Document mpGpOGBMnQOj0de6GmGpQRLBb

MONSANTO TERPHENYLS - Monsanto T e c h n ic a l B u lle t in No. P-106 November 6, 1950 V- Monsanto Chemicals'-Plastics ^L./^_____ :_ PLASTICIZER APPLICATION GROUP yO. . " MONSANTO TERPHENYLS '' !c? \'(>/s ' Monsanto Technical Bulletin No. P-106 November 6, 1950 \ Monsanto Chemical Company Phosphate Division St. Louis, Missouri MONSANTO TRADE LITERATURE PERMANENT Fit F *202 . INTRODUCTION The Monsanto TERPHENYLS are a series of hydro carbon solids ranging in melting point from a little above room temperature to as high as 210C. (410F.)." Monsanto TERPHENYLS have found use as plasticizers, softening agents, wax additives and extenders, and in paper coatings. Various properties of the TER- PHENYLS are presented in this bulletin to facilitate the selection of the proper one for specific appli cations. . Tm* contained in thle bulletin le. to our beet knowledge, true and accurate, but all recommendations or tigeel one are made without guarantee, since the'conditions of use are beyond our control. The Monsanto Chemical Company disclaim* any liability Incurred In connection with the uee of theee date or suggestions. i"'*'er0r. nothing contained herein shall be conelrut'J as\ recommendation to uee any product in conflict with existing patents covering any material or its uae. 0627407 TOWOLDMONOQ39974 Formula: PHYSICAL PROPERTIES Ortho Meta Para Color - NPA: <1.5 Density - k./oo.i 1.14 Melting Point: Completely liquid 55C. ,(131F.) <3-5 1.164 90C. (194F.) Solidification Temp.: First crystals -- <90C. 194F.) - Hold point , 53-55g. x (127-131 F-) Distillation Ranp;e: 330-3 50C. D-20 corrected (626-662F.) Flash Point: 171C. (340F.) 83-85C. (I8l-185F.) 368-378C. (694-712F.) Ot'-Oin 0 0 CM-st 00 OUf\ Flame Point: 193. ' (390F.) . Viscosity S.U.S. ----------- at'"2T0F.: 40.6 (See Graph No. I) 39.3 . Solubility: See Graphs Nos. II, III and IV < 2.0 1.236 213C. (4l5F.) 209-213C. (408-4l5F.) .-- 38l-388c (7l8-730F 207C. (405F.) 238?C. (460f.) 28.8 (at -1- 0627408 TOWOLDMONOQ39975 I Vapor Pressure (mm. of Mercury) TC. 90 100 110 120 130 WO 150 160 170 ,l80 190 200 ' 210 220 230 240 25Q. 260 270 280 290 300 310 320 330 340 350 360 37 380 .. Ortho 0.17 0.3 0.5 0.9 1.5 2.4 3.7 5.7 8.2 12.0 18.0 25.0 35.0 46.0 62.0 82.0 . 110.0 140.0 180.0 230.0 290.0 . .360.0 450.0 550.0 670,0 810.0 990.0 1160.0 1390.0 1600.0 - Meta _ - 0.15 0-3 0.5 0.8 1.3 2.0 3. 4.6 6.8 q.8 14.0 19.0 26.0 36.O 48.0 63.0 83.O 110.0 140.0 180.0 220.0 270.0 340.0 410.0 500.0 610.0 730.0 870.0 Para _ - - 0.1^ 0.3 0.6 1.0 1.9 3-2 5.5 9.1 14.0 19.0 26.0 35.0 46.0 61.0 80.0 101.0 130.0 165.O 210.0 260.0 320,0 390.0 470.0 570.0 680.0 Terphenyl 1 Ortho t-'vr :: Meta . 1 j Para ELECTRICAL PROPERTIES Dielectric Constant 2.54 2.62 - Resistivity - ohm-cm 106C. _ 8260 X lo9 2Boc. - 2600 X 109 -, '. - 30 X 10- STABILITY 1 i No deteotible effect on boiling Terphenyls in 10% Sulfuric Acid or Caustic Soda. + TOWOLDMONOQ39976 COMPATIBILITY Ortho Terphenyl Other Component % Ortho Terphenyl in Mixture 19 W 1---------75---------22 Paraffin (120/l25F.) Barnsdall (l60/l65F.) Beeswax Opal Wax Stearic Acid "N" Wood Rosin CC CC CCC CI III CCI c c I I I Meta Terphenyl Other Component > Meta Terphenyl in Mixture 9 IT M-------- 15------- 90 Paraffin (120%25F.) Incompatible with 2$ or more Meta Terphenyl Barnsdall Wax (160/i65F.) B II Ceresin III Carnauba Wax C C CI Candelllla Wax CII Montan Wax III Beeswax III Japan Wax CI Opal Wax CII I. 0. Wax 0 III Stroba Wax III Acra Wax CCB Stearic Acid III Shellac CII Manila Resin (Loba B) C I I Ester Gum CII "N" Wood Rosin (Hercules) C I I Piccolite Resin (85) ' C I I Staybelllte Resin BI I Para Terphenyl flther Component Paraffin (120/l25F.) Paradene No. 1 Paradene No. 2 "N" Wood Rosin # Para Terphenyl in Mixture T73-------T-2 ~v?---------- 5-------10-75 I CI CI I Note: C Compatible , I a Incompatible B a Almost Compatible -3- 0627M0 , TOWOLDMONOQ39977 COMPARATIVE HARDNESS (Smaller values denote greater hardness) Average Penetration In cm. x 10-2 in 60 seconds at 25C. under load indicated (ASTM D-5-25) Material . 50 Grams 150 Grams 250 Grams Meta Terphenyl Para Terphenyl Carnauba Wax Candelilla Wax Ortho Terphenyl 0 0 2.3 0 0 3-3 0 2.3 4.7 0 3.3 4.7 1.3 4.0 10.7 50$ Paraffin & 50$ Meta Terphenyl 3-7 75$ Paraffin & 25$ Meta Terphenyl 7-3 12.3 18.0 18.0 25-3 Ceresin Wax ~ . 95$ Paraffin & 5$. Meta Terphenyl 10.7 15.7 21.0 26.0 29-7 98$ Paraffin & 2$ Meta Terphenyl 11.7 26.0 32.7 Paraffin Wax Montan Wax Mixed Isomerle Terphenyl No aging Aged 24 hours 14.3 15.0 60.0 28.7 23-3 28.7 - 31-3 37-3 - AVAILABILITY The Terphenyls are available in limited quantities. se:wa-m-1150 rev. -4- 0627411 Q Printed In U.S.A. TOWOLDMONOQ39978 TEMPERATURE. DEGREES FAHREFMEfT TOWOLDMONOQ39979 VISCOSITY, SAYBOLT UNIVERSAL SECONDS VISCOSITY, SAYBOLT UNIVERSAL SECONDS Temp. r Graph II - SOLUBILITY OF ORTHO TERPHENYL TOWOLDMONOQ39980 Temp TOWOLDMONOQ39981 Graph IV - . SOLUBILITY OP PARA TERPHENYL 80 Temp Monsanto Chemicals-Fustics --------_________ For further information about Monsanto TERPHENYLS contact the nearest Monsanto office. MONSANTO CHEMICAL COMPANY St. Louis Birmingham Boston .Charlotte Chicago Cincinnati Cleveland Detroit Los Angeles New York Philadelphia Portland (Ore.) San Francisco Seattle Monsanto (Canada) Ltd. Montreal Toronto Representatives in the Principal Cities of the World . . o 0627416 .............................................................................. .... ------------------------------ --------------- TOWOLDMONOQ39983