendations from the Paris Commission. This nutrient medium provided all mineral nutrients essential for algal growth and also oT served as the diluent for all algal operations. The pHofthis syntheticalgal
medium was 8.2.
Stock and test solution preparation: A 1020 mg/L primary stock solution
was prepared by diluting 1.020 g of test substance in 1 Lof growth medium.
002339
Aliquots were test solutions.
then
added
directly
to
growth
medium
in
test
vessels
to
create
Exposure solution.
vessels:
100 ml flat-bottomed flasks containing 50 mi test
Agitation: Numberof
rSehplaikceantecso:nti3nuously
on
an
orbital
shaker.
NInuitmiablecrelolflcooandicnegn:tra2.t0ioxns1:0sciexlplls/umsLa blank control
WLiagthetrinCgh:eCmoinsttirnyu:ous fluorescent lighting at >50 pE/m? sek.
pH range (0-72 hours):
8.2-8.2 (control exposure)
Test te8m2pe-r8at3ur(e10r0a0ngmeg:/L2e0xp+o2surCe)
R0 ESWTS 0000
mNgo/mLi.naRlefceornecnecnetrsautbisotnasn:ceBl(a3n,k5-cdoincthrollo,ro3p.h2e,no1l0,)
32, 100, 320, at 1.5 mgiL.
and
1000
Algal
Growth
Response E/Cs, values (based 72-hour E,Cso = ~170 mg/L
on
growth
rate)
72-hour NOEC = 100 mg/L.
Element values are based on nominal concentrations.
Reversibility of Growth Inhibition: Not conducted.
SRuebmsatraknsc:e TReesmtianrgkwsafsieldc.onTduhcetveadluoenstrheepmoirxtteudraepapslydetosctrhiabtemdixitn utrheeaTnedstnot the fluorochemical proportion alone.
c0 onclusions 000
The The
test sample 72-hour No
exhibits a Observed
E7f2f-ehcotuCroEn,cCesnotrgartoiwotnh(rNatOeEvCa)luies
of ~170 mil. 100 mg for
growth rate.
tVahlaindi1t6y cirnittehreiatefusltfiplelerdi.odCoanntdrorlefceelrlednecnessiutybsitnacnrceeasweadsbwyaitfhainctnoorromfalmorraen.ge. __
Submitter: 3M Paul, Minnesota,
Company, 55133
Environmental
Laboratory,
P.O.
Box
33331,
St.
pa0 taQuau0 ry 0000
002340
tReesltiianbgi.litHyo:weKvieirm,isschamrpalnkeipnugri=ty2.waThsisnosttpurdoypmeerleytschtahreacctreitreirzieadfoarnqduatlhietystudy
lacks analytical solution.
confirmation
of
the
amount
of
fluorochemical
proportion
in
the
Treesqutewsatosfc3oMnduNcotregde,bLyaRbFreRfoegraelnacnednuRemsbeearr9c9h,31o2f4S,ta2v0a0n0g.er, Norway at the
o0 mer000000000 Last changed: 6/26/00
002341
L9a9b3.1re2f4no.
Page lof 31
os [(4hH[IiTNs!
RF well ROSAAER
"FC-603
EF
Light Water TM
ATC
ATC TM
3%"
Toxicity tests
#
.
Report RF-2000/004
2
FT Lab.rel. no.
993124 No. of pages: st
Author:
Elin Horve honi(e: 3M Norge
[===] VVeerrssi.on1N/o1.4.d0at1e2:000 i Research Program: S... 13
Samar:
=
Thefollowingtestresuswereobtained with FC-603EFLightWaterTM ATCTM 3%": se
1
Toxicity: Skeletonemacostatum 72HEC,
Acartiatonsa
Corophiumvolutator ~~
48hLC,
10dLC,,
Co men: mo
(mon: 280
(mg/kg cry weight): 53060
The results relate to the product as supplied by Novatech.
Ropworda: Toxity,Skeletonemacostatum,Acar tonsa,CorophiumVolutaor.
op"oBlLE
"Nopart of isdocumentmayBereproduced nanyfomwho peission i wingby RF - Rogaland Research.
IngerL-- isaAndersen
foKrdPrFo -Neotgiaalnadnd~Re~sear+ch+++=
IEE
002342
93134
:
CONTENTS:
2. TEST FOR TOXICITY WITH SKELETONEMA COSTATUM c.vvvvrvsrrsrrsmiesssssssssssesnesseessessssnns & 3. TEST FOR TOXICITYWITH ACARTIA TONSA ..cvvvvvrvrerrsesivssssssmsmmssmsssssssssssssseseesneen 10 4. TEST FOR TOXICITY WITH COROPHIUM VOLUTATOR..cvcevvrrrrerrssssssssssmsssssssssssssssenes 15
002343
LaLabbrreetfro
Pagsee 3ofo 31
PREFACE:
Ecotoxicological tests were performed on *FC-603 EFLight WaterTM ATCTM 3% in agreement with Novatech. The sample is a concentrate that normally will be used in a 3% AFFF/3%AR solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 1995/SFT 1998). The project wascarried out at RF - Rogaland Researchfor 3M Norge. All the tests were `performed by RF - Miljglab. Study director was SeniorEngineer Inger Lisa Andersen. The test results arepresented in separate sections. The results relate to theproduct as supplied by Novatech.
This test report is issued by a laboratory accreditedbyNorwegian Accreditation (NA). The accreditation states that the laboratory meets the NA requirements concerning competence, equipment and working proceduresfor all he test methods contained in the accreditation. Italso states that the laboratory has a satisfactory quality assurance system, which includes internal quality control schemes, participation in interlaboratory comparisons, and the use of certified reference materials and secondary reference materials.
The tests performedare cobvytheeacr crede itatd ion.
:
This test report may not be reproduced in anyform other than infull, without the permission in writing by RF - Miljolab.
002344
L5a9b3r1ef4ro.
