Document mpRYDw4D5vxgEr97ja4j2mv8Q

CMA Interoffice Memo November 17,1995 . To: CHEMSTAR Panel Managers From: Mike Heimowitz, Distribution Division, xl360 Subject: North American Emergency Response Guidebook For more than a decade, the United States Department of Transportation and Transport Canada have separately published and distributed Emergency Response Guidebooks to millions of people in the public response community and industry. These books cover hundreds of chemicals and chemical classes and provide basic information on what to do initially at the scene of an incident. Next year, in the spirit of NAFTA, the U.S., Canada and Mexico will publish a North American Emergency Response Guidebook which will supercede all previous editions and be used in all three countries. That's the good news. The bad news is that the deadline for publication is approaching and the government just released a semi-complete draft of the book. We must provide comments by the first week of December. Previous editions of these books have been full of errors. Adding to the complexity this year is the fact that the U.S. and Canada have rewritten virtually every Guide Page. I am enclosing the Guide Pages for the chemicals which your panels cover. The Guide pages are numbered from 111 to 170. If there is no listing for your panel name, please look in the index for all chemicals your panel covers. Here is an index by panel: PANEL NAME GUIDE# Hexamethylene Diisocyanate 156 Hydrazine, UN (several listings, depending on composition) 132,152,153 Hydrocarbon Solvents (several listings) 115,128 Hydroquione 153 HF 125 Inorganic Acid Mists (Acid, Liquid, n.o.s.?) 154 CMA 111329 % Isopropanol Ketones Maleic Anhydride Metal Catalyst Methyl Bromide (several listings) Napthalene Olefins (no listing under this name) a-Olefins (no listing under this name) Olexylamine (no listing under this name) Oxo Process (no listing) Petroleum additives (need more specific names) Phenol Phosgene Phosphorous (several listings) Phtalate Esters (esters, n.o.s. listed) PCB's Propylene Glycol Ethers (no listing) Propylene Oxide Rubber Additives (no listing) Sodium Bromide (no listing) Specialty Acrylates/Methacrylates (no listing) Terphtalates (no listing) Titanium Oxide (no listing with "oxide") Toluenediamines Tris(chloroalkyl)phosphates (no listing) Vinyl Chloride 129 127 153 170 (dry), 133 (wetted) 123,151 133 153 125 154, 133,136,139,137,125 127 171 127 151 116 CMA 111330 Vinilidene Chloride (no listing) Water additives (no listing) If you have any questions or comments, please call me at X 1360. CMA 111331 NAME OF MATERIAI C t fc> i>f r ^ GUIDE# ID# t-r~ Accumulators, pressurized, pneumatic or hydraulic Acetal Acetaldehyde Acetaldehyde ammonia Acetaldehyde oxime Acetic acid, glacial Acetic acid, solution, more than 10% but not more than 80% acid Acetic acid, solution, more than 80% acid . Acetic anhydride Acetone Acetone cyanohydrin, stabilized ~ Acetone oils Acetonitrile Acetyl acetone peroxide Acetyl benzoyl peroxide Acetyl bromide Acetyl chloride Acetyl cyciohexanesulfonyl peroxide Acetyl cyciohexanesulfonyl peroxide Acetyl cyclohexanesulphonyl peroxide Acetyl cyclohexanesulphonyl peroxide Acetylene Acetylene, dissolved Acetylene, Ethylene and Propylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with not more than 22.5% Acetylene and not more than 6% Propylene. Acetylene tetrabromide Acetyl iodide Acetyl methyl carbinol Acetyl peroxide Acid, liquid, n.o.s. Acid, sludge Acid butyl phosphate Acridine Acrolein, inhibited Acrolein dimer, stabilized Acrylamide Acrylic acid, inhibited Acrylonitrile, inhibited Adhesives (flammable) Adipic acid Adiponitrile Aerosols Air, compressed Air, refrigerated liquid (cryogenic liquid) Air, refrigerated liquid (cryogenic liquid), non-pressurized Air bag inflators Air bag inflators Air bag modules Air bag modules Aircraft evacuation slides Aircraft hydraulic power unit fuel tank Aircraft survival kits Alcoholates solution, n.o.s., in alcohol Alcoholic beverages Alcohols, n.o.s. 126 1956 127 1088 129 1089 171 1841 129 2332 132 2789 153 2790 132 2789 137 1715 127 1090 155 1541 127 1091 131 1648 145 2080 147 2081 156 1716 132 1717 148 2082 148 2083 148 2082 148 2083 116 1001 116 1001 116 159 156 127 148 154 153 153 153 131P 129P 153P 132P 131P 127 153 153 126 122 122 122 133 171 133 171 171 131 171 127 127 127 3138 2504 1898 2621 2084 1760 1906 1718 2713 1092 2607 2074 2218 1093 1133 9077 2205 1950 1002 1003 1003 1325 3268 1325 3268 2990 3165 3072 3274 3065 1987 07/11/95 12:31 Pagel CMA 111332 NAME OF MATERIAL GUIDE# ID* Alcohols, flammable, poisonous, n.o.$. Alcohols, flammable, toxic, n.o.s. Alcohols, poisonous, n.o.$. Alcohols, toxic, n.o.s. Aldehydes, flammable, poisonous, n.o.s. Aldehydes, flammable, toxic, n.o.s. Aldehydes, n.o.s. Aldehydes, poisonous, n.o.s. Aldehydes, toxic, n.o.s. Aldol Aldrin, liquid Aldrin, solid Aldrin mixture, dry Aldrin mixture, liquid Alkali metal alcoholates, self-heating, corrosive, n.o.s. Alkali metal alloy, liquid, n.o.s. Alkali metal amalgam Alkali metal amides Alkali metal dispersion Alkaline earth metal alcoholates, n.o.s. Alkaline earth metal alloy, n.o.s. Alkaline earth metal amalgam Alkaline earth metal dispersion Alkaline liquid, n.o.s. Alkaloids, liquid, n.o.s. (poisonous) Alkaloids, solid, n.o.s. (poisonous) Alkaloid salts, liquid, n.o.s. (poisonous) Alkaloid salts, solid, n.o.$. (poisonous) Alkylamines, n.o.s. Alkylamines, n.o.s. Alkylamines, n.o.s. Alkyl phenols, liquid, n.o.s. (including C2-C12 homologues) Alkyl phenols, solid, n.o.s. (including C2-C12 homologues) Alkyl sulfonic acids, liquid, with more than 5% free Sulfuric acid Alkyl sulfonic acids, liquid, with not more than 5% free Sulfuric acid Alkyl sulfonic acids, solid, with more than 5% free Sulfuric acid Alkyl sulfonic acids, solid, with not more than 5% free Sulfuric acid Alkylsulfuric acids Alkyl sulphonic acids, liquid, with more than 5% free Sulphuric acid Alkyl sulphonic acids, liquid, with not more than 5% free Sulphuric acid Alkyl sulphonic acids, solid, with more than 5% free Sulphuric acid Alkyl sulphonic acids, solid, with not more than 5% free Sulphuric acid Alkylsulphuric acids Allethrin Ally! acetate Allyl alcohol Allylamine Allyl bromide Allyl chloride Allyl chlorocarbonate Allyl chloroformate Allyl ethyl ether Allyl formate Allyl glycidyl ether Allyl iodide Allyl isothiocyanate, inhibited 131 1986 131 1986 131 1986 131 1986 131 1988 131 1988 129 1989 131 1988 131 1988 153 2839 131 2762 151 2761 151 2761 131 2762 136 3206 138 1421 138 1389 139 1390 138 1391 135 3205 138 1393 138 1392 138 1391 154 1719 151 3140 151 1544 151 3140 151 1544 132 2733 132 2734 153 2735 153 3145 153 2430 153 2584 153 2586 153 2583 153 2585 156 2571 153 2584 153 2586 153 2583 153 2585 156 2571 151 2902 131 2333 131 1098 131 2334 131 1099 131 1100 155 1722 155 1722 131 2335 131 2336 129 2219 132 1723 155 1545 07/11/95 12:31 Page2 CMA 111333 NAME OF MATERIAL Allyl isothiocyanate, stabilized Allyftrichlorosiiane, stabilized Aluminum, molten Aluminum alkyl halides Aluminum alkyl hydrides Aluminum alkyls Aluminum borohydride Aluminum borohydride in devices Aluminum bromide, anhydrous Aluminum bromide, solution Aluminum carbide Aluminum chloride, anhydrous Aluminum chloride, solution Aluminum dross Aluminum ferrosiiicon powder Aluminum hydride Aluminum nitrate Aluminum phosphate, solution Aluminum phosphide Aluminum phosphide pesticide Aluminum powder, coated Aluminum powder, uncoated Aluminum processing by-products Aluminum remetting by-products Aluminum resinate Aluminum silicon powder, uncoated Aluminum smelting by-products Aluminum sulfate, solid Aluminum sulfate, solution Aluminum sulphate, solid Aluminum sulphate, solution Amines, flammable, corrosive, n.o.s. Amines, liquid, corrosive, flammable, n.o.s. Amines, liquid, corrosive, n.o.s. Amines, solid, corrosive, n.o.s. 2-Amino-4-chlorophenol 2-Amino-5-diethylaminopentane 2-amino-4,6-dinitrophenol, wetted with not less than 20% water 2-(2-Aminoethoxy)ethanol 2-(2-Aminoethoxy)ethanol N-Aminoethylpiperazine Aminophenols Aminopropyldiethanolamine N-Aminopropylmorpholine Aminopyridines Ammonia, anhydrous Ammonia, anhydrous, liquefied Ammonia, solution, with more than 10% but not more than 35% Ammonia Ammonia, solution, with more than 35% but not more than 50% Ammonia Ammonia, solution, with more than 50% Ammonia Ammonia solution, with more than 50% Ammonia Ammonium acetate Ammonium arsenate Ammonium benzoate 07/11/95 12:31 GUIDE# IP# 155 155 169 135 138 135 135 135 137 154 138 137 154 138 139 138 140 154 139 157 170 138 138 138 133 138 138 171 154 171 154 132 132 153 154 151 153 113 153 153 153 152 153 153 153 125 125 1545 1724 9260 3052 3076 3051 2870 2870 1725 2580 1394 1726 2581 3170 1395 2463 1438 1760 1397 3048 1309 1396 3170 3170 2715 1398 3170 9078 1760 9078 1760 2733 2734 2735 3259 2673 2946 3317 1760 3055 2815 2512 1760 1760 2671 1005 1005 154 2672 125 2073 125 1005 125 3318 171 9079 151 1546 171 9080 Page3 CMA 111334 NAME OF MATERIA! Ammonium bicarbonate Ammonium bifluoride, solid Ammonium bifluoride, solution Ammonium bisulfite, solid Ammonium bisulfite, solution Ammonium bisulphite, solid Ammonium bisulphite, solution Ammonium carbamate Ammonium carbonate Ammonium chloride Ammonium chromate ~ Ammonium citrate, dibasic , Ammonium dichromate Ammonium dinitro*o-cresolste Ammonium fluoborate Ammonium fluoride Ammonium fluorosilicate Ammonium hydrogendifluoride, solid Ammonium hydrogendifluoride, solution Ammonium hydrogen fluoride, solid Ammonium hydrogen fluoride, solution Ammonium hydrogen sulfate Ammonium hydrogen sulphate Ammonium hydrosulfide, solution Ammonium hydrosulphide, solution Ammonium hydroxide Ammonium hydroxide, with more than 10% but not more than 35% Ammonia Ammonium metavanadate Ammonium nitrate, liquid (hot concentrated solution) Ammonium nitrate, with not more than 0.2% combustible substances Ammonium nitrate, with organic coating Ammonium nitrate fertilizer, n.o.s. Ammonium nitrate fertilizer, with not more than 0.4% combustible material Ammonium nitrate fertilizers Ammonium nitrate fertilizers Ammonium nitrate fertilizers Ammonium nitrate fertilizers, with Ammonium sulfate Ammonium nitrate fertilizers, with Ammonium sulphate Ammonium nitrate fertilizers, with Calcium carbonate Ammonium nitrate fertilizers, with Phosphate or Potash Ammonium nitratefuel oil mixtures Ammonium nitrate mixed fertilizers Ammonium oxalate Ammonium perchlorate Ammonium permanganate Ammonium persulfate Ammonium persulphate Ammonium picrate, wetted with not less than 10% water Ammonium polysulfide, solution Ammonium polysulphide, solution Ammonium polyvanadate Ammonium silicofluoride, solid Ammonium sutfamate Ammonium sulfate nitrate 07/11/95 12:31 GUIDE# IP# 171 154 154 154 154 154 154 154 154 171 143 171 141 141 154 154 151 154 154 154 154 154 154 132 132 154 154 154 140 140 140 140 140 140 140 140 140 140 140 143 112 140 154 143 143 140 140 113 154 154 151 151 171 140 9081 1727 2817 2693 2693 2693 2693 9083 9084 9085 9086 9087 1439 1843 9088 2505 2854 1727 2817 1727 2817 2506 2506 2683 2683 2672 2672 2859 2426 1942 1942 2072 2071 2067 2071 2072 2069 2069 2068 2070 2069 2449 1442 9190 1444 1444 1310 2818 2818 2861 2854 9089 1477 Page4 CMA 111335 NAME OF MATERIAL Ammonium sulfide, solution Ammonium sulfite Ammonium sulphamate Ammonium sulphate nitrate Ammonium sulphide, solution Ammonium sulphite Ammonium tartrate Ammunition, poisonous, non-explosive Ammunition, tear-producing, non-explosive Ammunition, toxic, non-explosive Amyl .acetates Amyl add phosphate Amyl alcohols Amylamines Amyl butyrates Amyl chloride n-Amylene Amyl formates Amyl mercaptan Amyl methyl ketone n-Amyl methyl ketone Amyl nitrate Amyl nitrite tert-Amyl peroxy-2-ethylhexanoate tert-Amyl peroxyneodecanoate Amyttrichlorosilane Anhydrous ammonia Anhydrous ammonia, liquefied Aniline Aniline hydrochloride Anisidines Anisidines, liquid Anisidines, solid Anisole Anisoyl chloride Antimony compound, inorganic, liquid, n.o.s. Antimony compound, inorganic, n.o.s. Antimony compound, inorganic, solid, n.o.s. Antimony lactate Antimony pentachloride, liquid Antimony pentachloride, solution Antimony pentafluoride Antimony potassium tartrate Antimony powder Antimony sulfide, solid Antimony sulphide, solid Antimony tribromide, solid Antimony tribromide, solution Antimony trichloride Antimony trichloride, liquid Antimony trichloride, solid Antimony trichloride, solution Antimony trifluoride, solid Antimony trifluoride, solution Antimony trioxide Aqua regia 07/11/95 12:31 GUIDE* ID* 132 2683 171 9090 171 9089 140 1477 132 2683 171 9090 171 9091 151 2016 159 2017 151 2016 "* 129 1104 153 2819 129 1105 132 1106 130 2620 129 1107 127 1108 129 1109 130 1111 127 1110 127 1110 140 1112 129 1113 148 2898 148 2891 155 1728 125 1005 125 1005 153 1547 153 1548 153 2431 153 2431 153 2431 127 9979 156 1729 157 3141 157 1549 157 1549 151 1550 157 1730 157 1731 157 1732 151 1551 170 2871 133 1325 133 1325 157 1549 157 1549 157 1733 157 1733 157 1733 157 1733 157 1549 157 1549 171 9201 157 1798 F CMA 111336 NAME OF MATERIAL Argon Argon, compressed Argon, refrigerated liquid (cryogenic liquid) Arsenic Arsenic acid, liquid Arsenic acid, solid Arsenical dust Arsenical pesticide, liquid, flammable, poisonous Arsenical pesticide, liquid, flammable, toxic Arsenical pesticide, liquid, poisonous Arsenical pesticide, liquid, poisonous, flammable ~ Arsenical pesticide, liquid, toxic Arsenical pesticide, liquid, toxic, flammable Arsenical pesticide, solid, poisonous Arsenical pesticide, solid, toxic Arsenic bromide Arsenic chloride Arsenic compound, liquid, n.o.s. Arsenic compound, liquid, n.o.s,, inorganic Arsenic compound, solid, n.o.s. Arsenic compound, solid, n.o.s., inorganic Arsenic iodide, solid Arsenic pentoxide Arsenic sulfide Arsenic sulphide Arsenic trichloride Arsenic trioxide Arsenic trisulfide Arsenic trisulphide Arsine Articles containing Polychlorinated biphenyls (PCB) Articles, pressurized hydraulic (containing non-flammable gas) Articles, pressurized pneumatic (containing non-flammable gas) Aryl sulfonic acids, liquid, with more than 5% free Sulfuric add Aryl sulfonic adds, liquid, with not more than 5% free Sulfuric add Aryl sulfonic adds, solid, with more than 5% free Sulfuric add Aryl sulfonic adds, solid, with not more than 5% free Sulfuric add Aryl sulphonic adds, liquid, with more than 5% free Sulphuric add Aryl sulphonic adds, liquid, with not more than 5% free Sulphuric add Aryl sulphonic adds, solid, with more than 5% free Sulphuric add Aryl sulphonic adds, solid, with not more than 5% free Sulphuric add Asbestos Asbestos, blue Asbestos, brown Asbestos, white Asphalt Azinphos methyl 1-Aziridinyl phosphine oxide (Tris) Azodicarbonamide 2,2'-Azodi-f2,4-dimethyl-4-methoxyvaleronitrile) 2,2'-Azodi-(2,4-dimethylvaleronitrile) 1,1 '-Azodi-(hexahydrobenzonitrile) Azodiisobutyronitrile 2,2'-Azodt-(2-methylbutyronrtrile) Barium Barium alloys, pyrophoric GUIDE# n> 121 1006 121 1006 120 1951 152 1558 154 1553 154 1554 152 1562 131 2760 131 2760 151 2994 131 2993 151 2994 131 2993 151 2759 151 2759 151 1555 157 1560 152 1556 152 1556 152 1557 152 1557 152 1557 151 1559 152 1557 152 1557 157 1560 151 1561 152 1557 152 1557 110 2188 171 2315 126 3164 126 3164 153 2584 153 2586 153 2583 153 2585 153 2584 153 2586 153 2583 153 2585 171 2212 171 2212 171 2212 171 2590 130 1999 152 2783 152 2501 149 3242 150 2955 150 2953 149 2954 150 2952 150 3030 138 1400 135 1854 07/11/95 12:31 Page6 CMA 111337 NAME OF MATERIAL Barium azide, wetted with not less than 50% water Barium bromate Barium chlorate Barium chlorate, wet Barium compound, n.o.s. Barium cyanide Barium hypochlorite, with more than 22% available Chlorine Barium nitrate Barium oxide Barium perchlorate Barium permanganate ~ Barium peroxide Barium selenate Barium selenite Batteries, containing Sodium Batteries, dry, containing Potassium hydroxide, solid Batteries, wet, filled with acid Batteries, wet, filled with alkali Batteries, wet, non-spillable Battery Battery Battery Battery fluid, acid Battery fluid, acid, with battery Battery fluid, acid, with electronic equipment or actuating device Battery fluid, alkali Battery fluid, alkali, with battery Battery fluid, alkali, with electronic equipment or actuating device Battery-powered equipment (wet battery) Battery-powered vehicle (wet battery) Benzaldehyde Benzaldehyde Benzene Benzene-1,3-disulfohydrazide Benzene-1,3-disulphohydrazide Benzene phosphorus dichloride Benzene phosphorus thiodichloride Benzene sulfohydrazide Benzenesulfonyl chloride Benzene sulphohydrazide Benzenesuiphonyl chloride Benzidine Benzoic acid Benzoic derivative pesticide, liquid, flammable, poisonous Benzoic derivative pesticide, liquid, flammable, toxic Benzoic derivative pesticide, liquid, poisonous Benzoic derivative pesticide, liquid, poisonous Benzoic derivative pesticide, liquid, toxic Benzoic derivative pesticide, liquid, toxic, flammable Benzoic derivative pesticide, solid, poisonous Benzoic derivative pesticide, solid, toxic Benzonitrile Benzoquinone Benzotrichloride Benzotrifluoride Benzoyl chloride 07/11/95 12:31 GUIDE* IP# 113 141 141 141 154 157 141 141 157 141 141 141 151 151 138 154 154 154 154 154 154 154 157 157 157 154 154 154 154 154 129 129 130 149 149 137 137 149 156 149 156 153 153 131 131 151 131 151 131 151 151 152 153 156 131 137 1571 2719 1445 1445 1564 1565 2741 1446 1884 1447 1448 1449 2630 2630 3292 3028 2794 2795 2800 1813 2794 2795 2796 2796 2796 2797 2797 2797 3171 3171 1989 1990 1114 2971 2971 2798 2799 2970 2225 2970 2225 1885 9094 2770 2770 3004 3003 3004 3003 2769 2769 2224 2587 2226 2338 1736 Page? CMA 111338 NAME OF MATERIAL Benzoyl peroxide Benzoyl peroxide Benzoyl peroxide Benzoyl peroxide Benzoyl peroxide Benzyl bromide Benzyl chloride Benzyl chloroformate Benzyl dimethytamine 4-[Benzyl(ethyl)amino}-3-ethoxybenzenediazonium zinc chloride Benzyiidene chloride ~ Benzyl iodide 4-{Benzyl(methyl)amino}-3-ethoxybenzenediazonium zinc chloride Beryllium, powder Beryllium chloride Beryllium compound, n.o.s. Beryllium fluoride Beryllium nitrate Bhusa, wet, damp or contaminated with oil Bicydo[2.2.1 Jhepta-2,5-diene Bicydo[2.2.ljhepta-2,5-<liene, inhibited Bifluorides, n.o.s. (Bio)Medical waste, n.o.s. Bipyridilium pesticide, liquid, flammable, poisonous Bipyridilium pesticide, liquid, flammable, toxic Bipyridilium pesticide, liquid, poisonous Bipyridilium pesticide, liquid, poisonous, flammable Bipyridilium pesticide, liquid, toxic Bipyridilium pesticide, liquid, toxic, flammable Bipyridilium pesticide, solid, poisonous Bipyridilium pesticide, solid, toxic Bisulfates, aqueous solution Bisulfites, aqueous solution, n.o.s. Bisulfites, inorganic, aqueous solutions, n.o.s. Bisulphates, aqueous solution Bisulphites, aqueous solution, n.o.s. Bisulphites, inorganic, aqueous solutions, n.o.s. Blasting agent, n.o.s. Bleaching powder Blue asbestos Bombs, smoke, non-explosive, with corrosive liquid, without initiating device Borate and Chlorate mixtures Bomeol Boron tribromide Boron trichloride Boron trifluoride Boron trifluoride, compressed Boron trifluoride, dihydrate Boron trifluoride acetic acid complex Boron trifluoride diethyl etherate Boron trifluoride dimethyl etherate Boron trifluoride propionic acid complex Brake fluid, hydraulic Bromates, inorganic, aqueous solution, n.o.s. Bromates, inorganic, n.o.s. 07/11/95 12:31 GUIDE* IP* 146 2085 146 2087 146 2088 145 2089 146 2090 156 1737 156 1738 137 1739 132 2619 149 3037 156 1886 156 2653 150 3038 134 1567 154 1566 154 1566 154 1566 141 2464 133 1327 127 2251 127 2251 154 1740 158 3291 131 2782 131 2782 151 3016 131 3015 151 3016 131 3015 151 2781 151 2781 154 2837 154 2693 154 2693 154 2837 154 2693 154 2693 112 -- 140 2208 171 2212 153 2028 140 1456 133 1312 157 2692 125 1741 125 1008 125 1008 157 2851 155 1742 132 2604 139 2965 156 1743 130 1118 140 3213 141 1450 Pages CMA 111339 NAME OF MATERIAL Bromine Bromine, solution Bromine chloride Bromine pentafluoride Bromine trifluoride Bromoacetic acid Bromoacetic acid, solid Bromoacetic acid, solution Bromoacetone Bromoacetyl bromide Bromobenzene Bromobenzyl cyanides 1-Bromobutane 2-Bromobutane Bromochlorodifluoromethane Bromochloromethane 1 -Bromo-3-chloropropane 2-Bromoethyl ethyl ether Bromoform 1 -Bromo-3-methylbutane Bromomethylpropanes 2-Bromo-2-nitropropane-1,3-diol 2-Bromopentane 2'Bromopropane Bromopropanes 3-Bromopropyne Bromotrifluoroethylene Bromotrifiuoromethane Brown asbestos Brucine Burnt cotton, not picked Butadienes, inhibited Butane Butane Butanedione Butane mixture Butane mixture Butanols Butoxyl Butyl acetates Butyl acid phosphate Butyl acrylate Butyl acrylates, inhibited Butyl alcohol n-Butylamine N-Butylaniline Butylbenzenes n-Butyl bromide Butyl chloride n-Butyl chloroformate sec-Butyl chloroformate tert-Butyl cumene peroxide tert-Butyl cumyl peroxide tert-Butylcyclohexyl chloroformate n-ButyM ,4-di-(tert-butylperoxy)valerate n*Butyl-4,4-di-(tert*butylperoxy)valerate 07/11/95 12:31 GUIDE* ID# 154 154 124 144 144 156 156 156 131 156 129 159 129 130 126 160 159 130 159 130 130 153 130 132 132 132 116 126 171 152 133 116P 115 115 127 115 115 129 127 129 153 129P 129P 129 132 153 128 129 130 155 155 145 145 156 146 145 1744 1744 2901 1745 1746 1938 1938 1938 1569 2513 2514 1694 1126 2339 1974 1887 2688 2340 2515 2341 2342 3241 2343 2344 .2344 2345 2419 1009 2212 1570 1325 1010 1011 1075 2346 1011 1075 1120 2708 1123 1718 2348 2348 1120 1125 2738 2709 1126 1127 2743 2742 2091 2091 2747 2140 2141 Pj CMA111340 NAME OF MATERIAL GUIDE* IP* Butylene Butylene 1,2-Butylene oxide, stabilized Butyl ethers n-Butyl formate tert-Butyl hydroperoxide tert-Butyl hydroperoxide tert-Butyl hydroperoxide, not more than 80% in DMert-Butyl peroxide and/or solvent tert-Butyl hypochlorite N,n-Butyl imidazole ^ n-Butyl isocyanate tert-Butyl isocyanate tert-Butyl isopropyl benzene hydroperoxide Butyl mercaptan n-Butyl methacrylate n-Butyl methacrylate, inhibited Butyl methyl ether tert-Butyl monoperoxymaleate Butyl nitrites tert-Butyl peroxyacetate tert-Butyl peroxyacetate tert-Butyl peroxybenzoate tert-Butyl peroxybenzoate tert-Butyl peroxybenzoate tert-Butyl peroxycrotonate Butyl peroxydicarbonate Butyl peroxydicarbonate tert-Butyl peroxydiethylacetate tert-Butyl peroxydiethylacetate, with tert-Butyl peroxybenzoate tert-Butyl peroxy-2-ethylhexanoate tert-Butyl peroxy-2-ethyihexanoate, not more than 50%, with phlegmatizer tert-Butyl peroxy-2-ethylhexanoate, with 2,2-Di-(tert-butylperoxy)butane tert-Butyl peroxy-2-ethylhexanoate, with 2,2-Oi-(tert-butylperoxy)butane tert-Butyl peroxyisobutyrate tert-Butyl peroxyisobutyrate tert-Butyl peroxyisononanoate tert-Butyl peroxyisopropyl carbonate tert-Butyl peroxyneodecanoate tert-Butyl peroxyneodecanoate tert-Butyl peroxy-3-phenylphthalide tert-Butyl peroxypivalate tert-Butyl peroxy-3,5,5-trimethylhexanoate Butylphenols, liquid Butylphenols, solid n-Butyl phthalate Butyl propionates Butyltoluenes Butyltrichiorosilane 5-tert-Butyl*2,4,6-trinitro-m-xylene Butyl vinyl ether, inhibited 1,4-Butynediol Butyraldehyde Butyraldoxime Butyric acid 115 115 127P 127 129 147 147 1012 1075 3022 1149 1128 2093 2094 147 135 152 155 155 145 130 12BP 129P 127 146 129 146 146 146 145 145 145 148 148 148* 145 148 2092 3255 2690 2485 2484 2091 2347 2227 2227 2350 2099 2351 2095 2096 2097 2098 2890 2183 2169 2170 2144 2551 2143 148 148 145 148 148 145 146 148 148 145 148 145 153 153 171 130 131 155 149 127P 153 129 129 153 2888 2886 2887 2142 2562 2104 2103 2177 2594 2596 2110 2104 2228 2229 9095 1914 2667 1747 2956 2352 2716 1129 2840 2820 07/11/95 12:31 PagelO CMA 111341 NAME OF MATERIAL GUIDEf IP* Butyric anhydride Butyronitrile Butyryl chloride Cacodylic add Cadmium compound Caesium Caesium hydroxide Caesium hydroxide, solution Caesium nitrate Caldum Calcium, metal and alloys, pyrophoric ~ Caldum, pyrophoric Caldum alloys, pyrophoric Caldum arsenate Caldum arsenate and Caldum arsenite mixture, solid Caldum arsenite, solid Caldum arsenite and Caldum arsenate mixture, solid Caldum carbide Caldum chlorate Caldum chlorate, aqueous solution Caldum chlorate, solution Caldum chlorite Caldum chromate Caldum cyanamide, with more than 0.1% Caldum carbide Caldum cyanide Caldum dithionite Caldum dodecylbenzenesulfonate Caldum dodecyibenzenesulphonate Caldum hydride Caldum hydrogen sulfite, solution Caldum hydrogen sulphite, solution Caldum hydrosulfite Caldum hydrosulphite Caldum hypochlorite, dry Caldum hypochlorite, hydrated mixture, with not less than 5.5% but not more than 10% water Caldum hypochlorite, hydrated with not less than 5.5% but not more than 10% water Caldum hypochlorite mixture, dry, with more than 10% but not more than 39% available Chlorine Caldum hypochlorite mixture, dry, with more than 39% available Chlorine (8.8% available Oxygen) Caldum manganese silicon Caldum metal, crystalline Calcium nitrate Caldum oxide Calcium perchlorate Calcium permanganate Caldum peroxide Caldum phosphide Calcium resinate Caldum resinate, fused Caldum