Document nNDJdR1XZE0RRx9q8L0BYvqM2

- __________________ __________ f/iAfERtAL SAFETY DATA SHEET IVIV s T 0350541 2V9 SPEC.'MSDS NUMBER OATE Nov. 4, 1985 PRODUCT IDENTIFICATION TRADE NAME Asbestos MANUFACTURER'S NAME Griqualand Exploration & Finance Corp. ADDRESS (STREET) P.O. Box 69 CITY STATE Kuruman, Cape Province RSA GENERIC NAME CroeidoHfe Asbestos CAS NUMBER 1332-21-4 PHONE NUMBER (EMERGENCY) (011-27-11)339-5458 ZIP CHEMICAL STRUCTURE Na,Fe,(OH)Si,0,,) 1 PRODUCT INCREMENTS CHEMICAL AND/OR COMMON NAME CAS NUMBER Crocldolite Asbestos ^Occupational Exposure Limits 1332-21-4 PEL 2.0 f/cc - 8 hr. TWA TLV 0.2 f/cc Celling cone. ACGIH. Documentation of 10.0 f/cc TLVs at 27 OSHA Standard at 29 CFR 1910.1001 (Fibers measured are those longer than than A 100.D_ TLV/PEL * II PHYSICAL DATA BOILING POINT VAPOR PRESSURE n/a n/a SOLUBILITY IN WATER VAPOR DENSITY (AIR m\) n/a n/a APPEARANCE AND ODOR Blue fiberous dry material - no odor. SPECIFIC GRAVITY 3.2-3.3 PERCENT VOLATILE n/a MELTING POINT n/a EVAPORATION RATE ( *'>n/a Ill FIRE AND EXPLOSION DATA FLASH POINT n/a -- ... EXTINGUISHING MEDIA non-flammable FLAMMABLE LIMITS fl/ft. FLAMA&LE LIMlU LEL UEL a/p______________ JLa/p-------- _____1 n/a SPECIAL FIREFIGHTING PROCEDURES none ____ UNUSUAL FIRE OR EXPLOSION HA2ARDS none IV HEALTH HAZARD INFORMATION HAZARD BY ROUTES OF EXPOSURE (Indicate chronic end acute) vmsFi :hrpnic-Avoid inhalation, Overexposure .can. cause asbestosls. ucfcening. effusion ana blagues are nondisabling conditions, a scarring of seen separately tether*.thiwatr. have heen ascnMat^ trft-h eyposui-e. The Tr .St HAt-rmTwpri .rlipro the ] or b It t< en INGESTION no increased harard evidenced. cien't evi'ddeenncce ffor the ccarcinoger.ic`i of jg aEsrob.easf.tMosnginhchKudmcamnhs. Caution way so is ad' qptTi EVE bodily harm. Acute- may cause eye irritation. SKIN CONTACT/ABSORPTtON Acute- mav cause skin irritation. signs and symptoms associated with exposure over TLV-Asbestosis is associated with symptoms of la breathing,chest pain, weakness and chest tightness. Symptoms are not usually manifest unt 15-20 years after exposure. MEOICAL CONDITIONS WHICH MAY BE AGGRAVATED Respiratory ailments. ANY OF PART I LISTED AS CARCINOGENS? (NTP. IARC, OSHA) Yes DOW 1 MATERIAL SAFETY DATA SHEET MC-XAIMI <V ST035054I 23/9 SPEC./MSDS NUMBER j DATE I Nov. 4. 1985 PRODUCT IDENTIFICATION TRADE NAME Asbestos MANUFACTURER'S NAME Orlqualand Exploration & Finance Corp. ADDRESS (STREET) P.0. Box 69 OTY STATE Kurunan, Capa Province RSA GENERIC NAME Croc idol!tp Asbestos CAS NUMBER 1332-21-4 PHONE NUMBER (EMERGENCY) (011-27-1H339-54S8 ZIP CHEMICAL STRUCTURE Na2Fe5(0HlSl>,011^ I PRODUCT INGRE0IENT6 CHEMICAL AND/OR COMMON NAME Crocidolite Asbestos Occupational Exposure Limita PEL______________ 2.0 f/cc - B hr. TWA TLV 0.2 f/cc CAS NUMBER 1332-21-4 Celling cone. lb.6 f/cc OSHA Standard at ACCIH. Documentation of TLVe at 27 29 CFR 1910.1001 -(Fibers measured _are those % HKLaJCL TLV/PEL PHYSICAL DATA BOILING POINT VAPOR PRESSURE n/a n/a SOLUBILITY IN WATER VAPOR DENSITY (AIR 1) n/a n fa APPEARANCE AND ODOR Blue fiberou8 dry material - no odor. SPECIFIC GRAVITY 3.2-3.3 PERCENT VOLATILE n/a MELTING POINT n/a EVAPORATION RATE { "'ln/a Ill FIRE AND EXPLOSION DATA FLASH POINT FLAMAbLE LIMITS /a_________________ ___________F_L_A_M__M_A_B_LE LIMITS n/.a__________ Xl/g___________ EXTINGUISHING MEDIA non-floanable .LEL -i n/a SPECIAL FIREFIGHTING PROCEDURES none________________ UNUSUAL FIRE OR EXPLOSION HAZARDS none UEL 1 n/a IV HEALTH HAZARD INFORMATION HAZARD BY ROUTES OF EXPOSURE (Indicate chronic and acute) mm** aether hat have been asBociatefl with ftvpaaur>. INGESTION no increased hazard evidenced. EYE Acute- nay cause eye irritation. Th TABC h.t /tfrfrrMnrt frhf rbirA/tc cient evidence for the carrcciinnooggddnieii oanf ahsrAbeasthtotnsgInncKhuometa-nncs. mCayaution 16apardli1 bodily harm. SKIN CONTACT/ABSORPTION Acute- mav cause skin irritation. SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV-Asbeatosis is associated with symptoms of lai breathingichest pain, weakness and chest tightness. Symptoms are not usually manifest unt 15-20 years after exposure. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED Respiratory ailments. ANY OF PART I LISTED AS CARCINOGENS? (NTP, IARC. OSHA) Yes DOW 06463  / 51035051(2 V HEALTH HAZARD INFORMATION (Continued) __ __ EMERGENCY/FIRST AID PROCEDURES in noN -Avoid breathing dust when handling,dunping,and nixing. -Use respirator if airborne con ccucrations exceed OSHA limits fsee Sec. VI). ______ __ INGESTION EYE CONTACT In case of eve irritation, gently rinse with water. If Irritation persists eet medical help SKIN CONTACT Remove slivers from skin promptly. If irritation persists get medical help. SKIN ABSORPTION n/a ______________________ VI CONDITIONS FOR SAFE USE (When over TLV) RESPIRATPRY PROTECTiOfL-Reusable or single.vse air purifying respirator-for exposures which do not need, the, PEL (see uyjspre hin,,lCX. Powered air purifying respirator-for exposures more ifiV hnr loce rhan TORY the _PFJ- Typp "fl" TTnu nr pV*Jignr< .aamand snpnTiM ryspi eEyYcE pPRrOoTtEeCcTtIiOoNn for exposures more than 1O0X the PEL. All r< (see "Other.. this Sec.) pirators must be NIOSH approved PROACTIVE GLOVES .(gee "Otheri.," this.. Sec..)--------------------------------------------------------------.. ....--.---------- OTHER protective clothing/eouipment -If the celling concentration (see Sec.l) limit is exceeded, clothing providing whole body covering must be supplied and its use required. ventilation requirements "Local ventilation if engineering controls are inadequate, (see OSHA Title 29 CFR Part 1910.1001, c (1), (ii). IS MATERIAL STABLE? Ye* INi 'ATIBILITY n/a HAZARDOUS DECOMPOSITION PRODUCTS none VII REACTIVITY DATA WILL HAZARDOUS POLYMERIZATION OCCUR? No CONDITIONS TO AVOID Avoid creating and breathing dust. VIII SPILL OR LEAK PROCEDURES steps to BE taken if mateial is spilled OR RELEASED-Avoid creating or breathing dust. Collect dust by HEP vacuum or in wet state (wet sweeping.wet wiping) to prevent emission of airborne fibers. ill SSfletS ` Swaste DISPOSAL METHOD-Bags, borne concentrations of wasahgetas and 6, scr, shopld be e use edercl, sposed of, I_n" a manner which all.avoid satautset-atnigc hltoctraialshrebgaug;lsatio<iorn'cso. ntainers. sInirs-u RCRA REGULATED CYw E No RCRA NUMBER CERCLA (Superfund) REPORTABLE QUANTITY DOT REGULATEO Yet No DOT PROPER SHIPPING NAME Asbestos DOT HAZARD CLASS ORH-C DOT NUMBER IX SPECIAL PRECAUTIONS S.unouPonrEsClooecIAaaoLfdnJo'tRinrrEogCc,AlJleJPmTaIreOnoaNitSsneugFsrO.etRscDH, oAoNunnDsteLaoINtinoGetuAarsNkstDef.S6spfTTur:(OirspoRmrAeteGfslEcas-DtjiaoiovgneencootlPnocrpttrrh.evoiaenlntgePmeoofalurrssubetr^qrereuseai,lpetmhsaueBdcnehut ,sawhtso,iFmHvbeoer.mnUnftsoienltarontdioyroy.lnbgolsnwoogker,sewppeirnootwprleoourraslcdeeiinnnsc|gilt luLx. curfaroofc,hafnrtdlpinrgfa,tanurs.eJlfatmndiB` Udtiinspso~nsr>aln. fFaoellKoowgcKgcood(.yh>onucas<ekne4engp-inAgitr.p. racticesin,hasulacrhjjnans wet wipi other precautions-Substantial medical evidence Indicates that smoking increases the risk from asbestos exposure. Those working with asbestos should not smoke. prepared by phone no. D--aaa=Bst TITLE DOW 06464 b to While the information ano reeommenoaiions sei forth herein are believed to be accurate as ol the date hereof. THE MANUFACTURER MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.