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CLASS A TYPE I
VAB.0001053776
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
ACETIC ACID, GLACIAL
TRADENAME(s)
CODE
Glacial Acetic Acid
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A
EXPOSURE LIMITS
CLASS A
TYPE 1
DEPARTMENT
PPM
TOXIC
LIMIT
VALUE
(tlv)
SH0RT"TERM
EXPOSURE LIMIT
(stel)
10 15 25 37
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE x LABORATORY
EFFECTS OF OVEREXPOSURE I
Highly corrosive. Causes severe burns. May be fatal, if swallowed. Eye and lung damage possible
PURPOSE AND METHOD
use:
A Lab solvent used in the TLC analysis of dry blend and in determining "Iodine values" of soya epoxy (latter test rarely performed).
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood, rubber gloves, rubber apron
FIRE HAZARDS: Moderate when exposed to heat. Can react vigorously with oxidizers;
incompatible with carbonates, hydroxides, many oxides and phosphates. Extinguish
with water, dry chemical or CO2.
FIRST AID: Internal: Call a physican. Do not give emeti
or milk of magnesia. If Inhaled; move to fresh air. skin with water for at least 15 minutes.
. Give tap water, milk. External: flush eyes or
VAB.0001053777
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
ALKYTIN MERCAPTIDE
tradename(s)
. CODE
414 538 536 537 203
Advastab TM-387 Advastab TM-692 Advastab TM-181 Mark 1925 Thermolite 101
ii
EXPOSURE LIMITS TOXIC SHORT-TERM
EXPOSURE
A
CLASS TYPE
A1
DEPARTMENT
COMPOUND X DRY BLEND
PLASTICIZER VINYL MAINTENANCE LABORATORY
OVEREXPOSURE!
Tin poisoning. Symptoms include brain damage, weakness, poralysis.
PURPOSE AND METHOD OF USE:
Used in large quantities as a heat stabilization additive in "Dry Blended'1 PVC rigid compounds.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, rubber apron.
FIRE HAZARDS:
Not easily ignited, but will support combustion. Extinguish with dry chemical
FIRST AID:
Fresh air for overexposure. Skin: Wash with soap and water, remove contaminated clothing. Eye: Flush with water, get medical attention.
VAB.0001053778
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ABETDEEkj MISSISSIPPI
CHEMICAL NAME: ALPHA METHYL STYRENE
RM CODE
tradename(s)
344 1 Alpha Methyl Styrene (AMS)
1 1
SW>F ^r** "nlbl<" /
p.
1
PPM Ms/M3
EXPOSURE LIMITS
1
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
100 100 480 480
CLASS TYPE AI
1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER X VINYL
MAINTENANCE , LABORATORY
EFFECTS OF OVEREXPOSURE:
Nasal irritation, dizziness, and narcosis. Liver and kidney damage possible.
PURPOSE AND METHOD
USE*.
Used as the normal polymerization terminator in PVC production. Poured from drums, by hand, into buckets, thence into open mixing tanks, thence into a reactor charge pot.
PROTECTIVE EQUIPMENT REQUIRED:
Plastic gloves.
FIRE HAZARDS:
Moderate when exposed to heat or flame. Incompatible with oxidizing materials, copper
and copper alloys. Extinguish with water fog, CO2, and dry chemical - use Scott
Air Pak.
FIRST AID:
Eyes: Flush with water for 15 minutes; Skin: Wash skin and clothing with soap and water: Inhalation: Remove to fresh air, keep warm and quiet, - if breathing stops, give artificial respiration Ingestion: Induce vomiting.
NOTE GET MEDICAL ATTENTION IN ALL CASES.
VAB.0001053779
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME: AMMONIUM HYDROXIDE
tradename(s)
. CODE
Ammonium Hydroxide
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A
CLASS TYPE
EXPOSURE LIMITS
DEPARTMENT
PPM Ma/M
TOXIC LIMIT
SHORT-TERM EXPOSURE LIMIT (stel)
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE!
Severe irritation of skin, eyes, and mucous membranes. May produce corneal (eye), heart, and respiratory tract damage.
PURPOSE AND METHOD OF USE:
amount
as a neutralization medium
in the determination of iron in waste water and VCM, and occasionally in phthalic
acid testing.
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood.
FIRE HAZARDS:
Slight; when heated, it emits toxic fumes.
Can
with oxidiz
FIRST AID:
Skin & Eyes:
Flush with water for 15 minutes
Inhalation $ Ingestion: See Physician.
VAB.0001053780
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
ANTIMONY TRIOXIDI
tradename(s)
. CODE
Antimony Trioxide 456 Oncor 75 RA
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A
EXPOSURE LIMITS
DEPARTMENT
PPM
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
0-5 (Sbl i' -75
X COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
overexposure:
Prolonged excessive exposure may result in gastro
intestinal upset, nervous complaints, and in-
fTarnation of mucous membranes of nose and throat.
PURPOSE AND METHOD OF USE:
Used as a flame retardant additive in certain PVC compounds. paper bags into compound blenders.
It is poured by hand from
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, cotton gloves.
FIRE HAZARDS:
Slight; when burned, it forms Sb204 and Sb20s.
water fog, CCb.
Extinguish with dry chemical,
FIRST AID:
Abnormal Ingestion: Call a physician at once, give milk and magnesium sulphate (Epsom Salt), and water. Eyes: Treat as a dust.
As first aid, induce vomiting. External: Wash skin with soap
VAB.0001053781
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ABERDEEN. MISSISSIPPI
CHEMICAL NAME: BARIUM/CADMIUM COMPLEX
tradename(s)
CODE
397 398
Synpron 1438 V-1313
402 411 412 401
Mark 1314 Mark 2045 Interstab R-4023 Mark SC III-32A
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A
EXPOSURE LIMITS
CLASS TYPE
A1
DEPARTMENT
PPM
TOXIC SHORT-TERM LIMIT EXPOSURE
0.6 (Cd)
X COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE , LABORATORY
EFFECTS
OVEREXPOSURE:
Many and Varied: Headache,incoordination, irritation, vomiting, abdominal pain, diarrhea, systemic toxic effects (heart, lung, brain).
