Document o95eaNaDan1gx5LEyJXwXNLe3
CeilcwteX
E 1 ELEBTHX I R PCI RATI Q
GENERAL. OFFICE 1SOO NORTH DALE MABRY
TAMPA, FLORIDA 33GOT
December 5, 1969
Mr. A. Plummer Purchasing Agent Bird & Son, Inc. 163 Washington Street East Walpole, Massachusetts
02032
Dear Art:
This will confirm our discussions and the progress to date for Bird wraps. We have forwarded your No. 45 Asbestos Roll Wrap copy to the vendors involved and requested plate preparation and proofs. This, as you know, will be a roll wrap for Chicago and involves 2rs?uare and 1% square product which will require a wrap for each. For Birmingham use, we have done likewise and will obtain sheet wrap for 2 square rolls only. The gummed tape copy for the #15 Asbestos Felt at the latter location has also been processed.
We have requested expediency from both sources and will advise when we" receive any definiteinformation on the progress of the copy.
I also spoke to Frank Molinari of your Advertising Department in reference to the wrapper copy we inquired about. This has been clarified and we informed Frank a copy of each would be forwarded to you when available, but he would not require proof approval before printing.
For identity purposes, we have also assigned temporary form numbers to the roll copy of Form 45-2 and Form 45-1%.
The writer also discussed in further detail, the ordering of these wraps and tapes with George Wright of U/L. For your general information, we have attached a copy of this written request and would suggest in submitting your request to George that a similar outline be followed. This will probably be initiated by your Mr. Carroll Homan who originated a letter dated October 22 which is no longer applicable since the procedure has been reversed.
I believe this covers our progress to date and if we can be of further assistance, please let me know.
Very truly yours, THE CELOTEX CORPORATION
bjc cc: Mr. W. E. Smith, Jr., Bird & Son, Inc.
BIRD 014009
GENERAL OFFICE 1500 NORTH DALE MABRY
TAMPA, FLORIDA 33507
December 5, 1969
Mr* George Wright Underwriters' Laboratories, 207 Ease Ohio Street CJiicago, Illinois
Inc.
Dear George:
This is to advise that Bird & Son has an arrangement with the Celotex Corporation to manufacture the following products with their label applied.
As discussed, we have listed the produces which Celotex manu factures. For further clarification, the identity of these same products are listed with the Bird label. As you also concurred, we have included the U/L reference information which applies to our particular products.
Celotex Product
No. 43 Asbestos Base Sheet Form W 2198 Type 15 B.U. We are manufacturing this at both our Chicago and Birmingham locations. U/L File K 2637 Vol. IV Section 1 Page 1
Bird Product
Bird No. 45 Asbestos Base Sheet Wrapper for 2 sq. and
1k sq. We will be furnishing this product at both of our plant locations.
Form No.'s 45-2 45-1.50
Celotex Product
#15 Perforated Asphalt Saturated Asbestos Felt - 4 square Form T-610D (printed gummed tape) U/L Type 15 Saturated Felt, Cap or Base Sheet U/L File R 2637 Vol. IV Section General Page 2
Bird Product
No. 15 Perforated Asphalt Saturated Ashes to;; Felt - 4 square
Mr. George Wright
-2- December 5, 1969
Based on the above information, we will within the next few weeks be ordering Bird wrappers for the Base Sheet and Bird gummed tape for the Asbestos Felt.
X believe the above includes all the details we discussed, and we have enclosed an extra copy of this memo for your referral to either Don Hock or Ray Hitchcock. You advised one of these men would be handling the orders which we will be submitting.
We have also discussed this with Bird and you may anticipate a similar memo from them regarding the reverse of this procedure with Celotex wraps.
If any further information is required, please contact the undersigned.
Very truly yours
THE CELOTEX CORPORATION
bje
B. F. Conaway
/
Purchasing Agent /
BIRD 014011
LElfrAR
BULLETIN LT-103
PULPEJf
for Adhesive and Coating Applications
GENERAL INFORMATION PRODUCTS SUMMARY AND APPLICATIONS PROPERTIES
BIRD 014012
General Information
PULPEXTM polyolefin pulps are high-surface-area, short-length fibrils that find use as an asbestos re placement in adhesive and coating applications. Be cause of its unique fibrillated structure (Figure 1), Pulpex functions to increase viscosity and improve crack- and slump-resistance ofa varietyof adhesives and coatings. These improvements are achievable at relatively mod est (0.4 to 3%) concentrations. In certain applications, Pulpex can replace asbestos shorts at one-tenth the asbestos concentration. Pulpex polyolefin pulps are also chemically inert, with excellent resistance to acids, alkalies, bleaches, solvents, mildew, and sunlight.
