Document oMVoOXyR5R33wR4dGbkq49kGw

Er ay ron meron PFOA/PFOS Analysis -- A ---- -- ri en o-- oma1.0 -- ti arnt, 20 ocr sownot Table Of Contents Standard Deliverables Report Contents TphSaertsCaoonvfedhriasLrSedaenrdDnaerdldiDhveeRerepaorbtlleCrosvoeracpkag.eTrhecopnosindesrendcomgpeinls es allpenmetmetdsTape Como ect + Tableof Contents + CaseNarrative + Executive Summar-y Detection Highlights + Methods Summary * MethodAnslyst Summary * Lot Sample Summary + Analytical Results + Summary Report + ChoafCuistondy `Total Number ofPages al Testanexica 1 DEP2.SDWB-000052 CasDeaCN2a0r0r28a0tive TQuhaelirteysuMlatnsuianlc.luAdleldoisnutlitss hfoapvoertbheaevnefboeunednoremveieewteadlforreqcuoimrpelmieanntcseowfiNtEhLeAGLaabnordaatnoyr.y `exceptions are noted below. hTQnhoissptorenemsppoorrtt.astDhiiaollntnooofntbtfhaectrsoerupsrsao.dnudcfeodoienxocleepsthianvfeul,bwoisthopurtovtihdeedwrointecnaacphprdoavaalhoofstth1e laabcocrtatory lSTahabemorptalhtreoereAyrwaiatvtaaelrteasmnapdmerpRaletceuerpierpoetsfe4n.t9edCoinnhiMsarrcephor2t0,we20r0e8.recNeoivaendoamtatlhieesTewsetrAemaorbiscearvDeednvduerring sampla receipt. SA(nPtaFalOnyAdt)ai.rcadPssFtaOnSdairsdascwoemrmeeprrceaplarperdepuasrinegdtahnedacciod frodrmsooflutthieonc.ompound peruorooctancic acd Perfluoro-n-{1.2,34:C.lociancic acid vas troduced at th extraction step and was used as PainnRtOriSnot.deurcneadl asttatnhdeaerxdtrfaocrtqiuoannstitteaptiaonndofwaPsFOuAs.edPaerfalnuoirnot-e1m-a{l1,s2t,a3n,4d-a"rCdJoocrtaqnuaatnetstualtfioonnaotfe was `TDSehnaevmepsrla'emspElSxeOtsrPapcrDtoEisoNenLnCta-end0d0nA1n2tah.tiyssriesp:ort were analyzed forth targat anlytos by TostAmerca caFanorrdtiwidatgtseesre.xstarEamacpctlheedssuaasmi2pn5lge0s0imsiLsdpapilhkuaeodsetwieohxftt@rhaaccthiionsntaoammpacllhesitisqanaudcaiwrdidif,hiepmdriowoitrtohh a1enxmtcLraocontfdii6otn.ioHAnfCsteGsr1ho8eon sfianmalplveoliusmpeasissebrdoutghhrtou0g.h5thmoLcaurstirnidggem,etthhaenaonlalayntdesthaereexetluriaecdwisitahna4lymz.edobfymeLtOhaMnSoIl.VST.ho TDMahlecehMeotftOh2o0CdhsSBaalmomapnplkledssesopfrtohceosssaamdoremaatgreinx.t wTahteermsaptihkoedd wbiltahnksuwrarosgnaotne aGnadtep!reapta1re6drwoiphocriancgh limit for the target analycs. lEeavcelhsbwaetrceh wiitphrionpeasrtoadbwiisthhadLacboonrtaotloriyiC.ontrol Samples (LCS). The LCS recoveries forboth AnNaolayntoimcaalliCeosmwmeerentobsserved. Testanerica 2 DEPZ.SDWB-000053 EXECUTIVE SUMMARY - Detection Highlights Decaoozs0 enmETER Resour MJEANORTH PINTSHED 03/17/08 09:30 001 esroosA.. 