PURPOSE AND METHOD OF USE:
These materials are heat stabilizer additives to certain PVC compounds.
compound blenders in bulk, they include liquids and powders.
Added to
PROTECTIVE EQUIPMENT REQUIRED:
Rubber apron, cotton gloves, dust mask with solid materials
FIRE HAZARDS:
Cadmium dry chemical, water fog.
Extinguish with CO2,
FIRST AID:
Eye: Flush with water for 15 minutes. Skin: Wash with soap and water. Ingestion: Consult physician Inhalation: Remove to fresh air.
VAB.0001053782
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ABERDEEN. MISSISSIPPI
CHEMICAL NAME:
BARIUM CHLORIDE
TRADENAME(s)
.CODE
Barium Chloride
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PPM
EXPOSURE LIMITS
T
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
0.5
CLASS
A
TYPE 1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL
X MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Highly toxic. May produce damage to heart, lungs, digestive tract, and central nervous
system.
PURPOSE AND METHOD OF USE:
Used in solution as a water testing reagent. Usage is minimal
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
Minimal hazard
FIRST AID:
If Swallowed: Give 1 tablespoon of Epsom Salt in a glass of wat vomiting by giving 1 tablespoon of salt in a glass of warm water warm salt water until vomit fluid is clear. CALL A PHYSICIAN.
Induce Repeat
VAB.0001053783
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ABERDEEN. MISSISSIPPI
CHEMICAL NAME:
BROMINE
TRADENAME(s)
CODE
Bromine
A
CLASS
A
TYPE 1
EXPOSURE LIMITS
DEPARTHENT
PPM
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM EXPOSURE
LIMIT (stel)
COMPOUND DRY BLEND PLASTICIZER VINYL
o.i
0.3
MAINTENANCE
0.7 '
2__________ X LABORATORY
EFFECTS
OVEREXPOSURE:
Causes severe burns to eyes, nose, throat, lungs (pulmonary edema possible).
PURPOSE AND METHOD OF USE:
A Lab chemical retained for possible use in Bromine/water testing. Use is very low.
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood, rubber gloves, faceshield, rubber apron
FIRE HAZARDS:
Moderate; may ignite a combustible material upon contact. A very powerful oxidizer. Emits highly toxic fumes when heated, will react with water or steam
FIRST AID:
Call A Physician. Eyes or Skin: Flush with water for 15 minutes. Inhalation: Remove to fresh air and give artificial respiration if
VAB.0001053784
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ABERDEENj MISSISSIPPI
CHEMICAL NAME:
CARBON BLACK
tradename(s)
CODE
444 929 950 445
Nuchar K-80 Carbon Black 83B104 F-5960 Black (Mupco) Darco S-51
A
CLASS TYPE
EXPOSURE LIMITS
DEPARTMENT
TOXIC SHORT-TERM LIMIT EXPOSURE
PPM
3.5
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Many suspected effects, including heart, corneal (eye) and bronchial damage. Material suspected of being carcinogenic in nature.
PURPOSE AND METHOD
USE:
compound interface indicator during plasticizer production.
a water/plasticiz
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, cotton gloves.
FIRE HAZARDS:
Slight; when exposed to heat or flame chemicals.
Avoid contact with strong oxidizing
FIRST AID:
SKIN/EYES: Flush with water
VAB.0001053785
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME: CATALYZED HYDRAZINE tradename(s)
CODE
Catalyzed Hydrazine
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# m it-nr r mm m
EXPOSURE LIMITS
DEPARTMENT
PPM Me/M
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
1.3
COMPOUND DRY BLEND PLASTICIZER VINYL X MAINTENANCE , LABORATORY
EFFECTS
OVEREXPOSURE:
Vapors irritating to eyes, nose, respiratory system. Direct contact results in caustic-type bums. Long-term overexposure may product liver/ blood damage. A suspected carcinogen.
PURPOSE AND METHOD
USE:
Used as a boiler water treatment additive
thence metered into water stream.
Poured from drums into mixing vats.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, faceshield.
FIRE HAZARDS:
Moderate to severe when exposed to heat and/or oxidizing agents.
FIRST AID:
Skin: Wash with large volumes of water. Eye: Consult eye physician immediately. Ingestion:
Flush with large volumes of water. CONSULT PHYSICIAN IMMEDIATELY.
VAB.0001053786
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ABERDEEN/ MISSISSIPPI
CHEMICAL NAME:
CHLORINE
tradename(s) CODE
Chlorine
PPM
COM O C O '
l MV li t
i
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EXPOSURE LIMITS
!
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
13
39
k
CLASS
A
TYPE
1
DEPARTMENT
1
COMPOUND DRY BLEND PLASTICIZER VINYL X MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Causes severe bums when inhalated. Can cause death if massive quantities are involved. Long term exposure suspected of causing cumulative
lung damage.
PURPOSE AND METHOD OF USE:
Used as a cooling tower water additive. Contained in pressured bottles and metered directly into water in a closed system.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, chlorine gas mask.
FIRE HAZARDS:
Moderate; can ether, ammonia
to cause fires or explosions upon contact with turpentine, , hydrocarbons, hydrogen, and powdered metals.
FIRST AID:
CALL A PHYSICIAN, Remove to safe keep warm, quiet.
EYES: Flush with water, SKIN: Flush with water, INHALATION: - if still breathing, place on back with head and back elevated.
VAB.0001053787
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME: CHLOROFORM
tradename(s) CODE
Chloroform
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K1
CLASS TYPE
EXPOSURE LIMITS
PPM
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
240
v+
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
An anethesiao. May produce cumulate liver and kidney damage. A suspected carcinogen.
