Document o93v571D8bmjJxz58Y0OJ56Zo

CDR* FLOW IMPROVER C P0o4 I. MATERIAL IDENTIFICATION Name CDR* Flow Improver CAS Registry Number Mixture; See Section XI Synonyms Polyolefin in Hydrocarbon Solvent Product Codes 102M, 102S, 102R, 132, 162, 220, 230 Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) H. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients Petroleum Hydrocarbons CAS Registry Number Mixture Concentration > 90% t Hazardous Physical Properties Class IIIA Combustible Liquid - NFPA Code 30-1987. III. PHYSICAL DATA Appearance and Odor Opaque, amber to light green liquid; Hydrocarbon solvent odor Specific Gravity (H,0 = 1) 0.80 - 0.83 Boiling Point/Range 346 - 510F ASTM D-86 Solubility in Water Nil IV. REACTIVITY DATA Stable: X Unstable:__ _ Conditions to Avoid: Store away from gases, heat, or flame. CSPI0170/January 1990 SAU O00009337 Conoco Inc., P.O. Box 2197, Houston, TX 77252 Su OOi 3 13 ( p oo 4 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): > 1420F ASTM D-3828-81 (Method A--Seta Flash Method-) Handle and store In accordance with NFPA procedure for Class II1A Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Does not flow well even in spill/flre situation. Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Dense black smoke produced. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Classification HealthJL Fire 2 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Store away from heat or open flame. Shipping Information: DOT: Proper Shipping Name: Petroleum Oil Hazard Class: Combustible Liquid UN/NA No.: NA 1270 DOT Label(s): None DOT Placard: Combustible 1ATA/IMO: Not Restricted VII. HEALTH HAZARD INFORMATION Exposure Limits for CDR* Row Improver PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm: 1600 mp/m* TLV: None Established Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, skin or lungs after prolonged or repeated exposure. CSPI0170/Januaiy 1990 2 0009338 SM- 00 C P004 VIII. Carcinogenicity: This material is not known to contain any chemical listed as a carcinogen or suspected carcinogen by OSHA, LARC, or NTP at a concentration greater than 0.1%. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. Remove contaminated clothing as soon as possible. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: This material is combustible. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris, and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: None normally required except in emergencies or when conditions cause excessive airborne levels of mists or vapors. Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VII. Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Mechanical ventilation required only in emergency or extreme conditions, such as confined space. Protective Gloves: Should be worn when the potential exists for prolonged or repeated skin exposure. NBR or neoprene recommended. Eye Protection: Chemical splash goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SAL 000009339 CSPI0170/January 1990 3 C P 00 4 SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material does not contain chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies oa the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous .if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product and a Canadian MSDS is available. CSPIO170/January 1990 4 SAL 000009340 C P 004 STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 fPROPOSITION 65") The material does not contain ingredient(s) subject to the Act. PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: H =* Hazardous Substance (i 1.0%) S = Special Hazardous Substance (> 0.01%) E - Environmental Hazard (a 1.0%) Ingredient Petroleum Distillates CAS Registry Number Mixture Category H Nonhazardous ingredient(s) information is withheld as trade secret in accordance with Section 11 of Pennsylvania Worker and Community Right to Know Act MSDS Code: CSPI0170 SECTIONS OF MSDS REVISED: DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: I, VII 1/90 - Replaces MSDS dated 3/89 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, .CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. CSPI0170/January 1990 SAL 000009341 5 i i' Material Safety Datasheet Emergency Medical Telephone (800) 441 *3637 (conoco) CDR* FLOW IMPROVER C P 00 4 I. MATERIAL IDENTIFICATION Name CDR* Flow Improver CAS Registry Number Mixture; See Section XI Synonyms Polyolefin