Document o3vEKxz1jBJ6xGX06pkdkMpR
THE UNION CARBIDE "CALIDRIA" ASBESTOS BUSINESS (J. L. Myers 5/1/79)
In 1957 a Union Carbide exploration geologist was in central California looking for nickel or other metallic mineral deposits which could be of value to the Corporation. He took note of a peculiar white, leathery mineral which was eventually determined to be chrysotile asbestos in a unique physical form. Exploration activities were centered in the nearly town of Coalinga, and the deposits have become known as Coalinga Asbestos.
Asbestos (from a Greek word meaning non-burning) is a commercial term applied
to several fibrous metal silicate minerals which are fire-proof and capable
of being processed into flexible fibers. There are six varieties of asbestos
which are divided into two groups, serpentine and amphibole, based on their
;
crystal structure (Att. 1). Chrysotile is the only member of the serpentine
group while the amphiboles include crocidolite, amosite, anthophyllite., tremolite
and actinolite.
Chrysotile accounts for over 95% of world consumption; and, of the amphiboles, only crocidolite and amosite have any commercial significance. Sources and general uses of the three varieties are shown in Att. 2; and Att. 3 summarizes comparative data for them.
Based on epidemiological and other data, many medical and scientific authorities agree that crocidolite and amosite are more harmful to human health than chryso tile. Although U.S. regulations do not reflect this, the UK and other countries have severely restricted the use of crocidolite and amosite.
Chrysotile has several characteristics which are responsible for its widespread usage in over 3000 applications: worldwide availability, positive surface charge, flexibility, softness, high tensile strength (see Att. 4). Chrysotile occurs only in serpentine (California's official State Rock), which is a fine-grain rock composed almost entirely of hydrous magnesium silicate minerals similar to chrysotile in composition. Canada is the free world's largest producer of chrysotile asbestos, and supplies about 90% of the U.S. asbestos requirements.
The Canadian and most other deposits of serpentine contain chrysotile in cross fiber veins that are rarely more than half an inch thick. A typical ore contains only 6-10% fiber, of random lengths and tightly bonded together in a parallel configuration (see Att. 5). The Coalinga Asbestos deposit bears little resem blance to other serpentine bodies found throughout the world since most of the mass has been highly sheared and pulverized by nature. It consists of soft, friable sheets and clumps of asbestos fibers, and the only other known ore body of this type is the Stragari deposit in Yugoslavia. In.contrast to the cross fiber arrangement of conventional ores, the Coalinga deposit occurs as a swirling mesh of disoriented fibers (see Att. 6). Each fiber or fiber bundle is only in point contact with its neighbor, and the fiber content ranges from 50-60%. #
The Coalinga deposit is located in the southern part of the Diablo Mountain range, in Fresno and San Benito Counties (see Att. 7). It is in what is known
UCC 004171
2- -
as the New Idria mining district, which has long been famous as the oldest producing mercury mine (since 1853) in the United States, and is thought to be the largest single mineral deposit in the world. (Union Carbide's trade name "CALIDRIA" is a combination of "CAL" from California and "IDRIA" from New Idria.) Rich asbestos ore has been found over an area of 40-50 square miles, and to depths of over 500 feet. Conservative estimates indicate that over one hundred million tons of Chrysotile asbestos are available, while Canada's ore reserves have been estimated at less than 50 million tons.
In addition to having a very low fiber content, Canadian ore deposits contain fibers of various lengths, from a few microns up to several inches. These are defined by Canadian screening tests and designated as Grades 3 through 7 (see Att. 8). Conventional Canadian processing techniques include blasting, crushing, grinding and air classifying. A typical Canadian Grade 7 product will contain about 30-40% serpentine rock dust and 60-70% asbestos fibers. Most of the fibers will still be in bundles as shown in Att. 9.
Union Carbide mines the Coalinga ore by conventional open pit methods (see Att. 10). After removing 20 feet or less of overburden, ripper-equipped bull dozers and self-propelled scrapers are used to remove ore from the deposit. Before hauling the ore 55 miles to the plant near King City,, it is screened to minus 3/4-inch. Mining operations are carried out every other year during the dry season (May to October), and ore is delivered to the plant every year during this same period. Mining and hauling are sub-contracted, but supervised by plant personnel.
