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PLAINTIFF'S EXHIBIT
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CA?AC!Toa DEPARTMENT
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P ro cess.... I n s t r u c t i o n
SAFETY RUIZS FC-R EAiIDLING AITD USE 07 PYRANCLS
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THIS IMSTRUCTICM IS VOID AFTER .l/.H /.6 3 .
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771500
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L iquid. P y ra n o ls, l ik e m in eral o i ls , a re an e s s e n tia l p a r t o f c a p a c ito r m an u factu re.
I n o r d e r t o p r o t e c t p e r s o n n e l , c e r t a i n common s e n s e r u l e s o f h a n d l i n g m u s t "be o b s e r v e d .
These p re c a u tio n s a re o u tlin e d in d e ta il in th is in s tru c tio n .
L iq u id P y ran o ls a re n o t a c id s o r a lk a lie s . They a re n o t inflam m able, nor. w ill. they su p p o rt com bustion. -
H a n d lin g o f L i q u i d P y r a n o l s C-E A1RB2A ( # 1 ^ 6 ) , A13B1C ( # 1 ^ 9 9 ) , (# 1 ^ 9 2 ) a n d A50FC8 . (Pvranol__II J -
C o n tin u ed ex p o su re to l iq u id P y ran o ls. may, a s w ith m in e ra l o i l s o r s o lv e n ts , p ro duce sk in ir r ita tio n s .
C l e a n l i n e s s , f o r men a n d women h a n d lin g P y r a n o ls , c o n s t i t u t e s a n a d e q u a te s a fe g u a rd a g a in s t such e f f e c t s . P e rso n a l com fort i s im proved, e s p e c ia lly d u rin g summer m onths, b y fre q u e n t w ashing o f han d s, arm s, and fa c e w h ile w orking w ith P y ra n o ls, i f such work n e c e s s ita te s P y ra n o l l i q u i d coming in c o n ta c t w ith th e s k in . A w ash in c o o l o r lu k e v a rr w a te r i s b e s t. A m ild soap ( th a t s u p p lie d in th e washrooms i s v e ry g o o d ), i s p r e f e r r e d t o a h a rs h so ap w h ich may s c r a tc h o r i r r i t a t e th e s k in .
G loves a re n o t recommended becau se th e y soak up P y ran o l and a re a c o n s ta n t so u rce o f d is tr ib u tin g P y ran o l to th e hands and fo rearm s. In cases w here i t becomes n e c e ssa ry to u se them , such a s f o r h an d lin g p ie c e s o f h o t ap p aratu s o r heavy w ork, th e g lo v es, w henever s a tu r a te d w ith P y ra n o l, sh o u ld b e re tu rn e d to to o l c rib and.new g lo v e s is s u e d .
B o th men a n d women w o rk in g w ith P y ra n o ls m ust w ash t h e i r h an d s b e f o r e u s in g t h e t o i l e t s a s P y ra n o ls may be tr a n s f e r r e d to o th e r p a r ts o f th e body and cau se i r r i t a t i o n .
P e rso n s who a r e w orking in d ir e c t c o n ta c t w ith P y ra n o ls m ust w ash hands b e fo re
e a tin g o r sm oking.
.
*
E a tin g , d rin k in g o r sm oking i n w orking a re a w here P y ra n o ls a re u se d o r p re p a re d , is n o t p erm itted - -
As in th e case w ith m in eral o il, P y ra n o l-satu rate d c lo th e s , in clu d in g fo o tw ear, sh o u ld n o t be w orn. I f ap ro n s, o r c lo th s serv in g as ap ro n s, a re u sed , care sh o u ld be ta k e n t o see t h a t th e y do n o t become s a tu ra te d and th u s convey th e P y ra n o l t o th e c lo th in g and s k in b e n e ath them .
I f P y ra n o l does g e t in th e ey es, do n o t rub them , a s t h i s o n ly s e rv e s to in c re a s e th e i r r i t a t i o n - N ever a llo w a fe llo w workman t o a tte m p t t o c le a n o u t y o u r e y e s , b u t so to th e d isp e n sa ry im m ediatel?/, where p ro p e r tre a tm e n t w ill be g iv e n .
GL.-IP 003335
A void ru b b in g th e hands th ro u g h tile h a ir and p ic k in g th e fa c e o r neck w ith th e f in g e r s . This, h a b it is a p t to cause in fe c tio n to th e p a rts com ing.in c o n ta c t w ith th e hands even when th e hands a re clean .