Page dof31
TEST FOR TOXICITY
Marine alga: Skeletonema costatum
002345
5La5v31r3e4no.
ragBeseragp
iif
TEST REPORT
GROWTH INHIBITION TEST WITH THE MARINE
ALGA Skeletonema costatum
Aiil oh nr
oa RESEARCH
TEST SUBSTANCE: "FC-603 EF Light Water TM ATCTM 3%"
TEST RESULT:
-
`The 72 hours ECsp was calculated to ~170 mg/l. `The test substance was supplied by Novatech, and the test results relate to this product.
`TEST DETAILS:
Ev
METHOD: NwiSt-hESNkeIlSeOto1n0e2m5a3,co1s9t9a8t:umWaatnedrPqhuaaeloitdyac- tMyalruimnetrailcgoarlngurtounw.th inhibition test
TEST
ORGANISM:
Skeletonema costatum, strain NIVA BAC 1. organism is kept at RF - Rogaland Research.
A
stock
cultureofthe
test
PREPARATIONS: aNsatbuarsails sfeorawtahteegrr(oswaltihnimtye:d3i4um%.)TfhreomwaatnerunwpaosllfuitletderseidtethirnoBuygfhjaorGdFw/aCsfuilsteerd,
n`auntdribernitesflaychceoartdeidngtotoabIoSuOt 710525C3,prainodr troeucsoem,me`nTdheatsieoanwastferrowmatsheenPraicrhiedsw.ith
Commission.
>
.
Tmegs/tlswoalsuptrioenpsawreedrbeyprsetpiarrreindgf1r.o0m2a0sgtroacmkssooflutthieopn.rAosdtuocictnk1solliturteioofn gorfo1w0t2h0.
`medium, Other concentrations were prepared from this stock solution.
INCUBATION:
Torebsittaclulsthuarkeesr,o3f 5r0epmllicawteersefoirnceuabcahtecdonicnen1t0r0atmiionf.laTte-sbtotctuolmtuerdefslwasekrseoinnoacnu`laTtheedtetsotawbaosutr2un00u0ndceerllc/omnitifnruoomusalnigehxtpo(n>e5nt0iWalEl/ymgrsoewki)nfgrionmocfulluourmecsaclefruirtc--y tubesof universal natural whit type, at a temperature of 20 2C. `tThheetetessttfwlaassksruenacfhordaabyofuotr 7g2rohwotuhrsm,eaansdurseumbesnatmsp.leAslogfal5grmolwwtehrweatsakmeenasfurroemd by fluorescence. pH measurements were performed as indicated on data sheet.
002346
L9a9b5r1e2f4no.
Pageseoof 31
DATA ANALYSIS:
CALCULATIONS: Gverroswutshtirmaet,esawsedreesccrailbceudlaitnedNSby-EloNgIlSinOea1r0r2e5g3r.ession on biomass (fluorescence) ECs: Tcohneceinnthriabtiitoornyoeffafepctroodnuctthegigvrionwgth50of%Srkeedluecttoionneomfagcrooswttharratisee(xEpCrse)ss.edThasisthe e3f2fe0cmtgc.oncentration was calculated by interpolation between 100mg] and
NOEC: CfaacltcourlaAtNioOn VofANfOolElCow(eNdobOybBsoenrfveerdrEofnfiecptroCcoendcuernetrfaotricoonm)piasrdionngeebaychsingleconcentration mean with the control mean.
TESTRESULTS:
COMMENTS: VALIDATION:
T--a_b--le 1. EC and NOEC values obtT ainedTwith Skr eletonnemaocotstaetur.
TeTessttssbusbsttanccee
EECCo
BECCwh
EGECe
"W-F_aC---t6e0TM3rEAFTLGiTMght304"
-
10
100<ECRe320
NOEC: 100
GVVraaallpuueehssPiaanrddeicncaataetclo3n0ccenburyalirnitoaenrsptogliaevtiinodgn.10N% 50aO %raencdaE l3c0u%latC bedbiyowinogftghrocwoimhpruatreepUrnoigroammmeg
dTuhreinrgeswulhtiscahrethbeagsreodwotnh girs ocwotnhsirdaetreesdftoorbtehe etxipmoenesnptainal0 i-n7t2heh,cotnhterpoelrciuoldtures (see growth curves).
Tcehlel dveanlsiidittyyicnrcirteeraisaegdibvyenaifnactthoertoefstmoprroetotchoalna1re6 fiunlftihleletde,stinpetrhaitodthe control (vcorabreysrmpoonyrdeintghtaona1,g0rounwitths rdautreionfgmtoheretetsthaannd0,t9hed'7')2, thhoeurcsonttersotlrepsHultdsidwintoht 3,5-dichlorophenol was in the range normally found.
Lab. ref. no.:
`TSeasmtppleeriroedc:eived.: Report date:
993124
07-2100..0192..9999 10.01.2000
Els Yon
EElningiHnoererve Analytical technician
Teor
SeniAorgeReseMaorlcvherSscmiyerntist Quality Assurance ~
Enclosed: Data sheets
"Tfhoirsmaebterephoatnsinsusll, wbityhoutothretoprisscorneienwdrbiynNgorbwyegKiaFn- MAcicsridbi.ation (NA). Thereportmaymoroeproduocneyd
002347
LSoa3b1r3i4e
rage rop31
PRIMARY DATA: Growth Inhibition test with Skeletonema costatum Tost substance: FC-603 EF Light Water TM ATC TM 3%
StLaabr.daotte:: 0079.31122949 MeasCuornce.meunnti:t: TmhgeAbiomasswas measuradby fluorescence; values in fluorescence units
Gonconvaon | 1450 |B09I30R|G1E02R5 | 01T15H5]||Gr|odrawayte-sh
aoftPteHensdt
00 0o1i2|| oozss || o1s7s|| e4z 115292|| 01090s0
00 00010 || o0s3 || 1111 || e6a 114428|| 008888
00 00000 || 002256 || o0s9s || 7s 115416|| 009909s5
000099 || 002483 || 11725 || 6131 | {116478| |1o.s0s0s0
008 | 023 | 1 | a7 | |142]1000
000098
a2s || 1w1ss || | 1[16891 |[os0essm
o1
22 | 166| 1.000
=2 0011 || o03z
a032 115577|| 009s0s0e
2 oi | 03
88 152| 09%
11000 00101 || 0o3s1s || o077s7 || ssta 113492| 0[9o9s1e
100 oi | 0%| om | sa 139 | 0987
2a0 00090..7| | 00003s || o0o0ra || ooooss|| [[oooooo
-
2 006 | 00s | 002 | ose| [oo
1100000 || o0o0o9 || o0o0r3 || ooooas || ooooss ||| [oooooo
82
1000 or | 00s| 00s | ose| [oo
BelerTe5ncmeosnubs|tance0(039.5|dihloriopsh|eno 075 | 02| tssmmotn || 000088|| 0o1rs|| o0t1e2 || o02z ||
Moan va0es: oo | 03
7
302 00009s|| ooas
37
1200
o0t1o0 ||
03 03
9 5
210000 00007s || oooo
[Reference subst.| 008|013| 02 | 02|
|[o032s8|o0s8s8s [ose |os
Ta [05%
a
115722|| 0o9s8s9
156| 0999|1
001003008| 0388 |pLaroswonse
Somat fog
=e 002348
Soi Lab.ref no.