in Hydrocarbon Solvent Product Codes 102M, 102S, 102R, 132, 162, 220, 230 Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients Petroleum Hydrocarbons CAS Registry Number Mixture Concentration > 90% Hazardous Physical Properties Gass II1A Combustible Liquid - NFPA Code 30-1987. HI. PHYSICAL DATA Appearance and Odor Opaque, amber to light green liquid; Hydrocarbon solvent odor Specific Gravity (HjO = 1) 0.80 - 0.83 Boiling Point/Range 346 - 510F ASTM D-86 Solubility in Water Nil IV. REACTIVITY DATA Stable: X Unstable: Conditions to Avoid: Store away from gases, heat, or flame. SAL 000009342 CSPI0170/January 1990 Conoco Inc., P.O. Box 2197, Houston, TX 77252 onor^l Inf/-' i-m otr f'lz-x /7 1 Ti 707 CCCO 5M A ooj 3 i3 f P0o4 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): > 142F ASTM D-3828-81 (Method A~Seta Flash Method! Handle and store in accordance with NFPA procedure for Class IIIA Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Does not flow well even in spill/fire situation. Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Dense black smoke produced. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association fNFPA) Classification HealthJD. Fire^2_ Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Store away from heat or open flame. Shipping Information: DOT: Proper Shipping Name: Petroleum Oil Hazard Class: Combustible Liquid UN/NA No.: NA 1270 DOT Label(s): None DOT Placard: Combustible IATA/IMO: Not Restricted VII. HEALTH HAZARD INFORMATION Exposure Limits for CDR* Flow Improver PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm: 1600 me/m3 TLV: None Established Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of lOCP-TOCPF; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, ceil damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, skin or lungs after prolonged or repeated exposure. CSP!0170/January 1990 2 SAL 000009343 C P 00 4 Vlll. Carcinogenicity: This material is not known to contain any chemical listed as a carcinogen or suspected carcinogen by OSHA, LARC, or NTP at a concentration greater than 0.1%. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. Remove contaminated clothing as soon as possible. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel maybe considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: This material is combustible. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residua] fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris, and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing materiat to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: None normally required except in emergencies or when conditions cause excessive airborne levels of mists or vapors. Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VIL Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Mechanical ventilation required only in emergency or extreme conditions, such as confined space. Protective Gloves: Should be worn when the potential exists for prolonged or repeated skin exposure. NBR or neoprene recommended. Eye Protection: Chemical splash goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCIA, 40 CFR 302 Not Applicable CSPI0l70/January 1990 000009*** s M3 C P 00 4 SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE in SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 * Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.096 concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 . List of Toxic Chemicals (40 CFR 372) The material does not contain chemical(s) at a level of 1.096 or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous .if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR U6.4A, SECTION 311 The material contains the following ingredients) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR I7I-I78 Not Applicable FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product and a Canadian MSDS is available. CSP10l70/January 1990 4 SAL 000009345 c P 004 STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") The material does not contain ingredients) subject to the Act PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The materia! contains the following hazardous substances: Categories: H - Hazardous Substance (> 1.0%) S -- Special Hazardous Substance (> 0.01%) E = Environmental Hazard (t 1.0%) Ingredient Petroleum Distillates CAS Registry Number Mixture Category H Nonhazardous ingredient(s) information is