PURPOSE AND METHOD OF USE:
A Lab solvent used in small quantities 1-2 times each year in preparing chromatoeranh columns.
PROTECTIVE EQUIPMENT REQUIRED:
Vent Hood
FIRE HAZARDS:
Slight, when exposed to high heat; otherwise practically non-flammable.
FIRST AID!
PHYSICIAN: INHALATION Remove to fresh air, give artificial respiration if necessary. INGESTION: Induce vomiting _i_f___c_o__n_s__c_i_o_us. Do not induce vomiting if unconscious. EYES/SKIN: Flush with water for 15 minutes.
VAB.0001053788
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ABERDEEN- MISSISSIPPI
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CHEMICAL NAME:
DIBASIC LEAD PHOSPHITE
tradename(s) CODE
451 Oiled Dyphos
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (STEL)
PPM
0.2 (Pb)
0.45
EFFECTS
OVEREXPOSURE:
CLASS TYPE
ma
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
Lead poisoning. Damage cells. Sympt
gum
and blood , cramps,
PURPOSE AND METHOD OF USE:
Used in large quantities as a heat stabilizer additive to certain PVC compounds. It is poured by hand from paper bags into compound blenders.
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves.
FIRE HAZARDS:
Moderate when exposed to high heat. There are no suitable extinguishing agents - isolate, scatter to cool and use sand to contain smoldering material.
FIRST AID:
ABNORMAL
PHYSICIAN
give milk and magnesium sulphate (Epsom Salt).
EYES: Flush with water.
aid, induce vomiting. SKIN; Wash with soap and water
VAB.0001053789
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME: DIBASIC LEAD PHTHALATE
TRADENAME(S) , CODE
302 Dythal XL 303 Cyastab 988
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f / \(
*m WWrf
\r 'V f ">
W KM Hfc J
^ mr m> n wii r wt mfi
%
CLASS
1A
TYPE
1
EXPOSURE LIMITS
DEPARTMENT
PPM
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (STEL)
0.2(Pb)
0.45
X COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE , LABORATORY
EFFECTS
OVEREXPOSURE:
Lead poisoning. Damages liver, kidney, and blood cells. Symptoms include gastric upsets, cramps, fatigue, loss of gum pigmentation.
PURPOSE AND METHOD
USE:
Used in large quantity as a heat stabilizer additive to certain PVC compounds, is poured by hand from paper bags into compound blender.
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves
FIRE HAZARDS:
Moderate when exposed to high heat.
Extinguish with dry chemical, CO2, water fog
FIRST AID:
ABNORMAL INGESTION: CONSULT A PHYSICIAN AT ONCE, vomiting, give milk and magnesium sulphate (epsom with soap and water. EYES: Flush with water.
P
aid, induce SKIN: Wash
VAB.0001053790
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME: DIBASIC LEAD STEARATE
tradename(s) .CODE
300 DS 207
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m * *cr a*
A
PPM
CLASS TYPE
A1
r
EXPOSURE LIMITS
DEPARTMENT
TOXIC LIMIT
l--
SHORT-TERM EXPOSURE
X
COMPOUND DRY BLEND
VALUE
LIMIT
PLASTICIZER
(tlv)
(stel)
VINYL
| r -r .
MAINTENANCE
0.2 (Pb) '
0.45
LABORATORY
EFFECTS
overexposure:
Lead poisoning. Damages liver, kidney, and blood cells. Symptoms include gastric upsets, cramps, fatigue, loss of gum pigmentation.
PURPOSE AND METHOD OF USE:
Used as a compound lubricant additive in certain PVC compounds. It is poured by hand from paper bags into compound blenders.
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves.
FIRE HAZARDS:
Moderate when exposed to high heat. Extinguish with dry chemical, CO2, water fog
FIRST AID:
ABNORMAL
PHYSICIAN
vomiting, give milk and magnesium sulphate (Epsom Salt),
and water. EYES: Flush with water.
SKIN:
aid, induce Wash with soap
VAB.0001053791
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ABERDEENj MISSISSIPPI
CHEMICAL NAME:
N.N - DIMLTHYL FORMAMIDE
::o/
n-
CLASS TYPE
TRADENAME(s) CODE
N,N - Dimethyl Formamide
EXPOSURE LIMITS
PPM
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
DEPARTriENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Possible cumulative liver damage via inhalation and skin absorption.
PURPOSE AND METHOD OF USE:
A Lab chemical kept on hand as a substitute for Dimethyl Acetamide, which is used twice each week in testing carbon for use in VCM dosimetry.
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood.
FIRE HAZARDS:
Moderate, when exposed to heat
Can react with oxidiz
FIRST AID:
INHALATION:
Remove from danger
and get prompt medical attention
EYES/SKIN: Flush with water for 15 minutes.
VAB.0001053792
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ABERDEENi MISSISSIPPI
CHEMICAL NAME:
DIPHENYLAMINE
tradename(s) , CODE
Diphenylamine
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Fr- rm m m *1 net -wrw **' ^
*
EXPOSURE LIMITS
CLASS TYPE
1A
1
DEPARTMENT
PPM Mk/M
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
EFFECTS
OVEREXPOSURE:
Cumulative liver, kidney, bladder damage possible
PURPOSE AND METHOD OF USE:
A Lab chemical intended
commonly
for use in testing Methocel
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
Slight, when exposed to high heat. Extinguish with water, CO2, dry chemical
FIRST AID:
Contact physician in
of overexposure
VAB.0001053793
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
ETHYL ETHER
tradename(s)
.CODE
Ethyl Ether
tconoco.'
PHf wi iff wiofi
A
PPM Mg/M
1A
TYPE
1
EXPOSURE LIMITS
T
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL
400 1200
500 1500
MAINTENANCE X LABORATORY
EFFECTS OF OVEREXPOSURE:
Narcosis and general anethesiac effect Irritant to skin and mucous membranes to drying effect.
