Document oe4Kgmr3zZJn74ZrKjd19dZ4w

-*h, h*. i c. rt i i-i u oHrti t uhih JsMttl r----T-----------------------------------------------------------------------------------------------------------------.--------------------------------------------------------- Dow Chemical U.S.A. Midland, MI 48674 Emergency Phone: 517-636-4400 PRODUCT NAME: C^gB.Qr^gNOXIDE^ Product Code: 14641 Page F -ctive Date: 04/15/87 Date Printed: 09/24/87 MSD: 000429 1. INGREDIENTS: Carbon monoxide 1007. This document is prepared pursuant to the 0SHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous' per this 0SHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: -311F, -191.50 VAP PRESS: Gas VAP DENSITY: 0.968 SOL. IN WATER: 2.3 ml/100 ml H20 SP. GRAVITY: Gas APPEARANCE: Gas, colorless. ODOR: Odorless. 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: METHOD USED: None - gas FLAMMABLE LIMITS LFL: 12.5 7. UFL.: 74 7. EXTINGUISHING MEDIA: Water fog -- stop -flow of gas. fires, C1I2 and dry chenifa] . For small FIRE ?< EXPLOSION HAZARDS: Extremely poisonous ga.s 1 Highly flammable. Do not put nut fire unless escaping gas ran be safely contained or contrr) l lsd. FIRE-FIGHTING EQUIPMENT: breathing apparatus. Wear positive--pressure, self-contained 4. REACTIVITY DATA: STABILITY: 6 IOC. (CONDITIONS TO AVOID) Ignition temperature 1126F, INCOMPATIBILITY: material. (SPECIFIC MATERIALS TO AVOID) Oxidizing 1 tinued on Page 2) (. . Indicates a trademark of The Dow Chemical Company f DO A 061583 CONFIDENTIAL -W. >4 | Cl U L M l- , 'i I-i i. Dow Chemical U.S.A. Midland, MI 486/4 Emergency F'hon: 517-676-4400 PRODUCT NAME: CARBON MONOXIDE Produr t Code: 1464 1 Page: 3 F 'ctive Date: 04/15/87 i Date Printed: 0^/24/87 MSD: 000429 7. FIRST AID: (CONTINUED) INGESTION: No adverse eT-fects anticipated by this route o-f exposure. INHALATION: Remove to -fresh air. If not breathing, give mouthto-inouth resusc 11 a t i on . If breathing is difficult, give oxygen. Call a physician. NOTE TO PHYSICIAN: Consult standard literature. Treat with 1007. oxygen. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE: Carbon Monoxide: is 400 ppm. OSHA PEL is 50 ppm. ACGIH TLV is 50 ppm, STEL VENTILATION: Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Lethal concentrations may exist in areas with poor ventilation. RESPIRATORY PROTECTION: Use an approved respirator. Selection of " a i r--pur i f y i ng or supplied--air will depend on the specific operation and the potential airborne coneentration of the material. For emergency and other' conditions where the exposure guideline may ho greatly exceeded, use an approved positive-pres^ure, s1f-rontained breathing apparatus. In confined nr pnnr 1 y von t i 1 >teri areas, use an approved pnsi tive-pressure, se)f-run la j ned breathing apparatus. SKIN PROTECTION: No prer->u11 one necessary fr'nm gas. EYE PROTECTION: Use safety glasses. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS 70 PE TAKEN IN HANDLING AND STORAGE: Avoid inhalation of gas. Store in a well-ventilated and protected area. MSDS STATUS: New MSDC. (r-' Indicates a bradorrarl 'll" Urn f.'-'W i .Ivm i o a 1 i.onii-- my 7 Informs I' i on Her ein T s i'i : vnn In `mml F a l I h , At i f fin Ida r r "n X; , F ..,--r ess Or' I mp 1 i ed I s Ma eje . f i n^u 1 i 7~i c-. T/ '..j i .Imu r -i i ^t 'iMon For' Further [nt'ninhnn. D0 A 061584 CONFIDENTIAL -M. A T E R I h U h i- b i i uA I A SHEtT Dow Chemical U.S.A. Midland, MI 48674 Emergency Phone: 517-636-4400 PRODUCT NAME: CARBON MONOXIDE Product Code: 14641 Page: 2 E active Date: 04/15/87 Date Printed: 09/24/87 MSD: 000429 4. REACTIVITY DATA: (CONTINUED) HAZARDOUS DECOMPOSITION PRODUCTS: None HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TALE FOR SPILLS/LEAKS: Clear area o-f all personnel. Wear self-contained breathing apparatus. Avoid sparks and fire which could cause an explosion. DISPOSAL METHOD: Controlled burning if possible. dissipate and dilute with air. Otherwise 6. HEALTH HAZARD DATA: EYE: No hazard from gas. SKIN CONTACT: No hazard from gas. /" INGESTION: No hazard from gas. INHALATION: Excessive vapor concentrations are readily attain able and may cause unconsciousness and death. Excessive exposure may cause carboxyhemoglobinemia, thereby impairing the blood's ability to transport oxygen. Excessive exposure may cause central nervous system and heart effects. Slight over'--exposure may cause headache, dizziness, nausea, visual disturbances and physical or' mental incoordi nat ion. Gross ovet'-e::posurp can cause asphyxiation and death. SYSTEMIC & OTHER EFFECTS: The NOEL (no observable effect level) is about 40 ppm. Repeated exposures to these levels are reported to have produced no significant adverse effects. Higher levels mxy cause serious adverse effects, even death. Birth defects are unlikely. Exposures having no adverse effects on the mother should have no effect on the fetus. Has been toxic to the fetus in laboratory animal tests. 7. FIRST AID: EYES: No adverse effects anticipated by this route of exposure. SKIN: No adverse effects anticipated by this route of exposure. ' .tinned on Page T) (n/ Indicates a trademark n+ The row rhemicil Pomn-my A 061585 CONFIDENTIAL