Union Carbide evaluated various dry processing methods but the best product looked little different than that depicted in Att. 9, and performed very similar to Canadian asbestos. An investment to produce such a product for conventional asbestos applications was not justified. In order to take full advantage of the unique features of the Coalinga ore deposit (summarized in Att. 11), a hydraulic beneficiation process was developed. Conventional mineral processing techniques were combined with the innovative use of special equipment and a plant was designed with three basic systems: rock fiber separation, refining, and special treatment (see Att. 12). This enables production of three basic product categories: fiber, colloidal, and modified, all with liberated fibers as shown in Att. 13.
The semi-works plant (see Att. 14) was started in 1963 and was expanded to its present capacity, except for RG-244, in 1966. The asbestos business was in the Nuclear Division until 1965 when it was transferred to the Metals Division. In an attempt to achieve better market compatibility, and hopefully increased sales, the business was transferred to the Chemicals and Plastics Division (Group I) in 1967. RG-244 was introduced in 1968; and, because of lack of sales growth and no apparent upper management interest, the asbestos business was put up for sale in 1969. It should be noted that considerable losses had been experienced since startup and negative net income was shown through 1970. The asbestos business has never had a good "fit" in the Corporation and probably never will have unless other non-metal lie minerals can be developed and marketed by the same group as a separate entity or department.
The business was not sold but it was transferred back to the Metals Division in 1970; and, in 1971, the first positive net income was realized. During 1970 the marketing philosophy was changed from trying to develop new products and
UCC 004172
-3-
markets, to selling existing products to conventional asbestos markets and spending a minimum amount of time on developmental selling. Personnel who had been with the business for several years in production and technical capacities were transformed into a sales group which also performed technical and marketing service functions. This group is essentially still intact and the financial performance of the business for the last seven years is shown in Att. 15. A historical summary of the asbestos business is shown in Att. 16.
Although, on paper, the asbestos business conforms to the regular organization of the Metals Division, there are some aspects which, in reality, are consider ably different when compared to other Division product lines. There are basically two groups which operate the business: plant production and product marketing. In addition to production, plant personnel also handle order entry, invoicing, shipments (domestic and foreign), inventory control, warehousing and associated responsibilities. In addition to direct sales, marketing personnel handle technical service, orders, health and regulatory matters, product and market development, sales promotion and literature development, international sales and other associated responsibilities which are normally handled by special departments within the Division. There is very close cooperation between plant and marketing personnel with little involvement by New Yrck management. There is obviously some concern over this type of operation but a small business, such as asbestos, can be operated successfully in this manner. (Plant and Marketing organization charts are shown on Att. 17 and 18.)
Union Carbide's asbestos business involves the mining, milling and production of short fiber, high quality asbestos fiber products for world-wide marketing into relatively small segments of various industries. Major tonnage sales are to the vinyl-asbestos floor tile industry and similar applications for short fiber asbestos. "Calidria" asbestos does not compete with non-short fiber asbestos in other markets, which comprise the major share of the asbestos indus try. Major dollar sales of our asbestos business are from viscosity control markets where the competition is non-asbestos products. Again, "Calidria" asbestos does not compete with these non-asbestos products in the major share of their markets.
As mentioned earlier, asbestos, especially chrysotile, is mined and produced throughout the world. Att. 19 summarizes the major sources of asbestos.
Apparent consumption of chrysotile asbestos in the U.S. has dropped from a peak of 876,000 tons in 1973 to an estimated 641,000 tons in 1978. Union Carbide is responsible for about 25% of U.S. production and supplies about 3% of total U.S. comsumption (see Att. 20). According to USBM estimates, UCC was responsible for 36% of U.S. production in 1978 and provided 4.1% of total U.S. consumption.
Based on preliminary estimate for 1978, chrysotile was used in the U.S. as shown in Att. 21. This was a' typical year and shows that the construction industry continues to use about 63% of the total consumption. The markets in which we are able to at least partially compete with Canadian asbestos are marked and total about 282,000 tons.
Attachment 22 summarizes the domestic applications for various "Calidria" products. As shown in Att. 23, the asbestos industry consumes 95% of tons and
UCC 004173
-465%, of dollars, while the non-asbestos industry consumes only 5% of tons but provides 25% of sales dollars. Attachments 24-31 describe how "Calidria" asbestos fits into the potential domestic asbestos and non-asbestos markets as previously described.
