Document nmow1nj4kqBKwbeY1kokn8X8R

c MONITORING OF PCB'S IN FISH tAKEN FROM THE HUDSON RIVER October 1975 DSIfiS 028875 c V- NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION STLCOPCB4012837 t MONITORING OF PCB 'S IN FISH TAKEN FROM THE HUDSON RIVER ' . by Bureau of Environmental Protection Division of Fish and Wildlife OCTOBER 1975 f.TTqfrr DSW 028876 "MP STLCOPCB4012838 ( i (. . MONITORING OF TOR'S IN FISll TAKEN FROM THE HUDSON RIVER by Bureau of Environmental Protection Division of Fish and Wildlife IT ' c V^VIFW Vff OCTOBER 1975 DSW 02887? STLCOPCB4012839 TABLE OF CONTENTS SECTION ' PAGE I Background and Purpose....................................................................... i..................1 II Sample Collection.......................................................................... 3 A. Procedures........ ............................................................................ .. 3 B. Sample Identification and Routing...................................................3 C. Surveys Conducted.......................................................................................... 5 D. Data Quality Assurance.................... 6 III Results Obtained From Monitoring Surveys......................................................7 IV Conclus ions......................................................................................................................12 APPENDIXES A General Reference Material B Results of PCB Analyses ` 1. 1975 Results 2, Prior 1975 Results C Sampling Instructions to Regions D Analytical Techniques and Original Laboratory Results E Regional Reports on Sampling F Data Quality Assurance ( t SW 028678 STLCOPCB4012840 Monitoring of PCB's in Fish Taken From the Hudson River by Bureau of Environmental Protection Division of Fish and Wildlife I. Background and Purpose The Division of Fish and Wildlife initiated analyses of fish flesh for DDT'in the early 1960's. This work was con ducted in response to data suggesting that the chlorinated hydrocarbons may adversely affect fish and wildlife resources by interferring with reproduction. Results of this investigation led to state restrictions on use of DDT in 1972. During this time period, definitive research indicated that DDT analyses could be contaminated with a similar compound, polychlorinated biphenyl. In order to preclude any error in future work, both DDT and PCB's were extracted and analyzed thereby giving separate values. Therefore, from 1970 to August 1975 PCB's were evaluated in all fish flesh analyses as a peripheral activity to DDT sampling. The recent disclosure of high PCB levels in fish detected by EPA's field sampling surveys has precipitated a shift in the Department's monitoring scheme leading to the present statewide activities. Prior to any long term definitive monitoring programs, several meetings were held both intra-Department (Fish and Wildlife, Pure Waters, Solid Waste) and inter agency (New York State Department of Environmental Conservation, New York State Department of Health, New York State Department of Agriculture and Markets, Environmental Protection Agency, Food and Drug Administration, New Jersey Department of Health and Vermont Department of Health) to define the proper . objectives and activities, define techniques for sampling and ' QSW 028879 ywmywm*-- \ rr STLCOPCB4012841 -2- analysis and shore existing data. A subsequent (9/11/75) meeting with external agencies further discussed the implementation of the findings to date. The statewide sampling program, as developed in the meeting of August 1975, included stations in most large waterways where PCB contamination could occur and, if possible, where earlier samples had been taken. In addition, several Adirondack streams were included so as to ascertain general .ambient conditions. Appendix A indicates the waterways and stations sampled. A review of this material will show a higher incidence of stations in the Hudson River as compared to other waterways. This is due to the inordinately high concentrations of the contaminant in fish from this location and therefore a need to sample intensively. The objectives -for this program were to: (1) determine the level and extent of PCB contamination in the fish inhabiting or migrating through a waterway (2) isolate, by means of sampling, portions of waterways so as to subjectively identify polluted reaches. The data generated was tabulated and submitted to both the Division of Pure Waters and the Deputy Commissioner for Programs and Development. In this manner, the analytical data would be available for inter program use. Appendix B_ contains this information as well as historical data. DSW 028880 STLCOPCB4012842 -3- II. Sample Collection (Hudson River) A. Procedures ' A statewide schedule for sampling was developed on August 19, 1975 which included the Hudson River. The regional staff were instructed as to the specific species and sizes of the fish, general location of the stations and deadline for collections (Appendix C). In addition, specific instructions were supplied relative to preserving and handling all species collected. All materials were subsequently transported to Albany or Rome for Storage. From those locations specific samples were delivered to the laboratories conducting analyses. Analytical techniques used by each laboratory were reviewed in a meeting held on 8/19/75. At this time, chemists representing New York State Department of Environ mental Conservation, New York State Department of Health, New York State Department of Agriculture and Markets, Environmental Protection Agency and Food and Drug Administration had the opportunity to comment on methods and suggest alterations where needed. The information desired from this ' gathering was utilized in developing the present analysis techniques and reporting system. Specific methods are appended (Appendix D). B. Sample Identification and Routing As collections were completed, at specific stations, regional staff contacted the Bureau of Environmental . Protection (BEP) of the Division of Fish and Wildlife to indicate species, numbers and projected arrival time at a * designated storage site. Individual fish were jaw tagged T*"1'v"*7`vwr* ^*irwn*,n`/w* >.tti w DSW 028881 ^~yln,rn in-rmiur i t-mur >r_1. ^ STLCOPCB4012843 -4 and placed in plastic bags (polyethylene) for shipment. A collection sheet and transfer document (continuity of evidence*) vas included with the sample and a copy forwarded directly from the region to the Bureau office. All fish collected for PCB analysis, except in certain instances, were tagged by monel jaw tags upon capture. Each tag contains an individual number which became unique to the fish upon which it was placed. The Bureau of Environmental Protection coordinated compositing of fish samples and distribution of the fish samples to the participating laboratories. For fish being distributed to Department of Ilealth or Department of Agriculture and Markets Laboratories, a sample identification, called the "Albany Ident.", was assigned for ( sample tracking purposes. The coding is as follows for all but one stations: ' ` 1 - The first one or two numerals represent the sample station number as given in Appendix A. 2 . - The alphabetic designation indicates class of fish, i.e. P *= predator species F *= forage species R = recreational species C ** commercial 6pccies 3.- The last numeral indicates the size grouping of the sample as follows: . 1 " small 2 * medium 3 large c J or 4 *= Jumbo ' ' # * Continuity of evidence forms provided for second round of sampling only. f ti in ,if I'H IKTT-F S DSW 028882 t v"w i ui cr STLCOPCB4012844 -5- The individual laboratory doing the analysis was permitted to assign its own laboratory identification ("Lab. Ident.") which accompanied their report of PCB analyses results. C. Surveys Conducted 1. DDT program samples of various species were collected from the Hudson River for DDT analysis (PCB's also run) 7/70, 9/72, 4/73, and 5/75. These fish were taken at several locations during each collection period and forwarded to the Rome Laboratory for analysis. This data is presented in AppendLx B-2. ' 2. PCB Program (8/75)- The program development on 8/75 located 12 sampling stations in the Hudson River (above Corinth, above Glens Falls, Fort Edward-below General Electric facilities, 5 miles below Fort Edward, Stillwater, Hoosick, Waterford, Coxsackie, Roeliff-Jansen Kill, Mainstem at Wappingers Creek, Mainstem at Esopus Creek, Mainstem at Rondout Creek), Samples collected were processed according to the instructions forwarded (Appendix C) and delivered to a storage facility. 3. PCB Fxe-survey of Upper Hudson - In order to reaffirm the data collected and arrive at a more supportable con- elusion, several stations were re-sampled during September and October 1975. These included: A. Fort Edward below Genernl Electric facilities B. Five miles below Fort Edward . DSW 028883 fi*W> o `it?* STLCOPCB4012845 6- Furthermore, two additional stations were selected and sampled in the Upper Hudson: . A. Champlain Canal (Lock 8) B. Stillwater This data is summarized in Appendix B-l. 4. Miscellaneous Samples - In those cases where specific species collected earlier indicated unique trends, an attempt was made to re-collect specific species so as to broaden the sample base. This was the case for striped bass aiid shad in the lower Hudson. In both instances, fish were collected by either Department of Environmental Conservation staff or the public and submitted for analysis. All materials collected were identified and transported to a storage station therein awaiting analysis by one of the three participating laboratories. Reports on the techniques, location and other.specifics relating to each regions activities on fish sampling are included (Appendix E). These discussions reflect the implementation of the sampling instructions prepared by the Bureau of Environmental Protection. The reports reflect collections of fish for the period thru October 15, 1975. D. PCB Data Quality Assurance New York State Department of Environmental Conservation and Not York State Department of Health, in cooperation with United States Environmental Protection Agency Region 2, . established a data quality assurance program for PCB analyses in water, sediment and fish flesh .to determine the com t parability of methodologies and techniques used for sampling DSW 028884 STLCOPCB4012846 -7- and analyses by various state and federal laboratories. The Division of Pure Waters, Bureau of Monitoring and Surveillance, was assigned primary responsibility for this effort. Mr. James Daly, New York State Department of Health Environmental Health Center, Quality Control'Officer and Mr. Gerard McKenna, United States Environmental Protection Agency Quality . Assurance Coordinator were principal operatives in this effort for their respective agencies. (Appendix F, Tables 1-4) III. Results Obtained from Monitoring Surveys . All information regarding the fish flesh sampling stations addressed by this Division's monitoring surveys described herein, is summarized in Appendix B of this report. Lab oratory analytical procedures and quality assurance efforts are described in the report and testimony of Mr. James Daly, ' Quality Control Officer, New York State Department of Health, Environmental Health Labs. All analytical results reported herein were obtained from the following laboratories as noted; . A. N.Y.S.D.E.C. Rome Laboratory B. N.Y.S.D.1I. Griffin Laboratory C. N.Y.S.D.A.M. Food Laboratory (Albany) Several lower Hudson fish flesh samples are still in the process of analyses and will be incorporated into this report when available. . Reference material in the form of maps, graphs and tabulations arc also provided in the Appendix A as an aid in , understanding the geographic' and physical setting of the Upper Hudson River system. DSW Q28885 STLCOPCB4012847 -8- The following paragraphs reflect a summary of the data collected and submitted in Appendix B-l. Discussion is generally oriented by station commencing with Corinth and progressing south. Station 1 Corinth - PCB's were found at trace levels in all species analyzed. (Appendix B-l, Table 1) Station 2 Above Glens Falls - PCB's were found at trace levels in all species analyzed. (Appendix B-l, Table 2) Station 3 At Fort Edward in the area of Rogers Island - PCB levels in all species analyzed were very high, in all instances exceeding 5ppm. Species included walleye, yellow perch, rock bass. ( white sucker and alewife. (Appendix B-l, Tables 306) ' Station 4 Five miles below Fort Edward - PCB levels in all species analyzed were very high, in all instances exceeding 5 ppm. Species of fish- analyzed include smallmouth bass, walleye, yellow perch, white sucker and brown bullhead. (Appendix B-l, Tables 7-9) ` Station 4A Stillwater, above Locks - Station was added in second round of fish sampling. PCB levels in all fish analyzed were very high. In all instances, analyses of tissues indicated that levels exceeded 5 ppra. A single individual (cel, f <?4J2975) had a total PCB level of 559.25. Species of fish analyzed include lavgemouth bass, American D5W 028886 STLCOPCB4012848 -9- eel, brown bullhead and white sucker. (Appendix B-l, Table 10) . Station 5 Waterford, below Lock 1.- This station reflects some influence of the Mohawk River as well as the Hudson River. Therefore, the data from this -* station must be interpreted with the realization that an additional external parameter has been included. (Appendix B 1, Table 11). PCB levels in all fish analyzed were high, in all instances exceeding 5 ppm. Species of fish analyzed include Bmallmouth bass, walleye and x*hite sucker. Station 5A Mouth of Roeliff-Jansen Kill - Station was added in second round of fish sampling. Primary emphasis was placed on collection of striped bass. Analysis is in process, however, first results indicate high levels of PCB's (Appendix B-l, Tables 22 and 23, Station 6 Catskill, mouth of Tributary 193 - Original station was indicated at Coxsackie, however, station was relocated. Only analysis for Aroclor 1242/1016 was conducted; In almost *i * all cases, Aroclor 1242/1016 levels were high, the exception being a composite of two yellow porch which yielded a total of 4.18 ppra. of PCB's (Appendix B-l, Table 12) Station 7 This station iYicludes collections from seven (Mainstcra at Rondout Creek, Wappingcrs Creek, Esopus Creek, lCingston-Rhinccliff Bridge, Toppan DSW 02888? STLCOPCB4012849 -10- Zee Bridge, West Point and George Washington Bridge) locations taken over a period of time. Analysis was conducted on a variety of recreational, commercial and forage fish species. In most instances, total FCB concentrations exceed Food and Drug actionable levels but concentrations vary depending on species and location. (Appendix B-l, Tables 13 thru 17 and 23 thru 25. Station 8 Rondout Creek at Bloomington - This station is above the tidal effects of the Hudson River. Aroclor 1254 was found at low concentrations \ in addition Aroclor 1242/1016 was absent. A slight decrease from 1970 PCB levels is noted for largemouth bass. (Appendix B-l, Table 21 and Appendix B-2, Table 2) Station 9 Mohawk River, below Schenectady - Some PCB contamination is present in all species tested. However, the levels were generally well below Food and Drug actionable levels. Species sampled include.smallmouth bass, largemouth bass, blueback herring, white sucker, and black crappie. (Appendix B-l, Table 19) . Station 10 Mohawk River, above dam at Little Falls - A source of l'CB contamination is indicated above this station. Most fish at this station had rcB levels that exceeded the Food and Drug actionable level. (Appendix B-l, Table 20) *. , ',k ' '4 .' - " '. I" . V V' ' ** ' BTtUiym,1 * DSW 028888 STLCOPCB4012850 -11- Station 32 Ualloomsnc and lloosic Rivers. These rivers vere sampled since an electronics plant operates in the watershed within Vermont. Fish analyzed indicate levels of PCB's approaching or 6omewhat exceeding Food and Drug actionable levels in all cases. (Appendix B-l, Table 18) Station 32A Champlain Canal (Lock 8) - Fish were sampled in the lock with the use of rotenone. Analysis indicate that levels of PCB's are generally below 5 ppm except for a single rock bass ' (6R7314) at 12.18 ppm. It is possible that this fish is a migrant from the Hudson River. (Appendix B-l, Table 26) Station 34B Champlain Feeder Canal. Wildlife samples were taken'to address any movement of PCB's from fish to wildlife. The species submitted include muskrat, a vegetarian and raccoon, On omnivore. Tissues of these animals reflect trace levels, however, the sample is obviously poor. Additional analyses are being conducted. (Appendix B-l, Table 27) QSW 028889 STLCOPCB4012851 -12- IV. Conclusion c 1. The data derived from the fish flesh analyses clearly indicates that specific waterways or portions of waterways contain levels of PCB's above the level recommended as "actionable" by'the Federal. Food and Drug Administration. One such waterway is the Hudson River at and below the Fort Edward Station. An examination of the existing data (Appendix B) will show that total PCB levels substantially exceed the Food and Drug Administration's recommended standard and levels found in similar species sampled from other watersheds. 2. A comparison of the data derived from fish analyses of species taken from the Hudson River at various stations indicates a notable difference in PCB concentration. The two uppermost stations on the River (Corinth and Glens Falls) indicate only trace concentrations of PCB's as 0 aroclor 1242/1016 and trace aroclor 1254. However, lower stations (Fort Edward, five miles below Fort Edward and Stillwater) indicate very high levels of the contaminant in all species sampled. This difference between two stations, above Glens Falls and below Fort Edward, indicates that PCB's 'are entering the aquatic environment between the stations and that fish, a "sink" for PCB's, are accumulating high levels of the contaminant. C DSW 028890 `WMWl1 'b*)irgw STLCOPCB4012852 c APPENDIX A Hap of Stations ( C. . QSW 028891 -ernttm mm ii^ w>| >grrr yw*/vrrj*r>\ttryn*v v9"tvtm STLCOPCB4012853 appendix Sampling Station Locations From Which Fish Were Analyzed Station No. I 2 3 4 4A 5 5A 6. 7 8 9 10 32 34A 34B Watershed Upper Hudson River Lower Hudson River Mohawk River Upper Hudson River Upper Hudson River Waterway Hudson River ^. ` Rond'out Creek Mohawk River Walloomsac River & Hoosic River Champlain Canal Champlain Feeder Canal Location Region Above Corinth 5S Above Clens Falls 5S At Fort Edward- 5S in Rogers Island area 5 miles below Fort Edward 5S Stillwater Waterford-below Lock 1 5S 5S Vicinity of Rocliff- 4 Jansen hill Coxsackie-Catskill, mouth 4 of Tributary 193 Lower Hudson '3 a) Mouth of Rondout Creek b) Mouth of Wappingers Falls c) Mouth of Esopus Creek d) Kingston-Rhinecliff Bridge e) Tappan Zee Bridge f) West Point g) George Washington Bridge area h) Highland-Poughkeepsie area Bloomington 3 Below Schenectady 4 Little Falls 6 Hoosick 4 Above Johnsonville 4 Lock 8 5S Above Hudson Falls Landfill 5S OSM 028892 STLCOPCB4012854 STATION 1 I>. KOLUMClvORTH AMD VOTE CO. (EaSTOM ILU . !CVTlf*YU.U 1TR it. jmiAua vc in1 JO. HftjtTDGA BOlsD Mint <F0*CKIY *>CUYaC0) n HICHAKICVILIC ITR jx vAUMtc rarc* co. n (UFRftoaTnOoCitaoCj OUNTY 10. *o. t 14. CtKCftAl fUCTMC At irAUftr&ffa ft. f *f G. At <*ATCftFO0 ft. con*tu rarck <a . IAOCK CITY #Alll) V. Oa(,1110n VA ITR Jt. IARaTOwA IRftlNGlU# It. ROUND t A*f VTf ft tffOCK AMOM3U1 UR >1. COUNTRY AhOLU 4CWIH 4RAOROUD URi ft COUNTRY KNOU.lAtU 1R JX COOH1RY F.NOt11 UR U. countny KKOiLt Aim.ii ur ft. CAHlfVOOfll (RflOfWO) STATIONS 34A and 34B STATION 3 STATION 4 t HAout vo mo. i lI. u>.x: lt tuiif.>a< aft mrxOrttMciot.tl AT CCRWtH 4. COCIMTH VC- TP v w. clems r*m srp v r*t*io< pape* CO. AT OLE MS FALLS >. fimck p*'-iTM paPc* CO. AT CLEMS FALLS .. CULMS PALLS IIP *. HU040U HIVE* 01G COD (P80P01E0I w. hekcuus roves* co. ' II. HUOSCW PAU.1 U GEKERU. ELECTRIC AT K;DS<X FAi.LV PT. EDVARD li icon PAPE* ca. at pt. to*o li ET. EOAAO VC. U. COUCLL PAPTB (FT. UULU PULP AND PAPE* CO) IL HUDSON PULP AND PAPE* COOP. AT FT. AtLLE* STATION WASHINGTON CO. ' RENSSELAER CO. COMOEt! vy -Jr BATEPVL't T ' l if--- STUDY AREA (11-01) UPPER HUDSON RIVER BASIN .scale: miles OSW 028893 STLCOPCB4012855 /*"V 10 DSW 0 2 8 8 9 4 DSW 0 2 8 8 9 5 . LEGEND' E5 r*wtcrj eowvtrt# A. >*9JtCTJ lOt* COWTRVCTTOn rmictt ftwrn* , iwTi o' *nmt REGION 3 t .4 STATIONS 7(a) and | 7(d) OVTCttCSS STATION 7(e) 20 REGION 2 NEW YORK CITY .