Document np50vJmqDMqwmy9OqXVgqVx4a

Monsanto 113.93 COPY I MOMSANTO RfSfARCM CORPORATION / PATTON lABORATORY / PATTON. OHIO 45407 ESC-Dayton IDirr /MCTONI Analytical v mxwt aceoaT RETORT NO.: NDA-35S JO0/PROJECT NO.: M3.4050 DATE: 15 April 1983 TITLE: ANALYSIS OF WATER SAMPLES FROM DELAWARE RIVER PLANT AUTHORS: 1. Mason Hughes end Robert F. Ivory U>.sJ 0 C. w u! Ku -S ABSTRACT: Water sanples froa the Delaware River Plant were analyzed for specified organic compounds, netals and chloride concentrations. The results of these analyses are shown in this Report. Technical Approval i* rP^0 :l Approved hy Robert F. Ivory ^ Environnentel Sciences center Service Project Manager Approval date: fS /V. / . ) * J__________________ s U *IAAY it ii RESTRICTED DISTRIRUT10W ( over) FILE COPY DO NOT REMOVE FROM FILE COMPANY CONFIDENTIAL HONS 022527 COPY NUMBER 1 E. Janro Delaware Rivar 2 >. f. Ivory 1250 1 Central PIloo 1250 4 Technical Reports Lbry. R2C ABSTRACT ONLY R. N. Scott/1250 H. L. Villiane, 02R j. d. wiioon, erne W. B. Vitaor/1250 H. A. Voltereann/1250 ROTE: Diatribution of this report ia restricted. Requests for additional copioo ahould bo nade through the principal contact at tha Monsanto location involved or the Manager, Environmental Seiencea Center, Dayton Laboratory, Dayton, Ohio. ACRRQWLEPCEHEltT Contributione of the following Dayton Laboratory peraonnel to this project are gratefully acknowledged: Analyses: A. Ford B. M. Hughes G. Thonaa 01R71/D ; C f' V ' ' C ;\c'Dr l When no Ipnear needed. ,or upon request return this raporpltt Central Files, Dayton. HONS 022528 11S93 S0PY1 Groundwater nonitoring iMplu collected at the Delaware Uni Mast by Geraghty a ItiUar, Inc., wn analysed and tastad for specified coapounda and paxanetara. Tba analyses and testing wara conducted In accordance with EPA approved or accepted procedurea [1,2). 2. SUMARY Table 1 shove tha analytical reaulta for the specified octal analyses and Table 2 above the applicable quality control data. Table 3 shows tha analytical results for the requested chloride analyses while Table 3 shows the applicable quality control data. Tables 5-34 shova the analytical results for the specified organic analyses. Figures 1-17 shows the applicable chroaatograaa for the OC/HS analysis for the specified organic analyses. 3. SAMPLING The sanples were collected at tha Delaware River plant sites by Geraghty A Miller, Inc. personnel. The sanples received by CSC/ MIC for analysis arrived in V.S. CPA approved containers. 4. ANALYSES 4.1 ICTALS ANALYSIS The analyses of tba aaaplea for the specified natals were performed in accordance to U.S. KPA approved or accepted procedures (1). 1 HONS 022529 9m <Ml)riM,e( the sanples for their chloride consult wn perforned in accordance to t.i. da approved or accepted procedures ID- 4.3 ORGANIC ANALYSES Sanplss Iron tbs Delaware River Plant were analyzed for bensaldehyde, benzyl chloride, benzyl alcohol, banzai chloride and Aroclor 124R. one liter and 0.01 liter sanples were extracted using eethylone chloride and hexane, respectively and the resulting 1-aL extracts analyzed using capillary CC/EC and capillary CC/MS analysis techniques. Table 5 suuaarizes the physical properties and identifications of sanples included in this study. Thirty* five sanples were extracted and analyzed with and without centri fugation in order to determine if the analyzes listed above (and in particular Aroclor 1248) are associated with the pure water phase or with the particulate/organic component of these sanples. Tables 6-14 sunnarize the capillary CC/EC analytical results for centrifuged sanples. Tables 1S-23 sunnarise capillary CC/EC ana lytical results for uncentrifuged sanples. Tables 24-32 sunnarize the capillary CC/MS analytical results for centrifuged sanples and Tables 33-34 sunnarise capillary GC/MS analytical results for eelected uncentrifuged sanples. Appendix A Figures 1-17, shows all CC/MS total ion and selected ion chronatograas fren the anal ysis reported in Tables 24-34. All high values of benzyl chloride and Aroclor 1248 appear to be associated with the partieulate/organic cenponent of the corre sponding saaple and the benzaldehyde and benzyl alcohol appear to be prinarlly associated with the water portion of each sanple. >0 bonsai chloride was detected in any sanple analysed. x/n i! 2 HONS 022530 1. Hathoda for Ch--lcal Aatiitii of Matar aad Motors. V.l. BA 00/4-27-020, Mli Ciaeianatl. Ohio, March 1777. 