H o t v a p o r s o f P y r a n o l s s h o u ld n o t b e i n h a l e d . An a i r l i n e r e s p i r a t o r s h o u l d b e v c r r
b y a n y man o r woman who i s w o rk in g o v e r a ta n k i n w hich t h e r e i s P y r a n o l a t a te m p e ra tm
CAP 33ft REV 12/31
T ,P - P ,S
date cf issu e J a n . . JL1*. .1965........... G E N E R A L G m ) E L E C T R I C SUPERSEDES ISSUE CT .O c t . 1> .1 9 5 5
. subject
CAPACITO* DEPARTENT Process... Instruction
r AF7.TY RULES F OH HANDLING AND USE O? PlftAIiCIfl
THIS INSTRUCTION IS VOID AFTER . l / l l / S o .
iftsTR. no. m ' . - .vo .. ;........ FA5E . . . 2 . ........ CF . . . 2 .......... IfR1TTEH BY .G - A . . S m i t h . ... ...................... ISSUED BY .'JS >S ....IlU lk W .........................
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h ig h e r th a n 85C* E x cep t i n em ergency c a s e s , th e r e sh o u ld be no c a u se f o r t h i s in c a p a c i to r m a n u fa c tu re . A ll ta n k s a re lo a d e d a t a p p ro x im a te ly room te m p e ra tu re . P y ran c
A13B2A ( # 1^ 36) i s n e v e r h e a t e d h i g h e r t h a n b 5C a s h e a t i n g i n a r. o p e n c o n t a i n e r f o r p r o l o n g e d p e r i o d n a y a f f e c t t h e c o m p o s itio n . I n t h e c a s e o f P y r a n o l A13B1C (1 ^ 9 9 )> t r e a t i n g t a n k s c a y b e o p e n e d a t t e m p e r a t u r e s h i g h e r t h a n 85 C , b u t t h e r e i s n o o c c a s
f o r w orking o v er th e ta n k s.- P ro cess la b o ra to ry and E n g in eerin g I n s tr u c tio n s , c o v e r!
tre a tm e n t v ith th e se P y ran o ls, lim it th e se alin g tem perature o f c a p a c ito rs in th e t r i n g t a n k s t o 7 0 ^ a t w h ic h te m p e r a tu r e v e r y l i t t l e e v a p o r a ti o n t a k e s p l a c e . G-F. l k
P y ra n o l i s h e a te d to 150 - 225C in a c lo s e d m e ltin g p o t, b u t th e r e i s no o c c a s io n
a workman to w ork d i r e c t l y o v e r th e v a p o rs.
The maximum a llo w a b le l i m i t o f P y ra n o l v a p o r i n th e a i r i s 1 0 mg. p e r c u b ic m e te r and equipm ent m ust be p ro v id e d to keep th e c o n c e n tra tio n below t h i s am ount.
As v i t h m o st v o l a t i l e m a te r ia ls , ex p o su re to c o n c e n tra te d v a p o rs in a c lo s e d room sh o u ld b e av o id ed . A ir-lin e re s p ira to rs , connected to a supply o f fre s h a i r , m ust be w orn when workmen a r e t o w ork in s id e a. ta n k p r e v io u s ly f i l l e d v i t h P y ra n o l. A workman m u st re m a in o u ts id e a n d w ith in c a d i w h ile men a r e w o rk in g i n s i d e su c h a ta n k -
A H to o ls , m achinery and ap p aratu s used fo r P yranol m ust b e k e p t c le a n , b o th as & p r o te c tio n t o th e workmen and to p re v e n t c o n ta m in a tio n o f P y ra n o l.
The f lo o r s m ust b e k e p t c le a n and d ry . Any P y ra n o l s p i l l e d m ust be c le a n e d up _
im m ediately.
..
A bsolute c le a n lin e s s is e s s e n tia l. T his a p p lie s n o t o nly when h an d lin g P y ra n o ls, b u t u n d er a l l circ u m stan c e s. C le a n lin ess o f th e p erso n n el and th e p la n t raw s be m ain ta in e d i n o rd e r to se c u re th e b e s t w orking and m an u factu rin g c o n d itio n s .
771501
GENP 003336
CAR 3 3 * REV 1 2 /6 1
G EH E R A L $11 E L E C T R IC
DATE CF ISSUE J a n . . *1 1 , *1?> . . : ................
s u p e r s e d e s i s s u e OF
.................