\ ' Scale In MlJtt DSW 028896 STLCOPCB4012858 APPENDIX B Results of Polychlorinated Biphenyl Analysis 02889? DSW STLCOPCB4012859 Appendix B Results of Polychlorinated biphenyl analysis of fish flesh in the Hudson River and its tributaries The results attached incorporated all the data currently available relating to species, collection dates, identification, lengths, weights, PCB concentrations, DDT concentrations, oil content and any other remarks. All values for lengths and weights have been converted to decimal form by the Albany office of the Bureau of Environmental Protection. The lengths and weights reported for fish analyzed by the Departments of Health and Agriculture and Markets are those reported by the regional personnel collecting the fish and converted to decimal form. The lengths and weights reported for fish analyzed by the Rome Pollution Laboratory are those reported by the laboratory. The laboratory measurements do not necessarily correspond with the measurements of length and weight obtained by regional personnel collecting the fish. This is generally caused by shrinkage due to freezing. These measurements were reported so that some consistency of reporting could be maintained. OSW 028898 V STLCOPCB4012860 8(u VI r- 4. O' . ,, ; * i .` . ' . *` osw 028899 STLCOPCB4012861 Seed e* Date Collected Saallmcuth bass 8/20/75 (Xicrooccrus 8/21/75 dolr'eui Vhite sucker (Catosto-rus cr.m-.er soni > Yellow perch (Rerca (lave- scent) 8/20/75 8/21/75 8/20/75 8/21/75 Date Analysis Reported S/2/75 Location Above Corinth 9/2/(75 ,* 9/2/75 Above Corinth Above Corinth Hudson River PCS Analysis Results (Analysis by Rome Pollution Laboratory) Lob. Albany Tdcnt. Ident. 5s HudCoap 5 Tag Length Veight So. (Inches') (Pounds^ 9.1 9.2 PPM as A roc lor 1242//016 PPM as Aroclor 1254 Trace Total PC3's PPX DOT/ PC3 Trace X on Remarks Compos its of 2 5 s Hud Coop 4 5s Hud Coap 1 5s Hud Comp 3 5 s Hud Comp 6 5s Hud Comp 2 5s Hud 17 5a Hud 18 . 5s Hud Coap 7 . 11.0 11.4 11.0 11.0 10.6 6.7 7.1 7.3 7.5 7.7 10.0 10.0 10.0 10.6 14.6 18.5 67 6.9 7.1 7.1 7.1 1.47 3.02 0.14 0.14 > 0 0 Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Composite of 2 Composite of 3 Composite of 3 Composite Of 2 ' Composite of 4 Trace Trace Trace Trace Trace ` - Composite of 5 DSW 028900 rymjnyi 7j 1Jft STLCOPCB4012862 i 'W/ ?rrc 5 c s Sate Cc! Srl Inovch bass 7/24-25/75 (Vi< r' -tv?*:* Vjlley* (ftiro-tedlen vj t Tellov perch C?-rc.i f lavorcc-ns) 7/24-25/75 7/24-25/75 '* White sucker (Catesto-ius cccrretsor.i) * . 7/24-23/75 Djte Analysis ?f 2Tr ; c<i Location Hudson River PCB Analysis Results (Analysis by Rook* Pollution Laboratory) Lab. Albany T^ent. 7<Vnt. Tos Length Weight ?'o. (Incbcsl fPounds} PPX as Aroclor 1242//015 ?7X as Aroclor 1254 Total pea's TABLE 2 PPM DDT/ dtp t .. Oil RcrutrVs 8/11/75 Above Ciena Falls :u<5-73-vp 4-Hud-75-up 5-1Iu<i-75-up 6-IIud-75-up 8-Hu^-75"up 9-!Iud-75-up 7-Hud-75~up 10-Ilud-75-up ll-:!ud-75-up 12-Hud-75-up 11.0 10.5 9.4 9.4 . 9.0 . 8.7 8.3 7.5 6.7 ' 6.3 0.54 o 0.46 0 0.35 0 0.31 0 0.30-------~__.o 0.21 . 0.26 0.16 o 0.13. ^ 0.10'^ Trace Trace Trace Trace Trace Trace * Trace Trace Trace Trace Trace 1 Trace Composite of 3 Composite of 3 * 8/11/73 .8/11/75 Above Glens Foils Above Glens Falls , 8/13/73 9/2/75 Above .. Glen* Falls Above Glens Falls 2-Hud-75-up l-Hud-75--up 16-Hud-75-up 13-Hud-75-up 13-Kud-75-up i7-Hud-75-u? 14-llud-75-up 26-ltucI-75"'Up 19-lIud-75-up 21-ilud-75-up 22-Hud-75-up 18-Kud-75-up ' ' ' 41-Hud-75-up * ' *. 42-Hud-75-up . 15.4 15.0 11.8 11.4 ' 11.0 10.6 10.6 10.2 9.8 . 9.3 ` 9.0 7.9 * _' 1.03 1.05 0 0 0.73 0.67 0.57 . 0.60 ,0.55 0.61 0.55 0.45 0.42 0.63 . 0 0 0 0 0. 0 0 0 0 0 0 0 Trace . Trace .* Trace Trace Trace Trace '' Trace Trace Trace ' ` Trace Trace Trace Trace Trace Trace Trace . Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace * * OSW 028901 fU? J|M a%ni 19*+mm,.' * mwH W'1'n.jfij* ,l."" j iwii,"i,^ jyj, .i > STLCOPCB4012863 ~.ocl; bass (A-Montites Dote Collected 7/24-25/75 Ale-.-ife 7/24-25/75 c seudoha rencas) Date Analysis Roo-ortcd 8/13/75 ' . Location Hudson River PCB Analysis Results (Analysis by Rook Pollution Laboratory) Lob. Albany Tdcnt. TdrnC. Tag Length Weight No. (Inches! (Pounds^ PPM as Aroclor 1262//016 PPM as Aroclor Total 1256________ PCB's TA3LE <J P?K DTT/ CC3 Oil Rc~ar'ic5 Port Edward 56 Hud-75-DR below C.E. 57 Hud-75-DN 27.35 * Composite of 2 8/13/73 Port Edward 55 Hud-75-DK below C.E. 20.35 * 1 } V i ? V I > \ i \ * Standard sample not run for this PCB therefore quantification-not possible and total PCB's can not to calculated. 0SW 0*8902 *' V I ifi \ [ ft i \ [ l i t STLCOPCB4012864 \j fleeter Cote Collected Vslleye (Siizor tedion vltriTs) ' 9/18/75 t \ - ' ` jt fellow perch (Pc-rca flavesccns) 9/18/75 . * >V Hudson River ?CB Analysis Results (Analysis by Rome Pollution laboratory) Dote Analysis Resorted ' Location Lob. Albany Tder.t; ' TdenC. Tog Length Weight Mo. llnches) (Founds^ P?X as Aroclor 1242//016 10/1/75 At Fort 4-Hud- Edward RI-Coop below C.E. 3-HudS.I-Conp 6R8286 6RS2S5 6R8288 6P.8289 6R8283 6R8284 6S82SO 6R8275 6R8282 6RS278 6RS276 6R3279 6R3277 6R8281 6.4 6.6 6.7 6.8 6.9 7.2 7.1 7.2 7.5 7.6 7.8 . 7.8 8.0 8.3 0.12------ --t-104.2V 0.12 0.12 . 0.12 / 0.16 / o.ur 0.16 0.16 ------,81.12 0.19 0.19 0.19 / 0.19 / . 0.22 / 0.22/ 5-HudRl-Comp 6R8291 6RS293 6R8292 6RS290 10.7 11.3 11.3 11.7 0.47-----0.53 0,56 / 0.66' r 9.88 10/1/75 ,1 # AC Fore 6-Hud- Edward Rl-Comp below C.2. ' 6R675 6.8 6R8298 6.8 6R8299 . 6.8 6R682 6.9 6R678 7.1 6RS295 7.2 6RS297 7.4 6R6S8 7.4 6RS296 7.7 6R8294 7.8 0.16------ ------7 61.10 0.19 0.19 0.22 0.22 0.19 j 0.22 / 0,22 0.22 / 0.25' TABLE 4 PPM as Aroclor 1256 28.29 Total PCB* s j>nv DDT/ DCS 232.50 2.81 7. .. Oil 4.25 Composite of 6 whole fish * 41.80 122.92 *7.05 5.52 Composite of 3 whole fish . <4 8.31 18.19 0.96 * 1.80 Composite of 4 fish fillets' 18.24 79.34 2.20 1,57 Composite of 10 ,* OSW 028903 I ( i f t i I c1l tfl i [ i r f f f j **r Dutc Hudson River ?CB Analysis Results (Analysis by Rosce Pollution Laboratory) PPM as ??H as TABLE 5 ?7M * STLCOPCB4012866 Species Bats Collected Vhite sucker . (Cieosrocus tomerjeni) 9/18/75 Cate Analysis Reported 9/30/75 Hudson Elver PCS Analysis Results (Analysis by Some Pollution Laboratory) TA3LE 6 Location Lab. Tdcnt. Albany IdenC. Tag Length Weight ^Jo. (Inches') fPourd*^ PPX as Aroclor 1242//016 PPM as Aroclor 1254 Total PCR's P?M 3^37/ r~* L on At Port Edward 1 HudRl-Conp 6R8265 6R8267 6RS266 6R8268 2 HudRl-Coap ' ' . . 6R8274 6R8269 6R8272 6R8271 6R8273 11.6---13.1 13.2 14.2 ^-82.88" 48.57 131.45 5.64 Composite 0( 4 O SC o (V 00 yO O U1 oo GU um.w* y. mi yryir M,ry 7" / CO STLCOPCB4012867 Date (see) rs_________ ' Col lee ted ir-llr.outh base 7/28-29/75 (Ml; rotten:3 da U--i -_-ut Vaileye (Sri sos t'edton yierc--) 7/2S-29/75 V>.lie sucker (C.c test emus cor.nersonl) 7/28-29/75 7/28-29/75 Date Analysis Reported Location Hudson River ?C8 Analysi s Results (Analysis by Rome Pollution Laboratory) Lab. Albany Idcnt. Id<*nt. PPM os Tag Length Weight ' A roc lor Vo. (Inches') (Pounds^ 1242/1016 PPM as Aroclor 1254 Total PCR's TAELS 7 J>pw BET/ PCD X, Oil Remarks 8/11/75 5 ml. below 23-Hud-75-DS Fort Edward 11.0 . 0.74 ICO. 27 22.64 122.91 8/11/75 5 mi. below 24-Hud-75-DH Fort Edward 13.4 0.87 157.27 ' 20.74 178.01 8/13/75 9/2/75 5 ml. belov 51-Hud-75-DN . Fort Edvard 48-Hud-75-DH 50-Hud-75-DN . 54-Hud-75-DN 5 ml. below 52-Hud-75-DM Fort Edward 49-Hud-75-DN ! , '. 51.39 47.57 22.05 20.80 29.74 28.03 * * it it 8.86 ^ 8.13 38.60 36.16 DSW 028906 * Standard sample net run for this PCB therefore quantification not poaoibla and total PCB1a can not be calculated. . Spec'|>S Dace Collected tellers perch . 9/17/75 (Perea f l.ayescens) O in x o N) CD vO o Dace Analysis Reported 9/26/75 Hudson River PC3 Analysis Results (Analysis by Rome Pollution Laboratory) TA3L2 8 Location Lab. ' Albany Ident. Idont. Tag Length Veight Ko. finches) /Pounds) 5 dies 1 Hud-Rbelow Port Cotnp-9-13 Edward 6R7S01 6R7802 6R7804 6R7807 6R7 800 6R7803' 6.5 6.5 6.5 6.6 6.7 6.8 PPM at Aroclor 1242//016 84.31 ??K as Aroclor 1256 18.95 Total PCB's PPM DDT/ DCS 103.26 2.37 Oil Rcr.ark* 3.52 Composite of 6 whole fish 2-Hud R 'Comp 9-18 6R7806 6R7805 6R7809 7.5 7.6 7.7 35.54 15.01 50.55 '1.71 3.55 Conposlt* of 3 8 Hud-R Comp-9-18 34.21 122.39 3.90 . 4.52 Composite of 20 ' whole iishj not tagged ' Valleye (5tf .royredlnn vitreun) 9/16/75 .9./17/75 9/29/75 9/29/75 5 dies 6R699 below Fore 6R697 Edward - yrg";' 6R699 6R697 11.5 0.62 7.13 5.70 5.56 10.89 0.35 12.69 0.41 1.14 1.49 STLCOPCB4012869 o 5'ecirs Date Collected Brown bullhead (let ilvrus r.cholor.xs) 9/16/75 White sucker (Catostomus cor-ersoni) 9/16/75 O 40 s: O !\) CD vO o 00 Date Analysis Reported 9/26/75 9/29/75 Hudson River PCB Analysis Results (Analysis by Rose Pollution Laboratory) IA3LS 9 Location 'Lab. Tdenc. Albany Tdenc. Tag Length Weight No. (Inches') fPottnds ??M *s Aroclor 1342//016 ??X as Aroclor Total 1754_______ TCP's ??M DDT/ DCS X, Oil Ko-arks 5 miles below Ft. Edward 3 Hud R Comp 9-18 62665 62687 62.662 10.0 10.0 10.6 0.44 0.66 0.63 73.24 36.38 109.62 4.23 Composite of 3 4 Hud R Comp 9-18 62669 6R698 11.3 11.4 0.73 0.78 33.52 123.32 3.82 Composite of 2 5 niles 7 Hud R below Ft. Comp .9-18 Edvard 62696 62680 6R663 6R677 10.2 10.7 10.9 11.0 0.59 0.53 0.59 . 0;62 12.86 48.89 1.35 1.88 Composite of 4 6 Hud R Comp 9-18 62694 62683 13.0 1.25 13.8 1.38' 78.00 . 23.79 101.79 3.47' 2.92 Composite of 2 5 Kud R Comp 9-18 62691 62661 14.0 14.3 1.44 1.44 37.54 41.10 93.64 2.99 5.31 'Composite of 2 > ** - STLCOPCB4012870 CJ u Pate Col lotted Largtnouth bass 9/17/75 (Micro-.tiTus saInoidcs) 9/17/75 American cel 9/17/75 dr.tuilla lostrata) Srcwn bullhead 9/17/75 (Tctaluru? nbulosus) White sucker (Catostonus 9/17/75 ec.-r-.erscni) 9/17/75 Hate Analysis Reported 10/1/75 10/2/75 10/2/75 10/1/75 Hudson Elver ?C3 Analysis Results (Analysis by Rone Pollution Laboratory) Location Lab. Albany Idont, tdcnC. Stillwater 1 SVH-Coap 2 SVH-Conp 3 SVH- Cotap Stillwater Stillwater . Stillwater 4J2970 4J29S6 4J3000 4J2975 4J2961 Tog Length Weight No. (Inches) f?our.d) 4J2977 4J29S5 4J2972 4J2979 4J2971 4J2965 4J2974 4J2934 4J2958 4J2957 4J2S70 4J2956 4J3000 4J2975 4J2961 12.4 12.9 5.7 5.9 6.0 6.2 3.4 4.2 5.2 5.6 9.6 7.7 17.0 32.0 9.0 PPM as Aroclor 1242//016 24.85 10/2/75Stillwater 5 SWH-Coap 1 10/3/75 Stillwater 4 SWH-Comp 4J2969 4J2954 4J299Q . 4J2983 4J2964 4J2980 7.0 7.2 7.6. 7.8 13.3 15.0 154.28 TABLE 10 PPM as Aroclor Total 1251_______ PCS' 15.97 40.32 9.84 24.15 PPM L3T/ BC3 on Sf-.ir'tJ 7.32 Composite of 2 4.09 Composite of 4 whole fish 6.99 15.98 2.4J- Conposlce of 4 whole fish 4.44 5.98 11.07 155.87 7.99 5.94 16.84 20.89 22.35 559.25 12.65 0.56 0,73 ' 18.68 3.93 5.74 30.04 Very Oilly 3.25 16.23 0.53 1.87 Composite of 4 35.92 190.20 5.69 3.71 Conposita of 2 O00 X o N) 00 vO o vO f. xf - . \: *tp~ STLCOPCB4012871 . ''W *' IV: tv 1f':v vm S^allr^uth bass {Mtc ro?:<*ru5 8/26/75 8/27/75 8/26/75 White aucker (Cajto-ttor-.u* cor-crscr.iV 8/26/75 8/27/75 * Walleye (Stlroscedlon vitreun) 8/26/75 8/27/75 S/26/75 > -< UuUxon lUvv-i />.. ty*ia Rt- (Ann] ysZ *. ;,y I\-pnrrrK'i;r ,->f Aj^ricultur. 1 ta -o K.-jr^vCs) .*:.t!yr if;., -vji. r]__ . jj'r' _ r T A lb/!ny 1^ VyVnf- , Ta;> 9/5/75 Waterford 9/5/75 Waterford 9/5/75 Waterford 9/5/75 Waterford 9/5/75 Waterford 10691 5S (1) 6R1410 6S1437 6R1411 6R1433 6R1436 6R1421 8.7 -- --.1 9.9 10.1 10.1 10.5 10.7 . --... -i 27.0 10692 5S (2) 6R1420 6R1419 6R1418 6R1417 10693 5S (3) 6R1430 6R1424 6R1429 6R1425 6R1426 6R1405 10694 5S (4) 6R1432 6R1438 6R1409 6R1423 6R1431 10695 . 5S <5) 6R1416 6*1415 .2^2 11 14.5 Si.5 ' Ccnpojice of 6 ' ,, OSW 028910 I I f I ! STLCOPCB4012872 -_/ o 'w 'w'' Specie* Bate Co 1 tectod llaauth bass [X'.crcetc rus dole-; Ci:t> 8/1/75 Tiair. pickerel Ziox nle.erl 8/1/75 eilou perch Perea rlavescensl 8/1/75 '* hlt perch Koreee amorlcana) 8/1/75 Date Analysis Keserted 8/11/75 Hudson River PCS Analysis Results (Analysis by Rosie Pollution laboratory) location Lab. Albany Idont. Ident. Cot ski 11 26-Hud-4-75 Trib. 193 Tag Length Vel&ht No. finches! fPoundO 11.4 1.01 . PPM as Aroclor 1242//016 PPM a* Aroclor 1254 Total PCS's 13.76 ' * ' TABLE 12 PPM 07/ X Cil 8/11/75 8/11/75 Catskill 25-Hud-4-75 Trib- 193 Catskill 28-Hud-4-75 Trib. 193 29-Hud-4-75 . 8/11/75 Catskill Trib. 193 27-l(ud-4-75 38-Hud-4-75 39-Hud-4-75 40-Hud-4-75 37-Kud-4-75 36-Kua-4-75 35-Hud-4-75 33-!Iud-4-75 34-Hud-4-75 32-Hud-4-75 30-Hud-4-75 31-Eud-4-75 17.7 7.9 7.5 1.76 8.63 0.24 l-s.-4.18 0.19--'T 10.2 11.0 8.3 7.9 8.7 8.3 7.5 7.1 6.7 6.3 5.9 5.5 0.61 0.34 8.47 * 0.32 ">*30.67 0.32-- 12.23 * n' *# * * * ' Conpos^ite of 2 Cocposite of 3 Composite of 3 Composite of 2 Coaposie* of 3 1 1 i J t ; f i i > i i i> i ? ^Standard sample not run for this PGB therafora quantification not possible and total PCB's can not be calculated; osu 028911 *v" ryiwui ry,.n>.rW q i ipn 111J I STLCOPCB4012873 Species Dote Dste Analysis Collected_ ... Reported Striped bass (Vi; fr*|i s.-x-.t i ins) 8/7/75 9/2/75 Largeaouth bass 8/7/75 9/2/75 White perch fMtrone acericano) 8/7/75 9/12/75 Yellow perch (Perea f iavescens) 3/22/73 9/15/73 ' Hudson River PC3 Analysis Results (Analysis by Rose Pollution Laboratory) TABLE 13 . Lab. Albany location______ Tdent. Tdcnt, Tag Length Weight No. (Inches! ('Pounds) PPM as Aroclor 1242//016 PPM as Aroclor 1254 Total PC?.'* PPM DPT/ r.C3. X. nil pe-a rk a Mouth of !lon<iouc Creek 2D219 23218 2D219 23213 10.4 20.4 0.44 3.23 0 0 4.03 7.01 4.08 0.49 7.01 1.37 Mouth of Rondouc Creek 23241 23238 2D242 Mouth of Rondouc Creek Hud-RCoxp 1A Hud-RConp 2A Mouth of RondouC .Creek Hud-RCoap LA 2D241 2D238 23242 2D237 23236 2D240 . 11.6 12.2 . 13.) 15.7 15.7 17.7 23223 2D233 23230 2D220 8.8 9.0 9.3 9.5 22226 2D228 23231 2D234 7.4 7.4 7.5. 7.8 2C8498 2C&496 23212 2D210 23211 8.6 8.7 8.8 8.9 9.0 0.96 1.06 1.41 2.38 2.50. 3.67 0 0 0 .0 0 -0 0.242 0.324 0.291 0.242 0.326 0 1.73 4.87 7.65 3.71 3.37 3.52 1.73 4.87 7.65 3.71 3.37 8.52 0.38 0.40 0.89 0.87 0.79 1.13 7.45 8.12 7.45 1.70 8.12 1.60 7.28 Composite of 4 ' . 8.22 Coaposi.ee of 4 `- 5.28 5.28 1.03 Cocposite of 5 ( j 5i I i I ! {I ! ! f 5 V > '< OSW 028912 f IP 1 I -ST-TS" /enemm uuiwjaiii'sgrn--JJ SP. "tew- n'-cios ' Bate Collected ar^cnouth bass 8/6/75 Ml c rv r t /* ruf vice perch -"rone JSfrie.-'o.i) 8/6/75 erican eel r.tntlla cs crata) ` 8/6/75 . iped bass ror.* xarilus) ce perch rone ericana) 8/8/75 8/8/75 -' '* Hudson River PCS Analysis Results (Analysis by Rose Pollution Laboratory) TABLE 14 Bate Analysis p.ranrted Location . Lob. Albany Trirnt. Tdent. Tag length Veighc No. finches') (Pounds) P?X as . PPM as Aroc lor Aroclor 1243/7016 1254 Tot2 I Pen's PPM DDT/ DCS Z Oil Re-ark* 8/22/75 Mouth of Happingers Creek 2C8402 2C8417 2C8403 2C8402 2CS417 2C8403 12.5 14.1 19.0 19.73 ' 4.01 10.73 3.35 17.99 5.19 23.74 14.08 23.18 8/22/75 Mouth of V..-ppi-ngers Creek 8/22/75 KouCh of Wappinger* Creek * 2C8449 6.0 --^ 2C3426 6.3 . 2CS423 6.4 ' 2C8439 6.6 2CS409 7.0__ 2CS429 7.0----- 2C8472 2CS487 2C8469 11.3--a. 11.4 11.7--- 2C847Q 14.3-----2C8436 14,4 2C8484 15.2---- >15.74 4.14 19.88 Composite of 6 . =--\3.36 3.00 * 16.36 =--41.69 . 10.42 52.11 > "i . * Composite of 3 Composite of 3 -. 2C8483 2C8483 17.0 123.61 . 53.64 177.25 >27.0 `f 9/12/75 , # Mouth of Esopus Creek 2C8451 2D24 ' 2C8451 26, 9` . 2D24 * 14.2 . 9/12/75 < Mouth of Esopus Creek - Bud R-Comp 3A . 2B42 2B43 2044 . 2047 6,5 6.5 6.6 6.6 0.94 0.1S--- 0.17 0.15 0.17-^ 14.11 0 ' 4.84 6.62 9.65 18.95 6.62 0.86 4.95 .. 9.65 1.59 _ Composite of 4 a _* DSW 028913 - - 'r rvwu wi'Wm^u.y^i".|iw^f!Wiyvtf,^i.i-i?esij'iiu^^w.>wKWji:ye!|r,^m|>,eli|>v,n'jww|rMV/'|w<w'"'ll'*'M l,,|fJ"11. m i1.1 -- . . . m. . . . . . . . . . . . . . . . .. - .rrp^i n m, ji Date Collected American shad (/-. P < J * s.ipidi ssimn) 5/22/73 Date Analysis Resorted 9/18/73 ' ,* * 3/22/73 9/23/73 . ` 3/22/73 9/12/73 3/22/73 10/1/75 * * Location KingstonRhinecliff Bridge KingstonRhinecliff Bridge KingstonRhinecliff Bridge Kings tonRhinecliff Sridga Hudson River ?C5 Aha lysis Results (Analysis by Rome Pollution Laboratory) Lab. Albany Idont. Ident. Tag Lengch Veighc Ro. finches) /Pounds) PPM as Aroclor 1242//016 2C8363 2C8369 2C8370 2C3353 2C8366 2C8364 2CS356 2C3354 2C8365 2C8355 ' 2C837X 2C8372 2C8363 2C3369 2C8370 2C8353 2C8366 2C8364 2C3356 2C8354 2C8365 2C8355 19.5 20.0 20.0 20.0 20.8 21.0 , 21.2 21.5 22.0 24.0 2C8371 20.0' 2C8372 21.5 2.18 2.82 3.04 3.17 2.88 3.23 3.39 4.07 4.20 4.82 . Trace Trace Trace Trace Trace Trace Trace ' Trace Trace Trace 3.30 3.37 22.91 ,58.13 2C8367 2C8367 21.0 , 21.0 3.19 3.10 Zraca 23.40 ,. - PPM * Aroclor 1254 Total pen's 2.52 6.91 5.29 2.98 3.83 3.23 39.56 33.14 7.78 19.35 2.`5 2 6.91 5.29 2.98 3.83 3.23 39.56 38.14 7.78 19.35 Trace 9.22 22.91 67.35 6.40 6.40 9.68. 33.08 . table 15 . PPM DDT/ PC?. Z. Oil Sw.irVs 0.57 1.50 1.49 0.39 0.90 0.77 4.41 4.24 1.60 2.99 .* ` ^v f l i ? * l 7 \t i << r it ' i }.32 3.52 \ .? t -; ' 5 .. i 0.65 Oil dark and thick z \ oCO A '* O N) CD vO ^1 4- rnr * . t f t i '< f t \ ___________t STLCOPCB4012876 u 'w/' STLCOPCB4012877 -rtr ripci boss lV*t ilu> DacTrl KS7 1975 Dote Analysis Re rt rd 7/24/75 Hudson River PCS Analysis Results (Analysis by Rone Pollution Laboratory) location Lab. . Albany Idenc . Tder.e. Tappan Zee Bridge 206 259 256 254 269 1 NT Tag Length Weight No. (Inches! (Pmird.O 22.8 24,4 24.8 32.6 37.4 37.8- 5.98 7.C8 6.60 14.74 20.24 21.12 PPM as Aroclor 1242//016 * * * * * PPM as Aroc lor 1254 37.80 6.75 7.93 3.25 6.53 3.86 Total ?C3'j TAELS Iff ppv DDT/ nr- X 0*1 i 4.39 1.52 1,69 0.93 2,07 . 1*3s9. 13.96 7.12 5.36 5.98 9.41 9.6.1 * Standard aasiplt not run for this PCS tharafora quantification not posslbla and total PCS'a can-not ba calculated a to ac o nj 00 VO m ripy n Vf ` l t r i 1 f !  Dote - Collected Sate Ana lysis R^norcod loc.it ion Hudson River PCS Analysis Results {Analysis by Rotae Pollution Laboratory) Lab. Albany Tdcnt. I dent. Tag Length Weight No. flnche*) fpni.ndsl ?FK as Aroclor 12A2//01 ft TA2L2 17 ??M 3 S Aroclor 1254 Tcto 1 ?C3*? DDT/ ro X Oi \ Fz-arlt* 1 \ 4 | Wback herring 4/27/75 Alev o a.-'tW.-ili*) ericsn shad lo< J soidossirta) 4/27/75 * uebaek herring lo,.i ' tszivalis) 4/27/75 .' o (/) X o M <X t-- O' 9/24/75 1 olio below llud-S-HE Ccorge Wash Corep 1 ington Bridge 9/24/75 1 oile above Kud-SK Ccorge Wash Cocp 1 ington Bridge . 1 mile above Hud-SK Kings ton-Rhine- Cotip 2 cliff Bridge 10/2/75 1 mile below Ccorge Wash- * ington Bridge, ` ` . * . 0 5.13 5.13 0.85 13.11 Composite of 2 fill-, ets abtair.ci fron. angler i \ ' 0 1.88 1,88 0.30 19.83 Cer-poslte of 5 . fillets obtained . fron anglers i -. ' 0, . 1.56 1.56 0.59 . 3.93 Composite of 3 -fillets obtained froa anglers f f ! j : ' 0.32 0.52 0.84 0.7 1.64 Roe | .i * . '* # '* . . * ; | *t i { I i1 ? ( f i tI i ii t "srr ijUj^i'jwl.V Wi'JWjll'l"; MJ . V" rk l* f > : rfr * ? STLCOPCB4012878 i "o^es 1X3 tC Col looted largesouth bass CMiernotorus s*j Isolde si 9/2/75 'el low perch 'Perea fl.ivescens) ' 9/2/75 hire sucker Cazcfz crr.us ccr-crsori) 9/2/75 O in Walloomas/Hoosic River ?CB Analysis Result* (Analysts by Department of Health) Date Analysis Rrnorrod 9/11/75 T.oc.icion Lsb Tdont, Hoosic River 32-P-2 above Johnsonville Albany To s Length Xc, (Inches) 32-P-2 7B1171 4X0753 11.2 13.3 Weight (Pot:nc's ) P?h as Aroclor '242//016 0.81 ---3-2.8 ` 1.56 32-P-3 32-P-3 7B1188 . 14.5 7B11S1 16.2 7BU82 16.3 1.69 1.81 3.19 ----- _Da-2.5 9/11/75 Hoosic River above ' Johnsonville 32-R-l , 9/11/73 Hoosic River 32-F-2 above Johnsonville Hal loons ac River in Valloomtac 32-F-l 32-F-3 32-R-l 4x4680 4X0759 4X4694 4X0785 32-F-2 7B1167 7B1194 No Tag 32-F-l 731197 7BU77 7B1198 32-F-3 7B1193 4.1 0.03 5.7 0.10 6.6 . 0.'l2 . J>2.0 7.3 O.io ------" 12.3 13.7 14.3 1.00 0,81 7>o.7 0.81 10.6 10.913.1 ' $.39 0.38 <>.70 J>2.9 15.0 1.20 i'.3 P?y. as Aroclor 12SL 2.2 Total rc?>' 5 5.0 3i5 6.0 3.4 5.4 0.6 1.3 2.9 5.8 0.6 ` 1.9 TABLE IS ppv DOT/ TV*3 % 011 Composite of 2 , Composite of 3 b Composite of 4 Composite of 3 .* Composite of 3 * OIM oo o WV*?.v ev nu ,i r * PI_J. f STLCOPCB4012879 }>J N-/ Ts- r i rs Dote Ca 11 re t.od Scuil Laocth bass C'lcreateres calor.icul ) Slue'oack herring (A lesa ae rclva tis) 9/1/75 9/3/75 .Tiite sucker (Catostorras cca^ierront) 9/3/75 _, Slack crappie (?o-ox{s niercn.iculatus) 9/3/75 Dote Analysis Rt-riorf <-d location Kohavk River PCB Analysis Results (Analysis by Department tf Agriculture and Markets) 1-ib. Albany Tclcnt. Ident, Tag Length Weight lr>. (Tnchesl <'a.~nitirls) rrti as A roc lor u`a://016 p?>: as Aroc Jor USA . Total PCB' no>* DOT/ twr. TAELS 19 O'. X 9/9/75 Belov 10933 Schenectady 9P-1 9/9/75 Belov 10937 9F-1 Schenectady 9/9/75 Belov 10936 Schenectady 9F-2 mm Belov 10935 Schenectady 9i-1 710628 71C630 710198 5.2 7.8 8.6- 710642 710633 710634 710637 710639 710641 710646 710643 710644 710647 710648 1.5 2.2 2.1 1>6 3.7 0.8 1.9 2.7 1.4 3.0 Composite of 3 s Composite of 6 Coaposite of 5 Coaposite of 5 10934 9R-2 0.8 1.3 Coaposite of 4 .srgmnouth bass 9/3/75 `Mlcrontcrus ' >j Ir.eides) . 9/10/75 Belov 11050 Schenectady 11051 DSW 028918 9P-2 9P-3 5H587 5K586 5K590 5H588 9.6 9.9 10.fi 11.0 5K591 511592 5H593 5H595 13.6 13.9 14.4 14.8 2.1 2.8 4.7 5.9 Composite of 4 Coaposite of 4' STLCOPCB4012880 v.J .* f e* Jllcyc 5t t rc< redion fit re.:-.) Cote Oll.