withheld as trade secret in accordance with Section 11 of Pennsylvania Worker and Community Right to Know Act MSDS Code: CSPI0170 SECTIONS OF MSDS REVISED: DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: L VII 1/90 - Replaces MSDS dated 3/89 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. CSPI0170/January 1990 OOOOO^6 5 sM- "Material Safety J)ata Sheet | Emergency Medical Telephone (800) 441-3637 (Snow) COKER GAS OIL - HEAVY PREMIUM/INTERMEDUTETLSR CP017 l. MATERIAL IDENTIFICATION Name Coker Gas Oil - Heavy Premium/Intermediate/LSR CAS Registry Number 64741-81-7 Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) Chemical Family Thermally Cracked Petroleum Hydrocarbon Product Code 0542/0543^)544 II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients CAS Registry Number Concentration Polynuclear Aromatic Hydrocarbons, i.e., Mixture 5 - 50% c benzo(a)pyrene Hazardous Physical Properties None 111. PHYSICAL DATA Appearance and Odor Brownish-green liquid; Cracked hydrocarbon odor Specific Gravity 1.1 Boiling Point 500 - 1000F % Volatiles (by volume) 0 Vapor Pressure Nil Solubility in Water Insoluble Vapor Density >1 IV. REACTIVITY DATA Stable: X Unstable:___ Hazardous Decomposition Materials: Normal combustion forms carbon dioxide; incomplete combustion may form carbon monoxide. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. (, ' GASC0156/February 1990 SAL 000009347 Conoco Inc., P.O. Box 2197, Houston, TX 77252 C P017 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): > 200F (TCC) Handle and store in accordance with NFPA procedure for Class 1IIB Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association fNFPA) Classification HealthJD_ Fire 1 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated IATA/IMO: Not Restricted VII. HEALTH HAZARD INFORMATION Exposure Limits for Material PEL: None Established* TLV: None Established* Du Pont AEL: None Established Ceiling Value: None Established Refer to Coal Tar Pitch Volatiles; 0.2 mg/mJ Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Mouse skin painting studies have shown that nonsoivent-refined petroleum distillates having a distillation end point above 700F, and which are similar to ingredients in this product, caused skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material; the resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. Also, limited studies of carcinogenic oils have shown that washing the animals'skin wiih soap and water between applications greatly reduces tumor formation. These studies demonstrate the effectiveness of cleansing the skin after contact. The product may contain polynuclear aromatic hydrocarbons (PNAs) which have caused cancer involving skin and internal organs in laboratory animals. The product may product a phototoxic reaction when contaminated skin is exposed to sunlighL The effect is similar in appearance to an exaggerated sunburn and is temporary in duration. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Listed as Carcinogen or Potential Carcinogen by: Polynuclear Aromatic Hydrocarbons, i.e.. benzo(a)pyrene NTP Yes IARC Category 2B OSHA No GASC0156/February 1990 2 SAL 000009348 C P0I 7 VIII. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: All sparks, Games and ignition sources must be restricted from the area. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provinrial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VIL Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: Normal ventilation. Protective Gloves: Should be worn when any potential exists for skin contact Use insulated gloves where material is being handled hot. NBR or neoprene recommended. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Face shield is recommended where splashing can occur. Other Precautions: Skin contact should be minimized. Complete protective clothing if material is being handled hot. Launder or discard contaminated clothing. Discard extremely contaminated leather material. GASC0156/February 1990 3 SAL 00000934-9 CP017 XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The materia] does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible (hat this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The materia] should be reported under the following EPA hazard categories: Immediate (Acute) Health Hazard x. Delayed (Chronic) Health Hazard Fire Sudden Release of Pressure