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eon material safety data sheet
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EXXON CHEMICAL AMERICAS P.0. BOX *17*, HOUSTON, TEXAS 77001
CHEMICALS Q5/14/0 division Of EXXON CHEMICAL COMPANY, division of EXXON CORPORATION
PAGE 1
SECTION I PRODUCT IDENTIFICATION ft EMERGENCY INFORMATION
PRODUCT NAME
Butyl Rubber CHEMICAL NAME
Isobutylene - Isoprene Copolymers CHEMICAL FAMILY
Isobutylene - Isoprene Copolymers
PRODUCT APPEARANCE Colorless to amber or milky white rubbery solid.
EMERGENCY TELEPHONE NUMBERS: EXXON CHEMICAL AMERICAS CHEMTREC
713-870-6000 600-424-9300
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
THE PRECISE COMPOSITION OF THIS MIXTURE IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE PILL SE PROVIDED TO A PHYSICIAN Of NURSE IN THE EVENT OF A MEDICAL EMERCENCY. THE FOLLOWING COMPONENTS ARE DEFINED HAZARDOUS IN ACCORDANCE WITH PBCFRIPIO. UOOl
Not applicable for this product.
For additional information see Section III.
SECTION III HEALTH INFORMATION AND PROTECTION
FIRST AID A NATURE OF HAZARD EYE CONTACT;
This product Is an inert solid. If In eye, remove as one would any foreign object. Particulates may scratch eye surfaces/cause mechanical Irritation. No hazard in normal Industrial use.
SKIN CONTACT;
First aid is normally not required. For hot product. Immediately Immerse In or flush affected area with large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention. No hazard In normal Industrial use. Exposure to not material may cause thermal burns.
INGESTION;
First aid is not applicable. No hazard In normal Industrial use.
INHALATION:
First aid Is not applicable. Negligible hazard at ambient temperature (-18 to 38 Deg C).
ACUTE TOXICITY OATA IS AVAILABLE UPON REQUEST
PERMISSIBLE EXPOSURE LIMIT; OSHA REQUIRES (29CFR1910.lOOO):
5 mg/m3 (respirable dust), and 15 mg/m3 (total dust) based on the OSHA PEL for nuisance dust.
THRESHOLD EXPOSURE LIMIT; ACGIH RECOMMENDS:
5 mg/m3 (respirable dust), and 10 mg/m3 (total dust) based on the ACGIH
TLV for Nuisance Dust.
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THISIUFORUFTIOU RELATES TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT EE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY
OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE IEST OF OUR KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE
DATE COMPILED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS
THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR
AGAINST PTENT I^IN '"mENt'" TV ^ *NY L0SS
DAMACi TM*T
OCCUR FROM THE USE OF THIS INFORMATION NOR 00 WE OFFER WARRANTY
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MATERIAL SAFETY DATA SHEET
CyM*Ci^S 05/14/85 PRODUCT NAME: Butyl Rubber
PAGE it NO. 301
PERSONAL PROTECTION
For open systems where contact Is likely, wear safety glasses with side shields. Where contact may occur with hot material, wear thermal resistant gloves, arm protection, and a face shield. Where concentrations in air may exceed the limits given In this Section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH/MSHA approved respirators may be necessary to prevent overexposure by Inhalation.
VENTILATION
Local exhaust ventilation of process equipment may be needed to control particulate exposures to below the recommended exposure limit. See personal protection recommendations.
SECTION IV FIRE & EXPLOSION HAZARD
FLASHPOINT DEG, F : 482 METHOD:
FLAMMABLE LIMITS-LEL:
UEL:
AUTOIGNITION TEMPERATURE DEG. F :
NOTE: Decomposes NOTE: Not Applicable
NOTE: Not Applicable
GENERAL HAZARD
Solid material, may burn at or above the flashpoint, and airborne dust may explode If Ignited . If thermally decomposed. flammable/toxic gases may be released. Toxic gases will form upon combustion.
FIRE FIGHTING
Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire . Extinguish the fire by cooling with water spray. Respiratory and eye protection required for fire fighting personnel.
HAZARDOUS COMBUSTION PRODUCTS
Oxygen-lean conditions may produce carbon monoxide and Irritating smoke.
SECTION V SPILL CONTROL PROCEDURE
LAND SPILL
Eliminate sources of Ignition. Prevent additional discharge of material. If possible to do so without hazard. For small spills Implement cleanup procedures; for large spills Implement cleanup procedures and, If In public area, keep public away and advise authorities. Also, if this product is an EPA hazardous substance (See Section X, Page 4) notify the U.S. EPA If appropriate. Recover spilled material and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
WATER SPILL
Prevent additional discharge of material. If possible to do so without
hazard. Advise authorities If floating material enters a watercourse or
sewer. If possible, try to contain floating material .
Skim from surface.
