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LOSS PREVENTION/FIRE/BURNER MGMTJCEI REVIEW (Date: Tuesday, December 3,1996)
AUDIT TEAM:
Buck Bailey, Bill Franklin, Leigh Hill, Steve Janda
PLANT TEAM:
Leigh Hill
ATTENDING:
PLANT CONTACT:
Leigh Hill
WRITER:
Buck Bailey
INTRODUCTION:
Following is a list of recommendations from the recent Consolidated Audit at the Glycol 1 plant. These were developed from a standard Loss Prevention questionnaire, plant inspection, and discussion with the staff and the Technology Center.
OPERATING DISCIPLINE
Recommendations: 1. This topic was reviewed and there are no recommendations for iurther action.
Action Taken/To Be Taken: Responsibility
Expected Completion Date
Actual Completion Date
CHEMICAL EXPOSURE
Recommendations: M 1. Complete the CEI plot plan documentation to show the extent of the exposure area for the spill scenario. Set up a permanent PHA / CEI file to comply with the OSHA documentation
practices.
Action Taken/To Be Taken:
Responsibility
Expected Completion Date
Actual Completion Date
M = Must-Do
DOW CONFIDENTIAL Page 15
DO A 045482 CONFIDENTIAL
HR = Highly Recommended
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Cttl . INTERMEDIATE SUPPOgTINS CALCULATIONS Pldl or Protect Non*; 1
................ .
Replied ly: 7 Dd. Replied: 1
Ccse Numbw
Eeieaae Seenoto
1. 2EUEF DEVICE or OWES CALCS. input fteleoie Rot* Ob/min) Tim* to Poploto Syitem inventory. (min) Airborne Guontity for CE1, AOr Ob/mln)
2. GAS RELEASE CALCS. Cotcuiatod Rdo*e ftot*. flbAnin) Tim* to Deplete Syitem inventory, (min) Airborne Quantity tor CEL AQg Ob/mln)
3. LIQUID RELEASE CALCS. (MPE/VESSEL HOSE) Sop 1: UdJd now Sato tetoated
Cdaiated Diameter to Uh. Dedc On) Calculated UaJd Releaw Rate. Lcae (Ibfrnin) Time to Deplot. Syitem Inventory, (min) Uguld Releate Rate to Ure. L (tiltnln) Step 2: Tolot Uqdd Releaied Calculated Tata Uodd Retoato. WTcde Ob) Syitem Inventcry. Wtovt Ob) Told Uqdd Reliaie. WT (to) Steps: FractionFlatted Fraction Batted. Fv Calculated Rath Rate. AQfodc (to/mm) Time to DapMe S/ftem Inventory, (min) Akbom* djmtrty by floih to U, AQf (to/min) Step 4: Uqdd Pool Size Mom of Uqud Entering Poof, Wp (to)
Liquid Pool Area, Ap (ft2) StepS: EvaporationIrom PoolSurtace
Moieauior Weight, MW Cttaractetrttle Pool Temperature. T (*F) vapor FVenure at T>. Pvcp (pea) Vapor Pr*m* at T. Pvap (pea)
Step 6: Totcti Airborne awntity
Tim* to 0eptet* System inventory, (min) Alibeme Oudttity lor CEI, Ad Ob/mln)
A OVERFLOW/SPILL CALCS. St*p t: Uqted Flow Rat* ReteOMd
Caiojated Liquid R*tea Rate, Lcdc (to/min) Urn* to Deplete Syitem inventory, (min) Liquid R*t*a** Rate to u*e, L ObAnin) Step 2; Told Uqdd Seleated Calculated Totct Uqiid Reieaie. WTcdc (to) Syvtem Inventory, Wtovt (to) Totd Uqdd RetoOM. WT (to) StopS: Fraction needed fraction Rained, Pv Cdeuated ftadt Rato, AQtcdc Ob/mln) Time to Deplete Syitem Inventory, (min) Aktocme Quantity by Ro*i to U>*. AQf Ob/min) stop A; Uatidtaotsb* Man or Uqdd Bnterfng Pool. Wp (to) CdculatedUatid Pod Area Apcdc(ft2) Iksjfd Pool Area, ApCff2) StopS: EvaporaSenRem PoolSwtoee Mafecxicr Weight, MW Cbaroctetetie Root Temperature. T CF) Vdpor PreieiredTi, Pvcp (pea) Vapor Preeure at T. Pvcp (pda) Evaporation from Pad Surface. AOp (to/min) StopS: Told Airborne Oucmtty
Um* to Oepiete Syitem inventory, (mto) Akbome Quality tor CEL AQot Ob/mln) (CB-2 Syitem Vet-2.0-S/lfM)
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CONFIDENTIAL
Dote: 1/15/97
CEI2: THE CHEMICAL EXPOSURE INDEX CALCULATION SYSTEM
Rotoroneo: 'Chemical Erpoouro lnd*x Quid*1 - Sooond Edition, SopdntwtMS Corpora* Soloty and bm Provonoon. Tbo Dow ChomBol Compony
Her* rlU moo [gklsrln..xl.lclI2_T>g
Hot! or Proioet Nano: CLYCOL-I Location: LAD
HaR Suporlntondont or Matagon C. JACKSON St* Rovtow Roprorontattvo: BUCK BAILEY
ftopaod By: 1BCHHKL Da* Propaort 11/15/96
Rovlowod By: WICK BAB.EY Doto Rovlowod 11/21/96
LCASIDAtA Cat* Number RM*a* sconato Cbomlca Nam*
RoloaMSconatoOotcrtotlon
i Gar Soloes*
CWOfln*
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RELEASE PROM "" -- -
EMERGENCY RESPONSE PLANNING Dow IHG (ppm) ACGIH TLV-TWA (ppm) SIElppm)
ERPG-I (ppm) ERPG-2(ppm) BPG-S (ppm)
KANT DATA Total Qucrtftty tn Rant. Ob) Lorpost Sngt* Contanmont, Ob) ftouur* a( Contanmont, Cpdg) DISTANCES TO Soot):
I.PuPIc 2. Othor ki-eompaiy tooWfy 3. Non-compary plant a budnoa
PHYSICAL PROPERTIES Oporattng TomporOw* o(UqUd, Tt CP) Molecular Wtight, MW Norma Baling Point a liquid, 1b CP) vqm PtMPuro a Ti, Prop (pda UcMd Dondty a it, Bho Ob/ttS) Hoa Capdotty, Cp (Stu/tbCF) Hoot a Vaporization, Hv (Bhi/lb)
It. AIRBORNE QUANTITY ESTIMATION
SYSTEM INVENTORY, linvt (gal
1. FROM A RELIEF DEVICE or OTHER Akborno QuanRty, AOr db/mln)
2. FROM A GAS RELEASE Saugo PraMuro, Pg (pdg)
Dlanotor a Holo, 0 On)
3. FROM A LIQUID RELEASE (PIPE/VESSEL, HOSE) Proeon npo/Voaot? a Ho**7 Dlanotor a Hdo, D On)
Hoiait or Liquid Abovo Raoato Pant, Ri an
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A FROM AN OVERFLOW/SP1U PBMng a uaoocSng Rato (gpmi DKodaoaat2)
CHEMICAL EXPOSURE INDEX
Rolooro Sconato ARttomo Quantity. AQ (to/min)
CEI
Hazard Diilatoo. 10-1 (toon Hazerd Defcrvce, HD-2 (foet) Hazard Dtrtaneo. PO-3 (toon
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DO A 045485 CONFIDENTIAL
Writ Date: 1/15/97