Document oegDRYR0GxrQboyLa17jYzno7

Annex 1: documents, data tables and figures referred to from the text Annex 1.1: Documents In 2021 the 5 member states working on the broad PFAS restriction under REACH have published multiple reports in which they collected information on the different uses and production of PFAS. Annex 1.2: Tables Table 13 Total fluoride emissions in Belgium (2017), source: https://prtr.eea.europa.eu/#/pollutantreleases Transfers per country Facilities Facilities Air (Accidental) Air (Accidental) Water Water (Accidental) Soil Soil (Accidental) Belgium 26 26 - - 118467 0 -- Bruxelles- 1 1 Capitale / Brussels Hoofdstedelijk Gewest - - 18300 - -- Lige 2 2 - - 919650 - -- Hainaut 5 5 Antwerpen 12 12 Limburg 4 4 East Flanders 2 2 Total 26 0 - - - - - - - - 0 0 18750 165340 22570 40060 - 1185 t 0 ----- 0 Table 14 Total fluoride emissions in Belgium per sector (2017), source: https://prtr.eea.europa.eu/#/pollutantreleases Transfer per industrial activities Facilities Facilities Air (Accidental) Air Water Water Soil (Accidental) (kg) (Accidental) Soil (Accidental) 1 Energy sector 2 2 - - 10350 - - - 1.(a) Mineral oil 2 2 and gas refineries - - 10350 - - - 2 Production and 5 5 processing of metals 2.(e) Production 3 3 - - - - 59270 18240 - - - - - of non-ferrous crude metals from ore, concentrates or secondary raw materials 2.(b) Production 2 2 of pig iron or steel including continuous casting 4 Chemical 12 12 industry 4.(b) Industrial 3 3 scale production of basic inorganic chemicals 4.(b) Industrial 2 2 scale production of basic inorganic chemicals 4.(b) Industrial 1 1 scale production of basic inorganic chemicals - - - - - - - - - - 41030 - 106858 0 931350 - 19350 - 912000 - - - - - - - - - - - 4.(a) Industrial 8 8 scale production of basic organic chemicals 4.(a) Industrial 7 7 scale production of basic organic chemicals 4.(a) Industrial 1 1 scale production of basic organic chemicals 4.(c) Industrial 1 1 scale production of phosphorous, nitrogen or potassium based fertilizers 5 Waste and 6 6 waste water management 5.(f) Urban 5 5 waste-water treatment plants 5.(a) Disposal or 1 1 recovery of hazardous waste - - - - - - - - - - - - - - 134520 130690 3830 2710 - 40980 38160 2820 - - - - - - - - - - - - - - - 6 Paper and 1 1 wood production processing 6.(b) Production 1 1 of paper and board and other primary wood products Total (ton) 26 0 - - - - 0 0 5490 5490 - 1185 t 0 - - - - 0 0 Table 15: Range, median and mean for each analyte in pg g-1 ww: detection frequency (%) for the food categories and total, for the individual countries. Median and means are calculated using the positive detects only. Source: D'Hollander et al. (2015). Table 16: (please see the excel file "List_substances_ShortChainPFASs.xlsx" below) The first sheet gives an overview of recently available information on short-chain PFASs from all over the world, regarding human biomonitoring (concentrations in blood, urine, tissues, ...) and ecological monitoring (concentrations in air, groundwater, drinking water, soil, ...). Information in the table is preceded by a number which refers to the scientific paper in which the information can be found. The numbers corresponding to the scientific papers can be seen in the second sheet. This table is updated each year with the most recent scientific papers, and is thus constantly adapted and following the newest information. Please