PURPOSE AND METHOD OF USE:
A Lab solvent used in small quantities in TLC testing and solvent for testing materials made for Western Electric.
an extraction
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood.
FIRE HAZARDS:
Highly dangerous, in the presence of heat or flame. Extinguish with dry chemical or
C02.
FIRST AID:
INHALATION: Remove to fresh air, apply artificial Call a physician. INGESTION: Call a physician.
spiration if
sary.
VAB.0001053794
ABERDEEN, MISSISSIPPI
CHEMICAL NAME: HYDROCHLORIC ACID TRADENAME(s)
, CODE
Hydrochloric Acid
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l am to
ten >m
^ mm m w
fc
EXPOSURE LIMITS
CLASS TYPE A1
DEPARTMENT
PPM Me/M
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
55 77
COMPOUND DRY BLEND PLASTICIZER VINYL X MAINTENANCE X LABORATORY
EFFECTS
OVEREXPOSURE:
Highly corrosieve. May be fatal if swallowed Marked irritation of eyes, nose, throat.
PURPOSE AND METHOD OF USE:
Used in the Lab as an additive to the extraction solvent utilized during the analysis of calcium stearate on PVC resin.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE
HAZARDS:
4
Low as such, however, material is highly corrosive to most metals with evolution of hydrogen gas. which is highly flammable when mixed with a
FIRST AID:
CALL A PHYSICIAN;
SKIN
Flood with water then water containing sodium bicarbonate.
EYES: Flush with water for 15 minutes. INGESTION: DO NOT GIVE EMETICS. Give
tap water, milk or milk of magnesia.
VAB.0001053795
ABERDEEN^ MISSISSIPPI
CHEMICAL NAME:
HYDROGEN PEROXIDE
TRADENAME(S) CODE
Hydrogen Peroxide
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O
^ ^ta 'W5 j
wmi *mw m a xr r
A
mmm*4
EXPOSURE LIMITS
CLASS
TYPE 1
DEPARTMENT
PPM
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
1.4 2.8
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
EFFECTS
OVEREXPOSURE!
A strong irritant. Can Effects may be delayed.
eye injury.
PURPOSE AND METHOD OF USE:
A Lab chemical retained for possible use as a use has been negligible.
reagent in solution. Actual
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, faceshield, rubber apron
FIRE HAZARDS:
Dangerous by chemical reaction with flammable materials. Avoid heat or shock Extinguish with water.
FIRST aid:
EYES/SKIN: Flush with water for 15 minutes, for
, contact physician.
VAB.0001053796
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ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
HYDROQUINONH
TRADENAME(s)
CODE
346 Hydroquinone
'L r'fnoV1n! I ornJ '
^ **wi m* m m * vy nn n*;-m ** ^
fV
EXPOSURE LIMITS
CLASS
TYPE 1
DEPARTHEMT
PPM Ma/M
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT Istel)
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Cumulative corneal (eye) damage possible over long-term. A suspected carcinogen.
PURPOSE AND METHOD OF USE:
Used as a polmerization inhibitor additive to the recovery compressor in the vinyl production area.
water
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
Slight, when exposed to heat.
Extinguish with dry chemical, C02, water spray
FIRST aid:
In case of eye contact, flush with water for 15 minutes and contact a physician.
VAB.0001053797
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
IODINE
TRADENAME(s) CODE
Iodine
' J-Of lOCO'j
^l1 mm mmm m y-f ^ ^
CLASS \A
TYPE 1
EXPOSURE LIMITS
DEPARTMENT
PPM
TOXIC LIMIT
0.1
SHORT-TERM
EXPOSURE LIMIT (stel)
COMPOUND DRY BLEND PLASTICIZER VINYL
0.1 MAINTENANCE X LABORATORY
effects
overexposure:
Highly toxic. Can produce severe damage to eyes, nose, throat and lungs (pulmonary edema possible)
PURPOSE AND METHOD OF USE:
amoun t s "Iodine Value" tests on soya epoxy.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
Dangerous; when heated, it emits highly toxic fumes of iodine and iodine compounds; can react vigorously with reducing materials.
FIRST AID:
CONTACT A PHYSICIAN: EYES/SKIN: Flush with water for 15 minutes, INHALATION:
Remove to safe area, begin artificial repsiration, if necessary.
VAB.0001053798
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
LEAD CARBONATE
TRADENAME(s)
.CODE
851 Halcarb 20 EP
i <.conoco,
W ?*r ion*
^
EXPOSURE LIMITS
CLASS TYPE
A ,1
DEPARTflENT
PPM Me/M
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
X
0.2 (Pb) 0.45
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Lead poisoning. Symptons include gastric upsets, cramps, fatigue, loss of gum pigmentation. Damages liver, kidney, and blood cells.
PURPOSE AND METHOD OF USE:
A material used as a heat stabilization additive in certain PVC compounds
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves.
FIRE HAZARDS:
Moderate, when exposed to high heat. Extinguish with dry chemical, CO^a water fog
FIRST AID:
ABNORMAL SKIN: Wash with soap and water.
i
EYES: Flush with water. VAB.0001053799
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
LEAD CHLOROSILICATE COMPLEX
TRADENAME(S)
. CODE
415 Lectro 125 M 416 Lectro SPL-125
PPM Mr/M
* or v v'o
^ ww -w*
rtf ".m
y
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
Lead and Silicon Dioxi
A
CLASS
A
TYPE 1
DEPARTMENT
X COMPOUND DRY :BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Lead Poisoning* Damages liver, kidney and blook cells. Symptons include gastric upsets, cramps, fatigue, loss of gum pigmentation.
PURPOSE AND METHOD OF USE:
Used as a heat stabilization additive in certain PVC compounds
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves.
FIRE HAZARDS:
Moderate, when exposed to high heat. Extinguish with dry chemical, CO2, water fog.