2. Draft Final Koport: Sailing ana Analysis Procodvras for scrocnlng of Industrial Effloanta for Priority Pollatanta U.S. EmrlronBontal Protactlon Apaacy, Cincinnati, Ohio, April 1777, 14S pp. 3 HONS 022531 TABLE 1. ANALYTICAL RESULTS FOR METALS ANALYSES OF DELAWARE RIVER PLANT SAMPLES, M9/ML Samplt ID 2-S -S 23-0 41-4 42-1 42-2 42-2 duplicate 42-3 43-1 43-2 44-1 44-2 45-1 45-2 44-1 44-2 47-1 47-2 44-1 44-2 Calcium iron Sodiue Staple ID 547 120 762 74.0 42.1 61.1 63.4 65.7 31.2 37.2 273 03.7 43.0 72.0 15.0 73.7 7.6 176 .2 a 10* 43.5 170 2,120 032 1.26 52.3 74.5 00.4 147 36.1 57.7 527 75.2 64.1 45.0 10.0 25.7 7.0 072 357 102 259 06.3 351 52.3 27.4 67.2 91.0 177 45.0 69.2 236 136 5.0 114 32.1 143 27.0 130 600 61.7 40-3 49-1 49-2 50-1 50-2 51-1 51-2 51-3 52-1 52-2 S3 53-1 53-2 53-2 duplicate 54-1 54-2 55-1 55-2 55-2 duplicate Blank 13.4 417 150 507 60.3 63.6 73.0 72.7 13.0 05.3 231 126 02.2 04.7 177 105 12.5 73.2 44.6 144 115 141 37.0 236 72.1 70.3 57.1 37.1 2,440 354 51.0 53.1 3.2 a 10* 102 27.0 244 240 1.7 125304 S*5sSSss3s2I*S *i HONS 022532 table 2. qbalitt camL wn ten mu analysis or DELAWARE MVZX SAMPLES, pg/kL Analvte Calciun Iron Sodiua Mtiruct standards ONirVM VllUt two V1M Paretfit rtcovtrv sa.s 100 09 71.4 6S.0 10S 912 1,000 91 TABLE 3. ANALYTICAL RESULTS FOR CHLORIDE ANALYSIS OF DELAWARE RIVER SAMPLES, ppm Sauole ID 2S 45 5S 23S 41S 42-1 42-2 42-2 duplicate 42-3 43-1 43-2 44-1 44-2 45-1 45-2 46-1 46-2 47-1 47-2 Chloride concentration 1.2 X 10* 4.0 X 10* 5.3 X 10* 3.6 X 10* 75 26.6 119 135 297 34.0 61.5 2.6 X 10* 342 245 146 41.2 242 24.4 2.6 1 10* (continued) 5 HONS 022533 DllU 3 (OMtiMMd) Wilt lb 4S-1 48-2 41-} 49-1 4t-Z 50-1 50-2 51-1 51-2 51-3 52-1 52-2 53-1 53-2 53-2 dupllcati 54-1 54-2 55-1 55-2 55-2 dupllcati Blink Hlwm concntrallon 6.S x 10* 273 146 2.6 X 10* 515 2.3 X 10* 320 586 707 760 41.0 207 4.3 X 10* 221 318 6.1 X 10* 715 88.8 874 988 <7 TABLE 4. QUALITY CONTROL DATA TOR CHLORIDE ANALYSIS Of BSLAMRRE RIVER SAMPLES. ppm Mimnet ttuMM Obumd vilua Trua valua Pcrcint ricovarv SEA 8501 EBA 8501 ERA 9401 ERA 3253 248 234 198 294 210 218 210 277 118 107 94 106 HONS 022534 TMU 5. QUALITATIVE DESCRIPTION OF SAMPLES RECEIVED FROM THE DELAWARE RIVER PLANT 403.40618 March 7, 1903 JBtiliS____ ftntrif-- 41-1 MS7 40-1 MSS 41*1. NF. MM 4*-J MSS SS-l MSS 0-1 M47 0-1 MS9 44*1 0070 40*1 MSS 00-0 MSS 0-1 MTS 46-0 MM 47-1 MSI IM MSI 46-1 MS? 40-1. 46-0 MSS 0000 =T I SictMiKwrl 2IM 21M 2127 2129 2109 2110 21M tux 211S 211? 21M ms nor 210 ana mo UM r" Sediavat Oraanic lavtr Calar 79 Moat Ora-- 7 Tract Matt Ora-- 7 Tract Mont Ortat 7 .b att nr S.S ----- 1 .0 w lllrar Hftr 11-- Srtat s.s .S m Hlltr o*r ( l/l-- Ora-- 7 Tract Matt Ttlltw s Tract Mm Ttlla* s Matt 0M 7 mm Brt-- s mm 74018V ? Tract mm Mkr s Tract mm Tall-- ? mm Ora-- ? mm Ora-- ? 4 rnm Ora-- s ttt mm -- adar aw mm mm mm m' m mm faal mm mm mm mm mm mm mm Warn mm "5K5Immmrnta CI44* *407 CI4407 Claadf M m Om* Om* Omt, C044* trnm <0var CM-- Oa4 MOMS 022535 TABLE 5 (continued) 483.40618 March 7. 1983 8Mte I M-l 49-* M-l IH 11-1 M-t-eeter* M-l M*l i*-a U-( ih a*. 14-1 M-l --........m MrllMH MKMlrUtNN 3903 3111 NM 3113 1973 3133 3074 3133 >887 MM Ml 3103 Ml 2184 MU >114 IM4 Ull SOW 3070 30S1 3113 MM MU MM MM MM MU M 0 7 7 S 4 7 0 0 0 0 0 s 0 SdianK Orflwic Uftr OWM lent Calar Irtu) Or** 0 0M lrw 0 Nmm VtUw 0 Rm T11V 0 Trtc* COtarltM 0 trace . trace m mm trace H mm Teller -1 Mm filter d /t----- kM --1 (OalMR fllur /l-- nii trace | Mae Ttllw -4 Uataaa Miter ef -- Tv11m -1 M-- (liter ef l/l------ Qma Mr Mae ant Mm Mae 0m Mat Mil Warn Met m m M- m m VleSr~ Mbmm (Mr (Mf Cta* CImt Clear dear Oca* dealt Oca* 0 dec# w HONS 022536 TABLE S (continued) 483.4061B March 7, 1983 CMtrlfoatd M-l 2m IW ii-i mb. IMS mz IS ms 48 MO M SMS W wm 411 NN Bran aa^le MSI yield UM 2007 t Oncnitrifnord 2141 2115 21M 21)1 21SS am 21)0 21)2 21M 21)0 m 5 0 0 0 0 5 0 5 5 S Sadimnt 0 0 Tran 0 Orotitic Lyr Mom Mom Mom Moot Tract Moot Moot Moot Tract Celer Tallow ft1 law Tallow Srtwo ehite Ortwo Black Colorlam ftltrlow Colorlow Mr Mom M M Mm leal real Maa Mae Mae Mm Weeel door Clear Otar Oo% O# daadr Om* amt Moor dear SanmU ihacacterirtlcl ef eater layer el wfla M-ti M*a ia C * far ike irpilr ykaaa ME la M at U-l t-Ular aa^la. *. m ef eeMaeat la l-liter kettle. *.? m at aadlaaat la 1-11tar kettle. Vl at eedMeat la 1-liter kettle. Ha aet aaalyaed. MOWS 022537 TABLE 6. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 lUrch 7, 1983 taql Mata Haul talari* Iratlar 1MR ------------------------------- Saaala MmtifUatia 42-2 42-1 42-2 DlfltClU 42-1 41-1 Iflllflll ..NttM oc/tc OC/IC oc/vc l.o.b.* s s s ND * rMCMtrit ta laaftl ND ND ND Hi ND m ND * mM ND <1.1 4H m m 4D. anaaata taikiaa r.n.nal taalytia MM MM (mb/L) aaaaair* (\) Hi liaaiar 4, se/se IB4. IBB M U M u m MB Batata talma (lltar) t.tl U1 D.Dt D.M Batract atai (aL) 1111 attact 8U tartar 1 11a - MV MS MD Mft mma - CtlW dM CtMB Qmm Va.. Halt W Micttai la ppl, Ijiat 4m aataB. Nr mm tatactaB with a Malta Halt giaaa 87 Ua 1.1.1. !