Document nmz4gp9Jox5MnjOn5JvdRB442
r XY&8RESEARCH
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Attachment 2
A1B222-1.7788-2- 4
Air Sampling Fluorochemical Report
IB
DuPont Washington Works -- Air Sampling Program Round 11
r
Exygen Research Report No. L0001668
Testing Laboratory
|
Exygen Research
3058 Research Drive
|
State College, PA 16801
|
Requester
|
MUiRchSaeClorDpoArautciooinn
BuilBdairnlgey27MiRllooPlmaz1a260
|
Lancaster Pike and Rt 141
`WilmingtoDnE, 19805
5 a
[ 5 Se !
o> 5
| s 7
ALLDATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
CROGAS | enim !
3058 Research Drive
SEosn, ,Toon, us Page 1of7
T: 800.281.3219
Summary
IB RSeesveeanrcshol)id(Emxeydgiean)safmrpolmeDsuwPeornetrCeocrepiovreadtiboyn.CeTnhtreemAendailaytriecparlesLeanbtorsaatmoprileess,oIfnca.ir(cdoblaleEcxteydgeonn [= OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes I collected.
|" The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography / mass spectrometry (LCMS). The method employed is entitled "Method of Analysis for the
~ Determination of Perfluorooctanoic Acid (PFOA) in OVS Airtubes by LCMS" (James Miller, | Exygen Research, February 17, 2003).
[The OVS tubes were separated into three fractions for specific fluorochemical analysis. Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD
|" wreassinnaotndaPnaUlTyzbeadckbiuntg.saFvreadctfioornspoAssaibnldeBfuwteurree aenxatlryascitse.dPweirtfhlu1ormodLecoafnomiecthAacniold.(FCr1a0ctiAocnidC)
I was added as a surrogate spike to each fraction prior to extraction.
~ Instrument operating conditions can be found at the beginning of cach analytical run. Raw
[" r
instrument data is given in Appendix A. Appendix B.
Chain-of-custody information can be found in
I
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 2017
n0526
Results Summary
SAairmpVloeldum(e1
Cg8/m Acid
I
IWCKAAAAUUSSIT-EE1111 A8
13139888
0<00.000000077
r
AWIAWK-ASAMST-1E1T1(TCo)
s1398emNA]
-
WWCAAAURSZEETAE18
|
WAASE E11
11434480 1348
<00..0000000077 NA
ANSE11 eta sou]
|
WWHHKIACAAMASUISEESNL A8
KASSEN O
9a3t1 pi
<00.00000011 NA
r
wha EUSIE11 ew)
1
000
.
CCAARRNSEA
|
WIKAMSEN C
<000000000077 NA
ARMS (To)
1
Gow
[
AARAISS E11118A
WHKAAMSS E110
11440022 1402
<00..000000307 NA
|
A ASE11 To) Tm
-
ar WWAAARNSESEErN A8
r=18n34
2<00..0000000077
[| ons tKrAeMSOE11 e(Tnoaorn teI mmm s etreeo ermm rie] my
1. "< is defined as not detected a or above the reported level.
2. Sample results have not been corrected for blank results or control spike recoveries.
|" 3. Please note th following descriptions of the OVS sample tube fractions:
|
FracAtion F[FirtacEtxitornacDtescription
c8 [12sntdssoottbbeeaaddsseexxttrraacctt (ot analyzed)
ALLDATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
|
Page 3007
|
20537
i z3 8iy0
roa
ro 5 E
ri5
ro 58
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FE3
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4
z aaE TT]
is .
