Document n9aoR45w0n7Nw7nGNpvoZqy3R

SEVERN T RENT STL STL Chicago 2 41/ Bond Street University Park, IL 6046b Tel: 708 534 5200 Fax; 708 534 5211 www.si/-jnc.com s iv e r n it r e M ANALYTICAL ::JOB :N C M B E K : i-2;33 6 2 9 Prepar ed For : ' /Weston o 1u tion s , Inc . 1,400 West o n Way Building " 5-2... .. West1 C h e s t e r , PA 19 3 8 C -14 9 9 Froj ecr. : Confidential D e c arur .EC Inve s t ig a t ion Attent.i or. : J a i K e s a r i Date' : 0 1 / 2 8 / 2 0 0 5 Name: : Ki chard C . Wright. Title : Proj ect. Manager E-Mail : rwright@st.l- inc .com Date . STL Chicago 2417 Bond. Street University Park, IL 60466 PHONE : (708) 534-5200 F A X .,: (708) 534-5211 31Ths Report Contains } Pages Leaders in Environmental Testing Severn TreriL Laburaturic;;, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 233629 Data Summary............................................................... 1 Chain of Custody......................................................... 12 Case Narrative.................................... 16 Raw D ata...................................................................... 18 STL Chicago is part of Severn Trent Laboratories, Inc. SAM P L E I N F 0 R M A T I 0 N Date: 01/28/2005 Job Number. 233629 Customer.., Weston Solutions, Inc. Attn...... Jai (Cesari Project Number........ : 20004891 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur - FC Investigation Laboratory .! . Sample ID Customer '..'.i Sample ID 233629-1 DLOl-5B-327R-0-0000 233629-2 DLOI -SB-327R-0-0005 233629-3 DLOI-SB-327R-0-0020 233629-4 DLOI-SB-327R-0-0050 233629-5 OLOI-SB-327R-0-0150 . .. Sample. ....Matrix Dato Sampled Sot L 01/14/2005 Soi L 01/14/2005 Soi L 01/14/2005 Soi L 01/14/2005 Soi L 01/14/2005 T ime Sampled 03:15 03:25 08:35 09:10 10:00 Date ..Time Race ived '' Received 01/20/2005 10:00 01/20/2005 10:00 01/20/2005 10:00 01/20/2005 10:00 01/20/2005 10;00 Page 1 >' 1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233629 CUSTOMER: Weston Solutions^ Inc. Customer Sample ED :DLOI-5B-327R--0000 Date S a m pled.......:01/14/2005 Tima Sampled...... :QE:15 Sample Matrix..... :Soi l TEST METHOD Lloyd Kahn :RARAMETE R/TEST. 0 ESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid N LABORATORY TEST RESULTS . PRDJECT: CONFIDENTIAL DECATUR . Laboratory Sample ID 233629-1 Date Received...... 01/20/2005 Time Received...... 10:00 Date:01/2/2Q5 ATTN: Jai Kesari SAMPLE RESULT 170 DO FLAGS HOL 780 RL 3000 DILUTION ;UNITS BATCH :DT DATE/TIME TECH mg/Kg 1404S7 01/27/05 1405 els * [r. Description - Dry Wgt. Page 2 STL Chicago is part of Severn Trent Laboratori es, Inc. Job Nunber: 233629 . CUSTOMER: Weeton Solutions, Inc. LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Date:I/28/2D5 ; ATTN: Jai Kesari P3 1 * ]n Description = Dry Ugt. Page 3 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233629 CUSTOMER: Weston Solutions, Inc. Customer Sample [0: DL01-SB-327R-0-0020 Date Sampled....... :01/4/2005 Time Sarrpled....... :00:35 Sample Matrix....,: Soil TEST METHOD Lloyd Kahn PARAWETER/TEST DESCRIPTION Total Organic Carbon (Soi Is) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT.: CONFIDENTIAL DECATUR Laboratory SampLe ID: 233629-3 Date Received...... : 01/20/2005 Time Received....... : 10:00 Date:01/23/2005 ATTN; Jai Kesari SAMPLE RESULT & FLAGS : 2600 MDL 200 RL DILUTION UNITS BATCH BT DATE/TIME TECH 790 mg/Kg 14Q4B7 01/27/05 1439- c Is * In Description - Dry Wgt. Page 4 in STL Chicago is part o-f Severn Trent Laboratories, Inc. Job Number: 233629 CUSTOMER: Weston Solutions,. Inc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DLI-SB-327R-0-0Q5Q 01/14/2005 09:10 Soi l TEST :METHOD. PARAMETER/TEST DESCRIPT10 ; LLoyd Kahn Total Organic Carbon <5oils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sarrple ID: 233629-4 Date Received....... : Q1/2/2QD5 Time Received....... : 10:00 Date:01/28/2005 ATTN : Jai Kesari