Page sof 31
GROWTH CURVES:
Test substance: FC.603
Growth
EFLight
inhibition test with
WaterTW ATC TM3%
La ot 999124 Skeletonema costatum
no cme
Ii
ihl
Ey ---
7 trnsnpen
No sew
iisll
i0
Lo
FZ msimoor
EN 10 mg
]i J
3
i1
Lat
e=
N wnsnsnoomn
17 32 mon i sf i
i1
2a
w= :
3 wsniontom
Ii34hi |
100 mg
i,
=
o est raionpoor)
Ll55n
320 mn
i
LF
ala otdratinPosie
Tlii
1000 mg
!| i31I a em
RS
_
002349
gf L9a9b3r1e2s4no:
Page9of31
wIinthhi:bition of the growth of Skeletonema costatum mg/l ( FC-603 EF Light Water TM ATC T 3%)
Experimental data:
FCCo-n6c0e3ntrEaFtiLoinghtinWater TM ATC TH 3% Growth rate
CCoonnttrrooll 21 CCoonnttrrooll 43 CCoonnttrrooll 6
Control mean :
331.2200 3120
1100.0000
3
10.00
3232..0000 32200
1100001.0000 10000
332200..0000 320000
+11000000.10000 1000.00
11.5292
-
114a8
od
114s6
1.45
11.4687 142
11.l8619 166
11.5577 1.52
11.3032 13s
00..0000 0.00
00..0000 0.00
Iinnhpiebricteinotn
--- 0ol.o0 1s 00.l0o olo 00X.00 oo 811.18 ls 1100002.00 10000 110000.000 100.0
002350
L9a9b3r1e2fr4o. 3
Page 100f31
5
3
3
@5 03
--
2
<3
ab
TEST FOR TOXICITY
:
Marine herbivore: Acartia tonsa
|
002351
La59b5r12e4po:
Page 11031
F TEST REPORT
ACUTE TOXICITY TEST WITH THE
MARINE COPEPOD Acartia tonsa
TEST SUBSTANCE: ~~ "FC-603 EF Light Water TM ATC TM 39
TEST RESULT:
The 48 hours LCs was calculated to 280 mg/l.
i The test substance was suppliedby Novatech, and the test results relate to this product.
{TEST DETAILS:
i MeTHoD:
ISO/DIS to marine
1c4o6p6e9po- d1s99(7C:opWeaptoedra,quCarluistt-ayceDae)t.ermination
of
acute
lethaltoxicity
i TEST ORGANISM: UAnciavretrisaittoynsoaf.C(oDpaenna)h,agseunpp.lied by the MarineBiologicalLaboratory,
-
CULTIVATION:
The
with
test
the
organisms were supplied
"Paris Commission - Rin
as. ggs,
g Test Pr
oatnodcowle"re(VcKuIl)t.ivaLtaerdgiencaocpceoproddiatnecse.
and adults were used in the test.
PREPARATIONS:
prior to use. Natural
as basis
seawater (salinity: 34 %c) from an for the dilution water. The water
unpolluted site in Byfjord was used `was filtered through a GF/C filter
:
Twmaegts/etlrs.woalOsuttphireoernspcaworneecrdeenbtpyrrasettpiiarorrneisndgwfe1r.ro0em0p0ar2esgptraocarkemdssooflfrutothmioetnh.prAoduscttocikns1olluitrieonofdoifl1u0t0i0on
is stock solution.
3 INCUBATION: The test was run in glass containers (28 mi rolled rim vials)cach containing
i
2
2Vi5almslwoefrteesktepstoluuntdieonr
and 5
a 16l
va8hnliightm/4draaerpkllpihcsoatt, eospefroirodcaacthactoenmcpeentrraattuiroen.o
The
f
"==
{
3 2da0ta1sheCe.t. pH and oxygen measurements were performed as indicated onthe i
002352|
5L9a5br1e2f4no.:
Pagsee 1201s2ef31
* DATA ANALYSIS:
CALCULATIONS: T2hperoedfufcetctloetnhatlhetosu5r0vi%vaolfotfheActaerttiaanitmoanlssa(isLeCx)p.resTsheed caosmtbhienceodncmeonrttraaltiitoyn of
peLstCrastnoedsavtradlcuopenrscoecanentddruatrtheieoPn9R5wO%eBrcIeoTunsfAeinddaelfynoscriescl,ailmNciuatltaiwtoeinoranel.cSaTwlheceduli2as4thehdEonbuvyrisursaoinnnmdge4nt3theahlouse
PcroontceecnttiroantiBoonasrldet(hValertsoio1n02%.3a,nd199900)%. oTfhithseptreostgarnaimmmales.also calculate test
:
NOEC: fCaacltcourlaAtNioOn VofANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingle-
concentration mean with the control mean.