1 pl g
if pl
531d
Ef pe
g3i3f | 8g
if
g38
:
Ext |
|
: ir ii
- gadiiftt [ ] g2 -p
|
|| ||||
|
|
|
|
Cnn5a8
|i
~|
Surrogates
[aSursruorgraotgaetsepsipkiekreec(oCv1e0riAecsiadr)ewgaisvaenddiendtthoe faollllOoVwiSngttuabbeles.toTghievreeaarfiennalocsoentccernittreraitaiofnorosfuSr0ro0gpatpebsipnitkhee extract |= recoveries. Advisory ranges are 75-125%.
i
[Mm | - AAFC X 50pp0b
ppb) 79
WKAAMSFBLKET 1 B 500
360
0) 7%2
I VWK AAK RRIMSSTEE1T1BA
550000
59684
111030
WWKKAAAANUSSZZEENN AB
[7] memes | - WKAAMSIEN A
550000 500
159873 517
1E17 103
% = VVIONNKK AAAAMMSSAEEENTTTA8
550000
I WKAANSSE11 A
500
556199 520
111044 104
WWKKAAAANMSSSSEN AE18
550000
552942
[| ses WKAANSSETT B
500
584
110158 17
= 2 a Conroispo 8
500
347
69
|" sumogate recovery outside of advisory range.
i |
ALLDATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page Sof?
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[elsicdi)
|
"Example Calculation
For sample WWK-A-AMSS-E11 AC8 Acid,
~
.
oo ~
=
(434 ng/mlofC8 Ac x(Ii ml)d x(1ug/ 1000 ng) x (1 mg/ 1000ug)] / [(1402L)(x1 m3 /
|
1000 L))
=
0.0003 mg / m3
! Signatures
[0 I Pbyd \|7 Toro
| 52h]
gs
by
|
hn M.Flaherty, Vico President
Date
|| ert Maron anfonia
.
AL DATA CONTAINED ITN HIS EPOWAS GENERATED BYEXYOB RESEARCH
[deliicic8
-
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} ANALYTICAL DATA REVIEW SHEET
.
-
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LC/MS
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TesB Miller
Lose tre 75,
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Analyst
ignature/Date
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Toto lake
I
Reviewed by
alm gulf shy
fgnature/Date
-
-
~
I
|
|
Uoog
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rose
=
LC/MS SYSTEM AND OPERATING CONDITIONS
-!
Client: _ Dupont
EXYGENSTUDY: _L0001668
i
Instrument: Hewlett-Packard 1100 LC/MSD (LC/MS 3)
APIS Interface - Negative SIM mode
-
Nitrogen: 10 L/min at 300C
'
Fragmentor: Variable; Vcap: 3500V
I
Computer:
Hewlett-Packard Kayak workstation
I
Software:
MAgiiclreonstofCthWeimnStdaotwisonNTVe4r.s0ion A.08.03
I~
HPLC Equipment: HP G1379A Solvent Degasser
HP G1311A Quaternary Pump
"
HP G1313A Autosampler
|
HP
HP
GG11391466AA
CMoSlDumn
Thermostat
[
HPLC Column: Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3pm
Column Temp.: 35C
I"
Mobile Phase (A): 2mM Ammonium acetate in OmniSolv Water
Mobile Phase (B): HPLC grade Methanol
Time
%A %8
-
0.0
70
30
|
6.0
10
90
|=
10.0
10.0
10
90
STOP
STOP
I
Post Time = 4 min.
Total run time = 14 min.