00.00106m 3 ORSI-ENSEL7 03/17/08 10:40 002 earoys 0o.l01s8 ON-RATMAY PLANT EFFLUENT 03/15/08 08:30 003 reeroons 0o.i00s0 RuEmPaOrRrTING ours 0o.o00l50 uugg//nu 0o.o0l00 uugg/n o0.0w050 ugu/gnn nwYmTmIoCpN, oDmExX -11c--00001122 bDaEnN -11cc--00001122 DDEENN --11c--00001122 Testanerica 3 DEP2-SDWB-000054 METHODSSUMMARY Dac200280 enenETER MAeLmYoTnICA c/us/us, eron DB -1-0012 References: Dry OSpeevreartninTgrePntrocLeadbuorraetores, Denver, Facility standard TPRHEPOARATION Testanerica 4 DEP2-SDWB-000055 METHOD/ANALYST SUMMARY Dac200200 AayTIGAL memo DEN -1c-0012 mewsr Saqueline Bonnett: References: Dew OSpeevreartninTgrenptrocLeadbuorrea.tores, Denver, Facility Standard nasT om 003601 Testanerica 5 DEP2-SDWB-000056 SAMPLESUMMARY Dacaoaase wos swLIL E se weir s KRIIOOK 000021 wUaNwNaJ-mHsAeWO1RrTH FINISHED KOXOM 003 UM-RSHAY PLANT SFPLUBN oTorn(s)cdecalsod eveed1 ep Atos fore oenieg 0id tfcre hind. Ren155or bloiepracae. es pn ndoywpapiie loolf,bciis.,d,s i, , es, ep,pry ir,cn, so tal ct a. eo,i,hy, rpc ae,ut bastwepLED msdwee 0033//1177//0088 0103::1300 03/15/08 08:30 TestAnerica DEP2-SDWB-000057 Cash in Advance / Prepaid sales Client Sample TD: THNI-EAMORTE FINISHED me LDoatt-eSSamapmlpeled......: Prep pate..:. D0S3C/21070/20880-0090:130 03/24/08 DWaotrek ROredceerivf.e.d...:: `Roalysis Date:. KIKOHIAR 0033//2208//0088 DPirleuptiBoantchac#t.e.r.:: 21084336 Analysis Tine... 10:25 Method..........: DEN -LC-0012 Matrix.........: WATER pRrRoanETER eros R0e.s0o1u6r loom a RmEaPOrRTING ours 00.0010090 ugg//mL sT3ucRaRoaparToE. 134 PROS RpeEcRoCEvNeTry a RLEaCwOVsERY ((5500 -- 220000)) Testamerica DEP2-SDWB-000058 Cash in advance / Prepaid sales Client Sample 1:OWNS.mHE17 wie TDaotte-SSamapmlpe le..d.:.: D0A3C/21070/20860-1000:240 WDaotrek ROercdeeirve{d.....:: KIXOKIMA 03/20/08 PPrreepp BDaatcthe#......:: 80033/42343/600 Dilution Factor: 1 oAnaallyyssiiss pTaitme.e..:: 0183:/4228/08 Method... DEN -1c-0012 Matrix.........: TER PrhomnmETER ros. R0e.s0o1u8r oo RwEaPOrRTING ours o0.o00o90 vuaa/iin. su1R3RaocpRrToE 13c4 PROS `eREmCROcVaEnRTY. 8a0 pRErCOeVyERY ((5500 -- 220000)) Testanerica 8 DEP2-SDWB-000059 Cash in Advance / Prepaid Sales Client Sample ID: UN-RAIAY PLANT EPFLURNT wie DLoatt-eSSamapmlpele#d......: 0D83C/21090/20880-0080:330 DWaotrek ROredceeriv.e.d...:: 0K3I/X2O0M/I0A8A PPrreeppDBaattec.h........:: 8030/82443/2068 Dilution Factor: 1 AAnnaallyyssiiss DTiamtee:..: 1083:/5258/08 Method.........: DEN -1C-0012 Matrix... WATER e=nenETER eros _ R0e.s0o0u0r 0.015 uREPrORTING oars c0.l0o0t% wuge//Ln. suTRacRaoGparToSn 13c4 Pros vEReRcCoEvNeTr.y an uReocotvERY ((5500 -- 220000)) Testanerica s DEP2-SDWB-000060 SEIS 001 002 003 QC DATA ASSOCIATION SUMMARY Dec200200 Sample Preparation and Analysis Control Numbers TIX yemLHYoTDIC WATER DEN -1c-0012 WATER DEN 10-0012 WATER DEN -Lc-0012 LBERrCiHe rmaeTpcE 084336 084336 s0s4336 ws mows sosaio sosa1se sosaase Testamerica 10 DEP2-SDWB-000061 METHOD BLANK RERORT merc MCBlieLnott-SLoatmple...