i i
TESTRESULTS: Ta_b--le 1. LC and NOEC values obtaineTd wiTthT"FTC-603TEFoLimghtWWaatetre"TMrAATTCOTM g-,
AcAciardtiiaotovnsea
2h6 ohowurss
48 hous
;
Len
280 (130-380)
shows 8 (4-120
i
Loo
610 (490-790)
280 220-360)
i
L=o=n
NEC:
v>100 00 320
so88e0w-01-s105000)) ~ 150
.
cVaahlleeuucieloamtpeundtbeycpPrR1oOa0gB%rIa5Tma0mn%alGayrnsaidsp,h9aP0na%dde9n5h%aScloynfa0ifdeern2c4eanedra8saanees.indUincteedn.oNgO.ECVsleascaoreilebdy
: VALIDATION: TothxheyepgveearnlciCedoninttcyaegcnertimrtoearrtitiaaolngiiatvtyetnihnietnehtnehdceootnfetsrttohplerstoewtsoatcswolalesasrsgertefhaualtnfeir1ll0teh%da,,nianonrtdheatqthueathl4e8tdohi4osusmorgls/vle,d
4
LCso of 3,5-dichlorophenol (reference) was in the range normally found.
, Lab. ref. nou:
"i! Sample received.:
"Tei sRetporptedraitode::
993124
2009.99
0170.102.11.12.09090
5: # Enclosed: Data sheets
QL Ror
Elin Horve
AnalyEtnigcailneteecrhnician
ye Hoorn
Age Molversmyr
SeniQouralRietsyeAasrscuhrSacniceentist __
i{JfoTmhoerrethpaonsinellm,twbityhaobuotratthoerypcriesoindn abreyoNgordbwyegRieFnAMcicgrre.tion(VA) Toereportmy moeeprodoesdny
002353
if tSorseao:
Page130s31
i
PRIMARY DATA: Acute toxicity test with Acartia tonsa
Test substance:
LSatbar.t ceatt:e: Measurement:
"FC-603 EF Light WaTMtAe TCrTM 3%"
rTo.1o1.90 Nomborof ead
i
Number of
NUMBER OF DEAD
I
nTuomtbaelr|r`s.pevcesismoeln
24hours
48hours f
Concoenoinraton |swopree|A8cioFm|eA[n8|0| Tea [8A5ceF| Tou |
! Gani!
5ss5565|0000a00
000001
1
0000
0000
I
I
00 00 0
I 000 1 i 11 i
i
0
5i 6 5 1011
I
Il
5c s4 23 13
55 33
so Releocosisarce @oeophenoy
ia
Theresultwiththereferencesubstanceiswithintherange normallyfound,
7
*
|
002354
a _--
--
[oToe] Tost substance:
wnat
"FC.603EFLight WerTHATE Ta smorea
sara:
10.11.99
LP --
concnizion [Gog
a) (mon)
on | comm
i (mg!)
| omen
- (mon)
-
Co T e e e e e eeo e T e o e T TTe w e oea [wm Jw we [a]
torresstares 55nocprare),
_
Lo [no m oe] | [we]
i;
i
al
002355
9L9a3b1r2e4t:
# 3#
Page 150/31
i
TEST FOR TOXICITY
Marine Amphipode: Corophium volutator
| 002356 |
x L9a9br3e1t2n4o
Pa1g6ofe31
! TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE
MARINE AMPHIPOD Corophium volutator
TEST SUBSTANCE: "FC-603 EF Light Water TM ATC TM 30,
TEST RESULT:
-
The
The
10d
test
LCs was
substance
calculated to
was supplied
>3060 mg kg" dry weight
by Novatech, and the test
sediment.
results relatetothis
product,
`TEST DETAILS: METHOD: TAoSxTiMciEtIy3T6es7t-s9w0i,thStMaanrdianredaGnudidEestFuoarriCnoenSdeudcitmienngts1.0 day Static Sediment . TEST ORGANISM: Corophim volutator, from an uapolluted site near Trondheim. CULTIVATION: faTeeheredaittneegds.tsoeragwaantiesrmast w1e5rCe.suAppslmiaeldlaasmaoduulnttsof(4n-a8tumruamlinsseiazwee)eadwnad sweurseedelfdorin
PREPARATION: wNSatatasuvrauanslgeedsrefawowraapstreuerspae(srdailfniognrittdeyis:ltu3st4eido%inm)weanfttresro..mTaShneeduinsmpeeodlniltmuectnoetldliessictteedinatByafnjuonrpdoelnlouuttesdisdiee
analysed for organic content and proportion silt for eachatemsut.ddy sand and was.
bdBuaaccmkhpettsewestdacisomnsecnhetanktienrnaatfpiolorans3wtahicosubrupscr.keepTtah.reed1s5eb0dymiamldedoniftnsgwetaahsweadtipevrriodwdeuadcstianidnod6te0hd0rtgeerdabemtasheof
t4gh0he0tdm.alm1op0fssaenediiammawelnsattwwweeaarrsse atahndeadnleyrdsaetndodfeooamrclwhya,tsaeenlrdetcchotneetbdfeenoatrk,eeaarncsdhwabelleracekoeare,ratAedsaovmeprlkeerosf,
.
calculated as mg kg! sediment dry weight.
ncentrations aus
INCUBATION: ,
csToehndecitemenestnrttwa,taiasopnp..ru4nT0hi0en mgblleaaoskfsercssoenawtweaairtneeerrkseapn(td60u10n0dmeairn)icmeoaanlctshi,nc3uoonrutesapilainciantges20f0orgpoafcht.est
wg
tinedmipceartaetduroen
otfhe1d5ata1sChe.et,pHand
oxygen
measurements
eration at a were performed
as
i
0023577
iA Fobrtgno:
Paagee 1177031
DATA ANALYSIS:
CALCULATIONS: rmToahrtetiaoelnfiftoeycftaporpnrtotedhsuetcsctuornlvceitevhnaatllratotofi5oCn0or%wooepfrlteihuuersmetdevsoftloaurtncaiatmloacrullsiast(eiLxoCpns.r)e.sTsheTedheascthoemcboinnceedn.
