Document npQedgGrVoMLJdLgvDMwGaz8z

1% ABD00022670 Georgia Gulf Corporation and Affiliates Category 3 . in.-' MATERIAL SAFETY DATA SHEET Date Juiy 26, 2000 Q t'fi) feJ8! h k i-1. MANUFACTURER Georgia Gulf Corporation- Compound Division, Flexible Group ADDRESS 210 Industrial Dr N, Madison, MS 39110 TRADE NAME Polyvinyl Chloride (PVC) Compound (Lead Stabilized) SYNONYMS Vinyl Polymers, chloroethylene homopolymer compound CAS NUMBER(S) Mixture - available upon request TELEPHONE NO.: (800) 822-7529 CHEMTREC (800) 424-9300 2. COMPONENTS AND HAZARD CLASSIFICATION 4 ,, --t *V~ A < * <* * ' ** 1 * ih 111 " rt r> *t >a f -~*zf > 1 s- . -- ' * * Compounded PVC is an inert material in its normal usage All the components listed below are encapsulated in the PVC matrix See Section 5 for hazard information Tspical compositions are listed below Polyvinyl Chloride Pohmer Inert Fillers Heat Stabilizer Plasticizer Colorant Flame Retardant 45- 80% 0-40% 3-10% 0-60% 0-5% 0-20% CACCy.talc carbon black TiOj clay Organometallic compounds of cadmium bariumcalcium-zinc or lead High molecular weight esters Organic and inorganic colorants (can contain lead chromiumand/or cadmium) Antimony Trioxide Aluminum Trihydrate PVC Compound contains less than or equal to 1 0 ppm residual vinyl chloride monomer Vinyl chloride is regulated as a carcinogen according to OSHA and listed by NTP and IARC as a carcinogen The product, in its purchased form, is not subject to SARA 302 or 311/312 reporting May contain less than or equal to 1% arsenic compounds 5% antimony compounds, 2% barium compounds 2% cadmium compounds 5% zinc compounds, 5% lead compounds and 2% chromium compounds which are chemicals subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372 This product may contain chemical(s) known to the state of California to cause cancer (California Proposition 65) 3 4 : [ 11, f:f |:f; ^mi P!t4!:' ii ;n i?,^1jv; BOILING POINT (F) Solid SPECIFIC GRAVITY(H20 =1) 115-17 VAPOR PRESSURE (mm Hg) Solid MELTING POINT SOLUBILITY IN WATER Solid VAPOR DENSITY Varies Solid APPEARANCE Pellets of varying size, hardness, and color 4. FIRE -' FLASH POINT Not Applicable AUTOIGNITION Not Applicable (TEST METHOD) TEMPERATURE EXTINGUISHING MEDIA Water Spray, C02, Dry chemical SPECIAL FIRE FIGHTING Cool exposed equipment with water spray Use self-contained PROCEDURES breathing apparatus if fighting fire in confined spaces UNUSUAL FIRE AND PVC evolves hydrogen chloride, carbon monoxide, and other gases EXPLOSION HAZARD when burned Exposure to combustion products may be fatal and should be avoided 5. HEALTHTjlAZ^RPJINFORMAXIONfNfSpf ' ;44 - ,i; ;4> - FIRST AID EYES Immediately flush eyes with plenty of water for at least 15 minutes Get medical attention immediately Call a physician ABD00022671 Polyvinylchloride PVC Compound SKIN Flush with water to remove material from skin INHALATION Remove to fresh air If breathing is difficult get medical attention INGESTION If swallowed, call a physician immediately Only induce vomiting at the instruction of a physician Never give anything by mouth to an unconscious person NATURE OF HAZARD This material may contain a trace amount of vinyl chloride monomer Under normal processing conditions no occupational exposure exceeding the established exposure limits for this material is anticipated Handling of this material may result in the generation of dust that may cause physical irritation of the e> es skin and respiratory tract Decomposition of this material (e g equipment failures or any condition causing excessive heat) may lead to production of hydrogen chloride gas that is irritating to the eyes skin and upper respiratory'tract and which when breathed in high concentrations, may be fatal Individuals with bronchial asthma or chronic obstructive respiratory diseases may develop constriction of the lung airways Employees should take personal protective measures under any conditions in which hydrogen chloride gas may be released Even under normal processing conditions various vapors may be produced that may be odorous irritating and in some individuals produce acute health effects The concentration and composition of these vapors depends on various factors including specific formulation in use processing method and temperature and the mechanical ventilation procedures employed CARCINOGENICITY IARC has determined that there is inadequate evidence of carcinogenicity of polyvinyl chloride (PVC) resin in both animals and humans The overall evaluation of PVC is Group 3 (not classifiable as a human carcinogen IARC Vol 19 1979) PVC is not listed as a carcinogen by OSHA, NIOSH NTP IARC or EPA Some additives used to make PVC compound may contain metals, which in some chemical forms are suspected or confirmed carcinogens These metals, if present, are bound in the crystalline structure of the additive and to the supplier s best knowledge, do not present a significant health risk Additionally, the low levels of additives used in PVC compounds are also bound m the polymer matrix and to the best of the supplier's knowledge, do not present a significant health risk EXPOSURE LIMITS No exposure limits ha\e been established for this material