5
Flow Rate:
Injected Volume:
05.p3LmL/min
i
-
Page 10f2 Juuy
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}S RtnaTteTument $:9 2000 61346: AP1_ES NegatiC ve modeBLSATR ONEAREE S.TOpage 1 of 3
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Calibration parts |" bine socation samplotene
Mothod cattey update s Update &7 Interval
[ iuDzwumadr omsmmseIoNemmE EemlEom}31 mfRepmalamece nAovpeermamgee 33-3
So Ssowvmad SmmoaNomrRm RRaEdo 1 hRemlase hMeennss 33
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3-3
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C2529
Method C:\HECKEN\1\METHODS\012204
Calibration Table
-- Calib. Data Modified :I Thursd, ay, February 26, 2004 10:08:53 AK
Based on
I beak Area
[comme ee [7 saebrs.. nReeffeerraennccee iWiinnddooww +: 5.00.00000 %min
EE --
~ AReblsl. NNoonn-rxeef.f WWiinnddooww || 05..000000 m3in
|" DPnaccatirailbrCaarleidbrsaetaikosn || mYeesc, fiedpeonrteidfied pesks are recalibrated
Correct All Ret. Times: No. only for identified pesks
_ vOeriiagnitn
[7 esercaatgieoraRceisopnonsseeseings:i
.. Average Retention Time:
TEqounaolted AFvleoraatgiengalAlvercaagleibrNaetwio7n5s%
~ BrinCtoaultibrofatiroencalTiabblreatiaofntserwiRtehcianliabrasceiqounence
|
If tRNhoeersmusaleltqsuReneofcpeorftiisrsatfdtoencreyclRweietcha(lebinrbdaricanktgeitpoirnnegv:ious bracket)
|" sSiigonnaal 210: MmSsDm) 346693,, mFIrCc-e4z6e8..77.1346699..07
~ Rettine vl amoumt Area Amc/Area Ref Grp Name
|
[min] $9, | (ppb) |
|
Joeelo1
- 77238 113 105001.000000000 52..2518259480044 1'.19.198631996%-033 1 C8 Acid
35 25500010000000000 12..368852180605 11..70969449400-33
.
5 1070500110000000000 33..5057741076655 11..58790382400--33
6.109 2 71 150500..000000000 77..i2450515d0e0a 27..00607236660e--34 1 C10 Surrogate
|=
23 1205001.000000000 13 46375669796e55 66..9765594212a0--44
35 57500010000000000 53..050217654600 77..241875743e0-4d
|-
7 11500000.0000000000 11..2765066056666 78..5943128450ea--4
Hore compound-speicci settings:
|" com"pTionuendW:incdsowacta
+ From 7.066 min To 6.067 min
~ Co"mTpiomuendW:inCd1o0w surrogate + From 7.913 min To 6.718 min
TTT
ea sam rane.
| cooara 2/26/08 10:10:50 aw Smiter1 Fite
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620530
| MethodC: \HECHEIN1\METHODS\012204.1
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-
Calibration Curves
oomo y
| eCReoorohtroelr3aa6tsiaotnt:exepi, n#07s.7360585753866
600000
Residual Std. Dev.: 14581.78795
[foo c Rn Stas i
s
a7 iS 55s
3
b: 13835.67745
[fm seg -
jao0o004
4
--
x: Amount(ppb)
--------
-
-Jeon,i
a
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SC10esurrnogatde atiexp.)7: 8.109
i[= | r|1.ei6eEs6-
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7 | cFRoeorsrriemdluaaao:YtlioSynto:d1.5m5Deedvo.:h 535207..9299689078
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|
|
2.00414 2/26/04 10:101:050:50aAnM ssmmitirerle
JO1 Vl
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Sample Name:STD 50 ppb
IB Sample Info:Warm Up Injection
Data file :C:\HPCHEM\I\DATA\Chemstor\12087705\AS21536\FC000001.D
[InATjcneqtcrOtupimeeosnnattoDrate i:| pm1/Ci20l20l/Ae0Lr4 4:38:06 or vsIinegaq.lLiNNneoe.: |
111
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r Last Changed : 2/26/04
10:08:53 am
BN
Ex, LC/MS analysis of perfluorooctanoic acid.
--
HISD 63, E1C-36879. (CHEMSTORORNASITSZSSF0CR0800770] APFES,No,SW,Frag Var
as00 000
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Thu, 26. Feb. 2004 10:12:17 am
Page 1 of 1
"2532
Sample Name:sTD 50 ppb
2
I Sample Info:
Data ile :C:\APCHEN\I\DNTA\Chomstor\12080405\AS893760FC000002.0
|| ~
DhT1ierniadjweecorciotpmoieenornntaptaotre":i:| T1JS/em2vi2ot/ie0nr4s
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Le/MS analysis of perfluorooctanoic acid.