* Ur ad 1 1 M Ml 1 t * am Oaaa 1 I HONS 022538 nui 7. RESULTS OT CAPILLARY GC/EC SCREEN I MG ANALYSES Of CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES S3.40618 March 7. 1983 laalru Rnapl aMwMa KmmI tklwMi Iraclar uw IlMlyiil MtM oc/tc e/vc c/vc L.O.D.* & % % SMlt l4MtiricatlM 1 44-1 j 44-2 4*-l 4~l 44-1 <SM SN 1U CxitnlNt laa team___ (Ml m TO <SM m m 1.) m m m 44-2 m n tmmmit aalyala 4M larianU NUaa cnnl BalhaS team . nm dt 1--in 6 e/vc IF TOH 42 M IT m Bath aalna (mar) .1 .1 at al . ,1 '{ l 1 1 11i RM 411 tartar 11I1t Ml Ml MU MU MIS tnha . Mrr Mrtr dan dan dan 1WI at RMIla k nA. aanpt Am MW. Nr ana RMM aiA a AUftlaa IMl Rian hr tht L.R.R. aaln far aacA M >4 i 1 1 JL MOWS 022539 TABLE . RESULTS Of CAPILLARY GC/EC SCREENING ANALYSES OP CnTTRIPUCRD OR FILTERED DELAWARE RIVER PLANT MATER SAMPLES 483.40618 March 7, 1983 laalna BMMTl ildwMi iMibl iUrUi imlw urn taalyaii HtM oc/tc BC/BC BC/BC L.4.8.* 5 S s 47-1 a? m m Malt MatificitlM 47-1 j 4B-1 4B-2 4B*J [awaUatla lia/u__ m mmm m m BB m m m mm ' Hint _______ ______ _ aMiytia MM MtM (M/U hwi rr C\) d, liaaa 4. BC/BC If4 n U 99 BB B1 mmU aalaa (Utar) Satrat aalaa M.I B.BI B.BI B.BI B.BI i 111 fe*mt Ml SaHar i 1 11 tdmttaMM Saaato mi 2BU mv MB ClM claa Cka Ctaa Vm. * U4t af SHactlaa la mA. . Va an* *MM with a ErtacUaa 1MI fiaaa bt tha LM. aalaa far aaah aiyial B^r i 8888 HONS 022540 TABU . RESULTS OP CAPILLARY CC/EC SCREENINC ANALYSES OT CENTRIPUCBD OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 3.40619 March 7. 1983 Mitt 1--|l cUatl* Imil cMmtMv Irattor 1149 Myiii MIM CC/IC oc/tc 9C/BC 1.0.9 * $ $ 9 IH 99 99 >vle l#iti(ieUM 44-2 $4-1 $9-9 Cwctllflt 1-- tn/ll 99 99 99 99 99 99 99 99 99 Rmau WUm tmmmt #9M MM MU _ nr d| Mil 8) 9C/9C 1*4 4S S3 99 M Iflt itlai (liter) - 9.91 9.91 9.91 9.91 Miirt wit (te.) - 1 1 11 tenet tel taster - 1I1I mi 99M 99T9 9994 - ClM Omm ClMi ClMO VlJ. UNI W tetectta. te nA. mm ARM viUl Ahctta IMt i*n bf R> 1A.I. nlw tar Mtb i iI HONS 022541 TABLE 10. RESULTS OF CAPILLARY GC/EC SCREENING ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1983 taalrt* NmjI cUcrl* BmmI iUicMi Imtor IMS SMirti* se/ic oc/vc c/tc L.a.a. * $ 1 1 SmIi NniUflcaUiR SI-1 51-1 Voter SI-3 SI-3 MB CKnitritim ( nU)aaA* 5M t.hll1 la.saia1 n.hN1 RR m M BM 30 44 in s.asas1 ................................................ toftlyala iMMt SMS Css/D _ blUI Bt Imaai 4, OC/BC it4 MM lak aahaa OlUr) S.SI S.SI S.SI Mart aataa U1 1I1 Brtract 4U tartar 1 IS IB NtaRmUaMM SMV Ml KM mmrnm . Blrtf Sirty Blrtf - 1WI af 4atactlaa la mA. aanpt Aera aau4. Via mmm AttcM oltk a AitacUaa lWt iaaa W tkt L.a.a. aalat far aac* - M* mm Mr MONS 022542 TABLE 11. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1903 aaltta Imyl ckterMr taaaal cklarMt meter IMS AMlftU Retted GC/tC OC/tC OC/BC 1.0.0.* 5 s s si< imufleetten Li*** 1 52-1 52-2 SH sj-j |ooimtt| aa* HO HO ' CMCWtriUMI lua/1) HO <S0 H0 HO HO <50 HO m HO <50 HO HO toliall totktoa MM Cl| >WWM << Imlyili HIM OC/BC ST CM/U ia*. ita ___________________________towan ttl___________________________ SI 00 09 00 4ft apb aataa (llur) - 0.01 0.01 1 I 0.01 MraaTValw |aL) - 1 1 I K1 Mad Ml Sartar - 1 1 it* 10 1 C aatraattoa MW - W) 2000 Ml mi daaa ta . tiim a*-____SOI____ Vm. a 1WI *4 BWcUa la PNL. aanpt ahan Mai \m m mm MmM oillt a AlaUa lut |ta> kf IN L.a.a. aalai to aach 0000 HONS 022543 TABLE 12. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF CEWTR1FUCED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1983 Mlrti BMtfl (UarMa iMtl dkrMi in*tor Uto JbMlytU mtM oc/cc oc/tc QC/VC Solt idntifUitlM ! Ml M-l M*2 SS-1 *J kifUeiif taVto L.o.i.* _____________________cctmTM(w/u____________________ MC * V m m 7.4 a M> 1 MA NO m m m M M 211 m m m 4M hillaa baial til faaaaaa 4 ImlftU is? MM toMU _______________________faaaaarr III________________________ toC/K If4. 148 Ml M 4 M St > aalaa Uttar) - 1 k .01 .M Brtaaat wkai RU - SI11 MM El (altar * 11 11 1 1 MC artractiaa MM m$ tm 2W mu - Ctott Mrtf CtoR nmm Vl.l. IWI at fataetlaa la mA. aaca* Am art*. *W . aaaa MMN aim a Malta Matt flam W Ma t.a.8. aalaa Hr Hd Hi - art aat|aa4. 1 1 MM . 1 I MM Matr MOMS 022544 TABLE 13. RESULTS OF CAPILLARY GC/EC SCREEN INC ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7. 1983 Isalrtt NMyl cMarMt ktaaal aklarMa inttor 1140 IkNlyiii Ntltod CC/CC CC/1C 6C/K s s s Swlt IdtfilificaUa* 25 45 ss 235 415 Cancantratiaa (aa/L) to tok 2.5 a 10* <500 toHO <500 <500 to 5.1 to to Mal4 Olato to to to | tti-kaaatat-R, ooalytU kthaf OC/OC kmml (M/l) !