selenate Calcium siiidde Caldum silicon Camphene 156 2739 131 2411 132 2353 151 1572 154 2570 138 1407 157 2682 154 2681 140 1451 138 1401 135 1855 135 1855 135 1855 151 1573 151 1574 151 1574 151 1574 138 1402 140 1452 140 2429 140 2429 140 1453 171 9096 138 1403 157 1575 135 1923 171 9097 171 9097 138 1404 154 2693 154 2693 135 1923 135 1923 140 1748 140 2880 140 2880 140 2208 140 1748 138 2844 138 1401 140 1454 157 1910 140 1455 140 1456 140 1457 139 1360 133 1313 133 1314 151 2630 138 1405 138 1406 133 9011 07/11/95 12:31 Pagell CMA 111342 NAME OF MATERIAL GUTOE* m# Camphor Camphor, synthetic Camphor oil Caproic acid Capryiyl peroxide Caprylyl peroxide, solution Carbamate pesticide, liquid, flammable, poisonous Carbamate pesticide, liquid, flammable, toxic Carbamate pesticide, liquid, poisonous Carbamate pesticide, liquid, poisonous, flammable Carbamate pesticide, liquid, toxic 4 Carbamate pesticide, liquid, toxic, flammable Carbamate pesticide, solid, poisonous Carbamate pesticide, solid, toxic Carbaryl Carbofuran Carbon, activated Carbon, animal or vegetable origin Carbon bisulfide Carbon bisulphide Carbon dioxide Carbon dioxide, compressed Carbon dioxide, refrigerated liquid Carbon dioxide, solid Carbon dioxide and Ethylene oxide mixture, with more than 9% but not more than 87% Ethylene oxide Carbon dioxide and Ethylene oxide mixture, with more than 87% Ethylene oxide Carbon dioxide and Ethylene oxide mixtures, with more than 8% Ethylene oxide Carbon dioxide and Ethylene oxide mixtures, with not more than 6% Ethylene oxide Carbon dioxide and Ethylene oxide mixtures, with not more than 9% Ethylene oxide Carbon dioxide and Nitrous oxide mixture Carbon dioxide and Oxygen mixture Carbon dioxide and Oxygen mixture, compressed Carbon disulfide Carbon disulphide Carbon monoxide Carbon monoxide, compressed Carbon monoxide and Hydrogen mixture Carbon monoxide and Hydrogen mixture, compressed Carbon monoxide, refrigerated liquid (cryogenic liquid) Carbon tetrabromide Carbon tetrachloride Carbonyl fluoride Carbonyl fluoride, compressed Carbonyl sulfide Carbonyl sulphide Castor beans, meal, pomace or flake Caustic alkali liquid, n.o.s. Caustic potash, dry, solid Caustic potash, liquid Caustic potash, solution Caustic soda, bead 133 2717 133 2717 128 1130 153 2829 148 2129 148 2129 131 2758 131 2758 151 2992 131 2991 151 2992 131 2991 151 2757 151 2757 151 2757 151 2757 133 1362 133 1361 131 1131 131 1131 120 1013 120 1013 120 2187 120 1845 115 1041 119 3300 115 1041 126 1952 126 1952 126 1015 122 1014 122 1014 131 1131 131 1131 119 1016 119 1016 119 2600 119 2600 168 9202 151 2516 151 1846 125 2417 125 2417 119 2204 119 2204 171 2969 154 1719 154 1813 154 1814 154 1814 154 1823 07/11/95 12:31 Pagel2 CMA 111343 NAME OF MATERIAL Caustic soda, flake Caustic soda, granular Caustic soda, solid Caustic soda, solution Cells, containing Sodium Celluloid, in blocks, rods, rolls, sheets, tubes, etc., except scrap Celluloid, scrap Cement (flammable) Cement, container, linoleum, tile orwallboard, liquid Cement, leather Cement, liquid, n.o.s. Cement, pyroxylin Cement, roofing, liquid Cement, rubber Cerium, slabs, ingots or rods Cerium, turnings or gritty powder Cesium Cesium hydroxide Cesium hydroxide, solution Cesium nitrate Charcoal Charcoal, briquettes Charcoal, shell Charcoal, wood, ground, crushed, granulated or pulverized Charcoal screenings, made from "Pinon" wood Charcoal screenings, other than "Pinon" wood screenings Chemical kit Chemical kit Chemical kits (containing corrosive substances) Chemical kits (containing flammable liquids) Chemical kits (containing flammable solids) Chemical kits (containing oxidizing substances) Chemical kits (containing poisonous liquids) Chemical kits (containing poisonous solids) Chemical kits (containing toxic liquids) Chemical kits (containing toxic solids) Chemical sample, poisonous liquid Chemical sample, poisonous solid Chemical sample, toxic liquid Chemical sample, toxic solid Chloral, anhydrous, inhibited Chlorate, n.o.s., wet Chlorate and Borate mixtures Chlorate and Magnesium chloride mixture Chlorates, inorganic, aqueous solution, n.o.s. Chlorates, inorganic, n.o.s. Chloric acid Chloric acid, aqueous solution, with not more than 10% Chloric acid Chlorine Chlorine dioxide, hydrate, frozen Chlorine pentafluoride Chlorine trifluoride Chlorite solution Chlorite solution, with more than 5% available Chlorine Chlorites, inorganic, n.o.s. Chloroacetaldehyde 07/11/95 12:31 GUIDE# IP# 154 154 154 154 138 133 135 127 127 127 127 127 127 127 170 138 138 157 154 140 133 133 133 133 133 133 153 171 154 128 133 140 153 154 153 154 151 151 151 151 153 140 140 140 140 140 140 140 124 143 124 124 154 154 143 153 1823 1823 1823 1824 3292 2000 2002 1133 1133 1133 1133 1133 1133 1133 1333 3078 1407 2682 2681 1451 1361 1361 1361 1361 1361 1361 1760 3316 -- -- -- ---- -- -- -- ......... 3315 3315 3315 3315 2075 1461 1458 1459 3210 1461 2626 2626 1017 9191 2548 1749 1908 1908 1462 2232 Pagel3 CMA 111344 NAME OF MATERIAL Chloroacetic acid, liquid Chloroacetic acid, molten Chloroacetic acid, solid Chloroacetic acid, solution Chloroacetone, stabilized Chloroacetonitrile Chloroacetophenone Chloroacetophenone, liquid Chloroacetophenone, solid Chloroacetyl chloride Chloroanilines, liquid Chloroaniiines, solid Chloroanisidines Chlorobenzene Chlorobenzotrifluorides p-Chlorobenzoyl peroxide p-Chlorobenzoyl peroxide p-Chlorobenzoyi peroxide Chlorobenzyl chlorides 1 Chloro-3-bromopropane Chiorobutanes Chlorocresols Chiorocresols, liquid Chlorocresols, solid 3-Chloro-4-diethy!aminobenzenediazonium zinc chloride Chlorodifluorobromomethane 1-Chloro-l ,1-difluoroethane Chlorodifluoroethanes Chlorodifiuoromethane Chiorodifluoromethane and Chlompentafluoroethane mixture Chiorodinitrobenzenes 2-Chloroethanal Chloroform Chloroformates, n.o.s. Chloroformates, poisonous, corrosive, flammable, n.o.s. Chloroformates, poisonous, corrosive, n.o.s. Chloroformates, toxic, corrosive, flammable, n.o.s. Chloroformates, toxic, corrosive, n.o.s. Chloromethyl chloroformate Chloromethyl ethyl ether 3-Chloro-4-methylphenyl isocyanate Chloronitroanilines Chloronitrobenzenes Chloronitrobenzenes, liquid Chloronitrobenzenes, solid Chloronitrotoluenes Chloronitrotoluenes, liquid Chloronitrotoluenes, solid Chloropentafluoroethane Chloropentafluoroethane and Chiorodifluoromethane mixture 3-Chloroperoxybenzoic acid Chiorophenates, liquid Chiorophenates, solid Chlorophenoiates, liquid Chlorophenolates, solid Chlorophenols, liquid 4 07/11/95 12:31 GUIDE* IP# 1S3 1750 153 3250 153 1751 153 1750 131 1695 131 2668 153 1697 153 1697 153 1697 156 1752 152 2019 152 2018 152 2233 130 1134 130 2234 146 2113 145 2114 145 2115 153 2235 15B 2688 130 1127 152 2669 152 2669 152 2669 149 3033 126 1974 115 2517 115 2517 126 1018 126 1973 153 1577 153 2232 151 1888 155 2742 155 2742 154 3277 155 2742 154 3277 157 2745 131 2354 156 2236 153 2237 152 1578 152 1578 152 1578 152 2433 152 2433 152 2433 126 1020 126 1973 146 2755 154 2904 154 2905 154 2904 154 2905 153 2021 Pagel4 CMA 111345 NAME OF MATERIAL GUIDE * ID* Chlorophenols, solid Chlorophenyltriehlorosilane Chloropicrin Chloropicrin, absorbed Chloropicrin and Methyl bromide mixture Chloropicrin and Methyl chloride mixture Chloropicrin and non-flammable, non-liquefied compressed pas mixture Chloropicrin mixture, flammable Chloropicrin mixture, n.o.s. Chloropivaloyl chloride Chloroplatinic acid, solid ~ Chloroprene, inhibited 2-Chloropropane 3-ChloropropanoM 2-Chloropropene 2-Chloropropionic acid alpha-Chloropropionic acid 2-Chloropyridine Chlorosilanes, corrosive, flammable, n.o.s. Chlorosilanes, corrosive, n.o.s. Chlorosilanes, flammable, corrosive, n.o.s. Chlorosilanes, n.o.$. Chlorosilanes, n.o.s. Chlorosilanes, n.o.s. Chlorosilanes, n.o.s. Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. Chlorosulfonic acid Chlorosulfonic acid and Sulfur trioxide mbdure Chlorosulphonic acid Chlorosulphonic acid and Sulphur trioxide mixture 1 -Chloro-1,2,2,2-tetrafluoroethane Chlorotetrafiuoroethane Chlorotetrafluoroethane and Ethylene oxide mixture, with not more than 8.8% Ethylene oxide Chlorotoluenes 4-Chloro-o-toluidine hydrochloride Chlorotoluidines Chlorotoluidines, liquid Chlorotoluidines, solid 1 -Chloro-2,2,2-trifluoroethane Chlorotrlfluoroethane Chlorotrifluoromethane Chlorotrifluoromethane and Trifluoromethane azeotropic mbeture with approximately 60% Chlorotrifluoromethane Chlorpyrifos Chromic acetate Chromic acid, solid Chromic acid, solution Chromic acid mixture, dry Chromic fluoride, solid Chromic fluoride, solution Chromic sulfate Chromic sulphate Chromium nitrate Chromium oxychloride Chromium trioxide, anhydrous 153 156 154 154 123 119 123 131 154 156 154 131P 129 153 130P 153 153 153 155 156 155 155 155 156 138 138 137 137 137 137 126 126 2020 1753 1580 1583 1581 1582 1955 2929 1583 9263 2507 1991 2356 2849 2456 2511 2511 2822 2986 2987 2985 2985 2986 2987 2988 2988 1754 1754 1754 1754 1021 1021 126 3297 130 2238 153 1579 153 2239 153 2239 153 2239 126 1983 126 1983 126 1022 126 2599 152 2783 171 9101 141 1463 154 1755 141 1463 154 1756 154 1757 171 9100 171 9100 141 2720 137 1758 141 1463 07/11/95 12:31 Pagel5 CMA 111346 NAME OF MATERIAL gyp>p ID* Chromosulfuric acid Chromosulphuric acid Chromous chloride Cigarette lighter, with flammable gas Cigarette lighter, with flammable liquid Cigarettes, self-lighting Clinical waste, unspecified, n.o.$. Coal gas Coal gas, compressed Coal tar distillate Coal tar distillates, flammable Coal tar dye, liquid Coating solution Cobalt naphthenates, powder Cobattous bromide Cobaltous formate Cobaltous sulfamate Cobaltous suiphamate Cobalt resinate, precipitated Cocculus Collodion Combustible liquid, n.o.s. Compound, cleaning liquid (containing hydrochloric (muriatic) add) Compound, deaning liquid (containing hydrofluoric add) Compound, rust preventing (corrosive) Compound, rust removing (corrosive) Compound, tree or weed killing, liquid (corrosive) Compound, tree or weed killing, liquid (flammable) Compound, tree or weed killing, liquid (toxic) Compound, tree or weed killing, solid (oxidizer) Compound, vulcanizing, liquid (flammable) Compound, vulcanizing, liquid (corrosive) Compounds, deaning, liquid (corrosive) Compounds, deaning, liquid (flammable) Compounds, polishing, liquid, etc. (flammable) Compressed gas, flammable, n.o.s. Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone C) Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) Compressed gas, n.o.s. Compressed gas, oxidizing, n.o.s. Compressed gas, poisonous, corrosive, n.o.s. Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) 154 2240 154 2240 171 9102 115 1057 127 1226 133 1867 158 3291 118 1023 119 1023 128 1137 128 1136 154 2801 127 1139 133 2001 171 0103 171 0104 171 0105 171 9105 133 1318 151 1584 127 2059 128 1993 157 1789 157 1790 153 1760 153 1760 153 1760 128 1993 153 2810 140 1479 127 1142 153 1760 153 1760 128 1993 127 1142 115 1954 119 1953 119 1953 119 1953 119 119 119 119 119 126 122 . 123 1953 1953 1953 1953 1953 1956 3156 3304 123 3304 123 3304 07/11/95 12:31 Pagel6 CMA 111347 NAME OF MATERIAL GUIDE* ID# Compressed gas, poisonous, corrosive, n.o.s. (inhalation Hazard Zone C) Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, poisonous, flammable, corrosive, n.o.s. Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) " Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, poisonous, flammable, n.o.s. Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) Compressed gas, poisonous, n.o.s. Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Compressed gas, poisonous, n.o.$. (Inhalation Hazard Zone D) Compressed gas, poisonous, oxidizing, corrosive, n.o.s. Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (inhalation Hazard Zone C) Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, poisonous, oxidizing, n.o.s. Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, corrosive, n.o.s. Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, flammable, corrosive, n.o.s. Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 123 3304 123 3304 119 3305 119 3305 119 3305 119 3305 119 3305 119 1953 119 1953 119 1953 119 1953 119 1953 123 1955 123 1955 123 1955 123 1955 123 1955 124 3306 124 3306 124 3306 124 3306 124 3306 124 3303 124 3303 124 3303 124 3303 124 3303 123 3304 123 3304 123 3304 123 3304 123 3304 119 3305 119 3305 119 3305 07/11/95 12:31 Pagel7 CMA 111348 NAME OF MATERIAL GUIDE# IP# Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, flammable, n.o.s. Compressed gas, toxic, flammable, n.o.s. (inhalation Hazard Zone A) Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, n.o.s. Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone A) ~ Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, n.o.s. (inhalation Hazard Zone D) Compressed gas, toxic, oxidizing, corrosive, n.o.s. Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, oxidizing, n.o.s. Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) Consumer commodity Copper acetoarsenite Copper arsenite Copper based pesticide, liquid, flammable, poisonous Copper based pesticide, liquid, flammable, toxic Copper based pesticide, liquid, poisonous Copper based pesticide, liquid, poisonous, flammable Copper based pesticide, liquid, toxic Copper based pesticide, liquid, toxic, flammable Copper based pesticide, solid, poisonous Copper based pesticide, solid, toxic Copper chlorate Copper chloride Copper cyanide Copra Corrosive liquid, acidic, inorganic, n.o.s. Corrosive liquid, acidic, organic, n.o.s. Corrosive liquid, basic, inorganic, n.o.s. Corrosive liquid, basic, organic, n.o.s. Corrosive liquid, flammable, n.o.s. Corrosive liquid, n.o.s. Corrosive liquid, oxidizing, n.o.s. Corrosive liquid, poisonous, n.o.s. Corrosive liquid, self-heating, n.o.s. Corrosive liquid, toxic, n.o.s. Corrosive liquid, water-reactive, n.o.s. Corrosive liquid, which in contact with water emits flammable gases, n.o.s. 119 119 119 119 119 119 119 123 123 123 123 123 124 124 124 124 124 124 124 124 124 124 171 151 151 131 131 151 131 151 131 151 151 141 154 151 135 154 153 154 153 132 154 140 154 136 154 138 138 3305 3305 1953 1953 1953 1953 1953 1955 1955 1955 1955 1955 3306 3306 3306 3306 3306 3303 3303 3303 3303 3303 6000 1585 1586 2776 2776 3010 3009 3010 3009 2775 2775 2721 2802 1587 1363 3264 3265 3266 3267 2920 1760 3093 2922 3301 2922 3094 3094 07/11/95 12:31 PagelS CMA 111349 NAME OF MATERIAL Corrosive solid, acidic, inorganic, n.o.s. Corrosive solid, acidic, organic, n.o.s. Corrosive solid, basic, inorganic, n.o.s. Corrosive solid, basic, organic, n.o.s. Corrosive solid, flammable, n.o.$. Corrosive solid, n.o.s. Corrosive solid, oxidizing, n.o.s. Corrosive solid, poisonous, n.o.s. Corrosive solid, self-heating, n.o.s. Corrosive solid, toxic, n.o.s. Corrosive solid, water-reactive, n.o.s. Corrosive solid, which in contact with water emits flammable gases, n.o.s. Cosmetics, liquid, n.o.s. Cosmetics, n.o.s. Cosmetics, n.o.s. Cosmetics, n.o.s. Cosmetics, solid, n.o.s. Cotton Cotton, wet Cotton waste, oily Coumaphos Coumarin derivative pesticide, liquid, flammable, poisonous Coumarin derivative pesticide, liquid, flammable, toxic Coumarin derivative pesticide, liquid, poisonous Coumarin derivative pesticide, liquid, poisonous, flammable Coumarin derivative pesticide, liquid, toxic Coumarin derivative pesticide, liquid, toxic, flammable Coumarin derivative pesticide, solid, poisonous Coumarin derivative pesticide, solid, toxic Cresols Cresylic acid Crotonaldehyde, inhibited Crotonaldehyde, stabilized Crotonic acid Crotonic acid, liquid Crotonic acid, solid Crotonyiene Cumene Cumene hydroperoxide Cupric acetate Cupric sulfate Cupric sulfate, ammoniated Cupric sulphate Cupric sulphate, ammoniated Cupric tartrate Cupriethylenediamine, solution Cyanide solution, n.o.s. Cyanides, inorganic, n.o.s. Cyanides, inorganic, solid, n.o.s. Cyanogen Cyanogen, liquefied Cyanogen bromide Cyanogen chloride, inhibited Cyanogen gas Cyanuric chloride 07/11/95 12:31 GUIDE# ID# 154 3260 154 3261 154 3262 154 3263 154 2921 154 1759 140 3084 154 2923 136 3095 154 2923 138 3096 138 153 133 140 128 154 133 133 133 152 131 131 151 131 151 131 151 151 153 153 131P 131P 153 153 153 128 131 147 171 171 171 171 171 171 154 157 157 157 119 119 157 125 119 157 3096 1760 1325 1479 1993 1759 1365 1365 1364 2783 3024 3024 3026 3025 3026 3025 3027 3027 2076 2022 1143 1143 2823 2823 2823 1144 1918 2116 9106 9109 9110 9109 9110 9111 1761 1935 1588 1588 1026 1026 1889 1589 1026 2670 page19 CMA111350 NAME OF MATERIAL Cyclobutane Cyclobutyl ehloroformate 1,5,9-Cyciododecatriene Cycloheptane Cycloheptatriene Cycloheptene Cyclohexane Cyclohexanone Cyclohexanone peroxide, not more than 72% as a paste Cyclohexanone peroxide, not more than 72% in solution Cyclohexanone peroxide, not more than 90%, with not less than 10% water Cyclohexene Cyciohexenyttrichlorosilane Cyclohexyl acetate Cyclohexylamine Cyclohexyl isocyanate Cyclohexyl mercaptan Cydohexyttrichlorosilane Cyclooctadiene phosphines Cyclooctadienes Cyciooctatetraene Cyclopentane Cyclopentanol Cyclopentanone Cyclopentene Cyclopropane Cyclopropane, liquefied Cymenes Dangerous goods in apparatus Dangerous goods in machinery DDT Decaborane Decahydronaphthalene n-Decane Decanoyl peroxide Denatured alcohol Denatured alcohol (toxic) Deuterium Deuterium, compressed Devices, small, hydrocarbon gas powered, with release device Diacetone alcohol Diacetone alcohol peroxides Diacetyl Diallylamine Diallyl ether 4,4'-Diaminodiphenylmethane Di-n-amylamine Diazinon 2-Diazol -naphthol<4-su!fochloride 2-Diazo-1 naphthol-4-sulphochloride 2-Diazo-1 -naphthol-5-sulfochloride 2-Diazo-1 -naphthol-5-sulphochloride Dibenzyldichlorosilane Dibenzyl peroxydicarbonate Diborane 07/11/95 12:31 GUIDE* IP# 115 2601 155 2744 153 2518 128 2241 131 2603 128 2242 128 1145 127 1915 147 2896 147 2118 .147 130 156 130 132 155 131 156 135 130P 128 128 129 127 128 115 115 130 171 171 151 134 130 128 148 127 131 115 115 115 129 148 127 132 131P 153 132 152 149 149 149 149 156 148 119 2119 2256 1762 2243 2357 2488 3054 1783 2940 2520 2358 1146 2244 2245 2246 1027 1027 2046 8001 8001 2761 1868 1147 2247 2120 1987 1986 1957 1957 3150 1148 2163 2346 2359 2360 2651 2841 2783 3042 3042 3043 3043 2434 2149 1911 Page20 CMA 111351 NAME OF MATERIAL GUIDE*1 IP# Diborane, compressed Diborane mixtures Dibromobenzene 1 ,2-Dibromobutan-3-one Dibromochloropropanes Dibromodifiuoromethane Dibromomethane Di-n-butylamine Dibutyiaminoethanol Di-(4-tert-butylcydohexyl)peroxydicarbonate Di-(4-tert-butylcydohexyl)peroxydicarbonate ~ Dibutyl ethers DMert-butyl peroxide 22-DI-(t*ri-butylperoxy)butane 1,1-Di-(tert-butylperoxy)cydohexane 1,1-Di-(tert-butytperoxy)cydohexane 1,1 -Di-(tert-butylperoxy)cydohexane 1,1 -Di-(tert-butylperoxy)cydohexane DMsec-butyl)peroxydicarbonate Di-(sec-butyl)peroxydicarbonate l,3-DH2-teri-butytperoxyisopropyl)benzene and 1,4-Di-(2-tertbutyiperoxyisopropyf)benzene mixtures i,4-Di-(2-tert-butyiperoxytsopropyl)benzene and 1,3-Di-(2-tert- butyiperoxyisopropyl)benzene mixtures DKtert-butylperoxy)phthalate Di-(tert-butylperoxy)phthalate Di-(tert-butylperoxy)phthalate 2,2-D(-(tert-butylperoxy)propane 2,2-DKtert-butytperoxy)propane 1,1-Di-(tert-butylperoxy)-3,3,5-trimethyl cydohexane 1 ,1-Di-(tert-butylperoxy)-3,3.5-trimethyl cydohexane 1 ,l-Di-(tert-butyiperoxy>-3,3,5-trimethyl cydohexane Dicetyl peroxydicarbonate Dicetyl peroxydicarbonate, not more than 42%, in water Dichloroacetic add 1,3-Dichloroacetone Dichloroacetyl chloride Dichloroanilines Dichioroaniiines, liquid Dichloroanilines, solid o-Dichlorobenzene p-Dichlorobenzene 2,4-Dichlorobenzoyl peroxide 2,4-Dichlorobenzoyl peroxide 2,4-Dichlorobenzoyl peroxide Dichlorobutene Dichlorobutene 2,2 -Dichlorodiethyl ether Dichlorodifluoroethylene Dichlorodifluoromethane Dichlorodifluoromethane and Difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane Dichlorodifluoromethane and Ethylene oxide mixture, with not more than 12.5% Ethylene oxide Dichlorodifluoromethane and Ethylene oxide mixtures, with not more than 12% Ethylene oxide 119 119 129 154 159 159 160 132 153 148 148 127 145 146 146 146 145 145 148 148 145 145 146 145 145 145 145 146 145 145 148 148 153 153 156 153 153 153 152 152 146 145 145 132 132 152 160 126 126 126 126 1911 1911 2711 2648 2872 1941 2664 2248 2873 2154 2894 1149 2102 2111 2179 2180 2885 2897 2150 2151 2112 2112 2106 2107 2108 2883 2884 2145 2146 2147 2164 2895 1764 2649 1765 1590 1590 1590 1591 1592 2137 2138 2139 2920 2924 1916 9018 1028 2602 3070 3070 07/11/95 12:31 Page21 CMA 111352 NAME OF MATERIAL Dichlorodimethyl ether, symmetrical Dichlorodiphenyttrichloroethane (DDT) 1,1-Dichloroethane 1,2-Dichloroethylene Dichloroethylene Dichloroethyl ether 1,1*Dichloro*1-fluoroethane Dichlorofluoromethane Dichloroisocyanuric acid, dry Dichloroisocyanuric acid salts Dichloroisopropyl ether Dichloromethane 1,1-Dichtoro-l-nitroethane Dichloropentanes 2,4-Dichlorophenoxyacetic acid Dichlorophenyl isocyanates Dichiorophenyftrichlorosilane Dichloropropane 1,2-Dichloropropane 1,3-DiChloropropanol-2 Dichloropropenes 2,2-Dichloroprupionic acid Dichtorosilane 1,2-Dichloro*1,1 ,2,2-tetrafluoroethane Dichlorotetrafluoroethane 3,5-Dichloro-2,4,6-trifluoropyridine Dichlorvos Dicumyl peroxide Dicycioheptadiene Dicyciohexylamine Dicyclohexylammonium nitrite Dicyclohexyl peroxydicartxmate Dicyclohexyl peroxydicartxmate Dicyciopentadiene 2.2-Di-(4,4-di-tert-butylperoxycyclohexyl)propane 1,2-DKdimethyiamino)ethane Didymium nitrate Dieldrin Diesel fuel Diesel fuel Diethoxymethane 2,5-Diethoxy-4-morpholinobenzenediazonium zinc chloride 3,3-Diethoxypropene Diethylamine 2-Diethylaminoethanol Diethylaminoethanol 3-Diethylaminopropylamine Diethylaminopropylamine N,N-Diethylaniiine Diethylbenzene Diethyl carbonate Diethyldichlorosilane Diethylenetriamine Diethyl ether N,N-Diethylethytenediamine Di-2-(ethylhexyl)peroxydicarbonate 07/11/95 12:31 GUIDE# IP * 153 151 130 132P 132P 152 160 126 141 141 153 160 153 130 152 156 156 130 130 153 132 153 119 126 126 151 152 145 127 153 153 148 148 129 145 129 140 151 128 128 127 150 127 132 132 132 132 132 153 130 127 155 154 127 132 148 2249 2761 2362 1150 1150 1916 9274 1029 2465 2465 2490 1593 2650 1152 2765 2250 1766 1279 1279 2750 2047 1760 2189 1958 1958 8264 2783 2121 2251 2565 2687 2152 2153 2048 2168 2372 1465 2761 1202 1993 2373 3036 2374 1154 2686 2686 2684 2684 2432 2049 2366 1767 2079 1155 2685 2122 Page22 CMA111353 NAME OF MATERIAL DH2-ethylhexyl)peroxydicart>onate Di-(2-ethylhexyl)phosphoric acid Diethyl ketone Diethyl peroxydicarbonate Diethyl sulfate Diethyl sulfide Diethyl sulphate Diethyl sulphide Diethylthiophosphoryl chloride Diethytzinc Difluorochloroethanes ' 1,1-Difluoroethane Difluoroethane Difluoroethane and Dichlorodifluoromethane azeotropic mixture with approximately 74% dichlorodifluoromethane 1,1-Difluoroethylene Difluoromethane Difluorophosphoric acid, anhydrous 2,2-Dihydroperoxypropane 2,3-Dihydropyran Di-(1 -hydroxycyclohexyl)peroxide Diisobutylamine Diisobutylene, isomeric compounds Diisobutyl ketone Diisobutyryl peroxide Diisooctyl acid phosphate Diisopropylamine Diisopropylbenzene hydroperoxide Diisopropyl ether Diisotridecyl peroxydicarbonate Diketene, inhibited 1 ,1-Dimethoxyethane 1,2-Dimethoxyethane Dimethylamine, anhydrous Dimethyiamine, aqueous solution Dimethylamine, solution 2-Dimethylaminoacetonitrile 4-Dimethylamino-6-(2-dimethylaminoethoxy)toluene>2-diazonium zinc chloride 2-Dimethylaminoethanol 2-Dimethylaminoethyl acrylate Dimethytaminoethyl methacrylate N,N*Dimethylaniline Di-(2-methylbenzoyl)peroxide 2,3-Dimethylbutane 1,3'Dimethylbutylamine Dimethylcarbamoyl chloride Dimethyl carbonate Dimethyl chlorothiophosphate Dimethylcyclohexanes Dimethyicyclohexylamine 2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane 2>5-Dimethyl-2,5-di>(benzoylperoxy)hexane 2,5*Dimethyl-2,5-di-(tert-butylperoxy)hexane 2,5-Dimethyl-2,5-di-(tert-biitylperoxy)hexane 2.5-Dimethyl-2,5*di*(tert-butylperoxy)hexyne-3 GUIDE# IP* 148 2123 153 1902 127 1156 148 2175 152 1594 129 2375 152 1594 129 2375 155 2751 135 1366 115 2517 115 1030 115 1030 126 116 115 154 146 127 145 132 127 127 148 153 132 145 127 148 131P 127 127 118 129 129 131 2602 1959 3252 1768 2178 2376 2148 2361 2050 1157 2182 1902 1158 2171 1159 2889 2521 2377 2252 1032 1160 1160 2378 150 132 152 153P 153 148 128 132 156 129 156 128 132 146 145 145 145 146 3039 2051 3302 2522 2253 2593 2457 2379 2262 1161 2267 2263 2264 2172 2173 2155 2156 2158 07/11/95 12:31 Page23 CMA 111354 NAME OF MATERIAL GUIDE# IP* 2,5-Dimethyl-2,5-dMtert-butylperoxy)hexyne-3, with not more than 52% Peroxide in inert solid Dimethyidichiorosilane Dimethyldiethoxysilane 2,5-Dimethyl-2,5-di(2-ethylhexanoyiperoxy)hexane 2.5-Dimethyl-2,5-dihydroperoxy hexane, not more than 82% with water Dimethyldioxanes Dimethyl disulfide Dimethyl disulphide Dimethylethanolamine Dimethyl ether N,N-Dimethylformamide Dimethylhexane dihydroperoxide, with 18% or more water 1,1-Dimethylhydrazine 1,2-Dimethylhydrazine Dimethylhydrazine, symmetrical Dimethylhydrazine, unsymmetrical