FIRST AID:
ABNORMAL INGESTION: Consult a physician at once, EYES: Flush with water for 15
minutes, SKIN: Wash with soap and water.
VAB.0001053800
ABERDEEN, MISSISSIPPI
.conoco,'
t** **rnp
CLASS TYPE
TOXIC LIMIT VALUE (tlv)
0.1
DEPARTMENT
1 x COMPOUND
SHORT-TERM EXPOSURE
1 ___
DRY BLEND
LIMIT
PLASTICIZER
(stel)
VINYL
MAINTENANCE 0.1 1 LABORATORY
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves
FIRE HAZARDS:
Moderate, when exposed to high heat. Extinguish with water
FIRST AID:
ABNORMAL INGESTION: Consult a physician at once. EYES: Flush with water for 15 minutes, SKIN: Wash with soap and water.
VAB.0001053801
t
if w
^ ----
ABERDEEN; MISSISSIPPI
CHEMICAL NAME:
LEAD CHROMATE/LEAD SULPHATE
n4
CLASS TYPE
TRADENAME(s) CODE
986 Yellow X2891
EXPOSURE LIMITS
DEPARTMENT
PPM
TOXIC
SHORT-TERM
EXPOSURE LIMIT (stel)
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Lead Poisoning . Damages liver, kidney and blood cells. Symptoms include gastric ups cramps, fatigue, loss of gum pigmentation. Lead Chromate is a suspected carcinogen.
PURPOSE AND METHOD OF USE:
A yellow color pigment used in certain PVC compounds
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves
FIRE HAZARDS:
Moderate, when exposed to high heat. Extinguish with water
FIRST AID:
ABNORMAL INGESTION: Consult a physician at once. EYES: Flush with water for 15 minutes, SKIN: Wash with soap and water.
VAB.0001053802
+c
ABERDEEN.; MISSISSIPPI
CHEMICAL NAME:
MANGANOUS SULPHATE
TRADENAME(s)
CODE
Manganous Sulphate
f ( >c
mmi
wmitiF **'**'*:
)
A
CLASS TYPE
PPM
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
(Mn)
(Mn)
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Cumulative kidney and central nervous system damage possible.
PURPOSE AND METHOD OF USE:
A Lab material used weekly in dilute solution waste water testing.
reagent during
PROTECTIVE EQUIPMENT REQUIRED:
None
FIRE HAZARDS:
Slight
FIRST AID:
INHALATION: Remove to fresh air. INGESTION: If conscious, induce vomiting and consult a physician.
VAB.000105380
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
MERCURIC ACETATE
TRADENAME(s)
CODE
Mercuric Acetate
.conocoj
^Trr'iiMirrnwnwnwiiirii
a
CLASS TYPE
EXPOSURE LIMITS
DEPARTMENT
PPM Ma/M
TOXIC
SHORT-TERM
EXPOSURE LIMIT Cstel)
0.1 0.1
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS OF OVEREXPOSURE:
Mercury poisoning, may be fatal if swallowed. Symptoms include tremors, headache, fatigue, loss of memory, insomia. Affects nervous system, kidneys, heart, lungs.
PURPOSE AND METHOD OF USE:
A Lab chemical retained for possible future use negligible.
a
reagent. Current use
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, Scott Air Pak - Use during
FIRE HAZARDS:
Highly dangerous, emits mercury vapor when heated. Remove personnel from aresi. immediately. Enter area only with Scott Air Pak during releases.
FIRST AID:
CALL A PHYSICIAN - Give milk, then tablespoon of salt in a glass of warm water and repeat until vomit fluid is clear. Repeat milk.
VAB.000105380
/-- 1
r
o
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
MERCURIC OXIDE
RM .CODE
TRADENAME(S)
Mercuric Oxide
1
(conoco)
IV
EXPOSURE LIMITS
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
PPM Mg/M3 _
--
0.1
--
0.1
CLASS TYPE
Ai
1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
EFFECTS OF OVEREXPOSURE:
Mercury poisoning, may be fatal if swallowed.
Symptoms include tremors, headache, fatigue, loss of memory, insomia. Affects nervous system, kidneys, hear, lungs.
1
1 1 1
PURPOSE AND METHOD OF USE:
A Lab chemical used in solution "COD" tests.
a test reagent in weekly waste water
PROTECTIVE EQUIPMENT REQUIRED:
Rubber Gloves , Scott Air Pak - use during
FIRE HAZARDS:
Highly dangerous, emits mercury vapor when heated area, enter only with Scott Air Pak.
Remove personnel from rel
FIRST AID:
CALL A PHYSICIAN -if swallowed if conscious, induce vomiting by giving a tablespoon of
salt in a glass of warm water and repeat until vomit fluid is clear. Give milk.
Keep warm and quiet.
VAB.000105380
ABERDEEN, MISSISSIPPI
CHEMICAL NAME: MERCURIC SULPHATE tradename(s)
. CODE
Mercuric Sulphate
\QCOJ
K
o
-b 4
EXPOSURE LIMITS
PPM
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM EXPOSURE LIMIT (stel)
----
DEPARTT1ENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
rH
o
EFFECTS OF OVEREXPOSURE:
Mercury poisoning, may be fatal if swallowed. Symptoms include tremors, headache, fatigue, loss of memory, insomia. Affects nervous system, kidneys, heart, lungs
PURPOSE AND METHOD OF USE:
A Lab test reagent formerly used in waste water testing and retained for possible reuse.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, Scott Air Pak - Use during
FIRE HAZARDS:
Highly Dangerous, emits mercury vapor when heated area, enter only with Scott Air Pak.
Remove personnel from rele
FIRST AID!
CALL A PHYSICIAN. If swallowed, if conscious, induce vomiting by giving a tablespoon
of salt in a glass of warm water. Repeat until vomit fluid is clear. Give milk.
Keep warm and quiet.