SAMPLE RESULT 2200 FLAGS :fb 150 RL : DILUTION UNITS BATCH DT, DATE/TIME TECH 600 mg/Kg 1404E7 01/27/05 1451 els * In Description = Dry Ugt. Page 5 STL Chicago is part of Severn Trent Laboratories, Ine. Job Number: 233629 CUSTOMER: Weston Solutions,. Inc. Customer Sample ID: DLQI-SB-327R-Q-015Q Date Sampled..... : 01/14/2005 Time Sampled..... : 10:00 Sample Matrix.... : Sol 1 TEST METHOD LLoyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORI TEST RESULTS ;:;PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233629-5 Date Received...... : 01/20/2005 Time Received...... : 10:00 Date:01/28/2005 ATTN: Jai Kesari SAMPLE RESULT 700 FUGS: 'MB'L: 98 RL -01 LUT ION UNITS. BATCH IDT ;DATE/TtME :;:-TECH 330 mg/Kg 14D4B7 01/27/05 1510 c Is * In Description = Dry Ugt. Page 6 STL Chicago is part of Severn Trent Laboratories, Ine. Job Number: 233629 LABORATORY CHRONICLE Date: 01/28/2005 CUSTOMER: Weston Solutions, Inc, Lab ID: 233629-1 METHOD EDD PKG 1NO (WD> Lloyd Kahn Client ID: DLOI-SB-327R--0 DESCRIPTION Electronic Data Deliverable PKG INO (WET CHEMISTRY) Total Organic Carbon (Soils) Lab ID: 233629-2 Client ID: DLO1-SB-327R-0-05 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233629-3 client ID: DL01-SB-327R-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carboh (Soils) Lab ID: 233629-4 Client ID: DLOI-SB-327R-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233629-5 Client ID: DLOI-SB-327R-0-0150 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT CONFIDENTIAL DECAT'JR ATTN: Jai Kesari Date Rccvd: 01/20/2005 Sample Date: 01/14/2005 1RUN# 1 BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1405 DILUTION Date Recvd: 01/20/2005 Sample Date: 01/14/2005 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1423 DILUTION Date Recvd: 01/20/2005 Sample Date: 01/14/2005 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1439 DILUTION Date Recvd: 01/20/2005 SampLe Date: 01/14/2005 RUN# BATCH# PREP BT #<S> DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1451 DILUTION Date Recvd: 01/20/2005 Sanriple Date: 01/14/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 . 01/27/2005 1510 DILUTION Page 7 7 Job Number.: 233629 c u s t o m e R: .Veston'SoLution?., I n c . . Q U A L I T Y C 0 N T R 0 1, R E S U L T S PROJECT: CONFIDENTIAL DECATUR Report Date.: 01/28/2005 ATTN: Jai Kesari Test Method....... : Lloyd Kafirr/!/ Method Doseription. : Total Organic Carbon (Soils) 'Parameter..... .... : Organic Carbon, Tot. { T O O OC Lab ID Reagent Units ICV 140487-002 JQ4LSTTC2 MB 140487-003 LCS 140487-004 100F5TLK3 LCD 140487-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1928.56 32.00 U 4761.61 4300.41 4761.61 cev 140487-015 104LSTTC2 CCB 144S7-016 CCV 140487-015 I04LSTTC2 CCB 140487-016 mg/Kg mg/Kg mg/Kg mg/Kg 2034.14 32.00 2088.83 32.00 U U 140487 Equipment Cock ___ : TOC3 Analyst...: els .. Test Code. : TOC ........ True Value 2000.00 4780.00 4780.00 2000.00 2000.00 orig. Value QC Calc. F * Limits Date Time 96 174.75 155.03 U 100 U 90 10 102 104 % 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 01/27/2005 0800 01/27/2005 0807 01/27/2005 0839 01/27/2005 0845 01/27/2005 1149 01/27/2005 1214 01/27/2005 1523 01/27/2005 1527 Page 8 * %=% r e c , r =r p d , a =ABS Diff., 0=7 Diff. 8 Q U A L t T 'Y S $ V ft.A R C E M.E T H' 0 D S R E f E R E N GiiMS'i' A-N-D N O t E S Report Date::01/28/2005! REPORT COMMENTS 1) All pages of this report are integral parts of the analytical data. Therefore, this report should be reproduced only in its entirety. 