Document mQw1DG5ekBpje3qB3Xv56380

FIRE & EXPLOSION INDEX AREA/COUNTRY 6ivisi6n racsrar TOT North America SITE Louisiana manufacturing unit Plaquamlna PROCESS UNIT 1/6/97 Plaquamlna PREPARED BY; Chlor-Alkall 2 D-501 APPROVED BY; (Sup*rlntndant) building John Dizor REVIEWED BY; (MMU0Miwnt) Gratchan C. Lablanc REVIEWED BY; (Tchnt>IOfly Ctntor) 3601 REVIEWED BY; (SlMy A L MATERIALS IN PROCESS UNIT Buck Bailey_______ Chlorine and Hydrogen STATE OF OPERATION BASIC MATERIAL'S) FOR MATERIAL FACTOR ___OESION ___ START UP JLNORMAL OPERATION _SHUTDOWN Hydrogen MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 *F (6C 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor................................................................................................. 1.00 1.00 A Exothermic Chemical Reactions 0.30 to 1.25 0.00 B. Endothermic Processes 0 20 to 0.40 0.00 C. Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0.25 to 0.90 0,00 0.00 E. Access 0.20 to 0.35 0.00 F. Drainage and Spill Control 0 oallons 0.25 to 0.50 0.00 1.00 2. Special Process Hazards Base Factor.................................................................................................. 1.00 A. Toxic Materiai(s) B. Sub-Atmospheric Pressure (< 500 mm Hg) C Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.20 to 0.80 0.50 1. Tank Farms Storage Flammable Liquids 0.50 2 Process Upset or Purge Failure 0.30 3. Always in Flammable Range D Dust Explosion (See Table 3) 0.80 0,25 to 2.00 E Pressure (See Fiaure 2) Derating Pressure 81 osia Relief Settina 150 osia F. Low Temperature 0.20 to 0.30 G. Quantity of Flammable/Unstable Material Quantity 1 lb He = 51.600 BTU/lb 1 Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids in Storage, Dust In Process (See Figure 5) H. Corrosion and Erosion 0.10 to 0.75 1. Leakage - Joints and Packing 0.10 to 1.50 1.00 0.00 0.00 0.00 0.30 0.00 0.00 0.26 0.00 0.00 0.00 0.00 0.20 0.00 J. Use of Fired Equipment (See Figure 6) K. Hot Oil Heat Exchange System (See Table 5) 0.15to 1.15 0.00 0.00 L. Rotating Equipment 0.50 Special Process Hazards Factor (F2)............................................................................ Process Unit Hazards Factor (FI x F2) * F3.............................................................. Fire and Explosion Index (F3 x MF F&EI).................................................................. 0.00 1.76 1.76 37 (1) For no penalty use 0.00. A 037035 CONFTDFNTTAl. FORM^^^J.a^7^?^|!^y{;.MWRPWrofles\u239601 \Desktop\Fei7denw\[ca2_1997.xls]FEI7_TMP MF DataFile:C:\WINDOWS\Profiles\u23960l\Desktop\Fei7denw\FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a Emergency Power b. Cooling C, Explosion Control d. Emergency Shutdown e Computer Control Credit Factor Range 0.88 0.87 to 0.88 0.84 to 0 88 0.86 to 0.88 0.83 to 0.88 Credit Factor Used (2) 0.88 1.00 1.00 0.88 0.83 Feature f. Inert Gas 9 Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.84 to 0.86 0.81 to 0,88 0.81 to 0.88 0.81 to 0.88 Credit Factor Used (2) 0.86 0.81 0.81 0.88 Cl Value (3) | 0.696 | 2. Material Isolation Credit Factor (C2) Feature a. Remote Control Valves b Dump/Blowdown Credit Factor Range 0.96 to 0.98 0.96 to 0 98 Credit Factor Used (2) 096 0.96 Feature c Drainage d. Interlock C2 Value (3) | 0.922 | 3 Fire Protection Credit Factor (C3) Feature a Leak Detection b. Structural Steel c. Fire Water Supply d Special Systems e Spnnkler Systems Credit Factor Range 0 94 to 0.98 0.9S to 0.98 0.94 to 0.97 0 91 0 74 to 0.97 Credit Factor Used (2) 0.98 1 00 0 97 1.00 1.00 Feature f. Water Curtains 8 Foam h Hand Extinguishers/Monitors i. Cable Protection C3 Value (3) | 0.922 | Loss Control Credit Factor Cl x C2 x C3 (3) * | 0.591 | Credit Factor Range 0,91 to 0.97 0.98 Credit Factor Used (2) 1.00 1.00 Credit Factor Range 0.97 to 0.88 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1,00 0 97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1 Fire and Explosion Index (F&EI).............. (See Front) 37 2. Radius of Exposure................................... <Fi*ur7) 31 ft 3 Area of Exposure.................................................................. - 3,028 q.ft. 4. Value of Area of Exposure 1968 Dollars................................................................................ $MM 5. Damage Factor....................................................... <fi* i| 0.48 6. Base Maximum Probable Property Damage - (Base MPPD) [4 x 5]................... $MM 7. Loss Control Credit Factor ................................(See Above)| 0.59 8. Actual Maximum Probable Property Damage - (Actual MPPD) [6x7]... ..................... $MM 9. Maximum Probable Days Outage - (MPDO) if^. s> 10, Business Interruption - (Bl).............................................................................. 20 ays ................................. |$MM 4.50 2.15 1.27 3.P* | | | * (2) For no credit factor enter 1.00 (3) Product of all factors used ^ONFIDFNTTAi. Refer to "Fire & Explosion Index Hazard Classification Guide'1 (Form #471-00001) for details aACKOFFO^(^`.v^m7.^lf.7eyMIWRPyy5^'e^239601\DeSktop\Fei7denw\[ca2_1997.xls]FEI7_TMP MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE A EXPLOSION INDEX - DATA AND COMMENTS Material Factor Material la From Database Material Name - Hydrogen Baaa Malarial Factor *21 Actuated Material Factor 21 Haai of Cwnbutten <BTu*>) - biboo Nti-0 Nf-4 Nr 0 Flash Point (*F) Gas BoHmg Point (*F) - -423 Procaaa Unit Tamparatura (*F) IS Exotherm Tamparatura (*F) * 1000000 Autoignition Tamparatura (*F) 1000000 Data For User Specified Material Ganaral Procaaa Hazards A Exothermic Chamical Reaction* Process Unit NOT A REACTOR and/or NO EXOTHERM occurs (Penalty-0) Comment 0 6. Endothermic Processes Process Unit NOT A REACTOR > Penalty-0 Comment 0 C Matenal Handling and Transfer None of the following situations apply (Penatty-0) Comment 0 D, Enclosed or Indoor Process Units Process is NOT ENCLOSED (Penelty-0) Comment 0 E. Access Access determined adequate for emergency equipment (Penalty>0) Comment 0 F Drainage and Spill Control Diking and drainage urtiich meats all entena (see help) (Penalty-0) Comment 0 Special Procaai Hazards A. Tone Matenel(s) Equals two tenths of the Nh B Sub-Atmosphenc Pressure << 500 mm Hg) Greater than 500 mmHg (Penalty-0) Comment 0 C, Operation In or Near Flammable Range Process can reach flammable range only in the event of instrument Comment 0 D Dust Explosion Process does not include dusts (Panalty-0) Comment 0 E Pressure Comment 0 F Low Tamparatura Temperatures remain safely above the ductile/bnttle Comment 0 G Quantity of Ftemmabie/Unstabia Matenal In Procats Comment 0 H Corrosion and Erosion Corrosion rate between 0 5 and 1 