UCC 004174
ATT, 1
A S B E S T 0 $ - HY D RATE D WET A L S I L i CATE
SERPENTINE
Chrysotile
AMP'H IBOLE
Crocidolite Amosite Anthophyllite Tremolite Actinolite
41
UCC 004175
RFNFRAl ASBESTOS INFORMATION - U.S.
ATT, 2
Chrysotile
Crocidolite Amosite
Major Sources U.S., Canada
So. Africa So. Africa
s--
1978 Estimated U.S. Consumption
CEMENT, TILE, FRICTION MATERIALS, TEXTILES, PLASTICS, INSULATION, ASPHALTICS
632,000 T
REINFORCING, INSULATION
INSULATION, PACKINGS
16,500 T 1,500 T
TOTAL
641,000 T
UCC 004176
ATT. 3
COMPARATIVE DATA FOR ASBESTOS MINERALS
FORMULA
CHRYSOTILE ! ; 3Mg0* 2Si02*2H20
i
CROCIDOLITE Na20* Fe2Q3*3FeO*
8Si02*H20
AMOSITE 1.5MgO*5.5
8Si02*H2
COMPOSITION,* Si 02 Mgo FeO Fe203 ai2o3 h2o CaO Na20 Ca0+Na20
CRYSTALS
1; : 37-44 . ! 39-44
0-6 0-5 0-2 12-15 0-5
-
49-53 0-3
13-20 17-20
-_ 2-5
-
4-8
"*
FINE FIBERS
BRITTLE FIBERS
49-53 1-7
34-44
-
2-9 2-5
-
-
0-3
PRISMATIC CRYSTALS
COLOR TEXTURE FLEXIBILITY HARDNESS ,Nlohs FIBER OIA., A TENSILE, Mpsi SURFACE CHG. RES. TO ACID RES. TO ALK.
GRAY/GREEN SOFT/SILKY VERY GOOD 2.5-4 180-300 800 POSITIVE POOR GOOD
BLUE HARSH GOOD 4 600-900 600 NEGATIVE GOOD GOOD
GRAY/BROWN , HARSH
GOOD 5.5-6 600-900 200 NEGATIVE GOOD FAIR
SOURCE: MODERN PLASTICS ENCYCLOPEDIA (1972-3), AND ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY, VOLUME 2, P. 136 (1948).
UCC 004177
ATT. 4
ADVANTAGES OF C HR Y SOT I L E FIBER Worldwide Availability Positive Surface Charge Flexibility High Tensile Strength Softness
UCC 004178
` UCC 004179
UCC 004180
ATT. 7 UCC 004181
i ATT. 8
Canadian Chrysotile Asbestos Classification
Standard Designation Of Grade
i/S" Mesh
Guaranteed Minimum Shipping Test*
4 Mesh
10 Mesh
Pan
Group Number
3F
10.5
3-9
1.3 0.3
3K 3R 3T
77
47
2a
1.5 . 4 4
0.5 1 2
Group 3 (Spinning Fibre)
3Z
19
42
4A
08
62
4D
07
63
4K
04
93
Group 4
4M
04
84
(Shingle Fibre)
4T
02
10 4
4Z
0 1.5
9.5 5
5D
0 0.5
10.5
5
5K
00
12 4
Group 5
5M
00
11 5
(Paper Fibre)
5R
00
10 6
GD
00
79
Group 6 (Waste)
7D 7F 7H 7K 7M
7R 7T
7RF (Floats) 7TF (Floats) 8S
0 0 0 0 0 0 0 No Test No Test No Test
0 0 0 0
0 0 0
5 ii 4 12 3 13 2 14 i 15 0 16 0 IS
Group 7 (Shorts)
"Guaranteed minimum shipping test Is that test below which the actual shipping test shall not tell. The shipping test is the average for each carload or smaller shipment of tests of representative samples taken at time of shipment.
Uses of Asbestos with Corresponding Recommended Carey Grades
Canadian Chrysotile Asbestos is an essential raw material for a wide variety of products. To meet the requirements of specific industries, sub-grades, or grades within grades, have been developed by research. Grades are divided into sub-grades according to fibre length, degree of
"crudiness" and amount or size of fines. Variations of this combination can change such characteristics as density, absorption, wet volume and setting rate. Carey Canadian produces a wide range of sub-grades as shown in the table below.