i
P2va3Rl,OueB19Ia9nT0d)A.tnhaTelhy9iss5is%p,rcNooagntrfiaiodnmeamnlecSeawllesiodmiictsaalhrceuEclnaavtliecrutoelnsamttecenodtnablyPursoitnegcttihoens1Bt0oanaddraadyrd(CVeorsion
90% of the test animals.
centrations lethal to 10% aud
NOEC: cfCoaancltccoeurnltaArtaNitoOinooVnfAmNefOaonEllCwoiw(tehNdotbhyOebBcsooennrftverorelrdomEnefiafsenpc.troCcoendcuernetfroarticoonmpiasrdionngeebaychsingle-
TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-$03 EF Light Water TM ATC TM a5
Corophium volutator
10sys
LCi
9-760)
Leo
3060
= ry Noe:
o>w30e60 3060
cVVaaallleuueelssaaitneddicbcayatlheceu1c0lo%atm5eb0pyd%ePaRpnOrdBoIg5Tr0aa%nmaemlyebsCiarsayaghnfedear9d51%0scdoeonnf.i3d1Ue,nrciecmnemmeele5a"rssmeedmsie0mteWweneigtrhse
VALIDATION:
toThxheyepgveearnlciecdoninttcyaegcneittmreoarrtitiaaolngiitavtyetinhneitnehtnhdceootnfetsrttohlpesrtwoetesotrcewolalsaesrgsertefauhltafenirll1te5hda%,n.ionrTtehhqeautpatelhrecd0ein6st0saog%le,ved
msfooerrdtioamrlgeiantntyiiwcnacsaonr1te6ef.ne7tr%eb.nucte`tTshhueebsssietldtainfmcreeaocntftiou2ns0e.isd9rimsegcfooFumlnmudoerntaodnebtedhehwniiegthhkeirgn.adcWrceyepwhteeaidvgelhitmits
osebdsiemrevnetd)absuitgtnihfeimcoanrttamloirttyaliinttyheinhoignheecsotnccoenncternattriaotnio(n10w6a0smngotksgigndirfyiwceanitg.ht
Tabl2e. Charaocfttheseedirmeintussetdfoirtecstisng
mm contenm (%)
Sit fraction (%)
EE
07
08
--
LSaabm.prleef.rneo.c:eived. ; TReesptorptedraitoed::
92903091.2949 007-.1001..1220.0909
% i Enclosed:Data sheets
BEliun HoWrvaev AnalyEtnigcailnteeecrhnician
Holirsny Senior ReMsoelavrechrsSmciyerntist
Quality Assurance
002358 |
lSL ori
Page 180f31
fa
PRIMARY DATA: Acute toxicity test with `Corophium volutator
Test substance:
TeaSr aortu:m e
snrsisarsznes ts "FC-603 EF Light WateTMr ATC TM3%"
[
rTaoruetr|| `vSNupamobncemcreeonf
| (mcoonrcaenytwatoon)|| scpeacnimeen
Gono
0 1100 010
= oo
`NUMOFBDEEARD
soa
06a
oa | a8c5e| row
030000
}
I 060 = | EE)
i
l
Roerencesubsnce tonne;
EE)
209
30
21
Tod
7%b} i
_ Tee
002359
3 L9a9b3r1e2fr4o.
Page 19.031
Test substance: "FC-603 EF Light Water TH ATC TH 3%"
Lab. ret:
9124
{
Start date:
17.1299
Measurementsof oxygenandpH.
| concenration | Ongen oH
[e o=we [[ v Toew e oo[o e e e we we wfo e e we] o ] ]wu] (mg/kgdryweight)| (%)
-
Oxygen
(%)
oH Oxygen oH
"
(%)
.
[= Jv + = oT =] Reference substance (uoranthene):
&
002360 |
Labret.
Page 200f31
i
i
.
!
DATA SHEETS
&I
002361 '
Lpabtreefno:
Page 21 oft
| ss-oamaaLao (Helse, Miljo- og Sikkernetsdacabled) i T|o oeorksuumaesnstears.: 027077208977307 uSskgtiecvser ue:: 0131//I1L1//9988 VSeirdesion lav+ 03.010;
fTenlSe-fcoant:asl63ede84s o7x5 u00ter/beTeildeefsaxa:v M61ilj84eav1d7e8l8ingen ved M Norge A/S. :
+ IOITITIXIAOSN AV KISMIALIE 06 ANSVARLIG FIRE:
:
tagorser: au Norse A/S
;|
Handel2s0n8a0v3n:27 LIGHT WATER (TH) AC 3 AR-ATET
3i
Seteresjossnunmes, Produksagissesets
!
Telefo2n2,'sG3i1f3ei0n0fomssjonssentralen:
::
2 OPPLYSNINGER OM KJIMISX SAMMENSETNING.
:
Informasjon on enkeltkomponenter, faresymbol(es) og risikosetninger
storeuav
@snr vsz-ssoszur
v1a2n-emanor
Tt7ra3i1ns5 salsas
2-F(are2sy-mYbE3oTlOe0KzS/7Yr)i-s02iTkKAoNsSOeLtai/nges: Kai Ri22 112-345
"0
(OIFEeTzYesLyEbRolGeLrI/rKiOsLikHoOLsNeTtORaRi)Tnger: Xi Ri36
i
SFYLNUTGERTMILSKKYLOOVVEERRFFLLAATTEEAAXKTTIIVVEESSTTOOPFFZR TTrraaddee SSeecczreest eiolss il
PLUORKIZMISK. ARRYLAT
Trade Secres 103
i: TrRREuISeETsTEARNOALVAMOIRNGANISKE FLUORKENINALIER ZTrraadd1ee02-sS7ee1cc-rr6eett 'Tkke1s-Kj1ent
:
002362
SLa3rg1ino:
rage aor
FC-603EF LIGHT WATER (TM) ATC 33 ARearrE
ems]
i 3 VIKTIGSTS FAREMOMENTER.
|
Vikeigste skadevizkninges
i
SelsesSaarne:vaze farlig ved svelging. Ken frritere synene.