Reactive Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material is not known to contain chemicals) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances and/or is otherwise in compliance with TSCA RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to the U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to stale regulations. This materia] could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline GASC0156/February 1990 4 0009350 C P017 HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") The material contains ingredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Polynuclear Aromatic Hydrocarbons, i.e., Benzo(a)pyrene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify us at the telephone number noted below if the' material results in Pennsylvania commerce. MSDS Code: GASC0156 SECTIONS OF MSDS REVISED: DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: I, II, VII 2/90 - Replaces MSDS dated 3/89 Safety, Occupational Health, & Environmental Affairs Hazard Communication Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASC0156/February 1990 5 000009351 Material Safety Data Sheet j Emergency Medical Telephone (800) 441 -3637 )<conoco BENZENE G S045 1. MATERIAL IDENTIFICATION Name Benzene CAS Registry Number 71-43-2 Synonyms Benzol, Coal Naphtha, Cydohexatriene, Phene, Phenyl Hydride, Pyrobenzol Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) Chemical Family Monocyclic Aromatic Hydrocarbon II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients Benzene CAS Registry Number 71.-43-2- Concentration >99% Hazardous Physical Properties Class IB Flammable Liquid - NFPA Code 30-1987. III. PHYSICAL DATA Appearance and Odor Colorless liquid; Sweet odor (Threshold: 2 ppm) Specific Gravity (HjO = 1) 0.884 Boiling Point @ 760 mmHg 80.1C (176.18F) % Volatiles (WT %) 100% Vapor Pressure (mmHg) 77 @ 21C (69F) 100 @ 26.TC (78F) Solubility In Water Negligible VBpor Density (Air = 1.0) 2.8 rv. REACTIVITY DATA Melting Point 5.5C (41.9F) Stable: X Unstable:___ Hazardous Decomposition Materials: Decomposes with heat Conditions to Avoid: Incompatible with strong oxidants, strong acids. Hazardous Polymerization: Will not occur. 1 4ISC0016/May 1990 SAL 000009352 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 V. FIRE AND EXPLOSION HAZARD DATA LEL: 13 UEL: 79 G S 045 r Flash Point (Method used)! -HC n2Fl (CO Autoignition Temperature: 560C (1.040^ Handle and store in accordance with NFPA procedure for Class IB Flammable Liquid. Extinguishing Media: Use foam, dry chemical, CO*. Special Fire Fighting Procedures: Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus. Wear full protective equipment. Cool lank/container with water spray. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect those attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Vapor forms explosive mixture with air. Vapors or gases may travel considerable distances to ignition source and flash back. Hazardous vapor produced in fire is carbon monoxide. National Fire Protection Association (NFPA) Classification Health_2_ Fire 3 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 i Storage Conditions: Store in well ventilated area. Store in cool place. Keep container lightly closed. Do not store with strong oxidants. Shipping Information: DOT: Proper Shipping Name: Benzene (Benzol) Hazard Class: Flammable Liquid UN/NA No.: UN 1114 DOT Label(s): Flammable Liquid DOT Placard: Flammable IATA/IMO: Proper.Shipping Name: Benzene Hazard Class: 3.2 UN No.: UN 1114 IMO/ICAO Label: Flammable Liquid Packaging Group: II ( Reportable Quantity: 10 lbs. If material is shipped in quantities greater than 10 lbs. per container, the Proper Shipping Name is RQ Benzene. VII. HEALTH HAZARD INFORMATION Exposure Limits for Benzene PEL: 1 ppm - 8 Hr. TWA 5 ppm - (Short-Term Exposure Limit) 0.5 ppm Action Level TLV: 10 ppm. 32 mgW . Du Pont AEL: 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Min. TWA Hazardous Materials Identification System (IIMIS) Ratines Health 2 Fire 3 Reactivity 0 HAZARD RATING Least-0 Slight-1 Moderate-2 Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. High exposures may also cause heart irregularities with sudden death. Benzene may cause irritation to the eyes, lungs, or skin after prolonged or repealed exposure. MISC0016/May 1990 2 SAL 000009353 0S045 Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Carcinogenicity; Benzene NTP Yes IARC Yes OSHA Yes VIII. EMERGENCY AND FIRST AID INFORMATION Eyes; In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin; In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Immediately give two glasses of water or activated charcoal slurry. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: To prepare activated charcoal slurry, suspend 50 g activated charcoal in 400 ml water in plastic bottle and shake well. Administer 5 ml/kg or 350 ml for an average adult. IX. SPILL, LEAK AND DISPOSAL INFORMATION Aquatic Toxicity: 96 hour LC 50, fathead minnow: 35 mg/l In Case of SplU or Leak: Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat, sparks, flame, impact, friction, or electricity. Dike spill. Prevent liquid from entering sewers, waterways, or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry, or other absorbent material. Superfund Reportable Discharge: 1,000 lbs. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Cleaned-up material is an RCRA Hazardous Waste. Treatment, storage, transportation, and disposal must be in accordance with applicable federal, state/provincial, and local regulations. Recover nonusable free liquid and dispose of in an approved and permitted incinerator. Do not flush to surface water or sanitary sewer system. X. PRECAUTIONARY MEASURES Generally Applicable Control Measures and Procedures: Keep away from heat, sparks, and flames. Keep container in a cool place. Keep container tightly closed. Ground container when pouring. Use of nonsparking and explosion-proof equipment may be necessary depending on type of operation. Use ventilation that is adequate to keep airborne concentrations below exposure limits. Personal Protective Equipment: The OSHA benzene standard (29 CFR 1910.I02S) has specific requirements for personal protective equipment including respiratory protection. Refer to OSHA Standard 29 CFR 1910.134 for further respirator requirements. Eye contact with liquid benzene must be prevented and skin exposure limited as much as possible. Eye and face protection must conform to OSHA Standard 1910.133. Only personal protective clothing which provides a good barrier against benzene should be used. The best material against pure benzene is 'VITON.* If liquid benzene contacts protective clothing, the clothing should be removed promptly and decontaminated. Safety Precautions: Do not breathe vapor or mist. Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Wash clothing after use. MlSC0016/May 1990 sal 3 000093s4 G 045 XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance Benzene Reportable Quantity 10 lbs. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The materia] is not known to contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x_ Immediate (Acute) Health Hazard x_ Delayed (Chronic) Health Hazard x Fire Sudden Release of Pressure Reactive Not Hazardous NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - Ust of Toxic Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the Ust of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical Benzene CAS Registry Number 71-43-2 Approx. Concentration (Upper Bound] 100% TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, wheo discarded or disposed of, is the listed hazardous waste U019. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Benzene Reportable Quantity 10 lbs. HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 The material contains the following ingredient(s) which is considered hazardous if spilled while being transported in commerce. Ingredient Benzene Reportable Quantity 10 lbs. MlSC0016/May 1990 4 G S 045 STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1984 (PROPOSITION 65*) The material contains ingredients) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Benzene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify Conoco at the telephone number noted below if the material results in Pennsylvania commerce. ADDITIONAL INFORMATION AND REFERENCES The OSHA Benzene Standard, 29 CFR 1910.1028, must be complied with. Specific requirements include permissible exposure limits, regulated areas, exposure monitoring, engineering controls and work practices, medical surveillance and removal, communications and training, and record keeping. The standard became effective December 10, 1987. MSDS Code: MISCQ016 SECTIONS OF MSDS REVISED: DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: VI, VII, XI 5/90 - Replaces MSDS dated 