save this `scPFAS_CCIEP_report' first on your computer in order to be able to open the link below. Table 17: List of fluorinated compounds from the EU regulation 10/2011 from 14 January 2014 regarding materials and products in plastic Substance name (Dutch) 1,1-difluorethaan Vinylideenfluoride Chloordifluormethaan Chloortrifluorethyleen Tetrafluoretheen Hexafluorpropeen 4,4'-difluorbenzofenon perfluormethyl-perfluorvinylether perfluorpropyl-perfluorvinylether ammoniumperfluoroctanoaat CAS number 0000075-37-6 0000075-38-7 0000075-45-6 0000079-38-9 0000116-14-3 0000116-15-4 0000345-92-6 0001187-93-5 0001623-05-8 0003825-26-1 magnesiumnatriumfluoridesilicaat 2,2'-ethylideenbis(4,6-di-tertbutylfenyl) fluorfosfoniet 9,9-bis(methoxymethyl)fluoreen perfluorazijnzuur, -gesubstituteerd met het copolymeer van perfluor1,2- propyleenglycol en perfluoro-1,1- ethyleenglycol, getermineerd met chloorhexafluorpropyloxygroepen perfluor[2-(poly(npropoxy))propaanzuur] perfluor[2-(n-propoxy)propaanzuur] 3H-perfluor-3-[(3-methoxypropoxy) propaanzuur], ammoniumzout 2H-perfluoro- [(5,8,11,14-tetramethyl)-tetraethyleenglycol ethyl propyl ether] perfluor[(2-ethyloxy-ethoxy)azijnzuur],ammoniumzout (perfluorbutyl)ethyleen 0037296-97-2 0118337-09-0 0182121-12-6 0329238-24-6 0051798-33-5 0013252-13-6 0958445-44-8 37486-69-4 0908020-52-0 0019430-93-4 Table 18: Non-exhaustive list of active substances following current PFAS definition authorized as plant protection products at ECHA Substance name Triflumoron/ tritosulfuron (ISO) (containing 0,02 % 2-amino-4-methoxy-6-(trifluormethyl)1,3,5-triazine); 1-[4-methoxy-6(trifluoromethyl)-1,3,5-triazin-2-yl]-3-[2(trifluoromethyl)benzenesulfonyl]urea (containing 0,02 % 2-amino-4-methoxy-6(trifluormethyl)-1,3,5-triazine) indoxacarb (ISO); methyl (4aS)-7-chloro-2{(methoxycarbonyl)[4(trifluoromethoxy)phenyl]carbamoyl}-2,5dihydroindeno[1,2-e][1,3,4]oxadiazine4a(3H)-carboxylate EC / List no 604-291- 0 605-6834 CAS no 14246914-5 17358444-6 CLH status Withdrawn Adopted isoxaflutole (ISO); 5-cyclopropyl-1,2-oxazol-4yl ,,- trifluoro-2-mesyl-p-tolyl ketone 604-2224 14111229-0 Adopted Submitted triflusulfuron-methyl; methyl 2-({[4(dimethylamino)-6-(2,2,2- trifluoroethoxy)1,3,5-triazin-2- yl]carbamoyl}sulfamoyl)-3methylbenzoate trifloxystrobin( ISO); methyl (E)methoxyimino-{(E)--[1-(,,-trifluoro-mtolyl)ethylideneaminooxy]-o-tolyl}acetate tefluthrin (ISO); 2,3,5,6-tetrafluoro-4methylbenzyl (1RS,3RS)-3-[(Z)-2-chloro3,3,3-trifluoroprop-1-enyl]-2,2dimethylcyclopropanecarboxylate 603-1469 12653515-7 604-2376 14151721-7 616-6996 79538-322 Adopted Adopted Adopted Classification adopted or proposed Skin Sens. 1B, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Submitter Slovenia Acute tox 3 H301 Acute tox 4 H332 Skin Sens 1 H317 STOT RE 1 H372 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 M- factor: 1 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Repr. 2, H361d*** STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Lact. Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic Acute Tox. 2, H300 Acute Tox. 2, H310 Acute Tox. 1, H330 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 United Kingdom Netherland s Italy France United Kingdom Germany Regulatory Program Active substance in biocidal and plant protection products Active substance in biocidal and plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Sedaxane Reaction mass of 3-(difluoromethyl)-1methyl-N-[(1RS,4SR,9RS)-1,2,3,4-tetrahydro9-isopropyl-1,4-methanonaphthalen-5yl]pyrazole-4-carboxamide and of 3(difluoromethyl)-1-methyl-N-[(1RS,4SR,9SR)1,2,3,4-tetrahydro-9-isopropyl-1,4methanonaphthalen-5-yl]pyrazole-4carboxamide; isopyrazam pyroxsulam (ISO);N-(5,7dimethoxy[1,2,4]triazolo[1,5-a]pyrimidin-2yl)-2-methoxy-4-(trifluoromethyl) pyridine-3sulfonamide pyridalyl (ISO); 2,6-dichloro-4-(3,3dichloroallyloxy)phenyl 3-[5(trifluoromethyl)-2-pyridyloxy]propyl ether picolinafen (ISO); N-(4-fluorophenyl)-6-[3(trifluoromethyl)phenoxy]pyridine-2carboxamide; 4-fluoro-6-[(,,-trifluoro-mtolyl)oxy]picolinanilide penthiopyrad (ISO); (RS)-N-[2-(1,3dimethylbutyl)-3-thienyl]-1-methyl-3(trifluoromethyl)pyrazole-4-carboxamide N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2yl]ethyl}-2-(trifluoromethyl)benzamide; fluopyram (ISO) N-methoxy-N-[1-methyl-2-(2,4,6trichlorophenyl)-ethyl]-3-(difluoromethyl)-1methylpyrazole-4-carboxamide; pydiflumetofen* 688-3312 632-6192 610-0076 605-8454 604-0300 606-0018 619-7977 817-8521 87496767-6 88168558-1 42255608-9 17910181-6 13764105-5 18367582-3 65806635-4 122828464-7 Adopted Opinion Development 000 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 2, H411 Skin Sens. 1B, H317 Repr. 1B, H360D Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 France United Kingdom Active substance in plant protection products Active substance in plant protection products Opinion adapted Opinion development Submitted Adopted Adopted Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Skin Sens. 1, H317 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Aquatic Chronic 2, H411 Pending Carc2 Repro 2 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 United Kingdom Netherland s Germany United Kingdom Germany France Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products N-(cyanomethyl)-4-(trifluoromethyl)pyridine3-carboxamide; flonicamid (ISO) 605-1270 15806267-0 N-(5-chloro-2-isopropylbenzyl)-N-cyclopropyl- - 3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide; isoflucypram* 125573428-1 Fluxapyroxad 620-0413 90720431-3 flutolanil (ISO); N-[3-(propan-2yloxy)phenyl]-2-(trifluoromethyl)benzamide; ,,-trifluoro-3-isopropoxy-o-toluanilide 613-9213 66332-965 flutianil (ISO); (2Z)-{[2-fluoro-5(trifluoromethyl)phenyl]thio}[3-(2methoxyphenyl)-1,3-thiazolidin-2ylidene]acetonitrile flurochloridone (ISO); 3-chloro-4(chloromethyl)-1-[3(trifluoromethyl)phenyl]pyrrolidin-2-one 812-8884 95864710-4 262-6613 61213-250 fluopicolide (ISO); 2,6-dichloro-N-[3-chloro-5(trifluoromethyl)-2-pyridylmethyl]benzamide 607-2856 23911015-7 flazasulfuron (ISO): 1-(4,6dimethoxypyrimidin-2-yl)-3-(3trifluoromethyl-2-pyridylsulfonyl)urea diflufenican (ISO); N-(2,4-difluorophenyl)-2[3-(trifluoromethyl)phenoxy]-3pyridinecarboxamide cyflumetofen (ISO); 2-methoxyethyl (RS)-2(4-tert-butylphenyl)-2-cyano-3-oxo-3-(,,trifluoro-o-tolyl)propionate 600-5140 10404078-0 617-4462 83164-334 642-9745 40088207-7 Adopted Pending Adopted Intention Adopted Adopted Adopted Intention Adopted Adopted Acute Tox. 4, H302 Acute Tox. 4, H332 Skin Sens. 1B, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Lact. Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, Mfactor=100 Acute Tox. 4, H302 Skin Sens. 1, H317 Repr. 1B, H360Df Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, Mfactor=100 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, Mfactor=100 Skin Sens. 1A, H317 Carc. 2, H351 France United Kingdom United Kingdom Netherland s United Kingdom Spain Austria Spain United Kingdom Netherland s Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant carfentrazone-ethyl (ISO); ethyl (RS)-2chloro-3-[2-chloro- 4-fluoro-5-[4difluoromethyl-4,5-dihydro-3-methyl-5-oxo1H-1,2,4-triazol-1-yl]phenyl]propionate benzovindiflupyr (ISO); N-[9(dichloromethylene)-1,2,3,4-tetrahydro-1,4methanonaphthalen-5-yl]-3-(difluoromethyl)1-methyl-1H-pyrazole-4-carboxamide 603-2918 691-7194 12863902-1 107295771-1 Benfluralin 217-4652 1861-40-1 [methyl(oxo){1-[6-(trifluoromethyl)-3pyridyl]ethyl}-6-sulfanylidene]cyanamide; sulfoxaflor (ISO) 4-{[(6-chloropyridin-3-yl)methyl](2,2difluoroethyl)amino}furan-2(5H)-one; flupyradifurone 807-3668 94657800-3 804-3738 95165940-8 3-chloro-N-[3-chloro-2,6-dinitro-4(trifluoromethyl)phenyl]-5(trifluoromethyl)pyridin-2-amine; fluazinam (ISO) 616-7125 79622-596 2-{2-chloro-4-(methylsulfonyl)-3-[(2,2,2trifluoroethoxy)methyl]benzoyl}cyclohexane1,3-dione; tembotrione (ISO) 608-8798 33510484-2 Intention Adopted Opinion development Adopted Adopted Adopted Adopted Carc. 2, H351 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Acute Tox. 3, H301 Acute Tox. 3, H331 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Carc. 2, H351 Repr. 2, H361d Lact., H362 STOT SE 2, H371 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Acute Tox. 4, H302 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Acute Tox. 4, H302 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Repr. 2, H361 STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Skin Sens. 1B, H317 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Belgium France Norway Ireland Netherland s Austria Austria protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection 1-[[](Z)-[[]2-(4-cyanophenyl)-1-[[]3(trifluoromethyl)phenyl]ethylidene]amino]-1[[]4-(trifluoromethoxy)phenyl]urea Metaflumizone (ISO) 1-(4-{4-[[]5-(2,6-difluorophenyl)-4,5-dihydro1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1yl)-2-[[]5-methyl-3-(trifluoromethyl)-1Hpyrazol-1-yl]ethan-1-one Oxathiapiprolin (ISO) (2RS)-2-[4-(4-chlorophenoxy)-2(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol1-yl)propan-2-ol; mefentrifluconazole 604-1676 801-2631 - 13996849-3 100331867-9 141778203-6 *The approval of these substances is pending. Adopted Adopted Adopted Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Repr. 2, H361d Lact., H362 STOT RE 2, H373 Aquatic Chronic 1, H410 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 United Kingdom Ireland United Kingdom products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Table 19: Non- exhaustive list of active substances following current PFAS definition authorised as biocides at ECHA Substance name EC/List no. CAS no. BAS number Product-type Approval start date 1-(3,5-dichloro-4-(1,1,2,2tetrafluoroethoxy)phenyl)-3-(2,6difluorobenzoyl) urea (Hexaflumuron) 4-bromo-2-(4-chlorophenyl)-1-ethoxy methyl-5-trifluoromethylpyrrole-3carbonitrile (Chlorfenapyr) Bifenthrin Fipronil Flocoumafen Fludioxonil -; 401-400-1 - -; 424-610-5 -; 421-960-0 -; 603-476-3 86479-06-3 122453-73-0 82657-04-3 120068-37-3 90035-08-8 131341-86-1 1314 66 8 33 34 1416 Indoxacarb (enantiomeric mass S:R 75:25) lambda-cyhalothrin Tralopyril reaction -; 415-130-7 - 91465-08-6 122454-29-9 64 41 1403 PT18-Insecticides, acaricides and products to control other arthropods 