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Air Sampling Fluorochemical Report
DuPont Washington Works -- Air Sampling Program Round 8
Exygen Research Report No. L0001448
Testing Laboratory
Exygen Research 3058 Research Drive State College, PA 16801
Requester
MUiRchSaeClorDpoArautciooinn
Barley Mill Plaza
LBaunicladsitnegr P2i7keRoaondmR1t261401
Wilmington, DE 19805
32 SO
5s ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page Lof7 600327 WoHnR,
|
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[ Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen
Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on r OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes
collected. Sample WWK-A-AMS6-E8 had sampler problems during collection. No results are
I reported for this sample.
`The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography
~~ / mass spectrometry (LCMS). The method employed is entitled "Method of Analysis for the [ Determination of Perfluorooctanoic Acid (PFOA) in OVS Airtubes by LCMS" (James Miller,
_ Exygen Research, February 17, 2003). The OVS tubes were separated into three fractions for specific fluorochemical analysis.
~ Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the
| first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD _ resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C
| was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (C10 Acid) was added as a surrogate spike to each fraction prior to extraction.
|" Instrument operating conditions can be found at the beginning of cach analytical run. Raw instrument data is given in Appendix A. Chain-of-custody information can be found in
| Appendix B.
I
ALL DATA CONTAINED IN THIS REPORT WAS GENERBAYETXYEGEDN RESEARCH
(-
Page20f7
|
600328
| Results Summary
-
|
SAarmpVloeudme(1)
c(magidma3
I
WWKA-A-MAMIS1-E808A
I
WAWK-AA-ASMS1-8ET8 cC)
16166868
1666
1
Z<0o.0000000086 00N0A07
| ud = A I-
cs AN E88 WWK-A-AMS2-E8 A
11j44a86h11
WIK:A-AMS2-E8 (Tota)
1
[
wKnAaAmSssEsSSA
TABS00
11440000 1400
r
AESE8 ct) ----
-
ican----e8
11552211
=<Z0o.0000000077
<0.00014
<Z0G0000000077 NA
000014 <Z0o0o000077
ARNE Tot) Two]
|
rWKAeAAANMrSSESEEeS30A
|
WWK-A AMSS-E8 (Total)
141144333111
<Z0o.oN00A0000077
TT Tv%owola____--1
NA = Not Analyzed. ration was below th quantiaton if, therefore the backup ration doos not requir analysis.
|
1. "<"is defined as not detected at or above the reported level.
| = 2. Sample results have not been corrected for blank results or control spike recoveries.
Fa Fo RR 3. Please note the following descriptions of the OVS sample tube fractions:
|
8A F[ r Exact--
c
land set beads extract (not analyzed)
.
ALL DATA CONTAINED IN THIS REFORT WAS GENERATED BY EXYGEN RESEARCH
- Page 3007 650329
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|
|
|
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
- Page sof7 620331
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| "Example Calculation
For sample WWK-A-AMS2-E8 A C8 Acid,
r
=
[31ngmlof 10001)
C8 Acidx (Lmi)x (Lug/ 1000 ng) x (1 mg/ 1000 ug)] / [(1461L)x (m3 /
= <000007 mg /m3
Signatures
FRAC Paul Gomnoly, LOMS Team Loader
los
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|
John M. Fiaherty, Vice President
| OtvertabMamba ContoiDanta
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James Miller
i
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ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
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ANALYTICAL DATA REVIEW SHEET
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LC/MS
[
Teves B Miler Ae zie
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Analyst
Sigfature/Date
Tob 10 Ploleaty
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Reviewed by
Un alf dh
Tgnature/Date
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Sequence Table:
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|
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loSfoTlDoouoe1ion5tt0il0beizspaepmbk
RRRFeCeao8ddd-d1doo0
LB1102 vVViiiaellalllss oooooooollliiiitseezss FrReaadddooo
LU1183 vVaiiaelll sl1r6 llIooovooonlnddsiicoess rrreocdeadol0
| 121300 vVviiieealll:lzso SoLoToolSoi00tseEieel FRroaaeddooo
|
3 Vial 32 solvent Blank Fpl0 22 OviaVl E21 Lo0o0o0n1i44d8e-n1s3 FtCo8d-1o0
| <3ZSi6 vvviiieaalnl:as oSDmoooooosllotoddpeeedsss rrreacedt-dooo
~ 22373 vvviiilla:l32 SsIo0ml'viSecn0tecmmDeaenk RFFoeBadddo0o
| 3S5i0 vvviiiealls:s SSSTmmOoiSas0s00oppbesmn rFFeeaddnoo
SB3 VWiaEll SSmitisoo bb Rmeeeddso
| Catibration Part Line Location SampleName Method
l 5ovviaallz SSo0e0 rmed0o
|
5 vVViiiaaalll:s4 SSST70D 3350000 0hpphb RRFCoe8nd-d1oo0
7 VViiaall?d Si10o1e000bpn RReesdcdoo
- 35510 vVViiaaalllis: SSmImDi2a%m00 heoeen ReRoonnndddooo
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Callev Update AF Update RT Interval
71 Rmepplacce ememrasse 2
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| LCS 12/30/03 5:24:45 PM miller
wld
Page 1 of 1
I
LC/MS SYSTEM AND OPERATING CONDITIONS
|
Client: Dupont
EXYGEN STUDY: _L0001448
Instrument:
Hewlett-Packard 1100 LC/MSD (LC/MS 5)
.