-er rJ 8/29/75 tallmouch baas iicrooterus Lolor.icuQ iltc sucker '.itostcrus orrr.crserO 8/29/75 8/29/75 own bullhead ctolurus gbu losusl A * 8/29/75 D-itc Analysis Rrr'.'fted 9/8/75 9/8/75 Mohavfc River PCB Analysis Results (Analysis by Department c Agriculture and Markets) l-nc-ttinn Lob. Albany T<tcnt. T<4~me. T.ij; Length Weight ?>. finches! fP^i ir.fi O to: as Aroe lor 1247//01P Little Fells 10802 10P-2 4X1038 4R3007 4R3463 53245 4X458 15.5 15.9 16.3 16.4 16.6 10801 10P-3 5B313 5E89 4R3059 5D661 5B237 17.4 17.8 19.8 22.3 22.8 Little Falls 10300 - 102-2 6WC753 630501 10.9 12.3 to: ai Aroclor 1254. ' 9.0 9.5 9.5 To: a 1 res`5 13.9 13.5 13.4 p5V tot/ rrn TA3LZ 20 % Pi 1 Composite of 5 Coaposlte of 5 Composite of 2 9/3/75 9/8/75 Little Fails 10803 10804 Little Falls 10805 107-1 10F-2 10F-3 6WC378 7X1053 6S7833 6X2271 630745 630497 8.3 8.3 8.6 8.6 8.9 9.4 6WC726 6M2461 7X1954 6WC768 6X3156 10.6 10.8 11.2 11.6 u.a 4R3262 4X907 4R3515 4R329S 6X2260 10.9 11.2 12.8 12.9 13.2 4.2 4.2 1.1 .1.1 11.3 14.0 Composite, of 6 Composite of 5 Composite of 5 DSW 028919 "mufiipp- m fui ! / t \ STLCOPCB4012881 1 -w^ *- cif** Date largcsouth bass CMicro-iCrruS s 8/18/75 Mt suckers Cacest*mjs cc~.crsoni ) 8/18/75 ar? Cvnrinus earpio) 8/18/75 . Dace Analysis Lee..){1 on Rondout Creek PCS Analysis Results ; (Analysis by Deportment of Agriculture and Markets) | Lob. Tdent. Albany THcnC. To3 Length V:oi3bc No. (Tn^hff ^ f'Vnr !< ) T?M as Aroc lor l74?//f)16 9/5/75 Bloomington . 10698 8P-1 2D178 23177 2D1S1 2D130 2D179 . 7.0 ---------------------------- __ 0 7.1 ___^ 7.1 7.7 8.0''"^ ` P?X as Aroclor 1256 1.2 Total rc^'t i.-2 ??* E3T/ re?. TABLE 21" z. 011 Composite of 5 / 10697 8P-3 2D175. 18.7----------------------2=SCI----- 0 1.9 1.9 23174 20.0 --------- ' . Composite of 2 9/5/75 Bloomington 10700 87-3 ' 9/5/75 Blooaingcon , 10696 80-3 2D192 2D186 2D1S9 23191 23190 16.8-------------------------4- 14.9 ^ 15.0 16.5 18.6 23194 22.7---------------------------- 2D193 24.0 __--------` 23195 25.9---' . 0 ' 1.6 * 1.6 * 1.5 1.5 ,* Composite of 5 # Costposite of 3 - O (/) sc c i\> CD . sO Ni O ' ' V 'j-;y H1 ^ -- r", ,;;i i l'I'm." T STLCOPCB4012882 ~*i <?3 T5ate Collected .ucbaeV* herring To? a aecivalls) 5/21/75 5/2/75 Cate Analysis Kcrerc e<J 10/17/75 10/22/75 Hudson River PCS Analysis Result* (Analysis by Rons Pollution Laboratory) T.ocn c ton Lab. Albany T<!nt. Tdort. Mouth of RocliffJansen Kill M | ` RJK-KER-l RJX-UER-3 RJK-KER-2 RJX-HER-4 ' Tag Length . Voighc finches) {Pounds) 10.2 . 10.2 0,44 0.37 10.6 U.O 0.41 0.42 PPM os A roc lor I'i?//016 1.05 1.85 0 0 PPM as Aroclor 1254 0 0 0.96 4.69 Total PC' ' * 1.05 1.85 0.96 4.69 TABU! 22 9tM DOT/ Z ,**. Oil p. , Vho'e fish Vhalc !lih 0 0.61 8.17 Vhole fish " 0.69 Vhole fish ' 'j 1 1 1 I ! 5 ) > l [ 9 U MuabocSc barring donated by Charles Zaoerlck. mmm ltu ipnipjiiiy^^p Vi*' V ' I \* *rr *Y fvf. i t rl i f t >f \ ! * f {4* Dote * Co I l-c trd rcrican shad A r><,1 t-JpidlssiruO 4/27/75 rripcd bass ->rcr.e saratilus) 10/11/75 10/11/75 10/11/75 getnauth bess erooterus sairoides) 10/11/75 Date Analysis Rv ;*o7X.f'& 10/20/75 - Hudson River PCS Analysis Results. . (Analysis by Rose Pollution Laboratory) ' Location Lob. Albany Td'-nt. Irfctic. 1 Bile below HTO-SRCco. Washing- coop-1 ton Bridge Tag Length . Ho. _(Inches) . Weight (Pounds) PIT, as Aroclor 7242//016, PPM as Aroclor 12 54 ' Total PCS'- * IABLS 23 DOT/ ' TL DCS Oil Rn-a.rks Roe 10/27/75 10/28/75 10/29/75 1.3 cl. So. of Rocliff Jansen Kill . 2D119 2DI20 2D121 20122 2D123 20129 HR-SB-3 HR-SB-2 **' . *> 10/29/75 1.0 mi. So. ' * 20133 of Roeliffi - . Jansen Kill 20119 2D 120 2D121 2D122 20123 2D129 20124 20127 2D113 2DU4 20115 2D110 26.0 20.9 21.1 16.2 18.2 16.2 17.9 17.3 8.1 8.3 8.4 6.4 20133 13.5 7.40 3.78 2.97 ' 2.40 3.63 2.04 2.14 -1-.98 0.33 0.29 0.18 0.12 ' ` 23.14 48.92 9.25 9.67 13.15 28.94 8.16 8.21 1.61 5.88 ' 27.68 40.84 8.07 6.79 11.51 23.26 5.38 2.87 .' ` 3.85 50.82 89.76 17.32 16.46 24.66 52.20 13.54 11.08 9.73 \ of fish . % of fish . Jj of fish Composite of 2 4* Composite of 4 *' ' * DSW 028922 r *. *?eaks evident ofl chroniatograph but do not natch PCBa 'or DDT . *. *i t% ~rr v e-'r (as Dote * Co 1 loctcd Date Ana lysis Re-ported Location Hudson River PCS Analysis Results (Analysis by Rome Pollution Laboratory) TA2LS 24 Lab. .Albany Tdcnt. TrfonC. Tag Length Weight Ho. finches') fPottnds) PPM as Aroc lor 1242//01G PPM as Aroclor '.'54 Total ?m' j ??m; edt/ rc? 7. , `uteri,can shad Spring 1575 (AXosa ~sa?Tdis*i=a) . Spring 1975 10/15/75 Poughkeepsie HRS -1 10/15/75 Highland HRS-2 Spring 1975 10/15/75 Highland HRS-3 9.00 0.96 0.74 0 0.60 9.00 1-.56 * 0.74 2 fillets contributed by Lave Seymour 1 fillet contributed ` ,*n* hy She ruin Alien Shad roe contributed by Sherudh Allen One anomalous peak noted in arcs' vhore Aroclor 1254 Is found. O C/p a: o .* Kj od ' vO I\1 OJ I i it W. mi wn 1miljmiimi iii xii 'Tri STLCOPCB4012885 crlptd tii 'v> ri- f; ttetc IO/H/75 5/75 10/14/75 o </> Hudson Elver PCS Analysis Result* (Analysis by Rome Pollution Laboratory) analysis 10/29/75 v T/><>; fen Tappaa Zee Bridge Lab. Albany Taj Length Weight ?PM .is Aroclor ri'-A as Aroelor Total TtVnt. Tdent. 'V, fTneher) fPe.rndr)13A.~'//0t& 12*4PCS . SU-Coap2-UX 21)140 20141 2D142 5.6 5.6 6.0 0 1.66 1.66 2D143 2D144 2D145 2D146 2DL47 2D148' 20149 3.5 5.0 4.5 4.2 ' 4.0 4.2 4.2 . *` . ' 2C6506 4.0 ,' 2C8520 2C8518 2CS521 2C8524 3.5 3.3 3.3 3.0 . . 10/29/75 10/29/75 . * . Weat Point Tappan Zee Bridge SB-Coap- 4-1-3. ' SB-Comp- 1-13 * Not tagged 2DI34 20137 2D135 2D136 2D139 2D138 7,5 6.9 7.0 6.7 6.5 6.3 . 0 2.19 . 7.54 1.96 . 7.54 4.15 TABLE 25 COT/ res Z ._< o:i _____ Composite of 15 whole fish Plllet* only-Ooaated by Mr. Rathjen . Composite of ' 6 whole fish Of\J to vD N) "uil II HH t m m^i.'T'wspwTin?'-w' r!'""y ( { STLCOPCB4012886 . Cate Collected ILitc Analysis .. Rr*r<~irteri ` Loention* <V bass ah- eel t tes r:.nt-.t.-i) `10/7/75 tshvatcr drua plciinatus rra.an-.cns) 10/7/75 10/7/75 llcw Perch erca 5 lavesctns) 10/7/75 * 10/27/75 Lock 8 10/23/75 Lock 8 10/27/75 10/29/75 Lock 8 Lock 8 evl fe - 10/7/75 lose . cr.Joharcneua) lte sucker atoster.us crr-crsonl) 10/7/75 10/27/75 Lock 8 10/23/75 Lock 8 pkinaetd eocnis giVcas'-is) 10/7/75 10/23/75 * Lock 8 Chen?lain Canal PCS Analysis Resales (Analysis by Rono pollution Laboratory) TA3LS 26 Lab. Albany I Jen t I dor.t. Tag Lcr-sth Ko. finches) ?7M as Weight Aroclor (P.nir.dO_______ 1742//016 ??N as Ar&clor '.234 Total PCR ' s PPM Z2~! P3 X m . rV: 6R7314 6R7314 6.6 0.25 4.40 7.73 12.18 whole fish | ii 6R1319 CC-Coap.l 6R7318 6R7323 6R7325 6R7316 6R7317 CC-Comp-3 6R7322 6R1319 11.6 6R7321 5.0 6R7320 5.0 6R7318 17.5 0.72 0.06-----0.06--" 3.18 6R7323Ir-3.0 ---r 0.13 t:, '4.9' 6R7325 1.9 3.1 0.41 6R7316 7.9 6R7317 9.5 6R7312 6.1 6R7315 6.2 6R7313 6.2 0.22 0.31 0.09 0.09 0.13 0 0.3S 0.-3S * H.D. 4.23 0 Trace Trace Trace 7ST3 Composite of o -. 2.33 . 2.33 0.38 ' 2 whole fish 0 * 0.92 0.92 Composite of 4 whole fish 1.60 Trace 0.92 0.68 1.60 0.43 Composite of 100 vholo fish' Trace 0.92 0.63 Trace Trace Trace 6.26 Vholc fish 4.55 Whole i*h 3^44 Composite of 3 whole fish tt ii ] 0.16 2.00 2.00 Trace 4.38 Composite of 5 whole fish o 00 Sl c N> CO vO N) V* rrj-7 ,\ t*. STLCOPCB4012887 JJ Dste Coll #CCcd krac da t ra . ibcthlcus) 10/3-6/75 10/3-6/75 D to SE O ho CD sO ru O' t Dote Analysis Xe-Ttrd Hudson Rivci PCB Analysis Result* (Analysis by Rome Pollution Laboratory) ' ' Ljb. Lacidon Tdonc. Albany Idont. Tog Lcr>3Ch Weight ho. flrchesl (PourulsX PPM as Aroclor 1747//016 * TABLE 27 PPM as Aroc lor 1754 Total pcb's DOT/ ncs T on r<--arks '' f r ;1 fr >t \i 10/14/75 Champlain KU Coop 1 5-W-3 Feeder Canal 5-V-4 in Hudson 5-W-8 Folio abovo C.E. landfill 6R6196 6X6197 6X6191 Within 1 mile below Ft Edvard KU Coop 2 5-W-6 6R6193 5-V-7 6X6192 10/14/75 Within 1 mile below Ft. Edvard BA Coop 1 5-W-l 6X6198 3-W-9 6X6194 Trace Trace Trace Trace Trace Trace Composite of 3 j :v ' Composite of 2 Trace Trace Trace Composite of 2 . ' 4 a ' * . ^ t f f 1 i 5 i \ P * 7 J r ( 1 iij. ' r 7^r i STLCOPCB4012888 /. PCS ANALYSIS RESULTS PRIOR TO 1975 DSW fH ' 02892? STLCOPCB4012889 > : *.\ 0* * ` ** \ . * ' ' "* mnsox RIVER PCC AKALYSTS RESULTS . -' _ Tabic 1 i l . Se-cies Month and/or Year _ Col lee ted Analvred ' Largcaouth bass /l* *. * , ! .. ' **. . 9/72 . 9/72 1972 1972 . ' *' * * . ` 7/70 1972 H- V Soallmouth bass ' 7/70 7/70 > 9/72 . * 1972 1972 1972 Striped bus 7 7/70 . 1972 1972 ' Location Mouth of Wappingers Creek Approximate Act Mouth nf Rondouc Creek Cornwall ' ' Mouth of Esopus . Creak Mouth of Rondouc Creek . . * ' Varransburg Mouth of Esopus Creek ' Lentth fin.} Voith-t fib.7 ??>: as A-roc'.or 1254 16.2 15.9 ' 14.2 13.S 10.0 2.5 5.59 2.7 5.24 1.9 ` 5.15 1.5 ; 1.24 ' 0.5 . 0-66 . 16.5 14.0 14.0 13.7 13.4 10.5 6.7 - S.O ' * 2.6 . 1.5 ' . . 1.4 . 1.4 1.3 0.7 0.20 - 0.20 . ' . 6.59 6.04 2.80 1.23 4.85 3.00 3.46 . 14.5 1.6 ' ' 11.04 - ' 14.2 . 1.4 ' 11.77' ' ' 13.? . '' 1:4 10.36 13.4 1.3 14.62 13.1 ' 1.2 . 21.60 12.8 .. . * 1.0 0.96 14.7 v 14.9 ' . ' 1.4 1.4 53.81 17.58 ' 17.3 12.4 10.9 2.6 0.7 ' 0.6 . 2.69 ' 2.84 . _ 2,56 ' 7 7 0.18 . 17,3 1.8 10.43 . 9/72 1972 ' Mouth of Rondouc . Creek 13.2 10.2 ' 1' 0.8 1.67 0.4 2.11 Pc-nrkx * V Composite of 2 . * ^ * ** t \ i l \ i v f c i [: f \ \ i *r *tl * t f STLCOPCB4012890 OSW 028928 STLCOPCB4012891 5--cclcs O to 22 o N) 03 sO N) 05 Sturgeon Month and/or Year Collected Analv~ed -- 4/73 1974 5/73 7/75 7/70 7/72 1972 1972 wyjmiiii mmjiimiw g<g>y frcnsoN* "tvrrp, pcs axalysi- SESI^TS (continued) Location Tappan Zee bridge Approximate Ace Length fin.) 36.5 Vl nhc (lb.) 23.5 -. ' . * ^ ', ' , . . - , ' 31.2 31.0 31.0 29.6 29.3 27.2 27.0 26.7 26.7 26.1 25.3 23.6 23.3 23.0 22;4 22.2 22.1 21.5 21.5 19.9 19.4 . ' . ' ' ' 37.8 19.5 18.5 13.8 21.2 17.0 14.4 . 9.3 12.0 4.9 14.2 . 10.2 9.0 6.3 . 8.0 8.3 7.0 7.2 .5.3 * 3.5 2.0 2.5 21.1 . Mouth o Readout Crae'K 7 37.4 32.6 ' ' 24.8 24.4 22.8 .' 33.3 . .7 7 7 2C.2 14.7 ` 6.8 7.1 6.0 6.0 0.39 0.33 0.20 Is X ??.'J as Aroc'or 1254 Rr!:- 15.61 4.25 4,06 3.70 12.or 7.63 12.40 13.17 9.80 49.63 25.12 . 28.32 24.59 . H.48 . * 3.73 14.27 20.03 . 15.29 9.54 13.37 3.70 16.53 13 of 22 (a 1`.27.) exceed 5.0 pp= * * . v. , 1 9 , - 3.86 4"o 6 (66.77.) exceed 5.0 ppa 6.S3 . 3.25 7.93 6.75 37.80 5.73 7.03 7.03 7.03 ' Campos lie, vhsia I ? f f7 i. r i i 7 i t i ! I \ il V i, i\ ti i t i ? r i t ft ! i *< i f i STLCOPCB4012892 Species Xorchern . pike Ycllov perch a* Month and/or Year Collected Anatvzed 9/72 1972 9/72 1972 ' White perch . . * ,\ 9/72 ' 1972 * * % D to x O N) 05 vO OJ o . * I .* ' 1 HOPSON* RTVCT Pf-3 ANALYSTS RESULTS (continued) Tail'a X F t Location Mouth of Rondout Creek Mouth of Rondout Creek Approximate - Ace .. Mouth -of Uappinger# Creek ' ' ' Lcnech (in.) 35.5 4.0 - 7.7 6.7 - 7.2 10.0 Weichr (lb.) 9.2 0.'08 - 0.17 0.10 - 0.20 . 0.56 ?p>: as 17.78 . 0.75 0.92 11.61 '' . '. . Mouth of Rondout Creek . ** `a ` 9.3 . 9.2 9.2 8.9 8.3 8.0 7.5 7.6 7.2 ` 7.2 7.2 710 6.5 . 6-3 5/5 - 8.9 6.9 - 7.3 . ** - 8.7 8.6 8.3 8.2 . 8.1 7.7 7.5 7.4 7.4 7.4 7.6 7,2 0.50 0.46 0.43 .. 0.45' . 0.55 ' 0.25 ' ' 0.26 0.25 0.27 0.26 0.24 f 0.25 0.5 0.16 0.10 - 0.40 0.20 - 0.25 9.00 12.07 * 8.30 11.33 5.67 2.76 * 2.41 0.44 IS.81 3.70 3.76 2.52 2.01 2.34 5.95 5.33 0.30 3.80 0.31 6.69 0.29 1.03 0.25 3.37 ` 0.25 1.34 0.23 7.22 0.20 . 1.69 0.24 0.38 0.22 4.50 0.21 10.Cl 0.20 _ 0.16 2.45 O.cS ' Composite of 10 fi Composite of 3 fix 7 of 15 {46.67.) ' exceed 5X3 pp= excluding corposic. fish cc=posice` of 5 fish f ecmposita of 5 fish ! 3 of 14 (21.67) exceed 5.0 ppa * Species Black Crappie Pvnpkinseed * BlueSiU Rcd-brcast Sunfish Hor.th and/or Year Collected Ar.alvred 7/70 . 9/72 9/72 1972 1572 1972 9/72 9/72 1972 1972 HCOSCiT RTVSR ?C3 AKALV5IS ^~St~TS (continued) * Location Approxinace Ace LerC~S fir..) Weight flb.l PPM as Arcelor 1254 Mouth of Kappingers Creek ' Mouth of Rondout Creek Mouch of Wappingers Creek" . : Mouth of Wspplnger* Creek 6.9 6.5 8.3 .. . 7.5 - 8.0 5.0 - 5.9 A.5 - 4.9 6.2 5.01 - 6.4 0 , H 1 0.13 0.12 0.30 0.21 - 0.24 0.05 - 0.15 0.05 - 0.10 0.15 0.20 ' 4.53 0.46 1.42 0.46 0.64 0.24 XD . 0.52 ' Mouth of Wappingers Creek . 6.0 - 6.7 0.15 - 0.20 0.75 Table 1 . Co-npcsitc of 2 f. Coepos ice of 10 i; Composite of 10 Composite of 4 fis Composite of 12 ff D in sc o IV 00 >> U) m Vn 1^ v tw* '.(W "WTI STLCOPCB4012893 1>J \ % 9 0 ' KO'^UT CS-21C 0~ "TVER PCS ai:a;.V5Ts ssswrs * $?>re tr*f Xonch and/or Year Coi'<*cc<J Anslvred S^allr^ouCh bass 1970 1972 Snallcoush bass 1970 1972 Larcoouch bass 1970 1972 Lar;e=x>ueh bass 1970 1972 Lar;c=ouch bass 1970 1972 Lar;c=ouch bass 1970 1972 Lirsctsouth bass 1970 1972 Lar^er-ouch bass 1970 . 1972 Lar;estou:h bass 1970 1972 ' location .- ' . Appro:: i:sace Aco . Lcr.~zh fir..} V+ 14.9 IV-r XV+ or v+ 13.2 . ' >{ , 13.6 ni+ 13.4 III+' ' 10.8. III+ . 10.6 III+ . 10.2 III+ ^ 10.1 XII+ .. ' 9.9 VeUhc rib.} 1.4 1.2 .64 1.40 . 0.66 0.69 . 0.64 ` 0.69 0.47 ??:: as Arne lor ' 17.58 10.33 ' 9.52 . 5.70 2.60 3.33 6.61 3.27 4.31 \ O co . X .1 *o fv 0= vO u> IV * __ '. . 1 >- W Tab14 2 Sneete* Month and/or Year ColIcctcd Aralvred Larjccouch bssa Scallnoush bass Stsallaouth bass l largcnouch bass 1972 1972 IS72 1972 1972 1972 1972 1972 1972 MISCStt-WBOGS STREAMS - PC3 ANALYSIS RESULTS Location Koosic River Hoosic River Mohayk River Racmpo River Approximate Ape Length fir..} 18.0 16.9 15.8 . ' 17.9 . > 16.2 13.5 11.25 - ' 10.0 , 15.8 Veieht flb.1 4.0 2.44 2.0Q 4.27 2.82 1.40 - 0.53 2.0 ??y. as Aroclcr 1254 ' 3.13 4.39 0.57 2.35 2.62 . 3.94 4.03 2.73 ' 0.57 .7iblc O </> sc o N) 03 v> IP 03 n' ''wpwyypiii* w y (/> oo oo DO o M oCoO r*ir*~.r"T".'>\m*'a) rf""as'rv:v APPENDIX C Sampling Instructions to Regions DSW 028934 STLCOPCB4012896 PQccggomc t-lfy/rf 'Hi-- :! 1 lowiin; lir.t indicates t un-c locations whore sampling should he ('minuted in Older to isolate llr* incidence of PCI! contamination in waters vf (li I n York State. 'Ihesc locations were selected since tiic waters in that vicinity were either suspected of receiving Industrial/commercia1 wastes or indicat'd contamination in earlier (1972) sampling. At all stations fish, water and sediments will be sampled and analysed for the presence of tiro contaminant'. Hold collections will start as soon as possible and be completed by 9/15/75. A. Pish ' "1. Freshwater Fiydi. In each sampling instance two trophic levels fpi'dators and pan/rough fisii) will be addressed so as to compare bio magnification and assess impact on each energy level. Predator species will include: Smallmouth bass, largcmough bass,.walleye ' l'anfish/roughfish will include: . bullhead, carp, goldfish, sucker . In order to maintain continuity and permit data interpretation, the following procedures must be followed as closely as possible. . At each station Division of Fish and Wildlife field personnel will choose a representative predator and pau/rough fish (as designated above) for collection, liach species will be sampled so as to create three separate composites: A. Small or sub-legal fish ' lv. Medium or minimally legal fish C. Large fish . The specific sixes for each category arc listed below. * If possible the fish should be tab.cn as specified. However, some situations will require a deviation. Where tin's is the case please attempt to keep the sample as uniform (sixe of individuals) as possible considering the constraints of the situation. Small Medium I.arg' Species . . Length* Minimum No. Length* No. Length Maxi' Snnll.meuVh bass Largcmruith bass V.'a 11 eye bullhead Carp ' Cold fish Sucker Striped bass 0- l 6i 1 81 1 5.*- 1 6; 1 5*1 7r 1 12 t 1 6 6. 6 6 6 6 6 :5 . . 11* 1 11*1 12 i l 91 14t i 8" 1 li r l 17 f 1 5 5 5 5 5 5 5 5 Weight** Weight* \7 Salmon (vohth.) (t hinooh) ' p.iinbov or Stoolheads Lake trout Length in inches; 'V 'la nmind': 1-2 3-5 ; 1-2 1-2 .5 5 5' 5 4-6 8-12 3-5 ' 4-6 5 '5 5 5 15 : 1 15! 1 20*- 1 .12*. 1 24 1 1 11 *- 1 in m 18-' 1 O' 00 30 l 2 eg o Weight* 5 5 5 5 5 5 5 5 35 00 8-12 5 15-20 . ` 5 5-8 5 8-12 5 STLCOPCB4012897 ' At exists in the sill ions whore a cot: rcial, or recreational salmonid fishery iplcs of those species oil. requested. These fish should be collected .and numbers specified above. ; All fish collected should he i dent if i cd , tapped , wrapped in polyethylene plastic h>,':s (no core than 6 fish per bar,) and refrigerated or placed in a coole.r osoon nflcr taking as possible. (Temperatures must be maintained below A5F if fisli arc not able lo be frozen at once). If fish are to be collected for several days, specimens must be frozen as soon ns possible so as to keep until sampling is completed. Transport frozen fisli or cooled fresh fish' to tHe Rome Laboratory. lilli'i. ;| rr i vo cn 1 d, preferably frozen. Trior to delivery call Earl Harris at the Laboratory. 315 337-0910 to be assured that fish can be received and placed in the freezer. ", - ' 2. Marine Fisheries. Commercially important species will be collected by the division of Marino and Coastal Resources. Size grouping for fish will follow that of the freshwater, fishes. The species and locations for collection are noted below: Specics Ixicat ions BluetIsh Pnrg ihs Striped bass 111 tie crab Hard c1.-il.-s_/" One site to be determined One site to be determined One site to be determined Peconic Hay, Western Long Island Sound, Great South bay, New York Harbor Five specimens of each size group'of fish and five crabs and clams will be collected. Preservation of samples will follow that described under freshwater fisli hut .samples will be forwarded to Jack Foehrenbach (telephone number 516 751"7900) for analysis. ' C. Water *flie Division of Pure Waters will collect twenty-five two-liter samples in glass bottles. A sample v.'ill be taken at each freshwater sampling station indicated on the statewide sampling station sheet. All samples collected will be grab samples and no preservatives will be added to the -samples. The samples will not bo refrigerated or frozen prior to analysis. Polyurethane plug filters will be used for field concentration. These filters will bo stored at the DEC Rome Laboratories for subsequent analyses. . I). Sediment ' The Division of Pure Waters will collect tv/enty-fivc 16 ounce sediment sa:rjTles, one from each freshwater sampling station indicated on the statewide simp line, station sheet. Samples will be taken from the top 5 cm. of .depth with a Peterson drcdp.e or a KR corcr and placed in 32 ounce wide mouth glass bottles. No prCsorvatives will be added to sediment samples. These samples will be cooled in t! te field then frozen prior to storage. Samples will be stored at DEC Rome Laboratories for subsequent analyses. HYSD11 Fnvi ronmenta 1. Ileal th (.`enter will initiate development of sediment PC1', analyses procedures in anticipation of requests for sediment analyses. bottom samples '..