01/04/2017 PT08-Wood preservatives, PT18-Insecticides, acaricides and products to control other arthropods PT08-Wood preservatives PT18-Insecticides, acaricides and products to control other arthropods PT14-Rodenticides PT07-Film preservatives, PT09-Fibre, leather, rubber and polymerised materials preservatives, PT10Construction material preservatives 01/05/2015 01/02/2013 01/10/2013 01/10/2011 01/04/2018 PT18-Insecticides, acaricides and products to control other arthropods PT18-Insecticides, acaricides and products to control other arthropods PT21-Antifouling products 01/01/2010 01/10/2013 01/04/2015 Table 20 RMOA list of PFAS for which an RMOA either is under development or has been completed since the start of the implementation of the SVHC Roadmap in 2013 Substance Tetrafluoroethylene C9-C14 perfluoroalkyl carboxylic acids including their salts and precursors (PFNA/PFDA/PFUnDA/PFDoDA/PFTrDA/PFTDA) EC/list no 204126-9 206203-2 CAS no 11614-3 30755-1 Concern CMR (reprotox) PBT/ vPvB(reprotox) widespread use Follow up CLH restriction Undecafluorohexanoic acid (PFHxA), its salts and related substances Perfluorobutane sulfonic acid (PFBS) and its salts - CMR (reprotox) SVHC (withdrawn) ELoC (PMT) CLH restriction - ELoC (PMT) SVHC restriction 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol; bisphenol AF 4-chloro-,,-trifluorotoluene 216036-7 202681-1 (3,3,4,4,5,5,6,6,7,7,8,8,8- - tridecafluorooctyl)silanetriol and any of its mono-, di- or tri-O-(alkyl) derivatives 1478 -61-1 9856-6 - ELoC (ED) CLH CMR (carcinogenic) Risks of acute lung injury from spray No suggestion yet restriction 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propionic acid, its salts and its acylhalides covering any of their individual isomers and combinations thereof (GenX) 2,4,6-trimethyl-2,4,6-tris(3,3,3trifluoropropyl)cyclotrisiloxane (F-D3) 219154-7 - ELoC (PMT) 2374 -14-3 PBT (human tox) SVHC CLH Notes: reprotox = reproductive toxicant; PMT = persistence, mobility, and toxicity; CMR = carcinogenic, mutagenic, or toxic to reproduction; ED = endocrine disruption; ELoC = equivalent level of concern Table 21 PFAS identified as SVHC and on the Candidate list for REACH Authorisation Substance 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propionic acid, its salts and its acyl halides (HFPO-DA) covering any of their individual isomers and combinations thereof (GenX) ECno - CASno - Concern ELoC having probable serious effects to human health and environment (Article 57(f) human health) Perfluorobutane sulfonic acid - - ELoC having probable serious and its salts (PFBS) effects to human health and PFHxS Perfluorononan-1-oic-acid and its sodium and ammonium salts (PFNA) Nonadecafluorodecanoic acid (PFDA) and its sodium and ammonium salts Henicosafluoroundecanoic acid (PFUnDA); Tricosafluorododecanoic acid (PFDoDA); Pentacosafluorotridecanoic acid (PFTrDA); - 206-400-3 218-165-4 206-203-2 276-745-2 - 335-76-2 2058-94-8 307-55-1 72629-948 environment (Article 57(f) human health) vPvB (Article 57e) Toxic for reproduction (Article 57c) PBT (Article 57d) Toxic for reproduction (Article 57c) PBT (Article 57d) vPvB (Article 57e) vPvB (Article 57e) vPvB (Article 57e) Table 22: PFAS substances on the CoRAP list as of August 2020 Substance 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl) phosphates, ammonium salt (HGC-TLF) reaction mass of 