2) SoiL, sediment and sludge sample resuLtg are reported on a "dry weight11 basis except when analyzed for LandfilL disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, chlorine Residual and Dissolved Oxygen analyses are to be performed inmediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on Laboratory receipt. Glossary of flags, qualifiers and abbreviations iany number of which may appear in the report) inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated limit. < Not detected at or above the reporting limit. J Result is Less than the RL, but greater than or equal to the method detection limit. B Result is Less than the CRDL/RL, but greater than or equal to the IDL/MDL. S ResuLt was determined by the Method of Standard Additions. F AFCEE: Result is Less than the RL, but greater than or equaL to the methoddetection Limit, Inorganic Flags (Flag Column) ICV,CCV,ICS,CCB,ISA,1SB,CRI,CRA,MRL: Instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control limits. + MSA correlation coefficient is Less than 0.995. A MS, MSD: The analyte present in the original sampLe is 4 times greater than the matrix spike concentration; therefore, controL limits are not appLieabLe. E SD: Serial dilution exceeds the control limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting limit or had a negative instriment reading lower than the absoLute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or Lower controL Limits. U AS(GFAA) Post-digestion spike was outside B5-115% control limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated limit. ND Compound not detected. J ResuLt is an estimated value below the reporting limit or a tentatively identified compound (TIC). Q ResuLt was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuelpattern. Z The chromatographic response does not resemble a typicaL fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or atentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds theupper or Lower controllimits. EBl, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sampLe. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; aLso compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I indicates the presence of an interfence, recovery is not calculated. M ManuaLLy integrated compound. P The Lower of the two values is reported when the % difference between the results of two GC columns is Page 9 9  IJ A L I T Y - A S S U R A N C E M E T H. 0 D R E ' f I E - ) i : C . S A.N D N O T t S ' . . Report Date: O1/2B/2O05 greater than 25%. Abbreviations AS Post Digest!oh Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation analysis of Al or D1 C2 Confirmation analysis of A2 or D2 C3 Confirmation BnaLysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CR I Low Level Standard check - ICP cv Calibration Verification Standard Dil Fac Dilution Factor - Secondary dilut ion analysis Pi Dilution 1 D2 Dilution 2 D3 Di Lution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Low LeveL DSM Distilled Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS LD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank ICV Initial Calibration Verification DL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB interference Check Sample B - ICAP Job Mo. The first six digits of the sample ID which refers to a specific client, project and sample group Lab ID An 8 number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation SLank MD Method Duplicate MDL Method Detection Limit MLE Medium LeveL Extraction Blank MKL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Mot Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike (ICAP) RA Re-analysis of original Al Re-analysis of DI A2 Re-analysis of D2 A3 Re-analysis of D3 RD Re-extract ion of dilution RE Re-extract ion of original RC Re-extraction Confirmation RL Reporting Limit RPD ReLative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 10 10 Q U A.L I T ;'-.;A:S\S.U R A N X' E M E'.T H' 0 D S R E F E R E E C 'E 'S ' A it D N O T E S Report Date; 01/28/.2OO5 RTW Retention Time Window SampLe ID A 9 digit number unique for each sampLe, the first six digits are referred as the job number SCB Seeded Control Blank SD serial Dilution (Calculated when sample concentration exceeds 50 times the HDL) UCB Unsecded Control