* _________________________hw H)________________________ 45 40 24 12 SO 04 fit ralsH (lltar) - 0.01 0.01 0.01 0.01 0.05 strati.ralMt (at.) - i 1 11 c 1I Mmt 411 factor 1 - 1 1 111 SOM sow SOM son aovo *--u - Claaa oirtr Hrtr doto *-- Va.. list! af ANctla Is MIL iscrt <*an mM. Si MSC auctW Vita a atKlln lisit fins fcf tin L.O.8. salat far sack 0.05 1 S am JL HONS 022545 TABLE 14. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OT CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1983 11 1 1 _____________ Nlm__________ ftmyl ifclwt* AMlftlS Rrlbad CC/KC Nwl cUwi4r GC/tC Omlor 1240 OC/IC loa* 5 S S NMhod Blank ? MG m Sml HMhod Unk HrtkoO BI*k RetH*4 Bltftk (mnntratiN tm/Ll NO HO HO HO m HO HO m _, Cli teaatar 4, . iMiftii 4M MM ClM/U ______________________ --caaatr CM______________________ mm laM* u 40 u SI tapir nlD (Uteri .*1 o.oi o.n 0.0 Mini wlai (N) 1 1i1 tract Ml frcter 1aa1 K rterattlra Nttes4 2fS2 2011 2072 2000 ChbhAs ClNft ClM elm V.. IMt af Crtactlaa la n*a. DM bucM NO MmUm IMt ftraa kf Du l.a.R. aalaa far elm HONS 022546 TABLE IS. RESULTS OF CAPILLARY GC/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 463.40616 March 7, 1663 NMyl iMlfU ImmI dklori*t ftrmUr INC AfMlftlft Nrttwd oc/tc oc/tc ec/ic 1 0.0.* % % % 42-1 a* m * 42-2 *>)!* ICrntilicidw 42-2 Delicti* 42-1 41-1 4J-2 Sfdimt ItCiHl CMCtMUliM (tMlU a tUk a m m mmm m mmm m m m ton--i*a totttoa fill ri| toaaww <t HIM C/1C SST Mi) to4 _________________________tore--nr HI______________________ - - - Sa--la calm (lltrr) atrart aahaa (at.) (tract Ml factar .1 1 >12* Ul im Ml 1 W t.oi i am i am 'I------------------------------------------------------------ 1---------------1------------- 1------------- 1--------- Vl.t. IMl ft OrlacUaa to nTl Sb a mm AtKlW aitk a totactlaa ltolt Rm to tto 1.6.1. aalaa far aacA n^aaa art aaalyaiC. i am 1 1 s 1 HONS 022547 TABLE 16. RESULTS OF CAPILLARY GC/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7. 1983 bwliU Iniyl (kliriii Imftil cMwl* 4r*cWv 1244 1i 44-2 Svl l*ntirieUA 45-1 45-2 49-1 iMlyiit NtlM ec/ic c/tc CC/IC L.O.D. * s s i MC M MM 42.4 ) .fcalO3 CmctMnt law IMA) tut Mt It Mt *> m Mt m m 49-2 L m Bmaaaia MUm hRal taalflll Mrd NtlM (M/U litwi nr W Clt Iwaan-A 9C/IC ia - - - --- Ipll nlw (lltat) .1 .1 9.91 9.91 1 V 1 Attract Nlw M) MINI 411 lactar - 1 2129 1 19 2121 1 2119 i 2117 t-RU - \.M. IMI af NUcUo U aa/L Nb awaa BImM altk MKll> Halt laa M Uv H I aalaa lac aach `M --lp4. 1 9.91 1 2124 9.94 1 STO HONS 02254B TABLE 17. RESULTS OF CAPILLARY C.C/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7, 1983 tMlytU ____________*asld_________ HftM femtyl cklwl* CC/IC 2 1 ec/tc meter ism cc/ic L.O 0.* s i s 47-1 MC Mk k *7-2 SmdI* Idintifiertiw *-1 4B-2 CMtctntrrtion (m/LI M M nm m ttk m m MB MB m n. iamaau Mklac ri anal tlfkaaaaaa 4, iMljfaii m%tm4 oc/tc MMRt iMH (M/i> i - Memn (%) -- - ala aaUMt Uttar) e.ti 01 I -->im wtei |n) i1I Mract 411 fcctar K aatrartlaa Naika4 sit? SIM Slit CM*. Vl.V IMt W AlKtl* la Nft. MM AIkIW *lth a atKtlM Halt flm N m 1.0.4. MlM far rack Sa a aat nlfn4. i Sllf Ml 1 SSJt MONS 022549 TABLE 18. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES Or DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7. 1403 AMlfl* iHNfl ChlMtll N--il (MtrMi ifUr IMi Sw|p linhlic<lti *? | SO-1 U-1 to*lyis n*Mwd cc/tc L.O.O.* s NAr 1 COftCtMVAliOft WU MA NA M 0C/C s M HA IU m GC/IC s k 0 m m OIMNI toiUao Cwal rt, if-- 4 tMifiii MtM OC/IC tJSil w - iacaaart 111 -- ayk wiM (Utar) i.ti Ml i I.M atraat Mm (aL) Ml ail 811 tartar me aalractlaa Ratkad i1 i1 --mi nia 1111 iia C-- t.0.8. liaU al datactlaa tit m/L Hb mm klKlN with a 4attiaa 1MI iaa by tha t.S.O. nIm lar tack SotaN aalfNl. MONS 022550 TABLE 19 RESULTS OF CAPILLARY CC/EC SCREEN INC ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7, 1983 AMlrt* Itnay! cfclaclds antal cklMl* hmlw IMI Analyst* Method oc/tc CC/KC oc/tc i.o.a.* s s s Seaele lOralilicaliaa SI-2 SI-1 Water SI-3 Conrentrstiaa (m/L) MAb NA NA NA NA NA O.llalO4 C.MalC4 t.ataia* hmatt Balkiaa W| Inna I| Analysis MM oe/ic StT (M/U ! - scaosrr (%) -- Baaakr <t)n (11tar) - Mract NlM (at) - Mract Ml lactar K aatraftIra artfead - -.......... V.. IWt at Btectlw U Rf/L. S aat Balm*. 0.010 0.010 0.010 k11 too 100 1000 loot 1103 1100 [f >lr<T____ HONS 022551 TABLE 20. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7. 1983 ftMlvlt Imyl chloride mol eMrl4i Imlw IMS Anolftie Method ec/tc 6C/KC OC/tC l.O.i.