Figure 1. Photomicrographic Comparison of Fibrils
types Available
Pulpex is available in two basic types: Pulpex P, made from polypropylene, and Pulpex E from polyethylene. Both types are available in various grades in the form of a wet lap (sheet), or as a wet or dry fluff. (See Fig ure 2.) Table I lists the types available and presents properties information.
The wet-lap form of Pulpextypically requires shearing action such as that obtained with a Cowles disperser to achieve dispersibility. If shearing equipment is not avail able, use of the wet-fluff form is suggested. Both forms are suitable for use in water-based adhesive and coat ing formulations.
For solvent-based formulations the use of the dry-fluff form is recommended.
J
3
Figure 2. Pulpex is supplied in a wet-lap form (left) and as a dry- or wet-fluff form (right). The lap form requires shearing for dispersibility.
''-SS'/
BIRD 014013
LE\TAR
APPLICATION DATA
BULLETIN LT-111
PULPED Polyolefin Pulps
Pulpex P, Grade AD-HR, for Asphalt Roof Coatings and Cements
Pulpex P, grade AD-HR, is a dry-fluffpolypropylene pulp developed for use in asphalt solvent cutback coatings and mastics. At low concentration and in combination with talc, it improves uniformity of product mixture and provides excellent wet- and dry-slump resistance.
Suggested Formulation
Asphalt cutback (65% solids) ...................... Talc (5 microns average size) ....................... Talc (16 microns average size) ................... Pulpex P, AD-HR ...........................................
Roof Coating
87.5 5.5 5.5 1.5
100.0
Percent by Weight Roof Cement
70.0 13.5 13.5 3.0 100.0
Typical Properties!*) Brookfield viscosity at 73 F (No. 6 spindle at 10 rpm), cps ................. Stormer viscosity at 73 F, KU ..................... Wat-slump resistance at 100F (40-mil coat on aluminum panel) ........... Dry-slump resistance at 150 F (100-mil coat on roofing felt) ................... Pliability at 32 F ............................................ Product uniformity After one week at 73 F ............................. .. After one week at 150 F ..............................
27,000 120
270,000
--
Passed
Passed
Passed Passed
Passed Passed
Slight bleed; stirs in Bleed; stirs in
<a>ASTM D 2822-75 and D 2823-75 used as a guide.
Formulating Procedure
Mix talc with asphalt cutback in a suitable mixer for about 2 minutes or until well dispersed. Add Pulpex P, AD-HR, over a l-minute period while mixing, and continue mixing until smooth.
Viscosity adjustments can be made by adjusting the base viscosity of the asphalt cutback or by adjusting the concentration of Pulpex P, AD-HR. A comparison of the viscosities obtained with Pulpex P, AD-HR, vs asbestos is shown in Figure 1.
Availability Pulpex P, AD-HR, dry-fluff polypropylene is packaged in plastic bags enclosed in paperboard boxes. Net weight is 20 pounds/box shipped 20 boxes/pallet, or 400 pounds.
(over)
A HERCULES INCORPORATED COMPANY WILMINGTON, DELAWARE 19899
Wa cannot anticipate all conditions under which this information and our products, or the products of other manufacturers in combination with our products, may be used. Wfe accept no responsibility for results obtained by the application of this information or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or product combination for their own purposes. Unless otherwise agreed in writing, we sell the products without warranty, and buyers and users assume all responsibility and liabilityforlossordamagearising from the handling and useof our products, whether used aloneorin combination with other products.
LEX. 26066 REV. 2-82
PRINTED IN U S.A.