Important ProdwcfJ Contatrteing Asbestos
Recommended Carey-Canadian Gradej*
Important Product! Containting Asbeitoi
Recommended Carey-Canadian Grades*
Acoustical Plaster Adhesives Asbestos Cement Products
Asbestos Millboard
Asbestos Paper and Felt
Asphalt Compounds
Caulking and Scalers
Cements Dry Wall Joint Fireproofing Insulation Finishing Refractory
Fibrated Greases
60-1, 7D-3, 7MS-1, 7M-5
7R-3, 7T-5, 7RF-9, 7TF-8
4K-1, 4T-1, 5D4, 5K-1, 5R-1, 5R-5, 6D-I, 6D-5
4T4, 5D4, 5K-1, 5R-1, 6D4, 7D-3, 7M-5
5D-1, 5K-1, 5R-1, 6D-1, 6D-(5l, 7D-3, 7M-5
7D-1, 7F, 7K3, 7KS-1, 7MS-1, 7M-5, 7RS4, 7R-3, 7TS-1, 7T-5, 7RF-9, 7TF-8
7D-3, 7F, 7K-3, 7MS-1, 7M-5, 7RS-1, 7R-3, 7TS-1, 7T-5, 7RF-9, 7RF-10, 7TF-8
7RF-9, 7RF-10, 7TF-8, 7TF-12 5D-1, 5R-L, 6D4, 7D-3, 7MS4 6D4, 7D-3, 7M-5, 7M-90, 7T5, 5R-1, 6D-1, 7M-5, 7M-90, 7MS4
7F, 7RF-9, 7RF4Q
Floor Tiles Asphalt Vinyl Asbestos Rubber
Friction Material
Magnesite Flooring Oil Well Muds Pipe-fibre Plastics
Cold Molded
Molding Compounds Pre-mix Molding Radiator Sealing Compounds Sheet Packing
Textiles Welding Rods
7R-3, 7RS-3 7R-3 7R-3, 7TS
5K-1, 5R-1, 5R-5, 6D-1, 6D-5, 7D-3, 7D-S, 7F. 7K-3, 7MS-1, 7M-5
7T-5, 7RF-9
7R-3, 7RF-9
7M-5, 7R-3
5R-1, 6D-1, 7D-3, 7M-5, 7T-5, 7RF-9 7RF-9, 7TF-3, 7TF42 7T5, 7TF-8
7M-S, 7T-S, 7RF-9
4K-1, 4T-1, 5D-1, 5K-1, 5R-1. 5R.01, 6D-1
3T-1, 4K-1
7M-5, 7R-3, 7T-5, 7RF-9
Sub-grade designations (or all grades except Shorts indicate: (*1) well-opened, (-5) semi-crudy. Sub-grade designations for Short grades indicate: (-1) high bulk and oil absorption, (-3) (-5) (-9)(`10(medium bulk and oil absorption,-8)(-90) tow bulk and oil absorption
UCC 004182
0
UCC 004184
UNIQUE CHARACTERISTICS OF THE COALINGA ORE DEPOSIT
All Chrysotile All Short Fiber Random-Oriented Fibers Over 50% Fiber 15-20% Moisture Easy to Mine .