!|
Sikkerihec:
|i
MidjotSepzees:ialaviail.
roRsTearLasTILIAK
i:
Tilsak oyne:
uSnkiydldlelsstarzaek.s oynene med rikelige mengder vann. Kontakt lege
.
|
si1cakSkyhLuLdSteaks tilsolt toy.
Ehvuidsen smyemdprosmiegre
oopgpsrtihkse,ligKeonmeeenkstdelsegev.asaV.eskFefrinlselt
|
ii
toy for det brukes igen og kest tilselt skotey.
i
kcEkvosinpstoarksnsyemsplitengogems.si:ilodepnp.stdSev,sbrfionrgfvreidskkomlmuefne.dsfvbiosrtsfymrpatomene vedvarer,
|| i
TilcemkKeodsnivtesalkigtnisnklge:speessuosniedldle.lbaGris.aldFrriesknaolslgbireeninncianguemseksunSiilseenchbdavmiessdcles
|: |
person.
|
e 5 TILAK VED BRaSLURNING. e |
SnesPbrroadnunkstleutkneixngestmibdrdaenlnsslukkingsmiddel. | -
i
Ikke egnet branaslukningsaiddel
4} P
Eksponeringsrisiko ved brana:
002363
4 i L9a9br3e1f2r4o.
Page 230/31
FC-603EF LIGHT WATER (TH) ATC 31 AR-AFFE
1 Forbesaminssoradieer ved ram
Prosedyzes ved siukking av brann:
TILTAX VED UTitsixret ursires.
PessoSnelivgeernveetrinlestialktaukn:der andre punter i dette E=Ms-databladet.
TiltanJkoSnvgeeiidbleeussseinoldmsecidkdmieaertt.esuieSspslileli.lsp:eSpvielrlensseesaleusmiodpdpelbuamritd.deDekk til med a
onshdet med vann. Plasseres i en egnet beholderlmbeadrt,logRye.mgjor
FlemiSnegsuanvksk'j1e3m,ixFaljieersnviinaglla:v kjemikalieavall.
|
i
7 HBAeNDrTmZRaINGa OG 073zuARINGm . et |
|
!
Betine#g4etlsitkekrheefrolraglresegiseknkieidrloenorzp.igdbeeLvaragrrheivsnogr:vepdrodtuekmtpeerratkuarn uknodmemre kontakt med
bCeephsoiludse.zenLagtezsets
vleudkket:emnpbezraptruordeuskzoevte:ik0kegraedxeri
cels4i3usg.raHdeeisd beak.
|
Uforenelise materiales:
|
Ventilasjon:
Opsbevar emballasjen ph et godt ventilere sted.
Sikkerhesstiltak for 4 forhindre braaa:
|| SikkerThkkeesbsrteinlntbaaks.for 4 forhindre eksplosjon:
;
| Sikkerhetstiltak for 4 forhindre statisk elekerisiters
1| &
Forhoflodlsdreesmibearllvaesdjebnrukt:est Produktet kan zoyking
fluokrkkerts.akeRoyfkoirnugzenfosrnbiundgc:
Under
bruk
ay
02364
av tobekken oureller
Largo:
J
993124
o/!
ense3er rows an (50) x50 1 sen
TL2511E4 gdeuee,sspyrayoentter sti oyoee, ux seven
i
Sintr$Mgvt5ineTsianngearvepcnieobhaenrsikees apyvbesnasplsiicksamsennenstssiymacseassiasstieatve veed |t
sosScisngeom itndvares
|
rah Trine Rndedrestsvesn: av Luteaices sasasiate. ses.eet ph Komsemtraesone TDI entree: Salanis eatid Sr2Ze'atd tekeVsepkinees,edsikaelslaetsiorcosvekpekseswwaodeersaraosteeizidesded j
--Chreno-- sdeidisre et-- TtitnaeirreaheiisnnedazseLsriaiesnnsgeSnogSfeeor uosefpisssiiinlgse.seaekcieteist,oiafbseaq,gnnes
Nn. naeagdaaaisnifsocrzafciovmeennonrmiensgog/eaislseairdskaotnatorsotlelreer, sfparbaryaneslle1r996tske.
|
JR STE cnaenivin nen,
|
1,2-ETANDIOL (107-21-1)
ET8o-ptiimomeeresy rvpoesremtdiaSeeppemm:se:n-3)(0stev)
|
+=
(3Be ruge oTORS)gE EhTEL/ (reDsaEnvEacLaiOsnOtatRs. Tsv p)endus(e1m1e3e-n5,625) |
4 ald]
S|YNTETTIeSsKm eOVmERFeLAsTEAiKTsIVTstSe oTrOeFF(1(cTrade Secret)
|
00236k
La9b9r3e1f2r4o.:
Page25of31
FE-GO3EF Lica WATER (a) ATC 3% am-arer
Asmezkninger: Ingen adm. mers
TRISTANOLAMIN (102-71-5)
88--ttiinmeessss vveerddii mpeosmm:a:- 5
f
:
TYKNEARnSme(cTkrnaidnegeSre:creIsn)gen adn. norm.
i |
RESTERB-AtiVneOcRsGANvIeSrKdEi mFgL/UmOlR:IE0M,I1NALGIrZenAse(vTerraddse aSnebcerefte)lt av iv.
| !
9SeFYrSeInSKeSa0Ge XJZMISKE e ZGENSXAPERe , ee
Tilstandsforn, farge, Luks:
PE:
Xokepunke/-intesvall:
Saeltepunks/-intervall:
Flammesunke:
Selvantennelighet:
Gul/brun vaske.