00 mrrtyr (Panalty-0 20) Comment External and Localized Corrosion I. Leakage - Joints and Packing Leakage of flsmmablei/eombuetibtes is insignificant Comment 0 J Use of Fired Equipment DOES NOT exist in the plant with the Process Unit Comment 0 K, Hot Oil Hast Exchange System Process does not use a hot oil exchange system, or the hot oil is not above it's boiling point Comment 0 L Rotating Equipment No rotating equipment deemed to be a hazard (No Penalty) Comment 0 pit-' *rW" v'3 S. M) Print Datr 1/16/07, Wort File CAWINDOWS\Prefiltato23960l\Deektop\Fai7denwca2JB7,xls]FEl7,.TMP MF DateFile,CAWINDOWS\ProfiteSlu23B60l\De*ktop\Fel7denw1FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS FrocoM Control Credit Fictor (Cl I 8) Emergency Power Automatic twiteft to emergency power for CRITICAL SERVICES Comment: 0 b) Cooling No credit (Factor*!.0) Comment: 0 c) Explosion Control No craM (Factoml.O) Comment 0 d) Emergency Shutdown Redundancy tystem that initiate! a shutdown (Factor*0.96) Comment. 0 e) Computer Control Computer with "faiLsafe* logic and at least one of the Comment 0 f) inert Gas Inert gas pad employed (Factor*0.96) Comment: 0 g) Operating instructions/procedures 1. Startup, 2. Routine Shutdown, 3 Normal operating conditions. 4. Turndown operating conditions, Comment: 0 h) Reactive Chemical Review Reactive Chemical program is a continuing part of operations Comment. Annual refresher training for all plant employees i) Other Process Hazard Analysis Management of Change Review (Factom0.98) Comment. 0 Material Isolation Credit Factor (C2) a) Remote Control Valves Remotely operated isolation valves exist AND are cycled at Comment: 0 b) Dump/Blowdown Process employs an emergency flare system OR a dosed vent Comment: 0 c) Drainage 0 Comment. 0 d) Interlock No credit (Fador=1 0) Comment: 0 Fire Protection Credit Factor (C3) a) Leak Detection Gas detectors alarm and identify a zone only (Factor*0,98) Comment- 0 b) Structural Steel No credit (Factor*1.0) Comment: 0 c) Fire Water Supply Firefighting water can be supplied for 4 hours at iess than 100 Comment: 0 d) Special Systems No credit (Factor*1 0) Comment: 0 e) Sprinkler Systems No credit (Factor*1 .0) Comment: 0 f) Water Curtains No credit (Factor*1 0) Comment: 0 g) Foam No credit (Factor*1.0) Comment- 0 h) Hand Extinguishers/Monitors The process is protected by monitor guns (Factor*0.97) Comment. 0 I) Cable Protection No credit (Fector*1.0) Comment: 0 00 A 03703B OONF TDFNTT Al IFIE-7 V*-2 S #*] Print Date 1/16/97. Worit File: C:\WIND0WS\Profile5\u239601\Desktop\Fei7denw\tca2_1997jds]FEI7_TMP MF DataFile.C:\WlNDOWS\Ptofilea\u239601 \Deatctpp\Fel7denw\FEI7_DAT.XLS $1' FIRE & EXPLOSION INDEX AREA/COUNTRY TO3!T LOCATION ir DATE North America SITE Louisiana MANUFACTURING UNIT Plaquemlne PROCESS UNIT 1/6/97 Plaquemlne PREPARED BY: Chlor-Alkall 2 Hyrdogen Trailer APPROVED BY: (SupHlnttMtant) BUILDING John Dizor REVIEWED BY: (M.n*gennt) Gretchen C. Leblanc REVIEWED BY: (Technology Center) 3601 REVIEWED BY: (SeMy S U Prevention) MATERIALS IN PROCESS UNIT Buck Bailey____________________ Hydrogen STATE OF OPERATION BASIC MATERIALS) FOR MATERIAL FACTOR __cxeroN __ itartuf _s_normalopcration enuraowN Hydrogen MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 *F (SC 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used(1) Base Factor................................................................................................. 1.00 1.00 A. Exothermic Chemical Reactions 0.30 to 1.25 0.00 B. Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0 25 to 0.90 0.85 0.00 E. Access 0.20 to 0.35 0.00 F. Drainage and Spill Control 0 oallons 0.25 to 0.50 0,00 General Process Hazards Factor (FI)............................................................................ 1.85 2. Special Process Hazards Base Factor................................................................................................. 1.00 A. Toxic Material(s) 0.20 to 0.80 B. Sub-Atmospheric Pressure (< 500 mm Hg) C. Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.50 1 Tank Farms Storage Flammable Liquids 0.50 2. Process Upset or Purge Failure 0.30 3 Always in Flammable Range D. Dust Explosion (See Table 3) 0.80 0.25 to 2.00 E. Pressure (See Fiaure 2) Ooeratino Pressure 2,200 osto Relief Setting 2,500 osio F Low Temperature 0 20 to 0 30 G. Quantity of Flammable/Unstable Material Quantity 320 lb Ho = 51.600 BTU/lb 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids in Storage, Dust in Process (See Figure 5) H Corrosion and Erosion 0.10 to 0.75 1. Leakage - Joints and Packing O.IOtol.SO 1.00 0.00 0.00 0.00 0.00 0.80 0.00 1.15 0.00 0.00 0,07 0.00 0.00 0.00 J. Use of Fired Equipment (See Figure 6) 0.05 K. Hot Oil Heat Exchange System (See Table 5) 0 15 to 1.15 L Rotating Equipment 0.50 Special Process Hazards Factor (F2)............................................................................ Process Unit Hazards Factor (FI x F2) F3.............................................................. Fire and Explosion Index (F3 x MF * F&EI).................................................................. 0.00 0 00 3.07 S.68 119 (1) For no penalty use 0.00. 00 A 037039 CONFTOENTTA1 les\u239601\Desktop\Fei7denw\[CA2 97 D-501 .xls]FEI7_TMP MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Fector (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown e. Computer Control Credit Factor Range 0.88 0.87 to 0.88 0.84 to 0.88 0 86 to 0 99 0.93 to 0.99 Credit Fector Used (2) 1.00 1.00 1.00 1.00 1.00 Feature f. Inert Gas 8- Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0,94 to 0.96 0.91 to 0.99 0.91 to 0.98 0.91 to 0.98 Credit Factor Used (2) 1.00 0.91 0.91 0.98 Cl Value (3) | 0.811 | 2. Material Isolation Credit Factor (C2) Feature a. Remote Control Valves b Dump/Blowdown Credit Factor Range 0 96 to 0.98 0.96 to 0.98 Credit Factor Used (2) 1.00 1 00 Feature c Drainage d. Interlock C2 Value (3) | 1,000 | 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b Structural Steel c. Fire Water Supply d. Special Systems e. Sprinkler Systems Credit Factor Range 0.94 to 0.96 0 95 to 0.88 0,94 to 0 97 0.81 0.74 to 0.97 Credit Factor Used (2) 1.00 1.00 0.97 1.00 1.00 Feature t Water Curtains 9 Foam h Hand Extinguishers/Monitors i. Cable Protection C3 Value (3) | 0.941 | Loss Control Credit Factor Cl x C2 x C3 (3) | 0.763 | Credit Factor Range 0.91 to 0.97 0.98 Credit Factor Used (2) 1.00 1.00 Credit Factor Range 0.97 to 0.98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1.00 0 97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (FSEI).......... (See Front) 119 2. Radius of Exposure.................... .............. 