-ill be collected from Hudson Falls and Waterford areas this week (11/ 1A/73-3/15/75) to initlaLe this. . DSW 028936 STLCOPCB4012898 . d ct. -t<0 a/v( a) <11 < ] o ^ ^ ou * c: Vh"(7r Procedures: A statewide fish sampling program, to be executed over a very short period of time, required mobilization of all Regional fisli management staff and equipment and close coordination of collections, transport, storage, processing, analysis and reporting. Coordination was provided by the bureau of Environmental Protection in Albany. Sampling Plan Ail Regional fisheries managers were instructed to attempt to collocJt fish in two traphic levels, predators and prey (or coarse fish), and in three size'categories,-small, medium and large for each species. A "jumbo" size category was established later for ' extra large fish. Details of the plan and a map showing general locations of fish collected are given in Appendices 1 and 2, respectively. Fish Collections anc! Distributions Except as indicated below all descriptions in this section refer to upstate fish collections. Long Island operations were separate. because of deadline requirements instructions for fish collections had to be issued prior to resolution of the problem of where processing and analyses would be executed. Early fish collections were sent to the Rome Laboratory for storage and processing and analysis -operations began at that location.immediately. . Consideration was given to 24 hour/day operation at tlje Rome Laboratory. This entailed the necessity for locating additional staff and equipment, especially grinders, freeze driers, extractors and gap chromatographs. Space and available electrical capacities and change potentials were also problems to be resolved. ' Also search for assistance in fish processing and analyses at sister laboratories at the Departments of Agriculture and Markets and Health at Albany and Voorheesville was begun. The latter plan proved more feasible and was adopted. However, this entailed new problems of transport, storage and scheduling to blend capture and shipments with limited freezer and lab processing capacities. Space in the freezer at the Wildlife Resources Laboratory at Delmar was recruited to use as a depot storage, base. Also a courier was recruited from the bureau of Wildlife to log in and shuttle lots of fish between freezers and to meet half way shipments made from distant areas of the State. ` Tentative distribution schedules were drawn based on laboratory capacities and anticipated availability of fish collections from specific locations. These schedules were adjusted as the collections materialized and according to the degree of success achieved in meeting prescribed species and size class quotas. - . SW 028937 STLCOPCB4012899 . In general, and wit!) minor exceptions, the Rome Laboratory concentrated on the Hudson River, Great Lakes and St. Lawrence Waterway fish. .y The ocean finfish and shellfish were collected,' handled, processed and analyzed by the Department's laboratory at Stony Jirook. Fish and shellfish were collected from the perimeter and . embayments of Long Island and are representative of those waters. All species are migratory to some degree. Assistance also was provided by the FDA. Laboratory at Buffalo for analyses of fish collected at Albany and Fulton Fish Markets. . As fish were delivered to the Health and Agriculture and Markets laboratories, instructions were given as to which fish were to be blended together into composite samples and which were to be done individually. Variable success in aciiieving species and size quotas at the various stations made it impossible to hold to the preferred lengths tor any species as specified in the sampling plan. Analysis Procedures and Techniques The use of four laboratories, two in different agencies, and each varying in equipment availability, required inter-laboratory communications to insure uniformity of results insofar as possible. This was achieved by visitation and telephone contacts between the chemists in charge of the operation at each of the laboratories. Instructions were given to ixisure uniformity in the portions of' fish used in the analyses. They are: Small all flesh Medium one filet Large one filet in the c.audal peduncle region Jumbos Control and uniformity samples were prepared and distributed to each laboratory for analyses. Three-sample lots were prepared by the Health Department and comparative results from the four laboratories. arc given in 0,)(yf ... V.v -i. .. OSW 028938 STLCOPCB4012900 APPENDIX D Analytical Techniques and Original Laboratory Results DSW 028939 STLCOPCB4012901 Report of the Department of Agriculture and Markets on Polychlorinated Diphenyl (PCD) Analysis of Fish Flesh The Hudson River and its Tributaries The Department of Agriculture and Markets laboratory was asked to participate in the statewide PCD monitoring program as developed by the Department of Environmental Conservation. Fish collected by DEC staff from various -locations were tagged, packaged and transported to this facility for analysis. Prior to any activity on specific fish, directions were supplied by the coordinating office (Bureau of Environmental Protection - DEC) indicating individuals to be composited, sequence of analysis and priority. In order to maintain a control on the samples, a Department of Agriculture and Markets identification number was used in addition to the Albany identification number (a tracking number used by the Bureau of Environmental Protection). These numbers appear on the appended report and indicate specific data relative to each sample. After receipt of the fish and compositing instructions, the tissues were analyzed according to the appended procedures (Appendix 1). The data relating to the Hudson River or its tributaries is presented as Appendix 2. rrEliffer Ge Director road-K^borato; Department of Agriculture & Markets i.A__ OltfQ [Umi'iPu.' ANTOINETTE CHOTKOWStO Notary Public, State of New York Reeldlna In Schenectady County No. 47 5S886GO Commission Expires March 30, 197' DSW 028940 STLCOPCB4012902 Analysis of fish for the Department of Environmental Conservation Onto Rec ' d 8/28/75 Lab 4 10G91 10G92 ' ENCON 4 5S (1) (2) FisJi Sm mouth Bass . - i it Source Hudson Riv vie Wtfd 1* i it n it ft 10693 5S(3) Wh Sucker 11 tt 11 ft 11 11 t 8/29 10694 - 5S (4) It* It '^ f 10695 5S (5) Walieye 10696 8C-3 Carp " 11 1! It It tt It 11 * 11 Roundout Cr/Blmgtn 11 10697 8P~3 Lg mouth Bass it ii ii 11 . 10698 8P1 11 10700 8F-3 It ` It It Wh Sucker It 11 11 It It * tt 9/2 10800 10R-2 Sm mouth Bass Reg 6 Mohawk Riv (Little Falls) It 10801 io.p-3 Walleye It * ' It 11 10802 10P-2 tt 11 . It . 11 10803 10F-1 Wh Sucker It If It 10004 10F~2 It It tt It tl 10S0S 10F-3 Brn Bu 1*11 id it. ii DSW 028941 PCB (ppnO 1242 1254 27 14.5 41.5 1242 1254 36 17.5 53.5 1242 1254 20.3 7.9 28.2 1242 1254 36.0 12.9 48.9 1242 1254 23.3 9.1 32.4 1242 none 1254 1.5 1242 none 1254 1.9 1242 1254 * 1242 1254 none 1.2 none 1.6 1242 3.9 1254 9.5 _ 13.4 1242 1254 4.0 9.5 13.5 1242 . 4.9 1254 9.0 13.9 124 2 none 1254 4.2 1242 none 1254 1.1 1242 1254 2.7 1.1 .3 14.0 STLCOPCB4012903 9/5 II 11 u' u 9/9 11 10933 9P-1 10939 9R-2 > Sm Bass' * Crappie 10935 9-R-l II lbOBG 9F-2 . Wh Sucker 10937 9F-1 4 1JLU5U 9-P-2 Herring Lm Bass 11051 9-F-3 ' II 11 Reg 9 Mohawk Riv below Schtdy H II It * If II It ' H 1* . 11 tl . II 11 * ' Mohawk River below ' Schenectady . 91 " If - 1292 1259 0.7 1.5 2.2 1292 1259 0.5 u. fl 1.3 129 2 1259 1.6 1.9 3.0 1292 1259 0.8 1.9 2.7 1292 1259 2.1 1.6 3.7 1292 .1259 0.7 2.1 2.8 1292 1259 1.2 9.7 S. 9 QSW 028942 STLCOPCB4012904 - v; auornioi'y Elliot /7 1220 Y.'nfinnfitci A-.cnuo ' Albany, NY 12: :J*> Polychlorinated-Jliphenvis .in Fish Reagents and equipment - (a) Reagents - sec PAH I 120-123 (b) Equipment - see PAM I 110-116 (e) Varian Aerograph 1800 Gas Chromotograph -EC detector'with tritium . . source. 61 x 2 mm i.d. glass column with 4.4% SE 30 on 60/80 Gas Chrom Q. Column temp. 183C, Injector temp. 205C, Detector temp. 205C, Carrier gas N2 30 ml/min. . Sample Preparation ' (a) Small fish under IS" - Remove and discard head and viscera; grind with tails - three times thru grinder. . (b) Medium fish above IS" - Remove and discard head and viscera; cut `lengthwise along backbone and grind one-half of the fish - three times thru grinder. (o) Extremely large fish - Cut off caudal section at anal opening, cut lengthwise along backbone and grind one-half of the section - three times thru grinder. . Extraction PAM I 2i.2.13a ' Weigh SO grams o.f prepared sample into a high speed biendor jar and add 200 ml acetonitrile, blend at high speed for 2 min. and filter through a funnel containing a loose plug of glass wool into a 250 ml graduated cylinder and record volume (F). ' Transfer measured filtrate to a 1 L separatory funnel. Carefully measure . 100 ml hexane into the same graduate and pour into the separatory funnel. Shake vigorously 1-2 min. Add 10 ml saturated NaCl soln and about COO ml ll^O ^nd mix thoroughly for 45 sec. Let layers separate, discard the aqueous layer id gently wash the solvent layer with two 100 ml portions of I^O. Discard washings, transfer solvent layer to a 100 ml glass stoppered graduate and record volume (P). Calculate the grains (G) of sample to be placed on Florisil column us follows: * 9' * ., G = S x ( F/T ) x ( P/100 ) (1) S c grams of sample extracted \ F *= volume of acetonitrile extract filtrate . T *= total volume (ml II2O in sample + ml acetonitrile added - correction in ml for volume concentration) Contraction volume of 5 ml is used ' for 80-45 ml IIpO/200 ml acetonitrile. In this equation the water content of fish iny be assumed to be 80%. . P = ml of hexane extract recovered ' ` ' Column Chromatography PAM I 211.14d Prepare 22 nun i.d. column with the amount of activated Florisil dictated by recovery studies. Top Florisil with about 1/2" anhydrous N112SO4. Prewet .column with 40 ml hexane. Place Kuderina-Dunish concentrator with graduated collection ` vessel under column to receive cluate. To the 100 ml glass stoppered graduate containing the hexane from the pnrti- . tioning stop, add IS gm anhydrous NapSOq and shake. Do not let extract 1'emain y with Nu2S0i|. Transfer solution to Florisil coliunn. Rinse graduate 3 times with \ S ml hexane and add to coliunn. When solution has' sunk .into column, rinse sides of column twice with S ml hexane. Elute column at about 5 ml/min with 200 ml 6% >yl cther/hexunc eluant. Remove K-D apparatus and add porcelain boiling chips. Place glass trap on top and concentrate'the eluant to 10 ml volume on the stcum DSW 028943 STLCOPCB4012905 bath. This is the assay solution. . Gas Chromatography Inject a 5 ul aliquot of the assay solution into the as .Chromatograph and compare the retention times of the subsequent peaks with those of a suitable standard whose peak heights are within + 10% of the injected sample. Quantitate the peaks on the basis of their peak heights. ' Calculation Results should be reported in terms of parts per million PCB's in the product. . '. Let A = .sum of heights of standard's peaks in millimeters ' B *= sum of heights of assay solutions peaks in millimeters C *= nanograms of standard represented by peak heights A . ' Then ( B/A ) x C = nanograms of PCB represented by the peak heights in the assay solution . (2) ^ From equation (1) , G " grams of sample placed on Florisil column which is also the grams of sample represented by the 1.0 ml assay solution. Let Y = ul of assay solution injected Z - G/10, gms of sample per nil assay solution or mg sample per ul of assay solution. . .. Then Y x Z *= milligrams of sample represented , in the amount of assay solution injected (3) Combining equations (2) and (3) with the definition of PPM: ( B/A ) x C ^ ppm PCB . YxZ in the product ... John J. Maxstndt Associate Chemist 9/10/75 UYS FOOD LABO.'kVj'OllY Stole Canpun - Laboratory Bldg. 1220 Washington Avcnuo Albany, Ny J223b DSW 028944 STLCOPCB4012906 flOBERT R. WHALCM, M.D. C&MMIIIIOKCn STATE OP NPW YORK DEPARTMENT OF HEALTH NEW SCOTLAND AVENUE ALBANY, NEW YORK 12201 DIVISION OF LABORATORIES AMD RESEARCH HEW SCOTLAND AVEMUE DONALD J. OCAN, 0.V,M. itc ion October 21, 1975 Report of the Department,of Health on Polychlorinated Biphenyl (PCB) Analysis of Fish Flesh The Walloomsac/ltoosic Rivers The Department of Health was asked to participate in the statewide PCB monitoring program as developed by the Department of Environmental Conservation (DEC). Fish collected by DEC staff from various locations were tagged, packaged, and transported to the Griffin Laboratory for analysis. Prior to any activity on specific fish, directions indicating individuals to be composited, sequences of analysis and priority were supplied by the coordinating offices (Bureau of Environmental Protection - DEC). All samples were given an identification number assigned by DEC and appears below on the report of analysis for those fish from the Walloomsac/Hoosic Rivers. After receipt of the fish and com positing instructions, the tissues were analyzed apcording to the appended procedure (Appendix 1). The data relating to the Walloomsac/lioosic Rivers follows! . Walloomsac and Hoosic River mq/q wet weiqht Sample No. No. Fish Name of Fish 1016 1254 Total 32-F-3 32-F-2 32-R-l 32-P-3 1 Sucker 3 * Sucker 4 Y. Perch 3 L.M. Bass 1.3 0.6 0.7 0.6 2.0 3.4 2.5 3.5 1.9 1.3 5.4 6.0 ( BBiJp \ f -- ~ ' > r' ' l \ 2 X-' * % t . ' - ! v * - <* A* L FA , 75 ZCOIC 7 1) Or - CfAI-OA.TDS DSW 028945 STLCOPCB4012907 Appendix! . Analysis Procedures and Techniques - Department of Health, Griffin Laboratory. : Clean up procedure for tissue in PCB analysis ' Soxhlet extraction '' 1. Weight 5 g of tissue which have been filleted, ground and composited. , .* .. 2* 3. Mix well with 15 g of anhydrous in a 50 mi beaker. * Transfer to an extraction thimble, (25 X 80 mm, single thickness). 4. Add 80 ml of hexane - acetone (2/1) mixture and some glass beads (about 50) to the bottom flask. 5. Set the flask on the heating mantle with the soxhlet extractor and condenser in place. 6. Turn on the water and the power-stat, (setting at 50). Reflux .for 12 hours. 7. At the end of refluxing, let the solution evaporate to 5 ml. 8. Add 25 ml of CrO^ mixture (prepared by dissolving 9 g of CrO-j in 6 ml of water and adding 50 ml of glacial acetic acid). Heat at 90-100 C for 45 minutes with stirring. 9. Pour the oxidation product into a 1/2 liter separatory funnel. Add 100 ml of water. 10. Add 25 ml. of petroleum ether. Shake vigorously for two minutes and allow for phase separation. After removing the aqueous phase, transfer the ox. phase into a' 125 ml flask. 11. Repeat the extraction (step 10) three more times with 15 ml of petroleum ether. 12. Combine the petroleum ether layer in the same separatory funnel, rinse the 125 ml flask 3 X 5 ml petroleum ether. Discard the aqueous phase. * 13. . Filter the petroleum ether solution through anhydrous Na^SO^ to remove any moisture. Collect the filtrate in a Kaauma-Danish evaporator. 14, Evaporate to 2.5 ml. 15. Transfer the extract to a vial for gas chromatography ** analysis. ' ' .. . oSW 028946 STLCOPCB4012908 16. The vial is loaded into the gas chromatograph sampler carrousel. The column is 27. Aplezon L on Gas-Chrome Q, 6 ft. column, temperature 185 C, flow rate 45 ml per minute. Hie integrator and computer have been calibrated with a mixture o 1221 plus 1016 plus 1254 (1:1:1) using BBHC as an external standard. .. 17. Hie area of the first peak retention time 0.77 minutes is used to estimate 1221. The next 2 peaks (1.80 and 1.55 minutes) are used to estimate 1221 plus 1016. Peaks with retention 2.M, 3.17 and 3.98 are-used to quantitate 1016; ''with peak retention time 6.48 used to estimate 1016 plus 1254f and peaks with retention-time 5.97, 7.61, 8.53, 10.95, 11.63, 13.89, 16.01 and 18.40 minutes are used to quantitate 1254. The mean of the estimate given by each peak is used to determine the total quantity of 1016 or 1254. 18. Calibration is effected by computing unique peaks relative to a mass of 5.0 ug/g of fish and xfh'ereas combined peaks are calibrated with respect to a mass of 10 ug/g of fish. The unique peaks give a better estimate of the quantity present than the combined peaks which are used only as a check on the analysis. 19. Results are expressed as ug/g wet weight of fish as Aroclor 1016 and as Aroclor 1254. The total PCB present is determined by adding these two estimates. QSW 028947 STLCOPCB4012909 Report of the Rome Pollution Laboratory on Polychlorinated Biphenyl (PCB) Analysis of Fish Flesh from the Hudson River The Rome Pollution Laboratory, which is administered by the Department of Environmental Conservation's (DEC) Bureau of Environmental Protection (BEP), analyzed fish samples from several stations on the Hudson River. These samples were collected by DEC staff in Regions 3,4 and 5S and were transported to the Rome Pollution Laboratory where they were stored at 0F. In most instances, the fish had been measured, weighed and tagged by the regional personnel and placed in polyethylene bags. ' Prior to analysis, analysis priority and compositing instructions were received from the central office of BEP. The fish were then thawed, decapitated and eviscerated, except in certain instances as noted by "whole fish" on the attached data sheets, and then analyzed according to the attached procedure (Appendix I). The results of the analyses were telephoned to the BEP central office and are given on Appendix II. Calculation sheets and chromatograms relating to these analyses are available at the Rome Pollution Laboratory for inspection. Associate Analytical Chemist DSW 028948 STLCOPCB4012910 /Vjij.t t..| i x. I Analysis l'tocv.uui os nuu iecuniques Conservation - Rome Laboratory. UV|JUI.CI)U;uL Ui L1IV i.1 Viuuu ulo*. I. Extract oil on soxhlet* II. Alkaline Hydrolysis t .' 1. Weight ca. I g. sample ' . 2. Add 10 ml 957. ETOH . 3. Add 1 mi KOI! 300g/200 ml 1^0 4 A. Heat irt waterbath 5 min. @ 77C , 5. Shake' stopper' return to waterbath. Shake 2x more in remainder of 30 min. 6. Allow to cool .. . 7. Add 10 ml 20 8. Add 10.00 ml benzene . ' ' 9. Shake 10 minutes on mechanical shaker . 10. Remove AQ. lower layer 11, Add t^SO^ anhyd. to dry benzene fraction III. Dehydrochlorination < ` 1. Take 5 ml of benzene fraction 2. Add 5 mi benzene - 3. Add boiling chip , A, Add .25 ml DBU soln. (5% w'v in benzene) Aldrich 13,900-9 1,5 diazobicyclo (5,A,0) undec-5-ene "1 5. Place in boiling water bath until benzene is boiled off * 6. Rotate tube while cooling to remove traces of benzene IV. 1, Add 5 ml chromic acid reagent to tube (5 g. Ct-03 + 3 ml 1^0 + 60 ml CH3 C00!!.) 2. Stopper and place in water bath 75 - 80C for 10 min. 3. Cool in cold water . A, Add 20 ml I^O'swiri to mix . 5. Add 15.00 ml hexane - 6. Shake 1 minute or 5 minutes on mechanical shaker . 7, Withdraw lower AQ layer 8, Add 20 ml 1I20 DSW 028949 STLCOPCB4012911 9. Shako 20 eoc. 10. Withdraw AQ layer 11. Add'20 ml 1^0 12.' Shake 20 eec. 13. Withdraw AQ layer completely . . ' 14. Add Ha2 SO^ to dry hexane fraction '* ` V. Chromatograph on E.C.G.C. ' ' t< - * Fish samples are ground three times in a Hobart Food Chopper and thoroughly mixed in a Hobart Planetary Mixer. An accurately weighed sample of approximately 50 grams is then lyophilized. This freezedried material is then extracted in a Soxhlit Apparatus with hexane. DSW 028950 STLCOPCB4012912 I .r \ <. ifc ! i 4 \ 1 V i *i 'i 4` 3> O' I * OSW 028951 STLCOPCB4012913 $?cclgy Bate Collected SasllDouth bass 8/20/75 Ci'tretterus S/21/75 dohnifui .T.icc sucker (Co tos cemus :o--cr:cr.i) fello-o perch (Perea flavcscent) 8/20/75 8/21/75 8/20/75 8/21/75 Bate Analysis Reported 9/2/75 - Location Above Corinth f* 9/2/75. # 9/2/75 , Above Corinth Above Corinth Hudson River ?CB Analysis Results (AnaLysis by Rome Pollution Laboratory) lab. Albany Idcnt. Tdenc. 5s Hud Coasp 5 Tag Length Mo. finches) 9.1 9.2 Weight fPoundsl PPM as Aroclor 1242//016 PPM at Arocloz 1254 0.35 - --_0 0.37'--'' Trace Total PCB*s PPM BBT/ DC8 Trace X Oil Remarks Composite of 2 5s Hud Coap 4 5 s Kud Coop 1 5s Hud Coop 3 5 s Hud Comp 6 5 a Hud Comp 2 5s Hud 17 5s Hud 18 5 s Kud Comp 7 11.0 11.4 , 0.64 ----- ----0 0.70 ---- " 11.0 11.0 10.6 6.7 7.1 7.3 7.5 7.7 10.0 10.0 10.0 10.6 0.20 -- --- ;__j--1 0 0.22 ---' 0.44 0.45 0.43 0.55 ---r 0 14.6 18.5 6.7 6.9 7.1 7.1 7.1 1.47 3.02 0 .0 C. 16--------- ------,0 0.14 0.14 v 0.15 / , 0.16^ Trace .Trace Trace -Trace Trace Trace Trace Trace -Trace Trace Trace Trace Trace Trace Tract Trace Composite of 2 Composite of 3 Composite of 3 Composite of 2 Conpofite o ' Composite of 5 Ml . osw 028952 Species Cate Collected Saailaouth bass 7/24*23/75 (Hie rerterus d?' ierr; -ut) Walleye (Stito rt*dion vi Cretan 7/24-25/75 fellow perch c?-' rc a flc/esccns) * 7/24-25/75 >Tiite sucker rca tostoirjs cc.--erroni) 7/24-25/75 Cate Analysis Reported 8/11/75 8/11/75 8/11/75 * "** / .1 8/13/75 9/2/75 Hudson River ?C3 Analysis Results (Analysis by Ro=e Pollution laboratory) Location Lab. Albany Idcnr. tdonc. tag Length tto. (Inches} Veighc (pounds} PPM as -Aroclor ` 1242//016 PPM a* Aroclor 1254 Total ?CB * s IDT/ DC?, Above Clone Falls Above Ciena Fall* 3-Kud-73-up 4-Hud-75-up 5-ikid-75-up 6-;!ud-75-up 8-Kud-75-up 9*l!ud-75-up 7-Hud-75**up 10-Kud-75-up ll-Kud-75-up 12-Hud-75-up . . 2*Hud*75-up l-Hud-75-up 11.0 10.6 9.4 9.4 . 9.0 . 8.7 ' S'. 3 7.5 6.7 6.3 15.4 15.0 0.54 - 0` ' 0.46 0 0.35 0 0.31 0 0.30------- -- ^0 0.21 0.26 ^ 0.16------- --_-0 0.13 0.10 1.03 1.05 '0 0 Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace .' Trace . Trace . Trace - Trace . Trace Above Clans Falls Above . Glens Fall* Above Ciena Fa 1 Is ' 16-Hud-75-up 15-Hud-75-up 13-Stud-75-up 17-Hud-75-up 14-Hud-75-up 26-Hud-75-up 19-!iud-75-up 21-llud-75-up 22-Kud-75*up 18-Kud-75-u? ' ' 11.8 11.4 11.0 . 10.6 10.6 10.2 9.8 . 9.8 ' 9.0 7.9 41-Hud-75-up 42-Hud-75-up , 0.73 0.67 0.57 0.60 0.55 0.61 0.55 0.45 0.42 0.63 ' 0 0 0 0 0 0 . 0, 0 0 0 ,0 . 0 Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trice Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace Trace z on S marks Composite of 3 - t<, i Coaposice of 3 DSW 028953 STLCOPCB4012915 Walleye (Pci 7.ostedicn Vic re---.) Date Collected 9/13/75 Yellow perch (Peres f lavescens^ . 9/18/75 D (/> X. c IS) 00 %0 U1 .p- Late Analysis Resorted 10/1/75 * * . 10/1/75 1 \ Hudson River PCB Analysis Results (Analysis by Rene Pollution Laboratory) '. ' ' Lncacinrt Lab.- Albany i den g Trfonc. Taj Length No, (Inches) At Fort 4-Hud- Edvard RI-Coap below C.E. ' 3-HudSl-Coap 6R8286 6.4 6RS285 6.6 . 6R323S 6.7 6RS289 6.8 6R32S3 6.9 6R3284 ` 7.2 . 6R8280 7.1 6R8275 7.2 6R8282 7.5 6R6278 . 7.6 6R8276 7.8 6R8279 7.8 6RS277 8.0 v 6R82S1 8.3 5-Hud- ` 6R8291 10.7 RI-Coap 6R32S3 11.3 6RS292 11.3 . 6R3290 11.7 At Fort 6-Hud- Edward RI-Coap below 0.8. .. 6R675 6.8 6R3293 .6,8 . 6R8299 6.8 6R6S2 6.9 6R678 7.1 6RS295 7.2 . 6R8297 7.4 . . '6R608 7.4 6R8296 7.7 6R8294 7.8 Weight (Pounds') PPM as Aroclor _I2A2//016 PPM as Aroclor total 1254_______ PCB1 s ppM tot/ ECR 2, Oil Ec-ur>s 23.29 *132.50 2,81 4.25 Composite of 6 - vhole r'ish 81.12 41.30 .12'2',92* 7.05 5.52 Co=?osite of S * whole fish 8.31 * 18.19 0.96 - 1.80 Composite of 4 '. fish fillets 18.24 79.34 2.20 1.57 Composite of 10 *\ v </) HI- oO oo DO oU Is) (O i*fw O' i ipm kip'ii .t Hate e; Collected Soak bass ( 'rb i res rjeestri?) 