Blank ssv Second Source Verification Standard SLCS solid Laboratory Control Standard(LCS) PHD pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control sample Duplicate MDPH pH SampLe Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS G1 GeLex Check Standard Range 0-1 G2 Gelex Check Standard Range 1-10 G3 GeLex Check Standard Range 10-100 G4 Gelex Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS=HS Post Spike (GFAA) Note 2: The MD calculates an absolute difference (A) when the sample concentration is Less than 5 times the reporting limit. The control Limit is represented as +/- the RL. Page 11 11 CHAIN OF CUSTODY 12 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM P3 rH 5 3 3 C5H Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19330 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.kesari@westo nsolution s.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 PAGE of ANALYSES REQUESTED Sampfer: E. Caldwell, B. McCanless 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLiMS # 1 K. Client Sample Identification DLOJ SB 327R 0 0000 DLOI SB 327R 0005 DLOI SB 327R 0020 DLOI SB 327R 0050 DLOI SB 327R 0150 Collection Date 14-Jan-05 14-Jan-05 14-Jan-05 14-Jan-05 14-Jan-Q5 Collection Time 8:15 8:25 8:35 9:10 10:00 X X X Zoo. iCcoSJ Sample Matrix SOIL SOIL SOIL SOIL SOIL Comments X X CHAIN OF CUSTODY Cooler ID No.: Rei inquisjT^e Oj*te Time Received By: S" ///? A r /fo * // fed Ex <1 Cooler Temp. ("C): Date Time / / $ & n '/fed ' i potati \ooo PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: Sample Lot#: STL Chicago Internal Sampie Custody Transfer Record _________________ Client: Sample No. t-* r Analysis /U Relinquished by: Received by: 1 D ate T im e // e * /# ? ' //l f r Comments CH1-22-11-00VC-1/99 rpjsckL Job Sample Receipt Checklist Report Job Humber.; 233629 Location.: 57222 Check List Number.: 1 Description.: Customer Job ID.... : Job Check List Date.: 01/20/2005 Project Number.: 20004891 Project Description.: Confidential Decatur - FC Investigation Customer..... .; Ueston Solutions, Inc. Contact.: Jai Kesarj Questions ? (Y/N) Comments V2 Date of the Report..: 01/28/2005 Project Manager.... : rcu Chain-of"Custody present?........... Y Were samples dropped off at or picked up by STL?.. N Custody seal on shipping container?............... Y ...If "yes", custody seaL intact?................. Y Custody seals on sample containers?.............. N ...If "yes", custody seal intact?................. Samples iced?...... .......................... Y Temperature of cooler acceptable? (4 deg C +/- 2). Y 2.2 Samples received intact (good condition??........ Y Volatile samples acceptable? (no headspace)...... Correct containers used?.................... Y Adequate sample volume provided?.................. Y SampLes preserved correctly?.............,........ Y Samples received within holding-time?.............. Y Agreement between COC and sample Labels?....... . Y Radioactivity at or below background Levels?...... Y A Sample Discrepancy Report (SDR) was needed?.... N If samples were shipped was there an air bill #?.. Y Sample custodiah Signsture/Date............. Y Rage 1 15 CASE NARRATIVE Client: Job #: STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc. 233629 Date Rec'd: 01/20/05 This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average of the sample bums is reported. 2, The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blank was less than the reporting limit. 5. The LCSs were within acceptance limits. 