100 ft 3. Area of Exposure.................................................................... 31,544 q ft. 4. Value of Area of Exposure 1968 Dollars................................................................................. $MM 5. Damage Factor........................................................ tFiur | 0.77 2.00 | 6. Base Maximum Probable Property Damage - (Base MPPD) (4 x 5].................. $MM 7. Loss Control Credit Factor ........................(See Above)| 0.76 8 Actual Maximum Probable Property Damage - (Actual MPPD) [6 x 7].... ................ $MM 89. Maximum Probable Pays Outage - (MPDQ)_________rriaurcn__________ 13____________ays 10 Business Interruption - (Bl)............................................................ ............................... |tMM 1.54 1,17 1.90 | | (2) For no credit factor enter 1.00 (3) Product of all factors used Refer to "Fire & Explosion Index Hazard Classification Guide" (Form #471-00001) for details nn A 0370A0 J ^ tjp>47 T Al C-ONi" B*CKci'fArPi?isaV?JvS7.M^9ftc^i^:-p^M'^^Bfl)I/'fl.r85tes'IJ^^9601^Des^top\Fei7denw\(CA2 97 D-, jrEi/_TMP MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX - DATA AND COMMENTS Material Factor Material la From Database Material Name - Hydrogin Baaa Material Factor- 21 Adluated Material Factor - 21 Haat of Combustion <BTU/lb) 51600 Nh-0 Nf-4 Nr 0 Fiaah Port (*F) - Oas Bolting Point (*F) - -423 Process Unit Tompareture (*F) - 120 Exotherm Temperature (*F) 1000000 Autoignttion Tamparatura (*F) 1000000 Data For U$y Specified Material General Process Hazard* A. Exothermic Chemical Reaction* Proceai Unit NOT A REACTOR indtor NO EXOTHERM occurs (PenaRy*0) Comment 0 B Endotharmre Processes Process Unit NOT A REACTOR - Penalty-0 Comment 0 C Material Handling and Transfer Warehouse or yard storage (Penalty-0 25 to 0 85) Comment 0 D Enclosed or Indoor Process Unrts Process is NOT ENCLOSED (Penatty-0) Comment 0 E Access Access determined adequate tor emergency equipment (Panetty-0) Comment 0 F Drainage and Spill Control Diking and drainage which meets all entena (see help) (Penalty-0) Comment 0 Special Procen Hazard! A Toxic Metenel(s) Equals two tenths of ths Nh 6 Sub>Atmosphenc Pressure (< 500 mm Hg) Greater then 500 mmHg (Penalty>0) Comment 0 C Operation In or Near Flammable Range Process that is by nature ALWAYS m or near the flammable Comment 0 D Dust Explosion Process does not include dusts (Penalty-0) Comment 0 E Pressure Comment 0 F Low Temperature Temperatures remain safely above the ductale/bnttte Comment 0 G Quantity of Ftemmabfe/Unttebte Materiel in Storage Comment 0 H Corrosion end Erosion Corrosion rote* Irolow 0 5 mm/yr WITHOUT risk of pitting Comment i Leakage Joints and Packing Laakaga of Aemmebtes/comtoustibtos Is insignificant Comment 0 j, Use of Fired Equipment DOES exist in the plant with the Process Unit Comment 0 K. Hot OH Heat Exchange System Process does not use a hot oil exchange system, or the hot oil is not above it's boiling point Comment 0 L. Rotating Equipment No rotating equipment deemed to be e hazard (No Penalty) Comment 0 A 03704t c ONF rDONT.TA( Print Date. 1/20/67, Work File C \WINDOWS\Prefllas\u230e0l\Da*ktop\Fai7denvA[CA2 67 D-50l.xi*)FEI7_TMP MF D*taFiteC'\WINDOWS\Prefli**W239eoi\D**ttopiF*i7denWtFEI7_DAT.XL$ LOSS CONTROL CREDIT FACTORS DATA AND COMMENTS Pfoc> Control Credit Factor (C1I a) Emergency Power No credit (Factor-1.0) Comment: 0 b) Cooling No credit (Factor*1.0) Comment: 0 c) Exploeion Control No credit (Fectoml.O) Comment 0 d) Emergency Shutdown No credit (Factor*1.0) Comment: 0 e) Computer Control No credit (Factoml.O) Comment: 0 <) Inert Ga* No credit (Fector-1.0) Comment 0 g) Operating ln>tnrctioni/Procedure> 1. Startup, 2. Routine Shutdown, 3. Normal operating conditions 4. Turndown operating conditions. Comment: 0 h) Reactive Chemical Review Reactive Chemical program la a continuing part of operations Comment: Annual refresher training for all plant employees. i) Other Process Hazard Analysis Management of Change Review (FaciomO 0B) Comment: 0 Material Isolation Credit Factor IC2I a) Remote Control Valves No credit (Factor* 10} Comment: 0 b) Dump/Blowdown No credit (Factorot.O) Comment: 0 c) Drainage 0 Comment. 0 d) Interlock No credit (Factoml .0) Comment: 0 Fire Protection Credit Factor (C3) a) Leak Detection No credit (Factor*1.0) Comment. 0 b) Structural Steel No credit (Factor*1.0) Comment: 0 c) Fire Water Supply FirefiQhtlng water can be supplied for 4 hours at less than 100 Comment 0 d) Special Systems No credit (Factor*1,0) Comment: 0 a) Spnnkler Systems No credit (Factor* 1.0) Comment. 0 f) Water Curtains No credit (Factor* 1.0) Comment. 0 g) Foam No credit (Factor* 1.0) Comment* 0 h) Hand Extinguishars/Monitors The process is protected by monitor guns (Factor*0.97) Comment: 0 i) Cable Protection No credit (Factor*1.0) Comment. - (FIE-7 Sr**TM V*r-2 4MMC] Print Date 1/2CV07, Work File: C:\WlNDOWS\Profiles\u239601\Desktop\Fei7denw\lCA2 97 D~50l.xls]FEl7,JMP MF DeteFile,C:\WINDOWS\Profiles\u239601\DesMop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX AftKA/iiWWTiW 1 Wi&5T ToSaTOR------------------------- RATE'"......... ......................... North America Louisiana Plaquemlne 1/6/97 { SITE MANUFACTURING UNIT PROCESS UNIT Plaquemine PREPARED BY; Chlor-Alkall 2 Taffy Pot APPROVED BY; (Suparinfendant) BUILDING John Dizor REVIEWED BY; (Minigamtiit) Gretchen C. Lablanc REVIEWED BY; (Technology Confer) 3601 REVIEWED BY; (Safety * Loa* Prevention) MATERIALS IN PROCESS UNIT Buck Bailey Nitrogen Trichloride, Chlorine, Carbon Tet STATE OF OPERATION BASIC MATERIAL^} FOR MATERIAL FACTOR __Dfc**ON tTAHT UP J(J*OftliUl OPERATION SHUTDOWN Nitrogen Trichloride MATERIAL FACTOR (Sw Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 *F (6C 40 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Uaed (1) Base Factor.......................................................................................... -- A. Exothermic Chemical Reactions 1.00 0.30 to 1,25 1.00 0.00 B. Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0.25 to 0.90 0.00 0.00 E, Access 0.20 to 0.35 0.00 F Drainage and Spill Control 0 gallons 0.25 to 0.50 0 00 General Process Hazards F 1.00 2. Special Process Hazards Base Factor................................................................................................. 1.00 A Toxic Material(s) B Sub-Atmospheric Pressure (< 500 mm Hg) C. Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.20 to 0.80 0.50 1. Tank Farms Storage Flammable Liquids 0.50 2 Process Upset or Purge Failure 0.30 3. Always in Flammable Range D. Dust Explosion (See Table 3) 0.80 0 25 to 2.00 E Pressure /See Fiaure 2) Deratino Pressure 70 osio Relief Settina 150 DSia F. Low Temperature 0.20 to 0.30 R Ouantitv of Flammable/Unstable Material Quantity 1 lb He 0 BTU/lb 1.00 0.60 0.00 0.00 0.30 0.00 0.00 0.14 0.00 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases In Storage (See Figure 4) 3. Combustible Solids in Storage. Dust in Process (See Figure 5) H. Corrosion and Erosion 1. Leakage - Joints and Packing 0.10 to 0.75 0,10 to 1.50 0.00 0.00 0.00 0.75 0.00 J. Use of Fired Equipment (See Figure 6) K. Hot Oil Heat Exchange System (See Table 5) 0 15 to 1.15 L Rotating Equipment 0.50 Special Process Hazards Factor (F2)........................................................................... 0.00 0.00 0.00 2.79 Process Unit Hazards Factor (FI x F2) * F3.............................................................. 2.79 Fire and Explosion Index (F3 x MF F&EI).................................................................. 111 (1) For no penalty use 0.00. Oo ^-O/yp- Waw^,ofiles\u23961\DesKtop\Fe,7denw\CA2 97 D-227 Taffy Pot.xls MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown e. Computer Control Credit Factor Range 0.98 0.97 to 0,99 0.84 to 0.88 0.96 to 0.99 0.93 to 0.99 Credit Factor Used (2) 0.98 1.00 1.00 0.98 0.93 Feature f. Inert Gas 0 Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.68 0.91 to 0.98 Credit Factor Used (2) 0.94 0.91 0.61 0.98 Cl Value (3) | 0.681 | 2. Material Isolation Credit Factor (C2) Feature a Remote Control Valves b. Dump/Blowdown Credit Factor Range 0.96 to 0.98 0 96 to 0.98 Credit Factor Used (2) 0.96 1.00 Feature c Drainage d. Interlock C2 Value (3) [ 0,960 | 3 Fire Protection Credit Factor (C3) Feature a Leak Detection b. Structural Steel c Fire Water Supply d. Special Systems e. Sprinkler Systems Credit Factor Range 0.94 to 0.98 0.95 to 0.98 0.94 to 0 97 0.91 0.74 to 0.97 Credit Factor Used (2) 0.98 1.00 0.97 1.00 1.00 Feature f. Water Curtains g Foam h. Hand Extinguishers/Monitors I Cable Protection C3 Value (3) | 0.922 | Loss Control Credit Factor Cl x C2 x C3 (3) = | 0.603 | Credit Factor Range 0 91 to 0.97 0.98 Credit Factor Used (2) 1 00 1.00 Credit Factor Range 0 97 to 0.98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1.00 0.97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F&EI).......... (See Front) Ill 2. Radius of Exposure ................................... (njurT) 94 ft 3. Area of Exposure.................................................................... 27.513 q.ft. 4. Value of Area of Exposure 1968 Dollars................................................ ............................... $MM 5 Damage Factor....................................................... <ngm)| 0.78 6. Base Maximum Probable Properly Damage - (Base MPPD) [4 x 5]................... 7. Loss Control Credit Factor ........................(See Above)| 0.60 $MM 2.00 1.55 | | 8 Actual Maximum Probable Properly Damage - (Actual MPPD) [6 x 7].... ................ $MM 0.93 | 9, Maximum Probable Days Outage - (MPDO) (Figuoi 10, Business Interruption - (Bl).............. ............................................ 21 ays ......................... ... ,, |$MM 3.08 ------------------ I 00 A 037044 (2) For no credit factor enter 1.00 (3) Product of all factors used CONFIDFNTTAI. Refer to "Fire S Explosion Index Hazard Classification Guide" (Form #471-00001) for details BACK OF WVv?.'Mles'u239601\DesktoP\Fei7denw\CA2 97 D-227 Taffy Pot.xls MF DataFile:C:\WINDOWS\Profl!es\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX * DATA AND COMMENTS Material factor Materiel It User Specified (NOT In petobete) Material Neme * Nteogan Titefttoride Bata Material Factor - 40 A*uited Materiel Factor-40 Haat of Combustion (BTU/fo) 0 Nh - 3 Nf*0 Nf-4 Flesh Po*rt(*F>*N/A Boibng Point <*F) * N/A Process Unit Temperatora (*F)BQ Exotherm Temperature (*F) 100 Autoignition Temperature (*F) * 1000000 Data For Uaer Specified Material Nr Selection, Bated On OuaMative Input Nf Selection Bated On' Non-eombuttibla Nh Selection Bated On. Nh-3 Mstenelt eauting aenout temporary or retidual injury Input Heat Of Combustion (BTUAb) 0 Comment - General Procett Hazards A Exothermic Chemical Reactions Procett Unit NOT A REACTOR endtor NO EXOTHERM occur* (Penelty-0) Comment 0 B Endothermic Processes Procett Unit NOT A REACTOR > Penalty-0 Comment 0 C Materiel Handling and Transfer None of the following tnuabont apply (PenaKy0) Comment 0 0 Enclosed or Indoor Procett Unite Procett it NOT ENCLOSED (Penefty-0) Comment 0 E Aocett Aocett determined adequate for emergency equipment (Penelty-0) Comment 0 f, Drainage end $pdl Control Diking and drainage which maett all entena (tee help) (Peneity*0) Comment 0 Special Procett Hazards A Toxic Materiai(a) Equate two tentht of the Nh B Sub-Atmotphtnc Protturt (< 500 mm Hg) Greater than 500 mmHg (Penelty*0) Comment 0 C Operation In or Near Flammable Range Procett can reach flammable range only in the event of instrument Comment 0 D, Duet Expiotion Procett does not indude dutte (Penelty-0) Comment 0 , Pretture Comment 0 F Low Temperature Temperatures remain safety above the ductile/bnttte Comment 0 G Quantity of Fiammebte/Unstabie Material No Flammebto/Unitsbte Material Comment 0 H, Corrosion end Erosion A potential for atiesa-corrotion credung exist* (Penelty-0.75) Comment ~ I. Leakage - Joints end Pecking I of flemmebieireombuttiblei It insrptlflcant Comment 0 J Use of Fired Equipment DOES NOT exist m the plant with the Prooes* Unit Comment 0 K. Hot Oil Heat Exchange System Process does not use a hot oH exchange system, or the hot oil is not above If* boiling point Comment 0 L. Rotating Equipment No rotating equipment deemed to be hazard (No Penalty) Comment 0 (FIS T S>^n V-J * W>) OO A O3704 CONF TOFNT TA| Print D.|t 1/21/97, Wort Fife. CAWINDOWS\Prellll\u23960t\Dktop\F7ii.nWCAS 07 D-227 Tlty Pot idi MF Dit*F.rt CAWINDOWS\Profil\u!3960HCmkU)p\Fr7llnwlFEI7_DAi aw LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Proce Control Credit Fector (Cl) a) Emergency Power Automatic switch to emergency power for CRITICAL SERVICES Comment: 0 b) Cooling No credit (Factor*! ,0) Comment 0 c) Explosion Control No credit (Factor*! ,0) Comment: 0 d) Emergency Shutdown Redundancy system that initiates a shutdown (Factor*0.98) Comment: 0 e) Computer Control Computer with "fail-safe" logic and at least one of the Comment: 0 f) Inert Gas Inert gas system can automatically purge total volume of unit Comment: 0 g) Operating Instructions/Procedures !. Startup, 2. Routine Shutdown, 3. Normal operating conditions, 4. Turndown operating conditions. Comment: 0 h) Reactive Chemical Review Reactive Chemical program is a continuing part of operations Comment: Annual refresher training for all plant employees. i) Other Process Hazard Analysis Management of Change Review (Factor*0.98) Comment: 0 Material Isolation Credit Factor (C2) a) Remote Control Valves Remotely operated isolation valves exist AND are cycled at Comment: 0 b) Dump/Blowdown No credit (Factor*! .0) Comment. 