#:: DRA9CC220400208000-336 WorkOrder ...: KIAMSIAA Analysis Date...: 03/20/08 PPrreepp DBaattec.h..1......:: 60038/42343/608 Dilution Factor: 1 Matrix.........: WATER Analysie Time..: 15:00 rPAoRnETER. EY su1m30s4oopartoen 1304 205 Cfleetd i--e nig Rwesour w ReEeCROcVaENRTY 90 3ed re dr RwEaROrRTING ows 00..0010095 ugg//Lt, RLuaacrorvsmy ((5500 -- 220000)) vDReYmo1n6-0017 om -1c-0012 Testamerica 1 DEP2-SDWB-000062 LABORATORY CONTROL, SAMPLI EVALUATION REPORT enc 1Cl0i5eLnott-1Soatmp#l.e.d.:: DRSACC220400200000-336 Work Order #...: KIMSIAC PPrreepp BDaattceh.........:: 20038/42242/608 AAnnaallyyssiiss DTaitme.e..:: 1053:/1230/08 Dilution Factor: 1 Matrix.........: WATER ronovna.vETER Armooson.tun Perfluorooctancate (ApPO) PREECROCVEENRTY a917 07 LREuCiOVsERY G(50 -- 1B2O0)) (0-130) MDEETNHO1D6-0012 pbeE --11cc--0o001122 1su3r0R4oGparToE": 134 pros kBotmE(ms) _ med tesanv 9 8 7 pERcaNt R2ECOVERY 02 nt RecovERY L(5o0 u- i200s) (50 - 200) Testamerica 12 DEP2-SDWB-000063 LABORATORY CONTROL, SAKVLE DATA REPORT mene C1l6iSenLtot-LSoatrpBl.e.d.:: RDS9CC220100208000-336 Work Order #...: KINSIAC PPrreepp DBaattec.h........:: 80038/42343/508 Dilution Factor: 1 AAnnaallyysaiiss Tbiantee....:: 1053:/1238/08 Matrix.........: WATER = PhmAETER. _ APmrmoosnium Perfluorooctanoate (Pro) sedrokweer 00..220000 0.200 MwEAoSUnRED ours 0o.2s87 wagr/nt ols waft, m`PeEcRoCEvNmTy Memo s8t7 DDEmN -110c--00001122 a7 Dx 1-0012 s13ucmaRobwrTOsR RBeRcEoNvETRY 5 RLEmCwOrVrEsRY (50 - 200) 1304 prog 2 (50 - 200) Corue(ns)ue ort toe oi vdnr crn -- Testhmerica 13 DEP2-SDWB-000064 LABORATORY CONTROL, SAMPLE EVALURTION REPORT mic 1C0lSieLnott-LSoatmp#l.e.h.:: RDESCC224000020800-336 Work Order B...: KIAMSIAD PPrreepp DBaattec.h..4......: 80033/42343/608 Aonaallyyssiiss TDaitme.e.:.: 0153:/2268/03 Dilution Factor: 1 Matrix.........: WATER ronornAETER Avmrmoosnium Perfluorooctancate (Avro) sPEcRoCvEeNRTy o10s1 105 RELCmOaVrEsRY 305--11200)0 (0-130) pewmo10002 ppmEsw -110c--0000122 `Ts3ucmmeoapnrtoen. 1361 0305 vReEeCcOaVvErRY 5as Cwows:erred er og ro ttrshid RECOVERY L(5m0rT-s300) (50 - 200) Testamerica 1 DEP2-SDWB-000065 TABORNTORY CONTROL, SAMPLE DATA REFORT nee 1C05lLoitL-ocSta#map.l.et.d:: RDACC220400208000-336Work Order ...: KIMSIAD PPrreepp DBaattec.h..#......:: 0830/32343/3065 `AhnoaallyyssiissTDiantee...:: 0135/:2268/08 Dilution Factor: 1 Matrix...o.LLs WATER PRaETER msoewreer eprroosn 00.00220000 `AmPmeornfiluaorooctancate (PFO) olo2c0 MwEAoSUmRED ours o0.l0o2w0n2 wwaarftt, loam wat, vERcEMT 1m0a1coveRy 19055 DMNemi1on6-0017 DDEENN --11c--00001122 saucReRopGnrToEn _ 13c4 pros orsti(se:)pero tsaig PERRECCEONETRY o5ss ek 5d RLeocowvsERY ((5500 -- 220000)) Testamerica . 15 DEP2-SDWB-000066. MATRIX SPIKE SAMPLE EVALUATION REPORT wie 5LotL-oSta-mspalemple...