6. The matrix QC in this analytical batch was done on a sample from Job #, 7. The first analysis o f sample 232679-5 was not reported, but repeated using more sample weight. See the raw data. Wet Chemistry Section Manager Date 17 RAW DATA 18 ### RUN LOG **# Ll< TDC, (92 > 1/28/05 10:01 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140487 Status,.... *r,,: RPT Batch Date...: 01/27/05 Batch Time...: 1528 User Name....... : els QC c o d e . : TOCS Calc Code....... : TOCS Location Code..: 57222 Equipment Code.: TQC3 Import Code____ : TEST CODE TTTTTTTTTTTTT 0000000CCC I1I CccCccC3SSCCC 23 4AAA 2A S ss VVV V 2A 234 2 2 SAMPLE: Grp Pos Sample ID Dilution TEST POS Date / Time 123456 7111222 78 90 12 11 ___ICAL_I05ASTTC1_ 0 12 ___ICV_I04LSTTC2_ 1/27/05 OSOQ 0 13 ___ MB__ 1/27/05 0807 0 14 ___ LCS_100FSTLK3_3 1/27/05 0839 0 15 ___ LCD_I00FSTLK3_3 1/27/05 0845 0 16 233507_5_S___ 1/27/05 0852 0 17 233507_5_SJ4S_104LSTTC26 1/27/D5 0917 0 18 233507_5_SJ1SDJ 04LSTTC2_6 1/27/05 0929 0 19 233507_6_S___ 1/27/05 0937 0 1 10 233507 7 S 1/27/05 0953 0 1 11 2 3 3 5 0 7 8 S ___ 1/27/05 1017 0 1 12 2335Q7_9_S___, 1/27/05 1034 0 1 13 233507_10_S___ 1/27/05 1100 0 1 14 1 15 233507^11^3___ ___ CCV_JQ4LSTTC2_ 1/27/05 1131 1/27/05 1149 0 0 1 16 CCB 1/27/05 1214 0 1 17 233629_1_S___ 1/27/05 1405 0 1 18 235629 2 S 1/27/05 1423 0 1 19 233629_3_S___ 1/27/05 1439 0 1 20 233629^4^3___ 1/27/05 1451 0 1 21 233629_5_S___ 1/27/05 1510 0 1 22 ___CCVJ04LSTYC2_ 1/27/05 1523 0 1 23 ___CCB__ 1/27/05 1527 0 19 *** QC Summary *** <VZ ) Total Organic Carbon (Soils) Report Date: 1/28/05 10:01 Method Code..: TOCS Batch Code...: 140487 Status...... : RPT Batch Date...: 01/27/05 Batch Time...: 1528 User Name____: els QC Code....... : TOCS Calc Code..... : TOCS Location Code..: 57222 Equipment Code.: TOCS Import Code____: Grp Smp Sample ID Pos Test Result Known Original Alternate QC Res F QC Res F 1 2 ___1CV_ID4LSTTC2_ 1 TOC 1928.56 2000 96 13 14 ___MB__ ___LC5_I00FSTLK3_3 1 TOC 1 TOC -2.33 4761.61 4780 -2.33 ... 100 15 17 LCD IOOFSTLK5 3 233507_5_S_MS_I04L5TTC2_6 1 TOC 4300.41 5 TOCAV2 2142.12 4780 2000 -2.33 906.24 4761.61 90 82 10 1 8 233507.5. SJ tS Dj ML ST TC Z^ 1 15 ___CCV_I04LSTTC2_ 5 TOCAV2 2242.53 1 TOC 2034.14 2000 2000 906 r24 2142.12 90 102 8 1 16 ___CCB__ 1 TOC "1.98 1 22 ___CCV_104LSTTC2_ 1 TOC 2088.83 2000 104 1 23 ___CCS__ 1 TOC -2.90 Rage 1 20 *** RAW TEST DATA *** (VZ > Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140487 Status....... : PtPT Batch Dato...: 01/27/05 Batch Time...: 1528 User Name___ : cts SAMPLE: Grp Pos Sample ID 11 12 13 1A 15 16 17 18 19 1 10 1 11 1 12 1 ' 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 ICAL I05ASTTC1 ICV I04LSTTC2 MB LCS I00FSTLK3 3 LCD I0QFSTLK3 3 233507 5 S 233507 5 S MS JQ4LSTTC2 6 233507 5 S MSD I04LSTTC2 6 233507 6 S 233507 7 S 233507 8 S 233507 9 S 233507 IQ S 233507 11 S CCV I04LSTC2 CCB 233629 1 S 233629 2 S 233629 3 S 233629 4 S 233629 5 S CCV I04LSTTC2 CCB QC Code........ : TOCS Calc Code.,.,..: TOCS Location Code..: 57222 Dilution TOC mg/Kg T0C2 mg/Kg Raport Date: 1/2S/5 10:01 Equipment Code.: TOC3 Import Code___ : OC3 mg/Kg TC4 mg/Kg TOCAV2 mg/Kg 1928.56 -2.33 4761.61 4300.41 928.65 2142,12 2242.53 484.15 423.10 27231.75 2883.66 1524.39 1123.08 2034.14 -1.98 12790.69 9670.66 2877.12 2427.88 815.33 2088.83 -2.90 883.82 289.32 363.79 26351.91 2510.29 1048.63 751.41 21624.69 6896,69 2295.93 1933.62 576.51 906.24 2142.12 2242.53 386,74 393.44 26791,83 2696.97 1286.51 937.25 17207.69 8283.67 2586.53 2180.75 695.92 Page 1 21 *** RAW TEST DATA *#* V2 ) Total Orgahic Carbon (Soils) Method Code Batch Code. Status.... TOCS 140487 RPT Batch Date.. : 01/27/05 Batch Time.. : 15ZB User Name... : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 lev Q4LSTTC2 13 MB 14 LCS IFSTLK3 3 15 LCD I00FSLK3 3 1 6 233507 5 S 1 7 233507 5 S MS I04LSTTC2 6 1 3 233507 5 S M5D I04LSTTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 11 233507 8 S 1 12 233507 9 S 1 13 233507 10 S 1 14 233507 11 S 1 15 CCV I04LSTTC2 1 16 CCB 1 17 233629 1 S 1 18 233629 2 S 1 19 233629 3 S 1 20 233629 4 S 1 21 233629 5 S 1 22 CCV I04LSTTC2 1 23 CCB GC Code....... : TOCS Calc Code..... : TOCS Location Code..: 57222 Dilution TOCAV3 mg/Kg TQCAV4 mg/Kg Report Date: 1/23/05 10:01 Equipment Code.: T0C3 Import Code.