0 c) Drainage 0 Comment. 0 d) Interlock No credit (Factor*1.0) Comment; 0 Fire Protection Credit Factor (C3) a) Leak Detection Gas detectors alarm and Identify a zone only (Fador=0 68) Comment' 0 b) Structural Steel No credit (Factor*! .0) Comment: 0 c) Fire Water Supply Firefighting water can be supplied for 4 hours at less than ! 00 Comment' 0 d) Special Systems No credit (Factor*l.O) Comment: 0 e) Sprinkler Systems No credit (Factor*! .0) Comment: 0 f) Water Curtains No credit (Factor*1.0) Comment 0 g) Foam No credit (Factor*! .0) Comment: ~ h) Hand Extinguishers/Monitors The process is protected by monitor guns (Factor-0,07) Comment: - i) Cable Protection No credit (Factor*! .0) Comment - A 0?7n/i GQNF T DFN T j^,6 [FIE-T ftrM*n W-2 S 4MMS] Print Date 1/21A97, Work File; C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\CA2 97 D-227 Taffy Potxls MF DataFHe:C.\WINDOWS\Profiles\u239601\Desktop\Fel7denvAFEI7_DAT.XLS FIRE & EXPLOSION INDEX AREA/COUNTRY DIVISION LOCATION " " TOS---------------------------------------- North America SITE Louisiana MANUFACTURING UNIT Plaquemlne PROCESS UNIT 1/6/B7 Plaquemlne PREPARED BY; Chlor-Alkall 2 Chlorine Cells APPROVED BY; (Supaflntarxfent) BUILDING John Dizor REVIEWED BY: (Marugamant) Gretchen C. Leblanc REVIEWED BY: (Tactinology Carrtar) 3601 REVIEWED BY: (Safety S Low PnwnUon) MATERIALS IN PROCESS UNIT Buck Bailey * Chlorine, Caustic, and Hydrogen STATE OF OPERATION BASIC MATERIAL^) FOR MATERIAL FACTOR __DE1WN .STARTUP ^NORMAL OPERATION SHUTDOWN Hydrogen MATERIAL FACTOR (See Table 1 Of Appendices A or B) Note requirements when unit temperatures over 140 *F (6C 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor................................................................................................. A. Exothermic Chemical Reactions 1.00 0.30 to 1.25 1.00 0.00 B Endothermic Processes 0 20 to 0.40 0.20 C. Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0.25 to 0.90 0.50 0.00 E. Access 0.20 to 0.35 0.00 F. Drainage and Spill Control 0 aallons 0.25 to 0.50 0 00 General Process Hazards FAr.tnr (FI)........................................................... ....... . 1.70 2. Special Process Hazards Base Factor................................................................................................. 1.00 A. Toxic Material(s) 0.20 to 0.80 B. Sub-Atmospheric Pressure (< 500 mm Hg) 0 50 C Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 1 Tank Farms Storage Flammable Liquids 0.50 2. Process Upset or Purge Failure 0.30 3. Always in Flammable Range D. Dust Explosion (See Table 3) 0 80 0.25 to 2.00 E Pressure fSee Fioure 2) ODeratina Pressure 0 dsiq Relief Setting 0 osla F. Low Temperature 0.20 to 0.30 G Quantity of Flammable/Unstable Material Quantity 51 lb He * 51.600 BTU/lb 1.00 0.00 0.00 0.00 0.30 0.00 0.00 0.16 0.00 1. Liquids or Gases in Process (See Figure 3) 2 Liquids or Gases in Storage (See Figure 4) 3 Combustible Solids In Storage. Dust in Process (See Figure 5) H. Corrosion and Erosion 1. Leakage Joints and Packing 0.10 to 0.75 0.10 to 1.50 0.00 0.00 0.00 0.50 0.30 J Use of Fired Equipment (See Figure 6) K, Hot Oil Heat Exchange System (See Table 5) 015 to 1.15 L Rotating Equipment 0.50 Special Process Hazards Factor (F2)................................................................................................ 0.00 0.00 0.00 2.26 Procsss Unit Hazards Factor (FI x F2) F3.............................................................. 3.84 Fire and Explosion Index (F3 x MF * F&EI).................................................................................... 81 (1) For no penalty use 0.00. DO A 037047 CONFIDENTIAL F^^te:R^VWM^fJlftE9^W9.^WleS\u239601\DeSktop\Fei7denw\CA2 97 * 5 Chlorine Cells.xls MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown e. Computer Control Credit Factor Range 0.68 0.87 to 0.88 0.84 to 0.88 0.86 to 0.88 0.83 to 0.88 Credit Factor Used (2) 1.00 1,00 0.88 0.88 0.83 Feature f. Inert Gas 0 Operating Instructions/Procedures h. Reactive Chemical Review 1, Other Process Hazard Analysis Credit Factor Range 0.84 to 0.86 0.61 to 0.88 0.81 to 0.88 0.81 to 0.88 Credit Factor Used (2) 0.84 0.85 0.81 0.88 Cl Value (3) | 0,711 | 2. Material Isolation Credit Factor (C2) Feature a Remote Control Valves b. Dump/Blowdown Credit Factor Range 0.86 to 0.88 0.88 to 0 88 Credit Factor Used (2) 1.00 0.86 Feature c Drainage d Interlock C2 Value (3) | 0.856 | Credit Factor Range 0.81 to 0,87 0 88 Credit Factor Used (2) 0.91 0.88 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b Structural Steel c Fire Water Supply d. Special Systems e. Sprinkler Systems Credit Factor Range 0.94 to 0.88 0.95 to 0 88 0.94 to 0,97 0 91 0 74 to 0.97 Credit Factor Used (2) 0.98 1.00 0.97 1.00 1.00 Feature f Water Curtains g Foam h Hand Extinguishers/Monitors i. Cable Protection C3 Value (3) | 0.922 | Loss Control Credit Factor Cl x C2 x C3 (3) * | 0.561 | Credit Factor Range 0,97 to 0.98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1,00 0.97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1, Fire and Explosion Index (F4EI).......... (See Front) 81 2. Radius of Exposure................................... irw7| 68 ft 3. Area of Exposure........................................ ........................... 14,420 q.ft. 4 Value of Area of Exposure 1968 Dollars................................................................................. SMM 5. Damage Factor....................................................... <FiguTM)| 0.53 3.00 | 6, Base Maximum Probable Property Damage - (Base MPPD) [4 x 5].................. 7. Loss Control Credit Factor ........................(SeeAbove)| 0.56 $MM 1.58 | 8. Actual Maximum Probable Property Damage - (Actual MPPD) [6 x 7].... 8, Maximum Probable Days Outage (MPDO) (Figures) 12 10. Business Interruption (Bl). ................ SMM ays $MM 0.89 1.74 (2) For no credit factor enter 1.00 (3) Product of all factors used | ------- , DO A 037048 oonftdfnt tai,, Refer to "Fire & Explosion Index Hazard Classification Guide" (Form #471-00001) for details BACKorpF3&o1m ^9Mi!e,^W9m^u239601^esktoP\Pei7denw\CA2 97 - 5 Chlorine Cells.xls MF DataFi!e:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX - DATA AND COMMENTS Mdtdrttl Factor Material it From Database Material Ham* - Hyftogan Baa# Material Factor-21 Asfuated Material Factor* 21 Haat of Combustion (BTU/to) * 91400 Nh*0 Hi-4 Nr- 0 Ftoah Paint (*F) - Oai toting Point (*F) - -422 Proeatt Unit Tamporaturt (*F) 190 Exxriherm Tarrgiemture (*F) - 1000000 Autoignition Tamparatura CF) 1000000 Data For U9r 5pacified Material Ganaral Proeatt Hazardi A. Exothermic Chamcal Reactions Proeatt Unit NOT A REACTOR and/or NO EXOTHERM OCCurt (Penalty-0) Comment 0 B. Endothermic Procatsat REACTOR with ELECTROLYSIS REACTION --> Penaity-0.20 Comment 0 C. Matonal Handling end Transfer Potential tor Introduction of air Into proeatt (Penaity-0,50) Commant 0 D Enetotad or Indoor Proeatt Units Proeatt it NOT ENCLOSED (Penaity-0) Commant 0 E. Aceatt Accatt datarminad adaquita for amergancy equipment (Penalty-D) Commant 0 F, Drainage and Spill Control Diking and drainage which meats ell entena (taa help) (Penetty*0) Commant 0 Special Proceaa Hazard* A- Tonic Matenal(i) Equals two tenths of tha Nh B Sub-Atmosphanc Pressure (< SD0 mm Hg) Creator than 900 mmHg (Penaity0) Commant 0 C Operation In or Near Flammable Range Process can raaeh flammable range only In tha event of instrument Commant 0 D. Dust Explosion Process does not include dusts (Penalty-0) Commant 0 E Pressure Commant 0 F. Low Temperature Temperatures remain safely above tha ductika/bnttto Commant 0 0 Quantity of FlemmeWe/Unatabto Matanal to Precast Comment 0 H Corrosion and Erosion Corrosion rata greater than 1.00 mnVyr (Panaity-0 50) Commant Cent made from corrosion resistant metenali 1 Leakage - Joints and Packing Regular leakage problems ansi at pumps, compressors, and Commant 0 J Uta of Fired Equipment DOES NOT exist m tha plant with tha Process Unit Comment 0 K. Hoi Oil Heat Exchange System Process does not use a hot oil exchange system, or tha hot oil is not above it's boiling point Comment 0 l Rotating Equipment No rotating equipment deemed to be a hazard (No Penalty) Commant 0 |T<.7 aytoi Vb.2 J. 4S) no A 037049 CONFTDFNTTAI Pnnt Dite 1/21/87, Wort; Filo. C \WINOOWS\PrtrtHU\u23M01\Dnktop\Foi7domrtCA: 97 - S Chlortno Colli III MF DoloFilo.C.\WINW3AS\Pra(il\u23#01\OMktop^ol7<IOfMrtFEI7_OAT XLS LOSS CONTROL CREDIT FACTORS DATA AND COMMENTS Procaat Control Credit Factor (C1> a) Emergency Power No credit (Factor-1.0) Comment: 0 b) Cooling No credit (Factor-1.0) Comment 0 c) Explosion Control Rupture diaphragm* or explosion went* (Factor-0 99) Comment 0 d) Emergency Shutdown Redundancy system that Initiates a shutdown (Factor-0.99) Comment: 0 e) Computer Control Computer with Tail-safe' logic and at least one of the Comment: 0 f) Inert Gas Inart gas system can automatically purge total volume of unit Comment 0 g) Operating Instructons/Proceduret 1. Startup, 2. Routine Shutdown, 3. Normal operating conditions, 4. Turndown operating conditions, Comment: 0 h) Reactive Chemical Review Reactive Chemical program is a continuing part of operations Comment. Annual refresher training for all plant employees. i) Other Process Hazard Analysis Management of Change Review (Factor-0.98) Comment: 0 Material Isolation Credit Factor (C2) a) Remote Control Valves No credit (Factor-1.0) Comment: 0 b) Dump/Blowdown Process employs s REMOTELY LOCATED emergency blowdown Comment: 0 c) Drainage 0 Comment. 0 d) Interlock Process is provided with an interlock system which prevents Comment: 0 Fire Protection Credit Factor (C3) a) Leak Detection Gas detectors alarm and identify a zona only (Fector*0.98) Comment 0 b) Structural Steel No credit (Factor-1 0) Comment: 0 c) Fire Water Supply Firefighting water can be supplied for 4 hours at less than 100 Comment: 0 d) Special Systems No credit (Factor-1.0) Comment: 0 e) Sprinkler Systems No credit (Factor-1.0) Comment. 0 f) Water Curtains No credit (Factor-1,0) Comment: - g) Foam No credit (Factor-1.0) Comment - h) Hand Extinguishen/Monltors The process is protected by monitor guns (Factor-0.97) Comment' - 1) Cable Protection No credit (Factor-1.0) Comment: - (TIC-7 Syvton Vw-2 ft - 4M/M] OO A 037050 OONFIDFNTTAt Print Date: 1/21/97, Work File: C:\WINDOWS\Profiles\u239601\Desktop\Fef7denw\CA2 97 - 5 Chlorine Cells.xls MF DetaFile C:\WNDOWS\PrOfiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX AREA/COUNTRY DIVISION LOCATION TESTS------------------------------- North America $JT Louisiana MANUFACTURING unit Plaquemine PROCESS UNIT 1/8/97 Plaquemlne PREPARED BY: Chlor-AIkali 2 Hydrogan Com|pressor APPROVED BY: (Superintend*!*) BUILDING John Dizor REVIEWED BY: (Management) Gretchen C. Leblanc REVIEWED BY: (Technology Center) 3601 REVIEWED BY; (Safety A Lote Prevention) MATERIALS IN PROCESS UNIT Buck Bailey Hydrogen STATE OF OPERATION BASIC MATERIALS) FOR MATERIAL FACTOR __ DEMON ^STARTUP JlJIOftMAL OPERATION ^SHUTDOWN Hydrogen MATERIAL FACTOR (So* Table 1 or Appendice* A or B) Not* requirement* when unit temperatures over 140 *F <6C 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor................................................................................................. 1.00 1.00 A Exothermic Chemical Reactions 0.30 to 1.25 0.00 B. Endothermic Processes 0.20 to 0.40 0.00 C Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0.25 to o.eo 0.00 0.00 E. Access 0.20 to 0.35 0.00 F. Drainage and Spill Control 0 oallons 0.25 to 0.50 0.00 General Process Hazards Factor (FI) *............... ................... ........................... ........... 1.00 2. Special Process Hazards Base Factor................................................................................................. A Toxic Material(s) B, Sub-Atmospheric Pressure (< 500 mm Hg) C. Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 1.00 0.20 to 0.80 0.50 1.00 0.00 0.00 . 1. Tank Farms Storage Flammable Liquids 2 Process Upset or Purge Failure 3 Always in Flammable Range D. Dust Explosion (See Table 3) E. Pressure /See Fioure 2) F, Low Temperature a Ouantitv of Flammable/Unstable Material 0.50 0.30 0.80 0.25 to 2.00 eeratlno Pressure 10 psiq Relief Setting 17 Dsio 0.20 to 0.30 Quantity 1 lb He* 51.600 BTU/lb 0.00 0.00 0.80 0.00 0.20 0.00 1 Liquids or Gases in Process (See Figure 3) 2 Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids in Storage, Dust in Process (See Figure 5) H Corrosion and Erosion 1. Leakage Joints and Packing 0.10 to 0,75 0.10 to 1.50 0,00 0 00 0.00 0.10 0.10 J. Use of Fired Equipment (See Figure 6) 0.00 K. Hot Oil Heat Exchange System (See Table 5) 0.15 to 1.15 0.00 L, Rotating Equipment 0.50 Special Process Hazards Factor (F2)........................................................................... 0.00 2.20 Process Unit Hazards Factor (FI x F2) * F3.............................................................. Fire and Explosion Index (F3 x MF * F&EI).................................................................... 