Dimethyl phosphorochloridothioate 2,2-Dimethylpropane Dimethyl-N-propylamine Dimethyl sulfate Dimethyl sulfide Dimethyl sulphate Dimethyl sulphide Dimethyl thiophosphoryl chloride Dimethytzinc Dimyristyl peroxydicartwnate Dimyristyl peroxydicarbonate, not more than 42%, in water Dinitroanilines Dinitrobenzenes Dinitrochlorobenzene Dinitro-o-cresol Dinitrocyclohexylphenoi Dinitrogen tetroxide Dinitrogen tetroxide, liquefied Dinitrogen tetroxide and Nitric oxide mixture Dinitrophenol, solution Dinitrophenol, wetted with not less than 15% water Dinitrophenoiates, wetted with not less than 15% water Dinitroresorcinol, wetted with not less than 15% water N.N'-Dinrtraso-N.N'-dimethyl terephthalamide N, N'-Dinitrosopentamethylene tetramine Dinitrotoluenes Dinitrotoluenes, liquid Dinitrotoluenes, molten Dinitrotoluenes, solid Dioxane Dioxolane Dipentene Diphenylamine chloroarsine Diphenylchloroarsine Diphenylchloroarsine, liquid Diphenylchloroarsine, solid Diphenyldichlorosilane Diphenylmethane-4,4'-diisocyanate Diphenylmethyl bromide 145 2159 155 1162 127 2380 148 2157 146 2174 128 2707 130 2381 130 2381 132 2051 115 1033 129 2265 146 2174 131 1163 131 2382 131 2382 131 1163 156 2267 115 2044 132 2266 156 1565 130 1164 156 1595 130 1164 156 2267 135 1370 148 2595 148 2892 153 1596 152 1597 153 1577 153 1598 153 9026 124 1067 124 1067 124 1975 153 1599 113 1320 113 1321 113 1322 146 2673 149 2972 152 2038 152 2038 152 1600 152 2038 127 1165 127 1166 128 2052 154 1698 151 1699 151 1699 151 1699 156 1769 156 2489 153 1770 07/11/95 12:31 Page24 CMA111355 NAME OF MATERIAL Diphenyioxide-4,4`-disulfohydrazide Diphenyloxide-4,4'-disulphohydrazide Diphosgene Dipicryl sulfide, wetted with not less than 10% water Dipicryl sulphide, wetted with not less than 10% water Dipropylamine 4-Dipropylaminobenzenediazonium zinc chloride Di-n-propyl ether Dipropyl ether Dipropyl ketone Di-n-propyl peroxydicarbonate Disinfectant, liquid, corrosive, n.o.s. Disinfectant, liquid, n.o.s. Disinfectant, liquid, poisonous, n.o.s. Disinfectant, liquid, toxic, n.o.s. Disinfectant, solid, poisonous, n.o.s. Disinfectant, solid, toxic, n.o.s. Disinfectants, corrosive, liquid, n.o.s. Disinfectants, liquid, n.o.s. (poisonous) Disinfectants, solid, n.o.s. (poisonous) Disodium trioxositicate Disodium trioxositicate, pentahydrate Dispersant gas, n.o.s. Dispersant gas, n.o.s. (flammable) Distearyl peroxydicarbonate Disulfoton Dithiocarbamate pesticide, liquid, flammable, poisonous Dithiocarbamate pesticide, liquid, flammable, toxic Dithiocarbamate pesticide, liquid, poisonous Dithiocarbamate pesticide, liquid, poisonous, flammable Dithiocarbamate pesticide, liquid, toxic Dithiocarbamate pesticide, liquid, toxic, flammable Dithiocarbamate pesticide, solid, poisonous Dithiocarbamate pesticide, solid, toxic Di-(3,5,5-trimethyM,2-dioxolanyi-3)peroxide Divinyl ether, inhibited Dodecylbenzenesutfonic acid Dodecylbenzenesulphonic acid Dodecyltrichlorosilane Driers, paint or varnish, liquid, n.o.s. Drugs, liquid, n.o.s. Drugs, liquid, n.o.s. Drugs, n.o.s. Drugs, n.o.s. Drugs, n.o.s. Drugs, solid, n.o.s. Drugs, solid, n.o.s. Dry ice Dye, liquid, corrosive, n.o.s. Dye, liquid, poisonous, n.o.s. Dye, liquid, toxic, n.o.s. Dye, solid, corrosive, n.o.s. Dye, solid, poisonous, n.o.s. Dye, solid, toxic, n.o.s. Dye intermediate, liquid, corrosive, n.o.s. Dye intermediate, liquid, poisonous, n.o.s. 0-7/11/95 12:31 guide*IP* 149 149 125 113 113 132 149 127 127 127 148 153 128 151 151 151 151 153 151 151 154 154 126 115 145 152 131 131 151 131 151 131 151 151 148 131P 153 153 156 127 153 153 133 140 128 154 154 120 154 151 151 154 151 151 154 151 2951 2951 1076 2852 2852 2383 3034 2384 2384 2710 2176 1903 1993 3142 3142 1601 1601 1903 3142 1601 3253 3253 1078 1954 2592 2783 2772 2772 3006 3005 3006 3005 2771 2771 2597 1167 2584 2584 1771 1168 1760 2810 1325 1479 1993 1759 2811 1845 2801 1602 1602 3147 3143 3143 2801 1602 Page25 CMA 111356 NAME OF MATERIAL GUIDE# IP* Dye intermediate, liquid, toxic, n.o.s. Dye intermediate, solid, corrosive, n.o.s. Dye intermediate, solid, poisonous, n.o.s. Dye intermediate, solid, toxic, n.o.s. EDTA Elevated temperature liquid, flammable, n.o.$,, with flash point above 37.8C (100F), at or above its flash point Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5C (141F), at or above its flash point Elevated temperature liquid, n.o.s,, at or above 100eC (212F) and below its flash point 4 Elevated temperature material, liquid, n.o.s,, (at or above 100C (212F) and below its flash point) Elevated temperature solid, n.o.s,, at or above 240C (464F) Endosulfan Engines, internal combustion, including when fitted in machinery or vehicles Engine starting fluid Environmentally hazardous substances, liquid, n.o.s. Environmentally hazardous substances, solid, n.o.s. Epibromohydrin Epichlorohydrin 1,2-Epoxy-3-ethoxypropane Esters, n.o.s. Etching acid, liquid, n.o.s. Ethane Ethane, compressed Ethane, refrigerated liquid Ethane-Propane mixture, refrigerated liquid Ethanol Ethanol, solution Ethanoiamine Ethanolamine, solution Ethers, n.o.s. Ethion Ethyl acetate Ethyl acetylene, inhibited Ethyl acrylate, inhibited Ethyl alcohol Ethyl alcohol, solution Ethylamine Ethylamine, aqueous solution, with not less than 50% but not more than 70% Ethylamine Ethyl amyl ketone 2-Ethylaniline N-Ethylaniline Ethylbenzene N-Ethyl-N-benzylaniline N-Ethylbenzyltoluidines Ethyl borate Ethyl bromide Ethyl bromoacetate 2-Ethylbutanol 2-Ethylbutyl acetate Ethylbutyl acetate 151 1602 154 3147 151 3143 151 3143 171 9117 128 3256 128 3256 128 3257 128 9259 171 3258 151 2761 128 115 171 171 131 131P 127 127 157 115 115 115 115 127 127 153 153 127 152 129 116P 129P 127 127 118 3166 1960 3082 3077 2558 2023 2752 3272 1790 1035 1035 1961 1961 1170 1170 2491 2491 3271 2783 1173 2452 1917 1170 1170 1036 132 2270 127 2271 153 2273 153 2272 129 1175 153 2274 153 2753 129 1176 131 1891 155 1603 129 2275 129 1177 129 1177 07/11/95 12:31 Page26 CMA 111357 NAME OF MATERIAL GUIDE# ID* Ethyl butyl ether 2-Ethylbutyraidehyde Ethyl butyrate Ethyl chloride Ethyl chloroacetate Ethyl chloroformate Ethyl 2-chloropropionate Ethyl chlorothioformate Ethyl crotonate Ethyl cyanoacetate Ethyl-3,3-dKtert-butytperoxy)butyrate Ethyl-3,3-di-(tert-butylperoxy)butyrate Ethyl-3,3-di-(tert-butylperoxy)butyrate, not more than 77% in solution Ethytdichloroarsine EthykJichlorosilane Ethylene Ethylene, Acetylene and Propylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with not more than 22.5% Acetylene and not more than 6% Propylene. Ethylene, compressed Ethylene, refrigerated liquid (cryogenic liquid) Ethylene chlorohydrin Ethylenediamine Ethylenediaminetetraacetic acid Ethylene dibromide Ethylene dibromide and Methyl bromide mixture, liquid Ethylene dichloride Ethylene glycol diethyl ether Ethylene glycol monobutyl ether Ethylene glycol monoethyl ether Ethylene glycol monoethyl ether acetate Ethylene glycol monomethyl ether Ethylene glycol monomethyl ether acetate Ethyleneimine, inhibited Ethylene oxide Ethylene oxide and Carbon dioxide mixture, with more than 9% but not more than 87% Ethylene oxide Ethylene oxide and Carbon dioxide mixture, with more than 87% Ethylene oxide Ethylene oxide and Carbon dioxide mixtures, with not more than 9% Ethylene oxide Ethylene oxide and Carbon dioxide mixtures, with more than 6 % Ethylene oxide Ethylene oxide and Carbon dioxide mixtures, with not more than 6% Ethylene oxide Ethylene oxide and Chlorotetrafluoroethane mixture, with not more than 8.8% Ethylene oxide Ethylene oxide and Dichlorodifluoromethane mixture, with not more than 12.5% Ethylene oxide Ethylene oxide and Dichlorodifluoromethane mixtures, with not more than 12% Ethylene oxide Ethylene oxide and Pentafluoroethane mixture, with not more than 7.9% Ethylene oxide Ethylene oxide and Propylene oxide mixture, with not more than 30% Ethylene oxide 127 129 129 115 155 155 132 155 129 156 146 145 145 151 139 116P 1179 1178 1180 1037 1181 1182 2935 2826 1862 2666 2184 2598 2185 1892 1183 1962 116 116P 115 131 132 171 154 151 129 127 152 127 129 127 129 131P 119 3138 1962 1038 1135 1604 9117 1605 1647 1184 1153 2369 1171 1172 1188 1189 1185 1040 115 1041 119 3300 126 1952 115 1041 126 1952 126 3297 126 3070 126 3070 126 3298 129P 2983 07/11/95 12:31 Page27 CMA 111358 NAME OF MATERIAL GUIDE# IP* Ethylene oxide and Tetrafluoroethane mixture, with not more than 5.6% Ethylene oxide Ethylene oxide with Nitrogen Ethyl ether Ethyl fluoride Ethyl formate 2'Ethylhexytamine 2-Ethyihexyl chloroformate Ethyl isobutyrate Ethyl isocyanate Ethyl lactate * Ethyl mercaptan Ethyl methacrylate Ethyl methyl ether Ethyl methyl ketone Ethyl nitrate Ethyl nitrite, solution Ethyl orthoformate Ethyl oxaiate Ethyiphenyidichlorosilane Ethyl phosphonothioic dichloride, anhydrous Ethyl phosphonous dichloride, anhydrous Ethyl phosphorodichloridate 1-Ethylpiperidine Ethyl propionate Ethyl propyl ether Ethyl silicate Ethylsulfuric acid Ethylsulphuric acid N-Ethyltoluidines Ethyltrichlorosilane Etioiogic agent, n.o.s. Explosive A Explosive B Explosive C Explosives, division 1,1,1.2,1.3,1.5 or 1.6 Explosives, division 1.4 Extracts, aromatic, liquid Extracts, flavoring, liquid Extracts, flavouring, liquid Fabrics, animal, synthetic or vegetable, n.o.s., with oil Fabrics impregnated with weakly nitrated Nitrocellulose, n.o.s. Ferric ammonium citrate Ferric ammonium oxalate Ferric arsenate Ferric arsenite Ferric chloride Ferric chloride, anhydrous Ferric chloride, solution Ferric fluoride Ferric nitrate Ferric sulfate Ferric sulphate FerTocerium Ferrosilicon Ferrous ammonium sulfate 126 118 127 115 129 132 156 128 155 128 130 129P 115 127 128 131 129 156 156 156 136 156 132 129 127 132 156 156 153 155 158 112 112 114 112 114 127 127 127 133 133 171 171 151 151 157 157 154 171 140 171 171 170 139 171 3289 1040 1155 2453 1190 2276 2748 2385 2481 1192 2363 2277 1039 1193 1993 1194 2524 2525 2435 2927 2845 2927 2386 1195 2615 1282 2571 2571 2754 1196 2814 ..... 1169 1197 1197 1373 1353 9118 9119 1606 1607 1773 1773 2582 9120 1466 9121 9121 1323 1408 9122 07/11/95 12:31 Page28 CMA 111359 NAME OF MATERIAL Ferrous ammonium sulphate Ferrous arsenate Ferrous chloride, solid Ferrous chloride, solution Ferrous metal borings, shavings, turnings or cuttings Ferrous sulfate Ferrous sulphate Fertilizer, ammoniating solution, with free Ammonia Fiber, animal or vegetable, n.o.s., burnt, wet or damp Fiber, animal, synthetic or vegetable, n.o.s,, with oil Fibers Fibers impregnated with weakly nitrated Nitrocellulose, n.o.s. Fibres, animal, synthetic or vegetable, n.o.s., with oil Fibres impregnated with weakly nitrated Nitrocellulose, n.o.s. Film Films, nitrocellulose base Fire extinguisher charges, corrosive liquid Fire extinguishers with compressed gas Fire extinguishers with liquefied gas Firelighters, solid, with flammable liquid First aid kit Fish meal, stabilized Fish meal, unstabilized Fish meal containing 6% to 12% water Fish meal containing less than 6% or more than 12% water Fish scrap, stabilized Fish scrap, unstabilized Fish scrap containing 6% to 12% water Fish scrap containing less than 6% or more than 12% water Flame retardant compound, liquid (corrosive) Flammable gas in lighter for cigars, cigarettes, etc. Flammable liquid, corrosive, n.o.s Flammable liquid, n.o.s. Flammable liquid, poisonous, corrosive, n.o.s. Flammable liquid, poisonous. n.o.s. Flammable liquid, toxic, corrosive, n.o.s. Flammable liquid, toxic, n.o.s. Flammable liquid preparations, n.o.s. Flammable liquids, elevated temperature material, n.o.s. Flammable solid, corrosive, inorganic, n.o.s. Flammable solid, corrosive, n.o.s. Flammable solid, corrosive, organic, n.o.s. Flammable solid, inorganic, corrosive, n.o.s. Flammable solid, inorganic, n.o.s. Flammable solid, n.o.s. Flammable solid, organic, molten, n.o.s. Flammable solid, organic, n.o.s. Flammable solid, oxidizing, n.o.s. Flammable solid, poisonous, inorganic, n.o.s. Flammable solid, poisonous, n.o.s. Flammable solid, poisonous, organic, n.o.s. Flammable solid, toxic, inorganic, n.o.s. Flammable solid, toxic, organic, n.o.s. Flue dust, poisonous Fluoboric acid Fluorine 07/11/95 12:31 GUIDE* IP# 171 151 154 154 170 171 171 125 133 133 133 133 133 133 133 133 154 126 126 133 171 171 133 171 133 171 133 171 133 154 115 132 128 131 131 131 131 127 128 134 134 134 134 133 133 133 133 140 134 134 134 134 134 154 154 124 9122 1608 1759 1760 2793 9125 9125 1043 1372 1373 1372 1353 1373 1353 1324 1324 1774 1044 1044 2623 3316 2216 1374 2216 1374 2216 1374 2216 1374 1760 1057 2924 1993 3286 1992 3286 1992 1142 9276 3180 2925 2825 3180 3178 1325 3176 1325 3097 3179 2926 2926 3179 2926 2811 1775 1045 CMA 111360 NAME OF MATERIAL Fluorine, compressed Fluorine, refrigerated liquid (cryogenic liquid) Fiuoroacetic acid Fluoroanilines Fiuorobenzene Fluoroboric acid FJuorophosphoric add, anhydrous Fluorosilicates, n.o.s. Fluorosiiicic acid Fluorosuifonic add Fluorosulphonic add ' Fluorotoluenes Fluosilidc add Formaldehyde, solution, flammable Formaldehyde, solutions (Formalin) Formaldehyde, solutions (Formalin) (corrosive) Formic add Fuel, aviation, turbine engine Fuel oil Fuel oil Fuel oil, no. 1,2,4,5,6 Fumaric add Fumaryl chloride Furan Furfural Furfuraldehydes Furfuryl alcohol Furfurylamine Fusee (rail or highway) Fusel oil Gallium Gas cartridges Gas, refrigerated liquid, flammable, n.o.s. Gas, refrigerated liquid, n.o.s. Gas, refrigerated liquid, oxidizing, n.o.s. Gas drips, hydrocarbon Gas generator assemblies Gas identification set Gasohol Gas oil Gasoline Gas sample, non-pressurized, flammable, n.o.s,, not refrigerated liquid Gas sample, non-pressurized, poisonous, flammable, n.o.s., not refrigerated liquid Gas sample, non-pressurized, poisonous, n.o.s., not refrigerated liquid Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid Genetically modified micro-organisms Genetically modified organisms Germane Glycerol alpha-monochlorohydrin Glycidaldehyde Grenade, tear gas Guanidine nitrate Hafnium powder, dry GUIDE* IP* 124 167 156 153 130 154 154 151 154 137 137 130 154 132 132 132 153 128 128 128 128 171 156 127 132P 132P 153 132 133 127 172 115 115 120 122 128 171 123 128 128 128 115 1045 9192 2642 2941 2387 1775 1776 2856 1778 1777 1777 2388 1778 1198 1198 2209 1779 1863 1202 1993 1202 9126 1780 2389 1199 1199 2874 2526 1325 1201 2803 2037 3312 3158 3311 1864 8013 9035 1203 1202 1203 3167 119 3168 123 3169 119 123 171 171 119 153 131P 159 143 135 3168 3169 3245 9278 2192 2689 2622 2017 1467 2545 07/11/95 12:31 page30 CMA 111361 NAME OF MATERIAL Hafnium powder, wetted with not less than 25% water Halogenated irritating liquid, n.o.s. Hay, wet, damp or contaminated with oil Hazardous substance, liquid, n.o.s. Hazardous substance, solid, n.o.$. Hazardous waste, liquid, n.o.$. Hazardous waste, liquid, n.o.s. Hazardous waste, solid, n.o.s. Hazardous waste, solid, n.o.s. Heater for refrigerator car, liquid fuel type Heating oil, light Heat producing article Helium Helium, compressed Helium, refrigerated liquid (cryogenic liquid) Helium-Oxygen mixture Heptafluoropropane n-Heptaldehyde Heptanes n-Heptene Hexachloroacetone Hexachlorobenzene Hexachlorobutadiene Hexachlorocyciopentadiene Hexachloroethane Hexachlorophene Hexadecyttrichlorosilane Hexadiene Hexaethyl tetraphosphate Hexaethyl tetraphosphate, liquid Hexaethyl tetraphosphate, solid Hexaethyl tetraphosphate and compressed gas mixture Hexaethyl tetraphosphate mixture, liquid Hexafluoroacetone Hexafluoroacetone, hydrate Hexafiuoroethane Hexafiuoroethane, compressed Hexafiuorophosphoric acid Hexafiuoropropylene Hexafluoropropylene oxide Hexaidehyde Hexamethylenediamine, solid Hexamethylenediamine, solution Hexamethylene diisocyanate Hexamethyieneimine Hexamethylenetetramine 3,3,6,6,9,9-HexamethyM,2,4,5-tetraoxacyclononane 3,3,6,6t9,9-Hexamethyl-1,2,4,5-tetfaoxacyclononane 3,3,6,6,9,9-Hexamethyl-1,2,4,5-tetraoxacyclononane Hexamine Hexanes Hexanoic acid Hexanoic acid Hexanols 1-Hexene Hexyltrichlorosilane 07/11/95 12:31 GUIDE* IP* 170 159 133 171 171 171 171 171 171 128 128 171 121 121 120 122 126 129 128 128 153 152 151 151 151 151 156 130 151 151 151 123 152 125 151 126 126 154 126 126 129 153 153 156 132 133 146 145 145 133 128 153 153 129 128 156 1326 1610 1327 9188 9188 3082 9189 3077 9189 1993 1202 8038 1046 1046 1963 1980 3296 3056 1206 2278 2661 2729 2279 2646 9037 2875 1781 2458 1611 1611 1611 1612 2783 2420 2552 2193 2193 1782 1858 1956 1207 2280 1783 2281 2493 1328 2165 2166 2167 1328 1208 1760 2829 2282 2370 1784 Page31 CMA111362 NAME OF MATERIAL GUIDE# ID# Hydrazine, anhydrous Hydrazine, aqueous solution, with not less than 37% but not more than 64% Hydrazine Hydrazine, aqueous solution, with not more than 37% Hydrazine Hydrazine, aqueous solutions, with more than 64% Hydrazine Hydrazine, aqueous solutions, with not more than 64% Hydrazine Hydrazine, hydrate Hydrides, metal, n.o.s. Hydriodic acid Hydriodic acid, solution Hydrobromic acid Hydrobromic acid, solution Hydrocarbon gas, compressed, n.o.s. Hydrocarbon gas, liquefied, n.o.s. Hydrocarbon gas mixture, compressed, n.o.$. Hydrocarbon gas mixture, liquefied, n.o.$. Hydrocarbon gas refills for small devices, with release device Hydrocarbons, liquid, n.o.s. Hydrochloric acid Hydrochloric acid, mixture Hydrochloric acid, solution Hydrocyanic acid, aqueous solution, with less than 5% Hydrogen cyanide Hydrocyanic acid, aqueous solution, with not more than 20% Hydrogen cyanide Hydrocyanic acid, aqueous solutions, with more than 20% Hydrogen cyanide Hydrocyanic acid, liquefied Hydrofluoric acid Hydrofluoric acid, solution Hydrofluoric acid and Sulfuric acid mixture Hydrofluoric acid and Sulphuric add mixture Hydrofluorosilidc add Hydroflubsiiidc add Hydrogen Hydrogen, compressed Hydrogen, refrigerated liquid (cryogenic liquid) Hydrogen and Carbon monoxide mixture Hydrogen and Carbon monoxide mixture, compressed Hydrogen and Methane mixture, compressed Hydrogen bromide, anhydrous Hydrogen chloride, anhydrous Hydrogen chloride, refrigerated liquid Hydrogen cyanide, anhydrous, stabilized Hydrogen cyanide, anhydrous, stabilized (absorbed) Hydrogen cyanide, aqueous solution, with not more than 20% Hydrogen cyanide Hydrogen cyanide, solution in alcohol, with not more than 45% Hydrogen cyanide Hydrogen cyanide, stabilized Hydrogen cyanide, stabilized (absorbed) Hydrogendifluorides, n.o.s. Hydrogen fluoride, anhydrous Hydrogen iodide, anhydrous Hydrogen peroxide, aqueous solution, stabilized, with more than 60% Hydrogen peroxide 132 2028 153 2030 152 3283 132 2028 153 2030 153 2030 138 1408 154 1787 154 1787 154 1788 154 1788 115 1864 115 1965 115 1964 115 1965 115 3150 128 3295 157 1789 157 1789 157 1788 154 1613 154 1613 117 117 157 157 157 157 154 154 115 115 115 119 lie . 115 125 125 125 117 131 1051 1051 1790 1790 1786 1786 1778 1778 1049 1049 1966 2600 2600 2034 1048 1050 2186 1051 1614 154 1613 131 3294 117 1051 131 1614 154 1740 125 1052 125 2197 143 2015 07/11/95 12:31 CMA111363 NAME OF MATERIAL Hydrogen peroxide, aqueous solution, with not less than 8% but less than 20% Hydrogen peroxide Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 60% Hydrogen peroxide (stabilized as necessary) Hydrogen peroxide, stabilized Hydrogen peroxide and Peroxyacetic acid mixture, with add(s), water and not more than 5% Peroxyacetic acid, stabilized Hydrogen selenide, anhydrous Hydrogen sulfide Hydrogen sulfide, liquefied Hydrogen sulphide ~ Hydrogen sulphide, liquefied Hydroquinone 3-(2-Hydraxyethoxy)-4-pyrTOlidin-l-ylbenzenediazonium zinc chloride Hydroxylamine sulfate Hydroxylamine sulphate Hypochlorite solution Hypochlorite solution, with more than 5% available Chlorine Hypochlorites, inorganic, n.o.s. 3,3'-lminodipropylamine Infectious substance, affecting animals only Infectious substance, affecting humans Ink, printer's, flammable insecticide, dry, n.o.s. Insecticide, liquefied gas Insecticide, liquefied gas, containing Poison A or Poison B material Insecticide, liquid, poisonous, n.o.s. Insecticide gas, flammable, n.o.$. Insecticide gas, n.o.s. Insecticide gas, poisonous, n.o.s. Insecticide gas, toxic, n.o.s. Iodine monochloride iodine pentafluoride 2-lodobutane lodomethylpropanes lodopropanes IPDI Iron oxide, spent Iron pentacarbonyl Iron sponge, spent Irritating agent, n.o.s. Isobutane Isobutane Isobutane mixture Isobutane mixture Isobutanol Isobutyl acetate Isobutyl acrylate Isobutyl acrylate, inhibited Isobutyl alcohol Isobutyl aldehyde Isobutylamine Isobutyl chloroformate Isobutylene Isobutylene Isobutyl formate GUIDE* IP* 140 2984 140 2014 143 2015 140 117 117 117 117 117 153 150 154 154 154 154 140 153 158 158 129 151 126 123 151 115 126 123 123 157 144 129 129 129 156 135 131 135 159 115 115 115 115 129 129 130P 130P 129 129 132 155 115 115 132 3149 2202 1053 1053 1053 1053 2662 3035 2865 2665 1791 1791 3212 2269 2900 2814 1210 2588 1968 1967 2902 1954 1968 1967 1967 1792 2495 2390 2391 2392 2290 1376 1994 1376 1693 1075 1969 1075 1969 1212 1213 2527 2527 1212 2045 1214 2742 1055 1075 2393 07/11/95 12;31 Page33 CMA111364 NAME OF MATERIAL Isobutyl isobutyrate Isobutyl isocyanate Isobutyl methacrylate Isobutyl methacrylate, inhibited Isobutyl propionate Isobutyraldehyde isobutyric acid Isobutyric anhydride isobutyronitrlle Isobutyryl chloride Isocyanate solution, flammable, poisonous, n.o.s. Isocyanate solution, flammable, toxic, n.o.s. Isocyanate solution, poisonous, flammable, n.o.s. Isocyanate solution, poisonous, n.o.s. Isocyanate solution, toxic, flammable, n.o.s. Isocyanate solution, toxic, n.o.s. Isocyanate solutions, n.o.s. Isocyanate solutions, n.o.s. Isocyanate solutions, n.o.s. Isocyanate solutions, n.o.s. (toxic) Isocyanates, flammable, poisonous, n.o.s. Isocyanates, flammable, toxic, n.o.s. Isocyanates, n.o.s. Isocyanates, n.o.s. Isocyanates, n.o.s. Isocyanates, n.o.s. (toxic) Isocyanates, poisonous, flammable, n.o.$. Isocyanates, poisonous, n.o.s. Isocyanates, toxic, flammable, n.o.s. Isocyanates, toxic, n,o.s. Isocyanatobenzotrifluorides Isoheptene Isohexene Isononanoyl peroxide Isooctane Isooctene Isopentane Isopentanoic acid Isopentenes Isophoronediamine Isophorone diisocyanate Isoprene, inhibited Isopropanol Isopropanolamine dodecylbenzenesulfonate Isopropanolamine dodecylbenzenesulphonate Isopropenyl acetate Isopropenylbenzene Isopropyl acetate Isopropyl acid phosphate Isopropyl alcohol Isopropylamine Isopropylbenzene Isopropyl butyrate Isopropyl chloroacetate Isopropyl chloroformate Isopropyl 2-chloropropionate 07/11/95 12:31 GUIDE* IP# 129 155 130 130 129 129 132 132 131 132 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 155 156 128 128 148 128 128 128 153 128 153 156 130P 129 171 171 129P 128 129 153 129 132 131 129 156 155 132 2528 2486 2283 2283 2394 2045 2529 2530 2284 2395 2478 2478 3080 2206 3080 2206 2206 2478 3080 2207 2478 2478 2206 2478 3080 2207 3080 2206 3080 2206 2285 2287 2288 2128 1262 1216 1265 1760 2371 2289 2290 1218 1219 9127 9127 2403 2303 1220 1793 1219 1221 1918 2405 2947 2407 2934 Page34 CMA 111365 NAME OF MATERIAL GUIDE# IP# Isopropyl isobutyrate Isopropyl isocyanate Isopropyl mercaptan Isopropyl nitrate Isopropyl percarbonate, unstabilized isopropyl peroxydicarbonate isopropyl peroxydicarbonate Isopropyl propionate isosorbide dinitrate mixture lsosorbide-5-mononitrate Kerosene Ketones, liquid, n.o.s. Krypton Krypton, compressed Krypton, refrigerated liquid (cryogenic liquid) Lacquer chips, dry Lauroyl peroxide Lauroyl peroxide, not more than 42%, stable dispersion, in water Leachable toxic waste Lead acetate Lead arsenates Lead arsenites Lead chloride Lead compound, soluble, n.o.s. Lead cyanide Lead dioxide Lead fluoborate Lead fluoride Lead nitrate Lead perchlorate Lead perchlorate, solid Lead perchlorate, solution Lead peroxide Lead phosphite, dibasic Lead sulfate, with more than 3% free acid Lead sulphate, with more than 3% free acid Life-saving appliances, not self-inflating Life-saving appliances, self-inflating Lighters (cigarettes) (flammable gas) Lighters for cigars, cigarettes etc. with lighter fluid Lighters for cigars, cigarettes (flammable liquid) Lighter refills (cigarettes) (flammable gas) Lindane Liquefied gas (nonflammable) Liquefied gas, flammable, n.o.s. Liquefied gas, flammable, n.o.s. Liquefied gas, flammable, poisonous, n.o.s. Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, flammable, poisonous, n.o.s. (inhalation Hazard Zone C) Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, flammable, toxic, n.o.s. Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 131 2406 155 2483 130 2402 130 1222 148 2133 148 2133 148 2134 129 2409 133 2907 133 3251 128 1223 127 1224 121 1056 121 1056 120 1970 133 2557 145 2124 145 2893 151 9500 151 1616 151 1617 151 1618 151 2291 151 2291 151 1620 141 1872 151 2291 154 2811 141 1469 141 1470 141 1470 141 1470 141 1872 133 2989 154 1794 154 1794 171 3072 171 2990 115 1057 127 1226 127 1226 115 1057 151 2761 121 1058 115 1954 115 3161 119 1953 119 1953 119 1953 119 1953 119 1953 119 1953 119 1953 119 1953 119 1953 119 1953 07/11/95 12:31 Page35 CMA 111366 NAME OF MATERIAL GUIDE# n># Liquefied gas, n.o.s. Liquefied gas, n.o.s. Liquefied gas, oxidizing, n.o.s. Liquefied gas, poisonous, corrosive, n.o.s. Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, corrosive, n.o.$. (Inhalation Hazard Zone D) Liquefied gas, poisonous, flammable, corrosive, n.o.s. Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) ~ Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone 0) Liquefied gas, poisonous, flammable, n.o.s. Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone 0) Liquefied gas, poisonous, n.o.s. Liquefied gas, poisonous, n.o.$. Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, n.o.s. (inhalation Hazard Zone A) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone 0) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, oxidizing, n.o.s. Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, corrosive, n.o.s. Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, flammable, corrosive, n.o.s. Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, flammable, corrosive, n.o.s. (inhalation Hazard Zone B) 126 126 122 123 123 123 123 123 119 119 119 119 119 119 119 119 119 119 123 123 123 123 123 123 123 123 123 123 124 124 124 124 124 124 124 124 124 124 123 123 123 123 123 119 119 119 1956 3163 3157 3308 3308 3308 3308 3308 3309 3309 3309 3309 3309 3160 3160 3160 3160 3160 1955 3162 3162 1955 3162 1955 3162 1955 3162 1955 3310 3310 3310 3310 3310 3307 3307 3307 3307 3307 3308 3308 3308 3308 3308 3309 3309 3309 07/11/95 12:31 Page36 CMA 111367 NAME OF MATERIAL GUIDE0 ID# Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, flammable, n.o.s. Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, n.o.s. Liquefied gas, toxic, n.o.s. - Liquefied gas, toxic, n.o.s. (inhalation Hazard Zone A) Liquefied gas, toxic, n.o.s. (inhalation Hazard Zone A) Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, n.o.$. (Inhalation Hazard Zone 0) Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone 0) Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, oxidizing, corrosive, n.o.$. (Inhalation Hazard Zone C) Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, oxidizing, n.o.s. Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) Liquefied natural gas (cryogenic liquid) Liquefied petroleum gas Lithium Lithium acetylide*Ethylenediamine complex Lithium alkyls Lithium aluminum hydride Lithium aluminum hydride, ethereal Lithium amide Lithium batteries Lithium batteries, liquid or solid cathode Lithium batteries contained in equipment Lithium batteries packed with equipment Lithium borohydride Lithium chromate Lithium ferrosilicon Lithium hydride Lithium hydride, fused solid Lithium hydroxide, monohydrate Lithium hydroxide, solid Lithium hydroxide, solution Lithium hypochlorite, dry Lithium hypochlorite mixture Lithium hypochlorite mixtures, dry 119 3309 119 3309 119 3160 119 3160 119 3160 119 3160 119 3160 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 124 3310 124 3310 124 3310 124 3310 124 124 124 124 124 124 115 115 138 138 135 138 . 138 139 138 138 138 138 138 171 139 138 138 154 154 154 140 140 140 3310 3307 3307 3307 3307 3307 1972 1075 1415 2813 2445 1410 1411 1412 3090 3090 3091 3091 1413 9134 2830 1414 2805 2680 2680 2679 1471 1471 1471 07/11/95 12:31 Page37 CMA 111368 NAME OF MATERIAL GUIDE* IP* Lithium nitrate Lithium nitride Lithium peroxide Lithium silicon LNG {cryogenic liquid) London purple LPG Magnesium Magnesium, in pellets, turnings or ribbons Magnesium alkyls Magnesium alloys, with more than 50% Magnesium, in pellets, turnings or ribbons Magnesium alloys powder Magnesium aluminum phosphide Magnesium arsenate Magnesium bisulfite solution Magnesium bisulphite solution Magnesium brumate Magnesium chlorate Magnesium chloride and Chlorate mixture Magnesium diamide Magnesium diphenyl Magnesium fluorosiiicate Magnesium granules, coated Magnesium hydride Magnesium nitrate Magnesium perchlorate Magnesium peroxide Magnesium phosphide Magnesium powder Magnesium scrap Magnesium silicide Magnetized material Maleic acid Maieic anhydride Malononitrile Maneb Maneb, stabilized Maneb preparation, stabilized Maneb preparation, with not less than 60% Maneb Manganese nitrate Manganese resinate Matches, fusee Matches, safety Matches, "strike anywhere" Matches, wax "vesta" Medical waste, n.o.s. Medicine, liquid, flammable, toxic, n.o.s. Medicine, liquid, toxic, n.o.s. Medicine, solid, toxic, n.o.s. Medicines, corrosive, liquid, n.o.s. Medicines, corrosive, solid, n.o.s. Medicines, flammable, liquid, n.o.s. Medicines, flammable, solid, n.o.s. Medicines, liquid, flammable, poisonous, n.o.s. Medicines, liquid, poisonous, n.o.s. 140 138 143 138 115 151 115 138 138 135 138 138 139 151 154 154 140 140 140 135 135 151 138 138 140 140 140 139 138 138 138 171 156 156 153 135 135 135 135 140 133 133 133 133 133 158 131 151 151 154 154 128 133 131 151 2722 2806 1472 1417 1972 1621 1075 1869 1869 3053 1869 1418 1419 1622 2693 2693 1473 2723 1459 2004 2005 2853 2950 2010 1474 1475 1476 2011 1418 1869 2624 2807 2215 2215 2647 2210 2968 2968 2210 2724 1330 2254 1944 1331 1945 3291 3248 1851 3249 1760 1759 1993 1325 3248 1851 07/11/95 12:31 Page38 CMA 111369 NAME OF MATERIAL Medicines, oxidizing substances, solid, n.o.s. Medicines, poisonous, liquid, n.o.s. Medicines, poisonous, solid, n.o.s. Medicines, solid, poisonous, n.o.s. Medicines, toxic, liquid, n.o.s. Medicines, toxic, solid, n.o.s. Menthane hydroperoxide, para, technical pure Mercaptan mixture, aliphatic Mercaptan mixture, liquid, flammable, poisonous, n.o.s. Mercaptan mixture, liquid, flammable, toxic, n.o.s. Mercaptan mixture, liquid, poisonous, flammable, n.o.s. Mercaptan mixture, liquid, toxic, flammable, n.o.s. Mercaptan mixtures, liquid,- n.o.s. Mercaptan mixtures, liquid, n.o.$. Mercaptans, liquid, flammable, poisonous, n.o.s. Mercaptans, liquid, flammable, toxic, n.o.s. Mercaptans, liquid, n.o.s. Mercaptans, liquid, poisonous, flammable, n.o.s. Mercaptans, liquid, toxic, flammable, n.o.s. Mercuric arsenate Mercuric bromide Mercuric chloride Mercuric cyanide Mercuric nitrate Mercuric oxycyanide Mercuric potassium cyanide Mercuric sulfate Mercuric sulphate Mercurous bromide Mercurous nitrate Mercurous sulfate Mercurous sulphate Mercury Mercury, metallic Mercury acetate Mercury ammonium chloride Mercury based pesticide, liquid, flammable, poisonous Mercury based pesticide, liquid, flammable, toxic Mercury based pesticide, liquid, poisonous Mercury based pesticide, liquid, poisonous, flammable Mercury based pesticide, liquid, toxic Mercury based pesticide, liquid, toxic, flammable Mercury based pesticide, solid, poisonous Mercury based pesticide, solid, toxic Mercury benzoate Mercury bisulfate Mercury bisulphate Mercury bromides Mercury compound, liquid. n.o.s. Mercury compound, solid, n.o.s. Mercury cyanide Mercury gluconate Mercury iodide Mercury metal Mercury nucleate Mercury oleate 07/11/95 12:31 GUIDE# ID# 140 153 154 151 153 154 147 131 131 131 131 131 131 131 131 131 131 131 131 151 154 154 154 141 151 157 151 151 154 141 151 151 172 172 151 151 131 131 151 131 151 131 151 151 154 151 151 154 151 151 154 . 151 151 172 151 151 1479 2810 2811 3249 2810 2811 2125 1228 1228 1228 3071 3071 1228 3071 1228 1228 3071 3071 3071 1623 1634 1624 1636 1625 1642 1626 1645 1645 1634 1627 1628 1628 2809 2809 1629 1630 2778 2778 3012 3011 3012 3011 2777 2777 1631 1633 1633 1634 2024 2025 1636 1637 1638 2809 1639 1640 CMA 111370 NAME OF MATERIAL Mercury oxide Mercury oxycyanide, desensitized Mercury potassium iodide Mercury salicylate Mercury sulfate Mercury sulphate Mercury thiocyanate Mesityl oxide Metal alkyl, solution, n.o.s. Metal alkyl halides, n.o.s. Metal alkyl hydrides, n.o.$. Metal alkyls, n.o.s. Metal aryl halides, n.o.s. Metal aryl hydrides, n.o.s. Metal aryls, n.o.s Metal carbonyls, n.o.s. Metal catalyst, dry Metal catalyst, wetted Metaldehyde Metal hydrides, flammable, n.o.s. Metal hydrides, water reactive, n.o.s. Metallic substance, water-reactive, n.o.s. Metallic substance, water-reactive, self-heating, n.o.s. Metal powder, flammable, n.o.s. Metal powder, self-heating, n.o.s. Metal salts of organic compounds, flammable, n.o.s. Methacrylaldehyde Methacrylaldehyde, inhibited Methacrylic acid, inhibited Methacrylonitrile, inhibited Methallyl alcohol Methane Methane, compressed Methane, refrigerated liquid (cryogenic liquid) Methane and Hydrogen mixture, compressed Methanesulfonyl chloride Methanesulphonyl chloride Methanol Methoxymethyl isocyanate 4-Methoxy-4-methy!pentan-2-one 1 -Methoxy-2ipropanol Methyl acetate Methyl acetone Methyl acetylene and Propadiene mixture, stabilized Methyl acrylate, inhibited Methylai Methyl alcohol Methylallyl chloride Methylamine, anhydrous Methylamine, aqueous solution Methylamyl acetate Methylamyl alcohol Methyl amyl ketone N-Methylaniline Methyl benzoate alpha-Methylbenzyl alcohol 07/11/95 12:31 GUIDE# IP* 151 151 151 151 151 151 151 129 135 138 138 135 138 138 135 151 135 170 133 170 138 138 138 170 135 133 131P 131P 153P 131P 129 115 115 115 115 156 156 131 155 127 129 129 127 116P 129P 127 131 129P 118 132 129 129 127 153 152 153 1641 1642 1643 1644 1645 1645 1646 1229 9195 3049 3050 2003 3049 3050 2003 3281 2881 1378 1332 3182 1409 3208 3209 3089 3189 3181 2396 2396 2531 3079 2614 1971 1971 1972 2034 3246 3246 1230 2605 2293 3092 1231 1232 1060 1919 1234 1230 2554 1061 1235 1233 2053 1110 2294 2938 2937 Page40 CMA 111371 NAME OF MATERIA! Methylbenzyl alcohol (alpha) Methyl bromide Methyl bromide and Chloropicrin mixtures Methyl bromide and Ethylene dibromide mixture, liquid Methyl bromide and more than 2% Chloropicrin mixture, liquid Methyl bromide and nonflammable, nonliquefied compressed gas mixture Methyl bromoacetate 3-Methyibutan-2-one 2-MethyM-butene 2-Methyl-2-butene ~ 3-MethyM-butene N-Methylbutyiamine Methyl tert-butyl ether Methyl butyrate Methyl chloride Methyl chloride and Chloropicrin mixtures Methyl chloride and Methylene chloride mixture Methyl chloroacetate Methyl chloroformate Methyl chloromethyl ether Methyl 2-chloropropionate Methylchlorosilane Methyl cyanide Methylcydohexane Methytcydohexanots Methytcydohexanone Methylcydopentane Methyl dichloroacetate Methyldichloroarsine Methyldichlorosilane Methylene chloride Methylene chloride and Methyl chloride mixture Methyl ethyl ether Methyl ethyl ketone Methyl ethyl ketone peroxide 2-Methyl-5-ethylpyridine Methyl fluoride Methyl formate 2-Methylfuran 2-Methyl-2-hepthanethiol S-Methylhexan-2-one Methylhydrazine Methyl iodide Methyl isobutyl carbinol Methyl isobutyl ketone Methyl isobutyl ketone peroxide Methyl isocyanate Methyl isopropenyl ketone, inhibited Methyl isothiocyanate Methyl isovalerate Methyl magnesium bromide in Ethyl ether Methyl mercaptan Methyl methacrylate monomer, inhibited Methyl methacrylate monomer, uninhibited 4-Methylmorpholine 07/11/95 12:31 GUIDE# IP# 1S3 123 123 151 123 123 155 127 127 127 127 132 127 129 115 119 115 155 155 131 132 119 131 128 129 127 128 155 152 139 160 115 115 127 147 153 115 129 127 131 127 131 151 129 127 147 155 127P 131 130 135 117 129P 129P 132 2937 1062 1581 1647 1581 1955 2643 2397 2459 2460 2561 2945 2398 1237 1063 1582 1912 2295 1238 1239 2933 2534 1648 2296 2617 2297 2298 2299 1556 1242 1593 1912 1039 1193 2550 2300 2454 1243 2301 3023 2302 1244 2644 2053 1245 2126 2480 1246 2477 2400 1928 1064 1247 1247 2535 Page41 CMA 111372 NAME OF MATERIAL N-Methylmorpholine Methylmorpholine Methyl nitrite N-Methyl-N'-NItro-N-Nitrosoguanidine Methyl orthosllicate Methyl parathion, liquid Methyl parathion, liquid Methyl parathion, mixture, dry Methyl parathion, solid Methylperrtadiene Methyl pentane 2-Methylpentan-2-ol Methylphenyldichlorosilane Methyl phosphonic dichloride Methyl phosphonous dichloride 1-Methylpiperidine Methyl propionate Methyl propyl ether Methyl propyl ketone Methyttetrahydrofuran Methyl trichloroacetate Methyltrichlorosllane alpha-Methylvaleratdehyde Methyl valeraldehyde (alpha) Methyl vinyl ketone Methyl vinyl ketone, stabilized Mevinphos Mexacarbate M.I.B.C. Mining reagent, liquid Molybdenum pentachloride Monoethanolamine Mononitrotoluidines Monopropylamine Morpholine Morpholine, aqueous mixture Morpholine, aqueous mixture Motor fuel anti-knock compound Motor fuel anti-knock mixture Motor spirit Muriatic acid Musk xylene Naphtha Naphtha, petroleum Naphtha, solvent Naphthalene, crude Naphthalene, molten Naphthalene, refined Naphthenic acid alpha-Naphthylamine Naphthyiamine (alpha) beta-Naphthylamine Naphthyiamine (beta) Naphthylthiourea Naphthylurea Natural gas, compressed 07/11/95 12:31 GUIDE* ID* 132 132 115 133 155 152 152 152 152 127 128 129 156 137 136 132 129 127 127 127 156 155 130 130 131P 131P 152 151 129 153 156 153 153 132 132 154 132 131 131 128 157 149 128 128 128 133 133 133 171 153 153 153 153 153 153 115 2535 2535 2455 1325 2606 2783 3018 2783 2783 2461 2462 2560 2437 9206 2845 2399 1248 2612 1249 2536 2533 1250 2367 2367 1251 1251 2783 2757 2053 2022 2508 2491 2660 1277 2054 1760 2054 1649 1649 1203 1789 2956 2553 1255 1256 1334 2304 1334 9137 2077 2077 1650 1650 1651 1652 1971 Pa CMA 111373 NAME OF MATERIAL Natural gas, refrigerated liquid (cryogenic liquid) Natural gasoline Neohexane Neon Neon, compressed Neon, refrigerated liquid (cryogenic liquid) Nickel ammonium sulfate Nickel ammonium sulphate Nickel carbonyl Nickel catalyst, dry Nickel chloride ~ Nickel cyanide Nickel hydroxide Nickel nitrate Nickel nitrite Nickel sulfate Nickel sulphate Nicotine Nicotine compound, liquid, n.o.s. Nicotine compound, solid, n.o.s. Nicotine hydrochloride Nicotine hydrochloride, solution Nicotine preparation, liquid, n.o.s. Nicotine preparation, solid, n.o.s. Nicotine salicylate Nicotine sulfate, solid Nicotine sulfate, solution Nicotine sulphate, solid Nicotine sulphate, solution Nicotine tartrate Nitrate, n.o.s. Nitrates, inorganic, aqueous solution, n.o.s. Nitrates, inorganic, n.o.s. Nitrating acid, spent Nitrating acid mixture Nitrating acid mixture, spent Nitric acid, 40% or less Nitric acid, fuming Nitric acid, other than red fuming Nitric acid, other than red fuming, with more than 70% Nitric acid Nitric acid, other than red fuming, with not more than 70% Nitric acid Nitric acid, red fuming Nitric oxide Nitric oxide, compressed Nitric oxide and Dinitrogen tetroxide mixture Nitric oxide and Nitrogen dioxide mixture Nitric oxide and Nitrogen tetroxide mixture Nitriles, flammable, poisonous, n.o.s. Nitriles, flammable, toxic, n.o.s. Nitriles, poisonous, flammable, n.o.s. Nitriles, poisonous, n.o.s. Nitriles, toxic, flammable, n.o.s. Nitriles, toxic, n.o.s. Nitrites, inorganic, aqueous solution, n.o.s. Nitrites, inorganic, n.o.s. Nitroanilines 07/11/95 12:31 GUIDE* IP* 115 128 128 121 121 120 171 171 131 135 151 . 151 154 140 140 154 154 151 151 151 151 151 151 151 151 151 151 151 151 151 140 140 140 157 157 157 154 157 157 157 157 157 124 124 124 124 124 131 131 131 151 131 151 140 140 153 1972 1257 1208 1065 1065 1913 9138 9138 1259 2881 9139 1653 9140 2725 2726 9141 9141 1654 3144 1655 1656 1656 3144 1655 1657 1658 1658 1658 1658 1659 1477 3218 1477 1826 1796 1826 1760 2032 2031 2031 2031 2032 1660 1660 1975 1975 1975 3273 3273 3275 3276 3275 3276 3219 2627 1661 Pagc43 NAME OF MATERIAL Nitroanisole Nitroanisole, liquid Nitroanisole, solid Nitrobenzene Nitrobenzenesulfonic acid Nitrobenzenesulphonic acid Nitrobenzotrtfluorides Nitrobromobenzene Nitrobromobenzene, liquid Nitrobromobenzene, solid Nitrocellulose, block, wet, with not less than 25% alcohol 4 Nitrocellulose, colloided, granular or flake, wet, with not less than 20% alcohol or solvent Nitrocellulose, colloided, granular or flake, wet, with not less than 20% water Nitrocellulose, solution, flammable Nitrocellulose, solution, in a flammable liquid Nitrocellulose, wet, with not less than 30% alcohol or solvent Nitrocellulose membrane filters Nitrocellulose mixture, without plasticizer, without pigment Nitrocellulose mixture, without plasticizer, with pigment Nitrocellulose mixture, with plasticizer, without pigment Nitrocellulose mixture, with plasticizer, with pigment Nitrocellulose with alcohol Nitrocellulose with plasticizing substance Nitrocellulose with water, not less than 25% water Nitrochlorobenzenes, liquid Nitrochiorobenzenes, solid 3-Nitro-4-chlorobenzotrifluoride Nitrocresols Nitroethane Nitrogen Nitrogen, compressed Nitrogen, refrigerated liquid (cryogenic liquid) Nitrogen and Rare gases mixture Nitrogen and Rare gases mixture, compressed Nitrogen dioxide Nitrogen dioxide, liquefied Nitrogen dioxide and Nitric oxide mixture Nitrogen peroxide, liquid Nitrogen tetroxide, liquid Nitrogen tetroxide and Nitric oxide mixture Nitrogen trifluoride Nitrogen trifiuoride, compressed Nitrogen trioxide Nitroglycerin, solution in alcohol, with more than 1% but not more than 5% Nitroglycerin Nitroglycerin, solution in alcohol, with not more than 1% Nitroglycerin Nitroglycerin mixture with more than 2% but not more than 10% nitroglycerin, desensitized Nitroguanidine (Ricrite), wetted with not less than 20% water Nitroguanidine, wetted with not less than 20% water Nitrohydrochloric acid Nitromethane Nitronaphthalene Nitrophenols GUIDE* IP* 152 2730 152 2730 152 2730 152 1662 153 2305 153 2305 152 2306 152 2732 152 2732 152 2732 127 2059 127 2059 113 2555 127 2059 127 2059 113 2556 133 3270 133 2557 133 2557 133 2557 133 2557 113 2556 133 2557 113 2555 152 1578 152 1578 152 2307 153 2446 129 2842 121 1066 121 1066 120 1977 121 1981 121 1981 124 1067 124 1067 124 1975 124 1067 124 1067 124 1975 122 2451 122 2451 124 2421 127 3064 127 1204 113 3319 113 1336 113 1336 157 1798 129 1261 133 2538 153 1663 07/11/95 12:31 Page44 CMA 111375 NAME OF MATERIAL Nitropropanes p-Nitrosodimethylaniline Nitrostarch, wet, with not less than 30% alcohol or solvent Nitrostarch, wetted with not less than 20% water Nitrostarch, wetted with not less than 30% solvent Nitrosyl chloride Nitrosylsulfuric acid Nitrosylsulphuric acid Nitrotoluenes Nitrotoluenes, liquid Nitrotoluenes, solid Nitrotoluidines (mono) Nitrous oxide Nitrous oxide, compressed Nitrous oxide, refrigerated liquid Nitrous oxide and Carbon dioxide mixture Nitroxylenes Nitroxylol Nonanes Nonyttrichlorosilane 2,5-Norbomadiene 2,5-Norbomadiene, inhibited Octadecyltrichlorosilane Octadiene Octafluorobut-2-ene Octafiuorocyciobutane Octafluoropropane Octanes Octanoyl peroxide Octyl aldehydes tert*Octyl mercaptan Octyltrichlorosilane Oil, n.o.s., flash point not (ess than 93C (200F) Oil, petroleum, n.o.s. Oil gas Oil gas, compressed Oleum Oleum, with less than 30% free Sulfur trioxide Oleum, with less than 30% free Sulphur trioxide Oleum, with not less than 30% free Sulfur trioxide Oleum, with not less than 30% free Sulphur trioxide Organic peroxide, liquid, n.o.s. Organic peroxide, solution, n.o.s. Organic peroxide, solid, n.o.s. Organic peroxides, mixtures Organic peroxides, n.o.s. (including trial quantities) Organic peroxides, samples, n.o.s Organic peroxide type B, liquid Organic peroxide type B, liquid, temperature controlled Organic peroxide type B, solid Organic peroxide type B, solid, temperature controlled Organic peroxide type C, liquid Organic peroxide type C, liquid, temperature controlled Organic peroxide type C, solid Organic peroxide type C, solid, temperature controlled Organic peroxide type D. liquid 07/11/95 12:31 GUIDE# IP# 129 135 113 113 113 125 157 157 152 152 152 153 122 122 122 126 152 152 128 156 127 127 156 128P 126 126 126 128 148 129 131 156 171 128 119 119 137 137 137 137 137 146 146 146 146 148 146 146 148 146 148 146 148 146 148 145 2608 1369 1337 1337 1337 1069 2308 2308 1664 1664 1664 2660 1070 1070 2201 1015 1665 1665 1920 1799 2251 2251 1800 2309 2422 1976 2424 1262 2129 1191 3023 1801 9277 1270 1071 1071 1831 1831 1831 1831 1831 9183 9183 9187 2756 2899 2255 3101 3111 3102 3112 3103 3113 3104 3114 3105 m Page45 CMA 111376 NAME OF MATERIAL GUIDE *_JP Organic peroxide type D, liquid, temperature controlled Organic peroxide type D, solid Organic peroxide type D, solid, temperature controlled Organic peroxide type E, liquid Organic peroxide type E, liquid, temperature controlled Organic peroxide type E, solid Organic peroxide type E, solid, temperature controlled Organic peroxide type F, liquid Organic peroxide type F, liquid, temperature controlled Organic peroxide type F, solid Organic peroxide type F, solid, temperature controlled Organic phosphate, dry Organic phosphate, solid Organic phosphate compound, dry Organic phosphate compound, solid Organic phosphate compound mixed with compressed gas Organic phosphate mixed with compressed gas Organic phosphorus compound, dry Organic phosphorus compound, solid Organic phosphorus compound mixed with compressed gas Organic pigments, self-heating Organoarsenic compound, n.o.s. Organochlorine pesticide, liquid, flammable, poisonous Organochlorine pesticide, liquid, flammable, toxic Organochlorine pesticide, liquid, poisonous Organochlorine pesticide, liquid, poisonous, flammable Organochlorine pesticide, liquid, toxic Organochlorine pesticide, liquid, toxic, flammable Organochlorine pesticide, solid, poisonous Organochlorine pesticide, solid, toxic Organometaliic compound, poisonous, n.o.s. Organometallic compound solution, water-reactive, flammable, n.o.s. Organometaliic compound, toxic, n.o.s. Organometaliic compound, water-reactive, flammable, n.o.s. Organometaliic compound dispersion, water-reactive, flammable, n.o.s. Organophosphorus compound, poisonous, flammable, n.o.s. Organophosphorus compound, poisonous, n.o.s. Organophosphorus compound, toxic, flammable, n.o.s. Organophosphorus compound, toxic, n.o.s. Organophosphorus pesticide, liquid, flammable, poisonous Organophosphorus pesticide, liquid, flammable, toxic Organophosphorus pesticide, liquid, poisonous Organophosphorus pesticide, liquid, poisonous, flammable Organophosphorus pesticide, liquid, toxic Organophosphorus pesticide, liquid, toxic, flammable Organophosphorus pesticide, solid, poisonous Organophosphorus pesticide, solid, toxic Organotin compound, liquid, n.o.s. Organotin compound, solid, n.o.s. Organotin pesticide, liquid, flammable, poisonous Organotin pesticide, liquid, flammable, toxic Organotin pesticide, liquid, poisonous Organotin pesticide, liquid, poisonous, flammable Organotin pesticide, liquid, toxic Organotin pesticide, liquid, toxic, flammable Organotin pesticide, solid, poisonous 148 3115 145 3106 148 3116 145 3107 148 3117 145 3108 148 3118 145 3109 148 3119 145 3110 148 3120 152 2783 152 2783 152 2783 152 2783 123 1955 123 1955 152 2783 152 2783 123 1955 135 3313 151 3280 131 2762 131 2762 151 2996 131 2995 151 2996 131 2995 151 2761 151 2761 151 3282 138 3207 151 3282 138 3207 138 3207 131 3279 151 3278 131 3279 151 3278 131 2784 131 2784 152 3018 131 3017 152 3018 131 3017 152 2783 152 2783 153 2788 153 3146 131 2787 131 2787 153 3020 131 3019 153 3020 131 3019 153 2786 07/11/95 12:31 Pagc46 CMA 111377 NAME OF MATERIAL GUIDE# IP# Organotin pesticide, solid, toxic ORM-A, n.o.s. ORM-B, n.o.s. ORM-E, liquid, n.o.s. ORM-E, solid, n.o.s. Osmium tetroxide Other regulated substance Other regulated substances, liquid, n.o.