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------re-- --
-
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|| rconura
Thu, 26. Feb. 2008 10:09:41 am 0019 Page 1 of 1
nos5aa
[Sar mple E ane:s7D 100 ppb
2
Data file C:\HRCHE\1\DATA\Chemstor\12080464\AS91609\FC000003
[TM
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5:09:09 PM wmTSeaqoteLvienee :
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Lo/MS analysis of perfluorosctanoic acid.
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7.246 -C8.
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Thu, 26. Feb. 2000 10:13:00 an 0020 Page 1 ot 1
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[Ssairpele HRanEe:5TD 250 ppb
:
Data file C:\HCHEN\1\DATA\Chemstor\12080548\AS93584\C000004.D
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Tos, 25. Fob. 304 10s om
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[ Ssaemepbliee Nmaimee::STD 500 ppb Data file :C:\HECHEU\I\DATA\Chemstor\12080667\AS962241EC000005..D
[ AITcnnqjgeoocrptuiemoernnattoDrate :|| 1sJ/cm2oi2oi/al0ie4sr 5:40:19 PX VnSeiyqneLei.nre :
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16/M8 analysis of perfluorooctancic acid.
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| Compound Name
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T-
Area
77003866306..635
I Amount sSialsoss
| Heas. Re:t. T C Signal Descm 7a.l2l3e2s MsSDI1 316633,, BEXiccoedaeeha.7i3d6e9s..7)
#++ End of Report **+
TT
Dave
ss roam sosiiom ulz2 rots onman6
[Sa= mple Name:STD 750 ppb
:
Data file :C:\HECHEM\1\DATA\Chemstor\12088166\A532672\7C000006.D
Fs erie | [I" Inajceqcotpieornatobrate: 1j/m2i2l/l0e8r 5:55:53 BM SvieaqlLiNon.e : s&
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--
TeTT CENSOR GSA COROOR] APogESWFSr
|
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[conse ha, 26. eb. 2008 10:15:15 am 0023 rage 1 ot 1 Cn0O537
__ sSaammppllee NIanmoe::STD 1000 ppb
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Data file :C:\HECHEM\I\DATA\Chemstor\ 12080375\AG02816\C000008.D
c= 1 [ AIScnnqjdeeOcrtupimeoernnattDeaste :|i 1sJ/mc2io2io/li0es4r 6:27:05BM SvIenqagLniNeneel :
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C2540
[seSammiplse Niaeme::11668-22
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Data file :C:\HPCHEN\1\DNTA\Chemstor\12068763\A541184\FC000010.D
I ATIncnsqjteeOcoptmieeornnattoD r a:|| 1t mP/Ci20l20e l/4e01r44 6:5e8M :0SvI7einqaj.lLNNioon..e :i
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sample Name:11668-23
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|
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Data file :C:\HICHEN\I\DATA\Chemstor\
12088932\AS43360\FCO00011.