2.20 46 (1) For no penalty use 0.00. DO A 037051 CONrtDFNTT Al Prin^r^f^j/gl^^jjgj tt^imQyy^yf||fi^Li239601 \Desktop\Fei7denw\CA2 97 C-601 H2 Compressor.xls MF DataFile'C:\W!NDOWS\Profiles\u239601 \Desktop\Fei7denw\FEI7_DAT.XLS LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Fsctor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown e Computer Control Credit Factor Range 0.98 0.97 to 0.99 0.84 to 0.88 0.96 to 0.99 0.93 to 0.99 Credit Factor Used (2) 0 98 0.99 1.00 0.98 0.93 Feature f. Inert Gas 9- Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.98 0 91 to 0.98 Credit Factor Used (2) 0.94 0.85 0-91 0.98 Cl Value (3) 1 0.704 | 2. Material Isolation Credit Factor (C2) Feature a Remote Control Valves b. Dump/Blowdown Credit Factor Range 0 96 to 0 98 0.96 to 0.86 Credit Factor Used (2) 1 00 0.96 Feature c Drainage d. Interlock C2 Value (3) | 0.941 | 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b. Structural Steel c. Fire Water Supply d. Special Systems e. Sprinkler Systems Credit Factor Range 0 94 to 0 98 0 96 to 0 98 0.94 to 0,97 0 91 0.74 to 0.97 Credit Factor Used (2) 1 00 1 00 0.97 1 00 1.00 Feature f. Water Curtains g Foam h. Hand Extinguishers/Monitors I. Cable Protection C3 Value (3) | 0.941 | Loss Control Credit Factor Cl x C2 x C3 (3) = | 0.623 | Credit Factor Range 0 91 to 0,97 0.98 Credit Factor Used (2) 1.00 0.96 Credit Factor Range 0.97 to 0,98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1.00 0.97 1,00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F&EI).......... (See Front) 2. Radius of Exposure................................... <Fiur n 3 Area of Exposure.................................................................... 46 39 4,721 ft q.ft. SMM 3.80 1 5. Damage Factor....................................................... 0.51 6. Base Maximum Probable Properly Damage - (Base MPPD) (4 x 5].................. 7. Loss Control Credit Factor ........................(SeeAbove)| 0.62 8. Actual Maximum Probable Property Damage - (Actual MPPD) [6 x 7].... $MM ................ $MM 1.94 1.21 | | 9 Maximum Probable Days Outage - (MPDO)_________(ngunw__________ 30____________ays 10. Business Interruption (Bl).............. . ........................... ................................. {$MM 0.20 *~| (2) For no credit factor enter 1.00 (3) Product of all factors used DO A 0370 OONFTDFNTT Refer to "Fire & Explosion Index Hazard Classification Guide" (Form *471-00001) for details Bi?^S^d^LvWf7i)So<S8^^P^^r9^es^9601\Desktop\Fei7denw\CA2 97 C-601 H2 Compressor.xls MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS FIRE & EXPLOSION INDEX DATA AND COMMENTS Material Factor Materiel It From Database Material Nam* - Hydrogen Base Materiel Fe*r-21 Abutted Material Factor 21 Heat of CofTtoustion (BTU/fo) * 51000 Nh>0 Nf 4 Nr*0 Flash Potrrf ("F) Gas Boiling Point (*F) - -423 Prooats Unit Temperature (*F) 120 Exotherm Tamparatura (*F) 1000000 Autoignttieo Tamparatura fF) 1000000 Data For User Specified Material General Process Hazardi A. Exothermic Chemical Reactions Procatt Unit NOT A REACTOR andfer NO EXOTHERM occurs (Penalty-0) Commant 0 6 Endothermic Processes Proeats Unit NOT A REACTOR Penatty-0 Comment 0 C Matanal Handling and Transfer Nona of the following situations apply (Penalty-0) Comment 0 0. Enclosed or Indoor Process Units Process is NOT ENCLOSED (Penatty-0) Comment 0 E. Access Access determined adequate for emergency equipment (Penatty-0) Comment 0 F Drainage and SpUl Control Diking and drainage which meets all criteria (sea help) (Ptnalty-0) Comment 0 Special Proceaa HazarcU A. Toxic Materfel(s) Equals two tenths of the Nh B Sub-Atmophenc Pressure (< 500 mm Hg) Greeter than 500 mmHg (Penalty-0) Comment 0 C Operation In or Near Flammable Range Process that Is by nature ALWAYS m or near tha flammable Comment 0 D Dust Explosion Process does not include dusts (Penalty-0) Comment 0 E. Pressure Comment 0 F Low Temperature Temperatures remain safety above the ductea/bnttte Comment 0 G. Quantity of Ftemmabte/Unstable Material In Procast Commant 0 H Corrosion and Erosion Corrosion rates balow 05 mm/yr WITH ntk of pitting and/or Commant 1. Laakaga * Joints and Packing Mmor laekaga Wrafy at pump and gland seals (Fenefty-0.10) Commant 0 J Use of Fired Equipment DOES NOT exist in the plant with tha Process Unit Commant 0 K. Hot Oil Heat Exchange System Process does not use a hot oU exchange system, or the hot oil is not stove ifs boiling point Comment 0 L, Rotating Equipment No rotating equipment deemed to to a hazard (No Penalty) Commant 0 Print Data 1/21/97, Work Fite C \WINDOW$\ProfttesW239601\Daskt0p\Fai7danwNCA2 97 C-601 H2Comprassor.ids MF DetaFUrC`1WINDOW5\Proflle$W239601\Dekt0p\Fel7denw\FEl7_DAT-XLS A 037053 confidfnttai. LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Ffoceat Control Crgdtt Factor fCl 1 a) Emergency Power Automatic switch to emergency power for CRITICAL SERVICES Comment 0 b) Cooling System provide* normal cooling for 10 minute* (Factor*0.99) Comment: 0 c) Explosion Control No credit (Faetor*1,0) Comment 0 d) Emergency Shutdown Redundancy system that initiates s shutdown (Factof*0.98) Comment: 0 e) Computer Control Computer with "fail-safe' logic end at least one of the Comment 0 f) Inert Gs* Inert ges system can automatically purge total volume of unit Comment: 0 g) Operating Instruetions/Procedure* 1. Startup, 2- Routine Shutdown, 3. Normal operating conditions, 4. Turndown operating conditions, Comment: 0 h) Reactive Chemical Review Reactive Chemical program I* a continuing part of operations Comment. Annuel refresher training for ail plant employees. I) Other Process Hazard Analysis Management of Change Review (Fector*0.98) Comment: 0 Material Isolation Credit Factor (C2) e) Remote Control Valves No credit (Factor*1.0) Comment: 0 b) Dump/Slowdown Process employs en emergency flare system OR a dosed vent Comment. 0 c) Drainage 0 Comment' 0 d) Interlock Process is provided with an interlock system which prevents Comment: 0 Fire Protection Credit Factor (C3) a) Leak Detection No credit (Factor* 1.0) Comment 0 b) Structural Steel No credit (Factor*1.0) Comment: 0 c) Fire Water Supply Firefighting water can be supplied for 4 hours at less than 100 Comment: 0 d) Special Systems No credit (Factor* 1.0) Comment: 0 e) Spnnkler Systems No credit (Factor*1.0) Comment: 0 f) Water Curtains No credit (Factor*1.0) Comment: 0 g) Foam No credit (Factor* 1,0) Comment: - h) Hand Extinguisheri/Monitor* The process Is protected by monitor guns (Factor*0.97) Comment: - i) Cable Protection No credit (Factor* 1.0) Comment. - fflfi-7 Wr-2. 