2,2,3,3,5,5,6,6-octafluoro-4-(1,1,1,2,3,3,3heptafluoropropan-2-yl)morpholine EC/list no 700-161-3 473-390-7 CAS no - - HFE 7000 (Trade name: 3M(TM) NOVEC(TM) ENGINEERED FLUID HFE-7000) HFE 7100 (Reaction mass of 1,1,2,3,3,3-hexafluoro-1methoxy-2-(trifluoromethyl)propane and 1,1,2,2,3,3,4,4,4nonafluoro-1-methoxybutane), Process related name: HFE7100 3M BRAND SPECIALITY LIQUID Potassium 2-(3-trifluoromethoxy-1,1,2,2,3,3hexafluoropropoxy)-2,3,3,3-tetrafluoropropionate (MV31Potassium salt) Polyhaloalkene 484-450-7 422-270-2 - 444-340-1 468-710-7 754-12-1 Perfluamine Hexafluoropropene 206-420-2 204-127-4 338-83-0 116-15-4 Authority NL BE ES ES Year 201 3 201 6 201 9 201 9 Concern Suspected PBT/vPvB Suspected PBT/vPvB, Exposure of environment, Wide dispersive use Suspected PBT/vPvB Suspected PBT/vPvB Status ongoing follow-up suspended suspended DE 201 Suspected PBT/vPvB, concluded 7 Exposure of environment DE 201 Other hazard based informatio 2 concern, exposure of n environment, high requested (aggregated) tonnage, wide dispersive use BE 202 Suspected PBT/vPvB, ongoing 0 Exposure of environment IT 201 Suspected CMR, High conclusion Bis(nonafluorbutyl)phosphinic acid 700-183-3 52299-25-9 DE Amphoteric Fluorinated Surfactant - - BE Ammonium salts of mono- and bis[3,3,4,4,5,5,6,6,7,7,8,8,8tridecafluorooctyl and/or poly (substituted alkene)] phosphate ammonium difluoro[1,1,2,2-tetrafluoro-2(pentafluoroethoxy)ethoxy]acetate ammonium 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propanoate (GenX/ C3 dimer salt) Ammonium 2,2,3 trifluor-3-(1,1,2,2,3,3-hexafluoro-3trifluormethoxypropoxy), propionate (Adona) 700-403-8 700-323-3 700-242-3 480-310-4 HFE 7500 (3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2(trifluoromethyl)-hexane), processed fluid 435-790-1 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl methacrylate (6:2 FTMA) 218-407-9 - BE 908020-520 62037-80-3 DE DE/NL DE 297730-93- ES 9 2144-53-8 DE 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl acrylate (6:2 FTA) 241-527-8 17527-29-6 DE 2H-Tricosafluoro-5,8,11,14-tetrakis(trifluoromethyl)- - 3,6,9,12,15-pentaoxaoctadecane (TFEE-5) HFE 7800 (2-Ethoxy-3,3,4,4,5-pentafluoro-2,5-bis[(1,2,2,2tetrafluoro-1-trifluoromethyl)ethyl] tetrahydrofuran), Trade 484-410-9 37486-69-4 DE - ES 5 (aggregated) tonnage 201 Suspected PBT/vPvB, 8 other hazard based concern, exposure of environment 201 Suspected PBT/vPvB, 8 Exposure of environment, Wide dispersive use 201 Suspected PBT/vPvB, 3 consumer use, wide dispersive use 201 Suspected PBT/vPvB, 7 Exposure of environment 201 Suspected PBT/vPvB, 7 Exposure of environment 201 Suspected PBT/vPvB, 7 Exposure of environment, Wide dispersive use 201 Suspected PBT/vPvB, 8 Exposure of environment, Wide dispersive use 201 Potential endocrine 6 disruptor, Suspected PBT/vPvB, Other hazard based concern, Exposure of environment, Wide dispersive use 201 Potential endocrine 6 disruptor, Suspected PBT/vPvB, Other hazard based concern. Exposure of environment, wide dispersive use 201 Suspected PBT/vPvB, 7 Exposure of environment 201 Suspected PBT/vPvB 9 under preparatio n concluded ongoing ongoing ongoing informatio n requested ongoing ongoing informatio n requested informatio n requested conclusion under preparatio n ongoing name: 3M(TM) NOVEC(TM) ENGINEERED FLUID 2-bromo-3,3,3-trifluoroprop-1-ene (2-BTP) 627-872-0 2-[methyl[(nonafluorobutyl) sulpho-nyl]amino]ethyl acrylate (N-Me FBSEA) 266-733-5 