BIRD 014014
LT-111 Page 2 of 2
Figure 1
Asphalt Cutback Viscosity-Concentration Comparison Asbestos 7TF1 and Pulpex P, Grade AD-HR
Brookfield Viscosity as a Function of Pulpex P, Grade AD-HR, Concentration
Brookfield Viscosity as a Function of Asbestos 7TF1 Concentration
Material Suppliers This listing identities the manufacturer of the specific material referred to in this bulletin. It is not our intention-to-imply that these products are the only ones that can or should be used with Pulpex polyolefin pulps.
1. Asphalt cutback--65% dead-level asphalt(Type I, ASTM A 312) dissolved in 35% Varsol 18 min eral spirits(Exxon Corporation). Brookfield viscosity was 1,400 cps at 10 rpm with a No. 6 spindle.
2. Talc--Vertal No. 5 (5 microns) and Vertal 3XD (16 microns). H. M. Royal, Inc., 689 Pennington Ave., Trenton, NJ 08601.
Product Safety Products cited herein may be considered hazardous under the U.S. Occupational Safety and Health Act of 1970. Material Safely Data Sheets should be obtained prior to use of these products.
6-62
BIRD 014015
LEMAR
APPLICATION DATA
BULLETIN LT-112
PULPEX" Polyolefin Pulps
Pulpex P, Grade AD-HR, for Aluminized-Asphalt Roof Coatings
Pulpex P, grade AD-HR, is a diy-fluff polypropylene pulp developed for use in asphalt solvent cutback coatings. At low concentrations and in combination with talc and aluminum paste, it provides a uniform product with excellent wet- and dry-slump resistance.
Suggested Formulation
Percent by Wright
Asphalt cutback (65% solids) .................................................................. Talc (5 microns average size) .................................................................. Talc (16 microns average size) ................................................................ Pulpex P, AD-HR ....................................................................................... Aluminum paste (coarse grade) .............................................................. Stabilizer (SyloidAL-1) ..............................................................................
65.00 5.00 5.75 1.25
22.00 1.00
100.00
Typical Properties**) Brookfield viscosity at 73F (No. 6 spindle at 10 rpm), cps .. Stormer viscosity at 73 F, KU ___ Mfet-slump resistance at 100F (40-mil coat on aluminum panel) Dry-slump resistance at 150F (100-mil coat on roofing felt) ... Pliability at 32 F ............................ Reflectance, % Initial .............................. ............ After 3 days at 96 F at 100% RH Product uniformity After one week at 73 F ............. After one week at 150 F ...........
32,000 140
Passed
Passed Passed
47 40
Slight bleed; stirs in Bleed; stirs in
(a,ASTM D 2823-75 and O 2824-75 used as a guide.
Formulating Procedure Mix talc and stabilizer with asphalt cutback in a suitable mixer for about 2 minutes or until well dispersed. Add Pulpex P, grade AD-HR, while mixing over a 1-minute period, and continue mixing until smooth. Add the aluminum paste and mix thoroughly at low speed for the minimal time required for dispersion.
Availability Pulpex P, grade AD-HR, dry-fluff polypropylene pulp is packaged in plastic bags enclosed in paperboard boxes. Net weight is 20 pounds/box shipped 20 boxes/pallet, or 400 pounds.
(over)
A HERCULES INCORPORATED COMPANY WILMINGTON, DELAWARE 19899
We cannot anticipate all conditions under which this information and our products, or the products of other manufacturers in combination with our products, may be used. VVb accept no responsibility for results obtained by the application of this information or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or product combination for their own purposes. Unless otherwise agreed in writing, we sell the products without warranty, and buyers and users assume all responsibility and liabilityforlossordamage arising fromthe handling and useofourproducts, whether used aloneor in combination with otherproducts.
LEX. 25066 REV. 2-62
PRINTED IN U.S.A.
BIRD 014016
L.T-112 Page 2 of 2
Material Suppliers This listing identifies the manufacturer ofthe specific materials referred to in this bulletin. It is not our intention to imply that these products are the only ones that can or should be used with Pulpex polyolefin pulps.
1. Asphalt cutback -- 65% dead-level asphalt (Type I, ASTM D 312) dissolved in 35% Varsol 18 mineral spirits (Exxon Corporation). Brookfield viscosity was 1,400 cps at 10 rpm.
2. Talc -- Vertal No. 5 (5 microns) and Vertai 3XD (16 microns). H. M. Royal, Inc., 689 Pennington Ave., Trenton, NJ 08601.
