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P.P. 03-1437 (1979-11)
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DU PONT CANADA INC. yfy^ MATERIAL SAFETY DATA SHEET
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SECTION 1 PRODUCT IDENTIFICATION
TRADE NAME
Motor Fuel Antiknock ComDOunds
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SYNONYMS
(Mixtures Contain) Tetraethv! and/or Tetramethvl
MANUFACTURER'S NAME
Du Pont Canada Inc.
ADDRESS
'
Maitland, Ontario
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Lead
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C.A.S. NUMBER
FORMULA
See below
TELEPHONE NUMBERS r eg u l ar 41.6-362-5621 EMERGENCY 613-348-3616
NAME
SECTION II HAZARDOUS INGREDIENTS
%
TLV* (Units)
NAME
Lead Alkyls
Kq - 61 4S wt
Ethylene Dibromide*
17.86 wt.
Ethylene Dichloride
18.81 wt.
Solvent, antioxidant, dye and
0.10 - 0.-15 mg Pb/M3
145 ma/M3 200 mg/M3
inerts**
12.51 -1.84 wt.
-
%
TLV (Units)
SECTION III PHYSICAL DATA
BOILING POINT <X)
Initial, calculated (DecomposesV. 95 - 150
MELTING POINT (C1
VAPOR PRESSURE (kPa)
A
@ 20 C.
VAPOR DENSITY (AIR - 11
.0.7-5.5
4--7
SPECIFIC GRAVITY |H,0 1)
1.5 - 1.7
PERCENT-VOLATILE BY VOLUME (%)
Minute but highly toxic.
EVAPORATION RATE
i
Similar to water.
0 38y C. % by wt.(Lead alkyl)
.oooo: ___ o.o:
APP&aterfalTs dved to detect leaks. Sweet, musty odour.
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE LIMITS _________
EXTINGUISHING MEDIA .W..ater, foam, dry ch, em._i_c_an l, ' rC>rO\ ?
LEL
Unknown___
AUTOIGNITION TEMPERATURE (C)
ua
Unknown___
SPECIAL FIRE FIGHTING PROCEDURES Keep container cool - for detail see Du Pont Booklet, "Thermal
Characteristics of Motor Fuel Antiknock Compound41 MSI71170
UNUSUAL FIRE AND EXPLOSION HAZARDS
Mav decompose if heated above 100 C. Rapid decomposition container explosion. *AviiatTORhjnitSfcitCflrata:ms.) no ethylene dichloride and 35.72 wt.i ethylene dibromide. **Dye colour may be red, orange, or blue.,_______ :-------------------
NOTICE FROM DU PONT: The information on this Materiat Safety Data Sheet is provided by Du Pont free of
charge. While believed to be reliable it is intended for use by skilled persons at their own risk. Du Pont assumes no responsibility for events resulting or damages incurred from its use. The information on this Materia! Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with
any other materia/ or in any process.
will
cause
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PERMISSIBLE EXPOSURE LEVEKSI ROUTES OF EXPOSURE
SECTION V HEALTH HAZARD DATA
0.075 mg Pb/M3 (OSHAl
EFFECTS OF OVEREXPOSURE
May be fatal if swallowed, inhaled or absorbed through the skin.
emer g enc y an d f ir s t aid pr o c ed u r es skin: Flush wi th kerosene, wash with Soap & plenty of water. Eyes: Flijish
copiously wit-h^water for min..of-15 minutes,--Inhalation: remove from.exposure. -Ingestion
if conscious, induce vomiting by sticking finger down throat. Promptly initiate gastric law ge.
anwiiVjri>:4tTuii*r ftaiiza-piisamagg*:
SECTION VI REACTIVITY DATA `
STABILITY
UNSTABLE STABLE
CONDITIONS TO AVOID
, t. .
Fire and/or heat and strong oxidizing agents.
Stable at ordinary temperatures.
INCOMPATABIUTY {Materials to avoid)
Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS Lead oxides and other Inorganic lead fumes,
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BETAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
1
Contain the spill* Evacuate area and keep all person? upwind. Wear self-contained
breathing apparatus and full protective clothing. Contact Du Pont representative.
n e u t r a l iz in g c h e mic a l s
tol&lmi naflS^ammable materials may be disposed of by burning. Contaminated earth or
porous surface should be removed and buried if permitted or weathered at isolated site. Lon.tgct.-Hu: Punt'"rgas
SECTION VIII SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS
Local ventilation.
pr o t ec t ive eq uipment Organic vapour cartridge type face mask for emergency or short duration.
r es pir at o r y _________Fy-o^h ai> typp maq.lf fnr_lnni]pr duration.
IEYE AND FACE Goggles as required.
HAND AND ARM
-
______ Impervious to protective gloves.
OTHER CLOTHING AND EQUIPMENT Boots and light coloured clothing.
SECTION IX SPECIAL PRECAUTIONS
PCRElCoAsUeTIOdNS TsOyBsEtTeAmKEN. IN HMANoDvLIeNG uANnDdSTeOrRINvGacuum. Keep away from fire, heat and s.trong .o..xJidjii.zJin..g agent_s. Provide cooling water in event of fire. DoERnolAtTreathe vapour. Do not get on skin, in eyes or on clothing. Do not take internally **
* Fbrmore details on`medical treatment o t organic lead polSOftlrtq see"Modtern OccupatlUlial Mgdicine" by Fleming, D'Alonzo and Zapp, 2nd edition. ** FemaTes of child-bearing capability hot assigned to alley! lead mfg. areas. Although there is no human data regarding..effects in
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