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* NALCO MATERIAL SAFETY DATA SHEET Emergency Telephone Number Medical (708) 820-1510 (24 hours) 6 S 7 03 TRADE NAME: NAIOO 5537 EMULSION BREAKER DESCRIPTION: CCtrplex mixture of polyether polyester condensation product and oxyalkylates in a hydrocarbon solvent NFPA 704M/HMIS RATING: 2/2 HEAISH 2/2 FI/MMABTLm 0/0 REACTIVITY 0=lnsignificarrt l=Slight 2=Moderate 3=High 4=Extreme 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient as hazardous under CSHA's Hazard Ocmnunicaticn Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard (s). INGREDIENTS CAS # APFRDX.% Heavy aranatic naphtha Naphthalene Ethylbenzene Xylene 68603-08-7 91-20-3 100-41-4 1330-20-7 70-100 1-5 10-20 5-10 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: Ccnbustible. May cause irritation to skin and eyes. Prolonged inhalation of vapor may be harmful. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Imnediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. - Call a physician at once. Remove to fresh air. Treat symptoms. Call a physician at once. NOTE TO FHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician'judgment should be PAGE 1 OF 8 SAL 000009310 sa NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS BO563-1190 MATERIAL SAFETY DATA SHEET __ NALCO 5537 EMUISION BREAKER PRODUCT NALCO Cr S7 OS Emergency Telephone Number Medical (708) 920-1510(24 hours) 9ECTTUIT MM Al'U IBrUWlATlUH T^Bwramn used to control symptoms and clinical conditicn. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INHALATION: May cause moderate irritation. Can cause severe irritation. Prolonged inhalation of vapor may be harmful. SYMPTCMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of product can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with product can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted cn this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Hazy airiber SPECIFIC GRAVITY: FLASH POINT: FCSM: Liquid ODOR: 0.95 60 Degrees F Minimum 120 Degrees F (FM0C) Hydrocarbon ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Minimum 120 Degrees F (LMOC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. PAGE 2 OF 8 SAL 000009311 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 10B mm unint onr t. 1 i 11-\ on t_ l_ i PRODUCT NALO 5537 EWUI5I(:!N BREAKER NALCO hours) (y 7 0 3Emergency Telephone Number Medical (708) 920-1510(24 SECTlO^^^PIR^S^BXPLOSIO^IOToIBBfffRr (COBHSBIBT UNUSUAL FIRE AND EXPLOSION HAZARD: Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. FEEDING EQUIPMENT: Do not use this product with rubber, Polyethylene, Neoprene, Buna N, Vinyl, PE, Ethylene propylene or Polyurethane. THERMAL DECOMPOSITION ER0DUCTS: In the event of combustion 00, 002 may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recconended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is reccranended. VEOTIIATION: General ventilation is reccmrended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols my be released. PROTECTIVE EQUHWENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is reocmmended if gross exposure is possible. The availability of an eye wash fountain and safety shcwer is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CAJL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: PAGE 3 OF 8 SAL 000009312 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1136 AREA 708-305-1 OOO MATERIAL SAFETY DATA SHEET NALCO 6S708 PRODUCT NALCO 5537 MJIICN BREAKER Emergency Telephone Number Medical (706) 920-1510 <24 hour*) SECTION 11 SPILL AND DISPOSAL INFORMATION 7"colilMJ!L 1 Small liquid spills: Contain with absorbent material, such as clay, soil or ary ccrrcnercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Ihose DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - OCMBUSTTBIE LIQUID, N.O.S. CXMBUSTIBIE LIQUID NA 1993 CONTAINS - ARCMA3TC HYCeDCARBONS, NAFHIHAIJENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGUIATIGNS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shewn belcw. PAGE 4 OF 8 SAL 000009313 ( NALCO CHEMICAL COMPANY ONE NALCO CENTER AREA 706-305-1 OOO NAPERVILLE. ILLINOIS 60563-1193 MATERIAL SAFETY DATA SHEET PRODUCT N*1'00 5537 EMULSION breaker NALCO Emergency Telephone Number Medical (708) 920-1510(24 hours) G S7 03 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Heavy aromatic naphtha - Combustible, skin irritant Naphthalene - Eye and skin irritant Ethylbenzene - Eye irritant Xylene - Eye irritant Naphthalene = TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mq/m3, 79 mg/m3 AOGHyTLV Ethylbenzene * TWA 100 ppm, STEL 125 ppm ACGIH/TLV 434 nq/n3, 543 mq/ra3 AOGIH/TLV Xylene = TWA 100 ppm, STEL 125 ppm AOGIH/TLV 434 mg/m3, 651 iog/m3 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m3, 75 irq/m3 OSHV^EL Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/FEL 435 mq/m3, 545 mgt/m3 OSHA/FEL Xylene ~ TWA 100 ppm, STEL 125 ppm OSHA/PEL 435 mq/irO, 655 mg/m3 ACGIH/TLV CERC1VSUEERFUND, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 2,900 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802) . SARA/SUFERRJND AMENDMENTS AND READTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the foilwing EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning cxmrriission, state emergency response commission and local PAGE 5 OF 8 o000093l> SAL NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 AREA 7O0-3O5-1OOO MATERIAL SAFETY DATA SHEET GS703 NALCO PRODUCT NAIx:) 5537 Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) fire department is required after October 17, 1987 if ycu have: - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. After October 17, 1989, MSDS(s), or a list of product names for all hazardous substances between zero (0) and 10,000 pounds, not previously reported, must be submitted. SECTION 313 - LIST OF TOXIC CHEMTCAIS (40 CFR 372) I This product contains the follcwing ingredient (s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Naphthalene Ethylbenzene Xylene 91-20-3 100-41-4 1330-20-7 1-5 10-20 5-10 TOXIC SUBSTANCES CQNIRDL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710) . RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPAKT C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): This product contains the following ingredients covered by the Clean Water Act: Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethylbenzene - Section 111 Xylene - Section 111 STATE REGULATIONS: CALIFORNIA REPOSITION 65: PAGE 6 OF 8 SAL 000009315 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 AREA 70H-3G5- 1 QOO MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5537 EMULSION BREAKER Emergency Telephone Number Medical (708) 920-1510(24 hours) 5 0 3ft o ry *1 o SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Substances known to the State of California to cause cancer may be present as an impurity or residue. MICHIGAN CRITICAL MATERIALS: This product contains the following substance (s) identified on the Michigan Critical Materials Register: Ethylbenzene, Xylene STATE RIGHT TO KNOW IAWS: Regulated in those states using the TLV for naphthalene, ethylbenzene, and xylene as a criteria for listing. INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Cannons of Canada Bill C-70. The product contains the following substance(s), firm the Ingredient Disclosure List or has been evaluated based cn its toxicological properties, to contain the following hazardous ingredient (s): Chemical Name CAS # % Concentration Range Heavy aromatic naphtha Naphthalene Ethylbenzene Xylene 68603-08-7 91-20-3 100-41-4 1330-20-7 70-100 1-5 10-20 5-10 SECTION 15 ADDITIONAL INFORMATION F 302657 SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. PAGE 7 OF 8 SAL 000009316 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 130 AREA 708-305-1 OOO MATERIAL SAFETY DATA SHEET NALCO GS703 PRODUCT NAHX) 5537 EMOISICN BREAKER Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., KLaassen, C. D., and Admur, M. 0., eds., Maanillian Publishing Ocnpany, Inc. N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Cenpany, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Ccnpany, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., Jchn Wiley and Sots, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist CATE CHANGED: 09/27/89 DATE PRINTED: 07/05/90 PAGE 8 OF 8 SAL 000009317 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198