$. Other regulated substances, solid, n,o.s. Oxalates, water soluble Oxidizer, corrosive, liquid, n.o.s. Oxidizer, corrosive, solid, n.o.s. Oxidizer, poisonous, liquid, n.o.s. Oxidizer, poisonous, solid, n.o.s. Oxidizing liquid, corrosive, n.o.s. Oxidizing liquid, n.o.s. Oxidizing liquid, poisonous, n.o.s. Oxidizing liquid, toxic, n.o.s. Oxidizing solid, corrosive, n.o.s. Oxidizing solid, flammable, n.o.s. Oxidizing solid, n.o.s. Oxidizing solid, poisonous, n.o.s. Oxidizing solid, self-heating, n.o.s. Oxidizing solid, toxic, n.o.s. Oxidizing solid, water-reactive, n.o.s. Oxidizing substances, liquid, corrosive, n.o.s. Oxidizing substances, liquid, n.o.s. Oxidizing substances, liquid, poisonous, n.o.s. Oxidizing substances, liquid, toxic, n.o.s. Oxidizing substances, self-heating, n.o.s. Oxidizing substances, solid, corrosive, n.o.s. Oxidizing substances, solid, flammable, n.o.s. Oxidizing substances, solid, n.o.s. Oxidizing substances, solid, poisonous, n.o.s. Oxidizing substances, solid, self-heating, n.o.s. Oxidizing substances, solid, toxic, n.o.s. Oxidizing substances, solid, which in contact with water emit flammable gases, n.o.s. Oxygen Oxygen, compressed Oxygen, refrigerated liquid (cryogenic liquid) Oxygen and Carbon dioxide mixture Oxygen and Carbon dioxide mixture, compressed Oxygen and Rare gases mixture Oxygen and Rare gases mixture, compressed Oxygen difluoride Oxygen difiuoride, compressed Oxygen generators, small Paint (corrosive) Paint (corrosive) Paint (flammable) Paint related material (corrosive) Paint related material (corrosive) Paint related material (flammable) Paper, unsaturated oil treated Paraformaldehyde 153 159 154 171 171 154 171 171 171 153 140 140 142 141 140 140 142 142 141 140 140 141 135 141 144 140 140 142 142 135 141 140 140 141 135 141 144 122 122 122 122 122 122 122 124 124 140 153 153 127 153 153 127 133 133 2786 1693 1760 9188 9188 2471 8027 3082 3077 2449 0193 6194 9199 6200 3098 3136 3099 3099 3085 3137 1479 3087 3100 3087 3121 3068 3139 3099 3099 3100 3085 3137 1479 3087 3100 3087 3121 1072 1072 1073 1014 1014 1980 1980 2190 2190 8037 1760 3066 1263 1760 3066 1263 1379 2213 07/11/95 12:31 Pagc47 CMA 111378 NAME OF MATERIAL GUIDE* ID* Paraldehyde Parathion Parathion and compressed gas mixture Parathion mixture, dry Parathion mixture, liquid PCB Pelargonyl peroxide Pentaborane Pentachioroethane Pentachlorophenol Pentafluoroethane ** Pentafluoroethane and Ethylene oxide mixture, with not more than 7.9% Ethylene oxide Pentamethylheptane Pentan-2,4-dione rvPentane Pentane*2,4-dione Pentanes 1-Pentene 1-Pentol Peracetic acid, solution Percarbonates, inorganic, n.o.s. Perchlorate, n.o.s. Perchlorates, inorganic, aqueous solution, n.o.s. Perchlorates, inorganic, n.o.s. Perchloric acid, with more than 50% but not more than 72% acid Perchloric acid, with not more than 50% acid Perchloroethylene Perchloromethyl mercaptan Perchloryl fluoride Perfluoroethyl vinyl ether Perfluoro(ethylvinyl ether) Perfluoromethyl vinyl ether Perfluoro(methy!vinyl ether) Perfumery products, with flammable solvents Permanganate, n.o.s. Permanganates, inorganic, aqueous solution, n.o.s. Permanganates, inorganic, n.o.s. Peroxides, inorganic, n.o.s. Peroxyacetic acid, solution Persulfates, inorganic, aqueous solution, n.o.s. Persulfates, inorganic, n.o.s. Persuiphates, inorganic, aqueous solution, n.o.s. Persulphates, inorganic, n.o.s. Pesticide, liquid, flammable, poisonous Pesticide, liquid, flammable, toxic Pesticide, liquid, poisonous, -flammable, n.o.s. Pesticide, liquid, poisonous, n.o.s. Pesticide, liquid, toxic, flammable, n.o.s. Pesticide, liquid, toxic, n.o.s. Pesticide, solid, poisonous Pesticide, solid, poisonous, n.o.s. Pesticide, solid, toxic, n.o.s. Pesticide, water-reactive Petrol Petroleum crude oil 129 1264 152 2783 123 1967 152 2783 152 2783 171 2315 148 2130 136 1380 151 1669 154 3155 126 3220 126 128 127 128 127 128 127 153P 147 140 140 140 140 143 140 160 157 124 115 115 115 115 127 140 140 140 140 147 140 140 140 140 131 131 131 151 131 151 151 151 151 135 128 128 3298 2286 2310 1265 2310 1265 1108 2705 2131 3217 1481 3211 1481 1873 1802 1897 1670 3083 3154 3154 3153 3153 1266 1482 3214 1482 1483 2131 3216 3215 3216 3215 3021 3021 2903 2902 2903 2902 2588 2588 2588 2210 1203 1267 07/11/95 12:31 Page48 CMA 111379 NAME OF MATERIAL Petroleum distillates, n.o.s. Petroleum ether Petroleum gases, liquefied Petroleum naphtha Petroleum oil Petroleum products, n.o.s. Petroleum spirit Phenacyl bromide Phenetidines Phenol, liquid Phenol, molten Phenol, solid Phenol solution Phenolates, liquid Phenolates, solid Phenolsulfonic acid, liquid Phenolsulphonic add, liquid Phenoxy pesticide, liquid, flammable, poisonous Phenoxy pestidde, liquid, flammable, toxic Phenoxy pesticide, liquid, poisonous Phenoxy pesticide, liquid, poisonous, flammable Phenoxy pesticide, liquid, toxic Phenoxy pesticide, liquid, toxic, flammable Phenoxy pesticide, solid, poisonous Phenoxy pesticide, solid, toxic PhenylacetonKrile, liquid Phenyiacetyl chloride Phenylcarbylamine chloride Phenyl chloroformate Phenyldichloroarsine Phenylenediamines Phenylhydrazine Phenyl isocyanate Phenyl mercaptan Phenylmercuric acetate Phenylmercuric compound, n.o.s. Phenylmercuric hydroxide Phenylmercuric nitrate Phenylphosphoms dichloride Phenylphosphorus thiodichloride Phenyltrichlorosilane Phenyl urea pestidde, liquid, flammable, poisonous Phenyl urea pestidde, liquid, flammable, toxic Phenyl urea pestidde, liquid, poisonous Phenyl urea pestidde, liquid, poisonous, flammable Phenyl urea pesticide, liquid, toxic Phenyl urea pestidde, liquid, toxic, flammable Phenyl urea pestidde, solid, poisonous Phenyl urea pestidde, solid, toxic Phosgene 9-Phosphabicydononanes Phosphine Phosphoric add Phosphoric anhydride Phosphorous add Phosphorous add, ortho 07/11/95 12:31 GUIDE* JP* 128 1268 128 1271 115 1075 128 1255 128 1270 128 1268 128 1271 153 2645 153 2311 153 2821 153 2312 153 1671 153 2821 154 2904 154 2905 153 1803 153 1803 131 2766 131 2766 152 3000 131 2999 152 3000 131 2999 152 2765 152 2765 152 2470 156 2577 151 1672 156 2746 152 1556 153 1673 153 2572 155 2487 131 2337 151 1674 151 2026 151 1894 151 1895 137 2798 137 2799 156 1804 131 2768 131 2768 151 3002 131 3001 151 3002 131 3001 151 2767 151 2767 125 1076 135 2940 119 2199 154 1805 137 1807 154 2834 154 2834 Page49 CMA 111380 NAME OF MATERIAL GUIDE# ID# Phosphorus, amorphous Phosphorus, amorphous, red Phosphorus, white, molten Phosphorus, white or yellow, dry or under water or in solution Phosphorus heptasulfide, free from yellow and white Phosphorus Phosphorus heptasulphide, free from yellow and white Phosphorus Phosphorus oxybromide Phosphorus oxybromide, molten Phosphorus oxybromide solid Phosphorus oxychloride Phosphorus pentabromide Phosphorus pentachloride Phosphorus pentafluoride Phosphorus pentafluoride, compressed Phosphorus pentasulfide, free from yellow and white Phosphorus Phosphorus pentasulphide, free from yellow and white Phosphorus Phosphorus pentoxide Phosphorus sesquisulfide, free from yellow and white Phosphorus Phosphorus sesquisulphide, free from yellow and white Phosphorus Phosphorus tribromide Phosphorus trichloride Phosphorus trioxide Phosphorus trisulfide, free from yellow and white Phosphorus Phosphorus trisulphide, free from yellow and white Phosphorus Phthalic anhydride Phthalimide derivative pesticide, liquid, flammable, poisonous Phthalimide derivative pesticide, liquid, flammable, toxic Phthalimide derivative pesticide, liquid, poisonous Phthalimide derivative pesticide, liquid, poisonous, flammable Phthalimide derivative pesticide, liquid, toxic Phthalimide derivative pesticide, liquid, toxic, flammable Phthalimide derivative pesticide, solid, poisonous Phthalimide derivative pesticide, solid, toxic Picolines Picric acid, wet, with not less than 10% water Picrite, wetted Pinane hydroperoxide alpha-Pinene Pinene (alpha) Pine oil Piperazine Piperidine Plastic molding material Plastic moulding compound Plastic, nitrocellulose-based, spontaneously combustible, n.o.s. Plastics, nitrocellulose-based, seif-heating, n.o.s. Poison 6, liquid, n.o.s. Poison B, solid, n.o.s. Poisonous gas, flammable, n.o.s. Poisonous gas, n.o.s. Poisonous liquid, corrosive, inorganic, n.o.s. Poisonous liquid, corrosive, inorganic, n.o.s. (inhalation Hazard Zone A) Poisonous liquid, corrosive, inorganic, n.o.s. (inhalation Hazard Zone B) Poisonous liquid, corrosive, n.o.s. Poisonous liquid, flammable, n.o.s. Poisonous liquid, flammable, n.o.s. 133 1338 133 1338 136 2447 136 1381 139 1339 139 1339 137 1939 137 2576 137 1939 137 1810 137 2691 137 1806 125 2198 125 2198 139 1340 139 1340 137 1807 139 1341 139 1341 137 1808 137 1809 157 2578 139 1343 139 1343 156 2214 131 2774 131 2774 151 3008 131 3007 151 3008 131 3007 151 2773 151 2773 130 2313 113 1344 113 1336 147 2162 127 2368 127 2368 129 1272 153 2579 132 2401 171 ... 171 3314 135 2006 135 2006 153 2810 154 2811 119 1953 123 1955 154 3289 154 3289 154 3289 154 2927 119 1953 131 2929 07/11/95 12:31 Page50 CMA 111381 NAME OF MATERIAL GUIDE* ID# Poisonous liquid, flammable, organic, n.o.s. Poisonous liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, flammable, organic, n.o.s. (inhalation Hazard Zone B) Poisonous liquid, inorganic, n.o.s. Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, n.o.s. Poisonous liquid, n.o.s. Poisonous liquid, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, organic, n.o.$. ~ Poisonous liquid, organic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, organic, n.o.$. (Inhalation Hazard Zone B) Poisonous liquid, oxidizing, n.o.s. Poisonous liquid, water-reactive, n.o.s. Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, which in contact with water emits flammable gases, n.o.s. Poisonous liquids, corrosive, n.o.s. (inhalation Hazard Zone A) Poisonous liquids, corrosive, n.o.s. (Inhalation Hazard Zone B) Poisonous liquids, flammable, n.o.s. (Inhalation Hazard Zone A) Poisonous liquids, flammable, n.o.s. (Inhalation Hazard Zone B) Poisonous liquids, oxidizing, n.o.$. (Inhalation Hazard Zone A) Poisonous liquids, oxidizing, n.o.s. (Inhalation Hazard Zone B) Poisonous liquids, which in contact wtttvwater emit flammable gases, n.o.s. (Inhalation Hazard Zone A) Poisonous liquids, which in contact with water emit flammable gases, n.o.s. (Inhalation Hazard Zone B) Poisonous solid, corrosive, inorganic, n.o.s. Poisonous solid, corrosive, n.o.s. Poisonous solid, flammable, n.o.s. Poisonous solid, flammable, organic, n.o.s. Poisonous solid, inorganic, n.o.s. Poisonous solid, n.o.s. Poisonous solid, organic, n.o.s. Poisonous solid, oxidizing, n.o.s. Poisonous solid, self-heating, n.o.s. Poisonous solid, water-reactive. n.o.s. Poisonous solid, which in contact with water emits flammable gases, n.o.s. Polyalkylamines, n.o.s. Polyalkylamines, n.o.s. Polyalkylamines, n.o.s. Polyamines, flammable, corrosive, n.o.s. Polyamines, liquid, corrosive, flammable, n.o.s. Polyamines, liquid, corrosive, n.o.s. Polyamines, solid, corrosive, n.o.s. Polychlorinated biphenyls Polyester resin kit Polyhalogenated biphenyls, liquid Polyhalogenated biphenyls, solid Polyhalogenated terphenyts, liquid Polyhalogenated terphenyls, solid Polymeric beads, expandable Polymerizable material, stabilized with dry ice 131 2929 131 2929 131 2929 151 3287 151 3287 151 3287 123 1955 153 2810 153 2810 153 2810 153 2810 153 2810 153 2810 142 3122 139 3123 139 3123 139 3123 139 3123 154 2927 154 2927 131 2929 131 2929 142 3122 142 3122 139 3123 139 3123 154 3290 154 2928 134 2930 134 2930 151 3288 154 2811 154 2811 141 3066 136 3124 139 3125 139 3125 132 2733 132 2734 153 2735 132 2733 132 2734 153 2735 154 3259 171 2315 146 2255 171 3151 171 3152 171 3151 171 3152 133 2211 171 _ 07/11/95 12:31 Page51 CMA 111382 NAME OF MATERIAL Polyester resin kit Polystyrene beads, expandable Potassium Potassium, metal Potassium, metal alloys Potassium, metal liquid alloy Potassium arsenate Potassium arsenite Potassium bifluoride Potassium bisulfite solution Potassium bisulphite solution Potassium borohydride Potassium bromate Potassium chlorate Potassium chlorate, aqueous solution Potassium chlorate, solution Potassium chromate Potassium cuprocyanide Potassium cyanide Potassium dichloro-s-triazinetrtone, dry Potassium dithionite Potassium fluoride Potassium fluoroacetate Potassium fluorosilicate Potassium hydrogendifluoride Potassium hydrogen fluoride, solution Potassium hydrogen sulfate Potassium hydrogen sulphate Potassium hydrosulfite Potassium hydrosulphite Potassium hydroxide, dry, solid Potassium hydroxide, flake Potassium hydroxide, solid Potassium hydroxide, solution Potassium metavanadate Potassium monoxide Potassium nitrate Potassium nitrate and Sodium nitrate mixture Potassium nitrate and Sodium nitrite mixture Potassium nitrite Potassium perchlorate Potassium permanganate Potassium peroxide Potassium persulfate Potassium persulphate Potassium phosphide Potassium selenate Potassium selenite Potassium sodium alloys Potassium sulfide, anhydrous Potassium sulfide, hydrated, with not less than 30% water of crystallization Potassium sulfide, hydrated, with not less than 30% water of hydration Potassium sulfide, with less than 30% water of crystallization Potassium sulfide, with less than 30% water of hydration Potassium sulphide, anhydrous GUIDE# ID* 127 3269 133 2211 138 2257 138 2257 138 1420 138 1420 151 1677 154 1678 154 1811 154 2693 154 2693 138 1870 140 1484 140 1485 140 2427 140 2427 171 9142 157 1679 157 1680 141 2465 135 1929 154 1812 151 2628 151 2655 154 1811 154 1811 154 2509 154 2509 135 1929 135 1929 154 1813 154 1813 154 1813 154 1814 151 2864 154 2033 140 1486 140 1499 140 1487 140 1488 140 1489 140 1490 144 1491 140 1492 140 1492 139 2012 151 2630 151 2630 138 1422 135 1382 153 1847 153 1847 135 1382 135 1382 135 1382 07/11/95 12:31 Page52 CMA 111383 NAME OF MATERIAL GUIDE* ID* Potassium sulphide, hydrated, with not less than 30% water of crystallization Potassium sulphide, hydrated, with not less than 30% water of hydration Potassium sulphide, with less than 30% water of crystallization Potassium sulphide, with less than 30% water of hydration Potassium superoxide Printing ink, flammable Propadiene, inhibited Propadiene and Methyl acetylene mixture, stabilized Propane Propane ~ Propane-Ethane mixture, refrigerated liquid Propane mixture Propane mixture Propanethiols n-Propanol Propargyl alcohol Propionaldehyde Propionic acid Propionic anhydride Propionitrile Propionyl chloride Propionyl peroxide n-Propyl acetate normal Propyl alcohol Propyl alcohol, normal Propylamine n-Propyl benzene Propyl chloride n-Propyl chloroformate Propylene Propylene Propylene, Ethylene and Acetylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with not more than 22.5% Acetylene and not more than 6% Propylene. Propylene chlorohydrin 1,2-Propylenediamine Propylene dichloride Propyleneimine, inhibited Propylene oxide Propylene oxide and Ethylene oxide mixture, with not more than 30% Ethylene oxide Propylene tetramer Propyl formates n-Propyl isocyanate Propyl mercaptan n-Propyl nitrate Propyttrichlorosilane Pyridine Pyrophoric alloy, n.o.s. Pyrophoric liquid, inorganic, n.o.s. Pyrophoric liquid, n.o.s. Pyrophoric liquid, organic, n.o.s. Pyrophoric metal, n.o.s. Pyrophoric organometaliic compound, n.o.s. Pyrophoric solid, inorganic, n.o.s. 153 153 135 135 143 129 116P 116P 115 115 115 115 115 130 129 131 129 132 156 131 132 146 129 129 129 132 127 129 155 115 115 1847 1847 1382 1382 2466 1210 2200 1060 1075 1978 1961 1075 1678 2402 1274 1986 1275 1848 2496 2404 1815 2132 1276 1274 1274 1277 2364 1278 2740 1075 1077 116 131 132 130 131P 127P 129P 128 129 155 130 131 155 129 135 135 136 136 135 135 135 3138 2611 2258 1279 1921 1280 2983 2850 1281 2482 2402 1865 1816 1282 1383 3194 2845 2845 1383 3203 3200 07/11/95 12:31 Pai CMA 111384 NAME OF MATERIAL Pyrophoric solid, n.o.s. Pyrophoric solid, organic, n.o.s. Pyrosulfuryi chloride Pyrosuiphuryl chloride Pyroxylin plastic, rod, sheet, roll, tube or scrap Pyrrolidine Quinoline Radioative material, articles manufactured from depleted uranium Radioactive material, articles manufactured from natural thorium Radioactive material, articles manufactured from natural uranium Radioactive material, empty packages ~ Radioactive material, excepted package, articles manufactured from depleted uranium Radioactive material, excepted package, articles manufactured from natural thorium Radioactive material, excepted package, articles manufactured from natural uranium Radioactive material, excepted package, empty packaging Radioactive material, excepted package, instruments or articles Radioactive material, excepted package, limited quantity of material Radioactive material, fissile, n.o.s. Radioactive material, instruments and articles Radioactive material, limited quantity, n.o.s. Radioactive material, low specific activity (LSA), n.o.s. Radioactive material, n.o.s. Radioactive material, special form, n.o.s. Radioactive material, surface contaminated objects (SCO) Radioactive material, Uranium hexafluoride, fissile Radioactive material, Uranium hexafluoride, non fissile or fissile excepted Rare gases and Nitrogen mixture Rare gases and Nitrogen mixture, compressed Rare gases and Oxygen mixture Rare gases and Oxygen mixture, compressed Rare gases mixture Rare gases mixture, compressed Receptacles, small, containing gas Red phosphorus Red phosphorus, amorphous Refrigerant gas, n.o.s. Refrigerant gas, n.o.s. (flammable) Refrigerant gas R-12 Refrigerant gas R-12 and Refrigerant gas R-152a azeotropic mixture with 74% Refrigerant gas R-12 Refrigerant gas R-12B1 Refrigerant gas R-13 Refrigerant gas R-13 and Refrigerant gas R-23 azeotropic mixture with 60% Refrigerant gas R-13 Refrigerant gas R-13B1 Refrigerant gas R-14, compressed Refrigerant gas R-21 Refrigerant gas R-22 Refrigerant gas R-23 Refrigerant gas R-23 and Refrigerant gas R-13 azeotropic mixture with 60% Refrigerant gas R-13 Refrigerant gas R-32 GUIDE# ID* 135 2846 135 2846 137 1817 137 1817 133 1325 132 1822 154 2656 161 2909 161 2908 161 2909 161 2908 161 2910 161 2910 161 2910 161 2910 161 2910 161 2910 165 2918 161 2911 161 2910 162 2912 163 2982 164 2974 162 2913 166 2977 166 2878 121 1981 121 1981 122 1980 122 1980 121 1979 121 1979 115 2037 133 1338 133 1338 126 1078 115 1954 126 1028 126 2602 126 1974 126 1022 126 2599 126 1009 126 1982 126 1029 126 1018 126 1984 126 2599 115 3252 07/11/95 12:31 Page54 CMA 111385 NAME OF MATERIA! GUIDE* IP* Refrigerant gas R-40 Refrigerant gas R-41 Refrigerant gas R-114 Refrigerant gas R-115 Refrigerant gas R-116, compressed Refrigerant gas R-124 Refrigerant gas R-125 Refrigerant gas R-133a Refrigerant gas R-134a 115 1063 115 2454 126 1958 126 1020 126 2193 126 1021 126 3220 126 1983 126 3159 Refrigerant gas R-142b Refrigerant gas R-143a 115 2517 ~ 115 2035 Refrigerant gas R?152 115 1030 Refrigerant gas R-152a and Refrigerant gas R-12 azeotropic mixture with 74% Refrigerant gas R-12 126 2602 Refrigerant gas R-161 Refrigerant gas R-218 115 2453 126 2424 Refrigerant gas R-227 126 3296 Refrigerant gas R-500 (azeotropic mixture of Refrigerant gas R-12 and Refrigerant gas R-152a with approximately 74% Refrigerant gas R-12) 126 2602 Refrigerant gas R-502 126 1973 Refrigerant gas R-503 (azeotropic mixture of Refrigerant gas R-13 and Refrigerant gas R-23 with approximately 60% Refrigerant gas R-13) 126 2599 Refrigerant gas R-1132a 116 1959 Refrigerant gas R-1216 126 1858 Refrigerant gas R-1318 126 2422 Refrigerant gas RC-318 126 1976 Refrigerating machine 128 1993 Refrigerating machines 115 8023 Refrigerating machines, containing Ammonia solutions (UN2073) 126 2857 Refrigerating machines, containing Ammonia solutions (UN2672) 126 2857 Refrigerating machines, containing flammable, liquefied gas 115 1954 Refrigerating machines, containing flammable, non-poisonous, non- corrosive, liquefied gas 115 1954 Refrigerating machines, containing non-flammable, liquefied gas 126 2857 Refrigerating machines, containing non-flammable, non-poisonous, liquefied gas 126 2857 Refrigerating machines, containing non-flammable, non-poisonous, non- corrosive. liquefied gases 126 2857 Refrigerating machines, containing non-flammable, non-toxic, liquefied gas 126 2857 Refrigerating machines, containing non-flammable, non-toxic, non- corrosive, liquefied gases 126 2857 Regulated medical waste, n.o.s. 158 3291 Regulated medical waste 158 9275 Resin solution 127 1866 Resorcinol 153 2876 Rosin oil 127 1286 Rubber scrap, powdered or granulated 133 1345 Rubber shoddy, powdered or granulated 133 1345 Rubber solution 127 1287 Rubidium 138 1423 Rubidium hydroxide 154 2678 Rubidium hydroxide, solid 154 2678 Rubidium hydroxide, solution 154 2677 Rubidium metal 138 1423 Seat-belt modules 171 3268 07/11/95 12:31 Page55 CMA 111386 NAME OF MATERIAL GUIDE# IP* Seat-belt pre-tensioners Seed cake, with more than 1.5% oil and not more than 11% moisture 171 3268 135 1386 Seed cake, with not more than 1.5% oil and not more than 11% moisture 135 2217 Selenates Selenic acid Selenites Selenium compound, n.o.s. 151 2630 154 1905 151 2630 151 3283 Selenium disulfide 153 2657 Selenium disulphide 153 2657 Selenium hexafluoride 125 2164 Selenium oxide 154 2811 Selenium oxychloride 157 2879 Selenium powder 152 2658 Self-heating liquid, corrosive, inorganic, n.o.s. 136 3188 Self-heating liquid, corrosive, organic, n.o.s. 136 3185 Self-heating liquid, inorganic, n.o.$. 135 3186 Self-heating liquid, organic, n.o.s. 135 3183 Self-heating liquid, poisonous, inorganic, n.o.s. 136 3187 Self-heating liquid, poisonous, organic, n.o.s. 136 3184 Self-heating liquid, toxic, inorganic, n.o.s. 136 3187 Self-heating liquid, toxic, organic, n.o.s. 136 3184 Self-heating metal powders, n.o.s. 135 3186 Self-heating solid, corrosive, inorganic, n.o.s. 136 3192 Self-heating solid, corrosive, organic, n.o.$. 136 3126 Self-heating solid, inorganic, n.o.s. 135 3190 Self-heating solid, inorganic, poisonous, n.o.$. 136 3191 Self-heating solid, inorganic, toxic, n.o.s. 136 3191 Self-heating solid, organic, n.o.s. 135 3088 Self-heating solid, organic, poisonous, n.o.s. 136 3128 Self-heating solid, organic, toxic, n.o.s. 136 3128 Self-heating solid, oxidizing, n.o.s. 135 3127 Self-heating solid, poisonous, inorganic, n.o.s. 136 3191 Self-heating solid, poisonous, organic, n.o.s. 136 3128 Self-heating solid, toxic, inorganic, n.o.s. 136 3191 Self-heating solid, toxic, organic, n.o.s. 136 3128 Self-heating substance, solid, corrosive, n.o.s. 136 3126 Self-heating substances, solid, n.o.s. 135 3088 Self-heating substances, solid, oxidizing, n.o.s. 135 3127 Self-heating substances, solid, poisonous, n.o.s. 136 3128 Self-heating substances, solid, toxic, n.o.s. 136 3128 Self-reactive liquid type B 149 3221 Self-reactive liquid type B, temperature controlled 150 3231 Self-reactive liquid type C 149 3223 Self-reactive liquid type C, temperature controlled 150 3233 Self-reactive liquid type D 149 3225 Self-reactive liquid type D, temperature controlled 150 3235 Self-reactive liquid type E 149 3227 Self-reactive liquid type E, temperature controlled 150 3237 Self-reactive liquid type F 149 3226 Self-reactive liquid type F, temperature controlled 150 3239 Self-reactive solid type B 149 3222 Self-reactive solid type B, temperature controlled Self-reactive solid type C Self-reactive solid type C, temperature controlled 150 3232 149 3224 150 3234 Self-reactive solid type D 149 3226 Self-reactive solid type D, temperature controlled 150 3236 07/11/95 12:31 Page56 CMA 111387 NAME OF MATERIAL GUIDE# ID# Self-reactive solid type E Self-reactive solid type E, temperature controlled Self-reactive solid type F Self-reactive solid type F, temperature controlled Self-reactive substances, samples, n.o.s. Self-reactive substances, trial quantities, n.o.s. Shale oil Silane Silane, compressed Silicon powder, amorphous Silicon tetrachloride ~ Silicon tetrafiuoride Silicon tetrafiuoride, compressed Silver arsenite Silver cyanide Silver nitrate Silver picrate, wetted with not less than 30% water Sludge acid Smokeless powder for small arms Smokeless powder for small arms Soda lime, with more than 4% Sodium hydroxide Sodium Sodium aluminate, solid Sodium aluminate, solution Sodium aluminum hydride Sodium ammonium vanadate Sodium arsanilate Sodium arsenate Sodium arsenite, aqueous solution Sodium arsenite, solid Sodium azide Sodium bifluoride, solid Sodium bifluoride, solution Sodium bisulfate, solid Sodium bisulfate, solution Sodium bisulphate, solid Sodium bisulphate, solution Sodium borohydride Sodium borohydride and Sodium hydroxide solution, with not more than 12% Sodium borohydride and not more than 40% Sodium hydroxide Sodium bromate Sodium cacodylate Sodium chlorate Sodium chlorate, aqueous solution Sodium chlorite Sodium chlorite, solution, with more than 5% available Chlorine Sodium chloroacetate Sodium chromate Sodium cuprocyanide, solid Sodium cuprocyanide, solution Sodium cyanide Sodium 2-diazo-1-naphthol-4-sulfonate Sodium 2-diazo-1-naphthol-4-sulphonate Sodium 2-diazo-i-naphthol-5-sulfonate Sodium 2-diazo-l-naphthol-5-sulphonate Sodium dichloroisocyanurate 149 150 149 150 149 149 ' 128 116 116 170 156 125 125 151 151 140 113 153 133 133 154 138 154 154 138 154 154 151 154 151 153 154 154 154 154 154 154 138 157 141 152 140 140 143 154 151 171 157 157 157 149 149 149 149 141 3228 3238 3230 3240 3031 3032 1288 2203 2203 1346 1818 1859 1859 1683 1684 1493 1347 1906 1325 3178 1907 1428 2812 1819 2835 2863 2473 1685 1686 2027 1687 2439 2439 1821 2837 1821 2837 1426 3320 1494 1688 1495 2428 1496 1908 2659 9145 2316 2317 1689 3040 3040 3041 3041 2465 07/11/95 12:31 Page57 NAME OF MATERIAL Quips* m* Sodium dichloro*s-triazinetrione Sodium dinitro-o-cresolate, wetted with not less than 15% water Sodium dinitro-ortho-cresolate, wetted Sodium dithionite Sodium dodecylbenzenesulfonate (branched chain) Sodium dodecylbenzenesulphonate (branched chain) Sodium fluoride Sodium fluoride, solid Sodium fluoride, solution Sodium fluoroacetate Sodium fluorosiiicate -- Sodium hydride Sodium hydrogendifluoride Sodium hydrogen fluoride Sodium hydrogen sulfate, solid Sodium hydrogen sulfate, solution Sodium hydrogen sulphate, solid Sodium hydrogen sulphate, solution Sodium hydrosulflde, solid Sodium hydrosulflde, solid, with less than 25% water of crystallization Sodium hydrosulflde, solution Sodium hydrosulflde, with less than 25% water of crystallization Sodium hydrosulflde, with not less than 25% water of crystallization Sodium hydrosuKite Sodium hydrosulphide, solid Sodium hydrosulphide, solid, with less than 25% water of crystallization Sodium hydrosulphide, solution Sodium hydrosulphide, with less than 25% water of crystallization Sodium hydrosulphide, with not less than 25% water of crystallization Sodium hydrosulphite Sodium hydroxide, dry Sodium hydroxide, bead Sodium hydroxide, flake Sodium hydroxide, granular Sodium hydroxide, solid