7/24-25/75 Alcvife 7/24-25/75 (A 105 3 oseucoharenem) Date Analysis Resorted 8/13/75 8/13/75 Hudson River PCS Analysis Results (Analysis by Rome Pollution Laboratory) Location Lab. Albany Idont. Tdont. Tag Length Weight (Inches! fprtinds^ PPM as Aroclor 1242//016 Fort Edvard 56 Hud-75-DN -----below C.Z. 57 Kud-75-DS ----- - -- 27.35 P?X as Aroclor 1254 Total PCS's ; PPli D3T/ DC3 7. l, Oil Sc-.arVs Fort Edvard 55 Hud-75-DS below C.E. 20.35 4 O In SC o N) Oo >o U1 I w '--** y TT o \t i I "V o STLCOPCB4012917 Saerjef Yello~j Perch (Perea f iavescer-s) Date Collected 9/18/75 Date Analysis Reported 10/1/75 Hudson Rivor PCD Analysis Results (Analysis by Roee Pollution Laboratory) Location Ac Fort Edvard Lab. Tdcn.t, 8-HudRl-Comp Albany Tder.t. ^=S Length Weight Ho. (Inchcsl (Pounds') PPM as Aroclor 1212//016 236.42 PPM as Aroclor 125C Total ?r IDT/ 62.88 299.30 7.67 --,-y . 5.70 Conpeslte or 13 vholc fish; rot tarr.-d 7-RudRl-Conp O Co 9C O tv CO v0 Ut O' 128.33 24.27 152.60 3.84 3.98 Conpos'ce o 20 whole fish; not STLCOPCB4012918 Steeles White sucker cemrersoni ) Date Co 1 leered 9/18/75 '* Date Analysis aborted1 9/30/75 Hudson River ?C3 Analysis Results ' (Analysis by Rome Pollution Laboratory) Location Lab. Tder.C. Albany Idenc. Tag Length Weight *iO . (Inches) (Pounds) PPM as Aroclor 1242//016 PPM as Aroclor 1254 Total pea's PPM EOT/ PC?.' I Oil RfrmsrV.s Ac Pore Edward 1 KudRl-Coap 2 HudRl-Coap 6R8265 6R8267 6P.3266 6R3268 6RS274 6RS269 6R8272 6SS271 6R8273 11.6--------------------------ps-- 32.8a 13.1 13.2 14.2 7.8-------------------------- S. 1 8.1 8.5 8.6"^ / 8.83 43.57 ' 131.45 5.64 Cocposice of 4 2.72 * 11.55 0.41 " . * *. Conposit* of 5 O Co X o 00 *0 U1 >J iy> i--wj. .i.ueJi 11 i'::yw;w^1;'?* . O w1 STLCOPCB4012919 Species Sate ` Collected Snailnouth bass 7/28-29/75 Cliereocerus Bate Analysis Resorted location Hudson River PC3 Analysis Results (Analysis by Rose Pollution Laboratory) Lab. Albany Idcnt. Ident. Tag Length Veight No. (Inches! fPoumi.O PPM as ' Aroclor 1242/1016 PPK as Aroclor 12 54 Total PCB's DOV COT/ 0C3 X Oil 8/11/75 5 si. below 23-Kud-7S-DN Fort Eduard . 11.0 0.74 100.27 22.64 122.91 Va Ileye. (Stiro^tocJton vttreun) 7/28-29/75 . 8/11/75 5 ai. below 24-Hud-75-BS Fort Edward -cite sucker (Cato? cc-.us co--crsor.i) 7/28-29/75 8/13/75 5 sii. below Fort Edward 51-Kud-75-DN 43-Hud-75-DH 50-Kud-75-21I 54-Kud-75-DN 7/28-29/75 9/2/7S ' 5 ai. below 52-Hud-75-DN Fort Edward 49-Hud-75-DN 13.4 0.87 . 157.27 51.39 47.57 22.05 20.80 29.74 ' 28.03 20.74 8.86 ' 8.13 .178.01 4 ^ * - 38.60 36.16 D Co sc o IV 00 SO UO 05 t\ T*" STLCOPCB4012920 'w' ^ Sn-'ti ei Date Collected Ycilav perch . tl.-vcsccrs) 9/17/75 O t/> Dace Analysis Reported 9/Z6/75 Hudson River ?C3 Analysis Results (Analysis by Rose Pollution Laboratory) ' location Lab. Idenc. Albany Idcnt. Tag Length No. finches) 5 =iles 1 Kud-R- beiov Fore Cosp-9-18 Edward 6R78G1 6R7S02 6R7S04 6R7S07 6R7 SCO 6R7S03 ' 6.5 6.5 6.5 6.6 6.7 6.3 . 2-Hud R Cocp 9-18 6S73C6 6R7805 6R7309 7.5 7.6 7.7 Weight (Pounds) PPM as Aroclor 12i2//016 8 Eud-R Coap-9-18 P i PPM as Aroclor 125 18.95 Tota 1 ?C3*s ppv LOT/ 1X3 103.26 2.37 TilRpnvrk? 3.52 Caraposite of 6 whole fish 15.01 50.55 1.71 3.53 Composite of 3 34.21 122.39 3.90. 4.52 'Ccaposite of 20 1, ' whole tiih) not t tagged f. N; 00 vO ui l r vO I ftt Vallcye /Sfltostedion vjjcrcinr) *r 9/16/75 .9/17/75 9/29/75 9/29/75 5 Biles 6R699 below Fort 6R697 ` Edvard - 6X6,99 6R697 11.5 0.62 7.13 5.70 5.56 10.89 0.35 1.14 12.69 0.41 1.49 - * * ci f r l irr | i i STLCOPCB4012921 5oeics Date Collected Brovn bullhead (lot.ilervs n-!)';]cccs) 9/16/73 White seeker (Cn tostnr.us ccrrr^rsor.O 9/16/75 Date Analysis Renortcd 9/26/75 9/29/75 Hudson River ?C3 Analysis Results (Analysis by Rose Pollution Laboratory) Lob. Location ' Idor.t. Albany Ident. Tog Length NTo. (Inches Weight (Pounds) PPM as Aroclor 12&2//016 5 miles 3 Hud R below Ft. Comp 9-18 Edvard 6R66S 6R687 6R662 10.0 10.0 10.6 73.24 4 Kud R Comp 9-18 6R669 11.3 6R698 11.4 85.30 5 miles below Ft. Edward 7 Kud R Com? 9-18 * 6S6966R6S0 6R663 63.677 ' 10.2 10.7 10.9 11.0 36.03 6 Hud R Conp 9-18 . 6R694 63.683 13.0 13.8 78.00 5 Hud R Comp 9-18 6R691 6R6S1 14.0 14.5 57.54 PPM as Aroclor Total 1254_______ ?C3's PPM DDT/ DC3 X Oil 36.38 105.62 4.23 33.52 123.82 3.82 12.86 . 48;89 1.35 23.79 101.79 3.47 41.10 98.64 2.99 * e i Remarks Composite of 3 j Coaposice of 2 Composite of 4 . I' Composite of 2 Composite of 2 O Co X o N) CD 03 O' O uit"""-h rw STLCOPCB4012922 l Bate Collected La rgemauth bas* 5/17/75 (Mlcrcaterus ` s i j.ra ides ) 9 /17/75 American cel 9/17/75 (An-nit lln tostr.itn) Brown. bullhead . 9/17/75 (Tctslurus nebulosus) White auclccr 9/17/75 (Citestor.us coorre-rsont) 9/17/75 Date Analysis Reported 10/1/75 10/2/75 10/2/75 10/1/75 10/2/75 10/3/75 Hudson River ?C3 Analysis Results (Analysis by P.one Pollution laboratory) Location Lab. Albany Idcnt. Ideat. Stillwater 1 SVK-Comp ` 2 SWH-Conp 3 SWH-Com? Stillwater 4J2970 . 4J2956 Stillwater 4J3000 . 4J2975 Stillwater ' 4J2961 Tag Length Ma. (Inches) 4J2977 4J29S5 4J2972 4J2979 4J2971 4J296S 4J2974 4J29S4 4J2958 4J2957 4J2970 4J2956 4J3000 4J2975 4J2S61 12.4 12.9 5.7 5.9 6.0 6.2 3.4 4.2 5.2 5.6 9.6 7.7 17.0 32.0 9.0 Weight (Pound.O Stillwater .5 SWH-Comp 1 Stillwater 4 SWK-Com? 4J2969 4J2954 4J2990 4J2983 4J2964 4J2S80 7.0 7.2 7.6. 7.8 13.3 15.0 PPM as Arocior 12S2//016 24.35 PPM as Aroclor Total 1254_______ PCP.'s 15.97 40.82 PPM DDT/ DCA Z. Cll RenarVs 7.22 Composite of 2 9.54 24.15 4.09 Composite of 4 whole fish 6.99 15.98 2.4J Composite of 4 whale fish . 4.44 5.93 11.07 155.87 7.99 5.94 16.S4 20.89 22.25 559.25 12.65 0.'56 0.73 13.68 3.93 5.74 30.04 Very OiUy 3.2S ' 16.28 0.53 1.87 Compositeof 4 154.28 35.92 190.20 5.69 3.71 Composite of 2 O60 SC oN) 0D o & STLCOPCB4012923 sjj '-mJ Sn<*c f e* Sate Collected Srallnauch bass (Micrentcrus dolor-.: ui) 8/1/75 ' Chain pickerel (asox ni-rr) 8/1/75 Yello-a perch (Pcroa f Ijvescer.s) 8/1/75 White perch (Kntor.e aaericana) 8/1/75 D SE (v sC aPO Date Analysis Pcnorccd 8/11/75 Hudson River PC3 Analysis Results (Analysis by Rome Pollution Laboratory) . Lab. location______ Jdent. Albany Irene. Cacskill 26-Hud-4-75 Trib. 193 Taj Length Weight Ko. (Inches) fpounds) 11.4 1.01 ??>: as Aroclor i;i2//016 13.76 PPM as Aroclor 1254 Total PCB's PPM DPT/ DCS 7. CU Remark* 8/11/75 8/11/75 CatskLll 23-Hud-4-75 Trib. 193 Cacskill 28-H.ud-4.-75 Trib. 193 29-Hud-4-75 17.7 7.9 7.5 1.76 "8.63 4.13 Composite of 2 8/11/75 Cacskill Trib. 193 27-Hud- 4-75 32-Hud- 4-75 39-Hud- 4-75 40-Kud- 4-75 37-Hud- 4-75 36-Hua- 4-75 35-Hud- 4-75 33-Hud- 4-75 34-Hud- 4-75 32-Hud- 4-75 30-Hud- 4-75 31-Hud- 4-75 10.2 0.61 8.47, . Coaposite of 3 Composite of 3 Coaposite of 2 Coaposite of 3 ; ry ue- a.".- rq^^p.,i^iJT.111 'l ir vwii>y STLCOPCB4012924 Date Co'. I/*ete<3 Striped bass (Morrr.c s;s.' t i lus) 8/7/75 Largeaouth bass ' 8/7/75 * White perch fKorone oacrienna) ' , ' 8/7/75 Tel low perch (Perea f lavcseer.s) 5/22/75 Date Analysis Reorrccd ' 7.ocnti on Hudson River PC3 Analysis Results (Analysis by Ro=c Pollution Laboratory) Lab. Albany Irfont. Tdont. Tag Length Weight Mo. /Inches) ('Pounds) PPM as Aroc lor 1242//016 9/2/75 Mouth of Rondout Creek 21219 2D218 21219 2D218 10.4 20.4 0.44 3.23 '0 0 9/2/75 ' Mouth of. Rondouc Creek 2D241 2D238 21242 ' ' 2D241 11.6 2D238 12 ..2 2D242 13.7 . 2D237 15.7 2D236 2D240 15.7 17.7 9/12/75 ' Mouth of Rondout Creek Hud-RCoop LA Kud-RConp 2A * 2D223 2D233 2D230 21220 2D226 2D228 21231 21234 8.8 9.0 9.3 9.5 7.4 7.4 7.5 7.8 0.96 1.06 . 1.41 2.33 2.50 3.67. 0 0 0 .0 0 0 9/15/75 Mouth of Rondout Creek Hud-RCoop 4A . 2C849 8 ` 8.6 2C8496 8.7 21212 8.8 . 21210 8.9 21211 9.0 0.242 0.324 o.m 0.242 0.326 0 PPM as Aroc lor 1254 Total ?C3's PPM DDT/ -c?, 4.08 7.01 '4.03 0.49 7.01 1.37 1.73 4.87 7.65 3.71 3.37 8.52 1.73 4.87 7,65 3.7'.' ' 3.37 8.52 0.38 0.40 0.89 0.87 0.79 .1.13 7.45 7.45 1.70 8.12 ` 8.12 1.60 5.28 5.28 1.08 X Oil Rcro.TrVr5 Cocposice of 4 8.22 Coaposizt of 4 Cosposice of 5 DSW 028963 STLCOPCB4012925 T 1 U P'M'ip I 'O i wr**" . . Seecies ' Dace Collected Largesouth bass (Micro otcrus s i I-aides) 8/6/75 '-"hits parch arerlcar.a) 8/6/75 American eel (Anrullla rostrate) 8/6/75 Striped bass (Moron e seratllus) Cute perch (Mar: re :.?ori c.-.no) 8/8/75 ' 8/3/75 Date Analysis Reported 8/22/75 8/22/75 8/22/75 9/12/75 ', 9/12/75 Hudson River PCB Analysis Results (Analysis by Rome Pollution Laboratory) Location Lab. leant. Albany Tdert. Tag Length Weight Mo. (Inches! (Pounds} Mouth of Wappingers Creek 2C3402 2C8417 2C3408 2C3402 2C3417 2C8408 12.5 .14.1 19.0 Mouth of Wappingers Creek 2C8449 6.0___ _ . 2C8426 6.3 ' 2C8423 6.4 2C8439 6.6 2C8409 7.0 2C8429 7.0*'"''^ Mouth of Wappingers Creek 2C8472 2C8487 2C3469 11.3--___ 11.4 11.7--------- ` 2CS670 14.3 _____ 2CS486 14.4 . 2C34S4 ------------------- - * 2C8483 2C8483 17.0 2C3451 2C8451 26.9 Mouth of Esopu* Creek 2D24 2D24 14.2 0.94 PPM as . PPM as Aroc lor Aroc lor 1242//016 1254 Total PCB's 19.7310.73 17.99 4.Cl 3.35 5.19 , *23.74 14. OS 23.18 PPM DDT/ DC." Z .. Oil Remark? ~15.74 -13.36 -41.69 123.61 14.11 0 4.14 19.88 * Composite of 6 3.00 16.36 .. * Composite of 3 10.42 52,11 Composite of 3 53.64 4.84 6.62 177.25 13.95 6.62 >27.0 0.86 4.95 Mouth of Ssopus Creek Kud R-Comp 3A 2D42 . 2D43 ' 2D44 2D47 6.5 . 0.15-~>_ 6.5 0.17 6.6 0.15 6.6 , 0.17^ >0 9.65 9.65 1.39 Composite Of 4 OSW 028964 ! iAC i enp ft ;wn ""CA"? / [ m*y9'w I- STLCOPCB4012926 'V**- STLCOPCB4012927 ., S~c{c ' Dace Collected American shad (r I *> s 3 saoldt-siaa) 5/22/73 5/22/73 5/22/73 5/22/73 O CO SC o fSJ CO vO O' Ul Date Analysis Pooorted 9/13/75 9/23/75 9/12/75 10/1/75 >. Hudson Hive? PCS Analysis Results (Analysis by Roce Pollution laboratory) Location !<<a b Albany Idcnt.* Icont. Teg length Weight No. finches') (Pounds) Xir.gstonRhir.cc lif f Bridge ' . 2CS363 2C8369 2CS370 2CS353 2Co366 2C3364 2CS556 2C8354 2CS365 2CS355 KingstonRhinecliff Bridge 2CS371 2C3372 KingstonRhinecliff Bridge 2C8367 Kingston- Rhinecliff 3ridgc . . ` 2C8363 19.5 2CS369 20.0 2CS370 20.0 2CS353 20.0 2C3366 . 20.3 2C8364- 21.0 2C335S 21.. 2 2C8354 21.5 2C3365 22.0 2C8355 24.0 2CS371 2O.0' 2C8372 21.5 2C8367 21.0 2.13 2.32 3.04 3.17 2.88 3.23 3.39 4.07 4.20 4.82 3.30 3.37 3.19 21.0 .* 3.10 ., PPM as Aroclor 1242//016 p?n as Aroclor 1254 Total PC?.' s Trace Ti ace Trace Trace Trace Trace Trace Trace Trace Trace 2.52 6.91 5.29 2.933.83 3.23 39.56 38.14 7.78 19.35 . 2.52 6.91 5.29 2.98 3.33 3.23 39.56 33.14 . 7.73 19.35 22.91 53.13 ' Trace 22.91 9.22 67.35 - Trace 6.40 6.40 23.40 9.68 33.08 ` PPM BBT/ PC3 X , on ?C?t37>. 5 0.57 1.50 1.49 0.39 0.90 0.77* 4.41 4.24 1.60 2.99 *, * j ( , J..32 3.52 , : J *1 *. 1 0.65 Oil far'* and chic ! ' .j - li< 7TT" Ll.t 1i t V i } \ cc I STLCOPCB4012928 \ . . iped bass rr r.* "tiles) Dote Co H ret* (5 May 1975 * '. Date Analysis 7/24/75 Hudson P.lver PC3 Analysis Results (Analysis by Rose Pollution Laboratory) Lrcnelcn bb. Idcnc, Albany Tdcnc. Tappan Zee Bridge 206 259 256 254 269 1 NT Tag Length Ncigbc No. /Inches) /Rounds) 22.3 5.98 24.4 7.03 24.3 6.80 32.6 14.74 37.4 20.24 37.8 21.12 PPM as Aroclor 1242//016 P?M as Aroclor 1354 Tot o 1 ?evs PPM LOT/ ' 7. u*n 37. SO . 4.39 13.56 6.75 1.52 7.12 7.53 3.25 * 1.69 5.36 0.98 5.53 6.53 2.07 5.41 3.86 1.39 J 5.6; .. i'. . .. A* I * Date r< ft____________Collm ted ebacfc herring 4/27/75 estiva li<) icon shid S3 Idossioa) 4/27/75 back herring S3 tivalis) .4/27/75 Analysis K'-onrcerf Location Hadson River ?C2 Analysis Results (Analysis by Rome ?oliucior. Laboratory) Lab. Idonc. Albany Idonc. Tag Ko. Length (Inchesl ??:; as Weight Aroclor fRo'inds)________ i:C2//0lfi 9/24/75 1 mile below Kud-R-KS Ceorgo Wash- Coop 1 ir.gtor. 3ridge 9/24/75 1 mile above' Hud-SH Cedrge Wash- Coop 1 ington Bridge . 1 mile above F.ud-SH Kingston-Rhine- Comp 2 cliff Bridge .. . , _ . ' . ' 0' 0 0 10/2/75 1 mile belou . Ccorge Wash . ington Bridge 0.32 V t. ??X as Aroclor list .5.13 Total ??;: TLT/ X - \ pc?. * s rc? *>"*-" T/t 5 "........ ... ' ' *................. *.................. .............. * 'll! X 5.13 C.25 13.11 Composite of 2 : ets obtained from anglers \ 1.S3 1.56 0.52 1,33 1.56 0.84 C.30 ^19.83 Composite of 5 fillets obtained from anglers ' 0.59 0.7 3.93 Composite of 3 fillets obtained from anglers 1.64 Roe * f i f X 1 1 \ r ? o co sc o M 00 vC O' vJ . | n r J n 4' |yu.i. w/. STLCOPCB4012929 W- APPENDIX E Regional Reports on Sampling OSW 028968 STLCOPCB4012930 FISH COLLECTIONS TAKEN IN THE HUDSON RIVER.FOR PCD ANALYSIS BY REGION 4 FISHERIES STAFF Fish collections were taken for PCB analysis by Region 4 staff at three locations in the Hudson River. Dates of collection and sampling method; identification; processing and transportation of samples are dis cussed below. In all cases, fish samples were taken under the direction of the Regional Fisheries -Manager. _ . Catskill Fish listed in Appendix 1 were collected on August 1 , 1975 with 230 V-DC boat electro-fishing gear near Catskill, N.Y. at the location shown on the Appendix 2 map. Fish collected were placed in plastic bags (no more than 6 fish per bag) and a tag listing species, date and location of collec tion was affixed to each bag. The samples were placed in a cooler with ice and transported to the Stamford, N.Y. Region 4_office and stored in a freezer. On August 4, 1975, the samples were picked up by a representative from the DEC laboratory facility at Rome, N.Y. and transported from Stamford to the Rome laboratory. Coxsackie `. Fish listed in Appendix 3 were collected on September 5, 1975 with 230 V-DC boat electro-fishing gear near Coxsackie, N.Y. at the location shown on the Appendix 4 map. Each fish collected for PCB analysis was weighed, measured and tagged with a numbered tag. Fish were then placed in plastic bags (no more than 6 fish per hag) and a tag listing the species, date and location of collection was affixed to each bag. The samples v/ere then placed in a cooler with ice and transported to the Stamford, N.Y. Region 4 'office and stored in a' freezer. On September 8, 1975 the samples were trans ported from Stamford to the DEC office facility at Delmar, New York where the fish were received by Dr. Stone. Stillwater ' . Fish listed in Appendix 5 were collected on September 17, 1975 with 230 V-DC boat electro-fishing gear near Stillwater, N.Y. at the location shown on the Appendix 6 map. Each fish collected for PCB analysis v/as weighed, measured and togged with a numbered tag. Fish were then placed in plastic bags (no more than 6 fish per bag) and a tag'listing the species, date and .location of collection was affixed to each bag. The samples were then placed in a cooler with ice and transported to the Stamford, N.Y. 'Region 4 office where the fish were stored in a freezer over night. On September 18, 1975, fish listed in Part I of Appendix 5 were traoported to the DEC Central Office in Albany, N.Y. where the fish were received by Larry Skinner. .. 9/29/75 . ' -' ,` 2--J^ Russell D. Ffeldhouse Regional Fisheries Manager DSW 028969 STLCOPCB4012931 Appendix l. Fish collected for PCB analysis in the Hudson ' River near Catskill, N.Y. . , Species Largemouth bass Smalltnouth bass Fhain pickerel f Stri1p1 ed basIIs WhiItIe pe IrIch 11 . II I.I 4 II II II H II M II II II II II II II II II II . . Yelllo( w pelrlch . White sucker l 11 tc . tt ' . length (Inches) 11.6" Weight (Pounds) 1# 1 oz. ' .7 *3 19.3 5 oz. Vi 14 oz. 8.5 4.5 oz. 8.4 3.5 oz. 11.1 10.3 8.7 8.4 8.3 7.9 7.5 7.1 6.8 6.5 6.0 5.6 ' '/ 10 oz. 7 oz. 6 oz. 5 oz. 5 oz. 4 oz. 4 oz. 3 oz. 3 oz. 3 oz. 2 oz. 2 oz. 7.5 7.7 3.5 oz. . 3.5 oz. 16.1 14.7 13.1 VI 9 V! 4 1H ` oz. cc. OSW 028970 STLCOPCB4012932 ^ . :^r ; /' .>r v':-.s ,V tS.,,',1..'..< "1.''^ ' ' 1 Appendix 2: .Map rdiuwimi in red the Hudson River sampling locations near f.atsi'.m, M.Y. From 7.5 minute Hudson 5ouUi Quadrangle. *. *;: //* * | . v-->/ 7 ft ^ .-X-A' t * * .*' ! * * ; .* .H>rvN/*; /^ / .VV./vA /y'' 4' ,t 1 ^ t>*-" 1 T` .,L' ' V V;J *A ? i ' -,7.- v. ,?'/*. / /. ,. / tKi^i n.i V. - h ! \*.r`;;\ i:7sii\\i..r!,..-/.r.*.rrt.v....< c;.*. "* *7 #.y! t, v / - Q^ < i Rogers - / i *' K*ti . . J / / ' /'Jr i #','7.,V /,, M. ..- ii/;! ;i // ;. /./`I /.n :?. , vI <, ^:;!; ! . :5'; ' A/ . S, J - ?'/ L,H:v'// .l-v / , l\! ; -' ' :,( b[J 7 'i.vv \: V i,-. . ,7 ' ;' / > . 1 \' 9J :v`7* V.\-iVv:. .-oh 7 t 7 a " . ` 7 * - ( '.n-vv .\ Uv-k- ...4f n..* - `7{ - ( I `V A ' .* v / 1*' r - , : 1 I i- V./ * * *'. * '.I'-'** \v, a J *. *. ** . *V M" .7.. 'rtv)r.V :U'\ ^ ^ )SK. U ,Vi;;. 's. v 1 *Z::'Sk a. \V r:r,':r/> : v.\ a /' > vV 7:. / /; : \ , ` v- .*.-V ./u , . (.J. ! . .* 'V^/ v - . * - \ . Tnf.l i'i.ll _ ...... . .f,-: ' rj,..f'rrQ : , 11 Vv u !' 1. / 1 'I r^ :. i ' ..///"/ - A 'V'V f.i ' . -.7;;' ` 7 . 1f> ii: r::< /'a--/I '.> \ 1 ' ! / V//7si ;Vvv:' )' 1 .'/i V^7, 1 / Vi:,''/ *> 0 /7, ' : Vi 7/i '^/;.7' i ////I} `AM!Vi.t "" *: 7 ' 0. ** / /`-l-c! :-l\ hr % ! /'Hf? kl:i//li lV. I i r/J : \ '7 '/ !' ' ' r' l;7 j/tv -.!/ vv i I ; / \.7.1' ,777\v'' 7! / \i {' 11 . ... . / I'1 j. vI \ ; i >: . ' ' /| iI : r- I .U** tf * :4-A J 7*V / 7 ; .. r-lr - ? r 7j` . Nti> V4V ? r.f' ' 7 ! >. i ' 1): , r-: . v 4 i r' / t \ ' / a. A ./ ' /. 7r7*VT7|rn.'tHlrl> iyfeI - !\-7(/ . 7-'v>.:M'^|.-/(V\ : ! 1. X* DSW / T'"- J. 028971 7 STLCOPCB4012933 Appendix 3. Fish collected for PCD analysis in the Hudson River near Coxsackie, N.Y. , . Species Largemouth bass It It n it ii ii nn it n 'ii it n i . Tag No. 4K 4685 4677 ' 4678 4670 4681 4672 4689 4698 Striped Cass It M II It It II II -11 , 4K 4692 4695 4675 4671 4669 American eel It II It It It II 4K 4667 4686 4699 4657 White perch MH 4K 4683 . 4696 White sucker It tt ' it n t it it 4K 4679 4662 4661 4666 4655 Lenqth (Inches) Weight (Pounds) . . 15.6" 15.1 14.9 14.2 13.7 13.5 11.0 6.2 29 29 29 29 'll 1# 7 oz. 2 oz. 3 oz. 2 oz. 7 oz. 4 oz. 12 oz. 2 oz. 11.1 8.5 7.8 6.4 5.7 8 oz. 3 oz. 3 oz. 2 oz. 1 oz. 25.5 21.5 19.0 16.5 9.5' ` 8.5 1// 14 oz. 15 oz. 9 oz. 6 oz. 7 oz. 4 OZ. 16.9 15.7 . 14.8 14.3 13.8 Iff Iff Iff Iff Iff 12 oz. 11 oz. . 5 oz. 3 oz. 0 oz. DSW 028972 STLCOPCB4012934 ,< ' i t - >'' ii ii ,`v' i?1 Appendix 4: Hap showing In red the Hudson River sar-spling locations near Coxsacl'ic, N.Y. .from 7.5 minute Hudson North anti Ravoiu Quadrangles. / \. r*\ ! / I , ># -V/- \ 0 .. : / i if : / - ; / n ' ;*v* :- ^ X. <' }/,~pi h! :' ' v W.C.* 'O . ttVAf y:'/ . ; / /.v ' - ' /'/ / / !;" . I` r;vr' / , ' / / ; / 4. ^ v, .yyv'..--- 1 . 7 f# s?M IV 'fv.sr.. *--H k ! ) i ) /,iV.V>.h'A'//. --.11 !/t ;| / * , / . C.* v: *!r#, <yp*: ;% / 'll7*'/ * . -,:riI \/ - i 7 1 . * ' / % / *'f ( .. Hit ' . ?t!/1/ : Jj | > A /* , IU; t.i / m/ * ;j.< : v4 )* '** / Cr>'* ? :: ' ; / I. ' II I!1 ,( ' \ hi. / ' ; (!\l ' . ' !.s \x : h ./iJ '' ------- 7~ . fi ; _--v.,`yV' 'T'f'Uc\ ' 'Vyr-^e ;s;-. I* . Wti > 1 '1 4( :.! // itj -n io '|i , < ] :f. /i7; e i!*yAyv a * *.* '^y **, s ' a . " ,*'(,' i( i-*i'i f/ yp-r ..>f. id.'?A' .* IA,^'f, -.1 i ; i ' * t,r ' * .^/\v igw 'S! y !<: J t V... . * >\\V' V I; .\ d i/f saw ' \ >\. vtV.' ' 7 \ ; '! / \ ; \m(' a> -v E / \ cC,v**-.vi..'..^X..2s..s.;.VvVv ^ -TC-i-l'/ ;' 'yr*-.i..'.T'Ji .\\\ '.vv://oo ' :: 4VI'.--,fV4 ;V*M ;;> .:V Si/- g.UKtjii ' - >i : : 1 ! v, ; j.w " ; ' ' fi! / '\-uirttAil.rl,s Vi;.-*'? '< > ii-; ''< \ , hl.v,lm,,J -A- V%!<`vX-'V \ . : sV>;i rj . " ^\'. \ i > '."f 'A..v-,..,-:,\.`P 1 ' , !>.*!/!.:/,(( ; < I*'-;, /.x\ v x^- ) x ' di'b ., \\ i w:x \CTOsalAioV...,,,j;.v};X4 m((, \j. |V"ty.-- -.,Kk /\ iVXX \\v \ 9 (ttl V|/::;7/V .7 \ I ? i- t /./ r)l' ' ' ,I.XL / 'a.': `J 'A ; rv.. ,i: ' A.. ,,M y * Vie-' 1 '<' \ *a- . j-tifi o i! \ i1'),! . ! '1- >X.Y *v' i ./ . \u\ v\ \V\ '/ 17.y-\ i/ i V.'!VSXyytiit.heM l.1 Xy / ^ 'Mir <A.Wj.t reitbl.l'fr,:.,..,.y' ;I y.' ... .j ..... -7 * / *A / | i \ i Xy* -,'.-iX#"i i1; 7tj'",j/f XI! i 1 'TV> ' ai.XV; V V) ' r. .!A' < ,-v*i *k-7f'( ' y /- ! yi:Ut ' .v\Mt/ Mti,' \ ' \ I / (;ft f7 0 v ''.,Xt -t i : X -:vV r.- l - }! -m' A \ i \ < 'I .' - \.V \I n/v\''. (/iI {.' 1v/t \\'u*r ! !'' i: , / 4 . v'1 yt.n. .* :'tr!- 7'yiV.V;':w.. V A , '/lln1l` :..'lnn\, ''.,1\'A**-.c.-,,r."d.\1 ''. \'\ Piyi l Xv :..f/ X('i, ji * i XV V - \ `OSW 028973 ,* \: \> STLCOPCB4012935 Appendix 5. Fish collected for PCD analysis in the Hudson River near Stillwater, N.Y. PART I Species LargeIImouth basu s N ' It H |l II II ft II II II II II II ll II It (1 M . II II . Tag No. 4J 2977 . 2985 2956 2970 2965 . 2957 2979 ' 2972 2974 2971 2958 2904 AmerIiIcan eIeI l 4J 2975 300.0 Broliwn bullIhI ead. M H. II II . 40 2961 2993 2963 2952 WhIIite sulcl ker II ll II ii l ll ll . II It It 4J 2980 2964 . 2983 2990 2954 2969 2951 PART II .' Northern pike Blallck crapli pie 40 2966 40 2999 2962 Length (Inches) 12.4" 12.9 7.7 9.6 6.2 5.6 5.9 5.7 3.4 6.0 5.2 4.2 . Weight (Pounds) li? 6 1/2 oz. ll? 8 1/2 oz. 5 1/2 oz. 9 oz. 2 1/2 oz. 2 oz. 2 1/2 oz. 2 oz. 1/2 oz. 1 1/2 oz. 1 1/2 oz. 1 oz. 32" 3i? 2 oz. 17 5 oz. 9.0" 6.4 3.8 3.5 15.o' 13.3 7.8 7.6 7.2 7.0 3.9 5 1/2 oz. 2 oz. 1/2 oz. 1/2 oz. 1// 10 oz. 1H 0 oz. . * 4 oz. 3 oz. 3 oz. 2 1/2 oz. 1/2 oz. 13.7 8.3 8.0 8 1/2 oz. 6 oz. 4 oz. OSW 028974 STLCOPCB4012936 Appendix 5. Fish collected for PCB analysis in the Hudson River near Stillwater, N.Y. . . PART II Con't. Species CaIrIp ti II II II VI II II II ll II Tag No. 4J 2976 2994 ' 2953 2991 2973 2992 . 