UCC 004185
ATT. 12
CALIDRIA ASBESTOS PRODUCTION
UCC 004186
ATT. 13 UCC 004187
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UCC 004188
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004189
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X4OC33JJ Q_
1957 8/63 1965 1/66 1966 1/67 2/68 1969 1/70 1970 1971 1972 1973 5/74 1975
1976 1977
1978
"CAUDRIA" CHRONOLOGY
ATT, 16
MINE DISCOVERED (NUCLEAR DIV.) SEMI-WORKS PLANT STARTED
TO METALS DIVISION PLANT EXPANDED SALES OVER ONE MILLION DOLLARS BUSINESS TRANSFERRED TO GROUP 1 INTRODUCED RG-244 BUSINESS FOR SALE BUSINESS TRANSFERRED TO METALS SALES ALMOST TWO MILLION DOLLARS FIRST POSITIVE NET INCOME SALES NEAR PLANT CAPACITY, OVER 3 MILLION DOLLARS SALES ALMOST 4 MILLION DOLLARS INTRODUCED RG-600 PLANT ON 21 SHIFTS/WK., SALES OVER 4 MILLION DOLLARS FIRST POSITIVE CASH FLOW SALES ALMOST 5 MILLION DOLLARS SALES OVER 5 MILLION DOLLARS, CASH FLOW OVER 1 MILLION DOLLARS SALES OVER 7 MILLION DOLLARS, RECORD PRODUCTION AND EARNINGS
UCC 004190
CALIDRIA" ASBESTOS MARKETING ORGANIZATION 4/1/79
ATT. 17
UCC 004191
Union Carbide C orporation M etals D iv is io n "C a lid ria " Asbestos Operations (5/15/78)
ATT. 19
MAJOR WORLD SOURCES OF ASBESTOS (Based on 1977 USBM Estimates)
COUNTRY
USSR Canada So. Africa So. Rhodesia' P.R. of China Italy Brazil U.S.A. Australia
' TOTAL
SHORT TONS 2,710,000 1,700,000
419,000 220,000 220,000 . 170,000 105,000 102,000
61,000 5,879,000
UCC 004193
ATT. 20
ASBESTOS STATISTICS, M Short Tons (JLM, 3/27/79)
1978 Estimates
1973-1978 Average '
U.S. Consumption U.S. Imports U.S. Exports U.S. Production
640* 588*
35* 100*
728 658
47 113
UCC Production UCC Dom. Shmpts. UCC Export
36 26
9
29 22
7
*From USBM reports and private communication with R. A. Clifton of USBM
*
UCC 004194
ATT. 21
U.S. Chrysotile Consumption - 1978
Asbestos-cement pipe Flooring Products* Friction Products Roofing Products* Asbestos-cement sheet Coatings & compounds* Packings & gaskets Paper Insulation (Thermal & Electric) Textiles Plastics* Other*
Tons 153,000 147,000
86,400 61,000 41,400 35,200 25,600 22,400 19,200
9,600 6,400 32,000
% of Total** 24.0 23.0 13.5 9.5 6.5 5.5 4.0 3.5 3.0 1.5 1.0 5.0
TOTAL
, 640,000
,, 100
** - "Asbestos", December 1978, pp. 16-18 * - Markets in which UCC partcipates
REB 4/30/79
UCC 004195
ATT. 22
"CALIDRIA" ASBESTOS PRODUCT APPLICATIONS
PRODUCT SG-100 S6-130 SG-200 Super Visbestos SG-210
HPP
HPO RG-110
RG-1A4
RG-24A
__________ APPLICATIONS
Vinyl-asbestos floor tile
Masonry coatings
Rubber floor tile
Drilling muds
Mastics Asphaltic coatings Phenolic molding compounds
Rubber sheet goods Mineral board (Japan) Paper (Japan)
Asphaltic coatings. Adhesives
Asphaltic spray'coatings Aluminized coatings Mastics, caulks & sealants
Adhesives (Epoxy, casim, phenolics) Coatings Vinyl plastisols (High build, dip
coatings) Mastics, caulks & sealants (Vinyl,
butyl, polysulfide, bituminous)
Polyester resins (Laminating, gel coats, putties)
Caulks & sealants (Vinyl, butyl, acrylic, polyurethane)
Coatings (Epoxy, urethane, asphaltic)
UCC 004196
ATT. 23
1978 CALIDRIA ASBESTOS DOMESTIC APPLICATIONS AREAS
0) Floor Tile (1) Phenolic Compounds 0) Roofing Compounds (1} Asphaltic Coatings
(1) Rubber-Sheet Goods
(2) Adhesives
(2) Sealants
(2) Polyester Laminates
(2) Coatings
.
