Document mpLez3wMNMYynmKeBRrrOe8j4

Mat rialSaf ty Data Sh t Document Number: Industrial 10-4033-6 Chemical Products Division 3M Cantor St. Paul, Minnesota 55144-1000 512/733-1110 Duns Wo.: 00-617-3082 Trade Name FX-9613 DYNAMAR Brand Polymer Processing Additive i mical Family iildorinated Elastomer 3M LD. Number 98-0211-3503-7 (33 lb. unit) 1. Ingredient* tiuoroeiastomer Talc Partitioning Agent Partitioning Agent CAS* 9011-17-0 14807-96-6 471-34-1 7631-86-9 % "go ~6 "2 "2 Exposure Limits None (5) 2 mg/m3 (1) 10 mg/m3 (1) 10 mg/m3 (1) Exposure limit data source: 1) ACGIH Threshold Limit Values, 2) Federal OSHA Permissibl a Exposure Limit, 3) 3M E> posure Guidel nes, 4) Chemical Manufacturer Recommended Guidelines and 5) None established. 2. Physical Data Boiling Point Solubility in Water NA Negligible i i-* CD Vapor Pressure Specific Gravity (Ha 0 - 1) NA Vapor Density (Air - 1) deration Rate Percent Volatile NA pH NA NA NA Appearance and Odor White rubbery, granular solid. 3. Fire and Explosion Hazard Data Flash Point (Test Method) Setaflash CC >600 F Extinguishing Media Water, Foam, C02, Dry Chemical Flammable Limits: LEL _ N A UEL " NA Special Fire Fighting Procedures None Known Unusual Fire and Explosion Hazards Toxic by-products, including HF, may be formed. 4. Environmental Information Spill Response Observe precautions from other sections. Collect spilled material. Recommended Disposal Dispose of waste product in a sanitary landfill. Disposal alternative: Mix with flammable material and incinerate in an industrial or commercial facility. Combustion products will include HF. Since regulations vary, consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste No.: None onmental Data I . determined. Form 15S93-2-D (11/85) NA Not Applicable ND = Not Determined DO 086262 Iss CONFIDENTIAL,------------- Jan-1987 I Jan-198* Trade Name vx-9613 DYNAMAR Brand Polymer Processing Additive 5. Heelth Hazard Pate_________________________________________________________________________________________ Eye Contact Low potential to cause irritation of eyes. sJn Contact The product has a low potential for causing irritation of the skin during intended use and handling. Animal studies indicate that fluoroelastomers are non-irritating to the skin of the albino rabbit. hhalation Low hazard at temperatures below the thermal decomposition point. At >660 F, the FX-9613 begins to break down emitting hydrogen fluoride, HF, and short chain fluorocarbons which are highly irritating and toxic. OSHA permissible exposure limits:- talc 20 million particles per cubic foot of air. Ingestion Considered practically non-toxic orally. Suggested First Aid EYE CONTACT: Immediately flush with plenty of water. Call a physician. SKIN CONTACT: Wash affected area with soap and water. INHALATION: If symptoms occur, remove person to fresh air. If symptoms continue, call a physician. INGESTION: Give two glasses of water. Call a physician or Poison Control Center. ' activity Data Stability Unstable X Stable Conditions To Avoid Not Applicable Incompatibility Hazardous Polymerization Materials To Avoid A1 or Mg powder & high shear/temperature May Occur X Will Not Occur Conditions To Avoid Not Applicable conditions. Hazardous Decomposition Products Thermal decomposition may produce toxic materials including HF. 7. Special Protection Information Eye Protection Safety Glasses Skin Protection Rubber Gloves Ventilation General mechanical ventilation is adequate below decomposition temperature. Respiratory and Special Protection If decomposition occurs, an air supplied respirator should be worn. B. Precautionary Information Avoid breathing the decomposition products. If processing at or above the decomposition temperature use local exhaust ventilation. Store below 100 F. Prevent moisture contamination. Do not smoke while handling. ^0 The information on this Data Sheet represents our current data and best opinion as to the proper use and handling of this product under normal conditions. Any use of the product which is not in conformance with this Data Sheet or which involves using the