*,, ; T0CR1 ug TOCR2 ug T0CR3 ug 96.4279 -0.3735 139.5152 139.3332 58.6906 141.5939 150.9224 40.4262 41.0404 313.1651 128.3230 44.6645 59.6358 101.7072 -0.3164 65.2325 85.1018 53.8022 75.2644 33.1839 104.4414 -0.4647 55.5039 24.7368 36.4885 292.5062 129.2797 40.4770 39.8247 175.1600 94.4846 73.6993 69.4171 37.0118 Page 2 22 *** RAW TEST DATA kirk (V2 ) Total Organic Carbon (Soils] Method Code..: TOCS Batch Code...: 140487 Status...... : RPT Batch Date...: 01/27/05 Batch T ifriE,.,,r 1528 User Name____: els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV 104LSTTC2 13 MB 14 LCS IQQFSTLK3 3 15 LCD I00FSTLK3^3 1 6 233507 5 S 1 7 233507 5 S MS I4L5TTC2 6 1 0 233507~5VmSD I04LSTTC2 6 1 9 2335Q7 6 f 1 10 233507 7 S 1 11 233507 8 S 1 12 233507 9 S 1 13 233507"10 S 1 14 233507_11_S__ 1 15 CCV 104LSTTC2 1 16 CCB 1 17 233629 1 S 1 18 233629 2 S 1 19 233629 3 S 1 20 233629V s 1 21 233629V s __ 1 22 CCV I04LSTTC2 1 23 CCB QC Code....... TOCS Calc Code..... TOCS Location Code.. 57222 Di lut ion TOCR4 ug UT1 9 Report Date: 1/28/05 10:01 Equipment Cede.; TQC3 Import Code___ : WT2 WT3 99 0.05 0.16 0.0293 0.0324 0.0632 0.0661 0.0673 0.0835 0.0970 0.0115 0.0445 0.0293 0.0531 0.05 0.16 0.0051 0.0088 0.0187 0.0310 0.0407 0.05 0.16 0.062B 0.0855 0.1003 0.0111 0,0515 0.0386 0.0530 0.0081 0.0137 0.0321 0,0359 0.0642 Page 3 23 *** RAW TEST DATA (V2 ) Total orgahic Carbon (Soils) Method Code..: TOCS Batch Code...: 140487 Status.... .. : RPT Batch Date...: 01/27/05 Batch Time...: 152B User Name.,,..: els SAMPLE: Grp Pos SampLe ID 11 ICAL IQ5ASTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 233507 5 S 1 7 233507 5 S MS I04LSTTC2 6 1 8 233507 5 S MSD I04LSTTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 n 233507 8 S 1 12 233507 9 S 1 13 233507 10 S 1 14 233507 11 S 1 15 CCV I04LSTTC2 1 16 CCB 1 17 233629 1 S 1 18 233629 2 $ 1 19 233629 3 S 1 20 233629 4 S 1 21 233629 5 S 1 22 CCV I04LSTTC2 1 23 CCB QC Code... calc Code. ___ : TOCS Locati oh Code..: 57222 Di luti on DLFAC N/A TCS mg/Kg 3.2000 1.0000 5.4608 4.9383 2.5397 2.4206 2.3774 1.8935 1.6219 14.1593 3.3333 4.7128 3.0160 3.2000 1.0000 24.2424 14.2222 6.2992 4.7833 3.0505 3.2000 1.0000 Report Date: 1/28/05 10:01 Equipment Code.: TOC3 import Code....: TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg Rage 4 24 Calibration Report Print Date/Time: 2005/01/27 7:40:56 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8.538e+04 Y Intercept (b): 436425 r-squared: 0.99800 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -4530 0,000 -5.165 No Sample Det 01/17/2005 09:63 10ugramC 1085240 10.000 7.599 01/17/200510:15 20 ugram C 1870210 20.000 16.794 01/17/200510:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210.740 01/17/2005 11:07 300 ugram C 26478564 300.000 305.025 01/17/2005 11:15 400 ugram C 33682344 400.000 389.401 01/17/2005 11:32 Multiple Analysis Report Print Date/Time: 2005/01/27 15:34:24 Sample ID Result Std. Dev. RSD Mode ALT ICV 96.4279 TC ICB-MB - 0.3735 TC LCS 139.5152 TC LCD......................... .........139.3332.............. ...TC .. 233507-5 58.6906 TC 233507-5 55.5039 TC 233507-5ms.......................... 141.5939... ........... TC 233507-5msd 150.9224 TC 233507-6 40.4262 TC 23350743................ ............24.7368... ........... TC 233507-7 41.0404 TC 233507-7 36.4885 TC 233507-8................ ............ 1038.8387... ........... TC 233507-8 313.1651 TC 233507-8 292.5062 TC 233507-9................ ............ 128.3230... ........... TC 233507-9 233607-10 129.2797 44.6645 TC TC 233507-10.............. ............. 40.4770... ........... TC 233507-11 59.6358 TC 233507-11 39.8297 TC CCV........................ ......... 101.7072.............. ...TC .. CCB -0.3164 TC 233629-1 431.2907 TC 233629-1................ ............ 65.2325... ........... T C 233629-1 175.1600 TC 233629-2 85.1018 TC 233629-2................ ........... 