Document npp1eYVz4pXQjBwbonpvVx4OG

G E 0 R b I ft G l i L F,- E H ID l-5O4-6gW!0QPP197 DLT 19'94 11 16 No 005 F 16 Georgia IMF Material Safety Data Sheet: PVC 1110 PBODUCtANDCOMPANY Product name Effective Date Synonyms Chemical Formula CAS Name & No Fire /1 Health 71 0 Reactivity PVC 1110 Special NFPA HAZARD RATING JHfiuary 14, 1994 Polyvinyl Chloride resin, PVC tesin, chloroethylene polymer, chloroethylene homopolymer (C47HjCI)n Chloroethylene polymer, [9002-86-2] Manufacturer's name and address Georgia Gulf Corporation PVC Division Headquarters P O Box 629 Plaquemme LA 70765-0629 Emergency telephone number Chemtrec (800) 424-9300 the only in the event of chemical emergencies involving a spill, leak, fire or exposure or accident involving chemicals MSDS Contact P.L. Logue, Industrial Hygienist P.O. Box 629 PlHquermnc, LA 70765-0629 Phone Number (504) 369*2642 Monday - Friday 7*30 a in until 4 OO p m C T Form SP-1 Page 1 bHIPGTP GULT - CHS TD 1-504-68/ABB80023198 OCT 19'94 U 1? No 005 P 1? Georgia GutF Material Safety Data Sheet: PVC 1110 Component Polyvinyl Chloride Resin Proprietary Additives CAS No. 9002-86-2 XX-XX-X WT% 99 6 - 99 9% 0.1-0 5% Caution: Eye Irritation Ib possible if solid material miters the eye. NCI can be liberated at elevated temperatures, POTENTIAL HEALTH EFFECTS Primary Routes of Exposure: Inhalation ot process emissions Eye: Solid or duet may cause irritation 01 scratch the surface of the eye, Skin Contact: Not considered hazardous by this route Skin Absorption: This material is a dry solid powder, no absorption is likely to occur. Ingestion; No effect expected If large amount is ingested get medical attention Inhalation: Inhalation of process emissions pah cause throat and lung irritation Exposure to low levels of PVC dust is not expected to oresent a ha7ard Form SP-1 Page 2 i.i GEORGIA GULF-EHS 199 ID 1 - 504-6^7-029? car iy'94 Li 18 No 005 P 18 Material Safety Data Sheet: PVC 1110 IDENTIFICATION CONTINUED Chronic Effecte/Carcinogenic; Chronic exposure to fumes and vapors from thermally decomposed plastics may causa hm asthma like syndrome due to the Inhalation of HCI vapors or fumes IARC has determined that there is inadequate evidence of carcinogenicity of polyvinyl chloride in both animals and humans The overall evaluation of this chemical is Group 3, meaning that it is not classifiable as a carcinogen (IARC Vol 19, 1979) Polyvinyl rhlunde is not listed ar. a carcinogen by ORHA, NIOSH, NTP, or EPA. iiiifRiT;AiD?MASURES inhalation No adverse effects anticipated by breathing small amounts during proper industrial handling If nigh dust exposure occurs remove victim to fresh air Skin Contact Wash off in flowing water or shower Eye Contact Immediately flush with water for at least 15 minuiey Do not rub the eyes Obtain medical attention if eye irritation occurs Ingestion This materiel is practically inert If. hnwaver, ingestion docs occur vomiting can be induced after diluting with water or milk, Call a physician for additions! medical advice measures Flash Ignition Temperature Flammable Limits (% By Vol.) Lower Explosive Limit (LEL) Upper Fxplosive Limit (UEL) Autoignition Temperature > 730nF Not Applicable Not Applicable Not Apoiicable Form SP-1 Page 3 'JC ijr\ u X T l|_! - ino LU l-'DU-y-b ABB0ck)232OO n c ' 1 q 91 11 Mr, 005 P 19 G&orgm Gulf Material Safety Data Sheet: PVC 1110 1 Fire Fighting Procedures/Fire Extinguishing Media Carbon dioxide or water Unusual Fire and Explosion Hazards Dense smoke emitted when burned without sufficient oxygen PVC will not continue to burn after ignition without an external fire source Do not allow fire