* s s t S2* 1 ft* ft aab Sasl( I4ta(ificatiaa S>*l SM SM U-2 Sedinent SediMent DfllClU Concentration (no/L) MA MA ft ft ft ft ft ft D m m iarraaala iatkiaa Caaaal Clt blMIM^ HUM OC/IC (M/l> _______________________arT (%)______________________ 104 - - - - l--p>i wtaM (liter) Mmt ftlaa |a4) btmt 411 factor K aatractlaa Kathai Ml 1 - 2114 4.41 i - I11S i - 2414 C--U V*:i. lUt a fetactiaa la ibf/l. Si MM 4*lac1*4 Milk a Balaatlaa Halt flaaa by tha L.1.1. aalaa far aacfc aat aaalfaai. - 1 - 2112 4.41 1 - mi HONS 022552 TABLE 21. RESULTS OF CAPILLARY CC/EC SCREEN INC ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40616 March 7. 1963 Nlftl Inert dilarM Mail cMwilt Araclar 1246 Analysis AM Hod CC/fC GC/SC CC/IC L.O.D * s 5 S !! S4- 1 *4-2 Sadia*fit Sadiaant SS-I S4-2 SS-2 Nana NU<M Saflt Ab W 174 Concanlratio* (ua/L) NA NA NA m m NA NA NA m m HI 32.3 1.2 NS I.T a M* tamau RRIw Oaaaaad Cl| lwiirl< Raalfaia ktM NC/BC tawit add'd (M/U 14* __ _________________________Wwi ID__________________________ - - ---- $m*H nlw (llt.r) Urtrwt nln (aL) MUM Ml IMH me ntractlaa MlM c--t I Vo.' IWt ( Mttctiaa 1 m/L. S art aaaljaa*. 1 BOW 1 1 2fU OBI 11 2141 im I tlM I.M 1 MM nm HONS 022553 TABLE 22. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7, 1483 aalTtr Mfl diltcMi M--1 CblWlli kneltf itoo KmIjiiii milwd cc/tc BC/fC CC/BC L.0,0.* S s % Sm| IBratilinliM JS 4$ 1$ 21$ Oil Concentrot ia tin/U c HA HA A m NA HA A m m nb O.ltaio* A SO m m nolo OIM m m Cli-kwm-4, tMWt iMlflil BM rntim* (M/U Oacaaarr (%) QC/KC IB4 - - SMpla nlM (lllar) Botroct iflw <>L) Him 411 factar MC ratractlaa Hatka4 - .1 I BUI 01 1 100 BIOS 0.01 1 am C--llU - *1.0.0. llatt at aataetiaa la Mfl. <M *i MW. *W a MM auttw alth a Auctlai IWt fiaaa Bf Ua 1.0.B. aalM far aach *m mi Mlpw. 0.01 1 1110 0.M 1 - nn OcOO 1 am J j HONS 02255A TABLE 23. RESULTS OF CAPILLARY CC/EC SCREENING ANALYSES OF DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7, 1983 ftMlVlt tottyl cfcUrM* Maul cbtorlM KkIk 1144 Analyaia MtM4 CC/IC CC/KC oc/sc L 0* S 1 % Ratted lank SmpU IdralificaUu i Ratted | lank CwtctnlritiM (m/II NA M Mk m Nnxu MUw cninl el|4Mw4) iMlftil MIM cc/tc tsr (MQ/U 10* ______________________________ cnnr (%)_____________________________ - tafh xlxB (11Hr) - MH Miact ntat IN) - >1 Mmt 8U IM> * am - tim e-- - Vl.l. INU N 4>lctlaa t mil. W mmm MmM witii atKtlM Halt (lx* kf Ik* L.O.B. nix Ik mcN Ha BBt bubIjmR. I a 1 HONS 022555 TABLE 24. RESULTS OF CAPILLARY GC/HS ANALYSES OF CEWTRIFUCCD OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7. 1983 5apl* iteittifintlM 42-2 42-2 Ouplicatv 42-) 43-1 42-2 kaalrtt littNte CC/MS l.O.D * it o` Cmctf(rtiM (M/L) m m <) I.D Ntyl cMtrM 6C/NC a HD HD HD m <t.M May) ilntel hail cfclarMt gc/m ccm 22 a HD HD HD m I 41 m HD m m <D.W <D.D4 anclar 1248 cm - HI m HD HD m hnwu loUim Ciiinal team JMlyiti H*Um4 U*ifU tetwin (\) H--al-4. cm It*. IN 24 14 24 12 M 44 K19M-4) OC/M 18*. 100 $2 47 42 42 47 u i.i-q, >--, h'-- 4 an-- in MK Mnctlaa bM C/M cm cm - 104, 100 104. 100 104. 100 - M ST 24*7 71 IM M SMS 44 14 24 2DM 44 n 47 2DS4 74 M 22 SD44 Ml M M2 mt (a--l< M. RotraetoB (II - - l.ll Ml Ml D.DS 1 1 V.. IWt tl Ruclta la 89/1. HUM at4. V mmm AUctW vita auctln Halt lm h Ik L.O.D. nla Im vach `at aalynO. HONS 022556 TABLE 25. RESULTS OF CAPILLARY CC/MS ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1983 r SwU tdvMificitlM 1 | 44-1 j 44-2 j IS-| 4S-2 4ft>1 4ft-l tellVtl mfl M*rl4i iMtfl ilniMl Mwl cMwMi AMlftlt Bitted OC/BS 0C/1V 0C/B 9c/m t 0.0 ______________________ CfucwitnUfM (aa/LI________ it l.i > 10* 103 tb m <.2 m m IB m 22 1.1 a 10* 0.0 10* > m ft MB IB m m <. <2 . <J <9. imtor lift* C/Bi - M*C m s?UMlyiii NWW WUM tatiMl Bitted tmM OC/IB 17 31 Bft m ft Ricofirt ft)______ 12 17 M m 17 HI'HimI-L C/Bi 14* M M ft* *S ft* m 1 ,hr1| C/Bi If* 72 U ft! 112 03 1U Tjnm-*,, 8C/RB It* M 7ft M US IN m RIRIM in C IlUaetUi Bitted C/M 0 ss 27 21 I1 12* m - MU MM 2*fti SMft 2*n am iMjlt tel. tetroctid U> - - -1 Ml 0.01 .ft . IWt of OttKUta la m/I. wpt 0trt iwt<4. Sr MM MtKtW vita a OtMtlM llMit Rwn Of tOf L.O.R. nIm Far aacR 'Ml m1tm4. f I HONS TABLE 26. RESULTS OF CAPILLARY GC/HS ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7. 1883 SmoU IftrM if tcfttiwt a,-, 4ft-1 40*2 4*0 ftMliti ImalMif* myl Mlflil HtUito CC/NS CC/RS LOO* I* nob NO CoAC*ntrtin (m/I) NO NO *42 <0.2 NO NO <0.0 <0.00 Hmfl CC/H5 22 NO NO NO 11 a It4 2.0 Nmi) cktorlto 6C/W * NO D m <0.ft <0.0* kraclar 1144 larraiu loUlai Caawl rkaaal>4. oc/ib hum4 c/m tmawi Bto (M/L) 104 c Nft m m m ________________________ Rmh I\)________________________ 13 24 i* 3* so I-Cl-fkaaal-A, l.l-C^-haaaaaa-A, tinm-*it * CkaTaaaa-8ia me htmtln totkto <c/ qc/i OC/IB C/W - 14 ftS ft* S3 00 00 14* 71 *7 SO Oft Oft I04 111 103 M 07 00 I0 11* 30 20 Oft M - 20*1 20*2 20*7 20*0 tm Sa^la 8*1. Batracla4 (L) - - 0.01 0.01 0.01 0.01 0.01 Vt.B. Halt af tatactiaa la mOL. aacaRt <*m aata. Sa a AtKIrt IU> a AlKtla Halt fiaaa by U> 1.0.8. nUa far aack *88 aa* aaalyaaO. MONS 022558 TABLE 27. RESULTS OF CAPILLARY CC/HS ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7. 