VAB.000105381
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
METHANOL
tradename(s) CODE
Methanol
EXPOSURE LIMITS
CLASS TYPE A1
DEPARTMENT
TOXIC SHORT-TERM LIMIT EXPOSURE
PPM Mk/M
200
260
250 325
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Narcosis, eye damage (optic neuritis).. (heart) depression may occur.
Cardiac
PURPOSE AND METHOD OF USE:
Minimal use in dissolving samples for G.C. analysis and fluid in the "Brittle Point" test.
a heat transfer
PROTECTIVE EQUIPMENT REQUIRED:
None
FIRE HAZARDS:
Dangerous, when exposed to heat. Extinguish with CO2, dry chemical.
FIRST AID:
CONSULT PHYSICIAN FOR EXCESSIVE EXPOSURE EYES/SKIN: Flush with water for 15 minutes, INHALATION: Remove to give artificial respiration, if necessary.
area. VAB.0001053*07
ABERDEEN- MISSISSIPPI
CHEMICAL NAME:
METHYL ACETATE
tradename(s) . CODE
Methyl Acetate
(conoco)
EXPOSURE LIMITS
CLASS TYPE
11 A
1
--
DEPARTMENT
PPM Me/M
TOXIC
200
610
SHORT-TERM EXPOSURE LIMIT (STEL)
250
760
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
EFFECTS OF OVEREXPOSURE:
Irritant to eyes, nose, throat, lungs. cause giddiness, stupor, depression.
Can
PURPOSE AND METHOD OF USE:
A Lab solvent retained for infrequent use.
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood.
FIRE HAZARDS:
Dangerous, when exposed to heat.
FIRST AID:
INHALATION: Remove to safe area, give artificial respiration if necessary.
EYES: Flush with water for 15 minutes. SKIN: Flush with water.
VAB.0001053808
LT+'
ABERDEEN.. MISSISSIPPI
CHEMICAL NAME:
METHYLENE CHLORIDE
TRADENAME(s) . CODE
Methylene Chloride
< ' . - \t \t /
k *m & i
J
^ HMf MM Mi i*r * OMf'lMt ^
h
CLASS TYPE
PPM
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
500
1900
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Harmful if inhaled. May cause irritation Eye damage possible with long-term use.
PURPOSE AND METHOD OF USE:
A Lab solvent used in preparing G.C. columns Usage is low.
exiglass parts
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood.
FIRE HAZARDS:
None under ordinary conditions.
FIRST AID:
INHALATION: Remove to fresh air, give artificial respiration if necessary.
Call a physician. EYES/SKIN: Flush with water for 15 minutes. For eyes, call
a physician.
VAB.000105380
\S _ .. W' >
I1
J
__________
ABERDEEN. MIS$ISSIF=I
CHEMICAL NAME:
NITRIC 0X1 DI
RM .CODE
--
tradename(s)
Nitric Oxide
*conoco)
^1*1!
*
CLASS
EXPOSURE LIMITS
X
DEPARTMENT
PPM
TOXIC LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
25 35 30 45
COMPOUND DRY BLEND PLASTICIZER X VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Principal hazard is inhalation of nitrogen dioxidq, formed when nitric oxide contacts air (oxygen). Excess inhalation of nitrogen dioxide can produce pulmonary edema within hours of inhalation.
PURPOSE AND METHOD OF USE:
Used as an emergency polymerization terminator in the prodr is stored in pressured bottles and used in a closed system.
It
PROTECTIVE EQUIPMENT REQUIRED:
Air-line respirators, Scott Air Paks - use during emergencies
FIRE HAZARDS:
Dangerous when heated. Can react with water or steam to product heat and corrosive fumes. Can react vigorously with reducing materials.
FIRST AID:
CONTACT A PHYSICIAN IF INHALED: Remove to fresh air, apply artificial respiration
if necessary.
VAB.000105381C
r j r
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
NITROBENZENE
RM , CODE
tradename(s)
Nitrobenzene
*^.r>
H| HI
VjH
t*
K
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (STEL)
CLASS TYPE
,A
1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
EFFECTS OF OVEREXPOSURE:
Skin contact causes a blood deficiency known as methemoglobinemia (oxidized hemoglobin).
PURPOSE AND METHOD OF USE!
A Lab solvent formerly used in viscosity testing, possible reuse.
PROTECTIVE EQUIPMENT REQUIRED:
Vent hood, rubber gloves, rubber apron
FIRE HAZARDS:
Moderate, when exposed to heat. Extinguish with water fog, COo, dry chemical.
FIRST AID:
INGESTION:
If conscious, induce vomiting with an emetic such
mustard and
water. EYES: Flush with water for 15 minutes. SKIN: Remove contaminated
clothing, wash with soap and water.
VAB.0001053811
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
PHENOL
RM .CODE
TRADENAME(S)
*
99 Pallet Glue
#m<! :*
r\
h
PPM Mg/M3
EXPOSURE LIMITS
CLASS
1A
TYPE 1
DEPARTMENT
TOXIC LIMIT VALU (TLV
SHORT-TERM
EXPOSURE LIMIT (stel)
5 10
COMPOUND DRY BLEND PLASTICIZER X VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Marked irritation of eye, nose, throat, lungs. Cumulative liver, lung, kidney damage possible. A suspected carcinogen.
PURPOSE AND METHOD OF USE:
This Phenol-containing liquid is used to glue 50-pound bags of finished product (PVC and PVC Compounds) together as they are formed into pallets for subsequent storage/shipment.
PROTECTIVE EQUIPMENT REQUIRED:
None
FIRE HAZARDS:
Extinguish with CO?, dry chemical,
fume
react with oxidizers.
FIRST AID:
CONSULT A PHYSICIAN. For any contact, flush with water for 15 minutes
VAB.000105381
i
^ -- ..>*/ --
I
V- __
ABERDEEN, MISSISSIPPI
CHEMICAL NAME: POTASSIUM CHROMATE
TRADENAME(S) . CODE
Potassium Chromate
h
TYPE
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Causes irritation. Harmful if inhaled or swallowed. May cause rash or external ulcers. Material suspected as being carcinogenic.