product in combination with any other product or any process is the responsibility of the user. Mrs - -t v : t r Rr ] A L E A r E *r Y 0t 1l fH EE T E: 1 L`OW CHEMICAL L'.S.A. ' ] d l ,* \: MICHIGAN A66A0 EMERGENCY H0\ll b 1 7 - t. 3 ft - A R 0 C E r F E C T I V E DMF: l? MAD F 0 product corr: 379 fed PRODUCT ! A K El FR-30Q-EA CA bO INGREDIENTS (TYPICAL VALUES-NQT SPECIFICATIONS;) :* : DECfiEROMODIPHENYL OXIDE OTHER BROMINATED DIPHENYL OXIDES ` >?G : : <10 I SECTION 1 PHYSICAL DATA BOILING POINT: DECOMPOSES : sol. in water: 20 ppe VAP PRESS: < 1 MMHG 8 250C : sp. gravity: 3.0 VAP DENSITY C A 1R = 1> : : % VOLATILE BY VOL: 0 APPEARANCE AND ODOR: WHITE TO OFF-WHITE powder. MELTING RANGE 563F-561F, 29 -3 05C SECTION 2 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: NONE : FLAMMABLE LIMITS (STP IN AIR) METHOD USED: ------- : LFLI NOT PETER. UFL: NOT DETER. EXTINGUISHING MEDIA: -------- SPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: HYDROGEN BROMIDE AWT POSSIBLY OTHER TOXIC GASES MAY BE GIVEN OFF AT ELEVATED TEMPERATURES? PRESSURE DEMAND SELF-CONTAINED BREATHING APPARATUS MAY BE NECESSARY. SECTION 3 REACTIVITY DATA STABILITY: MATERIAL "AY SLOWLY DECOMPOSE AT TEMPERATURES GREATER THAN 3 C 0 C TO GIVE TOXIC GASES. (MELTING POINT APPROX. 3000. INCOMPATIBILITY: OXIDIZING MATERIAL. HAZARDOUS DECOMPOSITION PRODUCTS: CHIEFLY HYDROGEN BROMIDE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION A SPILL? LEAK? AND DISPOSAL PROCEDURES ACTION TO TAKE FOR SPILLS (USE APPROPRIATE SAFETY EQUIPMENT): USE DJST RESPIRATOR? RUBBER GLOVES? GLASSES WITH SIDE SHIELDS DURING CLEAN UP. SHOVEL INTO PAKS. DISPOSAL METHOD: DISPOSAL OF EMPTY PAKS? POLYMER CONTAINING FR 300 3A LOST IN INDUSTRIAL OPERATIONS (DUST COLLECTIONS? ETC.) SHOULD BE DISPOSEO OF AT LOCALLY APPROVED LANDFILL SITES. CARRIER DAMAGED PAKS.* MATERIAL SHOULD BE TRANSFERRED TO GOOD PAKS AND RETURNED TO THE DOW CHEMICAL COMPANY. (CONTINUED ON PAGE 2 ) (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY DO 086264 CONFTDENTTAI r 1 7 - f-7 A - A A C " KM" rE HAZARDOUS FROM REPEATED r^ILY IE HALATION* EFFECTS OF OVEREXPOSURE.* NOT AVAILABLE. SECTION 6 FIRST AIC--NOTE TO PHYSICIAN FIRST AIL PROCEDURES.* LYES: IRRIGATION OF THE EYE IKMED IATEL Y WITH WATER FOR FIVE MINUTES IS GOOD SAFETY PRACTICE. SKIN: CONTACT WILL PROBABLY CAUSE NO MORE THAN IRRITATION. WASH OFF IN FLOWING WATER OR SHOWER. WASH CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSULT MEDICAL PERSONNEL. INGESTION: IF SWALLOWED* INDUCE VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND STICKING FINGER BCWN THROAT. CALL A PHYSICIAN. NOTE TO physician: eyes: MAY CAUSE MILD IRRITATION. STAIN FQR EVIDENCE OF CORNEAL INJURY. SKIN: MAY CAUSE MILD IRRITATION. TREAT AS ANY CONTACT DERMATITIS. respiratory: NO EFFECT EXPECTED. SYSTEMIC: ANIMAL STUDIES SHOW WITH EXCESSIVE ORAL ADMINISTRATION . KIDNEY A\D LIVER CHANGES AND THYROID HYPERPLASIA CAN BE DEMONSTRATED. HUMAN EFFECTS NOT ESTABLISHED. NO SPECIFIC ANTIDOTE. TREATMENT BASED ON THE SOUND JUDGMENT OF THE PHYSICIAN AND THE INDIVIDUAL REACTIONS OF THE PATIENT. SECTION 7 SPECIAL HANDLING INFORMATION VENTILATION: RECOMMEND CONTROL OF DUSTS TO SUGGESTED GUIDE. LOCAL EXHAUST DESIRED AT THOSE POINTS UHERE DUSTS MAY BE GENERATED. RESPIRATORY PROTECTION: NONE NORMALLY NEEDED. IF REQUIRED* USE AN APPROVED DUST RESPIRATOR. PROTECTIVE CLOTHING: CLEAN BODY-COVERING CLOTHING. EYE PROTECTION: SAFETY GLASSES WITHOUT SIDE SHIELDS. WASHING FACILITIES NEAR WORK AREA. SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRACTICE REASONABLE CARE TO AVOID SKIN AND EYE CONTACT. PREVENT BREATHING DUSTS IF GENERATED. STORE PAKS IN DRY AREA. (CONTINUED ON PAGE 3 ) (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY '' T t 1 I - L C DOW CML " IC 1L l.. S. A . ' ! OL AND I :rFECTJVr DATE: ! A*- 81 PRODUCT (COM'D): F-7 0D-F- PRODUCT Cl:.:: ?1793 s~: o a s c LAST (' A &e (R } INDlL-TuS a TRADEUANR OF THE LOW Cr.LUCAL CO'FANY CONSULT TH: COw CHEMICAL COMPANY FOR FURTHER INFORMATION* THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH* EUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.