API-ES Interface - Negative SIM mode
|
Nitrogen: 10 L/min at 300C
Fragmentor: Variable; Vcap: 3500V
|
Computer:
Hewlett-Packard Kayak workstation
r
Software:
Microsoft Windows NT 4.0 Agilent ChemStation Version A.08.03
|-
HPLC Equipment: HP G1322A Solvent Degasser
HP G1311A Quaternary Pump
|-
HHPP GG113311634A ACuotlousmanmpTlheerrmostat
HP G1946A MSD
HPLC Column: Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3ym Column Temp.: ~~ 35C
|-
Mobile Phase (A): 2mM Ammonium acetate in OmniSolv Water
Mobile Phase (B): HPLC grade Methanol
Time
%A %8
-
|
0.0
6.0
1700
9300
10.0
10
90
|-
10.0
STOP
STOP
Post Time = 4 min.
Total run time = 14 min.
|
Flow Rate:
0.3 mL/min
I
Injected Volume: 5 pL
\
Pagetof2 0012
|
Go0338
=
i
I
lons monitored:
|"
Analyte C8 Acid (PFOA)
C10 Surrogate.
lon (m/z) 369
469
Extraction Date: December 30, 2003
Analyst:
|-
James R. MilleJr e assy
E3x0y5g8eRnesReeasrecahrcDrive, State College, PA 16801
Phone: (814) 272-1039, FAX: (814) 231-1580
-
pez 0013
0r0339
| TIunesDtreueme1n6t 1: 2L7O1M5S5S45 2003
|-
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[ | Aacnaa.lE yswiesthMoe eathod :: CaE:cs\r-H1P0C.HxEM\1\HETHODS0\21:25380:02136Fpm LC/4S analysis of perfluorocctancic acid.
- --WET 35,ECR73697 CHEWSTOR 77SSTET30FG3v0e000o05n APTES
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Mon, 5. Jan. 2004
0024
03:34:39 pm
Page 1of 1
GNNIS0
[_sSeammplee Nmaemee::sT> 1000 pob
:
Data 1le :C:\ECHEM\I\DATA\Chemstor\11772782\A151232\2C000007.
| AIIcnnasjterocuptmieeornnattoDrat|e :| m21C2io/lo3la0et/rs03 Dilution il
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| Asenga,iysmiosnMaethod | Gr:e\WsEcCHoEN\1\METHODS\123003F
[ERE A
32:58:56 pm
L/S analysis of perfluorooctanoic acid
SDT 59 EIC8873607 CHESTORT ETAT GIT APES, i SW Fri
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++ End of Reporetr
oT
u025
von, 5. san. 2008 03:17 pm
roe rot:
G003SL
[| wo [7 sSawmepilae Niaeve::STD 1500 ppb
1
Data file iC:\HPCHEN\1\DATA\Chemstor\11776198\A184576\FC0000.08D
"InAcjqecOtpioenrabattoer:: ngtruent |
1m2i/l3l0e/r03 p000414
= Dilution
ir
7:12:29 Bi Sevmqija.lpiNNoon..e n i s17
m3! vel. :
5 ul
| ArneaglyswiestnMoeathod : Cs:e\HaPsCH.EM\I\METHODS\123003F
[ Last Changed: 1/5/04
02:58:26 om
L/S analysis of perfluorocctanoic acid.