fighting punoff water to enter streams, rivers 01 lakes The water wil* collect HO from the by-products of combustion Fire-Fighting Equipment Wear full hunker gear including a positiVH pressure self contained breathing upparatu& in any closed space : i Sweep or vacuum matenal end place in a disposal container Seo Section 11 ,~w / , *-*: WMLIfJtl AND STORAGE ''SpZj. Avoid contact with eyes Avoid breathing dust Minimize dust generation and accumulation Store in dry protected area Engineering Controls Provide general and/or local exhaust ventilation to contiol airborne levels below th5? exposure guidelines Good ventilation should be sufficient for most conditions Respiratory Protection For most conditions, no respiratory protection should be needed, however, in dusty atmospheres, use approved dust respirator Form SP-1 Page 4 'j bh.UPL-LH bULF-EHS D 1 SC 4- 5XBIW0023201 GCT 19'94 II 19 No 005 P 20 Ga&s^gm GuH* Material Safety Data Sheet: FVC 1110 4Jt. a 'osr CONTRQlS/PERSQNAt. CDNTtPlUED v' ~ v " Eye Protection Use safety glasses If there is a potential for exposuie to particles which couid cause mechanical injury to the eye, wear chemical goggles Skin Protection No precautions other than clean clothing snoulH bn needed Exposure Guidelines OSHA R-hour TWA i$ 15 mg/rrr total dust, and D rtig/rn3 respirable dual ACGIH TLV tor total dust is 10 mg/m3 tfBiBsjeAL-AND CHEMICAL PROPERTIES Appearance Odor Boiling Point, Melting Point, Freezing Point Specific Gravity (Water - i o> Vapor Pressure (mm of Meroury) pH White powder Odorless Not Applicable 1 39 <0 1 Not Applicable - Solid imifrABtUTY AND reactivity k*s& Stability Stable xx Unstable Polymerization Hazardous polymerization will nor occur Hazardous Decomposition Products Temperatures of 30QrjF, (150C) over on extended period of time may cause therma) degradation of FVC resin. The formation of hydrocnlonc acid HCI, nmy be generated during this thermal degradation HCI fumes and vapors may causo irutation of the eyes, mucous membrane and respiratory tract Form SP-1 Page 5 EORGIfl Giiir-EHS A ID 1-50 ) EABBQDD23202 OCT 11 20 No 005 P,21 Material Safety Data Sheet: PVC 1110 v*0 -- *. '"iv ? n3rTT''?' tV' 0,21'1'""''''"' ,.f'r '-Vi AND REACTIVITY CONTINUED Incompatible Materials Polyvinyl chloride materials should not come into contact with acetal or acetal copolymers tn elevated temperature processing equipment The two materials are not compatible and will react in a violent decomposition when mixed under conditions or heat and pressure Strong oxidizing agents afeeDiSPOSAfc CONSIDERATIONS Waste Management Information. Any disposal practice must be m compliance with local, state and federal laws and regulations (contact local or state environmental agency for specific rules) T21ETRANSPQRTATI0N INFORMATION Proper Shipping Name DOT - Hazard Class DOT - Shipping ID No DOT - Labeling Polyvinyl Chloride None None None Form SP-1 Page 6 GEORG I n GU'.F-EIIS ID 1-504-6^-W?3203 OCT 19 ' 94 J1 21 No 005 P 22 Georgia BM Material Safety Data Sheet: PVC 1110 OSHA 29 CFR 1910.1017 *- *1 his msm mey contain trace levels, <00005%, of VCM Under normal working condition with adequate ventilation, ncilhci the 051 IA'r 8-hour TWA, llppm) nor the {0 5 ppm) uciion level should be exceeded. The workplace should be muniloicd, and if the level exceeds the PEL or action level, refer to 29 CFR 1910.101 7 In addition, containers of PVC resin shall be legibly labeled with the following warning Polyvinyl Chloride Contains Vinyl Chloride Vinyl Chloride is a Cancer Suspect Agent 111 in'! MSDS Status: Revision Dele 1/14/94 Supersedes 1/15/90 Form SP-1 Page 7