3. Aluminum paste (coarse leafing grade No. 6233). Alcoa, Pittsburgh, PA. 4. Stabilizer -- Syloid AL-I. W. R. Grace Co., Baltimore, MD. Product Safety Products cited herein may be considered hazardous under the U.S. Occupational Safety and Health Act of 1970. Material Safety Data Sheets should be obtained prior to use of these products. 642
BIRD 014017
LEVTAR
APPLICATION DATA
BULLETIN LT-104
PULPEXTM Polyolefin Pulps
Pulpex E, Grade D-H, for Asphalt Roof Cements
Pulpex E, grade D-H, is a dry-fluff polyethylene pulp that is an effective replacement for asbestos in asphalt cements formulated with thickening clays. The end product is a highly viscous, uniform cement with excellent slump resistance.
Typical Properties Appearance ..........................................................................................................dry, white fluff Polymer ................................................................................................................polyethylene Specific gravity ................................................................................................... 0.96 Melting point, C................................................................................................ 132 Fibril length, mm Average ............................................................................................................0.6-12 Maximum ......................................................................................................... 2.5 Fibril diameter, n .................................................................................................30-40 Surface area (BET, Na), m2/g ............................................................................10-15 Moisture content, % .......................................................................................... <5 Chemical reactivity ............................................................................................ essentially inert<a>
^Swells in chlorinated hydrocarbons.
Product Safety Products cited herein may be considered hazardous under the U.S. Occupational Safety and Health Act of 1970. Material Safety Data Sheets should be obtained prior to use of these products.
Suggested Starting Formulation
Asphalt cutback (65% solids) Bentone 34 Wat methanol Talc (5/i size) Talc (16m size) Pulpex E, grade D-H
Roof Cement (% by Weight)
69.5 2.0 .5
12.5 12.5 3.0
100.0
. (over)
A HERCULES/SOLVAY COMPANY WILMINGTON, DELAWARE 19899
We cannot anticipate all conditions under which this information and our products, or the products of other manufacturers in combination with our products, may be used. We accept no responsibility for results obtained by the application of this infor mation or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or product combination for their own purposes. Unless otherwise agreed in writing, we sell the products without warranty, and buyers and users assume all responsibility and liability
for loss or damage arising from the handling and use of our products, whether used alone or in combination with other products.
LEX 26066 6-79
PftINTEO IN O.S.A.
BIRD 014018
LT-104 Page 2 of 2
Propartles<b> Brookfield viscosity at 73 F and 10 rpm .......................................................... 248,000 cps (spindle #7) Product uniformity After 73 F, 7 days ...................................................................................... .. no separation After 150 F, 7 days ...................................................................................... ;. no separation Wet-slump resistance at 100 F (40-mi! wet coat on aluminum panel) ..........................................................pass Dry-slump resistance at 150 F (100-mil dry coat on roofing felt) ..................................... ............................. pass Pliability at 32 F ........................ .......................................................................... pass
<b>ASTM o 2822 at guid*.
Formulating Procedure Bentone 34 and asphalt cutback are shear-mixed with a Cowles disperser at 3,000 rpm for 10 min. Then wet methanol activator is added and mixed for an additional S min.
Transfer mixture to a Hobart paddle mixer, and at low speed add talc, mix for 2 min, then add Pulpex , grade D-H, over 1 min and stir 5 min or until smooth. Raw Material Suppliers Asphalt cutback
65% dead-level asphalt (Type I, ASTM D 312) dissolved in 35% Varsol 18 mineral spirits (Exxon Corp). Brookfield viscosity (10 rpm) was 1,400 cps. Talc 5ft size, Vertal #5 talc 16ft size, 3XD Vertal talc H. M. Royal Inc. 689 Pennington Ave. Trenton, NJ 08601 Bentone 34 NL Industries Inc. P.O. Box 700 Highstown, NJ 08520 Availability Pulpex E, grade D-H, is shipped in multiwall paper bags (10 lbs net),. 100 bags per pallet. 10*1
BIRD 014019
Products Summary and Applications
Suggested applications for Puipex include asphalt coatings and mastics, caulks and sealants, construction mastics, stucco cements, block filler, and textured paints. Current grades and applications are as follows:
Puipex E, grade D-H
Dry-fluff polyethylene pulp is effective in applications such as asphalt emulsions, caulk and sealants, con struction mastics, stucco cements, and ceiling and wall texture compounds. It is effective in both water- and solvent-based formulations.