|-
SOT 358E10-36873(8G3H7ENSTORY 775SRATERS Tan.can TESNog SH Fag Var
ao
| oo
es
|
[|=
| woo
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|
SOT 459, EG=AERTI4507 CHEMSTORY11761GBATESSFCORRES) PLES, =ogSW Fig Var
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-
E z E i
| "820"acSiudrrogar 11459026.1139
78.1200969 15494709884
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DwslDl a3e6s9,, EBiXcC--d3e6s8..7:d3e6s9..77
or
[- revouss
-
ei EndofReport wer
or
on, 5. Jam. 2004 03:35:23 pmulZ6 Paige 1of 1 GHOBSR
R_ Sa=mple tame:solvent. blank
2
Date Eile Co\HECHEN1\DHTA\Chemstor 11772053\A349760FC000009 5
i
TE
aremlia Acq Operator + jmiller
VIhiaaldNeo.:=
su9l2?
|
|
Ercqi, vAweetLheosthod
|L. s&onVD-At0R.mGA WETHODS\Le 23003m
LMS analysis of perluorosctanoic acid,
r
EE
--
L- l=
-
i
7.294- C8 Acid
| | 200-
| ow
--
|
~"MSDT480,EIC=468.7:465.7 (CHEMSTOR 1772083AT3497610000003 0)
[l=200
PIES,Nog,SM,Frag: Var
rl[|
[|
=-=
wo
1501
| coors som arr
[a 30 Sn itov538
men
Vaaahpt
| signal
amiasa smeesismaiaegs
Ep -- Won, 5. Jan. 2008
0027 03:10:22 pm
vege 1061
GHD3ST
[|-- Ssaimpele Nmakme::L0001448-20
1
Data file C:\HECHEM\I\DATA\Chenstor\11775443\AL60512\FC000011.D.
| hIIonngsjteOrcutpmieeonnrtaDtaoter;|: 1mPCi20l/0l43e10r4/0|3 7:57:28 BA Sv5eiqaltiNNmeole. r | i1i
| ~ sdeial,utmioonos i+ reacton
il vel. |
sul
I LAansatlyCshisanMgeetdhod | C1:/5\/H0P4CHEM\L\WETHODS0\21:25380:0236om
Lo/MS analysis of perfluorooctancic acid.
|-
NST G58,EC=3887360(CHESTORT77STES ATSOSTEFa GO00070T) APVES,Nog: SW.FirVr
owe
wo
low
[| w
| =o
-|
"MDT
| eo | | ao
1200
| 10000
Es 5s 0 CHESe OR renare es er 469, sar. EIC=(4 CHE6 MS6 TOR. \177 7544: 39\A4 1606 5T2F9 C00. 00117 .0) cos.API-ES,Neg,SIM,Frag:Var
[| | oooe ao
r | amd I
Compound amount (ng/mL) |8Ho"AcSiurarogac 20.70708s
i
R.T. 8s1a07n7
Area r1a3n4s755
5
T
Signal HwSDoL 34669d,. BBiicC--a3c6e0.7:436699..77
_o
Fi PCO0414
CE of Report ee
Mon, 5. Jan. 2004
03:21:37 pm
u02y
Page 1 of 1
0355
02035!
[_ mSameple ame 100014481
)
Data ile iC: \HRCHEN\oLr\\17O75N50T2\AALG\E36C0\hFC0a00m012s.0
-"TbHraiidoeceipckrtpiialvnoie negia1d0l70ls
BAI A
r sneerl mE
su82
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-
PBsoeEmqivaLmioseoHteethtod:|2
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[| = -1
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|
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| scone
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Mon, 5. Jan. 2004 03:23:p2m8 u03%0 mes iot1
GHO3SE
|"_ SSiammppllee NIantnee::10001448-2
2
I Data file :C:\KECHEN\I\DATA\Chemstor\11775560\A64224\7C0000103
T
~
ADIIicnnlqsjutetOrciputoemineronanttdoarte
:|| am1c2io/lo3li0et/rd03 i
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BT u1 sul
[ I Asnega,lE yssiosoNsed thod | CTs:e\nEHcRsCoHE\1\ETHODS\012725380102361on
LC/MS analysis of perfluoroctancic acid.