Consult an exp rt on disposal of recovered material and ensure conformity to local disposal regulations.
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MATERIAL SAFETY DATA SHEET
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MATERIAL SAFETY DATA SHEET
CHEMICALS os/14/85 PRODUCT NAME: Butyl Rubber
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SECTION VII TYPICAL PHYSICAL & CHEMICAL PROPERTIES
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SOLUBILITY IN WATER. WT. % at F
Insoluble
VISCOSITY OF LIQUID. eST at " F
Not Applicable
SP. GRAVITY OP VAPOR, at 1 ATM AIR-1
Not Applicable
EVAPORATION RATE, n-BU ACETATE-1
Not Applicable
FREEZING MELTING POINT/RANGE.0 F
Not Applicable
BOILING POINT/RANGE.0 F
Not Applicable
SECTION VIII REiHCTIVITY DATA
STABILITY?
Stable
CONDITIONS TO AVOID INSTABILITY
Not Applicable
HAZARDOUS POLYMERIZATION OCCUR*
Will not occur
CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION
Not Applicable
MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY
None
HAZARDOUS DECOMPOSITION PRODUCTS
Flammable hydrocarbons
SECTION IX TRANSPORT & STORAGE
ELECTROSTATIC ACCUMULATION HAZARD
No, but use proper grounding procedure
STORAGE TEMPERATURE," F
Ambient
STOfiACEfTRANSPORT PRESSURE, mmHo
Atmospheric
LOADiNG/UNLOADtNG TEMPERATURE,6 F
Ambient t
VISCOSITY AT LOADINGIUNLOADING TEMPERATURE,eST
Not Applicable;
SECTION X HAZARD CLASSIFICATION
U.S. DOT CLASSIFICATION
Not Regulated
EPA HAZARDOUS SUBSTANCE
Not applicable
ADDITIONAL INFORMATION
Not Available
AMOUNT LBS.
REFERENCE NUMBER
HDHA-J-OOOOI
DATE PREPARED
MAY 14,1985
" - -- 1 S(JPER
i FOR ADD 11IONAL PRODUCT INFORMATION CONTACT YOUR TECHNICAL SALES REPRESENTATIVE FOR ADDITIONAL HEALTH/SAFETY INFORMATION CALL 713-870-6885
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MATERIAL SAFETY DATA SHEET **************************
The C.P. Hall Company 7300 S. C ntral Avenue, Chicago, IL 60638
Emergency Telephone No: 312/767-4605
* _______________________________________________SECTION I________________________
Chemical Name: Butoxyethoxyethyl ester of mixed dibasic acids
Chemical Family: Ester Formula: Proprietary
Product Name: PLASTHALL 83SS
HMIS Number:
110 Gloves & Safety Goggles
SECTION II - HAZARDOUS INGREDIENTS
None
SECTION III - PHYSICAL DATA
Boiling Point (F): Vapor Pressure: Vapor Density: Solubility in Water:
N/A N/A N/A @ 10%
Appearance & Odor: Clear amber
liquid,
Specific Gravity: (H20=1 at 25/25C) % Volatile by Vol: Evaporation Rate: (But. Ace.=l) alcohol odor
0.990
10 N/A
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used): 285F (C.O.C.)
Extinguishing Media: C02, Dry Chemical, Water Fog
Flammability Limits: Not available
Special Fire Fighting Procedures: Wear MESA/NIOSH approved selfcontained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers.
Unusual Fire and Explosion Hazards: Water may cause frothing.
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value: Not determined by the ACGIH.
Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation.
Emergency & First Aid Procedures: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. affected skins areas with soap and water.
Wash
N/A = NOT AVAILABLE
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SECTION VI - REACTIVITY DATA_______________________________________________
Stability
Unstable:
Stable:
X
Incompatibility
*
Conditions to Avoid: Not Available (Materials to Avoid): Strong oxidizing agents
Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when burned.
Hazardous Polymerization
May Occur:
Conditions to Avoid:
Will Not Occur: X
Not Available
SECTION VII - SPILL OR LEAK PROCEDURES
Steps To Be Taken In Case Material Is Released or Spilled: Dike and contain spill with inert material (sand, earth, fuller's earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spill out ofall sewers and open bodies of water.
Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulations.
SECTION VIII- SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify Type): None required for normal operations.
Ventilation Local Exhaust: Normal room ventilation Mechanical (General):
Special: Other:
Protective Gloves: Impervious
Eye Protection: Splash goggles
Other Protective Equipment: Eyewash facility
(ANSI Z87.1, 1968)
Impervious apron
SECTION IX - SPECIAL PRECAUTIONS'
Precautions To Be Taken In Handling And Storing: Avoid open flames, excessive heat.
Other Precautions: None
Revision Date: 4/87 JTH 3578
Supersedes: 5/86 JTH
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