2996 2982 2997 2988 2955 2960 length (Inches) 18.8" 19.7 9.5 9.4 8.1 8.7 9.6 5.2 7.4 9.6 6.5 '5.5 Weight (Pounds) 38 11 oz. 48 t 0 oz. 13 1/2 oz. 12 oz. 7 oz. 11 oz. 12 oz. 2 oz. 5 1/2 oz. 11 1/2 oz. 4 oz. 2 1/2 oz. DSW 028975 STLCOPCB4012937 STLCOPCB4012938 New York Slate Department of Environmental Conservation MEMORANDUM John Spagnoli , i-komi , Hichncl Gann `,, JUBJECTi Hudson River fish collections for PCB analysis in Region 3. DATEi September 29, 1975 I. General Information, Under the direction of Regional fisheries Manager, William H, Kelly, collections of fish were taken from the Hudson River at various locations for PCB analysis. The field collection crew was under the direct supervision of Michael Gann, Conservation Biologist, Region 3. Specific locations of collecting stations are shown as shaded areas on xerox copies of appropriate USGS 7 1/2 minute quadrangles. Gear used in these collections in cluded a 230 volt AC boat electroshocker, and a 150' X 11/2" mesh gill net. Upon capture, fish were placed in plastic tubs and transported live to the fisheries labor atory at the. Region 3 office in Hew Paltz. After total .length data was obtained, the fish were tagged with in . dividual serialized.metal jaw tags, wrapped in either aluminum foil or plastic bags and frozen. Collections were transported, in coolers, from the Region 3 office to Albany, Delmar or the Rome fish lab, with applicable data sheets attached to each shipment. Various fisheries personnel were responsible for delivering the collections, under the direction of William Kelly on arrangements made with Hr. Spagnoli, . 11 . Collection Station Information. Mouth of Wappingers Creek 1. Date of collection : August 6, 1975 ' 2. Method of collection : 230 VAC boat shocker 3. .Method of packaging : Aluminum foil, ' Vanderburgh Cove 1. Date of collection I August 6, 1975 2. Method of collection : 150' X 1 1/2" 3. Method of packaging ; Aluminum foil. mesh gill net Mouth .of Rondout Creek (below Lddyville dam) ' 1. Date of collection t August 7, 1975 2. Method of collection : 230 VAC boat- shocker 3. Method of packaging : Plastic bags, ' OSW 028977 STLCOPCB4012939 John Spagnoli Pago 2 . c September 29, 1975 Rondout Creek nt Bloomington (above Eddyville dam) 1. Date of collection : August 18, 1975 2. Method of collection : 230 VAC boat shocker 3. Method of packaging : Plastic bags. . Mouth of Esopus Creek (below falls at Saugorties) 1. Date of collection : August 8, 1975 ' 2. Method of collection : 230 VAC boat shocker 3. Method of packaging : Plastic bags. . Hudson P.iver at H. Tivoli Bay 1. Date of collection : August 8, 1975 2. Method of collection : 230 VAC boat shocker 3. Method of packaging ; Plastic bags. Mouth of Moodna Creek 1. Date of collection : August 11, 1975 ' 2. Method of collection, : 230 VAC boat shocker 3. Method of packaging : Plastic bags. Ill, Miscellaneous Collections. ,, On August 0 , 1975 a total of .35 blue claw crabs were collected by means of direct contact with crab fishermen. . George Haug, seasofial technician, collected these samples from the following sites: (1) railroad bridges at Iona " Island, (2) railroad bridge at Annsville Creek, (3) U.S. route 9 bridge at Annsville Creek and, (4) piers 1 at Verplanck, These crabs were labeled as a total collection, placed in plastic bags and frozen at the Region 3 Fisheries Lab, Hudson River Sloop Restoration, Inc., headquartered in Poughkeepsie, donated a collection of fish from the ' Hudson, which were picked up at their office on September 8, 1975 by Michael Gann, These fish were frozen and packaged in plastic bags. They were transported to the Region 3 fisheries lab, where paper tags were written and placed in each individual package of fish. . Senior Tish and Wildlife Technician, Robert Bard, submitted an Atlantic sturgeon, found dead off Popolopen Creek, on August 14, 1975. The fish was transported by Mr. Bard to the Regional Fisheries Lab, tagged, wrapped in a plastic bag, nnd frozen. ' Commercial fisherman, Mr, Emil Tuchudin , submitted a sample of American shad, shad roe and herring, taken from the Hudson, in the vicinity of the Mid-Hudson Bridge, on DSW 028978 STLCOPCB4012940 John Spncnli Page 3 September 29, 1975 Hay 10 , 1975. The sample was brought in by Mr; "Tschudin on August 20, 1975, A paper tag was attached to the entire collection and it was frozen. IV. Attachments, - 1. Copies of raw data sheets on all Hudson River fish collections for PCB analysis, indicating location, . date of collection, species, length and tag number, 2. Xerox copies of appropriate USGS 7 1/2' quad maps showing specific sampling areas, Sample locations are indicated by dark outline and cross-hatching, A label appears on each map indicating the title of the map., name of sample station and date .of collection, Submitted MCG:db Attach. ./ Hicbae 1 C, Gann Conservation Biologist Region 3 DSW 028979 STLCOPCB4012941 3lo CLAuJ C&8S '{ tfUDSotJ.P. i .' G NO. ' 5 STATE OF NEW YORK,.., - - INTERDEPARTMENTAL MERCURY ANALYSIS REPORT - . Report cf M-^eurty Content In $ Laboratory Making. Analysis ba & j. Analytical Method-< Analyzed Ey___________Report Date (See instructions on Reverse) LAB NO. "ORIGIN DATE TAKEN SPECIES | SEX | LENGTH Hg.- WT. PPM ** ; REMARKS * SUBMITTED Q C 0>kl ~ r>rtV>.\\ zt 'z hf* #' p (}^:Jx U. rlif.:'1 ~/.',r v, {Ip Cx), NhIk V N't r-.W l 9-X V * c-L.* t. iv-.vcrsU U v r. l f1 ....... f s. \ t it *i' . I! f *9. ' ** fO < I a </> Ofw CD *0 1-- CO o i *- | **Data from additional analysis 2s follows. | | ~ror/)L 3S- ot/ep Hu&sctJ CcJ3 STATE OF NEW YORK INTERDEPARTMENTAL MERCURY ANALYSIS REPORT Report cf h'rcury Content In Laboratory Making-Analysis 3 NO. 'Wc3 . 0<J . CS" ob ' n Analytical Method;Analyzed By Report Date (See instructions on Reverse)__________________________________________________________________________________________ _ LA3 NO. ORIGIN r. / &T lOyff/y<rss DATE TAKEN P-Pr > * SPECIES Carp SEX LENGTH WT. -- <20,3* -- Hg. PPM ** j REMARKS ! SUBMITTED ' Carp ^3 - P3. $ - 1' [' : 7 Crrp r- 2,6 | j ' ...... LCXjo oMCvOOOD ...................... 11 ' 1 i ' **Data from additional analysis as follows. !! l /oTAC - 5 O/f/TE SOCK^/Z ' y^o STATE OF NEW YORK, , - - ETCERDEPARTMENTAL ^SSCSRT ANALYSIS REPORT Report of h'rcury Content In__________ Laboratry Malcing Analysis 3 NO. <0/ /3 Analytical Method________ Analyzed 5y.Report Date (See instructions on Reverse)' DATE Lab no. origin r , . . TAKEN SPECIES fil(X.tl!L yrl iOsfjctin&rf \ Cye-cfc. ' zhhs Uj, Shc^p^ SEX LENGTH /6,'ZT ________ _ Hg- WT. PrM -- (M, Su-t-U-t^ - . /*/ 7 -- 1 ' " Mte tit REMARKS SUBMITTED \ t1 " . , . | 1 ! osw 1 No oo o !0\J0 .... **Data from additional analysis as follows. 1 .......... 1 1 J J lOTfi-/- - j 1 1 es-s~f s5T^7?-/?&/'j Ho^so/J PcB STATS OF NEW YORK , - - INTERDEPARTMENTAL M3EHEY ANALYSIS REPORT Report of !> rcury Content InLaboratory Making Analysis 3N0.I ?LhA 2l\ 4A 4L! so << Si f-s <5 Analytical MethodAnalyzed By Report Date (See instructions on Reverse).______________________________________________________________ ,LAB NO. ORIGIN .. jjlc+Cf/l iOcffri-r?'}*AS . . rretk f/ r .... . _ DATE TAKEN v j/*iS~ SPECIES Tbs /?A55 Kg. SEX LENGTH KT. PPM - t4\- 6>4 - /las ~~ SSf Tbs -- 7<0 -- Tbs -- . s.ar -- \ ass L4 - ass -- - KcsDor BBS ' -- >4 -- O Bes - 4$ -- IV sOCD ass . - C.S~ - U> ' ' ** REMARKS . DATE SUBMITTED * :! I| STLCOPCB4012945 **Data from additional analysis as follows. 1i TOTAL /A I i Pom PF//JSFBX> SunF/s/f /4u'T>o/J gl . P^B> STATS OF MEW Y0?K#s, - - INTERDEPARTMENTAL MEEGcRY ANALYSIS REPORT ' Report of K *rcuxy Content In________________ _____________ Laboratory Making Analysis . Analytical Method (See instructions on Reverse) AG MO. LA3 NO. ORIGIN r . - 4n >. Cz-e^A. ^ - s4 SI t-o 6/ 43 44 4^ Mill . ......... o(/) *. (M 03 vO CD _________________ Analyzed ByReport Bate ___________________________________________ " BATE j TAKEN | SPECIES HgSEX LENGTH WT. PFM HATE ** REMARKS SUBMITTED r/i-p\' li i pks Pps .-- -- S.X .? -- Pks -- LI - ,,| i Pks i ?KS - s,i C,S~ - PKS - 67/ - PKS PKS PKS - L! -- - pK - - FI - |' - 1 ! iii i i i i .... i 1 iI i .i i 1 : ! '. | i ! . **Data from additional analysis as follows. /OT/tL - f STLCOPCB4012946 EloZG/l-l. SauF/stf H-O&SokJ k!iUtzL. 8 Pcb> STATE OF NEW YOPK.., - - .INTERDEPARTMENTAL MER65JRY ANALYSIS REPORT Report of hi'rcury Content InLa borat cry Making Analysis_ AG NO. cV/f 45 . Analytical MethodAnalyzed Ey__ Report Date (See instructions on Reverse)___________________________________________________ LAB NO. ORIGIN ,, . . jno^crli or Cr<r<r/c: Sate TAKEN S/b/lS - SPECIES 3&S KgSEX LENGTH WT. PPM -- .! - ` j 3GS 6'7 * - .______________ . ** * REMARKS DATE SUBMITTED B&S Q&S 1 - 7.0 - -- s,c - 1 \ \ 1\ * .\ o ' V9 : o r\j CD *) 03 U> . .i 1 1 ! i ' i i l j. _ i\ **Data frcoi additional analysis as follows. j 41t /<D/A 5 . rB/ZC/-/ '' STATE OF NSW YORK ,, - - INTSRDS?AFT:-iSNTAL MERCURY ANALYSIS REPORT Report ox h'rcury Content In Laboratory Making Analysis. HVDSafJ Ritss/Z^ _ fOTflrL HuVsofJ PCD ' STATE OF NEW YORK..., - - INTERDEPARTMENTAL KESSSRY ANALYSIS REPORT Report of >. Tcury Content InLaboratory Making Analysis fetuBkL TAG NO. 70 ' 12. 7& 19 $3 2<4 37 ... Analytical Method ' Analyzed By Report Date (See instructions on Reverse) _____________________________________ ________________________________________________ Date -T%r... . LAB NO- ORIGIN ... TAKEN SPECIES SEX LENGTH WT. PFM ** REMARKS fihuUl ej~ LUz}pictr$ ) / , CretL, * r 1 war - MB/ - ` DATE SUBMITTED * * . - Be/' ,, -. ) t:e / < // 7 - /^/ 3 - l\1r .. 1 jfcg/ - ... // 5 -. &./ - is, j -. . O -. to , o' s '' i eo i Be/ B-eJ Be/ ! &/ ! e.f ! iS?/ ; j *t -- IZO -- -- 10.6 - 17.0 - fS.2- -- - tf.lo - 14.4 -- -- tt.4 - * . ' : 1 J STLCOPCB4012949 1 'I 1 ! **Data free: additional analysis as follows. ' TOTfiL. 'T'X iirl*Mr ii i irtm riiitiii n tUrflTE PEECM '' ' ffc.3 STilTE OF MEW YORK- INTERDEPARTMENTAL-MERtroRY ANALYSIS REPORT Report of h *rcury Content In.____________________ -Laboratory Making Analysls_ HvtXcu Ptvf<L \Cr .\'0. . ` ' Analytical Method (See instructions on Reverse) ~ .. 1 DATE ' LA3 NO. ORIGIN . i TAKEN Pic,ex/Ji d ILiippnuffrs 3re?/L * -Analyzed By____________________________________ Report Date ' '. SPECIES ' ' '____________________________________________________ SEX LENGTH!l VfT. ' PPnMg REMARKS Mte . SUBMITTED iO. P. .<r 70-1 r ojT 74 - 33 ' .; . U, R . u . 3C Cu, P. ' 3- . . Lo,p ' -- 70 - 30 . ' - 00. R.- . -13( -- 33. 3L ' 37 ' ` of 37 SiOnT .; ' s0ic\O5j ' " . ' CD , . . . ' V; CO. P ot. /u,P. ' . to,?, : CJ'P, -- -- ' -- 23 S.7 43 ' -- S-4 - LG - . 41 t-1 . ; ' ' p.p 7>4- ' - ' . * . 1 ' lo,P. '* ' -- c.o -- ; j ' cu< P, ; SJ - _w*Dat2 fro additional analysis as follows. 1i /TOTAL - a . ioCDf'/SH ' ' f(O&S0}U WUi='b> PcB . . ST^TS OF NEW YORK,., - - EfFERDEPARTMBNTAL MESeCTY-ANALYSIS REPORT . Report of h'rcuxy Content In.Laboratory Making Analysis ` G NO. 4/o // td . ' Analytical Method' :Analyzed By (See instructions on Reverse).____________________ - s^TE j . - ' LAB NO. ORIGIN ^ ! TAKEN f SPECIES SEX //Uic/Ji or Litef*,icers s/c*/-nr \ O-eet ' v . ~r~f-------- j----------------------- - LENGTH to,4 :/o:C 1 ' i' -- /3>o CT. -- - - /(, '-- - 30 t' f-- . - ZA5? -- 32 o*r ,, .\ ' ' <zr: &A~ - //- c5~ - rO'ir -- <3> 33 o'/ . in * s: . oN) ' v> O*/D* '. :> -'* ` cr - /&.( - - // 4 -- &F-: ' -/o,& 3j &F-' ' -- ' /A A - df GP - : - /4 o - ' * * : kg'*... . PPM Report Date ISte ** REMARKS submitted * li - *_ , 1 . 1 i ' ' - 'k'k Data from additional analysis as follows. 1O/AL -/Jw STLCOPCB4012951 ismemouTrt SflSS ' . . ' PCB . STATS OF NEW YORK,., - INTERDEPARTMENTAL =KEK5GItY-ANALYSIS REPORT . ' -Report of h'rcury Content Ir.Laboratory Making Analysis rAG-NO. >?y./7 Analytical Method (See' instructions on Reverse)' LAB NO. ORIGIN ,, hu-ictii of LUo^m^rs . DATE j TAKEN ; ?Mr1 : .SPECIES Lm& ' 03 0f JW 1? 4o khs 1 Lmd i-mB lmd ' f LmQ 4l &T y L/nQ ' img O CO Irng r'. 21 . N) . CvfDl ' '*: C . o Lnu3 Analyzed By SEX | Kg. LENGTH wt: ! pin - T.( - -- U-S~ - - (1.0 1,8 - Z.S -- (p, 0 - -- 7 f -- -- 6.3 -- i H'O'DSOM n? Report Bate ' r^T ** REMARKS ! SUBMITTED ; - - * STLCOPCB4012952 -* .' **Data from additional analysis as follows. ` . i 1 Total - <7 ?OLSE)J-/SiH - ' . . . PC8 f~iotd>Soh /P!-- V'a^ieh Cav<*> ^ STATE OF NEW YORK.., - - INTERDEPARTMENTAL N22CCR.Y ANALYSIS REPORT Report of-h^-pcury Content In Laboratory Making Analysis PC3 . .---------------------------------------------- , Analytical Method. Analyzed ByReport Date_ (See instructions on Reverse)_________________________________________________________________________~ rNO.t 15! X' - lab no. ORIGIN _. Hi*dS>oi\ K * 1/` h X:~V\r{< V- i>U t-i 1/ <t- DATE | TAKEN j SPECIES SEX t/uI-jAgMtisL -- if A - j. i'/* '* /* teGjdfn 5 - LENGTH WT. 9- ? - -- /* 51 ' Hg. PRT ** ~]U 15 : <f " v. It u. ft H tv u -- /6-5 - /O'5 - - 77 *f ;/ l< ' n -- <?./ -- REMARKS 7? V' ft ft K - z/.y - -- * LATE . SUEMITTED ( 70 Ki ' it : // - '/ // (Z fr tf -- /0'7 - <r -- f/o -- 1 . ion s: o 00 o H* - 9 V *KBata from additional analysis as follows. ' !'' : /oT/f/L - | OkiT& SOCKB^ :' 1 fioDSOtJ 1' * . -, .| STATE OF NEW YORK,.,----- XNTERDEPAirTHENTALilSIXUEffjAXALYSIS REPORT Report of K'rcury Content In _____ '.jLaboratory Making Analysis G NO. -9- <(! 7 `-7^ 7 C'S\i t,'5, ( <7 c;r > -.0 ft ^ .? t <r 7 n< > 7-!>7 * ^ _ .Analytical Method (See instructions on Reverse) LAB K0. pracin ..... , /TnTc-<jj ctreje. - cJt~ -koddcfui/fe </ . . ' 'V* ; : *' * .. < a- t *, . . ... 0 . to sr O fNJ OD vD vO _____________ Analyzed ByReport Date __________ - - _______ ____________________________________________________ Gate i TAKEN ! " SPECIES ' Kg. SEX LENGTH WT. PH-1 ** REMARKS S^ck-pr ; ( ' 1" - \* [ /$\? /fc.A hr- O V f '/& ( > -s = r r. 1 &-7 u' 1 n. 1. j$~<r i* . < t* N. % u . if /6.3. /<?. * SSfE SJjgVTT'nrj) [ { * **Bata frorrr additional analysis as follows. 11 Tome Wf+ITE . Pcb HObSoW STATE OF NEW YORK,.,-------INTERDEPARTMENTAL MERCERY. ANALYSIS REPORT Report of h 'rcury Content InLaboratory Making Analysis t^lUe/SL_ >0 NO. Oil P3 ) >20^ o:r7 t I'O' /jdQ rn* o^ *t ^ 5cD33 *r* .j . ' 'Analytical -Method - " : (See instructions on Reverse) - LAB NO. ORIGIN ., ' ,, . t(tnti&+cc Creel*. DATE 1 TAKEN !' : ett Eddm/lil-t . .4 . *. (. 1 ...i , %* * ; * _ . ' -' .___________ ' SPECIES Analyzed By ' Report Date '_________ _________________________________________ ' % SEX LENGTH W7- PPM DATE 4* REMARKS SUBMITTED r, : ; 8-0 . u- 8-7 2'$ tt ^ * K.t . 1* .o ' ' ' 1 * - - -... w < CD in ` . '' O CD . sO ' ........ .. OJ ft V It M .. \\ . 1'* f. . 1' - . &-r '93 7-r 2-3T .9-0 ; 7* 3 | * * '?.o 1 . **Bata from additional analysis as follows. STLCOPCB4012955 77)77? A V K* -- >.(.6,4pfc>,Bass ' . ' . , . PtB . STATS OF NEW YORK,..----- INTERDEPARTMENTAL MERCURY ANALYSIS REPORT * _ . Report of h'rcury Content In ' Laboratory Making Analysis Hodscjo ___________ ` ; no. 2 i~q 1 !7 . . v Analytical Method .(See instructions on Reverse) LAB NO. ORIGIN , Ko>\dc<ct Cr-eek" cd~ EjAu villz u. ' * ' ~ DATE ( TAKEN ! .' . . SPECIES l -1 boss. i .' i * - : ` * . t Analyzed By Report Date _____________________________________ __________________ ' SEX length! wt. Hg. PPM . ** LSfiTS REMARKS SUBMITTED K Z. j | ------------------------1!1--------- ' ~ ' ; .* '- *, ^ ... o Cft SC ` * o N) * ' . CD . - sO . 1 vO ! . 4 '* .. " STLCOPCB4012956 ' ' ____**Data frcn additional analysis as follows. STLCOPCB4012957 f&iLOu) Pencil - . Hvdsoaj >9ius/Z pc> ' STATE OF NEW YORK.,--------INTERDEPARTMENTAL HERONRY ANALYSIS REPORT * Report of h' rcury Content In_Laboratry Making Analysis ________ G NO. W'tf */u T ,J C ~J - vr.7 DlaT 2 fO D if 2 1? . Analytical Method ___________________________ Analyzed By Report Date (See instructions on Reverse)_____________________________________________________________________ _____________________ ` ` LAB NO. ORIGIN , ^ . Kt-^zlo<.cC Creek. v DATE TAKEN SPECIES sjijrr 'Y-p/fcv V .w Hg. SEX LENGTH WT. pm 7-4 7? R.7 J DATE . ' ** REMARKS i SUBMITTED ------------------ 1----------- -- .< tl 14 t tl ^ 7.*? ?.c * r. 7^ e> ii ' t . ... tOA a: o fv <x> wt .... j M' ii m 9.o 8.o i ! i i |' l 7-7 !i 7-7 It 7. 9 * t1 . !| 3 '7 . if i| i iI '> * 4 **Data ran additional analysis as follows. ~~7~7) / PrP ~~ ~7 i i i | i i ; SuMPtsn SuAJPtStt . . Hudson 0r<$/l L~ SOAJp/SH PcB. STATE OF NEW YORK f. - - INTERDEPARTMENTAL. MERCURY ANALYSIS REPORT Report of h'rcury Content In_______ ________________ Laboratory Making Analysis Rive&_. ' NO. `u<f . Analytical Method__________ _________________Analyzed By.Report Date (See instructions on Reverse) `1 * LAS NO- ORIGIN , ^ DATE | . - TAKEN ! SPECIES "~W* SEX LENGTH WT. PPM Kci\( W^'Ck., s/i/RR&r i a.f' Edritruift-e "7'f ' : ; </ .. 1' . 1 Vo ^ 1 5\A.i\', l REMARKS DATE SUBMITTED 1 t . 10? . w* t suTvTT ^ L - 7- t 6-0 ** CoO * - o i\> CD vO . O' . - ' . ' . # *. . **Data free additional analysis as follows. ^ - . lOTftL -- ' STLCOPCB4012958 'mUMoc/Ttf Mss . "v':- ' | . ` ' " PcB ( . '.v . STATE OF NEW YORK,.,----- INTERDEPARTMENTAL MERCURY ANALYSIS REPORT : _ Report of h `rcury Content Ie 'VLaboratory Making Analysis flo&so/j - Analytical Method;, . f Analyzed By - ' Report Date_ (See instructions on Reverse) ' . Cate' j : NO. LAB NO. ORIGIN . iOivxcU^ Cr-rek yjf" E/ft&Ua-Ui(f' ' . jTAKEN- SPECIES . ahhrY'*!!:r ^ 1.1 i-" . - 1 SEX LENGTH VrT. Hg " PPM 93 J* f' ! ' ' : ' .. ' . 1 \1 ' . rc {. \ *. - " ~""" ~ ** REMARKS LATE SUBMITTED .1ii '; . . . ' t. * j. i i . - - ;. ' i 1 osw or\j '. . OD vsOD .. . * ' -- * **Data fron additional analysis as follows. ' Terrft c _ '-A&g-emduw 8/9ss j .' - Pdk STATS OF NEW YORK,., - - INTERDEPARTMENTAL MERCURY ANALYSIS REPORT . .Report of h'rcury Content In`j Laboratory Making Analysis HuXiSo/j 'Qnjg/z. \Q NO. 021 > 0.37 6 3*/5. Z.VW .- Analytical Method^______________________ > Analyzed By_________ _________________ Report Date. (See instructions on Reverse)________ ______ )______________________ .___________________ Bate j LA3 NO. .ORIGIN .- I-' , ' TAKEN ! C-/~f SPECIES "$SSEX LENGTH WT. PRi ** ` REMARKS DATE SUBMITTED <*-/ -t:dJluw/le Jb.X 9- ' : / { j--t------------ t ' -if V* ,* * n i a?v * - ' .. - ** ......... " -I' 1 ' ;- .n CO at _ . 1c f\j . <i vO .. -....... OD . ' . 1 m ,* .1 i , l ? . * *> i r- I- i |- /f.R IZ'X MX 7 <? - ' ' '. - *. . .t j\ * STLCOPCB4012960 "Data xoz additional analysis as follows. T077k. - 7  flysVcC. K-s^ian i. /Mew paXty' PCS STLCOPCB4012961 **2nta frcn additional analysis as follows? '^aJ . - STATS C? SSW TC3X . '"Escort Ys ot .-Re* 'toi* 3 fllcu): pun- C-:. :7 f, ; ncs - . ` - I^23ES?Aie*^AL MgksSSr ANALYSIS -REPORT ' '. . Content In ' jjj__Lcbcr~try Making Asslysis Analytical Kethod Analyzed By i Report xno^ vunJ* . 0O)ltf i " //i' "m " m\ .. f ' ; LAB HO. ORIGIN . ' ' \ifa*cUvit Cr-tfk ClT. . 5 ' fwrsf>*/nn<*t~&*\ i" l1 SC t o! H : " ~bATE."j TAKEN 1 '4 1 .<! 5 t |." '' length! wt. - Hg. ' SPECIES ' SEX PRi 7 1------------ i} 1 "v <* ' ! L_ _u n?-7 1 4 #M ..it '" 1 /o. */ 7, / 1 I' . ** RE-'AEKS : J' 'Hi'S r i .j i ii r! r . 1 "ml 1 "ml " /Trt \ " /*/ vH-- K "i 1 ' ' ' " H. . : ' . ---------------- ... .. ---< -- if 1 st 1 "r j' r, i-n . lf \ *' f ' : . If '' ! 1 7 i. - Smce^Is>\o u(L 7,o x.d. 1 I- ! 7,7 7./ . *^ *'-- >t " /! : . W (t. . ____ _ ' . ' j -- ------ - ----" -I- - " .. i r . j ; . >r . 0? -4-------- ------- --------- ---- #*, ' ------ -- --- it . \&!tack i 15 s.rf\OPtC* r/ " ` % ......... _........ ---------- j-------- ------------ - JDI?S i ] ' /{ .. >' - . t 1i ' . , 7-? 1t 1 _______________ .......... .:,, ! f - - * Ir*V.ta. fret .additional analysis as ollcv;o. ii i i .! . i :* , y* ; . i -------------------------- ------ ` il ; ` - if ------- -------- i _________ i 1f 1i - * STLCOPCB4012962 no. so Sf V? / > 4? -/7 % do M V3 v/ 4? !~ju(AddSSo h k'll/Cf- IESopus Clr+ok, STATE OF NEW YORK Report of . rc& - - IKTERDEFAKTHENTAL MESSUStf ANALYSIS REPORT Content In\Laboratory Making Analysis Analytical Method 1 i: Analyzed By Report Date DATE LAB NO. ORIGIN . TAKEN t-iudztC'ft &usch iWfU s*l / l~*>onu<> / (2\r- f/r/ys */ if If n '/ tf H i( V ' SPECIES /? p // y 11 // /r 'f /*\cLr$ SEX LENGTH 03.} L ; ?./ f > 7/ .r \ <5- C WT. * Hg. pm /f >f _I , - --------- f # tf tf . tr _ ii' . << . ft ' ! jft *r L-L T.T Tf O , ,, aCro !', '( O IV " C> it *o *" // If tf .. it H" ft * / if ,t H. tf . ' Jf f &(* &0 S-E 7-7 . ** REMARKS DATE ' SUBMITTED i \ "" - ' i -I 1 J STLCOPCB4012963 . **rDv ata frcn additional analysis as follows. ' lJ (kJfD TOTAL, * peg 1 f-jtfdsok t50f>US fvtft. STLCOPCB4012964 **Data from additional analysis as follows. 'w' ~TorfiL 1 f-jU-dSOh K t IS? \r c'i 'v pc h Eso'f<C/5 C.V-^rJs, STATE OF ml YORK..____ OTTERDEPAKrMEOTAL HBSGBKtf ANALYSIS REPOST Report of.-te=cesy Content In:jLaboratory Making Analysis ^. Analytical Method [r Analyzed By JReport Date d5te G KO. :> J&S --------------------t' f--S-J*7*!