r
SDT ESETCHESTORT 775538
TO RPES, oS Fira
r =o
|0
[=
rl| w-d |
[1] -
| SL
T3046 467 CHEcT Soro O45R A ET EFCOS TE0) APESiy8 Si Fevar
wm
ase. co
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-
1 PCO0414
Mon, 5. Jan. 2004
Jo3i
03:24:18 pm
Page 1 of 1
-
620357
Sample Name:10001448-4
| Sample Info:
1
Data file :C:\HECHEM\I\DATA\Chemstor\11772158\A138432\FC000014.D
I AIIcnnajsetcrotupimeoernnattoDrat|e :i| 1m#2i0/l03l04e/1r03 8:42:28 PM
VSTieoaqglLivNoon.ue |:
1is:
|~ sDielqutsioonos H+ hseston
Im vel.
sul
[=An=aivaCihsanNgaetdhod | G1:/\5H/0E4CHEM\1\UETHODS\10253:05083:8261pm
Lous analysis of perfluorooctancic acid.
[| - SDT ETT
ETAT osOy APESNegSW FagVar
I=
| 350
-}|lm
re0
:
[~
WSO 480 E5834887 CHENSTORY31721SSATS7BRGBAPFVECSE,NRogESaWTFrAagDV)ar:
8060. C105
~
| | 20000
| 15000
[|=
Lo| wo
| comoms moms wazrms nx. I nen 5 si5gan
| So20h"eSiuarrogac 3o3o4n727
F8a0n0 iJielso wMeDbI 346639,, BBiicce-3d6e8h.7.:73i6e9s..7
TTT end ofreport ee
| pcooa1a
Mon, 5. Jan. 2004 03:11:33 pm
u03z
Page 1 of 1
Gn0358
sample Name:u0001445-5 | bSaatmapleFilIenfo:SC: \HPCHEN\L\D1N77T5A61\7ACLGGhOSaO\nFCsO0t00o15r.D 1
|" fdmInjeeercgteiironegDeatase :t0: d1me2/3es0/03 8:57:28 BM
wSmpemq eLoine :
su1il5:
[7Brfeego, esooctoaee:+siSconacr-- etsom -- em
| cars anetrss of pesttuossactamote asia.
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=
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ax
[| | sooo wo
|" jE 2000
r
7
1
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8.076
------z ----------T ------ wo01e0Se.o
1
1
signa
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123582 MSDL 469, EIC=468.7:469.7
. I.
| coves
"ii End of Report ter
Jon, 5. dan. 2008 03:26:02 pm 0033 rage ior:
GHO359
[sSaammplee mNaemee::L0001448-7
1
Data file :C:\HPCHEM\1\DATA\Chemstor\11772271\A140288\FC000016.D
I AIInncjsetocrtupimeoennrtaDtatoer:|: pm1cioln2laelar/390:12/:205P3 M SvIenigqa.lLiNNnoo..e : 16n1
|~ sDielqutisoonnioa +irreson
vel.
sul
[Ane aiysis s Method Cw:i\HdECHEN\1\METHODS0\21:25380:02364Fpm
Lo/HS analysis of perfluorooctancic acid.
| i WSOT389, ECIRRTIIT wim resTSoOnAPES Fo, SW,Fi Var
2250
I 2007
| ms.
I | N 1500.
50
| wo
|
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WSO 460 ECE 5i4597 CHENSTORY7 17227\KIATZB: BFCORETNEo),3SAWPVFiErSVa,r
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[1] | a
[7] row
r soo
o [
Compound
z Amount (ng/ml)
|830AScuiedrogac 2317.511326
i R.T. 78.1207941
Area 20221294530
: signal
SNSDDL 436699,, EBiIcC--a3es6.87.:73:633.679.7
r
5 Ena of Report wo
| econ
Yon, 5. Jan. 2004 03:12:15 pm
Page 1 of 1 050360
[SSaimpele Nsaomee::10001448-8
1
Data file :C:\HPCHEM\I\DATA\Chemstor\11775675\A167536\2C0000.17D
IAnTcnjqgetcOrtupimeoernnattDoarte :+: 12mPC/iO3l00l4/eL0rA3 9:27:24 PM vSniegaq.lLNNiono.e o:::
I17s1
|~ aDiclautvioornrea +irsoacton
mil vel. :
sul
[teAnsatlysCihsaMnegtheodd:: C1:/5\/H0P8CHEM\L\METHODS0\21:25380:0236XFpm
| Lens analysis of perfluorooctanoic acid.
r
HOT 359, EC=388723597
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7289. ca.