SPILL CONTROL METHOD HUDSON FALLS
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General Several s p i l l clean up sta tio n s have been deployed throughout the p la n t. They c o n s is t o f a metal drum labeled "PCB Contaminated So lid (L iq u id ) F a ste -F o r In c in e ra tio n " , and a f ib e r drum labeled "Speedy Dry - Clean A ll S p il ls Im m ediately". There are a lso scoops in the fib e r drums fo r handling dry "Speedy Dry" o n ly. In the near fu tu re disposable rags w ill be provided a t these s t a t io n s . Also in conjunction w ith the s p i l l control clean up s ta tio n s s p e c ia lly designed leak containing p a lle ts have been provided.
Purpose In e v it a b ly , s p i l l s w ill occur from leakin g and/or damaged u n its or other so u rces. The above sta tio n s and p a lle ts w ill provide the means fo r an immediate and convenient clean-up. No_ s p i l l s are to be l e f t uncleaned or ju s t covered w ith Speedy Dry. Area Supervisors should request a d d itio n a l clean-up s ta tio n s from M. R o s a ti, i f they are needed.
Procedure 7T. For sm all le ak s u su a lly re s u ltin g from leaking cap acito rs and/or other
sm all c o n ta in e rs. Immediately upon detecting any pool o f o il on the f lo o r o r other s u rfa c e , cover t h is pool w ith Speedy Dry and then l i f t th e saturated m ate rial into the metal drums. Repeat t h is procedure u n t il the s p i l l area is d ry . Disposable rags should be used fo r f in a l wipe up. N .B. The Foreman s h a ll be re sp o n sib le fo r having any clean-up u t e n s ils
and/or m a te ria ls (o ther than Speedy Dry) immediately a v a ia lb lg to do the jo b . In the event that the s p ill is a re s u lt o f a leaking capacitor or other small co n ta in e r, put th is cap acito r or container into a leak containing p a lle t im m ediately. Then cle an the s p i l l thoroughly and arrange t r a n s p o rta tio n fo r the le a k e rs to the R .A . Area where they w il l be co nso lidated f o r r e p a ir , and replacement p a lle t s are a v a ila b le . The Area S u p e rviso r w i l l be re sp o n sib le to have the sp ecial p a lle ts a v a ila b le . Under no circum stances s h a ll any le a kin g co ntainers be transported w ithout the leak containing p a lle t.
B. For la rg e s p i l l s u s u a lly re s u ltin g from toppled t r e a t l i n e r s , broken p ip e s, ruptured drums, e tc . In the event o f a la rg e s p i l l , fin d the source o f the le a k and stop i t , i f p o s s ib le , using a l l a v a ila b le a s s is ta n c e . For example o rie n t a drum to stop leakag e, is o la te a pipe le a k by clo sin g appropriate cu t o f f v a lv e s , e t c ., then dike the s p ill com pletely, i f p o ssib le , again using a ll a v a ila h l h e lp . N o tify Maintenance and J . F rig h t immediately and/or a v a ila b le Super v is o r who w il l d ir e c t clean-u p . In any circum stance q u ic k , d e c is iv e actio n should be a p p lie d .
S u p e rv iso rs s h a ll w itness se a lin g o f drums to assure drums are f u l l and compact before transp o rtin g to the Receiving Holding Area - Bldg. 1-2. Arrangements to obtain empty drums should be made through Store B Stoe kk.se" a ls o S u p erviso rs should keep f ib e r drums f u l l o f Speedy Dry.
GENP 003337
771502
S P ILL CONTROL METHOD HUDSON FALLS___________ Page 2
Note:
Mo contaminated m aterial is to be placed in any c o n ta in e r o th er than those s p e c if ic a lly designated fo r PCB contaminated m a t e r ia l. Do not use dumpsters or compactors fo r disp osal o f PCB contaminated m aterialsT
Mo drums are to be transported unsealed.
G .P. Challenger September 22, 1975
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771503
GENF 003338
METHOD FOR HANDLING RETURNED APR. LEAKING UNITS HUDSD?.1 FAL IS _______________________________._______________
General Leak co ntaining p a lle ts are provided a t both Receiving A re a s, namely 1-2 and 4A along w ith clean-up s ta tio n s . In the near fu tu re dikes w ill be co nstructed a t the 1-2 R eceivin g rea and in the T re a t M illin g Area to handle la rg e R .A . bulk re tu rn s.
Purpose T r a d it io n a lly most RA lo ts contain leaking u n it s , sw itch e s, e tc . I t i s urgent th a t a l l such le a k e rs be contained immediately upon re c e ip t of the u n its and/or equipments.
Procedure TnrtTaTTy a l l RA lo t s received a t 1-2 Area sh a ll be 10055 unpacked and inspected fo r le a k s . Leakers s h a ll be handled per the " S p ill Control Method". A ll s p i l l s , both on and o f f d e liv e ry t ru c k s , s h a ll be thoroughly cleaned.