#:: DDAICC210900226105-001 Work Order #...: KIRNIIAC PDarteep DSaamptleed......:: 0033//1274//0088 09:30 ADnaatleysRiesceiDvaetd.e..:: 0033//2188//0088 DPirleuptBiaotnchac#t.o.r.:: 81084336 Mateix.........: WATER A=RAMETER eros s1u3R0s4ogparTOeA 134 pros olomui)s:weeto PREECROCVEENRTY 584s RLemcaotvsery GG90 -- 11230)0 PREERCCOEVNETR.Y 0a ineaig 070od 7 ld_ MeDTEHNO1D6.-0012 -- Dew -1c-0012 RpErCeOsVsERY ((5500 -- 220000)) Testamerica 16 DEP2-SDWB-000067 MATRIX SPTXR SAMPLE DATA REFORT MISotL-oSta-mspalempl.e..4:: DDEaCC2L0E00228105-001 WorkOrder f...: KIRNTIAC DParteeppSaatmepl.e.d...|.:: Prep Batch #...: 0033//2147//0003 8084336 09:30 DAnaatleyRseicseiDvaetde...:: 0033//1288//0088 Dilution Factor: 1 Matrix.........: WATER PPraoRnETER eros . SAAMMOPULNET ASPTIK_E AMMEOADSNRED puITS 00..00005640 00..220000 00..119043 ~ uugg//LL ReEERCcOaVnETR.Y METHOD 85 DDEENN ---11cC--00001122 s3ursoaprtosn _ `eRuEcRoCvEENRTY.. a RLEaCrOVsERY (50 - 2007 1304 prOS 0 (50 - 200) owe._________________ Testamerica 17 DEP2-SDWB-000068 1 Adi as 1 |WE] ARAL i i ie BSERENL ERRIIMEESRHY2E8 Ep Ry | 58 Shy 35 | Fk H|||EEdELITR eaRglee: i rss LLLTHEERRD] remy P0!1 HH FEE He Pi RM FERRE] | dE y ee e NE | R 3 el3 RiEN JN eassE acsaE csessi 10YE"N8 NDfe FEAHAFEEEEC] LR [io SIT EE | | EE | EH 1S 2 G5e H HEE T ---- | Ailoe + i HHH 12 7| fel ky |i i El 3 `TestAmerica ' ft T. SamplTeesRteAmceeriivcianDgenCvheercklist Lot DC%0=m Date/Time Received: ashy Ooo CoNmamep&SaamplningSyite:_(ited, Wake NS ~ RFeotsosCohmopreecThheeSeriione.Fe Ne Quer: 75790 Special nsrctions: Quomind: a0 ohee T+iEnDsZToEnSeT: COICST MDTAMST +PTRST +OTHER Unpacking Checks: werny NtietmpveenwNeoscey Lg 0 0 1. Coolersessintact? (N/Ai handdelivered) fo,documenton CUR. 602 Chuinof stdpresetIfan,documentan CUR: Tits I-- oo#"6.3. BMoalliepshbsriocksenuapnld/soroarveisle?ak1ing? Ifdyeosc,admoecoutmeonntCoUnRC.UR. 05. Propercomsiner &preservausteid?v(efs. AachDoifSOmP#eDEnN-QtA-0003) Ifno,documoneCnUtR. 6.pifofl samples checked andmec remem? fo,documoenCnUtR #" 7. Sduoffciucmieenntt ovnolCuUmRe.provicdoedtfoaraPllManbaleyssispreqouecstoed?,(re. AttacDhomfeSnOPt# DEN-QA-G003) Ifo, 5. DidchainofcustodyagreewithlabelsIDandexnplsreceived?If no, documenton CUR. : 9. War VOAsamples lon headspace? Ifan,document on CUR. oo 10. WesVOA vispreserved?Preserve GCI of22oSThi oAscorbs icAcid 0 1.Did samplesreq preservation withsomtial? 0 12 1yes 011, 6dthesamples cominresinchoi? Iyes docamoneCnUtR oo 15. Seinenpresentindisbasv?Ie,ldoecumreseonCdUR b 14.CoIerfaiPcMobveofhourmerprooovdidfor cl requested MS, MSD a ti daplicats? no,document nCUR, nd 15 Rect dws 43borsot hecolton das? es, nly PAT 16. Are oes withshortholdin es resid? of 17. War uk Tm Ar(oTATu)renquedst? TesQtAameFOrRiMcSaSarmpi Receiving\Sumple Recerving Checks 4-12.07 revision anor : 20 DEPZ.SDWB-000070 SamplTeesRteAmceeriivciaDnegnCvehrecklist : Lat. DCwos CompanyName & Sampling Site_{Jnited, __DateTimeReceived Szohy Ofer WakecwNN I Residualchloinecheckrequired: -- Quamined: Ae Qe: 75790 . Special cons: a+mEeDTZEoSeT COT/CST +MDTAST + POTAST OTHER Unpacking Checks: Coolers: _ tepenwescey LY it vesho pr. somes Sm. ii Tis 0 0 1.Coolersealsintact? (N/Aif handdelivered) If no,documentonCUR. A oo 2. Cainof custodypreset? Ifno,document on CUR. 63. oo". BMootltilepshbarsoisksenuanpd/eoroarveilesa?kingy?Ief,ydeso,cduocumeonntCUonRC.UR. & 5. Propercontainer & preservuastedi?v(efs.AaDc of SOh P# DENe -QA-0n 003) 1fno, documoneCnUtR. e--0 6. ghofallsumplscheckedam meetreiemens? 1o ocumoenCnURt. #07. Sudfofciucmieenntt ovnoCluUmRep,rsonvdidceodftoar PalManbaloyrsiss preqrueostged.?(ref. AtaD cofShOP#mDENe-QAn-00t03) Ifo, &0 oo 5. 9. DViedrcehaViOnoAfccuastmopdsyawgirteheouwtihthelaabdelisIaDcIaefnd?,sadmpolecs ruecomenivCeeUdn?RIfno, docuomneCUnRt. 10. Wars VOAvis resrved? rset oI 04:2CoSodiamThess AscrbiAccid oa?T"1.Did spies quire preservation with diam ile? oo 12. yes 1011 idth samplescoinreso cine? Is, docuomnCeURr. 0 13. Seinenpresetin dissed bees? yes, documoneCnURt. b 0 14 lCsosmfeftcinbveofhormeepprorcoevsididnfor cotrusted MS, MSD omar plats? 1on docu onCUR,amd } 15 Rec>48hoowsr actthedcollecs tiond) t? 1es, ny PAM 16 Aresoswithht bin res ees? ob 17 Wasaquick Tor Around AT)requested? restanerica QAEdiSa\mp FRecOeivR ing\MSamSpleReceiving Checklist 4-12-07 revision. anor - 20 DEPZ.SDWB-000071 Co SamplTeestRAemceeriivcianDgenCvherecklist Lot DBC Login Checks: i reo oo 15.Sufi voleprovid for ssi peed?(ef, Ash Se ofSOPS DENA) 11 {oo 19 ctmictonveClUaRn,e arocvoifoPcglbtefrosreesrtocM,.MSDor i pct, dontonCUR. 0 20DciotnhseecPhoubmlfcrsordoyacnd.srecivedby"sloshed" sigs,de ndies? o ro 21 Ver pse we dao delves? 0 0 22 Were ARCEEmolsloggedforreferedsng? 0 23.Were tes gedcheckedagainstheCOC?Wichsamples weeconned? O4__ 4 oo oo 2. WasaRushformcompl or quik TAT? 25 WasaShor Holdfo completedforanyshortho? oo 26 Verspc schiviog ncsons nied heGenel Comments?1s,wtwere ey? Labeling nd Storage Checks: tt Ln Noo 28 Waste ont COCsignedadssw snes blers? No 2. Wersupe dsb chckedby secondpecs? Xoo 20. Vr mpc tr nd COC dlc fi dss lsby snd esos! 4 oo 31. 32, DeeI, Dt,ad Ti Weresickerforspc ivi omemss int vas os? susaff cachbo nde 1CDCTSc27 { oo 33. VereACEEmealssored eigrsl? Document any proobdilscreepamncises an the acions keto snole hemon Condition UponReceiptAnomaly Rept (CUR), "TP estamexicR a ------ am pi DEP2.SDWE-000072 34 i 4 EH LE | pA Hi op|| E=r 1 gl! rH | | | 2 soll:i5 |e e rrH i8i BE gl 12 A 5 10 EH i NS \ <iN2o ut is i iN tip 1E ELEHEJapbs}| PH SR ean I 3 4 E I ECEFE A FH * i" = I 3 a laTT T; 3| 7J204iH4El 8 3 3 13 PFHNaHiENlEHEe OE 5i3 : |; hs I | 53 ft 18-8309 | 13 Eg | i :