1983 44-1 j 44-1 SU ldtn(ilillM S0-I S0-2 iNlrtt Analysi* mtM cc/m L.9.D.* II a.* Conetnlratlm (nb/L) MO NO HO ltw|l MrUi GC/MS 0 MO HO NO MO MSfl ilnlMl gc/ho 22 MO MO NO M0 aaaal cMarMa oc/wo o MO m m HO kneh* INI GC/HO - aa' HO RoraaaU (aUiaa Cm III It H--al 4 OMlytU HIM oc/ho mM*T (hWU 18* n 10 no HO (araaarr ID 32 14 Kl phaaal-4. OC/NO 18* 01 44 04 11 1.2-Clf >IHM OC/W It4 TS S2 123 110 him hi / lt M 0 124 Qw|--wA,i gcfm I*4 SI 10 141 K Batractlaa 8lUa4 - - 2003 2004 2013 (Via 8al. 8rtrarta4 (L) - - 0.01 o.ot 0.01 *1.8.8. 1WI a Rtecllai la mA. S aaaa MmM with a SaUctlaa Hall 8>"> *T 1.8.8. aalat far tack Sa aat aaalfiai. 120 122 2014 8.81 HONS 022559 TABLE 26. RESULTS OF CAPILLARY GC/MS ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SANPLES 483.40616 March 7, 1983 $*1* IdtMifiutiM SI-1 SI-2 Water SI-3 OMlTtt MuMritf* Hmyl eOlaeiOt ftiMijrti* Aolfco# CC/HS CC/NS L.O.h.* 10 Concentration (uo/L) 4 0 a 10* I I a 10* l.l a 10* 442 It a 10* I t a 10* Nwyl iIcoIm! ImnI dOtritfi 6C/RS 0C/IU> 22 III 10* 40 a 10* 1.4 a 10* 0 N0b <00 <00 mclw IMI oc/os 9000 ' w 19 37 MllhH MUn CmmI HIM (M/L) rhoaol-4. ocm IS ns 6*40317 161 27 Kl-flNMl-l, ocrm 50 i 102 l.l-ClfhMMM-4, ocm 04 ot 00 Oytww <t oc/m 90 4) 40 ftqfci In OC/NS 90 70 11 t MractlM MIM - loot 2009 200S <Mll M. btncul (L) - - 0.01 0.01 0.01 Va.i. IMI W fatoctioa in n/l (> I9M tar S1-1-4M). anN 4m Mtat. Nr Ml MkM with i AtictLi ltait fim hr Iht L.S.h. ! for ooch <M| Sk Mt OMlyMf. SI-2 000 itataA. l.l 0 10* l.l a 16* l.t 0 If* m l.t f M* 2000 - HONS 022560 TABLE 29. RESULTS OF CAPILLARY GC/HS ANALYSES OF CENTR1FUCED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40616 March 7, 1903 tMlfW RMkUtbfR tootyl efcloclOt MBf! tlctlml BmmI tblwM tractor IMS Vwlpii NftKod CC/NS LOO * it CC/RS a oc/ie 0C/04 22 4 ocm $2-1 b HD HR HO ' 11-1 $NI laniificitiM 1 j 53-1 93-2 93-2 Hflieitf fonctntratim (m/I) NO 90 I HO HD 0 12 <0.00 HO HO i.i i io 41 m HO m <0.04 m NH 04 H4 m totnralr Mlrtoo Crara* iMlyilt RIM 0C/ MM (M/U ________________________ Oraorarr HI________________________ It4. 100 u 13 13 41 14 1 k 2-Cl*plml-d oc/n I04. 100 SI 94 32 97 44 1 ,KI| tnerm-t. OC/IS it*, too 19 40 21 70 74 HmHir OC/OO 104. too 94 90 10 49 112 oc/*o 104, too 49 29 24 2.7 100 M litricUn IttM - - SOSJ 2094 SOSO 2041 2009 Mfl* <M. Mraet4 (L) - - 0.01 0.01 1 1 0.01 Iteit ( 4iUUi la mA. MtW. mm OttocttO vttti a RUctlaa lkil fim Dy IN L.O.t. vain* far tack Hr hr Muiyui. WOMS 022561 TABLE 30. RESULTS OF CAPILLARY CC/HS ANALYSES OF CENTRIFUCED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7. 1983 iMliti Nwni*Hiy<t BMtyl chltrl* Staayl alcakal ImmI dOwMi inclor KIM 11 i AfMljrtlt 1 MrthM cc/at 6C/M5 cc/ns oc/nh OC/M 19 0 * 14 27 i M 1 2 a IP* < 400 11 10* <M0 ho S4-1 n an SJ1 ND m SmI Idrnt if icaIim > 1 >1-1 i | 11-2 i ! taplirait lr lOlt rnft<i(rtiM im/1) jm k at 11.8 a It4 | n HO HO I t a It* 1.1 a It1 HO HO 4.1 a It* ho HO aac m m m UNO anali 6UIM C--ill H-->-4| ftMlytlt 4M MUwi (M/U C/Mi n', iaa 44 44 l-CI-fknal-4, C/IB is4, ito US 104 l.l-Clt liaun-6 9CfM i*4. iaa 142 71 1 fi 8|-- *ia dqiiw Sit ocm C/Mi It4. 100 it4, itt - M US 2044 44 JO 2M1 Sa^lt M. attract** (U - - 11 V.. 1MI a* Manila to mfl. anM aknra aatat. St HM NUcIN viik a Mictla Itoil i*aa M U tot. * art atalrtat. Mctwnr i\l li to 44 ss 71 M 4 44 so IS 2M4 IMS .1 .01 I" tack tI IS ii 4 *1 11 2M2 -M m 4t n ss IS MM 0.01 HONS 022562 TABLE 31. RESULTS OF CAPILLARY CC/MS ANALYSES OF CENTRIFUCCD OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 483.40618 March 7, 1983 St IdMtidCllUM 1 25 4$ 55 23S 41S Malytt MMimfeyfe Bawyl cfcterlSi iMtyl ilniwl IwmI cklarlSa IMMlytU ftttM CC/RS 9cm ocm ocm 1.0 1 * 14 21 4 im (m/L) as* S3 a IS* I.S a IS* m m m 1.1 a IS1 m m m m 2.3 a IS* I.l a IS* m m m <424 m m m meter IMS Nnwu iplklaa Crawl oe/m teilpli HIM OC/MB iMUlt M IlM/L) 11* mc m n.i 24 mm 4c-- rr (%) iM m M i-aiM-44 1 kiwti-4. C/1B c/m it* 10* S2.I 4) 44.7 72 77 74 Fnra-Sia CWlira l|. ac/w c/m IS* IS* 4.4 44.4 34 34 144 44 WC wtractlw RtlkaS * - 2H4 MSS 2444 Saapte *al. tatracta* (11 - 4.41 4.41 aU VlJ. Itelt W tetactlw la pan. wrapt Nan WN. Si awt attctN vlll a AtMtla llait pw Sy tka 1.1.1. aalaa far aaak S a aat walyaaS. 142 44 72 73 2*77 .41 7f m m 44 3474 4.44 fteM 41m4 m m m m m 14 73 m 44 23 mn .44 MOMS 022563 TABLE 32. RESULTS OF CAPILLARY CC/NS ANALYSES OF CENTRIFUGED OR FILTERED DELAWARE RIVER PLANT WATER SAMPLES 403.40610 March 7. 