_-`f[ 3 LA3 NO. ORIGIN TAKES j4ufi>oi\ K\v<* <vfi VAA? :fl &!/<, Y~ // SPECIES UO l\*h. 5 u t keys . - r . a MS 5 / i(/ / ' ct // k tf ar ... --............. .................. {f' p. --___ _ .. - .......... -- - --------- -------------- ------------- ... f SEX- LENGTH KT. O,.; *" 9 l t /-............. \______ 9 ;- V*/-P * .-- i. ! i i 1-r K.3 6,-R KgPPM - Lf.tf ----------------- --------------- \ a1 ** . REMARKS \ | Mte SUBMITTED " i , ....------------------------------. --------------- --- -- * i -........... iDn sc c' vO o o UJ * 1 i i- ! STLCOPCB4012965 **Data free, additional analysis as follows. i ..J_______________________ | fkJPSo/J /<'. cdr A/ f MOU &* PCJSi . . STATE OF NEW YORK.., - - IOTERDEPAR1MENTAL MERCURYi;ANALYSIS REPORT Report of Vtassray- Content In VLaboratory Making Analysis ' ; xo. "^0 "/7 --j-/8 -f? -/ Analytical MethodAnalyzed ByReport Date (See instructions on Reverse)f _____ ^ LAB NO- ORIGIN _ , ft/sS*i* /w /\4 tJjX " M> TTt/o/f' s^ojj^ DATE TAKEN ^Mr * j` ----L---- c*J~ zttrs k). 'Ti'sn//' <r>>o/ " SPECIES C.O. y p L/kB> rtudoo^ //. ~Tiuo/>' r^>,. i ujp hg* SEX LENGTH WT. PPM r~~"~ ----) tr 1"i " 1 h i - 21: .f \ P/-7 -- . '<----. -- V.1 ... i % ' </?//> ** - REMARKS DATE SUBMITTED ---------------- ____________ -v-------- i . .. -_______________1 // ~i?" C>Jt> Ii1-. 6.0 /y . . .. 1>JP i S'-? i --------- -K-- --w- ------------------- ----------->---- A< //. ~n\fC>A' <k5U/U .o o C/0 X ,, //S' * 1 1 1 o frj kO o o i 1 .. **Bata fron*. additional analysis as follows. ._ ,'J1 S'.-- ^ .. . /W/recOA {vf/rj AG NO. ':'-Rr'3- . STATE OF NEW YORK,, - - TNTERDEPAKTHSNTAL MERCURY ANALYSIS REPORT ` Report of JhcC5ry Content In -" Laboratory Making Analysis PC B ----------------------- :------------------ ------------ --------------------------- .. Analytical Method'______________________________ Analyzed EtyReport Date (See instructions on Reverse)_____________________________ ________________________________________________ " LAB NO. ORIGIN DATE TAKEN SPECIES Hg* SEX LENGTH WT. PPM DATE **. REMARKS | SUBMITTED rlunEdm 2 kiM*. Hoccfwl Ct lit''hf C ^~0r Q 1 1 ; bft/ M2. bH dst 57 .DSL- ba / ; i j .. a CO s: oNi vO ... o o U1 i t' t* i Scc./c-i<~ tt M n 1'. /(TrfftW/ 04.33 // u f . m-Q ,'4'-C f>Crt> t 1i /-T- ? /s-. 3 n.t n /9.3 A3-*7 ' /A 6 , ?-.r j ' i 1 l **Data from additional analysis as follows. STLCOPCB4012967 S 8 VCT?\ ' STATE OF NEW YORK,., - - INTERDEPARTMENTAL iJERS?/ ANALYSIS REPORT Report of_b==cc3?y Content In ' ' Laboratory Making Analvsis ?c& ' t ' Analytical Method Analyzed By Report Date G NO. 'LAB NO. ORIGIN , >/5'Vr i * ! i i 7S* J!T7 l<TZ !<r9 , * . i i . ' ., .. f* j i ; ', " ... . * . DATE TAKEN SPECIES \ W * 'H // i /I >i ; V || SEX LENGTH WT. PPM 1- r. 1. 't . P 1 ' ..... b 4-JF 6-3 f 6.r f S'. 9 i. , s>? i 7.6 ; ** . REMARKS UATE SUBMITTED ! r - ' [LZ >iU if>Z o . </) 2L ^ .r c~i ' ho - .' . O) . O 111 ...... ' O' . K-7 .f 1 /6?r )}'C* . ' * *> ci ? t v -v*' <- A r /f r 6,3 ! ,S o ' S'-9 s-.r sV tSmStDT* ata from additional analysis as follows. /c.t,uU STLCOPCB4012969 teB \ STATE OF NEW YORK,.,- - - INTERDEPARTMENTAL ME285t&> ANALYSIS REPORT Report of h'rcary Content In'i .Laboratory Making Analysis Analytical Method h Analyzed By AG NO. LAB NO- ORIGIN ' A'67 r> V 6? . ' . ' LW^1 V ?4` 'fivjys . M. * i * ' M7D 1 .' 4. 1 D at ; c. f>w0 o o .. DATE TAKEN sf/z/isl SPECIES >: - ) ... . . If - .1 -- . . [SEX ! 1 ?f * i %. . r t LENGTH // ?-r . i. . -. 1' i i ' KT. .* :* , t ! _ 'j .* . .: * . * PFM ' - i I Data front additional analysis ;as follows- (/~>zcu Oc'ty}) Report Date Mrs ** REMARKS SUBMITTED * STLCOPCB4012970 i i LJ osw /-ftrOSo^ss % crCIATS HSH YOKX;., - - IKTEXDEPARTI'IEhTAL MSSCCXY ANALYSIS' REPORT P.apcrt of >. ` rcnry Content InLaboratory Making Analysis Analytical Method Analyzed Ey TAG SO. ZTVoV i :- LAB XO\ ORIGIN . ' | DATE | I TAKEN' ( , SPECIES | c / /. i /V] SEX ' ! ' Hg. LENGTH WT. PPM O- .. L S_ i . i i S' ! VV^'iUr-- VU~V __ r' 1* i ! i i . * >' ! 1 .! i i i1f ` 1 ' * !' '' Noj . . * l *+> . *\ t ` 4oC/"> .- - ./ I 1 ' -. ' ! ( i I- : . .i \ 1 \ i , i i - **Eata frcra additional analysis as follows. . .. Rep ** SEMAKS S\1E 1 f i. - i ? 1 1 ii l i : "r I !i < " !- ' . i 1 i .i ! . > . . j. o 8 r-. ' <8 CJ rj cj H . P> . a 3 a oH TH3 TOJ 43 a) rf * jlft ' STLCOPCB4012972 STLCOPCB4012974 STLCOPCB4012976  '*'^1;''<! ****..' /m *1* * ' -' ' *kr* *Y*'^(. I *1 /** * * f ** :! From: Gauccrties 7 1/2' . Hudson River at' Ilorth Tivoli Bay ElcctrofiGhing Station. August 0, 1975 , _ |' M Tck ^H "'Tv^ V IjjS'"' StS.ln^^V) <*%.*/'JL \ *V Vh y / y'y fe) i (. ^ ;l' ; ; U'W,r:I'//' ^ *-' '5 I I! ;, g` * I ;: MeEdIen } jI 'I > i Itland ' /. / , * 'A :y * ` * ` -1 /* /; i t ' VA /1W//-' /I'-/-// ^AA M^//////y7 /.x? M; Wlj WJ// XMpi.. (U!.\f\1 T$1\\!; I "nW.i'VI j V;' 'grp/ / . - v:.v / M/Xpk'-'-iXy / |j - ,/ I . A1/ /' "C-"v - 44li#^v ^-.imkmm/. gm > .' ' '/* v-; ' (' A' *A ' 5\ / fj/ / / / / OSW 1 ! U--r .,.;V :y'$v^XA'S. fiPw;-;'X.m^{//;;'V7(7 /* /'// //i y k //. , "?A nV tt^- fut Vk* l' ' ^ ` J--J 029015 STLCOPCB4012977 STLCOPCB4012978 REPORT OF ^ PCB FISH SAMPLE COLLECTIONS r * UPPER HUDSON RIVER ' Ry: Region 5-South, Warrensburg Inland Fisheries Management Unit Introduction The VJarrensburg DEC, Division of Fish and Wildlife, Bureau of Fisheries, Inland Fisheries Management Unit, under the supervision of Fisheries Manager Gene Lane, Associate Aquatic Biologist, collected representative fish samples from the Hudson River at six (6) sample stations, described below, from Corinth downstream to Waterford: Station Humber________ Dates,Area__________________________________ U.B.G.S. 7.5 Minute Quad Map Reference 1 Aug. 20-21, 1975 Above Corinth Figures 1 & 2 (One-halX mile below the Lake Luzerne (Fig. l) . mouth of the Sacandaga and Corinth Quads ' River dovmstreara approx. (Fig. 2) . ' 5 miles to 1/2 mile above . - - the dam at Corinth) 2 July 24-25, 1975 Above Glens Falls Figure 3 . (Approx. 2 miles downstream Glens Falls Quad from U.S. Rte. 87, Northway Bridge Crossing) 3 July 1-2, 1975 Below Hercules, Inc. Hudson Falls, N.Y, Figure 4 Hudson Falls Quad '4 a. July 24-25, 1975 Fort Edward . Figure 4 (Below G.E. plants in .Hudson Falls Quad Vicinity of Rogers Island) b. Sept.lO, 1975 Fort Edward (Same as 4a) Same DSW 029017 STLCOPCB4012979 5 a. July 28-29, 1975 Approx. 5 miles below Fort Edward b. Sept. 15-17, 1975 'Game _ 6 Aug. 25-27, 1975. Waterford, K.Y. (Lock //l downstream approx. 3 miles to 0.5 mi. above mouth ` * of Mohawk River) Figure 5 Fort Miller Quad Same . Figure 6 Troy North Quad ' Fish samples were collected by gill netting, fish toxicant (rotenone) and * .t . by angling. Sampling techniques were determined by recreational useage conflicts, water quality and clarity, velocity of flow and, in one instance, potential for additional vandalism of nets. Upon capture, all fish samples were immediately put in polyethylene bags and placed in an insulated, portable cooler filled with ice. On the same day of capture, the bags containing the sample were labeled with information as to the species contained, capture date and location and placed in a walk-in freezer located in a locked building on the Uarrensburg DEC Regional office property. Building security is supervised by the Regional Supervisor of Fish and Wildlife, Principle Fish & Wildlife Biologist Robert Brewer. Samples were held in the ** , freezer until they were transported to various laboratories for analysis. Clean samplfes of the polyethylene bags were also sent with the samples, for analysis. Collection methodology, field supervision, transportation methods and sample destination will be described for each sample station on the section that follows. Sample collections will be described from the most upstream station to the down stream location rather than in chronological order. Two stations (4 and 5) were sampled twice to provide more comprehensive fish collections. . DSW 029018 STLCOPCB4012980 -3- Fish Collection Stations . Station I - Above Corinth - Aug. 20-21, 1975 Conservation Biologist Bruce Shupp supervised the 3 man field crew . on this collection. Nylon, raultifilament gill nets were chosen as the collection method. Netting was difficult due to diurnal changes in volume and velocity of flow, due to releases from the Conklingville Dam on the Great Sacandaga Lake. Electrofishing was eliminated as a sampling tool because of low conductivity and a mean vrater depth which would have re duced efficient electrofishing to minimal effectiveness. Fish toxicants were also eliminated because of the heavy use of this section of the Hudson by boaters, swimmers and anglers. On 8/20/75> gill nets were set in 5 locations, designated as G-l-1, G-l-2, G-l-3, G-l-1* and G-l-5 on Figure 1. The five sets totaled 600 linear feet of 6 ft. deep mesh (2-150' variable mesh nets, 1-|" stretch through 4" stretch) and 3~l00', 3" stretch mesh nets). Nets were pulled in the AM on 8/21/75* One 150' variable mesh net was vandalized beyond repair and the other 150' variable mesh net was stolen. The remaining three nets caught a satisfactory sample, except for smallmouth bass (Micropterus dolomieui). To eliminate further net vandalism, angling was used on 8/21/75 to complete the smallmouth bass sample.. The areas where the rod and reel captured bass were taken are designated on Figures 1 and 2 by the yellow shaded areas A-l-1 and A-1-2. OSW 029019 STLCOPCB4012981 -4-. Table No. 1 lists numbers, length range and average length for the combined sample of fish captured by netting and angling. That portion of the total sample which was transported by truck; to the D&J Rome Fishery Laboratory on 8/22/75 by Temporary Fish and Wildlife Technician Raymond Smith and received by DEC Chemist Earl Harris is iden-. tlfied on Table No. 1 by Bpecies, length and designated composite number. Station 2 - Above Glens Falls - July 24-25, 1975 Senior Fish and Wildlife Technician Burton Morehouse supervised the 3 man collection crew. A total of 1350 linear feet of 6 ft. deep multi filament nylon gill net was set 7/24/75 and fished for 20 hours (overnight) in 4 net locations designated as G-2-1, G-2-2, G-2-3 and G-2-4 oft Figure 3. The nets fished efficiently and when pulled 7/25/75 produced a'total col lection as listed on Table 2. Also on Table 2 is the sample of fish from the total fcollection which was transported to the DEC Rome, New York, laboratory on 7/28/75 by a technician from the Rome Lah and received by DEC Chemist Earl Harris. These samples are listed by total length, total weight, and are iden tified by a designated composite number. Station 3 - Below Hercules, Inc. - Hudson Falls - 7/1-2/75 ' This stution was sampled at the request of the United States Food and Drug Administration. Senior Fish and Wildlife Teclmician Burton Morehouse supervised the 2 man crew. DSW 029020 STLCOPCB4012982 -5- Multifilament nylon gill nets were fished overnight in two locations for 22 hours below the outfall of the Hercules, Inc., Hudson Falls plant. One location consisted af a l^O linear foot x 6 ft. deep x variable mesh ' net. The other set was 300 linear feet of similar depth and mesh size. . These sets are designated G-3-1 and G-3-2 on Figure 4. The total 450' of gill net was discarded -due to the severe accumulation of fibrous sludge which is present in voluminous quantitites through the water volume. Total lengths of fish captured are listed on Table 3. Also listed is the sample of fish which was selected from the total collection, packed with 4 lbs. of dry ice in a sturdy, insulated ice chest, sealed in a card board carton and transported on 8/6/75 by Fish & Wildlife Technician Hay Brown to the Alleghany Air Lines Air Freight Terminal at the Albany County Airport for shipment to the FDA Lab in Washington, D.C. * Station 4 - Fort Edward - Rogers Island Vicinity Station 4a - July 24-25, 1975 Senior Fish and Wildlife Technician Burton Morehouse directed a 3 man crew which attempted to obtain a comprehensive fish sample in the vicinity of Rogers Island by setting multifilament nylon gill nets in three locations designated as G-4-1,' G-4-2 and G-^-3 on Figure 4. The three net gangs consisted of 2 panels each of 150' x 6' x variable graded mesh (l^" stretch through 4" stretch mesh). The total 900 linear feet of net was ultimately discarded due to massive accumulations of fibrous sludge which also caused the destruction of the nets at Station 3. . OSW 029021 STLCOPCB4012983 ~6~ The nets were set on 7/2!*/75 and fished overnight.for 20 hours v'1! * 'vi ' . . 'ri'T.anse of '.I'M .r L t ';! tu- e-'.tc did not fish efficien'.jy. "t-I.1. 5 f!>sh, listed ii: Table ha, were captured. The entire collection was subsequently transported to the DEC Chemistry Lab in Rome, N.Y., on 7/28/75 by personnel from the Rome Lab and received by DEC Chemist Earl Harris. . Individual fish used for analysis from this sample have been designated as 55 Hud-75-DN, 56 Hud-75-DN- and 57 Hud-75-DN and are also listed on Table Ua. Station hb - Sept. 18, 1975 1 Because the netting on 7/2h-25/75 resulted in a poor catch due to the disastrous fibrous sludge accumulation a second attempt was made to sample fish in the vicinity of Rogers Island at Fort Edward. On 9/15/75 ah attempt was made to collect specimens by electro fishing the mainland and island shoreline areas in the Rogers Island area. Although a few fish were captured during a 3*5 hour period, the extreme water turbidity caused extremely poor visibility, thus electrofishing proved an inefficient sampling method. Fish toxicant was the only other alternative! On 9/18/75 two areas in the Rogers Island area were treated with 5^ emulsifiable Rotenone at 2 ppm under direct supervision of Conservation Biologist Bruce D. Shupp. These areas are indicated as R-^-l and R-U-2, in red, on Figure U. ' ' . . ' . * ' * DSW 029022 STLCOPCB4012984 -7- The total fish collection resulting from this method is listed on Table 4b, Listed on Table 4c are .the lengths, weights and raetal jaw tag numbers which were placed on some individual fish specimens, and bagged composites of smaller untagged specimens. This sample was transported by truck to the DEC Chemistry Lab at Rome, N.Y., on 9/19/75 "by Fish and Wildlife Technician Raymond Smith, Documentation of delivery and receipt are on Table 4d, Delivery received by Senior Analytical Chemist Ralph Karcher Jr. . Station 5 - 5 miles below Ft. Edward, New York Station 5a - July 28-29, 1975 `. A crew of three under the supervision of Senior Fish and Wildlife Technician Burton Morehouse set a total of 850 linear feet of 6 ft. deep multifilament nylon gill net in 3 locations designated as G-5-la, G-5"2a, and G-5~3a on Figure 5- Linear footage of utilized stretch mesh dimensions are: 150' of variable mesh (l-g"-4" stretch); 300 ft. of 3'" stretch; 30 feet of 4" stretch; and 100 feet' of 5" stretch. The nets were set 7/28 and pulled 7/29/75 after fishing 18 hoxirs. Although the nets had accumulations of fibroUs sludge material, they caught some fish and the nets were salvaged. Table 5a lists the species and the total lengths for individual fish caught in this netting. Also listed are the designated composite numbers identifying the samples from this collection which were transported to the DEC Chemistry Lab, Rome, N.Y., by DEC Water Resources Technicians from Albany on 7/30/75 and were received by DEC Chemist Earl Harris. .' ` . DSW 029023 STLCOPCB4012985 -8- Station 5a - Sept. 15-17, 1975 .Predator species vere lacking in the 7/28-29/75 sample (desig nated 5a) in this location 5 miles downstream from Fort Eduard; therefore, additional sampling was required to .obtain a more conpre- h'ensive sample. On 9/15/75, under the direct supervision of Conserva tion Biologist Bruce D. Shupp, a it.man crew set a total of 1400 linear feet of 6' deep multifilament nylon gill net. The nets were set in 7 locations designated G-5-Ib, G-5~2b, G~5~3b, G-5-4b, G-5-5h, G-5~6b, and G~5-7b on Figure 5* Totals of various stretch-measured mesh sizes include: 500' of 4" mesh, 300' of 3" mesh, 300'-of 2^" mesh, and 300' of variable-graded lg-n-4" mesh. The'nets vere pulled on 9/16/75 after fishing approximately 24 hrs. Density of fibrous sludge in the river had increased during the period the nets were fishing. This occurred either as a result of disturbance of bottom sludge deposition from increased barge traffic, or from increased discharge from the source. Whatever the reason for the increased sludge density, the result was destruction of the 1400' of gill net and a negligible fish sample. As in the situation at Station 4b, fish toxicant was utilized to obtain a comprehensive cample. * '. On 9/17/75, under direct supervision of Regional Fish Manager Gene A. Lane, a 5$ solution of emulsifiable rotenone was applied at 2 ppm to the areas shown with brown shading and designated R-5-1, R-5-2 and R-5-3 on Figure 5. DSW 029024 STLCOPCB4012986 o9 The total fish collection resulting from the rotenone applica tion is itemized on Table 5b. Table 5c lists the lengths, weights and individual Jaw tag numbers on individual species specimens, the composite plastic bag sample of untagged smaller specimens, and a 5 lb. snapping turtle sent live also for PCB analysis. The sample was transported by truck to the DEC Chemistry Lab in Rome, N.Y. on 9/l8/75 by. Fish and Wildlife Technician David Kenyon i and received by DEC Chemist Earl B. Harris. Table 5d documents de~ livery and receipt of this sample. ' Station 6 - Waterford, New York - 8/25-27/75 This station was netted two nights 8/25-26/75 and 8/26-27/75 under direct supervision of Conservation Biologist Bruce D. Shupp. A total of 8 net sites were fished. These are designated G-6-1 through G-6-8 on Figure 6. Sites G-6-5 and G-6-6 were fished both nights. Sites G-6-1. through G-6-4 were fished.8/25-26/75 only. Sites G-6-7 and G-6-8 were fished only 8/26-27/75. Over the two net-nights a total of 1935 linear feet of 6* deep . multifilament nylon gill net was employed. Although the debris accumulated in the nets (including raw human sewage) limited netting efficiency, a satisfactory comprehensive sample was obtained. The total catch is summarized on Table 6. Table 6a item izes the species, their lengths and tag numbers which were utilized as DSW 029025 STLCOPCB4012987 . -10- . c. ' ' . .' the sample transported to' the New York State Department of Agriculture and Markets Laboratory in Albany, New York on 8/28/75 by Fish and Wildlife Technician Raymond Smith'and which were received by Dr. Elmer George of Agriculture and Markets. 4 Prepared: September 29,/-1975 3JL ___ BruccT D. Shupp Conservation Biologist Fish and Wildlife Region 5 - Warrensburg Approved by: . Gene A. Lane Regional -Fisheries Manager Fish and Wildlife Region 5 ~ Warrensburg DSW 029026 STLCOPCB4012988 * . 1I ' I i< I j i o 4 tc I i < r r STLCOPCB4012989 .;.. ; - ; vt >. ; 2 . . :?.?. 3 .- a FIG. L V - " 3/I^GUWG. SAJHPt^ AdCA A ~1 STLCOPCB4012990 ^' STLCOPCB4012991 flfpiu/S0K; RXI.LS o ` \tT 'v-] ir\vv>- 1| tr *. . * . ;V*.1 *2?-'M^Vi> V*jAS\fr.\ V* -y.y JFrnimore .1 -------- ?"' *iv / !< # NYf J ! i V,. . r * . .* Vt=*; l K=-V>;' ^ /' 'v/. "T^V ' 7, M^S'Ji X' _ y < A'- & 1'j ' iy'* id by the Geologic*! Survey CE, U. S. take Survey methods f<om trat 1 chrcUd 1966 rth American datum Yorit cooid.nate tyvtem. east r* Mercator end t*tM, wI# j. tjH * fir^irr.- L Fkcted fence and f*eid tmee *ha*e n uwtcH-oCriaph.v. . TThhu.t imnrf/oMtmmaint.efnft it urfhrrLi-d Utft*ctKAall0#ND MIHcCw*Uta8*|oHrCsAhCuMt H \ ent/ Urvdmurk bv<1di*ftt 41* shown V. V Svre * A----i ti~^uzn&i^3i2&j7mnjzr;jiLjjHLiM.j&'X CONTOUR INTERVAL 10 FEET 0A1UM t% MEAN StA LCVU * OSW 029030 THIS MAP COMPLIES WITH NATIONAL MAP ACCHOASV SANpf.^t ron KALE OY U.S. crot OG1CAL SURVEY, WASHINGTON. D C A rot out ntCCfctOING TOPOGRAPHIC MAPi 4HO tYUmtO; ts, 4V41UIUV STLCOPCB4012992 j&torritnTTid STLCOPCB4012993 STLCOPCB4012994 TABLE NO. 1 HUDSON RIVER - STATION 1 - ABOVE CORINTH, N. Y. 8/20-21/75 - TOTAL COLLECTION. Species Total # Range * - _ * Ave. Size Hicropterus dolomieui/Smallraouth Bass Esox lucius/Northern Pike . Btizostedion vitreum vitreum/Walleye Aitibloplites rupestris/Rock Bass - Lepomis gibbosus/Pumpkinseed Sunfish Catostomus commersoni/Common sucker Perea flavescens/Yellow Perch . Semotilus corporalis/Fallfish 20 1 1 .' 8 1 4 6 2 6.8" to 11.4" ~ 5.4" to 8.4" - 15.6" to 19.3" 6.7" to 8.7" 10.6", 14.8" , 9.6" 17.4" 9.9" 7.0" 5.8" 17.5" 8.0" 12.7" Sample Transported to DEC Rome Lab 8/22/75 ft Species ' Location Length (inches) Weight (pounds) Composite No. Smallmouth bass (Micropterus dolomieui) Above Corinth 9.1 0.35 5S Hud. Comp, 5 9.2 0.37 Q \ \ _ ' ' - ' .. 11.0 11.4 11.0 11.0 10.6 6.7 * 7.1 7.3 0.64 0.70 0.62 0.66 0.64 0.12 0,17 0.17 5S Hud. Comp. 4 5S Hud. Comp. 1 * 5S Hud. Comp 3 7.5 . 7.7 0.20 0.22 5S Hud. Comp. 6 .' White sucker > (Catostomus commersoni) ' ' Above Corinth 10.0 0.44 10.0 0.45 10.0 0.48 19.6 0.55 14..6 18.5 1.47 3.02 5S Hud . Comp. 2 5S Hud. 17 5S Hud.