It is recommended that exposure be kept below the limits for Nuisance Dust (PNOC) OSHA-PI I 15 mg/M1 8 hr-1W A (total dust) 3 ntg/M1 8 hr-TWA (respirable) ACGIH-11 V 10 mg/M 8 hr-1WA (mhalable) smg/M 8 hr-1W A (respirable) I he lollowing materials ma\ be present in this produet Calcium Carbonate OSHA-PFL U mg/M 8 hr-lW A (total dust) s mg/M1 *8 hr-1 WA (respirable) ACG1H-TLV 10 mg/M 8 hr-TWA \ntimonx Tnoxide ACG1H-TLV 0 5 mg/M' 8 hr-I W A Carbon Black OSHA-PI I ACGIH-TLV 3 5 mg/M 8 hr-1 W A 3 s mg/M 8 hr-1W \ Titanium Dioxide OSHA-PLL 10 mg/M 8hr-IWA ACGIH-Il V 10 mg/M1 8 hr-I W A (total dust) Lead Compounds OSHA-PI L ACGIH- n V 0 05 mg/M 8 hr-I WA 0 05 mg/M1 8 hr- T\V A \ m\l Chloride (all compounds) OSHA-PFL I ppm 8 hr-TWA 5 ppm SI LL/Ceilmg \CGIH-riV I ppm 8 hr-TWA Cadmium Compounds OSHA-PI l 0 005 mg/M1 8 hr-TW A \CGIH-TLV 0 01 mg/M1 8 hr-I W A (mhalable) 0 002 ntg/M3 8 hr-TW A (respirable) ( hrommm ( ompounds OSIIA-PL1 0 5 mg/M 8 hr-TW A (Cr IIand Cr III) ACGIH-1 LV 0 5 tne/M' 8 hr-IW \ (Metals and Cr III) Patze 2 of 4 Revised New Supersedes ABD00022672 Polyvinyl Chloride, PVC Compound Arsenic Compounds OSHA-PEL 0 5 mg/M5 8 hr-TWA (organic compounds) 0 1 mg/M3 8 hr-TWA (inorganic compounds) ACGIH-TLV 0 01 mg/M3 8 hr-TWA (elemental/inorganic) Barium Compounds (soluble) OSHA-PEL 0 5 mg/M 8 hr-TWA ACGIH-TLV 0 5 mg/M3 8 hr-TWA TOXICITY DATA While PVC is generally considered an inert polymer, exposure to PVC dusts has been reported to cause lung changes m animals and humans including decreased respiratory capacity and inflammation However, exposures approaching the nuisance dust exposure limits are not anticipated to pose any significant health risk Rodents exposed to PVC by the dietary or inhalation routes for 6 to 24 months have shown no significant toxicological effects SPECIAL PRECAUTIONS AVOID INHALATION OF COMBUSTION PRODUCTS AND UNNECESSARY EXPOSURE OF EYES AND SKIN CONDITIONS CONTRIBUTING TO INSTABILITY: Do not allow this product to come in contact with acetal or acetal copolymers within the extruder or moldmg machine At processing conditions, the two materials are mutually destructive and mvolve rapid degradation ofthe products Equipment should be purged with acrylic, ABS, polystyrene, or other purge compound to avoid even trace amounts of this product and acetals from coming m contact with each other INCOMPATIBILITY Acetal or acetal copolymers HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen chloride, carbon monoxide and other fumes generated with combustion CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Not applicable In case of spill, sweep, scoop or vacuum and remove Remove in a method that avoids the creation of dust. Dispose of only in accordance with local, state, and federal regulations WASTE CLASSIFICATION If discarded in its purchased form, this product is not a RCRA hazardous waste. Re-evaluation of the product may be required by the user at the time of disposal, since the product uses, transformations, and mixtures may change the classification. VENTILATION RECOMMENDATIONS General ventilation for thermal processing and nuisance dust control PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION If dust is produced during handling, a NIOSH-approved air purifying filter respirator that meets the requirements of 29 CFR 1910 134 should be used Full-face self-contained breathing apparatus may be needed when dealing with fumes from combustion of product Revised New Supersedes Page 3 of 4 \ ABD00022673 Polyvinyl Chloride, PVC Compound EYES Chemical safety glasses or goggles GLOVES Necessary when handling hot or molten compound (thermal protection gloves) OTHER CLOTHING AND EQUIPMENT As necessary when handling hot or molten compound 9. SHIPPING, TRANSFER, AND-STORAGE1 *. # *n < - a **, a _ , . 9 s' _ M .t_j ut*N * r*. >-o ill SHIPPING INFORMATION * i * k This product is not a hazardous material or hazardous substance as defined by the Department of Transportation, nor is it a dangerous good as defined by IATA for air transportation TRANSPORTATION AND STORAGE USUAL SHIPPING CONTAINERS Polylined steel tank cars or trucks, 1500-1600 lb. gaylords and 2400 lb super sacks STORAGE / TRANSPORT TEMPERATURE Extended storage or transport at temperatures above 150 F should be avoided to prevent potential agglomeration HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE Stainless or Polylined THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH GEORGIA GULF CHEMICALS & VINYLS, LLC BELIEVES AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY GEORGIA GULF CHEMICALS & VINYLS LLC'S PRODUCTS ARE INTENDED FOR SALE TO INDUSTRIAL AND COMMERCIAL CUSTOMERS GEORGIA GULF CHEMICALS & VINYLS LLC REQUESTS THAT CUSTOMERS INSPECT AND TEST OUR PRODUCTS BEFORE USE TO SATISFY THEMSELVES AS TO CONTENTS AND SUITABILITY GEORGIA GULF CHEMICALS & VINYLS LLC DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THERIN SHALL CONSTITUTE A GUARANTEE WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY GEORGIA GULF CHEMICALS & VINYLS LLC WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE EVEN IF THAT PURPOSE IS KNOWN TO GEORGIA GULF CHEMICALS & VINYLS, LLC Revised New Supersedes Page 4 of 4