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78208537 213471394 SMSDDL 346699,, BEIICC--36688..77::436693..77
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TT edotrepre ee
Mom, 5. Jam. 2004 03:27:27 pm 0035 Page 1 of 1
60361
sample samscanntasa-10 | sSeacmapleEilIenfo:\IRCHChaEnsoIn11717234\\ALO2208N\0C0T0001N8.0 1
SaBmeemr | Injection Date Acq Operator
oEf N : 12/30/03
: miller
9:42:25 PM
EarLe Seq Line
vial No.
:
sd1198:
| fr
AaE ca,imE ovnaon
L|rEoaGsksions woos
H 22002I 8
[ et-s anT atyasa ofB perluorssctanciEc SaciOd.S area ESSF
[I La
[7]| -
rl =
| ow
|=
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2
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5
I wo so. cross |
"MSD 469E,i 7:469.7(CHEMSTORN11772344A142208\FCO00018.0) AP NegE ,SIN,S Frag, :Var
| ao
Fn
| | 10000
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:
| pcooara
ST--
Mon, 5. Jan. 2004
0036
03:13:17 pm
Page 1 of 1
10362
Sample Nane:zo001ads-11
| Sample Info:
1
Data File 1C:\HPCHEN\I\1D17A75T73A3\\ACLGhS6e4\mRCs0t00o01r5.\D
|
"
-
EiIenjreecateiotn oDate
|l : m11 b2im /t3e0s/03 9:57:25 PM
SSnehqiLveiane:
I
|"
Rseeqi,yemd TeemoHsachodS |+ CsCe\sRiP0OH0ENL\WETHODS\s1e2i30n0e380om
20/45 analysis of perflusrooctanois atid.
I TE ESET CREO TSAR CORTE PES
sa139: SW Fr
r= p"
r | ~-Low=ewlliI reer J a, |
"MSD1469,EIC=488.7.460.7(CHEMSTORI 1776733 A 160664FC000019.0) API Neg,-SIME ,FrS ag:V,ar
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|
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i= * | - 2000| compouna_ Soha
T
I
T
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mmeune gris mr. een
signa
oe
To im Wot 363. rosea nian.
--
IR
| scooese
o #** End of Report ***
EE
won, 5. Gan. 2004 03:28:22 pm u037 rage ofl
GOODIES
[J EmT a
:
Data file 1c: \HPCHEN\I\DATA\Chemator\LLTI2417\ALE3936\FCD00020.D
| Diipneoesrs:rLfor Ii So re onyeee
5:
. Bi +
ERR
sul
Entoet | W GeERTe.n
rr a aint 1 wems analysis of perfluorooctanoic acid.
[|=
1 om
wo
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|
"WSD1 469, EIC=468.7:469.7(CHEMSTORW 1772417AT
wo
| 250001
-| | ed
| 10000.
rl = r.
Gogh, Se
T wots yal 5. meas
Tan heme
|
20.0) APNIeg,-SIME ,FrS ag:V,ar
085 - C10Surrogate
|
I
1
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went ves, mimesis
r I| ~ rcooass
TIT er Raper RTT ---- Mon, 5. Jen. 2004 03:13:52 pm 0033 Page 1 of 1
650364
[_.Ssaammplee Noaeme::solvent blank
1
Data file :C:\HPCHEM\1\DATA\Chemstor\11775790\A171520\FC000021.D
I AIIcnnajsetOcrtupimeoernnattoDrate :+ 1j2C2mO/i03l40lL/eA0r3 10:27:27 PM
SvIeinqja.lLiNNnooe..