PURPOSE AND METHOD OF USE:
A Lab material retained for possible use as a test reagent. Current usage is negligible.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, rubber apron.
FIRE HAZARDS:
Slight. Extinguish with water, CO?, dry chemical.
FIRST AID:
EYES:
Flush with water for 15 minutes; call a physician.
SKIN;
Flush with
water. INHALATION: Remove to fresh air, give artificial respiration if necessary.
call a physician. INGESTION: Induce vomiting, CALL A PHYSICIAN AT ONCE
VAB.000105381
I 1 ' __
ABERDEEN, MISSISSIPPI
CHEMICAL NAME: POTASSIUM DICHROMATE
RM CODE
tradename(s)
Potassium Dichromate
tun ^ H V 1 Ism
wW'MWmwiiw mw*i
A
EXPOSURE LIMITS
CLASS TYPE
A1
DEPARTMENT
TOXIC
LIMIT VALU (tlv
SHORT-TERM
EXPOSURE LIMIT (stel)
EFFECTS OF OVEREXPOSURE:
COMPOUND DRV BLEND PLASTICIZER VINYL
MAINTENANCE X LABORATORY
Causes irritation. Harmful if inhaled or swallowed. May cause rash or external ulcers. Material suspected of being carcinogenic.
PURPOSE AND METHOD OF USE:
A Lab test reagent used in solution during weekly waste water testing.
PROTECTIVE EQUIPMENT REQUIRED:
None
FIRE HAZARDS:
Moderate by chemical reaction. A powerful oxidizer. Extinguish with CO2,
dry chemical.
FIRST AID:
EYES/SKIN:
Flush with water for 15 minutes, call a physician.
INHALATION;
Remove
to fresh air, give artificial respiration if necessary, call a physician.
VAB.000105381
ABERDEEN; MISSISSIPPI
CHEMICAL NAME: PHTHALIC ANHYDRIDE
TRADENAME(S)
CODE
485 486
Phthalic Anhydride (Bag) Phthalic Anhydride (Molten)
f \f \ \f i \
Jt wt f mm ftn
h
PPM
EXPOSURE LIMITS
TOXIC LIMIT
SHORT-TERM
EXPOSURE LIMIT (stel)
CLASS TYPE A1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Causes skin and eye burns. The vapor and dust is irritating. Long term exposure may cause allergic reactions and eye damage.
PURPOSE AND METHOD OF USE:
Used as a principal raw material in the esterification process of producing plasticizer.
Ant
PROTECTIVE EQUIPMENT REQUIRED:
Air-line respirator, cotton gloves
FIRE HAZARDS:
Slight, when exposed to high heat. Extinguish with dry chemical, water spray Use Scott Air Paks to prevent inhalation.
FIRST AID:
PHYSICIAN
Flush with water for 15 minutes. INHALATION
to fresh air, apply artificial respiration if necessary.
Remove
VAB.000105381
ABERDEEN; MISSISSIPPI
CHEMICAL NAME:
SILVER SULPHATE
RM CODE
tradename(s)
Silver Sulphate
' ror\ if * \ iCT
t nr m vr
"T
h
CLASS
A
TYPE 1
EXPOSURE limits
DEPARTMENT
PPM
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
0.01
0.03
COMPOUND DRY BLEND
PLASTICIZER VINYL
MAINTENANCE
x
I
LABORATORY
EFFECTS OF OVEREXPOSURE:
Silver poisoning possible over long-term exposure. Dark slate gray color over face, forehead, neck, hands, and forearms. Locali blue spots on skin.
ed
PURPOSE AND METHOD OF USE:
A Lab test reagent used in solution during weekly waste water testing
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
Slight. Use any media suitable for the supporting fire. Use agents suitable for extinguishing primary fire.
FIRST AID:
ANY CONTACT:
Wash with water for 15 minutes.
VAB.000105381
MISSISSIPPI
CHEMICAL NAME:
sulfuric: acid
RM , CODE
tradename(s)
Sulfuric Acid
*
EXPOSURE LIMITS
CLASS TYPE
A1 1
DEPARTf'iENT
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
fe
COMPOUND DRY BLEND PLASTICIZER VINYL
--
1
'
--
X MAINTENANCE JL LABORATORY
overexposure:
Causes severe burns. May be fatal if swallowed.
PURPOSE AND METHOD OF USE:
-Added to waste water treatment lagoons in large quantities as needed to regulate PH Handled in closed system of tanks and piping.
-Used weekly in the Lab during waste water "COD" testing and in TLC analysis.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, faceshield, rubber boots, rubber coat, rubber pants.
FIRE
HAZARDS:
Moderate to Dangerous; when heated it emits highly toxic fumes, will react with water or steam to product heat, can"react with oxidizing or reducing materials. DO NOT use water to extinguish if the water can get into concentrated acid. Use Scott Air Pak. Purge all vessels or lines that have contained the material before opening.
FIRST
AID:
ANY CONTACT: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER .FOR 15 MINUTES. Call
*
4
Physician. INGESTION: DO NOT GIVE EMETICS! If conscious, wash mouth out with water.
Drink milk - if not available, drink as much water as possible.
%*
VAB.0001053817
ABERDEEN.. MISSISSIPPI
m fwv: > w
Ifr 9-m n x*r
CHEMICAL NAME:
SILICON DIOXIDE, AMORPHOUS
RM CODE
TRADENAME(S)
816 321
Filtrol K 85 Hyflo Super Cel
PPM Me/M
EXPOSURE LIMITS
CLASS TYPE
A1
,
DEPARTMENT
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE LIMIT (stel)
5 (total) 2 iresoir ble
COMPOUND DRY BLEND X PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS
OVEREXPOSURE:
Silicosis possible over long-term exposure
PURPOSE AND METHOD OF USE:
A de-coloring additive to plasticizer. color batches.