9 4 4846,., ........... TC 233629-3 53.8022 TC 233629-3 73.6993 TC 233629-3................ ............ 75.2644... ........... TC 233629-4 69.4171 TC 233629-5 33.1839 TC 233629-5................ ............ 37,0118... ........... TC CCV 104.4414 TC CCB -0.4647 TC 26 Detailed Analysis Report Print Date/Trme: 2005/01/2715:34:29 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270753 Timestamp: 01/27/2008^ 08:00 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 96.4279 96.4279 8669169 0.795 17 9 4 327 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270804 /" " M Timestamp: 0f/27/2005o8:07, Sample Type: Sample / / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3735 -0.3735 -6120 1.073 0.986 120 Last Message: No Sample Detected Sample ED: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270834 Timestamp: 01/27/2005 08:39 Sample Type: Sample / R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 139.5152 139.5152 11937182 1.135 2.132 279 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270840 ___-- (Timestamp: 01/27/2005 08:45 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 139.3332 139.3332 11921644 1.692 2.690 261 Sample ID: 233507-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mpde: TC Filename: 01270847 ? Tim ^tam p: 01/27/: 005 08:52 Sample Typ- Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Tim^s. 1 59.6358 59.6358 5117301 1.754 2.750 240 Sample ID: 233507-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL \ Mode: TO \ Filename: 01271133 \ Timestamp: 01/27/2005 11:37 \ Sample Type: Sample Rep # ppm C ug C Raw Data \Beginning Ending Integration Baseline Baseline Time 1 39.8297 39.8297 3426312 1.854 2.853 223 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271143 Timestamp: 01/27/2005(11:4 Sample Type: Cal. Vrificatif R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 101.7072 101.7072 9119898 1.495 2.494 280 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271212 Timestamp: 01/27/20 Sample Type: Sample ) Rep# ppmC ugC 1 -0.3164 -0.3164 Raw Data Beginning Ending Integration Baseline Baseline Time -1251 1.551 1.550 120 Last Message: No Sample Detected Sample ID: 233629-1 \ - Mode: TC Method: boat \ ^ f v / f i l e n a m e : 01271353 Cal. Curve: SOILCURVE yOperator ID: CAROL V Timestamp: 01/27/2005 13:58 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 431.2907 431.2907 36848^44 5,883 6.878 296 Sample ID: 233629-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271400 Timestamp: 01/27/20051 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline 1 65.2325 65.2325 5595131 2.851 Time 3.847 243 Sample ID; 233629 1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271408 Timestamp: 01/27/2005 14:14 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 175.1600 175.1600 14980432 2.218 3.216 309 Sample ID: 233629-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271417 yTimestamp: 01/27/2005 14:23 Sample Type: Sample i R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 85.1018 85.1018 7291513 2.294 3.292 253 Sample ID: 233629^2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271427 Timestamp: 01/27/2005 14:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 94.4846 94.4846 8092595 2.002 3.000 278 Sample ID: 233629-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271434 Timestamp: 01/27/201 Sample Type: Sample I 14:39 R e p # ppm C u g C Raw Data Beginning Ending integration Baseline Baseline Time 1 53.8022 53.8022 4619249 1.972 2.972 236 Sample ID: 233629-3 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271440 Timestamp: 01/27/2005 14:46 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 29 1 73.6993 73.6993 6318007 1.969 2,969 249 Sample ID: 2 3 3 6 2 9 ^ 1 Method: boat iu Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC -- --------- . Filename: 01271446 ^ Timestamp: 01/27/2005 14:51^ Sample Type: Sample / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 