1514-82-5 ES 67584-55-8 DE 201 Suspected reprotoxic, 9 potential endorcrine disruptor 201 Suspected PBT/vPvB, 8 other hazard based concern, exposure of environment, wide dispersive use concluded concluded Table 23: CLH processes on PFAS substances that are developed or under development Substance name* 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10heptadecafluorodecan-1-ol EC / List no 211-648- 0 CAS no 678-39-7 CLH status Opinion adopted Reaction mass of 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol and benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]bis[phenol] (1:1) Reaction mass of 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol and benzyl(diethylamino)diphenylphosphoniu m 4-[1,1,1,3,3,3-hexafluoro-2-(4hydroxyphenyl)propan-2-yl]phenolate (1:1) Perfluoroheptanoic acid Benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]bis[phenol] (1:1) benzyl(diethylamino)diphenylphosphoniu m 4-[1,1,1,3,3,3-hexafluoro-2-(4hydroxyphenyl)propan-2-yl]phenolate Ammonium pentadecafluorooctanoate 947-368- - 7 943-265- - 6 206-7989 278-3055 375-85-9 75768-65-9 479-1005 223-3204 577705-90-9 3825-26-1 Opinion Development Opinion Development Opinion Development Opinion development Opinion development Adopted Classification adopted or proposed Proposal: Repr. 1B, H360D Opinion concluded no harmonised class. for this endpoint Repr. 1B, H360F Submitte r Norway Sweden Regulatory Programme Chemical REACH Chemical REACH Repr. 1B, H360F Sweden Chemical REACH Repr. 1B, H360D STOT RE 1, H372 Repr. 1B, H360F Repr. 1B, H360F Adopted (5. ATP); Carc 2; H351 Repr 1B; H360D Belgium Sweden Sweden Norway Chemical REACH Chemical REACH Chemical REACH Chemical REACH Pentadecafluorooctanoic acid 206-3979 * Listed are only CLH intentions for substances under REACH biocide and plant protection products are excluded). 335-67-1 for which no RMOA Adopted has been Lact; H362 Acute Tox. 4; H332 Acute Tox. 4; H302 STOT RE1; H372 (liver) Eye Dam 1; H318 Adopted (5. ATP); Carc 2; H351 Repr 1B; H360D Lact; H362 Acute Tox. 4; H332 Acute Tox. 4; H302 STOT RE1; H372 (liver) Eye Dam 1; H318 established or is ongoing (CLH intentions Norway Chemical REACH for substances used in Annex 1.3: Figures Figure 3: Comparison of dietary exposure to PFIA (left) and PFOS (right) estimated by PERFOOD and EFSA (2012) for adults and children based on lower-bound (LB) estimates (upper figures and upper-bound (UB) estimates (lower figures). Source: Kenlow et al. ( 2013). Figure 4: Comparison of mean concentrations of PFAAs (pg g -1 ww) in 7 different food groups sampled in the Czech Republic, Italy, Norway and Belgium. Error bars represent the standard errors of the mean. *: levels < LOQ; /: not sampled. Note: the respective food groups can differ in composition between the regions. Source: D'Hollander 2015. Figure 5: Comparison of the sum of PFAA concentrations (pg g-1 ww) between the Czech Republic, Italy, Norway and Belgium in apples, pears and strawberries (ns: not sampled; < LOQ: levels in apples and pears from Norway were below LOQ). Source: D'Hollander et al. (2015). Figure 6: Contribution of the individual PFAAs (>LOQ) to the total sum of PFAAs that were detected in apples (left side) and pears (right side) sampled in the Czech Republic, Italy, Norway and Belgium. Pears sampled in Norway are not shown as all the analysed PFAAs-levels were <LOQ. Source: D'Hollander et al. (2015).