(D Drilling Muds
0) Miscellaneous
--
(1) Asbestos Industry
SG-100 SG-200
SG-210 HPO
SG-210 HPO
SG-130 SG-144 RG-110
HPP RG-100
RG-144 RG-244
RG-144 RG-244
RG-244
CG-135 RG-144 RG-244
Visb. CSV SHUR
T 17,500
350 510 940
370 280 430 100 550
3,000
1,920 25,950
$M 1800
80 100 180
% of Total T_ S 67 39
12
22
44
130 1 3 230 1 5 540 2 12 200 0.5 4 630 2 14
400 11 9
280 4570
76
(2) Non-Asbestos; Industry
Summary:
Asbestos Industry Non-Asbestos Industry
24,590 . 1,360
2970 1600
95 65 5 35
UCC 004197
ATT. 24
"Calidria11 Participation in Typical Domestic Asbestos Markets in 1978
Flooring Products
Domestic Market, Tons
147,000
Roofing
61,000
Coatings & compounds (Asphaltic Coatings)
35,200
Plastics (Phenolic & Rubber)
6,400
Drilling Muds
8,000
Other
24,000
Potential Segments, Tons
75,000
"Calidria" Share of Seqment
Tons
%i
17,500
23.3
6,000
510 8.5
12,000
940 7.8
6,000 8,000 24,000 (?)
720 3,000 1,920
12.0 37.5 8.0
TOTAL
281,600
131,000
24,590
18.9
REB 4/30/79
N.
UCC 004198
ATT. 25
DOMESTIC MARKET DETAIL
.
Typical Asbestos Markets for "Calidria"
I. Flooring Products Total market "Calidria" share
147,200 tons 17,500 tons (11.9% of total)
.A V
ri^
'/ -z'
Total market includes both tile & sheet goods.
"Calidria'1 participation only in tile market which is about 1/2 of
total. "Calidria" share of this reduced market is, therefore, about 24%.
Major competitors - Carey Canadian - Canada
Johns-Manville - Canada
Atlas Mineral
- California
Floor tile market is split as follows:
rA
Carey J-M Atlas
30%
y<-u
20% ^ fC
/ lyfi'ii'i|
26% *,J
J
"
"Calidria" 24%II.
II. Roofing Compounds
Total market
61,000 tons
"Calidria" share
510 tons (0.8% of total)
Market includes primarily asphalt compounds using asbestos as a
floor control agent. Much of the market requires slightly longer fibers
than "Calidria" has available. Realistically we can probably only compete
for perhaps 10% of the total or 6100 tons.
UCC 004199
ATT. 26
Major competitors - Johns-Manville
_ Carey
Bell
Market is split as follows:
J-M 60%
Carey
. 20%
Bell
19%
"Calidria" 1%
Most Canadian suppliers
it n
n
nH
ii
III. Coatings & Compounds
.
Total market
35,200 tons
"Calidria" share
940 tons (2.7% of total)
"Calidria" particpates primarily in the asphaltic coatings portion of
this market which excludes roof coatings. Products include automotive
undercoats, coatings for waterproofing below grade concrete and for driveways
and tennis courts. The portion of the market in which "Calidria11 might
compete is unknown, but is probably at least 1/3 of the total market.
Major competitors - Canadian producers
Market is split by all manufacturers (primarily Canadian) and
represents an outlet for as much short fiber product as can be allocated
to this high volume, low cost application.
v
IV. Plastics
'
Total market
6,400 tons
"Calidria" shares
720 tons (11.3% of total)
Market includes primarily plastics used for structures,, molded goods,
etc. Larger segments include chemical resistant fibers, molded phenolic
parts and some rubber goods.
UCC 004200
ATT. 27
"Calidria" participates primarily in the latter two areas. Major competitors - Johns-Manville Market is split as follows:
J-M 89% "Calidria" 11%
Other
(Oil and gas well drilling)
Total market for short fiber asbestos
20,000 tons
"Calidria" share
4,000 tons (20% of total)
Current market is about 6-8000 tons because of regulatory restraints.
Total market could be realized in the absence of regs.
Major competitors - Johns-Manville (Flosal)
Current market is shared by "Calidria" and Johns-Manville about equally
Production capacity is adequate for full development of market.
UCC 004201
"i
DOMESTIC "Calidria" Markets - Not Typical Asbestos
(Viscosity Control)
ATT. 28
Adhesives Sealants Polyester Laminates Coatings
Tons 280 430 100 550
Total Market* 2500 1500 3400 4600
UCC % 11.2 28.7 2.9 12.0
TOTAL
1360 /
12,000
5A
11.3
*Total Market estimates -
- Modern Plastics, January 1979
- C & P sources (Skeist Laboratory Market Analyses - 1978)
---
- Assumed nominal loadings for "Calidria," i.e., 1% in polyesters, etc.
REB 4/30/79
UCC 004202