75.2644 75.2644 6451626 2.200 3.200 242 Sample ID: 233629-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271455 Timestamp: 01/27/2005 15:00 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 69.4171 69.4171 5952398 1.801 2.801 278 Sample ID: 233629-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271506 Timestamp: 01/27/2005 15:10 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 33.1839 33.1839 2858911 2.827 3.826 203 Sample ID: 233629-5 Method: ' boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename: 01271510 Timestamp: 01/27/200615:15 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 37.0118 37,0118 3185730 2.389 3.386 225 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271517 X' Timestamp: 01/27/2005 15:23 Sample Type: Cai. Verification...^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 104.4414 104.4414 9353335 1.826 2.823 305 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271524 f Timestamp: 01/27/2005 15:27 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4647 -0.4647 -13914 2.272 2.081 120 Last Message: No Sample Detected STL Chicago 130 Page No.: j_ 1 TOC in Soils Book No.: 3 / 3 / Method: Uoyd Kahn Instrument: Phoenix BOOO(TQC*1 LabNet flalctr/ V C 7 7 ? Calculation: Data of Slanciarci Curve: / / ? - V i \ TOCimg/kg) = ug C / grams sample B o o k * 3 7 7V P aoa * / 2.{ MS, M SD Known Cone, (mgflig) = 100 ug C lgrams sample MS, M SD Observed (mgflg) = ug C / grams sampte MS, M SD R a d tofaserved rnarttg-awo. sample reauH fmaflarti x 100 known conoentralion in mg/kg Standard Traceability: (Kotw Working Standards are prepared dally from the noted Slock Solutions.) Stock I (Curve) J. O C / K 7 7 0 < Stock il (ICVCV} / / 3 / 5 7 Z. LCS Source ID / / . y 3 ? LCS True Vakie 7 ? .,/ - i Acceptance R a n g e 7 3 f ^ C Sampia CD: Sample Weight fg> ugC Commante: 77V l7'n -frf* 71 C} . / 'V y ?3 3 07 (p,o-2Y3 W ^ V. L t D . .i . O 3 7 Y --X----3----3-- 'r----n------'rTrT" ,C'(r 3 X O. o 3 3 ! i -r -- JC--L n . r - (r 7 / V-'t- f'C- / 5 V y ? 3 /3 Q&C, 2fi 5-57 3 - 3 7 ' / ______ ; _/:v t w W 2 . ( 3 / 7 V / 7 7 7 / 3 3 0 2 / 7 7' i3, ?/ 17n & r / f o 3 - -- (fi- : ~-n C :,7 ^ 3 V . . r i T s~ r & / ?c V i 3 3 - <i 3 3 /7 7 / i ' v / V/Y V * "V :r ^ Oj _V o - / 3n3 o : ( T T ? t ------ 7" c / / / 3- r 3 /7 /7 V -jZa-2 i -f ______ !___ - d -f :0 v v r ' 7 , r j/ r' L/'/! ' Lfi.-, ~ :/ 3 V' /J .9 J 117 W iV v r - ( V 7 7 /7 3 5- 7 ?&.- 7 / 7 / i - / / . 5 3 / 5V. 3 7r 3 k _ _ : - W O ( / 3 < l-xy c cY 3 3 .53V? ? ffno-7i\ Pep Analyst: Analyst: ./7 Reviewed bvr . ->-i ______________Dater : .-4 -.y ,__________________ Dater / / / 7 / V ^ Y / a- V . ^ ------- Data: cni-a-i:-isra-o*H5i STL Chicago TOC in Soils Method: Lloyd Kahn Page No Scoli Wo.. instrument Fncenu 3000 .'TOC-j LaoWet Batcfv ~i Cafctitottone: roc (mgrkg) 3 14C/grams sample Oate of Standard Curve: Sock #_______ PageX ~ MS, MSD Known Cone, (mgfkg) = 100 ug C t grams sample MS, MSD Observed (m gikgi = ug C / grams sample MS, MSD Rec. * (observed mod - aw . sample result (m ortall j r l t f i known concentration' in mgikg ^ / v , X Standard Twcwbilftr: Sloe* I (Curve). (Not*: Working Standards are prepared daily from the rated Slock Sciutcns.) s*,L- ' __________ i'S fo c k N (IC W C C V )___________________ LCS Source 1D -LS True Value Acceptance Range Sampia ID: /? c,-./C' -O <? Sample Weight fg) ug C v /X ' Commenta; .X X lX j X / - X O / , X xv / 1 rJ. Oflt_. _/ - x. __ X" - / r.x '-)' Cl.i _ -a . i-V.J 7 --jLa^Tf- X V, Vv^x, X< xXX W ( / i.-iX 1 > x ' ./,' . XV X t X ! -.."2 3 - x / v ; . SX rv j.2 - __ - ] _ 3 , X . X 3 X / - --I _.t : Y3 _- .n x. <X- r r v l-fjXtcT-/n>i/X/ ('x3/f'-tu-ys ' 1 - X V( s ' . -,r"" 1 X', / 6 XXX X J tv v . X3/7_ 7(ritX3tr/V. -r; vX? _x . J Jx. -V ---------------X- ^ -- X b X X X ----- Prep Analyst, Analyst . Reviewed by: -3 f PfTfnata: J s? / M -- i 3 .; = cm-rs-ii-w^sior