Puipex E, grade O-V
Wet-fluff polyethylene pulp is effective in water-based formulations that include asphalt emulsions, construc tion mastics, stipple paints, and block filler paints.
Puipex E, grade 0
Wet-lap polyethylene pulp can be used in latex-based textured paint and block fillerpaints. Shear is required to achieve dispersibifity.
Puipex E, grade A-H
Dry-fluff polyethylene pulp Is effective in oil-based caulks and ceiling texture compounds.
Puipex P, grade AD-H
Dry-fluff polypropylene pulp is suggested for use where high processing temperatures are required, such as in manufacture of certain gun cements or in manufacture of PVC floor tile and phenolic molding compounds.
Puipex P, grade AD-HR<"
Dry-fluff polypropylene pulp is designed specifically for use in asphalt-solvent cutback coatings. It offers the advantages of good dispersibility, wet- and dry-slump resistance, and airless spraying.
.^
"OtwtopmanW grades, uvatebta in (mitadquanHias only.
Table I
Typical Properties
/-----------------------------
Dry-Ruff Grades
Grade Appearance
PulpexE
A-H D-H
Dry, white Dry, white
fluff*
fluff*
PulpexP AD-H
Dry, white fluff*
Polymer
Polyethylene Polyethylene Polypropylene
Spedfic gravity
.96
.96
.90
Mefting point, C
132
132
165
Fiber length, mm Average
0.6-1.2
0.6-1.2
0.8-1.5
Maximum
2.0 2.5 2.5
Fiber diameter, it
10-20
30-40
20-40
Surface area (BET, N2), rn^/g
6-10
10-15
5-10
Moisture content, % <5 <5 <5
L Chemical reactivity Inert101
Inert10'
Inert1
Wet-Ruff Grades
^
PulpexE
A-V D-V
Wet, white Wet, white
fluff*
fluff*
Pulpex P AD-V
Wet, white fluff'
Polyethylene Polyethylene Polypropylene
.96 .96 .90
132 132 165
0.6-1.2 2.0
10-20
0.6-1.2 2.5
30-40
0.8-1.5 2.5
20-40
6-10 50 Inert10'
10-15 50
Inert10'
5-10 50 Inert1
j
"Packagedinp*prbag, 10 bsnutweigt*. '"Packaged inpotyethytena^inedpaperbag, 40 lb* nt weight
"SwaikkidfciinaMhydibcsibaRs. 'Raact*wis!rongaxitoing agent* aJelavaladtflrTpefalums.
r-................ -... -
Grade
Appearance Polymer Specific gravity Melting point, C Fiber length, mm
Average Maximum Fiber diameter, n Surface area (BET, Nj), m2/g Surface Total solids L of wet lap, %
Wet-Lap Grades ....... .. ......... -v
PulpexE
AD
Wetiap10'
Wet tap1'1
PulpexP AD
Wet lap(,)
Polyethylene Polyethylene Polyethylene
.96 .96 .90
132 132 165
0.6-1.2 2.0
10-20
0.6-1.2 2.5
30-40
0.8-1.5 2.5
24-40
6-20 Hydrophilic'"
10-15 Hydrophilic10
5-10 Hydrophilic10
50 50 50 .... ^
3
"Packaged 2,000wet lbs hi apatet <1,D00 bsdry). m Fibersurface-treated with polyvinyl alcohol forwaterdispersibility.
NOTE: For specific information on the above grades, request an Application Data sheet
Product Safety
Material Safety Data Sheets should be obtained prior to use of these products.
A HERCULES/SOLVAY COMPANY WILMINGTON, DELAWARE 19899 We cannot anticipate all conditions under which this information and our products, or the products of other manufacturers in combination with our products, may be used. We accept no responsibility for results obtained by the application of this infor mation or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or product combination for their own purposes. Unless otherwise agreed in writing, we sell the products without warranty, and buyers and users assume all responsibility and liability for loss or damage arising from the handling and use of our products, whether used alone or in combination with other products.
1041
PRINTED IN U.S.A.
BIRD 014021