A ll lo t s re ce ive d in the 4A are to be 100% unpacked and inspected f o r le a k s . I f an equipment has leaking u n it s , they are to be removed immediately and handled 'per the " S p ill Control Method". Under no circum stances s h a ll a'ny leakin g u n it (o r suspect u n it) be placed o u tsid e . A gain, the d e liv e ry tru c k should be inspected and cleaned along w ith any flo o r s p i l l s .
G.P. Challender September 22, 1975
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GENP 003339
771504
METHOD FOR HANDLING BULK LIQUID PC3 CONTAMINATED WASTE HUDSON FALLS
General Enclosed drums labeled "PCB Contaminated Liquid Waste" w ill be provided to handle la rg e q u a n titie s of PCB contaminated lia u id s ; such as d rip pan d rain in g s, sink drainings, etc. A lso, special leak containing p a lle ts are provided fo r the tran sp o rtatio n o f such drums. Note: These drums must be accessed through a bung hole and care should
be taken not to introduce s o lid waste in to the drum.
Purpose To provide a s p ill control method o f handling liq u id PCB contaminated m a te ria l in b u lk , i . e . 55 g allon drums.
Procedure In the event th at la rg e q u a n titie s o f PCB liq u id waste can be handled by the bulk drum method, care must be taken to assure th a t s p illa g e is prevented an th a t the drum is placed on a le a k containing p a lle t both during and a f t e r f i l l i n g - The drums should then be pro perly id e n tifie d per the e sta b lish e d p r a c t ic e . I f the liq u id is com patible, i t w il l then be pumped in to the' main bulk scrap tank a t the R e fin e ry .
G .P. Challender September 2 2 , 1975
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GENP 003340
771505
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D,;TE* S ep tem b er 1 0 , 1975
subject- contro l o f Pyranol (PC3) Discharges from Wash and Laboratory Sinks
As a* r e s u lt o f the recent p u b lic ity concerning PCB discharges in the outgoing water several additional commitments have been made to reduce these discharges by ye ar end. One o f these commitments was to control the discharges from sinks re su ltin g from the washing o f hands and other o b jects coated with pyranol. To contain and t re a t the discharges in a l l sin k s in the p lant would be an uneconomical and unmanageable p ro p o sitio n . Th erefo re, i t was decided th a t the discharge of PCB's could be elim inated by the posting of sig n s, the in s tru c tio n of personnel, and the containment o f s p e c ific sin k d ra in s.
B a s ic a lly the sin k s were divided in to three ca te g o rie s:
1 . *- Contained S in ks - These are sinks in areas such as the CEB crim per area and the SI Recovery area where the sin ks are used by a larg e number o f people coming in contact w ith pyranol. Since the discharge from these sinks are contained and treated these sin k s should be s p e c if ic a lly used fo r removing Dyranol from hands. Personnel should be in stru cte d to use these sin ks s p e c if ic a lly fo r removing pyranol and to li m it water usage by the use o f the sp ecial hand cleaners provided. Attached sign #1 posted a t these s in k s . .
2. Controlled sin k s - These are sinks in areas such as la b o ra to rie s where a lim ite d number of people come in contact w ith pyranol. At these sin ks paper towels and sp ecial cleaners have been provided in order th at pyranol can be removed from hands before washing in the normal manner. In addition other o bjects such as t e s t tubes th at come in contact with pyranol should be washed w ith so lvent in sp ecial containers before rin s in g in the s in k . Attached sign #2 posted a t these s in k s .
3. ' Other Area Sinks - Other sin ks clo se to areas where pyranol i s a t use have been posted w ith signs requesting people not to wash hands wet w ith pyranol in these s in k s . For the people th a t do come in contact with pyranol there should be e ith e r a contained or co n tro lled sin k c lo se r to the area where they work. Personnel should continue to wash t h e ir hands in these sin k s as they would normally unless they have a su b sta n tia l amount o f pyranol on t h e ir hands. Attached sign #3 posted a t these sin ks.
GENP 003341
771506
Page 2 9/10/75
APPENDIX f,T"
Please inform your people th a t the purpose o f these sig n s I s mainly to in s t r u c t those people th a t freq u en tly come in contact w ith pyranol. For people in such areas as Winding, Components and P re tre a t Assembly th a t have in s ig n if ic a n t contact with pyranol there w ill be no change in the method o r place where they wash t h e ir hands.
R . . C , Padowicz M gr.-Proc. & Equip. Eng.
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