:
+
2511
Dilution
iY
mil vel. :
su
| bAnaalysCihsanMegtehdod":| C1:73\/H0E4CHEM\I\METHODS0\21:25380:02.36FXom
1 toss analysis of perflucrooctancic acid.
| =WOT ECR
TORT
Ty
APES No, SW Fig Var
[I 207
[=]
|=
r| o wdow
[ow
| - OT49,E488i4897 CHENSTORI11775TSORITEZIFGIO:00210) APioT i,SW,SFra:;Var po
|0
0
|
I] -
roe
~0 | compound
z amount (ng/my
| 810"acSiurdrogac 0o.o0d0
I mT. 00.000000
Area 00
i
5
=
signal
NMSSDD 436639,, BBIICC--346688..77::346699..77
f i
0
| PCO04LE
TT endof Report wav
Mon, 5. Jan. 2004
0039
03:30:14 pm
Page 1 of 1
GNO36S
sorte nomecon0RA-12
| Sample Info:
1
| anor "Injection Date Tne : 12/30/03 10:42:25 PM we Seq Line :
222
UticRdiegenT . sownN Les amstyata of oEluorosciamnic acid.
| 1 aw
|] mr
pe SET
|
I. | - 2000
[|
r= | aw a------------p--o--------
[ee
[7]
[| oxo
1|
1 | wo
H[o
:
A
[S3 eeses5a% T pig ia mm
!
:
7
=
sion
eambv mseeamTaane
| | C0014
+++ Bnd ofReport +++
Mon, 5. Jan. 2004
u040
03:14:42 pm
Page 1 of 1
Gn0366
= . Semple Nune:L000448-14
:
Data File 20 \APCHEN\I\DATA\Chamabor\LLTTSOAT\ALTISO0NPCO000283
[ifloeftpeepreetser i fnses ss gSwemem1Bz?
Be Hh
ne
| rfeomeormOon R zenctAom --------
sul
|
EEL
seins smatons
of
pSeistaiacssossane
en
seid.
RC
[] =
|
260-
;
240
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J.
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"MSD1469,EIC=468.7:460.7 (CHEMSTOR\1 177584T\AT73606AP\I-FECS,0Ne0g,0S0IM2,F3ra.g:0Va)r
.5000:
|
| 20
| coos moms arms mr. ween
siomat
e | SrtrT oons 38%
T TEEahBie ewme aieS, mBeEneTTIaSe
| scooase
+++ End of Report **+
TTT
0041
Wom, 5. Jan. 2008 03:31:16 pm
wage orn
GROBET
| Sample Info:
1
| Injection Date : 12/30/03 11:12:23 BM
Seq Line :
24
Tw5= ms= es ire
cl z=
[| ==
|
[=:
|
"| Lo
"MSD 469, EIC~468.7:469.7 (CHEMSTOR\I 1772563147584FC000024.0) API-ES, Neg, SM,Frag: Var
i
8.089 - C10 Surrogate
t
|| | 15000 r|l | =
Ho
cont ot
|| vr ia.m --- :
:
| PCO0414
STITT
Mon, 5. Jan. 2004 03:15:32 pm
Page 1 of 1 Gn0368
[Esammple Nane:L0001848-17
:
sata file C:\HRCHEN\1\DA17T7A30\39C\Ah1e65m28s\FtC0o00r02\5.D
" p Iia njeecte iron Date L :f HA12/i h30/03 11:27:24 PM nSumeoqmeLiene :
su2554
| I nfeqo,rmiore moa + rSaevenst------on
| sors nateats of pertrsseasceanets scss.
|"
ET CRESTOR
57 es SF
Low
| = 2]
[=
7.291 C8,
w
[1] wd
| i re 7 ermr: ds TT weesse=
| 10000]
a101- C10 Sump
[I
| vo
| ne |
||
| w-
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Shela oe
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i100 141968
1
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MSDL 469, EIC=468.7:869.7
ST
| -J--
"<< Endof Report i+
TTT
Mon. 5. Jan. 2008 03:19:57 pm u043 Page 1 of 1
Gn0369
Sample Name:$TD 500 ppb
| Sample Info:
1
eTocletriatoen jmaatanr rT fwree Data file :C:\HPCHEM\1\DATA\Chemstor\11772980\A155072\FC000026.D %:S
ie i
mL su
[ | seE g, shR eau.nd L|reEonSS ctom AETHP ODS\1E 23L 003m 8
LerHs analysis of porfluorocctancic acid.
|-
pal
r
| oe | |
-
fIL|. o=o--.o 3 TR or tetra,LC ---- |
"MSD1469,EIC=460.7:460.7(CHE 177M 2000S A18T 5072OCO0R 002I 6.0) APNogI,S-IM,EFraSg:V,ar
[7] ond
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TT mT
vU44
won, 5. dan. 2006 03:10:p5m0
ge 1oe1
GHOBTO
| Sample Info:
1
| Injection Date : 12/30/03 11:57:25PM Seq Line
27
|
"MSD 360, EIC=068.7:360.7 (CHEMSTORT 1775005\A175424FCO00027.0) APNIeg,-SIEM,SFr,ag: Var
I -" I=
=. [wl
| - | =fr- eesW485D ,EIC=466.7:460.72
| -190.