7.5 - 8.5
<1s0c
Ikke relevant
Ingen (Setaflash)
Tkke kjent
i
i
i
-
:
|i
i
:
i
Eksplosjonsgrenser, ovre:
* Ikke relevant
i
|
Demptryiic:
Loselighet i vamn:
ce. 15.8 mug (Kalkulert v/20c) - |
Fullstendig
SPesLeikk veke:
ca. 1.05 (vana=1)
Damptatshes:
SL OND mates
Firkeise
orsantake
forbindelser
(VOC):
v/20C)
= 355 5/1
scAQMD
.
(Kalkutere
pe)
--
|
Fordanpningshastighes:
Ikke kjent
:
Viskositet:
|i
< 5000 centipoise
-
Hata ealean, ve
002366
La9b3r1e2f-r4o.
Page 26of31
FC-60JEF LIGHT WATER (TH) ATC 3% AR-ArEr
10 STASILITST OG ReaxTIviTeT,
Forhold som skal uanghs:
MateriIaklkeeskesonmt.skal vnngds:
|
Fazlise spaltaingsozocukses:
i
SSfooarrrvrueeanrntaeeoslnloiekkrakiepdeso&csirkeklpeersreb.soenndDtieeskrkoesmipdno.oneanrRiynrdigssoiagkveon.btrluu.ok.rsifde.rdiGsifSehiugnedidnasmes, i
SeabilSieatdeitleo.g Fraerslkissivoitleyrm:eisasjon vil like forekomme.
| i
SefekUzelraoyynees:rsisesion: cases.
symptomer
kan
vase
rednet,
hevelse,
smarter
og
|| |
Ettektes hud:
:
oSyaadptodmuedrirkraincasviaroen r(oecshteess, lhaenvgevlasreigogelKleirsegjentatt kontake):
i
|
Leaguesig eller gientatt eksponering kan fore til:
AogitsKiressi.sk hucssakasjon: symptomer kan vase rodhet, hevelse, blemmer |
|
Etekser inndading:
:
Hnoomeoen,kelksenovferoeekstgioln:ering som overstiser anbefalte administrative
]
i
beoP[vlhriavesxissec,tjklononisssnohegvevnnriae.gv,hessse,aocrmzeaasnlgnlteearlnvede,esyssktoveoimrmedmtie:nldhses:yjmoonpgsteovmineeer,ksktaarneedmeveaarrsteilhfoedelplienre, | = sTveenligge,tihoons,ti(negvsoglnuytseivnagi.er): symptones kan vase skrhet {nese og
EffektJoeytrseeefsovPrerslogedikunkgut:tetre,r:vmiesedroerfgfaankitsekre
Eek
fslouuorLkejveemrifkoarlsiteyrs,iersoonmr.fimnonrerscip,
|
ai
BUKSiBpYyEiEe,s boipnpyerteicto,F shelmoavthoeltogsia.atDaetffeFkorteelrissaonm phtveiercskehr eneealrorest, ! 02367 |
| La9b5r3e1f24ra:
Page270f31
7 re-6oaer Laces water (mw) anc 3% anoarer
veiledning. SP+viuevsliigsniieaasigaogkgenavryfnasyzgceeemneceri:cl:ers.ymptomer kaa vare redusers urinmesgde, blo AKo%soppmkieazssats.jn)oe:dnspsinyelmuuanncgoaenmntees.(kLaZunnngvaealbrmeeicnennhenosletilisgnegA,rssospnkusstkteiylvladneSssiklesartt,anfdgreiensmpmiaenrdgl,egeme: Hoste ope blod og lungedetennelse son kan vare Livstraente. Inforaesion on allezgi, ovesfolsomnet:
Keeftfzonkatiende esenskeper:
Arvestoftskadelige esenskapes:
Repzoduksjonsskadelise agenskaper:
AndzeoDZvelsesuktroaezdkeTjvpeeirnnrogikdeknuaiklnttigieeeds,sr,,i`nesnhnoeeclmresoneml:udsleoirngeuentnsgaenlkglaaenmsoalbfelskeoyrrlebeetorrsseelonigsiesklesaogemes i keappen i
Sedbrysaingsstofer (metabolitter), og Ken akiumcleres ved
Snfjosreamdtoaesnzbeersukkeeekrsspsoronanez`ifenokgzseup:to.snaecDrteitngogfoovrLeerlhfieegnrhgoeolrrdgianingliesnkveekijlefenldtuneoirnhkgei,lesaetekfafleiketrer
gVFEeoSnrTseckpeoulmblsleziesnbeeraf:volosiizadgieannngeins1k9e7o0gfublrnuadonererk.pjoepaIuiMlksaaslejipoein:deesniibosilooomdgsiatszkbeetiidlsetradede,nierharav
-
osm aheiders vise: ingen skadelise affekier.
12 ORPLYSNINGZR on MiLjoTARS.
Persi"sDeetltevtniess/ssitnceoldfofgeicistkeersntieekrdkberfyotrlbeatlrtehseebti:bslloolgoigsiksknendebdrybtrbyaerbta,rhemre.n brytes
sll
aDfielltujtooerektpjreon(dipukekartlaeiiresrceisnntoneme)h.moulldiegrenesn eilklkeererflneeredbroyrtgbaanrieskeog forblir {
OkotokDseittxeolosgtiosfkfeerdaetxa:minimalt gifeig ovesfor akvasiske organismer (100 002368
i
Lsabtret:
Page 280f31
TC-603ZF LIGHT WATER (TH) ATC 3% AR-ATEE
Andzebseksasdeovnicbkinoilnoggeiss,k mnieldjber:ytbashet: O30D0 5(Cahegaetrcsal (O3xiyogcehnemiDceamalndO)x:yge7n400D0e0manmgd/)k:s:216000 mg/kg; 530000 2100 ddeaggeezzss:: 437466000000 mmgg//kkgg;; 80D 28 dagers: 602000 mg/kg. Akvatisk gifeighes: 916000timzge/zLs; C50 for fisk (Fathead Minnow (Pimeshales promelas)): > 3408 mtiinzuescszesEsCS0ECSd0aphMniicraot(oWxa:te:124Flmega/l(;Daphnia-magna)): 480 mg/l; 24 tizers.ECS0 Alge (Selenastrum cepricornucea)): 170 mg/l. Behandling i renseanlegg: 3 timess 250, Activated Sludge Respiration Izibitfon: > 1000 s/t. Sery for aviailshbntering int. sieldende forsirifter.