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hu, 26. Feb. 2008 10:20:18 am 0031 rage 1 of 1
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Thu, 26. Feb. 2004 10:25:47 am
0033 Page 1 of 1
C0057
Sample Name:11665-8
1
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Data file :C:\HPCHEM\I\DATA\Chemstor\12089968\AS56032\FC0000107
hITnonjagetcortpiiemoernnactoDrate |:|:: mS1oi/olo2la2eirs/04 8:47:16 BM SVeIniqga.LiNvnaol.e i
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Thu, 26. Feb. 2004 10:26:36 am u034 Page 1 of 1
Cnn518
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Thu, 26. Feb. 2004 10:27:58 am
Page 1 of 1 10519
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Data file. :c:\HPCHEN\1\DATA\Chamstor\12080656\AS64608\EC0000201
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Thu, 26. Feb. 2004 10:30:23 am uu38 Page 1 of 1
cnha5s2
[sSaimpele Nmamoe::L1668-13
1
Data file :C:\HPCHEM\I\DATA\Chemstor\12090837\AS66720\FC000022.D
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Thu, 26. Feb. 2004 10:31:13 am u039 Page 1 of 1
N2553
Sample Nane:L1668-14
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Data file :C:\HPCHEN\L\D12N09T10A32\\ACSGh8Te04m\RsCAt00o02r3.\D
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Thu, 26. Feb. 2000 10:31:46 am
sage 1 of 1
C554
[+ Ssaammpeltee Nzaomoe::L1668-16
Data file :C:\HPCHEN\1\DATA\Chemstor\12091175\AS71008\FC0000.24D
I ------ ~~ InjectionDate : 1/22/04 10:36:21 BM SeqLime :
24
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I Last Changed _: 2/26/04
10:08:53 am re ------------ I
Le/ms analysis of perfluorooctanoic acid.
--- I WETS68EG-3E873687 CHENSTTTTSOUSTRCGTRFGE00S002SB)PLESNg SW. Frag Var
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*** End of Report ***
-
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Thu, 26. Feb. 2004 10:39:50 am uuPage 1 of 1 C0559
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Thu, 26. Feb. 2004
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Page 1 of 1
CNN560
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Data file :C:\HPCHEM\I\DATA\Chemstor\12062179\A650816\FC000030.D
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Sample Name:STD 100 pob
2
I sample Info:
Data file :C:\HPCHEN\1\DATA\Chemstor\12082231\A652600\FC0000.31D
[| " AIcnqjeocptieornatoDrate Instrument
:: j1m/i2l3/l0e4r 12:25:16 AM i PCO04L
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{I+ [HDT 10-38873607 (CHEWSTOR R20a822S3 EBIOO00F B)~APIES,Nerg.enSWEFitgVar
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++ End of Report *++
or
| ecooa1a
Thu, 26. Feb. 2004
u048
10:42:43 am
Page 1 of 1
CNN562
Sample Kame:ST> 250 po
\
I Sample Info:
Data File sC:\HPCHSN\I\DATA\Chemstor\12082266\AGS4846\FCO0002>.
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Data file :C:\HPCHEN\I\DATA\Chemstor\12052091\AS92256\FC000034 0
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Thu, 26. Feb. 2008 10:45:45 am
0051 Page 1of 1
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499924.22
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*** End of Report
|i ecooats
Thu, 26. Feb. 2004
10:46:12 am
0052
Page 1 of 1
C2566
[sSeammplee Ntanmte:STD 1500 ppb
Data file :C:\HECHEN\1\DATA\Chemstor\12087617\A519552\FC000036.D
[req menos + reson I AIcnqjeOctpieornatDoarte :: 1j/m2i3ll/e0r4 1:43:15AK SveiqalLiNnoe. :
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78..213098
SSDDLI 346695,, EEIICC--346688..77::346699..77
"ev End of Report cer
| scanase
0053
ha, 26. seb. 2008 10:46:54 am
rage 108 1
C0567
:E
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en. 3058 Research Drive
State College, PA 16801 RESEARCH
Phone: 814-272-1039
Fax: 814-231-1580
PrPrEeoEpcet :Storage: | SCoobmmpiatneydNBay:me:
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ReportVersionP:aDgeoc22l242003 10:44AM
Instance:
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| "ooo1ess-0007 I ConCsontaoimneerr1NONE
L0001668-0008 [ 0C2ont1ai8neetr81NO7NE
[7 L00016c68o-r00e09
Co026e7t8N7ONTE | "Looo1ess-0010 [+ cCoonmtaienerrs
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ReportVersion: Dec 222003u10l:4b4A6M Page 3014
Instance:
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[7 co026cTo7m5aoniverrNONE
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