1903 ftMlVtl iMMlMqr# imyl chloride Oemjl ileikil Itmel chloride hmlor 1240 kulyiii Mllwd oc/m 0C/HS CC/RS oc/m oc/m tea.* II 0 ft - Hrthod llml ho* HD HD m c Svlf l|pnu(ieiliM Method ftlonk Hrlhod lUnk Method ilonk Concent rot ion (n/L) HD HD HO HD HO HD HD HO m HD HD HO mmm tarraata taltlaa Caaaiail Htaaal-4t iMlyiii HiUm4 oc/m 4M (m/U 10* ________________________ Raaaaara (\1________________________ IS M M is l*l-f6aaal*4a l,HI|4aMaa-4| oc/m !* ft! ft] 70 M oc/m ia 72 00 100 1 P|taaa*4a ChfT*aaa*4|l me Mractlaa RaUa4 C/M oc/m - 14* 00 91 ait 72 I4 27 2ft in 29 20S2 2071 2072 2000 latU al. MikM |l| - 0.01 0.01 0.01 0.01 *L..R. Malt af 4atactlau la a/l. *! mm MM altk a tatactlaa lull ftaaa by Ua L.oa. aalaa far aacb 'M aaalraa*. HONS 022564 TABLE 33. RESULTS OF CAPILLARY GC/MS ANALYSES OF SELECTED DELAWARE RIVER PLANT WATER SAMPLES CONTAINING SEDIMENT 483.40618 March 7. 1983 Wlftt 9*myl cMwi* . 1I kaMrtSlyotdit i l 0 4 * CC/RS It CC/RS t S*r>l# iftcatio* SI-1 || wsai-tr#r 1 j 3.-1 s Pfa Cencontratio (ua/t) I 10* 1 a 10*I a 0 Hi la' VI a 14* 4.1 a 14* 14a 10* 44 a 14* 1 S a 14* M a 14* l.t a 14* imji ilniwl ItMii Url4i CC/ltS QC/RS 22 4 mb NO NO m 4.4 4 14* Incltr 1240 gc/rs ma' AffOURl m 00 1.3 4 14* tottol. tolkln tM.l MumI 4t iMlyitl mtM CC/RS addad tOd/U 1# IkcRYin t\i 4 91 0 w*0C/00 90 90 59 50 I.I-Cll-toaaaM-4, ryvw*-4|| OC/RS 104 102 05 90 51 CC/RS I#4 09 77 50 01 - ni'M'-iii 0C/R9 If4 0 00 27 00 - me btrMtiN IblM !. tatractad (L) - - 2099 2109 1104 2105 2100 - 0.01 0.0K 0.01 0.01 0.01 Vl.l. llHit toucliaa to K*/l mm AIKtH with a trtactiaa ltoit |im tj 1.8.4. aalaa far aacA i m 1lai. MOMS 022565 TABLE 34. RESULTS OF CAT ILLARY GC/MS ANALYSES OF SELECTED DELAWARE RIVER PLANT SEDIMENT SAMPLES 483.40618 Htrch 7. 1983 SJ-I S4* 1 Sedia*nt S*WQt AmIvU ttaulMii^r kMfl (kiwi* tMifl link*! JMlynt WtM cc/ns L.O.O * It | WO cc/ns 'em CC/NS 22 t 1 > It*' " HD concentration* (in/L) 1____ Nkl (kiwi* kraclar 1241 CC/NS ocm S 100 MO NS- m tonau Spftkiaa cxxnl Sulnii IZ7 IktM tuc/U ItCWIfT (\) rktwi*4| CC/NS 10* 33 IS 2-C1-9**mI-4 CC/NS id* U n 1,1-cit kmiM^ tfrinHn CC/NS it* 7J CC/NS It* 130 00 so Ckryw mC MracUo *tM CC/NS - 18* ISO - 2070 2097 MNk M. MimM (LI - - -- Vl.l. lUt N AUctla l> M/L. S> MM MartW lth AtKtiw liail fix* hr U* L.o.h. 1m lx rack 'cimIiiUmi nlaUIH mli| Vl> m< MHlrnR. L mmIi Imi. HONS 022566 APPENDIX A 39 HONS 022567 rPNi X .86 V t.M 16754 35SM C43-n 8946 _Ll 11 15755 35 555 15749 35(M 15754 35nt C48-33 5565 , 1.1 i C48-83 8565 (MTUOftTE) III is I 1 j*+ "T* 3 ^1 H* C -* 1 3 1 ________1_____ P T 1 15755 35- C45-13 5557 d_____________ TIME figure 1 1 MOMS 022568 i'16^7* irS3r5W- 11 C4S-B32M6 C36 CM X. .96 v l.M C46-13 8M5 /** 1C7M 36- Nt 6 i KJ i .1ten* <hi .* .1 - .CM * C44-S3 M7C i -JT44-13 MM 1C7CI || 3*3, llrtm C43-C3 IMT 1 MMtilt3141MMTIMMM2. rlguz* 2 1 J1 l HONS 022569 HONS 022570 I I rPNi >- .06 V 1.00 ............. ! 1C74B 3S500 1*744 IN CFICID L*NO 8*97 4. ..... ..'U < -i t~ ! 1 J t "f 11 k 1] 1*7*1 C4*-*3 M* CDH. Ill*) ___________________________ nm i *34**7* MMU*U141*MI71MIMii Figure 4 1... .4,______ HONS 022571 HONS 022572 HONS 022573 V I.M 1CTM CO-13 MM (DXL 1IIM) ft trm IN I ai 13 a1111 r 11111 i i 11 i i i i" I I 1 4 11 7 I NNIUUMtlWnn Figure 7 HONS 022574 HONS 022575 HONS 022576  FPfll i i j10740 35SOO lores 30 500 X cntTwoo 1 .96 crrmoo luwa otto 1 10721 ; CHETHOD UNO 0071 i'h ^ V - l .* ______ i____ 3 0 -Is1 J |( 1 kk MTOO DKINOO tuna aooa ______ 1_________ TWO 1 0 0 4 0 0 7 1i nnumn+9MnmmmwMmmmmmmnm Figure 10 HONS 022577 MOHS 022578 HONS 022579 HONS 022580 HONS 022581 rmi iCTSl X .5* CS1-13 MSB (DXl ill#) V l.M iim CS4-C3 8MB inn I 1 i MTM HH3 MM MOM IM STB. L L . illLI___. a TVS n '94 m m Figure IS HONS 022582 rimt >170 CS1-XJ 11*4 (OIL . V l.M aJlJ|L Li Jl Dt-n MM (DIL 1HN) um oJL IPTSP mUiCtl-P(0MP>3 PPPP (PIL 1I1MM) ia 1C7M 1P1PP Bl-KUMIlin IM (Dtt KIP) JL1 Lii JlIM PTP. "I........... .. T MU T----------- I Figure 16 HONS 0225B3 FUN! He .SO C4*3 IIM (OIL Hit) V l.M 1C7M * ONUn MVU3 MM (DZL 1UM) AL_1 -1.4 Ji L _1CTVT A. A .1 a. l M0CL0M ISM OTD. U9M JlL JLl u_ i 14 M M | tiii Figure 17 HONS 022584 Monsanto 1119? COPYi urn*nwi miuwcn iwwmiwr; patiw uioiutohy / paviph, bmp jmoj ESC - DAYTON i" /MC10Ni ANALYTICAL TH 0# ftlWT ftlHMIT IK POUT MO Addendum: KDA - 359 ECEIVED X*OJ(CT MO 0ATI 483.4050 23 December 1983 j*\;> 1 at pir*od covirid n onUANTO-DAYTON CENTRAL FILES > tiui ANALYSIS OF SAMPLES FROM DELAWARE RIVER PLANT at authors F. D. Hileman e abstract A temple previously subritted for analyses by the Delaware River Plant was analysed for 2,3,7,8-TCDD and 2,3,7,8-TCDF. Results of this analysis is shovr. in this report. ; Technical