13 FIZRNING AV KIZMIKALIZAVEALL.
NetodeS:pesfioarlafvjfeanlil.ngLaevverkjeanvifkaalllietaivlfaelnl:offentlis gockjent innsenles, mottaks- eller benandlingsanlegs for spesialeviall. AHnObVeEfDaRlAcTeZGOaRvIfa0l7l:sgArVupFpAeLrL: FRA ORGANISKE PROSESSER. OzNeDnEgRjSeArTiEnGgOsRaIidl0e7r,`06d:esAivnffaelklsjoznasmPiSdDlBeravogfekrotssmteosfifkeks., sipe, E0A5x-mkooddezelu0z7.06 03 Halogenerte organiske leseaidler, veskevaskes Aveallsoffnummer: 7151 Organisk avfall med helogen. Spesielle komponenter: inneholder fluorforbindelser.
14 OPPLYSNINGER ON TRANSPORT.
ADR-klasse:
-
sitters
-
002369
L59a3b1r2e:f4ro.
Pageuae 29of31
FC-603EF LIGHT WATER (TH) MTC 33 AR-ATIT
bokstav:
-
mazgaummes:
.
cerzeoxore:
O-ncames:
-
IeA-Klasse:
-
I4G-klesse:
-
40G-side:
-
Evens.
-=
rac:
:
-
ovsigeTiokepstlryasnnsipnoerss:faslig gods.
15 OPPLYSNINGER OM LOVER OG FORSKRIFTER.
Heskeesixert: SymbolES(LexS)Z:SKADELIG (XA) IanehoZlcdyelze:aglykol 22,5 4, 2-(2-butoksyetoksy)-etanol 10 3,
Triesenolemin 13 R-sesaFianrgleisg:ved avelging. S-secnUinnaggehs:inadnding av demp/spreytethke. Uangh kontaks med huden og
emyennednee.s vPAe:namaong ksotnotffaekre ilegeey.nenFei;z mskaynllstosftfrakpsh ghurduennd,igvmaesdkesstore Sotnzgalkesadmeedogsvtiosredmeennnegdebrehoslpdeereong vealnlse.r Veetdikestvteelng.ing, kontakt lege Yi-gru0ppe: Korz. yrkeshyg. luftbehov:
yi
OvrigOevoepnpnleyvsnntiengmeerrkoinmgmeerrkebeatsiekretttpehn:tidligere merkeforskeifter og vilo(b3g
:
Lab.refno.:
993124
Page 300f 31 age 300:
FO-032F LIGHT WATER (TH) ATC 3% pR-arTE
zeviderse meskeforsiziteer av auar 1933. Symsoi: Tagen TIonlneehcoalcdoelsa:nin1,2-etandiol, 2-(2-busoksyetoksy)-etanol,
aKavndvaamspe/spfraocylciegchvxeed. sUvnenlggihngk.ontKaekntirmreidtehruedenoynoegsee.yneUnnea,ghFii:nnmiannding Ksoonftteekrs liegoey.nenFei;z msaknyllstosfsfzakpsh hgurduennd,igvamesdkesstosreezamkesngmdeedrstvoarnes og sdeennndeerbenshooredesoegnvaeslal.erVeedciksevseclegni.ng, kontakt lege onghende og vis
Yoi-gruppe::
ST
Speste1l.leFozLsokvezrifeogombesusceamsmbeelisdeerl:se og distribusjon av Helse-, Hiljo- og
S2.ixFkoerzshiezsisfdtatoamblaKdlasfsorififsaerrliingge kojgeamiekrakliiaegr.av farlige kjemikalier.
k3.enFmoerdsfiozrietcmiolmjoKfieasses.ifisering, meckisg av. ev scoff som
5.. Foorrsscaziitfse oonn sscpoefsiikaalrasvoitaelkl..
-
& ze
16 ANDRE O2PLYSNINGER AV ZTYONING FOR BRUKERNES SIKKERSET OG HELSE.
AavendFeillsaedseannnzeinddees:skunkonsenteat for slukking av bana. VikeigDsetteeblKaidldef(rra) 0vedGenueicearlbeiOfdfeilcseesn, avSt.MisPe-adle,sebMliancneets:ota, USA.
ArsaEkSSteille_dodapatptadababltlaeadrdfieonrrgs:keexifreeavri,derfsa.stTaialtptasseJtannuyaer m1e99r8k.e-Seoeg.
Z5ne opplysninges:
|
Infornasjonen ph deste HMS-databladet ex i henhold til vice nivarends
oaipykpkeldyestotnfein&pgresoradmuoskgvtaebrresmteuedndoedpreptftnaeotmnmHieNnlSge_daaftnoagrbhlloealnddd.eet,Ernihkevtleilrgerbbrrsuuokka aomvgedfpheirrnoeddrtuekribierntugkesneavm
;
perxodburkutkeetzen|sksonmsbvianra.sjon med andze produkter eller sahver annen proses
i
002371
L9a9b3r1e2f4ro.:
Page 31of31
FC-603EF LIGHT WATER (TM) ATC 3% AR-AFFF
FOLGENDS PRODUKTER DEXKES AV DETTE HMS-DATABLADET:
3 10-nr.
X-0008-0223-1
3iMngAsFsEkEum/ATC PFrCo-d6u0k3s2j7onBrammslukn
3M 10-ne. 3M 10-nz. 3 10-ne.
+ X2-0008-0209-0
3M Light Fighting
WFaoatme,rd/FICN-A6F0F3EE/FA,T10C00FirLe
+
X-0008-0208-2 3M Light Waterl/3NAFFE/ATC
2F:ire
Fighting Foam, FC-603E7, 200 L
+: X7-0008-0207-4
3% Light Fighting
WFaoatme,rd/FICN-A60T3FEEF/,ATC 20FiLre
| 002372