Sodium hydroxide, solution Sodium methylate Sodium methylate, alcohol mixture Sodium methylate, dry Sodium methylate, solution in alcohol Sodium monoxide Sodium nitrate Sodium nitrate and Potassium nitrate mixture Sodium nitrite Sodium nitrite and Potassium nitrate mixtures Sodium nitrite mixture Sodium pentachlorophenate Sodium percarbonates Sodium perchlorate Sodium permanganate Sodium peroxide Sodium peroxoborate, anhydrous Sodium persulfate Sodium persulphate Sodium phenolate, solid Sodium phosphate, dibasic 141 2465 113 1348 113 1348 135 1384 171 8146 171 8146 154 1680 154 1680 154 1680 151 2628 154 2674 138 1427 154 2438 154 2438 154 1821 154 2837 154 1821 154 2837 154 2823 135 2318 153 2822 135 2318 154 2848 135 1384 154 2823 135 2318 153 2822 135 2318 154 2848 135 1384 154 1823 154 1823 154 1823 154 1823 154 1823 154 1824 138 1431 132 1288 138 1431 132 1288 157 1825 140 1488 140 1489 140 1500 140 1487 140 1487 154 2567 140 2467 140 1502 140 1503 144 1504 140 3247 140 1505 140 1505 153 2497 171 8147 07/11/95 12:31 Page58 CMA 111389 MMEOTMMEMAi Sodium phosphate, tribasic Sodium phosphide Sodium picramate, wetted with not less than 20% water Sodium potassium alloys Sodium selenite Sodium sulfide, anhydrous Sodium sulfide, hydrated, with not less than 30% water Sodium sulfide, with less than 30% water of crystallization Sodium sulphide, anhydrous Sodium sulphide, hydrated, with not less than 30% water Sodium sulphide, ^th less than 30% water of crystallization ~ Sodium superoxide Solids containing corrosive liquid, n.o.s. Solids containing flammable liquid, n.o.s. Solids containing poisonous liquid, n.o.s. Solids containing toxic liquid, n.o.s. Spirits of nitroglycerin, not exceeding 1 % nitroglycerin Stannic chloride, anhydrous Stannic chloride, pentahydrate Stannic phosphides Stannous chloride, solid Steel swarf Stibine Straw, wet, damp or contaminated with oil Strontium arsenite Strontium chlorate Strontium chlorate, solid Strontium chlorate, solution Strontium chromate Strontium nitrate Strontium perchlorate Strontium peroxide Strontium phosphide Strychnine Strychnine salts Styrene monomer, inhibited Substances, which in contact with water emit flammable gases, liquid, corrosive, n.o.s. . Substances, which in contact with water emit flammable gases, liquid, n.o.s. Substances, which in contact with water emit flammable gases, liquid, poisonous, n.o.s. Substances, which in contact with water emit flammable gases, liquid, toxic, n.o.s. Substances, which in contact with water emit flammable gases, solid, corrosive, n.o.s. Substances, which in contact with water emit flammable gases, solid, flammable, n.o.s. Substances, which in contact with water emit flammable gases, solid, n.o.s. Substances, which in contact with water emit flammable gases, solid, oxidizing, n.o.s. Substances, which in contact with water emit flammable gases, solid, poisonous, n.o.s. Substances, which in contact with water emit flammable gases, solid, self-heating, n.o.s. 07/11/95 12:31 guide# id# 171 139 113 138 151 135 153 135 135 153 135 143 154 133 151 151 127 137 154 139 154 170 119 133 151 143 143 143 171 140 140 143 139 151 151 128P 9148 1432 1349 1422 2630 1385 1849 1385 1385 1849 1385 2547 3244 3175 3243 3243 1204 1827 2440 1433 1759 2793 2676 1327 1691 1506 1506 1506 9149 1507 1508 1509 2013 1692 1692 2055 138 3129 138 3148 139 3130 139 3130 138 3131 138 3132 138 2813 138 3133 139 3134 138 3135 Page59 CMA 111390 NAME OF MATERIAL Substances, which in contact with water emit flammable gases, solid, toxic, n.o.s. Substituted nitrophenol pesticide, liquid, flammable, poisonous Substituted nitrophenol pesticide, liquid, flammable, toxic Substituted nitrophenol pesticide, liquid, poisonous Substituted nitrophenol pesticide, liquid, poisonous, flammable Substituted nitrophenol pesticide, liquid, toxic Substituted nitrophenol pesticide, liquid, toxic, flammable Substituted nitrophenol pesticide, solid, poisonous Substituted nitrophenol pesticide, solid, toxic Succinic acid peroxide ~ Sulfamic acid Sulfur Sulfur, molten Sulfur chlorides Sulfur dioxide Sulfur dioxide, liquefied Sulfur hexafluoride Sulfuric acid Sulfuric acid, fuming Sulfuric acid, fuming, with less than 30% free Sulfur trioxide Sulfuric acid, fuming, with not less than 30% free Sulfur trioxide Sulfuric acid, spent Sulfuric acid, with more than 51% acid Sulfuric acid, with not more than 51% acid Sulfuric acid and Hydrofluoric acid mixtures Sutfurous acid Sulfur tetrafluoride Sulfur trioxide Sulfur trioxide, inhibited Sulfur trioxide, stabilized Sulfur trioxide, uninhibited Sulfur trioxide and Chlorosulfonic acid mixture Sulfuryl chloride Sulfuryl fluoride Sulphamic acid Sulphur Sulphur, molten Sulphur chlorides Sulphur dioxide Sulphur dioxide, liquefied Sulphur hexafluoride Sulphuric acid Sulphuric acid, fuming Sulphuric acid, fuming, with less than 30% free Sulphur trioxide Sulphuric acid, fuming, with not less than 30% free Sulphur trioxide Sulphuric acid, spent Sulphuric acid, with more than 51% acid Sulphuric acid, with not more than 51% acid Sulphuric acid and Hydrofluoric acid mixtures Sulphurous acid Sulphur tetrafluoride Sulphur trioxide Sulphur trioxide, inhibited Sulphur trioxide, stabilized Sulphur trioxide, uninhibited 07/11/95 12:31 GUIDE.!--ID.* 139 3134 131 2780 131 2780 153 3014 131 3013 153 3014 131 3013 153 2779 153 2779 146 2135 154 2967 133 1350 133 2448 137 1828 125 1079 125 1079 126 1080 137 1830 137 1831 137 1831 137 1831 137 1832 137 1830 157 2796 157 1786 154 1833 125 2418 137 1829 137 1829 137 1829 137 1829 137 1754 137 1834 123 2191 154 2967 133 1350 133 2448 137 1828 125 1079 125 1079 126 1080 137 1830 137 1831 137 1831 137 1831 137 1832 137 1830 157 2796 157 1786 154 1833 125 2418 137 1829 137 1829 137 1829 137 1829 page60 CMA 111391 NAME OF MATERIAL GUIDE# IP# Sulphur trioxide and Chlorosulphonic acid mixture Sulphuryl chloride Sulphuryl fluoride Tars, liquid TDE (1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane) Tear gas candles Tear gas devices Tear gas substance, liquid, n.o.s. Tear gas substance, solid, n.o.s. Tellurium compound, n.o.s. Tellurium hexafluoride ~ Terpene hydrocarbons, n.o.s. Terpinolene Tetrabromoethane Tetrachloroethane Tetrachloroethylene Tetraethyl dithiopyrophosphate Tetraethyl dithiopyrophosphate, mixture, dry or liquid Tetraethyl dithiopyrophosphate and gases, in solution Tetraethyl dithiopyrophosphate and gases, mixtures Tetraethyl dithiopyrophosphate and gases, mixtures, or in solution (LC50 more than 200 ppm but not more than 5000 ppm) Tetraethyl dithiopyrophosphate and gases, mixtures, or in solution (LC50 not more than 200 ppm) Tetraethylenepentamine Tetraethyl lead, liquid Tetraethyl pyrophosphate, liquid Tetraethyl pyrophosphate, solid Tetraethyl pyrophosphate, liquid Tetraethyl pyrophosphate and compressed gas mixtures Tetraethyl pyrophosphate and compressed gas mixtures (LC50 more than 200 ppm but not more than 5000 ppm) Tetraethyl pyrophosphate and compressed gas mixtures (LC50 not more than 200 ppm) Tetraethyl pyrophosphate mixture, dry Tetraethyl silicate 1,1,1,2-Tetrafiuoroethane Tetrafluoroethane and Ethylene oxide mixture, with not more than 5.6% Ethylene oxide Tetrafluoroethylene, inhibited Tetrafluoromethane Tetrafluoromethane, compressed 1,2,3,6-Tetrahydrobenzaldehyde Tetrahydrofuran Tetrahydrofurfurylamine Tetrahydrophthalic anhydrides 1,2,3,6-Tetrahydropyridine Tetrahydrothiophene Tetralin hydroperoxide Tetramethylammonium hydroxide 1,1,3,3-Tetramethylbutyl hydroperoxide 1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate Tetramethylmethylenediamine Tetramethytsilane Tetranitromethane Tetrapropylorthotitanate 137 137 123 130 151 156 159 159 156 151 125 128 128 159 151 160 153 153 123 123 123 123 153 131 152 152 152 123 123 123 152 132 126 126 116P 126 126 132 127 129 156 129 129 145 153 145 148 132 130 143 128 1754 1634 2191 1696 2761 1700 1693 1693 1663 3284 2195 2319 2541 2504 1702 1897 1704 1704 1703 1703 1703 1703 2320 1646 3018 2783 2783 1705 1705 1705 2783 1292 3159 3299 1081 1982 1982 2498 2056 2943 2698 2410 2412 2136 1835 2160 2161 9069 2749 1510 2413 07/11/95 12:31 Page61 CMA 111392 NAME OF MATERIAL GUIDE* ID* Textile treating compound or mixture, liquid (corrosive) Thallium chlorate Thallium compound, n.o.s. Thallium nitrate Thallium sulfate, solid Thallium sulphate, solid 4-Thiapentana! Thia-4-pentanal Thioacetic acid Thioglycol Thioglycolic acid Thiolactic acid Thionyl chloride Thiophene Thiophosgene Thiophosphoryl chloride Thiram Thorium metal, pyrophoric Thorium nitrate, solid Tinctures, medicinal Tin tetrachloride Tin tetrachloride, pentahydrate Titanium disulfide Titanium disulphide Titanium hydride Titanium powder, dry Titanium powder, wetted with not less than 25% water Titanium sponge granules Titanium sponge powders Titanium sulfate, solution Titanium sulphate, solution Titanium tetrachloride Titanium tetrachloride and Vanadium oxytrichloride, mixture Titanium trichloride, pyrophoric Titanium trichloride mixture Titanium trichloride mixture, pyrophoric TNT, wetted with not less than 30% water Toe puffs, nitrocellulose base Toluene 2,4-Toluenediamine Toluenediamine Toluene diisocyanate Toluene sulfonic acid, liquid, with more than 5% free Sulfuric acid Toluene sulfonic acid, liquid, with not more than 5% free Sulfuric acid Toluene sulfonic acid, solid, with more than 5% free Sulfuric add Toluene sulfonic add, solid, with not more than 5% free Sulfuric add Toluene sulphonic add, liquid, with more than 5% free Sulphuric add Toluene sulphonic add, liquid, with not more than 5% free Sulphuric add Toluene sulphonic add, solid, with more than 5% free Sulphuric add Toluene sulphonic acid, solid, with not more than 5% free Sulphuric add Toluidines Toluidines, liquid Toluidines, solid 2,4-Toluylenediamine Toxaphene 07/11/95 12:31 154 1760 141 2573 151 1707 141 2727 151 1707 151 1707 152 2785 152 2785 129 2436 153 2966 153 1940 153 2936 137 1836 130 2414 157 2474 157 1837 151 2771 162 2975 162 2976 127 1293 137 1827 154 2440 135 3174 135 3174 170 1871 135 2546 170 1352 170 2878 170 2878 157 1760 157 1760 137 1838 137 2443 135 2441 157 2866 135 2441 113 1356 133 1353 130 1294 151 1709 151 1709 156 2078 153 2584 153 2586 153 2583 153 2585 153 2584 153 2586 153 2583 153 2585 153 1708 153 1708 153 1708 151 1709 151 2761 CMA 111393 page62 NAME OF MATERIAL Toxic liquid, corrosive', inorganic, n.o.s. Toxic liquid, corrosive, inorganic, n.o.s. (inhalation Hazard Zone A) Toxic liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, corrosive, organic, n.o.s. Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, flammable, n.o.s. Toxic liquid, flammable, organic, n.o.s. Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, inorganic, n.o.s. ~ Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, n.o.s. (inhalation Hazard Zone A) Toxic liquid, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, n.o.s. Toxic liquid, organic, n.o.s. Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, oxidizing, n.o.s. Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, water-reactive, n.o.$. Toxic liquid, water-reactive, n.o.$. (Inhalation Hazard Zone A) Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, which in contact with water emits flammable gases, n.o.$. Toxic liquids, flammable, n.o.s. (Inhalation Hazard Zone A) Toxic liquids, which in contact with water emit flammable gases, n.o.s. (Inhalation Hazard Zone A) Toxic liquids, flammable, n.o.s. (Inhalation Hazard Zone B) Toxic liquids, which in contact with water emit flammable gases, n.o.s. (Inhalation Hazard Zone B) Toxic solid, corrosive, inorganic, n.o.s. Toxic solid, corrosive, organic, n.o.s. Toxic solid, flammable, n.o.s. Toxic solid, flammable, organic, n.o.s. Toxic solid, inorganic, n.o.s. Toxic solid, n.o.s. Toxic solid, organic, n.o.s. Toxic solid, oxidizing, n.o.s. Toxic solid, self-heating, n.o.s. Toxic solid, water-reactive, n.o.s. Toxic solid, which in contact with water emits flammable gases, n.o.s. Toxins, extracted from living sources, n.o.s. Triallylamine Triallyl borate Triazine pesticide, liquid, flammable, poisonous Triazine pesticide, liquid, flammable, toxic Triazine pesticide, liquid, poisonous Triazine pesticide, liquid, poisonous, flammable Triazine pesticide, liquid, toxic Triazine pesticide, liquid, toxic, flammable Triazine pesticide, solid, poisonous Triazine pesticide, solid, toxic Tri-(l-aziridinyl)phosphine oxide, solution Tributylamine 07/11/95 12:31 guide* n> 154 3289 154 3289 154 3289 154 2927 154 2927 154 2927 131 2929 131 2929 131 2929 131 2929 151 3287 151 3287 151 3287 153 2810 153 2810 153 2810 153 2810 153 2810 153 2810 142 3122 142 3122 142 3122 139 3123 139 3123 139 3123 139 3123 131 2929 139 3123 131 2929 139 3123 154 3290 154 2928 134 2930 134 2930 151 3288 154 2811 154 2811 141 3086 136 3124 139 3125 139 3125 153 3172 132 2610 156 2609 131 2764 131 2764 151 2998 131 2997 151 2998 131 2997 151 2763 151 2763 152 2501 153 2542 CMA 111394 Page63 NAME OF MATERIAL Tributylphosphane Tributylphosphine Trichlorfon Trichloroacetic acid Trichloroacetic acid, solution Trichloroacetyl chloride Trichlorobenzenes, liquid Trichlorobutene 1,1,1-Trichloroethane Trichloroethylene Trichloroisocyanuric acid, dry ~ Trichlorophenol 2,4,5-Trichlorophenoxyacetic acid 2,4,5-Triehlorophenoxypropionie acid Trichlorosilane Trichloro-s-triazinetrione, dry (mono)>(TrichloroHetra-(monopotassium dichloro>-penta-s- triazinetrione, dry Tricresyl phosphate Triethanolamine dodecytbenzenesulfonate Triethanolamine dodecylbenzenesulphonate Triethylamine Triethylenetetramine Triethyl phosphite Trifluoroacetic acid Trifluoroacetyl chloride Trifiuorochloroethylene Trifluorochloroethylene, inhibited Trifluoroethane, compressed 1,1,1-Trifluoroethane Trifluoromethane Trifluoromethane, refrigerated liquid Trifluoromethane and Chlorotrifluoromethane azeotropic mbcture with approximately 60% Chlorotrifluoromethane 2-Trifluoromethylaniline 3-Trifluoromethylaniline Triisobutylene Triisocyanatoisocyanurate of Isophoronediisocyanate, solution (70%) Triisopropyl borate Trimethoxysiiane Trimethylacetyl chloride Trimethylamine, anhydrous Trirnethylamine, aqueous solution 1,3,5-Trimethylbenzene Trimethyl borate Trimethylchlorosilane Trimethylcyclohexylamine Trimethylhexamethyienediamines Trimethylhexamethyiene diisocyanate Trimethyl phosphite Trinitroaniline, wetted Trinitrobenzene, wetted with not less than 30% water Trinitrobenzoic acid, wetted with not less than 30% water Trinitrophenol, wetted with not less than 30% water Trinitrotoluene, wetted with not less than 30% water Tripropylamine 07/11/95 12:31 GUIDE# IP* 135 3254 135 3254 152 2783 153 1839 153 2564 156 2442 153 2321 152 2322 160 2831 160 1710 141 2468 153 2020 152 2765 152 2765 139 1295 141 2468 141 151 171 171 132 153 126 154 125 119P 119P 115 115 126 120 2468 2574 9151 9151 1296 2259 2323 2699 3057 1082 1082 2035 2035 1684 3136 126 2599 153 2942 153 2948 128 2324 127 2906 129 2616 132 9269 132 2438 118 1083 132 1297 129 2325 126 2416 155 1298 153 2326 153 2327 156 2328 129 2329 113 9073 113 1354 113 1355 113 1344 113 1356 132 2260 CMA 111395 Page64 NAME OF MATERIAL Tripropylene Tris-(1-aziridinyl)phosphine oxide, solution Tungsten hexafluoride Turpentine Turpentine substitute Undecane Uranium hexafluoride, fissile containing more than 1% Uranium-235 Uranium hexafluoride, fissile excepted Uranium hexafluoride, low specific activity Uranium hexafluoride, non-fissile Uranium metal, pyrophoric Uranyl acetate Uranyl nitrate, hexahydrate, solution Uranyl nitrate, solid Urea hydrogen peroxide Urea nitrate, wetted with not less than 20% water Urea peroxide Valeraldehyde Valeryl chloride Vanadium compound, n.o.s. Vanadium oxytrichloride Vanadium oxytrichloride and Titanium tetrachloride, mixture Vanadium pentoxide Vanadium tetrachloride Vanadium trichloride Vanadium trioxide Vanadyl sulfate Vanadyl sulphate Vinyl acetate Vinyl acetate, inhibited Vinyl bromide, inhibited Vinyl butyrate, inhibited Vinyl chloride Vinyl chloride, inhibited Vinyl chloride, stabilized Vinyl chloroacetate Vinyl ethyl ether Vinyl ethyl ether, inhibited Vinyl fluoride, inhibited Vinylidene chloride, inhibited Vinyl isobutyl ether Vinyl isobutyl ether, inhibited Vinyl methyl ether Vinyl methyl ether, inhibited Vinylpyridines, inhibited Vinyttoluene, inhibited Vinyttrichlorosilane Vinyltrichlorosilane, inhibited Waste Type 1 Waste Type 2 Waste Type 3 Waste Type 4 Waste Type 5 Waste Type 6 Waste Type 7 Waste Type 8 07/11/95 12:31 GUIDES B># 128 152 125 128 128 128 166 166 166 166 162 162 162 162 140 113 140 129 132 151 137 137 151 137 157 154 151 151 129P 129P 116P 129P 116P 116P 116P 155 127P 127P 116P 129P 127P 127P 116P 116P 131P 130P 155 155 153 153 131 153 131 154 154 153 2057 2501 2196 1299 1300 2330 2977 2978 2978 2978 2979 9180 2980 2981 1511 1357 1511 2058 2502 3285 2443 2443 2862 2444 2475 2860 2931 2931 1301 1301 1085 2838 1086 1086 1086 2589 1302 1302 1860 1303 1304 1304 1087 1087 3073 2618 1305 1305 9301 9302 9303 9304 9305 9306 9307 9308 ' CMA 111396 Page65 NAME OF MATERIAL Waste Type 9 Waste Type 10 Waste Type 11 Waste Type 12 Waste Type 13 Waste Type 14 Waste Type IS Waste Type 16 Waste Type 17 Waste Type 18 Waste Type 18 Waste Type 20 Waste Type 21 Waste Type 22 Waste Type 23 Waste Type 24 Waste Type 25 Waste Type 26 Waste Type 27 Waste Type 28 Waste Type 29 Waste Type 30 Waste Type 31 Waste Type 32 Waste Type 33 Waste Type 34 Waste Type 35 Waste Type 36 Waste Type 37 Waste Type 38 Waste Type 39 Waste Type 40 Waste Type 41 Waste Type 42 Waste Type 43 Waste Type 44 Waste Type 45 Waste Type 46 Waste Type 47 Waste Type 48 Waste Type 49 Waste Type 50 Waste Type 51 Waste Type 52 Waste Type 53 Waste Type 54 Waste Type 55 Waste Type 56 Waste Type 57 Waste Type 58 Waste Type 59 Waste Type 60 Waste Type 61 Waste Type 62 Waste Type 63 Waste Type 64 07/11/95 12:31 GUIDE# IP* 153 9309 153 9310 153 9311 153 9312 153 9313 153 9314 153 9315 154 9316 154 9317 154 9318 154 9319 154 9320 154 9321 154 9322 154 9323 152 9324 127 9325 152 9326 131 9327 131 9328 153 9329 153 9330 129 9331 129 9332 129 9333 129 9334 153 9335 153 9336 153 9337 153 9338 153 9338 153 9340 132 9341 129 9342 154 9343 132 9344 132 9345 153 9346 132 9347 153 9348 153 9349 153 9350 153 9351 153 9352 153 9353 153 9354 153 9355 153 9356 153 9357 153 9358 151 9359 132 9360 151 9361 151 9362 151 9363 151 9364 CMA 111397 Page66 NAME OF MATERIAL Waste Type 65 Waste Type 66 Waste Type 67 Waste Type 68 Waste Type 69 Waste Type 70 Waste Type 71 Waste Type 72 Waste Type 73 Waste Type 74 Waste Type 75 Waste Type 76 Waste Type 77 Waste Type 76 Waste Type 79 Waste Type 80 Waste Type 81 Waste Type 82 Waste Type 83 Waste Type 84 Waste Type 85 Waste Type 86 Waste Type 87 Waste Type 88 Waste Type 89 Waste Type 90 Waste Type 91 Waste Type 92 Waste Type 93 Waste Type 94 Waste Type 95 Waste Type 96 Waste Type 97 Waste Type 99 Waste Type 100 Water pump system Water-reactive liquid, corrosive, n.o.s. Water-reactive liquid, n.o.s. Water-reactive liquid, poisonous, n.o.s. Water-reactive liquid, toxic, n.o.s. Water-reactive solid, corrosive, n.o.s. Water-reactive solid, flammable, n.o.s. Water reactive solid, n.o.s. Water reactive solid, oxidizing, n.o.s. Water-reactive solid, poisonous, n.o.s. Water reactive solid, self-heating, n.o.s. Water-reactive solid, toxic, n.o.s. Water-reactive substances, liquid, corrosive, n.o.s. Water-reactive substances, liquid, n.o.s. Water-reactive substances, liquid, poisonous. n.o.s. Water-reactive substances, liquid, toxic, n.o.s. Water-reactive substances, solid, corrosive, n.o.s. Water-reactive substances, solid, flammable, n.o.s. Water-reactive substances, solid, n.o.s. Water-reactive substances, solid, oxidizing, n.o.s. Water-reactive substances, solid, poisonous, n.o.s. 07/11/95 12:31 CITTPE# ID* 151 9365 151 9366 152 9367 154 9368 151 9369 151 9370 133 9371 151 9372 151 9373 127 9374 - 153 9375 . 153 9376 131 9377 153 9378 153 9379 151 9380 154 9381 154 9382 154 9383 151 9384 154 9385 154 9386 154 9387 151 9388 154 9389 154 9390 153 9391 154 9392 153 9393 151 9394 153 9395 151 9396 153 9397 137 9399 137 9400 126 1956 138 3129 138 3148 139 3130 139 3130 138 3131 138 3132 138 2813 138 3133 139 3134 138 3135 139 3134 138 3129 138 3148 139 3130 139 3130 138 3131 138 3132 138 2813 138 3133 139 3134 CMA 111398 Page67 NAME OF MATERIAL Water-reactive substances, solid, self-heatinQ, n.o.s. Water-reactive substances, solid, toxic, n.o.s. Wheelchair, electric, with batteries White asbestos White phosphorus, dry White phosphorus, in solution White phosphorus, molten White phosphorus, under water Wood .preservatives, liquid Xenon Xenon, compressed Xenon, refrigerated liquid (cryogenic liquid) Xylenes Xylenols Xylidines Xylyl bromide Yellow phosphorus, dry Yellow phosphorus, in solution Yellow phosphorus, molten Yellow phosphorus, under water Zinc acetate Zinc ammonium chloride Zinc ammonium nitrite Zinc arsenate Zinc arsenate and Zinc arsenite mixture Zinc arsenite Zinc arsenite and Zinc arsenate mixture Zinc ashes Zinc bisulfite solution Zinc bisulphite solution Zinc borate Zinc bromate Zinc bromide Zinc carbonate Zinc chlorate Zinc chloride, anhydrous Zinc chloride, solution Zinc cyanide Zinc dithionite Zinc dust Zinc fluoride Zinc fluorosilicate Zinc formate Zinc hydrosulfite Zinc hydrosulphite Zinc nitrate Zinc permanganate Zinc peroxide Zinc phenoisulfonate Zinc phenolsulphonate Zinc phosphide Zinc powder Zinc resinate Zinc selenate Zinc selenite Zinc sulfate 07/11/95 12:31 QyiPF* 138 3135 139 3134 154 3171 171 2590 136 1381 136 1381 136 2447 136 1381 129 1306 121 2036 121 2036 120 2591 130 1307 153 2261 153 1711 152 1701 136 1381 136 1381 136 2447 136 1381 171 9153 171 9154 140 1512 151 1712 151 1712 151 1712 151 1712 138 1435 154 2693 154 2693 171 9155 140 2469 171 9156 171 9157 140 1513 154 2331 154 1840 151 1713 171 1931 138 1436 151 9158 151 2855 171 0159 171 1931 171 1631 140 1514 140 1515 143 1516 171 9160 171 9160 139 1714 138 1436 133 2714 151 2630 151 2630 171 9161 CMA 111399 Page68 NAME OF MATERIAL Zinc sulphate Zirconium, dry, coiled wire, finished metal sheets or strips Zirconium, dry, finished sheets, strips or coiled wire Zirconium hydride Zirconium metal, liquid, suspension Zirconium metal, powder, wet Zirconium nitrate Zirconium pieramate, wetted with not less than 20% water Zirconium potassium fluoride Zirconium powder, dry Zirconium powder, wetted with not less than 25% water Zirconium scrap Zirconium sulfate Zirconium sulphate Zirconium suspended in a flammable liquid Zirconium suspended in a liquid (flammable) Zirconium tetrachloride GUIDE# ID* 171 0161 170 2858 135 2009 138 1437 170 1308 170 1358 140 2728 113 1517 171 9162 135 2008 170 1358 135 1932 171 9163 171 9163 170 1308 170 1308 137 2503 07/11/95 12:31 CMA 111400 Page69 Sheetl Go\oe Vv< Stop all traffic and clear the area for at least 500 m in all directions and let bum. Do not move cargo or vehicle if cargo has been exposed to heat. TIRE or VEHICLE Fires: Use plenty of water - FLOOD itl If water is not available, use C02, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 m OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF. EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID Move victim to fresh air. Call emergency medical care Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, flush skin or eyes with running water for at least 15 minutes. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. SUPPLEMENTAL INFORMATION Packages bearing the 1.4S label contain explosive substances or articles that are designed or packaged in such a manner that when involved in a fire, may bum vigorously with localized detonations and projection of fragments. Effects are usually confined to immediate vicinity of packages. If fire threatens cargo area containing packages bearing the 1,4S label, consider initial isolation of at least 15 m (50 feet) in all directions. Fight fire with normal precautions from a reasonable distance. 11> GASES - FLAMMABLE - INCLUDING CRYOGENICS POTENTIAL HAZARDS FIRE OR EXPLOSION EXTREMELY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapo(u)rs from liquefied gas are initially heavier than air. Vapo(u)rs may travel to source of ignition and flash back. Containers may explode when heated. Ruptured cylinders may rocket. HEALTH Vapo(u)rs may cause dizziness or asphyxiation without warning. Some may be irritating in high concentrations. Contact with liquefied gas may cause bums, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50-100 m in all directions. Keep unauthorized personnel away. Stay upwind. Page 5 CMA 111401 Sheetl PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. Always wear thermal protective clothing when handling cryogenic liquids. EVACUATION Large Spill Consider initial downwind evacuation for at least 800 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (% mile) in all directions. EMERGENCY RESPONSE FIRE DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires: Dry chemical or C02. Large Fires: Water spray or fog. Move container from fire area if you can do it without risk. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. When impossible, withdraw from hazard area and let bum. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Stop leak if you can do it without risk. All equipment used when handling the material must be grounded. If possible, turn leaking containers so that gas escapes rather than liquid. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. Do not direct water at spill or source of leak. Prevent spreading of vapours through sewers, ventilation systems and confined areas. Isolate area until gas has dispersed. Caution: When in contact with cryogenic liquids, most materials become brittle and are likely to break without warning. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. --v 116- GASES - FLAMMABLE - UNSTABLE J POTENTIAL HAZARDS FIRE OR EXPLOSION EXTREMELY FLAMMABLE. Sheetl Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Some may ignite spontaneously in air. Some may polymerize (P) explosively when heated or involved in a fire. Vapo(u)rs from liquefied gas are initially heavier than air. Vapo(u)rs may travel to source of ignition and flash back. Containers may explode when heated. Ruptured cylinder may rocket. HEALTH Vapo(u)rs may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause bums, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50-100 m (150 to 300 feet) in all directions. Keep unauthorized personnel away. Stay upwind. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least BOO m (Vi mile). Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires: Dry chemical or C02. Large Fires; Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. When impossible, withdraw immediately from hazard area and let bum. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). All equipment used when handling the material must be grounded. Stop leak if you can do it without risk. Do not touch or walk through spilled material. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. If possible, turn leaking containers so that gas escapes rather than liquid. Page 7 CMA 111403 Sheetl Prevent entry into waterways, sewers, basements or confined areas. isolate area until gas has dispersed. FIRST AID Move victim to fresh air. Call emergency medical care Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 117- GASES TOXIC - FLAMMABLE - EXTREME HAZARD POTENTIAL HAZARDS HEALTH Toxic; extremely hazardous. May be fatal if inhaled or absorbed through skin. Initial odo(u)r may be irritating or foul and may deaden your sense of smell. Contact with liquefied gas may cause bums, severe injury and/or frostbite. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. FIRE OR EXPLOSION These materials are flammable. May form explosive mixtures with air. May be ignited by heat, sparks or flames. Vapo(u)r5 from liquefied gas are initially heavier than air. Vapo(u)rs may travel to source of ignition and flash back. Runoff may create fire or explosion hazard. Containers may explode when heated. Ruptured cylinders may rocket. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50-100 m (150 to 300 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances. Fire Page 8 CMA111404 Sheetl If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (14 mile) in all directions; also, consider initial evacuation for 800 m (14 mile) in all directions. EMERGENCY RESPONSE FIRE Use extinguishing agent suitable for type of surrounding fire. Small Fires: Dry chemical or C02. Large Fires: Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Damaged cylinders should be handled only by specialists. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. When impossible, withdraw immediately from hazard area and let bum. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Keep combustibles (wood, paper, clothing, oil, etc.) away from spilled material. Do not touch or walk through spilled material. Stop leak if you can do It without risk. If possible, turn leaking containing vessel so that gas escapes rather than liquid. Do not direct water at spill or source of leak. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Isolate area until gas has dispersed. Caution: When in contact with cryogenic liquids, most materials become brittle and are likely to break without warning. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim warm and quiet. Ensure that medical personnel are aware of the matenal(s) involved, and take precautions to protect themselves. 123- GASES - TOXIC POTENTIAL HAZARDS HEALTH Toxic, may be fatal if inhaled or absorbed through skin. Vapo(u)rs may be irritating Contact with liquefied gas may cause bums, severe injury and/or frostbite. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. FIRE OR EXPLOSION Some may bum, but none ignite readily. Vapo(u)rs from liquefied qas are initially heavier than air. Page 16 CMA 111405 Sheetl Containers may explode when heated. Ruptured cylinders may rocket. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper n t available or no answer, refer to appropriate telephone number listed on the inside back c ver. Spill or leak area should be isolated immediately for at least 50-100 m (150 to 300 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; . also, consider initial evacuation for 800 m ('A mile) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical or C02. Large Fires: Water spray, fog or regular foam. Do not get water inside container. Move container from fire area if you can do it without risk. Damaged cylinders should be handled only by specialists. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material. Stop leak if you can do it without risk. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. Do not direct water at spill or source of leak. Do not get water inside container. Isolate area until gas has dispersed. FIRST AID Move victim to fresh air. Call emergency medical care Page 17 CMA 111406 Sheetl Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Effects of contact or inhalation may be delayed. Keep victim under observation. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 124 COMPRESSED GAS- TOXIC-OXIDIZING-CORROSIVE POTENTIAL HAZARDS HEALTH Toxic, may be fatal if inhaled. Contact with gas or liquefied gas may cause bums, severe injury and/or frostbite. Vapors from liquefied gas are initially heavier than air and spread along ground. Runoff from fire control may cause pollution. FIRE OR EXPLOSION Do not bum but will support combustion. These are strong oxidizers and will react vigorously or explosively with many materials including fuels. May ignite other combustible materials (wood, paper, oil, etc.). Some will react violently with air, moist air and/or water. Containers may explode when heated. Ruptured cylinders may rocket. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50-100 m in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 1500 m (1 mile) in ail directions; also, consider initial evacuation for 1500 m (1 mile) in all directions. EMERGENCY RESPONSE Page 18 CMA 111407 Sheetl FIRE Small Fires: Water only; no dry chemical, C02 or Halon. Contain fire and let bum. If fire must be fought, water spray or fog is recommended. Do not get water inside containers. Move container from fire area if you can do it without risk. Damaged cylinders should be handled only by specialists. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. When impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material. Keep combustibles (wood, paper, clothing, oil, etc.) away from spilled material. Stop leak if you can do it without risk. Use water spray to reduce vapors or divert vapor cloud drift. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Isolate area until gas has dispersed. Ventilate the area. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Clothing frozen to the skin should be thawed before being removed. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least IS minutes. Keep victim warm and quiet. Effects of contact or inhalation may be delayed. Keep victim under observation. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 125- GASES - CORROSIVE HEALTH Toxic, may be fatal if inhaled. _ Vapo(u)rs are extremely irritating and corrosive. Contact with gas or liquefied gas may cause bums, severe injury and/or frostbite. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. FIRE OR EXPLOSION Some may bum, but none ignite readily. Vapo(u)rs from liquefied gas are initially heavier than air. Some may react violently with water. Page 19 CMA 111408 Sheetl Containers may exDlode when heated. Ruptured cylinders may rocket. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50*100 m (150 to 300 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). and structural firefighters protective clothing will provide limited protection. Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will not provide sufficient protection. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances. Fire If tank, rail car or tank truck Is involved in a fire, ISOLATE for 800 m (% mile) in all directions; als , consider initial evacuation for 800 m (Vt mile) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical or C02. Large Fires: Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside containers. Damaged cylinders should be handled only by specialists. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material. Stop leak if you can do it without risk. If possible, turn leaking container so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. Do not direct water at spill or source of leak. Isolate area until gas has dispersed. FIRST AID Move victim to fresh air. Call emergency medical care Page 20 CMA 111409 Sheetl Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Effects of contact or inhalation may be delayed. Keep victim under observation. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 126- GASES - COMPRESSED OR LIQUEFIED IRRITANTS POTENTIAL HAZARDS FIRE OR EXPLOSION Some may bum, but none ignite readily. Containers may explode when heated Ruptured cylinders may rocket. HEALTH Vapo(u)rs may cause dizziness or asphyxiation without warning. Vapo(u)rs from liquefied gas are initially heavier than air. Contact with liquid may cause frostbite. Fire may produce irritating, corrosive and/or toxic gases. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m (75 to 150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of tow areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 500 m (1500 feet). Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m ('A mile) in all directions. EMERGENCY RESPONSE FIRE Use extinguishing agent suitable for type of surrounding fire. Small Fires: Dry chemical or C02. Large Fires: Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Page 21 CMA111410 Sheeti Damaged cylinders should be handled only by specialists. Fire involving Tanks Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. Some of these materials, if spilled, may evaporate leaving a flammable residue. SPILL OR LEAK Do not touch or walk through spilled material. Stop leak if you can do it without risk. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Ventilate the area. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim warm and quiet. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 127-FLAMMABLE LIQUIDS-POLAR POTENTIAL HAZARDS FIRE OR EXPLOSION HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapo(u)rs will form explosive mixtures with air. Vapo(u)rs may travel to source of ignition and flash back. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapour explosion hazard indoors, outdoors or in sewers. Some may polymerize (P) explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. HEALTH Inhalation or contact with material may irritate or bum skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapo(u)rs may cause dizziness or suffocation. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Page 22 CMA 111411 Sheetl Keep unauthorized personnel awav. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 300 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE Caution: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, C02, water spray or alcohol resistant foam. Large Fires: Water spray, fog or alcohol resistant foam. Do not use straight streams. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapo(u)r suppressing foam may be used to reduce vapo(u)rs. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean non-sparking tools to collect absorbed material. Large Spills: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapo(u)n but it may not prevent ignition in closed spaces. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Wash skin with soap and water. Keep victim warm and quiet. Page 23 CMA 111412 Sheetl Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 128-FLAMMABLE UQUIDS-NON-POLAR POTENTIAL HAZARDS FIRE OR EXPLOSION HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapo(u)rs will form explosive mixtures with air. Vapo(u)rs may travel to source of ignition and flash back. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapour explosion hazard indoors, outdoors or in sewers. Some may polymerize (P) explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Material may be transported hot. HEALTH Inhalation or contact with material may irritate or bum skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapo(u)rs may cause dizziness or suffocation. Runoff from fire control or dilution water may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25*50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 300 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (% mile) in all directions. EMERGENCY RESPONSE FIRE Caution: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, C02, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not use straight streams. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Coot containers with flooding quantities of water until well after fire is out. Page 24 CMA 111413 Sheetl Withdraw immediately in case of rising sound from venting safety devices or discoio(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapo(u)r suppressing foam may be used to reduce vapo(u)rs. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean non-sparking tools to collect absorbed material. Large Spills: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapo(u)r; but it may not prevent ignition in closed spaces. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Wash skin with soap and water. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 129-FLAMMABLE LIQUIDS-IRRITANTS-POLAR POTENTIAL HAZARDS FIRE OR EXPLOSION HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapo(u)rs will form explosive mixtures with air. Vapo(u)rs may travel to source of ignition and flash back. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapour explosion hazard indoors, outdoors or in sewers. Some may polymerize (P) explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. HEALTH May be toxic if inhaled or absorbed through skin. Inhalation or contact with material may irritate or bum skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapo(u)rs may cause dizziness or suffocation. Runoff from fire control or dilution water may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Page 25 CMA 111414 Sheetl Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entenng. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 300 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m {Vi mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE Caution: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, C02, water spray or alcohol resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Large Fires: Water spray, fog or alcohol resistant foam. Do not use straight streams. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapo(u)r suppressing foam may be used to reduce vapo(u)rs. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean non-sparking tools to collect absorbed material. Large Spills: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapo(u)r but it may not prevent ignition in closed spaces. FIRST AID Move victim to fresh air. Cali emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, immediately flush skin or eyes with running water for at least IS minutes. Wash skin with soap and water. Keep victim warm and quiet. Page 26 CMA 111415 Sheetl Effects of exposure (inhalation, inaestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 130-FLAMMABLE UQUIDS-JRRITANTS-NONPOLAR POTENTIAL HAZARDS FIRE OR EXPLOSION HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapo(u)rs will form explosive mixtures with air. Vapo(u)rs may travel to source of ignition and flash back. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapour explosion hazard indoors, outdoors or in sewers. Some may polymerize (P) explosively when heated or involved in a fire, . Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. HEALTH May be toxic if inhaled or absorbed through skin. Inhalation or contact with material may irritate or bum skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapo(u)rs may cause dizziness or suffocation. Runoff from fire control or dilution water may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 300 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE Caution: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, C02, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not use straight streams. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Page 27 CMA 111416 Sheetl Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Wash skin with soap and water. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 132-FLAMMABLE LIQUIDS-CORROSIVE POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible: May be ignited by heat, sparks or flames. Vapo(u)rs will form explosive mixtures with air. Vapo(u)rs may travel to source of ignition and flash back. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapour explosion hazard indoors, outdoors or in sewers. Some may polymerize (P) explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. HEALTH May be toxic if inhaled or ingested.(swallowed) Contact with material may cause severe bums to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapo(u)rs may cause dizziness or suffocation. Runoff from fire control or dilution water may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 50 to 100 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Large Spill Consider initial downwind evacuation for at least 300 m. Fire Page 30 CMA 111417 Sheetl If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; als . consider initial evacuation for 800 m CA mile) in all directions. EMERGENCY RESPONSE FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, C02, water spray or alcohol resistant foam. Large Fires: Water spray, fog or alcohol resistant foam. Move container from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Do not get water inside containers. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Fully encapsulating, vapo(u)r protective clothing should be worn for spills and leaks with no fire. ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapo(u)r suppressing foam may be used to reduce vapo(u)rs. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal, (except for Hydrazine) Use clean non-sparking tools to collect absorbed material. Large Spills: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapo(u)n but it may not prevent ignition in closed spaces. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 133- FLAMMABLE SOUDS POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may bum rapidly with flare burning effect. Page 31 CMA 111418 Sheetl Powders, dusts, shavings, borings, turnings or cuttings may explode or bum with explosive violence. Material may be transported in a molten form. May re-ignite after fire is extinguished. HEALTH Fire may produce irritating or toxic gases. Contact may cause bums to skin and eyes. Contact with molten substance may cause severe bums. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 10*25 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 100 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (% mite) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical, C02, sand, earth, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Cool containers with flooding quantities of water until well after fire is out. For massive fire in cargo area, use unmanned hose holder or monitor nozzles. if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. Always stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Small Dry Spills: With dean shovel place material into dean, dry container and cover loosely; move containers from spill area. Large Spills: Wet down with water and dike for later disposal. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. Page 32 CMA 111419 Sheetl In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Removal of solidified molten material from skin requires medical assistance. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 134-FLAMMABLE SOUD-TOXIC POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material. May be ignited by heat, sparks or flames. When heated, vapo(u)rs may form explosive mixtures with air indoors, outdoors, and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. HEALTH Toxic, inhalation, ingestion, or skin contact with material may cause severe injury or death. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Fully encapsulating suits should be worn for maximum protection. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Large Spill Consider initial downwind evacuation for at least 100 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (14 mile) in all directions; also, consider initial evacuation for 800 m (14 mile) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical, C02, water spray or alcohol foam. Large Fires; Water spray, fog or alcohol foam. Move container from fire area if you can do it without risk. Do not use straight streams. Do not get water inside containers. Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. Page 33 CMA 111420 Sheetl ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all Ignition sources (no smoking, flares, sparks or flame in immediate area). Stop leak if without risk Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Prevent entry into waterways, sewers, basements or confined areas. Use clean non-sparking tools to collect material and place It into loosely covered plastic or fibreboard containers for later disposal. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the materials) involved, and take precautions to protect themselves. 135-SUBSTANCES-SPONTANEOUSLY COMBUSTIBLE POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material. May ignite on contact with air or moist air. May bum rapidly with flare burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. HEALTH Fire will produce irritating, corrosive and/or toxic gases. Inhalation of substance or decomposition products may cause severe injury or death. Coritact with substance may cause severe bums to skin and eyes. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 100-150 m in all directions. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. EVACUATION Page 34 CMA 111421 Sheetl Spill Consider initial downwind evacuation for at least 250 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (VS mile) in all directions; also, consider initial evacuation for 800 m (14 mile) in all directions. EMERGENCY RESPONSE FIRE DO NOT USE WATER, C02 OR FOAM ON MATERIAL ITSELF. Some of these materials may react violently with water. Small Fires: Dry chemical, soda ash, lime or DRY sand. Large Fires: Use DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire bum. Caution: Dithionite (Hydrosulfite/Hydrosulphite) fires may require flooding with water in order to eliminate hazardous reaction since the materials generate their own oxygen. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers or in contact with substance. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Stop leak if without risk. Small Spill: Cover with DRY earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect the material and place it into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 136-SUBSTANCES-SPONTANEOUSLY COMBUSTIBLE-TOXIC-AIR REACTIVE POTENTIAL HAZARDS FIRE OR EXPLOSION Extremely flammable; will ignite itself if exposed to air. Bums rapidly, releasing dense, white, irritating fumes. Material may be transported in a molten form. May re-ignite after fire is extinguished. HEALTH Page 35 CMA 111422 Sheetl Fire will produce irritating, corrosive and/or toxic gases. Ingestion of substance or inhalation of decomposition products will cause severe injury or death. Contact with substance may cause severe bums to skin and eyes. Some effects may be experienced due to skin absorption. Runoff from fire control may be corrosive and/or toxic and cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 100-150 m in'all directions. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical, sand, earth, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not scatter spilled material with high pressure water streams. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if without risk. Small Spills: Cover with water, sand or earth. Shovel into metal container and keep material under water. Large Spills: Dike for later disposal and cover with wet sand or earth. Prevent entry into waterways, sewers, basements or confined a areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Page 36 CMAIH423 Sheetl In case of contact with material, keep exposed skin areas immersed in water or covered with wet bandages until medical attention is received. Removal of solidified molten material from skin requires medical assistance. Remove and isolate contaminated clothing and shoes at the site and place in metal container filled with water. Fire hazard if allowed to dry. Effects of exposure (inhalation, ingestion or skin contact) may be delayed; keep victim under observation. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 137-SUBSTANCES-CORROSIVE-WATER-REACTIVE POTENTIAL HAZARDS HEALTH Inhalation, ingestion or contact (skin, eyes) with vapours, dusts or substance may cause severe injury, bums, or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Contact with molten substance may cause severe bums to skin and eyes. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may bum, but none of them ignites readily. May ignite other combustible materials (wood, paper, oil, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Flammablertoxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars etc.) Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Material may be transported in a molten form. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 15-25 m in all directions. Keep unauthorized personnel away. Stay upwind Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA) Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION SPILL See the Table of Initial Isolation and Protective Action Distances. FIRE If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vx mile) in all directions; also, consider initial evacuation for 800 m CA mile) in all directions. EMERGENCY ACTION FIRE When material is not involved in fire: do not use water on material itself. Page 37 CMA 111424 Sheetl Small fires: Use C02, dry chemical. Move container from fire area if you can do it without risk. Large Fires: Flood fire area with large quantities of water, while knocking down vapo(u)rs with water fog. If insufficient water supply: knock down vapo(u)rs only. Fire involving Tanks or Car/Trailer Loads Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if without risk. Fully encapsulating, vapo(u)r protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapo(u)n do not put water directly on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Small Spills: Cover with DRY earth, DRY sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect the material and place K into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Removal of solidified molten material from skin requires medical assistance. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. 138-WATER REACTIVE SUBSTANCES POTENTIAL HAZARDS FIRE OR EXPLOSION Produce flammable substances on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in flammable liquids. Runoff may create fire or explosion hazard. May re-ignite after fire is extinguished. HEALTH Page 38 CMA 111425 Sheetl Inhalation or contact with vapo(u)r, substance, or decomposition products may cause severe injury or death. May produce toxic gases and/or corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least SO-100 m in ail directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate the area before entry. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 250 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m 04 mile) in all directions. EMERGENCY RESPONSE FIRE DO NOT USE WATER OR FOAM. Small Fire: Dry chemical, soda ash, lime or sand. Large Fire: Use DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire bum. Move container from fire area if you can do it without risk. Magnesium Fires: Use DRY sand, sodium chloride powder, graphite powder or Met- L-X' powder. Lithium Fires: Use DRY sand, sodium chloride powder, graphite powder, copper powder or LithX' powder. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Stop leak if without risk. Use water spray to reduce vapours or divert vapour cloud drift. DO NOT GET WATER on spilled substance or inside containers. Spills: Cover with DRY earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Dike for later disposal; do not apply water unless directed to do so. Page 39 CMA 111426 Sheetl Powder Spills: Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. DO NOT CLEAN-UP OR DISPOSE OF. EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID Move victim to fresh air Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, wipe material from skin immediately; flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 139-WATER REACTIVE SUBSTANCES EVOLVING FLAMMABLE AND TOXIC SUBSTANCES POTENTIAL HAZARDS FIRE OR EXPLOSION Produce flammable and toxic substances on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard. May re-ignite after fire is extinguished. HEALTH Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. Inhalation or contact with vapo(u)r, substance, or decomposition products may cause severe injury or death. May produce cprrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 100-150 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate the area before entry. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Large Spill See the Table of Initial Isolation and Protective Action Distances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (% milel in all directions. Page 40 CMA 111427 Sheetl EMERGENCY RESPONSE FIRE DO NOT USE WATER OR FOAM. Small Fire: Dry chemical, soda ash, lime or sand. Large Fire: Use DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire bum. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Traiier Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ' Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Fully encapsulating, vapo(u)r protective clothing should be worn for spills and leaks with no fire. Stop leak if without risk. Use water spray to reduce vapours or divert vapour cloud drift. DO NOT GET WATER on spilled substance or inside containers. Spills: Cover with DRY earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Dike for later disposal; do not apply water unless directed to do so. Powder Spills: Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID Move victim to fresh air Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes at the site. In case of contact with material, wipe material from skin immediately; flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 140-OXIDIZERS POTENTIAL HAZARDS FIRE OR EXPLOSION These materials will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heating or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.) Fire may produce irritating, corrosive and/or toxic gases. Containers may explode when heated. Runoff may create fire or explosion hazard. Page 41 CMA 111428 Sheetl EVACUATION Large Spill Consider initial downwind evacuation for at least 250 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (14 mile) in all directions; also, consider initial evacuation for 800 m (14 mile) in all directions. EMERGENCY ACTION Small Fires: Dry chemical, C02, water spray or regular foam. Large Fires: Use flooding guantities of water. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads BEWARE OF POSSIBLE CONTAINER EXPLOSION Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. Always stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Stop leak if without risk. Absorb with earth, sand or other non-combustible material and transfer to container. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 151- SUBSTANCES - TOXIC-NON COMBUSTIBLE POTENTIAL HAZARDS HEALTH Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. FIRE OR EXPLOSION Material itself does not bum but may decompose upon heating to produce corrosive and/or toxic fumes. Fire will produce imtating, corrosive and/or toxic gases. Containers may explode when heated. Runoff may pollute waterways. PUBLIC SAFETY Page 56 CMA 111429 Sheetl CALL Emergency Response Telephone Number n Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances for highlighted substances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m PA mile) in all directions. EMERGENCY RESPONSE Small Fire: Use dry chemical, C02 or water spray. Large Fire: Use water spray, fog or regular foam. Move container from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Do not use straight streams. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb with earth, sand or other non-combustible material and transfer to container. DO NOT GET WATER INSIDE CONTAINERS. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armiift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Page 57 CMA 111430 Sheetl Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 152- SUBSTANCES - TOXIC and COMBUSTIBLE POTENTIAL HAZARDS HEALTH Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe bums to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or poisonous and pollute waterways. FIRE OR EXPLOSION Combustible material: may bum but does not ignite readily. Containers may explode when heated. Some may decompose (E) or polymerize (P) explosively when heated or involved in a fire. Fire will produce irritating, corrosive and/or toxic gases. Runoff may pollute waterways. Material may be transported in a molten form. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances for highlighted substances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE Small Fire: Use dry chemical, C02 or water spray. Large Fire: Use water spray, fog or regular foam. Move container from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Do not use straight streams. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. When impossible, withdraw from hazard area and let bum. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Page 58 CMA 111431 Sheetl Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb with earth, sand or other non-combustible material and transfer to container. DO NOT GET WATER INSIDE CONTAINERS. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the materials) involved, and take precautions to protect themselves. 153- SUBSTANCES - TOXIC and/or CORROSIVE-COMBUSTIBLE POTENTIAL HAZARDS HEALTH Inhalation, ingestion, or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe bums to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. FIRE OR EXPLOSION Combustible material: may bum but does not ignite readily. When heated, vapours may form explosive mixtures with air indoors, outdoors, and sewers explosion hazards. Some may decompose (E) or polymerize (P) explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Material may be transported in a molten form. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. Page 59 CMA 111432 Sheetl EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances for highlighted substances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) In all directions. EMERGENCY RESPONSE Small Fire: Use dry chemical, C02 or water spray. Large Fire: Use dry chemical, C02, alcohol resistant foam or water spray. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolo(u)ration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb with earth, sand or other non-combustible material and transfer to container. DO NOT GET WATER INSIDE CONTAINERS. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the materials) involved, and take precautions to protect themselves. 154- SUBSTANCES - TOXIC and/or CORROSIVE-NON COMBUSTIBLE POTENTIAL HAZARDS HEALTH Inhalation, ingestion, or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe bums to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. FIRE OR EXPLOSION Non combustible Material itself does not bum but may decompose upon heating to produce corrosive and/or poisonous fumes. Page 60 CMA 111433 Sheetl Some may decompose (E) or polymerize (P) explosively when heated or involved in a fire. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances for highlighted substances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (V4 mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE Small Fire: Use dry chemical, C02 or water spray. Large Fire: Use dry chemical, C02, alcohol resistant foam or water spray. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding guanfities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to container. DO NOT GET WATER INSIDE CONTAINERS. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. Page 61 CMA 111434 Sheetl In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the materials) involved, and take precautions to protect themselves. 155- SUBSTANCES - FLAMMABLE, TOXIC and/or CORROSIVE (Water sensitive substances) POTENTIAL HAZARDS FIRE OR EXPLOSION HIGHLY FLAMMABLE Will be easily ignited by heat, sparks or flames. Vapo(u)rs form explosive mixtures with air indoors, outdoors, and sewers explosion hazards. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapo(u)rs may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Some may decompose (E) or polymerize (P) explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Fire will produce irritating, corrosive and/or toxic gases. Containers may explode when heated or if contaminated with water. HEALTH Bromoacetates and chloroacetates are extremely imtating/lachrymators Inhalation, ingestion or contact (skin, eyes) with vapo(u)rs, dusts or substance may cause severe injury, bums, or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Keep upwind. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial Isolation and Protective Action Distances for highlighted substances. Fire Page 62 CMA 111435 Sheetl If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (V mile) in all directions. EMERGENCY RESPONSE Small Fire: Use C02, dry chemical, dry sand, alcohol foam. Move container from fire area if you can do it without risk. Large Fire: Use water spray, fog or alcohol foam. Note: Most foams will react with the material and release corrosive/toxic gases. Do not use straight streams. Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapo(u)r suppressing foam may be used to control vapo(u)rs. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. DO NOT GET WATER INSIDE CONTAINERS. Prevent entry into waterways, sewers, basements or confined areas. Small Spill: Cover with DRY earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect the material and place it into loosely covered plastic containers for later disposal. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 156- SUBSTANCES - TOXIC and/or CORROSIVE-COMBUSTIBLE (Water sensitive substances) POTENTIAL HAZARDS FIRE OR EXPLOSION Combustible material; material will bum but it may take some effort to ignite. Page 63 CMA 111436 Sheetl Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Some may polymerize (P) explosively when heated or involved in a fire. When heated, vapo(u)rs may form explosive mixtures with air indoors, outdoors, and sewers explosion hazards. Most vapo(u)rs are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapo(u)rs may travel to source of ignition and flash back. Fire will produce irritating, corrosive and/or toxic gases. Containers may explode when heated or if contaminated with water. Contact with metals may evolve flammable hydrogen gas. HEALTH Bromoacetates and chloroacetates are extremely inttating/lachrymators Inhalation, ingestion or contact (skin, eyes) with vapo(u)rs, dusts or substance may cause severe injury, bums, or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or poisonous gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 15*25 m in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. Structural firefighters' protective clothing is not effective for these materials. EVACUATION Spill See the Table of Initial isolation and Protective Action Distances for highlighted substances. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (Vi mile) in all directions; also, consider initial evacuation for 800 m (VS mile) in all directions. EMERGENCY RESPONSE Small Fire: Use C02, dry chemical, dry sand, alcohol resistant foam. Move container from fire area if you can do it without risk. Large Fire: Use water spray, fog or alcohol foam. Note: Most foams will react with the material and release conosive/toxic gases. Do not use straight streams. Fire involving Tanks or Car/Trafler Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. Page 64 CMA 111437 Sheetl ALWAYS stay away from the ends of tanks. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapo(u)r suppressing foam may be used to control vapo(u)rs. Use water spray to reduce vapo(u)rs or divert vapo(u)r cloud drift. DO NOT GET WATER INSIDE CONTAINERS. Prevent entry into waterways, sewers, basements or confined areas. Small Spill: Cover with DRY earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect the material and place it into loosely covered plastic containers for later disposal. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; use the Holger Nielsen method (back pressure-armlift) or proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that attending medical personnel are aware of the materia!(s) involved, and take precautions to protect themselves. 157-SUBSTANCES-TOXIC/CORROSIVE-NON-COMBUSTIBLE (WATER-SENSITIVE) POTENTIAL HAZARDS HEALTH Inhalation, ingestion or contact (skin, eyes) with vapo(u)is, dusts or substance may cause severe injury, bums, or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or poisonous gases. Runoff from fire control or dilution water may be corrosive and/or toxic and pollute waterways. FIRE OR EXPLOSION Non combustible (Water reactive) Material itself does not bum but may decompose upon heating to produce corrosive and/or toxic fumes. Vapours may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Heat of reaction may be high enough to ignite combustibles. Containers may explode when heated or if contaminated with water. Page 5 CMA 111438 Sheetl Keep unauthorized personnel away. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Wear flame retardant structural firefighters protective clothing, including faceshield, helmet and gloves, this will provide limited thermal protection. EMERGENCY RESPONSE FIRE Do Not Use Water, except in life threatening situations and then only in a fine spray. Do Not Use halogenated extinguishing agents or foam. Move combustibles out of path of advancing pool if you can do so without risk. Extinguish fires started by molten material by using appropriate method for the burning material; keep water, halogenated extinguishing agents and foam away from the molten material. SPILL OR LEAK Do not touch or walk through spilled material. Do not attempt to stop leak, due to danger of explosion. Keep combustibles (wood, paper, oil, debris, etc.) away from spilled material. Material is very fluid, spreads quickly, and may splash. Do not try to stop it with shovels or other objects. Dike far ahead of spill; use dry sand to contain the flow of material. Where possible allow molten material to solidify naturally. Avoid contact even after material solidifies. Molten, heated and cold aluminum look alike; do not touch unless you know it is cold. Cleanup under the supervision of an expert after material has solidified. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. For severe bums, immediate medical attention is required. Removal of solidified molten material from skin requires medical assistance. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. 170 METALS -Powders, dusts, shavings, borings, turnings, or cuttings POTENTIAL HAZARDS FIRE OR EXPLOSION Some may polymerize (P) explosively when heated or involved in a fire. May explode from heating, shock, friction or contamination. May react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May be ignited by friction, heat, sparks or flames. Powders, dusts, shavings, borings, turnings or cuttings will bum with intense heat and may react explosively with water. Dusts or fumes may form explosive mixtures in air. Containers may explode when heated. May re-ignite after fire is extinguished. HEALTH Oxides from metallic fires are a severe health hazard. Page 83 CMA 111439 Sheetl inhalation or contact with vapour, substance, or decomposition products may cause severe injury or death. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 25-50 m in all directions. Stay upwind. Keep unauthorized personnel away. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 50 m. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m ('/> mile) in all directions. EMERGENCY RESPONSE FIRE DO NOT USE WATER, FOAM OR C02, Dousing metallic fires with water may generate hydrogen gas, an extremely dangerous explosion hazard, particularly if fire is in a confined environment(i.e. building, cargo hold etc...). Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1~ or Met-L-X" powder. Confining and smothering metal fires is preferable rather than applying water. Move container from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads If impossible to extinguish, protect surroundings and allow fire to bum itself out. SPILL OR LEAK ELIMINATE all ignition sources (no smoking, flares, sparks or flame in immediate area). Do not touch or walk through spilled material. Stop leak if without risk. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim warm and quiet. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 171-LOW TO MODERATE HAZARD SUBSTANCES POTENTIAL HAZARDS FIRE OR EXPLOSION Some may bum but none ignite readily. Page 84 CMA 111440 Sheetl Containers may explode when heated. Some may be transported hot. HEALTH Inhalation of material may be harmful. Contact may cause bums to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic fumes. Runoff from fire control may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 10 m in all directions. Keep unauthorized personnel away. Stay upwind. PROTECTIVE CLOTHING Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters' protective clothing will provide limited protection. EVACUATION FIRE If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 m (% mile) in all directions; also, consider initial evacuation for 800 m (Vi mile) in all directions. EMERGENCY RESPONSE FIRE Small Fires: Dry chemical, C02, water spray or regular foam. Large Fires; Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Do not scatter spilled material with high pressure water streams. Dike fire control water for later disposal. rire involving Tanks Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tank. ALWAYS stay away from the ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. Small Dry Spills: With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Small Spills; Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. FIRST AID Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Page 85 CMA 111441 Sheetl Remove contaminated clothing and shoes. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Ensure that attending medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 172-GALLIUM or MERCURY POTENTIAL HAZARDS HEALTH Inhalation of vapours or contact with substance will result in contamination and potential harmful effects. Fire will produce irritating, corrosive and/or toxic gases. FIRE OR EXPLOSION Material itself does not bum but may produce corrosive and/or poisonous fumes upon heating. Runoff may pollute waterways. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Spill or leak area should be isolated immediately for at least 10 m in all directions. Stay upwind. Keep unauthorized personnel away. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will provide limited protection. EVACUATION Large Spill Consider initial downwind evacuation for at least 100 m. Fire When any large container is involved in a fire, consider initial evacuation for 500 m in all directions. EMERGENCY RESPONSE FIRE Use extinguishing agent suitable for type of surrounding fire. Material itself does not bum or bums with extreme difficulty. Do not direct water at the heated metal. Runoff may pollute waterways. SPILL OR LEAK Do not touch or walk through spilled material. Do not touch damaged containers, packages or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk.' Prevent entry into waterways, sewers, basements or confined areas. Do not use steel or aluminium tools or equipment. Cover with earth, sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. For mercury, use a mercury spill kit. Mercury spill areas may be subsequently treated with calcium sulphide or with sodium thiosulphate wash to neutralize any residual mercury. FIRST AID Page 86 CMA 111442