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Pfizer Inc. 235 East 42nd Street : New York, NY 10017 :
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Product: LlhESTOhE - LUCERO ; . VALLEY
MSDS Noi MINERAC, / MINOIO Revisicn: 02 Date: June, 1998
Naticnal Paint and Coatings Association
Hazardous Material Identification Syst&m-"'
HEALTH HAZARD 1 - Slight
FLAhTIABILITY HAZARD 0 - Minimal
FEACTIVITY HAZARD 0 - hfinimal
. FERSONAL PROTE---1'C1 TIO\ Nt,
E - Glasses, Gloves, Dust
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SECTION I. MATERIA- IDGNTIFICATICN
Tr^/I^tet^^N^ne* lilHESTONE
Description: Limestone;, Calcium Carbonate
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Other Designations: Vicron 10-20, Vicrcn 15-15, Vicron 25-11, Micron 31-6, Vicrcn , ,
41-8, Vicrcn 45-3. Vicron SO, Vicron 200, Marblewhite 326, Marblewhite 325, .Marblewhite1 200, Marblewhite 125, Marblewhite 80, Marblewhite 30, Marblewhite -16+-4G, Calcium Meal 30, Calcium Grits #6, Calcium Brits #9. Calcium Grits,v#69, Pcultry^BlenU, Viroc #1, Viroc #2, Viroc #3, Glass Limestone, Vical 5075, Vical 2000, Vical 3005, Vical 4000, Vical 4030, Marblemix
CPS: 1317-65-3
Chemical Naiie: CaCOs
htanufactuner: Pfizer Inc. 235 East 42nd Street New York, NY 10017
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-Phone: (619)- 248--7334, (Lucerne,
: Valley, CA Plant)
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.SECTION II. INBFEDIENT5 AMD HAZARDS
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Ingredient Ftame: Limestone .
CAS Waiter: / Percsit: 1 Exposure Limits: -hr:'-
1317-65-3 /.
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;:`h , ACGIH TLV: lO.mg/M35,
. 'i , Total Dust . `
- 0SHA..PEL:. 5 mg/M*.
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Respirable :
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PPm
Chromium (VI) - less thap 0.1 ppm ::>
Lead 1 - "4-6 ppm
These levels are "typical" .quantities andf:mayvchange slightly wiU^i'dif.ferent, lots..
The term "less than" indicates ('that' the'hsubstance .was:, detected,,
airojnL was
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CHARDO 01692
Material Safety Data Sheet
Pfizer Inc.
235 East 42nd Street New York, NY 10017
Product; '.LIMESTONE - LUCERNE VALLEY
tSDS No: MINERAL / MIN010 Revision: 02 Date: -June, 1983
INGREDIENTS AND HAZARDS continued from page 1
less than the quantifiable limit.
Limestone contains crystalline silica at levels above 0.17. but less than 17,, levels are "typical" and may change; slightly with different lots.
These
SECTION III. PHYSICAL DATA,
Appearance & Odor: White powder, no odor Water solubility (X): Insoluble
........ Specific gravity (HaO=l): 2.6-2,8
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SECTION IV. FIRE AND EXPLOSION DATA
Flash Point (method): Non-flammable Extinguishing Media: Nan-flammable. As appropriate for surrounding combustibles. Lhusual fire or explosion hazards: None Special fire-fighting procedures: None
SECTION V. REACTIVITY DATA
Material is stable Hazardous polymerization will not occur Chemical incompatibilities: Reacts with acid to liberate cartoon dioxide gas. Conditions to anxoid: None known" Hazardaus decampasitiXTt Praducts: None
SECTION VI. HEALTH HAZARD INFORMATION
Summary of risks: Calcium Carbonate is !a "Nuisance Particulate". , They "have a long,:, history of little adverse effect on lungs and do not produce significant organic ' disease or toxic effect when exposures are kept under reasonable control" (ACGIH TLV definition). May cause eye and skin irritation from abrasion. .
Primary entry route(s): Inhalation and ingestion.
Acute effects: Abrassiveness may cause eye and skin irritation.
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CHARDO 01693
Material Safety Data Sheet
;Pfizar Inc. 235 East 42nd Street , New York, NY 10017 ,
Product: LIMESTOH LUCERIsE VALLEY ,,
M3DS fto: MINERAL f MIN01Q fWisicn: 02 Date: June, 1980
l-EPLTH HAZARD IInFCR-IATICN continued from page 2
Orel lie effect(s): No known chrcnic health effects.
First aid:
Eye contact: Flush eyes with plenty, of water for at least 15 minutes. . If irritation\persists, ;.seek medical,attention.1 ;
Skin ccntact: Wash from skin with mild soap and water.
Inflation: Remove,from the exposure,area;
Ingestion: Ingestion should not cause any significant health 1 problems.' If a large amount'is ingested and if conscious, give lange quantities of water to induce "vomiting. Get medical attention. ,'
' Limestone is not listed as a carcinogen by :IARC, NTF, OSHA, Or.ACGlH. Crystalline "" 'silica which may be present in quantities less, than 17. has been reviewed by, IARC.
I PRC found limited: evidence for, .carcinogenicity, of, .crystalline silica, in humans .and sufficient evidence in experimental animals.1
SECTION VII. SPILL, LEAK PND DISPOSAL PROCEDURES
Spill / Leak procedures; Those involved in clean-up of spills should use respiratory protection for airborne dust. , Vacuum or scoop up spilled material for recovery or disposal, avoiding dusting conditions and usinq good ventilation. Wetting the spill with a water spray may help to keep the airborne dust levels down.
Waste management / Disposal: Calcium Carbonate is not considered to be a RCRA hazardous waste and may be disposed in a site suitable for industrial wastes. Refer to any local, State or Federal regulations for specific disposal information.
Far transportation emergencies, call 0-EMTREC, 24 hour information service, 1-000--424--9300.
SECTION VIII. 5FECIAL PROTECTION INFCRhATICN
Personal protective .equipnent:
:
Gaggles: .Safety glasses or dust-tight goggles.
Gloves: Leather or rubber gloves.
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CHARDO 01694
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Material Safety Data Sheet
Pfizer Inc. '
'235 East 42nd Street : New York, NY 10017
Pmtrti LIMESTETvE -LUCERNE ,, VALLEY
f*EDS tos MlfvERPL / HXn6iO Revisions 02 __ Date: June, 1988
SPECIAL PROTECTION IWTttTICN/ta)tinued from 'pageVS;;
Respirator: If exposure limits are exceeded.;,'dust respirator
should be used.
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Workplace considerations:
Vtentilaticn: Provide adequate exhaust ventilation to meet TLV^n^irejinmts^^ exhaust filter system may1 "'be required to avoid environmental \
; contamination.
Safety"statimsi , An eyewash station should be
iSble to the area of use.
v.
SECTION IX, SPEEIAL FSECALTTICNS ,
Other precautions: Good industrial hygiene practice requires that employee exposure
tie maintained be lew the recommended TLV. This is/preferapl y achieved thrrugh -thev.;
.provision "of adequate ventilation where necessaijy.vWhere dust- cannot; be ccntrolled
this way, personal respiratory txhstaztim/shSild^
.......
........lr
Whf Class.:; Not, regulated.
Pnepared/revised 'by: M. G. Larsen
January, 1989
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The data1 and recommsndatians presented herein''"are based upon.:aireview,:of_^izer1 files,
published MSDS's, and standard tpxica1ogical> reference sources. Pfizer Inc. makes no guarantee or warranty, either express or implied as to the accuracy or completeness of these data and recommendations.
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CHARDO 01695