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(CHEWSTORI1776005175s 424l FCO0o00Z70) API-ES,Nog,w SIM,m Frag:Var.
|=
160
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3 Acid 0.00
0.000
0
6
-8 mi
MSD1 369, EIC=368.7:369.7
{
[ome wnsommon mouse u04s mere gar
Sample Name:STD 50 ppb
| Sample Info:
1
Data file :C:\HPCHEN\1\DATA\Chemstor\11776257\A186432\FC000028.D.
"Injection Date : 12/3112/:102:235 AM
Seq Line
28
~ ATDinclsquttrOiopomenernattor H+ PHjCmOi0lAlLe4r
vnIinjaj..l vNNeolo.. o:+
sul11
OT -- |- ALnaastlysCihsangMeedthod + C1:/3\/H0P4CHEM\I\METHODS0\21:25380:0236Fpm
| Less anaysts of perfiuorooctanic acid.
-
HOT 359,EC<78397(8CH8ENSTOR 1776257 ISG
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"+ Endof Report +++
-
0046
on, 5. Jan. 2004 03:36:30 pm
Page 1 of 1
60372
compte nase. 100
| Sample Info:
1
| Injection Date : 12/31/03 12:27:22 AM
Seq Line
29
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Sample Name:sTD 250 ppb
I Sample Info:
Data file iC: \HPCHEN\L\DKTA\Chemstor\11776375\ALSG272\C000030.D
1
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Mon, 5. Jan. 2004
u048
03:38:08 pm
Page 1 of 1
Gn0374
---- [s_ eSmampprlee Nmaome::STD 500 ppb
1
Data file :C:\HECHEN\1\DATA\Chamstor\11776434\A192448\FC0000.31D
| hIIcnngjsetocrtupimeoennrtbataotre::+ p1o2m0/iD3li1li/e40r3 12:57:22 AW SvSeiqaNLleiNn.oe. | Ta14
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[AanaiyEsis iMethTMod i C:\eKECHEN\1\VETHODS\0122:35080:2361pm
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|
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Area
Signal
213s1e6s92;1 | wweedbi a2e6s9,, EEiicc--a3e6s8..77i:d3e6s9..77
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*** End of Report *t*
TT
Von. 5. san. 3008 63:39:45 5m u049 nmior:
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*** End of Report **+
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Wom. 5. gan. 2004 03:40:1pm3 wUoU
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sample Name:STD 1000 ppb
| sample Info:
1
Data file :C:\HECHEN\1\DATA\Chemstor\11772921\A153280\FC0000.33D
"IATnnjosetcortpuiemoernnattoD r a :++ 1t pm2oi/o3ld1le i/e0dr3 1:27:21 AM
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|= ALansatiysCihsanMgeetdhod | G1:/3\/H0E4CHEN\1\METHODS0\21:25380:0236Fpn
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436779537625 | SSDDlI 436659,, EBIiCC-e36e8..77::36699..77
| . Epp ---- msessssssssssssssscsssssssssssssssssssssssssssssssssss=ss=sssssssssssss==
I| necovsta
Mon, 5. Jan. 2004 03:18:14 pm u0si page 1061 000)0377
[7 sSaammpilee mNarmee::STMD 1500 ppb
1
Data file :C:\HPCHEN\1\DATA\FCO00034.D
||" AITcnnqjsetceotupimeoernnattDoarte :|: 1mP2Ci/O3l01lA/eL0rA3 1:42:15AM SveIinqaj.lLiNNnoo.e. :
321
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sul
| Ascnaa.lysmiostnMoeathod + Cs:es\sHoE.CHEM\1\NETHODS\1230038
r Last Changed : 1/3/04
02:58:05 pm
10/5 analysis of perfluorooctancic acid.
-
TSO 350,EC=368.7:989(7FOGGGISR0] APIS og, SWFajg Vgr
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| ~Thio"cSiuarrosac 1a43i6.e00
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area 654286606473
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signal
MWSSDDL 436699,, EBIICC--36688..77::436699..77
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