5/90 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc (713) 293*5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. J I MISC00I6/May 1990 SAL 000009356 5 YIELD AEROSOL SECTION IX > SPECIAL PROTECTION XNFORMATIOPAOE REOUIREO VENTILATION LOCAL EXHAUST VENTILATION SUFFICIENT TO MAINTAIN WORKPLACE CONCENTRATION BELOW PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION TYPICAL USE OF THE PRODUCT DOES NIOSH APPROVED MASK IF MISTING. RESPIRATOR IS RECOMMENDED: lOOO PPM: CCROVF 5000 PPM: GMQV/SAF/SCBAF 10,000 PPM: SAP PO.PP.CF ESCAPE: GM0V/SC8A NOT IN REOUIRE CASE OF THE USE OF A AN EMERGENCY RESPIRATOR USE THE FOLLOWING PROTECTIVE GLOVES NEOPRENE OR NITRILE RUBBER GLOVES SHOULD BE WORN IF REPEATED OR PROLONGED EXPOSURE IS ANTICIPATED. EYE PROTECTION CHEMICAL GOGGLES IF METHOD OF APPLICATION PRE SENTS THE LIKELIHOOD OF EYE CONTACT OTHER PROTECTION N/A GS 3s SECTION X - STORAGE AND HANDLING INFORMATION STORAGE 120 F.< TEMPERATURE --MAX 0 f<`-MIN ! INOOOR |X JHEATEO } PRECAUTIONS TO BE TAKEN IN HANOLING & STORING STORE AT TEMPERATURES < 120 F. TO PREVENT POSSIBILITY OF RUPTURE. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USE DELIBERATE CONCENTRATION AND INHALATION OF VAPORS CAN BE FATAL. ! REFRJDERATED! OUTDOOR I| SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR IZATI ON ACT OF (CONTINUED) YIELD AEROSOL SECTION XI - REGULATORY INFORMATION PAGE . OB 1906 ANO 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNOER UPPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USEC AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH A$ FERTILIZERS ANO HER81CIDES ) , OR THE PRODUCT IS USED ANO LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR < - - IMCO SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER AEROSOL PROPELLANT(S) <--TAflIFF 6 0 <--lATA C--MILITARY AIR (AFR 71-4) ! 10 NUMBER j REPORT OTY | LIMITED OTY j NET EXPLOSIVE VT SECTION XIII - REFERENCES 1. VENDOR'S MSDS SHEET 2. NIOSH POCKET GUIDE TO CHEMICAL HAZARDS. 1978. 3. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, 6TH EDITION, N. IRVING SAX 4 NIOSH REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES. 1982. INGREDIENT PERCENTAGE IS A TRADE SECRET. MASS TRADE SECRET NUMBER SAL 000009357 MATERIAL SAFETY DATA SHEET YIELD AEROSOL {090825-0189 -BO 161S48-50*8 > DATE OF ISSUE ! 12/13/8* SUPERSEDES 09/01/8* SECTION I - GENERAL INFORMATION CHEMICAL NAME * SYNONYMS N/8 CHEMICAL FAMILY ALIPHATIC PETROLEUM OISTILLATE TRADE NAME * SYNONYMS YIELD AEROSOL FORMULA X<--MIXTURE MANUFACTURERS NAME : NATIONAL CHEMSEARCH OIV. OF NCH CORP. ADDRESS (NUMBER. STREET, CITY. STATE * ZIP CODE) BOX 152170 IRVING, TEXAS 75015 PREPARED BY: KEVIN UHL/T.S. CHEMIST I PRODUCT CODE NUMBER | EMERGENCY TELEPHONE NUMBER 5068 214-438-1381 5 2. SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS > ALIPHATIC PETROLEUM OIST. ETHYL ACETATE - SEE SECTION XIII PROPANE ISOBUTANE ; HAZARD COMB. FLAMMABLE ! tlv NA 4OOP PM ASPHYXIANT FLAMM. N/E N/E ! PEL* lOOPPM 400PPM lOOOPPM N/E : . cas 8030-30-8 141-78-8 74-*e- 75-28-5 SECTION IIA NON -HAZARDOUS INGREDIENTS (CONTINUED! YIELD AEROSOL SECTION ITA - NON-HAZARDOUS INGREDIENTS PAGE : 02 NON-HAZARDOUS INGREDIENT NAMES ANO CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY a 40S363-5050P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG) VAPOR OENSITY (AIR-1) PH * lOO* PERCENT, VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY | 160 | 13.6 | 1.8 IN/A | 50 \ 1\ SPEC GRAVITY (H20- 1 ) t 1 COLOR AMBER 1 1 ODOR SOLVENT 1 1 CLARITY TRANSPARENT 1 11 EVAPORATION RATE (BU AC - 1 1 0.6 1 \ NEGLIGIBLE \ NON -viscous 0. 860 SECTION IV - FIRE AND EXPLOSION NAZARO FLASH POINT (METHOD USED) 80 F. T CC- EXTINGUISHING MEDIA ALCOHOL' X<--FOAM < - -FOAM j flammable limits 1 X <--C02 DRY X<--CHEM1CAL I12.2 LEL WATER < - - SPRAY ! UEL | 1 1 -O <--OTHER SPECIAL FIRE FIGHTING PROCEDURES SPRAY WATER ON AEROSOL CONTAINERS TO COOL THEM, AV010ING RUPTURING WEAR SELF-CONTAINED 8REATH1NG APPARATUS WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND Oft OTHEft POSITIVE PRESSURE MODE WHEN FIGHTING FIRES. UNUSUAL FIRE 8 EXPLOSION HAZARDS VAPORS ARE HEAVIER THAN AIR AND MAT TRAVEL TO AREAS DISTANT FROM HANDLING 01 NT . FLAME EXTENSION: > 18* BURNBACK: 5 - 6 INCHES LEVEL 3 AEROSOL (NFPA SOB) NFPA HA2AR0 RATING (0-INSIGNIFICANT;1 - SL IGHT;2"MODERATE:3-HIGH:4-EXTREME ): 1 <-- HEALTH 3 < --FLAMMABILITY 0 <--REACT IV I TY <--$PECIAL SAL 000009358