Charged, by hand, from bags, into high-
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, cotton gloves
FIRE HAZARDS:
Slight
FIRST aid:
N/A
VAB.000105381
< Km I
I-J.
i \ i, -- 0 -. 11
ABERDEEN, MISSISSIPPI
A
CHEMICAL NAME:
TRIBASIC LEAD SULPHATE
RM , CODE
852 855 856 405 406 408 407
TRADENAME(S)
Tribase EXL Tribase XL (Non-Dusting) Tribase Cyastab 563 (Non-Dusting) Cyastab 563 Cyastab 810 McGregor 810
EXPOSURE LIMITS
CLASS TYPE
A1
DEPARTMENT
TOXIC
SHORT-TERM
EXPOSURE LIMIT
(stel)
X
0.45
COMPOUND DRY BLEND PLASTICIZER VINYL
HI
MAINTENANCE LABORATORY
EFFECTS OF OVEREXPOSURE:
Lead poisoning. Damages liver, kidney, and blook cells. Symptoms include gastric upse cramps, fatigue, loss of gum pigmentation.
PURPOSE AND METHOD OF USE:
Used in large quantities as a heat stabilizer additive to PVC compounds poured, by hand, from paper bags into compound blenders.
It is
PROTECTIVE EQUIPMENT REQUIRED:
Dust mask, rubber apron, cotton gloves.
FIRE HAZARDS:
Moderate, when exposed to high heat.
Extinguish with dry chemical, CO2, water fog
FIRST AID:
ABNORMAL INGESTION: Consult physician at once
SKIN: Wash with soap and water.
EYES
Flush with water.
VAB.0001053819
ABERDEEN, MISSISSIPPI
CHEMICAL NAME:
TRICHLOROETHYLENE
RM .CODE
tradename(s)
854 TCE
Ik -->
Nm
'w W if
A
PPM Me/M
i CLASS
I
1A
TYPE
1
EXPOSURE LIMITS I
TOXIC LIMIT VALU (TLV
100
SHORT-TERM EXPOSURE LIMIT (stel)
200
X
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL MAINTENANCE LABORATORY
effects of overexposure:
Narcosis and acute cardiac failure possible. Following inhalation of large amounts, kidney and liver damage' possible. Material suspected of being carcinogenic.
PURPOSE AND METHOD OF USE:
B3
A solvent formerly used as a resin dryer screen cleaning medium. Current use is neglibible.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves.
FIRE HAZARDS:
t
Low, when exposed to heat.
.
Extinguish with water fog
FIRST AID:
EYES/SKIN: Flush with water and get medical attention. INHALATION: Remove to
h
fresh air, apply artificial respiration if necessary, contact a physician. INGESTION:
DO NOT INDUCE VOMITING!
immediately
VAB.0001053820
.. \
IZ--.f 1
i\ * k
ABERDEEN, MISSISSIPPI
(conoco
i
CHEMICAL NAME:
QUATERNARY AMMONIUM, AMINES, ORGANOTINS
RM .CODE
--
tradename(s)
Biosperse 201
EXPOSURE LIMITS 1
TOXIC
LIMIT VALUE (tlv)
SHORT-TERM
EXPOSURE
LIMIT
ISTEL)
*
CLASS TYPE
A t
1
DEPARTMENT
COMPOUND DRY BLEND PLASTICIZER VINYL
PPM MgAr
0.1
-- X MAINTENANCE -- LABORATORY
EFFECTS OF OVEREXPOSURE:
- May cause skin/eye irritation, Swallowing may be fatal.
- *+
PURPOSE AND METHOD OF USE:
r
Used as a cooling tower water treatment additive for the control of microbal growth. Poured from drums into water.
PROTECTIVE EQUIPMENT REQUIRED:
Rubber gloves, faceshield.
FIRE HAZARDS:
Slight. Extinguish supporting fires with C02, dry chemical.
FIRST AID:
SKIN:
Wash with plenty of water.
EYES:
Flush with water for 15 minutes and obtain
0
medical attention. INGESTION: Induce vomiting and call physician.
VAB.0001053821
i
w -- 0 * O'
ABERDEEN; MISSISSIPPI
CHEMICAL NAME : VINYL CHLORIDE MONOMER
(
RM . CODE
864 865 866 867 868 869 870
TRADENAME(S)
" ...
VCM - B.F. Goodrich VCM - Uniroyal VCM - Dow VCM - Shell VCM - Lake Charles VCM - Allied VCM - Monochem
\
1
(conoco)
%
EXPOSURE LIMITS
pm
CLASS TYPE
r\ J-
DEPARTMENT
1 ppM |ms/M^
TOXIC LIMIT VALUE (tlv)
1
SHORT-TERM EXPOSURE LIMIT (stel)
* .X
.5
X
X
COMPOUND DRY BLEND PLASTICIZER VINYL
MAINTENANCE LABORATORY
EFFECTS OF OVEREXPOSURE I
VCM is a cancer-suspect agent, with the liver being the principal target organ.
PURPOSE AND METHOD OF USE:
Used as a principal raw material in the manufacture of polyvinyl chloride (PVC).
w
Used daily in Lab, in low quantities, as a reference standard during vinyl chloride monomer testing.'
PROTECTIVE EQUIPMENT REQUIRED:
1-10 ppm: Canister gas mask. 10 - 1000 ppm: Air-line respirator. 1000+ or unknowii: Scott Air Pak (Pressure demand)
FIRE HAZARDS:
Very dangerous; when exposed fo heat. It emits highly toxic fumes, can react vigorously with oxidizing materials. EXTINGUISH with dry chemical, water spray/fog. Use Scott Air Paks.
FIRST AID:
INHALATION: Remove from exposure, apply artificial respiration if necessary.
SKIN: Flush spills with water immediately, remove contaminated clothing.
VAB.0001053822
%
I
I-
H