Approval M O J<z Approved By: i < R. F. Ivory ' / Environmental'Sciences Center Service Project Manager Approval Date: -/* F In ig ii r. ^ ' ---- i COMPANY CONFIDENTIAL HONS 022585 COfY NUMBER 1 E. Jaaro 1290 2 R. F. Ivory 1250 ] P. 0. Hileaian 1250 Central Files 1250 5 Technical Reports Library 1250 IO\ ABSTRACT ONLY R. M. Scott 02B H. A. Wolterman 1250 NOTE: Distribution of this report is restricted. Requests for aoditional copies should be made through the principal contact at the Monsanto location involved or the Manager, Environmental Sciences Canter. Dayton Laboratory. Dayton. Ohio. ACKNOWLEDGEMENT Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged: Analytes: F. D. Hilenan B. M. Hughes D. Kirk (' O :> CONFIDCMIAl kgns A single sample labeled 'Sample Point 51-2, 2-1-13* was received for tin analysis of 2,3,7,8-tatrachlorodibenzo-p-dioxin (2370TCDD) and 2,3,7,0-tetrachlorodibenzofuran (237t-TCDF). Ttia sampla had been aasi9nad MAC log number 1-B3-02-04-04. The aample that waa analyzed coniiatad of the bottom layer of a two phase sample. This layer was a dark organic layer with a very distinctive odor. The analysis of this layer proved to be quite a challenge. This Is due to the significant amount of aromatics which were present. These compounds either eluted the TCDD and TCOF off the clean up column used to retain them in the clean up procedures or were so similar to TCDD and TCDF that they inter fered in the final analysis. The analyses were finally carried out by taking 1 gram of the lower layer organic and dissolving this in 100 mL of petroleum ether. One mL aliquots of this dilution were used for the sample, repli cate, low spike (1 ppm) and high spike (10 ppm). All aliquots were spiked with "C,-2371-tcdo and *'Cl.-2378-TCDr to serve as surrogates in the quantitative analyses. These 1 mL aliquots were diluted with 40 mL of petroleum ether and then repeatedly partitioned against 30 mL portions of concentrated sulfuric acid until the sulfuric acid did not change color. After the sulfuric acid washes were completed the petroleum ether was partitioned against 50 mL of organic free water and then dried over anhydrous sodium sulfate. The samples were then passed through a multistage column consisting of (top to bottom) 2 grams of silica, 4 grams of 40t concentrated sulfuric acid on silica, one gram of silica, 2 grams of 3fl KOH on silica and finally oee gram of silica. This column was then flushed with an additional 50 mL of hexane with the entire effluent passing onto a Koala B alumina column which retained the 2,3,7,I-TCDD. The taoela column was eluted with 10 mL of 21 CSaClj/hexane to elute FCBs and other AOhS 022SB7 1 potential intarfarancas and this fraction was discarded. This COlimn was than alutad with 15 sL of sot ClaCla/hMant which was collected and concentrated to 50 al and subaittad for GC/HS analysis. The GC/HS analyses ware carried out on a Hewlett Packard 59I5B GC/HS systen. The gas chroautographic analyses ware performed on a 10 sister DB-5 capillary colunn with the Mass spectroeieter operating in the selected ion aonitoring node. Quantitation was achieved by ratioing the observed anount of 2371-TCOO or 237STCDF to the isotopically labeled surrogates. Table 1 shows the results of the analysis for 2170-TCDD. Table 2 Shows the results for the analysis of 2171-TCDF. Note that in Table 2 the low and high spike values are conparable to the saaple and replicate. This results iron the fact that the spike levels were too low to be observed. The total aaiount of TCDFs present in one of the sanplcs is also shown in Table 2. Figure 2 illustrates the actual ion traces allowing that at least twelve TCDFs were present. Nota that there are M possible tetrachlorodlbeniofurans. It is possible that other TCDFs coelute with the 2171-TCDF and therefore the result given in Table 2 should be viewed as the naxiaua amount of 2J78-TCDF which could be present. 2 HONS 022588 TABU 1 ANALYSIS OF 'SAMPU POINT 51-3 FOB 3378-TCDO Sample Sample point 51-2 Semple point Sl-2(Rep) Sample point Sl-2(Spike) Sample point 51-2 (Spike) Method Blank Method Detection limit 2378-TCDD Sound NO* NO .86 11.7 NO 0.10 PPm 2378-TCDO added . 96 9.6 NO - none detected at the method detection limit 3 HONS 022589 TAM* 2 . analysis or 'sample point si-2* POA 2J78-TCDT Sample Sample point Sl-2 Sample point 51-2 (Rep) Sample point 51-2 (Spike) Sample poir.t Sl-2 (Spike) Method Blank Method Detection Limit ppr. 2378-TCDF found SO 92 9 58 NO* 0.10 PP" TCDF added 1.4 14 - *KD non* detected et the method detection limit Semple Sample point Sl-2 (Rep) PI* Total TCDFs 382 MOMS 022590 4