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M ICROBICS M ICROTOXO TOXICITY TEST TEST SUBSTANCE Identity:Perfluorooctanoiaccid,ammonium saft;may alsobe referredto as PFOA ammonium saltA,mmonium perfluorooctanoateP,FO, FC-1 16, FC-1 26, FC-1 69, FC-1 43 oras the major component of FC-1 18. (Octanoicacid,pentadecafluoro-a,mmonium salt, CAS # 3825-26-1) Remarks: The testsample isFC-1 18. It'psuritywas notsufficiently characterizedt,hough currentinformationindicatesis20% FC-143 in80% water. The 3M productlotnumber was not noted. The followingsummary appliesto the testsample as a mixture of the testsubstance In water solutionwith Incompletelycharacterized concentrations of Impurities.Data may not accuratelyrelatetoxicity of the testsample with thatof the testsubstance. METHOD: Method: MicrobicsMicrotox@"BASIC" Procedure Test type:Staticacute GLP: No Year Completed: 1996 Species: Photobacteriumphosphoreum Analyticalmonitoring:pH and osmoticcondition Exposure period:30-minutes Statisticamlethods: EC50 valuescalculatebdy statisticlailnear regressionprogram providedforMicrotox@ Test organism source: Microbics'Reagent. Test conditions: Diluent:MilliporMeilli-QTM water Stock and testsolutionpreparation:A primary10 g/Lstocksolution was prepared inMilliporMeilli-QTM water. The pH ofthe stocksolution was 6.0 (no adjustment)and an osmoticadjustmentwas made using200 mg NaCl in10 mL stocksolution.Appearance oftestsolutionswas noted as "clearand soloriess"A.lltestsolutionswere made by proportional dilutions. Exposure vessels: 3 mL Cuveftes. Number of replicates:two Number of concentrations: Four plusa blankcontrol Element basis: Percent lightloss. RESULTS NominalconcentratioBnlsa:nkcontro6l2,5,12502,500,and5000mg/L Element value: 5-minuteEC50 = 4460 (4020- 4950) mg/L 15-minuteEC,50= 3360 (3090 - 3641) mg/L 30-minuteEC50= 3150 (2910- 3420) mg/L Element valuesbased on nominal concentrations. Remarks: Testingwas conducted on the mixtureofthetestsubstanceas describedinthetestsubstanceremarks fieldT.he valuesreportedapply tothatmixtureand notthetestsubstance. CONCLUSIONS The FO-118 30-minuteEC50for Photobacteriumphosphoreum was determinedto be 3150-mg/L witha 95% Confidence Intervaolf2910 to 3420 mg/L. Submifter:3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,MN, 55133 DATA QUALITY ReliabilityK:limischranking2. Testingmeets allcriterifaorquality testingb,utlacksanalyticaclonfirmatioonftestsubstanceconcentrations. There isa lackofcharacterizatiofnthetestsample. REFERENCES Thisstudywas conductedby the3M EnvironmentalLaboratoryS,t.Paul, Minnesota,Lab Request number Pl626. OTHER Last changed: 5/25/00 ENVMONMZ&NTAL TESTSUBSTANCE: LABORATOR*: MCROTOX PREP SHEET Lp-, -"3 .4W&ySt: 9 c@V i PreparationofStock Solution Maw7o4 TestSUbSI,2nce. FlnalDilutionVolume. DUuenr L LI-C I- FinalConcenuafionofStock Solution: 2.pH Adjustment of Stocksolution nitWPHOfStock Solution: *pH,4djustedto: *pH,4djusted**h: 63@otic Adjustment ofStock Solution OsMOM' :.4jduster,- 4@- ranceof pH and Osmotically Adjuste@dStock S@l, ..FILE@FC-118.K5 @P162 It :Test Time, 5 mirtu te@. IIC. DATA REPOFIT ba,iic Test NUMBER tc)h tra 1 o!itra I 96.4.;,' ;.-1 93.9 EiI .el!@ 0 f,-5 oooo_ 5;00 0 -44@L1 -'ZR (3AMM At., 6 -4p '@69E; 4:65i%A c L -1 ur e E,7 21 :,4 T i,ANC-) 49 . T 7 494,-. L)74-,w;n C, FILE FC-118 'tICROTOX DATA REPC)P@T Test Timpt IS minlites r-ontrul C;C)Ptral IT 96.44/:79.14 .@.-9,'6ci 7-92 '7/ 57. Ci7 -89:121 59.47, 3@- 9.4,-S/ 49.,l 6'7.29/ 45' 7 3!:j 22.41 CR L tc/5'/ C;fjNFI Ubmotic ---------- Adji-s't'mentiNaCi "x I--@T-:-R-IG-AMMA o .,e2-i6i, OC)@-)O 0.344 0 2-- -.4 a 15'IL TC,,7,,641''.-l4 4.1 Si EST 0'f-, 7 D D,DVDDP D DDDDDDVDDDDDDDDDDDDDOD-16D@D, D.7D"-OaODD;, 7't ;41 FILE FC MICROTOX Dn,rA REpo;.@T Test. Time: 30 minutes NUMBER'-' Ctintrol !Zcjrtrol 10/11' ------ .96'.44/77. i Ad ust amnit t4@ci CON------------ 0 .4@RICAMMA 0 i@03:$- 2.. 9@-9 4 '97 8. gt; 54. IL)7 -4:, 47.7,t 6 't37.29./ 4--l.25 7 19 1,25: 12'@0.1 .@:737 @1.643 COC-@;@k@--::TION- FA(.TL)r@ fc)r C L54.,-171z mc, (95% CC)Ni'lrjE@4CI- 91 TE) t iimpoo ZDDDDDDDD TE-3T I)ATE- T IM Et