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MATERIAL SAFETY DATA SHEET
(APPROv'.n oi" t^e ij.s, department of labor as - "entiaii)i migr" to <o.m osha-TTi
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$<** 1 NAME * PRODUCT
d I I V . JfATE 2iP CODt
DOW CHEMICAL U.S.A.
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MIDLA--N--D--.--M--ICHIGAN 48640
January 4. 1973
THifjt NAM
Vinyl Chloride, . Monomer
--rvnowyoi
91575
CM*<5CNC_f >m'6n| *</. 1* MO'jm
517 - 636 - 4400
BOILING POINT fF.)
VAPOR PRESSURE
J09)
Va0R DENSITY T.l. = 1)
+7.16________ .. 2524
2x15
SOLUBILITY IN HATER SPECIFIC GRAVITY (H 70 = 11 *1 VOLATILE by VOLUME
[ f light 1 0.9104 20/20C 1 100
______ ____sgion * fire ahp explosion hazard OAra faint 'phenolic- odor fro
HAJri POINT UNO UTMOO OJEOl
IF L*MM*lLt
*1 UP -4 4 - *
1-TlH.jLb ]L tOt
-108.4 e
Cleveland Open Cup L.i
4
|u r l
26 "
E XTInguiSHInG MEOIa....... -
Xg.rr---i'bi wratceorntarTrrrinnenc
LXJ fog
[XJfoam
ori--itailrceohoal ndr^p-i rotectiormnDf?oy f surri--oul ndinog
L |foam
I^Jco7
iXJchemical I J
eiquiprment only
`"C,*L "Ht r,CMT,"G fotact,o.
anu Self-contained breathing apparatus.
Vapors can form flammable & explosive mixtures with air at ail normal ambient
tenroeratures. All sources of ignition should be avoided in areas where vinyl chloride vapors are present.
S.ciion 5 REACTIVITY DATA
STABILITY
(NORMAL CONOlTIONSI
c6mLVti"3hs ic * jO'O
Avoid exposure to air, oxygen,
stable
Ignites in air at 882F.
unstable
sunlight,
heat,
moisture.
INCOMPAT
To AVO'O
* AT ER | IaCIQ
base
corrosive
H.ov1m**;o.lEizF'N'A-L;
IBILITY -"o>uj ok c ?moos< i 'OH afltfbUifiTr
Hydrogen chloride, carbon monoxide.
hazardous
polymeriz
X
MAT CONQinONi to a void OCCUR . Exposure to oxygen (air), sunlight, moisture & free
ation
WILL NOT radical initiators or other catalytic impurities.
IPwD cUn1 0O3s
03
OCCUR
section fi SPILL OR LEAK PROCEDURES
S l ^ ^ rob. t AKL'I |M
UATL ' AL IS NiLLOEO OR SP-LLfU
*' "
Remove all sources of ignition, supply ample ventilation, allow only properly
protected personnel into the area; do not allow vinyl chloride to enter the sewer .system because of explosive hazard. __ _______________ _______________ ________ __
i , tv r mo j
Dispose of vinyl chloride as a vapor, venting to an area free of any source of ignition.
MATERIAL? SAh*E IY DA IA Ii>rr fct: <cont.,
Section 7
HEALTH rU7*RO DATA
' -+< L*
# * i -
m01.Mt>, MICHIGAN 44C
Noc considered a problem because product is a gas at ambient temperatures.
CY*. CONTACT "
Gas - not likely to cause ill effects. Liquid - capable of causing frostbite-type burns. Inhibitor may accumulate
---------------------------------------------------------------------------------------------------
Gas - not likely to cc use irritation.
Liquid - capable of causing frostbite-type b\irna. Inhibitor; if concentrated,
may be absorbed in toxic amounts._______________________ _________ _________________ 1 * IN A RtOH3 TIQH Not absorbed through skin in pure fomu Inhibitor/ If concentrated may be absorbed in tjxic amounts.
f lOn
Ik* *VTC- T#2uQupv_EPWPcamp
(u1w C9L7o2we)Dr ocworneccoemnmtraentidosn
using's guide - dizziness &
level of 50 ppm.. drunkenness, possibly
!.ung irritation. High concentration - anesthetic effect.
EYF
: LUSH WITH r LOWING WATER O, *t LEAST
15
-"INUTE5
EYES & SKIN: Flush with plenty of water for at least 15 min.; for eyes, get medical attention. Remove contaminated clothing and free of chemical before reuse. INHAIATION: If person experiences ill effects, remove hLm to fresh air, keep him quiet & warm & get medical attention. Give artificial respira tion if breathing stops. INGESTION: Not a problem. Gas at room temperature.
Jivf *uv* oa
VQtt.TtWG tF FAT:l*` 1 UNIONS'
SR v k3 CSmVjIUC**
Swct.an 8 SPECIAL PROTECTION INFORMATION
1 """Six or more air changes per hour. . Contro^l to TLV level, or preferably
Dow/ s rp.ganwipnrftiAJndiiR trial hygfgnp IpupT. \ _ _ _ _ _ _ _ :_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
* * 11 * 'WO : C ''3U > 1 p c i ly y
--w
Up to TLV - none,. TLV to 2% for % hour or less - full-face gas mask and
canister. Greater - self-contained breathing apparatus.
*'.`rret <1 c lothinc
Impervious gloves, aprons, shoes. Clean, body-covering clothing. Rescue harness & lifeline for entering tanks or enclosed storage space.
* 11
PROTECTION
NOT HECES1AHY
r Is AFtTV GLASSES L|| I*1 * HOy S'OE IHI 6 LOS
| ~ j^4Ff. r -T cA So f.S ` I*' T h ttt,C iH'CLPS
[ I * H `V : * -
1^
** " 5 G L C S
___BGAS TIGHT GOGGLES OW EQUIVALENT
ggME" Eyewash stations & safety showers should be
Sadia* 9 special ' pRECAimirNS~OR~OTHER comments ~r ead~jly~ avafTable
A ! dm o GE TAKEN (N nlNLlllNC AMU STONING
Storage should be in an isolated, well-ventilated area. Pits, depressions and basements should be avoided.
Avoid all skin and eye contact, especially with inhibited product. Avoid breathing vapors. Vinyl chloride should always be handled with full recognition of its volatility and its flammability. Keep the material enclosed and eliminate all sources of ignition.