- 18 Yellow perch (Perea flavescens) l ri i, iff / Above Corinth 6.7 0.16 5S Hud. Comp. 6.9 0.14. * 7.1 0.14 7.1 0.15 7.1 0.16 ' DSW 029033 STLCOPCB4012995 ItMVrr-T* * TABLE NO. 2 HUDSON RIVER - STATION 2 - ABOVE GLENS FALLS 7/24-25/75 - TOTAL COLLECTION Species Perea flavescens/Yellow Perch Ictalurus nebulosus/Brown Bullhead StiroBtodion vitreum/Walleye Micropterus dolomieui/Smallraouth Bass Lepomis gibbosus/Pumpklnseed Sunfish Ambloplites rupestris/Rock Bass . Lepomis aurltus/Red-breasted Sunfish Serootilus corporalls/Fallfish Catostomus commersoni/White Sucker Total # 49 29 2 11 87 29 3 4 7 Range . 6.8" to 11.8" 10.2" to 12.8" 15.0", 15.4" 6.4" to 11.0" 6.5" to 8.4"- 4.6" to 8.8" 5.3" to 5.7" 7.3" to 15.3" 16.3" to 20.1" Ave. Size 8.9" 11.3" 15.2" 8.5" 7.8" 6.7" 5.5" 12.9" 17.7" A Species Sample Transported to DEC Rome Lab ' Location . Length Weight (inches) (pounds) Composite No. Smallmouth bass (Micropterus dolemieui) << \ Above Glens Falls ~ 11.0 10.6 9.4 9.4 . 9.0 8.7 8.3 7.5 6.7 6:3 'J 0.54 0.46 0.35 0.31 0.30 0.21 0.26 0.16 0.13 0.10 3 Hud. 75 Up 4 Hud. 75 Up 5 Hud. 75 Up 6 Hud. 75 Up 8 Hud. 75 Up 9 Hud. 75 Up 7 Hud. 75 Up ' 10 Hud. 75 Up 11 Hud. 75 Up 12 Hud. 75 Up Walleye (Stlzostedion vitreum) Above Glens Falls 15.4 15.0 1.03- 1.05 2 Hud. 75 Up l Hud. 75 Up Yellow perch (Perea flavescens) - *^ ' V Above Glens Falls 11.8 11.4 11.0 10.6 10.6 10,2 9.8 9.8. 9.0 7.9 0.73 0.67 0.57 0.60 0.55 0.61 0.55 0.45 0.42 0.63 16 Hud. 75 Up 15 Hud. 75 Up 13 Hud. 75 Up 17 Hud. 75 Up 14 Hud. 75 Up 26 Hud. 75 Up 19 Hud. 75 Up 21 Hud. 75 Up 22 llud'. 75 Up 18 Hud. 75 Up White sucker (Catostomus commcrsonl) Above Glens Falls ` 41 Hud. 75 Up 42 Hud. 75 Up OSW 029034 STLCOPCB4012996 Species TABLE NO. 3 HUDSON RIVER - STATION 3 - BELOW HERCULES OUTFALL 7/1-2/75 - TOTAL COLLECTION rr Total # Range -Xc'talurus nebulosus/Brown Bullhead Perea flavescens/Yellow Perch Catostomus comraersoni/Coramon Sucker Esox niger/Chain Pickerel - Leporais gibbosus/Pumpkinseed Sunfish Arabloplites rupestris/Rock Bass 9 9.8" to 11.0" 3 8.2" to 10.1" 7 12.9" to 15.6" 1 3 5.4" to 5.8" 4 5.2" to 7.2" Ave. Size 10.4" 9.4" 14.1" 18.7" 5.6" 6.4" Samples sent to USFDA Lab, Washington, D. C. - 8/6/75 Species Number Length Range (inches) Ictalurus nebulosus Perea flavescens Catostomus commersoni Esox niger Lepomis gibbosus Ambloplites rupestris .. - . . ' 5 2 3 1 3 4. 9.8 - ll.o 10.0 - 10.1 12.9-15.3 18.7 5.4 - 5.8 . 5.2 - 7.2 DSW 029035 STLCOPCB4012997 . TABLE NO. 4a . HUDSON RIVER - STATION 4a - BELOW FT. EDWARD (ROGERS ISLAND) 7/24-25/75 . Species;! (Rock Bass) Ambloplites' rupestrls (Yellow Perch) Perea flavescens (White Sucker) Catostomus commersoni (Alewife) Alosa psuedoharengus _ Number 4 2 1 1 Specimens From This Sample Analyzed by DEC Rome Lab - 6/13/75 Species Number Composite No. Ambloplites rupestrls Alosa psuedoharengus 2 56 Hud-75-DN 57 Hud-75-DN 1 55 Hud-75-DN 'j DSW 029036 ( STLCOPCB4012998 TABLE NO. 4b . HUDSON RIVER AT ROGER'S ISLAND (STATION 4b) - BELOW FT. EDWARD 9/18/75 - TOTAL SAMPLE COLLECTED Species__________ __ _____________ ;_________ Total Range_______________ Ave. Size Notemigonus crysoleucas/Golden Shiner Carassias auratus/Goldfish Xepomis gibbosus/Pumpkinseed Sunfish Saltno trutta/Brown trout ^ Ictalurus nebulosus/Brown Bullhead Ambloplites rupeetris/Rock Bass Esox niger/Chain Pickerel Semotilus corporalis/Fallfish Ethcostoma nigrum/Johnny Darter Percopsis omiscomaycus/Trout-perch Alosa pseudoharangus/Alewife . Perea flavescens/Yellow Perch Catostomus comraersoni/White Sucker Stizostedion vitreum vitreum/Walleye Assorted Cyprinids (minnows) 7 1 2 1 i i 7 3 2 2 120 127 68 18 44 4.5" to'5.8" 1.1", 4.7" .- ' - ' 6.6" to 7.9" 8.0" to 8.8" ' 2.0", 2.1" 2.2", 3.2" 2.4" to 11.7" 3.1" to 7.7" 2.2" to 14.2" 6.4" to 11.7" 1.6" to 4.8" 5.2" 10.8" 2.9" 10.1" 6.2" 2.1" 7.4" 8.4" 2.05" 2.7" 5.2" 5.2" 5.2" 8.5" - 2.9" f DSW 029037 STLCOPCB4012999 TABLE NO. 4c SAMPLE FROM STATION 4b TRANSPORTED TO DEC ROME LAB - 9/19/75 HUDSON RIVER - FT. EDWARD VICINITY OF ROGERS ISLAND Date Tag No. ' ` Length Weight Species________ ________________ (inches) (ounces) 9/18/75 9/18/75 91 1 n 1 II If ii 91 II .n II * it i I n H ti ii it n ii ii if 91 11 11 91 S> ii n 6R8265 6R8266 6R8267 6R8268 6R8269 6R8270 6R8271 6R8272 6R8273 6R8274 6R8275 6R8278 6R8276 6R8280 6R8277 6R8279 6R8281 6R8282 6R8283 6R8289 6R8285 6R8284 6R8286 6R8288 6R8290 6R8291 6R8292 6R8293 6R8294 6R8296 6R8295 6R8297 White Sucker . n .ii ,, 91 IV 91 11 91 If II VI 91 II I II # it II * ii . j 91 Walleye II 91 l . H 9* * ' 91 II 91 91 .*> 91 . - 'z'+' 91 w . t.i ' . .. . 91 . tf Yellow Perch i n ii ii II 99 ii 6R8299 . ii ii 11 6R8298 91 tt It 6R675 It It 91 6R688 n 6R678 tt It 91 II ii * 6R682 II Vt 91 Untagged in Plastic Bag '* " ii 91 11 II ii ii ii n n II II 91 It It ii 11 II 11 98 If 91 ii 91 91 91 n tt ii B< . II 91 91 ii n ti 91 n 91 91 91 91 It 91 91 II 91 91 91 It 91 91 91 91 91 It It . . ` ` " . . ' .. ' : ' 11.6 11.5 13.2 13.1 14.2 8.1 9.6 16.0 15.5 19.5 4.5 6.5 V. ^ - 8.5 8.1 8.6 . 4.5 4.5 4.5 7.8 4.0 7.2 2.5 7.6 3.0 - 7.8 3.0 .. 7.1 ' 2.5 ; 8.0 3.5 . . 7.8 3.0 8.3 4.0 7.5 3.0 6.9 2.5 6.8 2.0 6.6 . 2.0 7.2 . ' 2.5 6.4 2.0 6.7 2.0 11.7 10.5 10.7 7.5 11.3 9.0 11.3 " 7.8 . 8.5 4.0 7.7 3.5 7>2 3.0 . 7.4 3.5 . 6.8 3.0 6.8 3.0 6.8 . 2.5 7;4 3.5 7.1 3.5 6.9 3.5 3.6 4.7 4.4 4.2 . 3.5 3.5 ` 3i8 3.7 * ft ' * OSW 029038 STLCOPCB4013000 TABLE NO. 4c - Continued Date 9/18/75 H. * II II . . 1 * II II ' If tl II ^ II II . II It tt * ' II II Tag No. ; Length - >. `Species.___________________________ (inches) Untagged in Plastic Bag II If . ft II tl II tl II n 11 II tv IV it II >1 VIII II It , II II If II n tl tl tl II tl tl II n II . It It ' *It 11 11 tl II tl II II 11 II ft II 11 If - II IIII tl tl tl tt tl II tt tl ' It II n * II II ft tl tl II II II tl 11 II It . tl tt II Yellow Perch 11 II II tt II tl II i If II 11 tl It tl tl II 11 II II II tl It 11 II II tt tt i II . tl If tl II tl tl tl tl * t 11 It , . . .' 3.5 4.3 4.4 3.8 4.3 3.0 3.9 3.1 3.8 3.2 3.7 4.9 5.1 4.8 5.0 4.8 5.4 4.7 5.5 4.8 5.8 .9 Weigh't (ounces) osw 029039 STLCOPCB4013001 ./ --V TABLE 4d. % TRANSFER DOCUMENT - FOB SAMPLES A/ >!m fr3i__ I* RV/710N6 tl * >V/ftmi ~ Gene /aye (name) on .* have received 9-/4-7S " (naae) tfubSON fl\Yf'{ (datif the following from__________ j. (water) ' Tag No, Species Sr2o5 Common Sucker 6R8266 Common Sucker 6R3267 6R3263 Common Sucker Common Sucker 6R8269 Common Sucker . 6R8270 . Common Sucker 6R8271 Common Sucker 6R8272 Common Sucker 6R3273 6RS274 Oojnmon Sucker ' Common Sucker 6R8275 Walleye 6R8278 Walleye 6R8276 ' Walleye 6R8280 Walleye . 6R8277 Walleye . 6B8279 6R8281 Walleye Walleye. . 6R8282 Walleye 6R8283 6R8289 6R3285 Walleye Walleye Walleye . . 6rS284 Walleye ` 6R8286 Walleye . . . 6R8268 Walleye 6R3290 Walleye . 6R8291 Walleye . 6R3292 Walleye 6R3293 Walleye . . 6R3294 Yellow Perch 6R8296 Yellow Perch 6R3295 6R3297 ' Yellow Perch Yellow Perch 6R8299 6R3298' Yellow Perch Yellow Perch 6r675 6r688 Yellow Perch Yellow Perch 6Ro73 . Yellow Perch 6R082 Yellow. Perch One plastic bag containing 20 untagged yellow perch ranging in size from 3.0" to 4.7" in total length. ' One plastic bag containing ?r> untagged yellow perch ranging in :;!ze from 4.7" to 5.o' in `o^al length.- ' * DSW 029040 STLCOPCB4013002 TABLE (continued). ~2- from The aforementioned items were obtained by X/9 Mb tfvx>soN ( name) in the vicinity of_ ftntt-RS Ts/flSb- FoQrbuJfbM located in the TOWnCQff^rftcO^RO V ftlofrL'rl U , tip* V Xn RFiTOff) Counting$SPccr>s*rLY Time Collected: ^'00 /?M ~fo 00 ftAj. . ' Date Collected:Q * f 3 *7^__________ ' ' .... Said items were first transported and hand-delivered and were in the custody of (T/c hU? /j9aJ{T at all times until transferred to and hand-delivered by those persons at times and dates indicated below: Delivered To______ .____________' ' Time . Date .__________ Signature !-1.$nurri loizoRM <?/? 7a" l?c^ Ml M v- K.-i, s r t n Pin //rjl V t. . ^* Jjr Collector Last Received: (Name-Print) (Signature) DSW 029041 STLCOPCB4013003 TABLE NO. 5a HUDSON RIVER - STATION 5a , 7/28-29/75 - TOTAL COLLECTION w Species Catostomus commersoni/White Sucker Ictalurus nebulosus/Brown Bullhead Perea flavescens/Yellow Perch __ Micropterus dolomieui/Smallmouth Bass Notemigonus crysoleucas/Golden Shiner Lepomis gibbosus/Pumpkinseed Sunfish Cyprinus carpio/Carp Carasslus euratus/Goldfish Total # 37 22 5 1* 1 12 1 10 .1 Range 5.9" to 14.9" 6.2" to 12.0" 4.5" to 5.5" 4.8" to 7.2" 6.9" to 17.3" Ave. Size 12.0" 10.7" 5.1" 11.0" 13.4" 5.7" 6.2" 12.1" 9.9" . 4 Species ' Sample Transported to DEC Rome Lab . Location Length (inches) Smallmouth bass CHicropterus dolomieui). 5 miles below Ft. Edward 11.0 Walleye C* (Stizostedion vitreum) . 5 miles below Ft. Edward . 13.4 White sucker (Catostomus couriersoni) 5 miles below Ft. Edward . 'J / Weight (pounds) 0.74 0.87 -. Composite No. 23-HUD-75-DN 24-HUD-75-DN 51-UUD-75-DN ' 48-HUD-75-DN 40-HUD-75-DN 54-HUD-75-DN ' 52-Hud-75-DN * 49-Hud-75-DN C osw 029042 STLCOPCB4013004  fipecies TABLE NO. ?b HUDSON RIVER - 5 mi. DOWNSTREAM FROM FORT EDWARD-STATION 5b SAMPLE COLLECTED - 9/l6-17/75 Total # . Range Ave. Size Catostomus commersoni/White Sucker Lepomis gibbosus/pumpkins eed Sunflsh Perea flavescens/Yellow Perch Ambloplites rupestris/Rock Bass Notemigonus crysoleucas/Golden Shiner Salmo trutta/Brown Trout Esox niger/Chain Pickerel Stizostedion vitreum vitreum/Walleye. Micropterus salmoides/Large-mouth Bass Carassias auratus/Goldfish Ictalurus nebulosus/Brown Bullhead Percina caprodes/Log Perch t Alosa pseudoharangus/Alewife Etheostoma nigrum/Johnny Barter Assorted Cyprinid Species 53 37 . 222 11 ia 1 4 4 2 2 8 1 125 2 e? 2.8" to 14.5" 1.5" to 6.3" 2.9" to 7-7" 1.7" to 7.3" 2.7" to 7.5" - 7.2" to 8.1" 5.6" to 11.4" 6.9" 3.9" 4.2" ' 3.8" 4.9" 10.0" 7.6" 8.2" 3-5% 3-9" 2.9", 4.2" 2.4" to 11.4" - 2.1" to 4.0" 3.7" 3-5" 9.9" 2.7" 2.8" 1.3", 1.8" 1*5" to 3.5" 1.5" 2.6" DSW 029043 STLCOPCB4013005 TABLE MO. 5c . SAMPLES FROM STATION 5*> TRANSPORTED TO DEC ROHE LAB - 9/18/75 HUDSON RIVER - 5 MILES DOWNSTREAM FROM FT. EDWARD Date Tap:. No. A Species Length (inches) 9/17/7.5 It ft f ft- ft ft ft ft ft. ft ft ft ft ' * ft ft n ft / ft ft ' M ft II * ft ft . ft 9/16/75 ft ft ft ft ft ft ft ft . 6R7800 6R7801 6R7802 6r?803 ' ' 6R7804 6r?805 6r?8o6 6r?807 6R7808 6R7809 Untagged in Plastic Bag ft ft ft ft ft ft ft * * ft ft ft t, ft ft ft .* M *f ft ft ft . ft N - W ft ft ' ft ft M. t 1 ft ft ft ft ft ft ft ft ft n ft w ft ft ft ft ft ft ft ft ft ft ft ft ft ft ft . ft ft ft ft ft ft ft ft w ft ft ft ft ft ft ft ft 6R698 6R679 6r665 6r662 6r68? 6n669 6R694 6R683 6R691 6r66i 6r6?3 Yellow Perch ti it it ft ft t ft ft 11 ft . tt * ft ft . ft ft ft ft ft ft ft ft f ft ft . . ft . ft ft t ft tt ft ft ft ft . w . ft It w . ft .' . * ft it * f ft ft ft ft ft - Broun Bullhead ft ft ft ft ft - ft ft ft ft . ft . White Sucker ft ft ft ft ft ft ft ft 6.7 5-5. 6,5 5.4 6.5 7.6 7.5 . 6.6 6.8 7.7 3.9 4.2 3.3 3.8 3/5 4.0 4.2 3.7 3.4 3.8 3.4 3.3 3.2. 3.4 ' 3.2 3.7 3.5 3.5 3.7 3.4 11.4 9.3 10.0 10.6 lo.o 11.3 13.0 13.8 14,0 14.5 12.8 Weight (ounces 2.5 2.5 2.5 2.0 2.5 4.0 4.0 2.5 3.0 4.5 - 12.5 7.0 7.0 10.5 10.0 12.5 . 20,0 22.0 23.0 23.0 19.0 OSW 029044 STLCOPCB4013006 Tta.te 9/16/75 ** # M t< 9/17/75 9/16/75 ' TABLE NO. $c - Continued Tag. No. 6R67? 6r6Q0 6R696 6R663 6R695 6R699 6R697 " . Suedes White Sucker . *1 ! . ' M t* - t fl M Walleye Walleye Length * Weight . (inches) (ounces) 11.0 10.7 10.2 10.9 8.9 9.9 11A 10.0 8.5 9.5 9.5 5.5 6.5 10.0 Snapping Turtle - 5 lb. (live) r< j 8 * QSW 029045 STLCOPCB4013007 i* * TABLE 5<5L........... * ' TRANSFER DOCUMENT - FOB SAMPLES frbm 6R7302 Yellow Perch 6R7803 6R7804 Yellow Porch Yellow Perch 6R7805 6R7806 Yellow.Perch Yellow Perch 6R7807 6RT308 Yellow Perch . Yellow Pprch 6R7809 Yellow Perch * 6R698 Brown Bullhead- 6r6?9 6R665 6R662 Brown Bullhead Brown Bullhead Brown Bullhead .6R687 6B669 Brown Bullhead Brown Bullhead 6R694 White Sucker 6R633 White Sucker 6R691 6b66i White Sucker White Sucker . - 6R673 . 6R677 6R680 White Sucker White Sucker White Sucker 6R696 White Sucker. ' 6R663 White Sucker 6R695 t6rd99 White Sucker Walleye 6R697 Walleye A plastic bag containing 20 untagged yellow perch ranging- in size from 32" to 4.2" in total length. 1 snapping turtle, approximate weight 5 pounds, live The aforementioned items were obtained by_ (yfj /f) tlx hlubSON PiV/Sfl (name) in the vicinity of /T fll/Oc"L OUJtisrtffi (water) __ located in the Towtf^jf f'pfif /fbiOFtRh PlofWf} U VlhSlUMIo* f totA Coun^. ttif&rioeiY. ; OSW 029046 STLCOPCB4013008 '* TABUS 5d (continued) ' /< ' *"2- . Time Collected: Cj'.ooRm i-jb'ao f/fl . Pate Collectedq/iihsRHb *!17/74-__________ __ Said items were first 'transported and hand-delivered and were in the custody of _ frfc/v/T ____________ at all times until transferred to and hand-delivered by those persons at times and dates indicated below: T DSW 02904? STLCOPCB4013009 TABLE NO. 6 HUDSON RIVER - WATERFORD - STATION 6 SAMPLE COLLECTED 8/26-27/75 Species ' Total # Catostomus commersoni/White Sucker Hicropterus dolomieui/Smallmouth Bass Micropterus salmoides/Largemouth Bass Stizostedion vitreum vitreum/Walleye Morone. americana/White Perch ' .. Morone.saxatilis/Striped Bass Cyprinus carpio/Carp . Carassius auratus/Goldfish Ambloplites rupestris/Rock Bass Lepomis gibbosus/Pumpkinseed Sunfish Ictalurus catus/White Catfish Xctalurus natalis/Yellow Bullhead Ictalurus nebulosus/Brown Bullhead Dotosoma cepedianum/Gizzard Shad 83 10 -1 3 67 7 4 5 4 6 3 1 1 .1 Range Ave. Size 8.8" to 16.9" 8.7" to 14.0" .- ' 14.2" to 18.5" 6.0" to 9.0" 8.7" to 22.1" 14.5" to 27.0" 7.6" to 12.3" 6.5" to 8.8" 6.4" to 6.9" 9.4" to 10.5" . .. ' . .. - .. ' 13.0" 11.2" 8.9" 16.3" 7.3" 13.9" 20.6" 10.7" 7.6" 6.6" 9.8" 10.8" 12.5" 12.4" DSW 029048 STLCOPCB4013010 TABLE NO. 6a PCB SAMPLE - HUDSON RIVER - STATION 6 - WATERFORD, N. Y. AREA . MOUTU OF MOHAWK RIVER UPSTREAM TO LOCK til . * 8/25-27/75 . Date .. Tag No. ' 8/26/75 If ft 8/27/75 i * n 8/26/75 tl it . 6R1410 6R1411 6R1421 6R1433 6R1436 6R1437 6R1417 . 6R1418 6R1419 6RI420 8/26/75 II . it it tl 8/27/75 8/26/75 II 8/27/75 ft II 8/26/75 II * 6R1405 6R1424 6R1425 6R1426 6R1429 6R1430 6R1409 6R1423 6R1431 . 6R1432 6RI438 6R1415 6R1416 . Species Smallmouth "Bass > If 91 It ft II It II It n II ft ' tl White Sucker ' II it ft ft II t it II it " It . It - ft Walleye It . . - * . ' '. - . . Length (inches') 8.7" 10.1 .10.7 10.1 10.5 9.9 14.0 13.3 12.9 11.5 12.5 11.0 . 11.8 12.1 11.7 8.8 16.5 16.5 16.5 15.5 15.7 ' 18.5 16.1 Weight (ounces DSW 029049 STLCOPCB4013011 APPENDIX F ( Data Quality Assurance C .. . (* osw 029050 STLCOPCB4013012 COMMISSION CPI STATE OF NEW YORK DEPARTMENT OF HEALTH NEW SCOTLAND AVENUE ALBANY. NEW YORK 12301 October 30, 1975 division of laboratories AND RESEARCH DONALD J. OEAN. D.V.M. DIRAC TO A 0. WOLFCANO FUHS, Ph.O. OIRtCTOR tNVmONMENTAL HEALTH RENTER Mr. Russell Mt. Pleasant . Division of Pure Waters ' Bureau of Monitoring and Surveillance N.Y.S. Department of Environmental Conservation 50 Wolf Road Albany, New York Dear Mr. Mt. Pleasantt Enclosed please find a report on the quality assurance for PCB analyses comprised of the currently available data for several collaborative studies. An updated report will be issued as more data becomes available. f Very truly yours, C rs> James C. Daly Principal Sanitary Chemist XD/mb EnCs. \ \ S DSW 029051 STLCOPCB4013013 Quality Assurance for PCB Analyses In order to ascertain the reliability and comparability of polychlorinated biphenyl (PCB) data being generated by several laboratories involved in PCB analysis of environmental samples in New York State, a series of interlaboratory comparison studies was initiated. These interlaboratory studies included the analysis of the following types of samples: (1) Known amounts of single Aroclors in an organic solvent, (2) Known amounts of mixtures of Aroclors in an organic solvent, (3) Known amount of a single Aroclor in water, (4) Split samples of fish tissue, (5) Split sample of sediment. The following laboratories participated in one ox more of these collaborative studies. N.Y.S. Department of Environmental Conservation, Rome, New York . N.Y.S. Department of Health, Albany, New York U.S. Environmental Protection Agency, Edison, New Jersey U.S. Environmental Protection Agency, Cincinnati, Ohio N.Y.S. Department of Agriculture and Markets, Albany, New York N.Y.S. Department of Environmental Conservation, Stony Brook, New York U.S. Environmental Protection Agency, Duluth, Minnesota U.S. Food and Drug Administration, New York, New York The preliminary results of each of these collaborative studies is presented in this report. .... . . . . The relative standard deviation (RSD) and bias have been calculated where 3 or more values have been reported. Hexane Solutions of Single Aroclors . A blank and two known concentrations of single Aroclors in hexane as described in Table 1 were prepared by Dr. Brian Bush of theDivision of Laboratories and Research in the New York State Department of Health. These three solutions were distributed to four participating laboratories. This study was designed to determine the capability of the laboratories to identify and quantitate a single PCB in an organic solvent containing no interfering substances. The results of this intercomparison are tabulated Jn Table 1. For the record it should DSW 029052 STLCOPCB4013014 ^aHWrilli<lili><>r->r,tfnfflrrr>ir 'i..1................ be noted that laboratory 1 originally reported a value of 0.43 for Aroclor 1254 in sample D. The value in Table 1 is a corrected value, the original value of,0.43 reflected an error in the injection volume. Iso-octane Solutions of Aroclor Mixtures Two PCB mixtures in iso-octane with known concentrations as noted in Table 2 were prepared by the Operations and Review Section of the Environmental Protection Agency in Edison, N.J. These two solutions were distributed to five laboratories for analysis. The intent of this interlaboratory comparison was to test the ability of the laboratories to distinguish Axoclors in PCB mixtures and to quantitate the components of the mixture. The data for this study is presented in Table 2. Needless to say, the differentiation of Aroclor 1016 from Aroclor 1242 is extremely difficult, thus sample E-2 presents a most difficult case for interpretation of gas chromatographic data. PCB In Water A blank and two known concentrations of a single Aroclor in water were prepared and distributed by the Operations and Review Section of the EPA Laboratory in Edison, N.J.. No comparison data is available for these three samples at this time. Split Samples of Fish The fish samples were composited, ground and mixed by EaxT Harris of the Department of Environmental Conservation in Rome, New York. Five fish samples were split among six laboratories. The samples were placed in small polyethylene bags for distribution by Dr. Brian Bush of the New York State Department of Health, The samples were shipped frozen to the participating laboratories. The data for the split samples of fish appear in Table 3. Split Sample of Sediment One sample of sediment was split among three laboratories. The sample was mixed, then portions placed in all-glass containers for shipment to the participating laboratories. The data for the split sediment sample is presented in Table 4. James C. Daly Quality Assurance Officer C Environmental Health Center tJ.Y.S; Department of Health October 30, 1975 DSW 029053 V STLCOPCB4013015 table 1 Laboratory Intercomparison Study of Single Aroclors in a Hexane Solution Sample A' B Aroclor 1016 1242 1254 1016 1242 1254 Known (pg/mL) 0 0 0 Laboratory Code 1 . 2 3 4 RSD (pgM) _ (pg/tnl) (pg/ml} (pg/ml} 000 0 0000 000 0 0.80 0 0 0.89 a a a 1.09 a 1.15 a a t y 21# a Bias +20# D 1016 0 a a -a a 1242 0 a a a a 1254 0.95 0.92 1.32 1.01 0.97 17# +11# a) No va lue reported for this Aroclor. Sample E-l Table 2 Laboratory Intercomparison Study of Aroclor Mixtures in an Iso-octane Solution Laboratory Code Aroclor 1016 1242 1254 Known (ng/mi) 55.5 0 72.0 1 (pg/ml) a 73.3 92.8 2 (ng/mi) 3 (ng/mi) > 8 39.8 90.4 4 (pg/ml) .- 7 RSD (pg/ml) rV26a 52# 91 1.4# Bias -17# +21# . B-2 1016 1242 1254 61.0 64.5 0 70.0 50.0 a a 70.3 a 38 60 17# -6.8# a 1 ) No value reported for this Aroclor. . .' DSW 029054 STLCOPCB4013016 Table 3 Laboratory Intercomparison Study of PCB in Fish Sample F4830 F4831 F4842 F4844 F4845 Aroclor 1016 1254 1016 1254 1016 1254 1016 1254 1016 1254 Laboratory Code 1 234 56 (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ba - 3.69 a. 3.3 a 2.58 4.3 6.0 , 0 2.32 4.37 b -a a 1.0 b 4.34 8.4 7.16 9.5 8.49 aa 6.6 5.55 c a - 4.2 a 6.34 c RSD 45# 11# a) No value reported for this Aroclor. b) No sample sent to this laboratory. c) Sample not analyzed. . DSW 029055 STLCOPCB4013017 Table 4 Laboratory Intercomparison Study of PCB in Sediment Sample 1. ' Laboratory Code Aroclor 478 (mg/kg) (mg/kg) (mg/kg) 1016 1254 .. 59 4 45.5 4.4 RSD a) Calculated as mg PCB/kg of dry weight. DSW 029056 STLCOPCB4013018