4WM) Print Date. 1/21/87, Work File: C:\WINDOWS\ProfilaiNu23B60l\DesMop\Fel7denw\CA2 97 C-601 H2 CompreMorjds MF 0etaFllB:C:iW!ND0WSIPro/ilM!u239601\Dosk!op\Fei7denvAFEI7_DAT,XLS DO A 037054 OONFTDFNTI Al. FIRE & EXPLOSION INDEX AREAtoduNTRY rasisr LOCATION OATS North America SITE Louisiana MANUFACTURING UNIT Plaquemlne PROCESS UNIT 1/6/97 Plaquemlne PREPARED SY: Chlor-Alkall 2 Gas Turbine djwl roRg.iAJj, APPROVED BY: (SuperinUnduit) BUILDING John Dizor REVIEWED BY: (Msiurgwinnt) Grstchen C. Leblanc REVIEWED BY: (Technology Cantor) 3601 REVIEWED BY: (Safety S Lou Pmontion) MATERIALS IN PROCESS UNIT Buck Bailey________________ Methane and Air STATE OF OPERATION BASIC MATtRlAL(S} FOR MATERIAL FACTOR ___ DEMON _X_*TAKT U* . NORMAL OPERATION MWTBQWH Methane MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirement* when unit temperatures over 140 *F (6C 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor................................................................................................. 1.00 1.00 A, Exothermic Chemical Reactions 0.30 to 1.25 1.00 B, Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer D Enclosed or Indoor Process Units 0,25 to 1.05 0.25 to 0.90 0.00 0.00 E Access 0 20 to 0.35 0.00 F Drainage and Spill Control 0 gallons 0.25 to 0.50 0.00 GAnitraf Process Hayerris Factor (FI)..........................................*.................. ............. 2.00 2. Special Process Hazards Bass Factor................................................................................................. 1.00 A. Toxic Material(s) 0.20 to0.80 B. Sub-Atmosphenc Pressure (< 500 mm Hg) C, Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.50 1. Tank Farms Storage Flammable Liquids 0.50 2. Process Upset or Purge Failure 0.30 3. Always in Flammable Range D, Dust Explosion (See Table 3) 0 80 0.25 to 2.00 E. Pressure fSee Figure 2) Derating Pressure 35 Dsiq Relief Setting 0 Dsig F. Low Temperature 0.20 to 0.30 G Quantity of Flammable/Unstable Material Quantity 1 lb He = 21.500 BTU/lb 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases In Storage (See Figure 4) 3. Combustible Solids in Storage, Dust in Process (See Figure 5) H. Corrosion and Erosion 0.10 to 0.75 1. Leakage - Joints and Packing 0.10 to 1.50 1.00 0.20 0.00 0.00 0.00 0.80 0.00 0.29 0.00 0.00 0.00 0.00 0.10 0.00 J. Use of Fired Equipment (See Figure 6) K. Hot Oil Heat Exchange System (See Table 5) 0.15 to 1.15 L. Rotating Equipment 0.50 Special Process Hazards Factor (F2)........................................................................... 0.00 0.00 0.50 2.89 Process Unit Hazards Factor (FI x F2) * F3.............................................................. S.78 Fire and Explosion Index (F3 xMF F&EI).................................................................. 121 (1) For no penalty use 0.00. Date: ________ \Desktop\Fei7denw\CA2 97 - 6 Gas Turbine (replace new).xls MF rToToPilA'^'iiA/iur.rT\Aic\D.Ar;tAe\..hoacnT\r\ABL*Ai<\\iTa;'7rlAnuj\trd7 33 A 0370 5 5 OONFTOFNTTAl LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown e. Computer Control Credit Factor Range 0.98 0.97 to 0.99 0.84 to 0.88 0.96 to 0.99 0.93 to 0.99 Credit Factor Uead (2) 0 98 1.00 1.00 0.96 0.93 Feature f. Inert Gas 9 Operating Instructions/Procedures h. Reactive Chemical Review j. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.98 0.91 to 0.96 Credit Fector Used (2) 1.00 0.95 0.91 0.98 Cl Value (3) | 0.741 | 2. Material Isolation Credit Factor (C2) Feature a. Remote Control Valves b. Dump/Blowdown Credit Factor Range 0.96 to 0.98 0 96 to 0.98 Credit Factor Used (2) 0.98 0.98 Feature c. Drainage d. Interlock C2 Value (3) | 0.941 | 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b Structural Steel c. Fire Water Supply d Special Systems e Sprinkler Systems Credit Factor Range 0 94 to 0.98 0.95 to 0 98 0.94 to 0.97 0 91 0.74 to 0.97 Credit Factor Used (2) 1.00 1.00 0.97 1.00 1.00 Feature f. Water Curtains 9 Foam h. Hand Extinguishers/Momtors i, Cable Protection C3 Value (3) | 0.941 | Loss Control Credit Factor Cl x C2 x C3 (3) |__0;6S6__J Credit Factor Range 0.91 to 0.97 0.98 Credit Factor Used (2) 1.00 0.98 Credit Factor Range 0.97 to 0.98 0,92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1.00 0.97 1,00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F&EI).......... (See Front) 121 2. Radius of Exposure................................. <nwr n 102 ft 3 Area of Exposure.................................................................... 32,679 q.ft. 4. Value of Area of Exposure 1968 Dollars............................................................................... $MM 5. Damage Factor....................................................... <fiw.i| 0.77 6 Base Maximum Probable Property Damage - (Base MPPD) [4 x 5].................. SMM 7. Loss Control Credit Factor ........................(SeeAbove)| 0.66 8. Actual Maximum Probable Property Damage - (Actual MPPD) [6 x 7) ... ................ $MM 9 Maximum Probable Days Outage - (MFDO) (Fiqur. > 10, Business Interruption (Bl)........................................................... ## .............................. .ItMM 60.00 46.29 30.37 11.11 | | | (2) For no credit factor enter 1.00 (3) Product of all factors used Refer to "Fire & Explosion Index Hazard Classification Guide" (Form #471-00001) for details Print I^tft:cJ/?i?^7c.2yyi?ir|fe^;j!!S-'P(iVy.yyiS6,VJ^^9R^W?3#-6ii1^Pesk,0P^ei7deriw'CA2 97 - 6 Gas Turbine (replace new).xls MF DataFile:C:\WINDQWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS DO A 037056 COKIFTDFNTTAI FIRE & EXPLOSION INDEX - DATA AND COMMENTS Material Factor Material I* From Database Material Name * Methana 6am Material Factor-21 Abutted Material Factor-21 Heat of Cemtouetion (BTU/to) 21500 Nf-4 Nr-0 Flaah Point fF) Gas Bating Point ('F) - -259 Precast UnM Temperature (T) 1667 Exotherm Temperature (*F) - SM 9 Autoignition Tamperatura (*F) 998,6 Date For User Specified Material General Procesa Hazania A. Exothermsc Chemical Reeebona REACTOR with CRITICAL-TO-CONTROL EXOTHERM (Fenelly*1 00) Comment 0 B Endothermic Processes Precast Unit is a REACTOR, but NO ENDOTHERM occua > PtnaHy-0 Comment 0 C Matanal Handling and Transfer Nona of tha following situation* apply (Penalty*!)) Comment 0 D Enclosed or Indoor Process Unit* Process is NOT ENCLOSED (P#n*ttyQ) Comment 0 E Access Access determined adequate for emergency equipment (Penalty-0) Comment 0 F Drainage and Spill Control Diking and drainage which meets all entens (see help) (Penalty-0) Comment 0 Special Proceit Hazard* A. Toxic Metenal(i) Equals two tenths of the Nh B Sub-Atmospheric Pressure (< 500 mm Hg) Greater than 500 rnmHg (Renaity-0) Comment 0 C Operation In or Near Flammable Range Process that is by nature ALWAYS in or near the flammable Comment 0 D Dust Explosion Process does not include dusts (Penalty*!)) Comment 0 E, Pressure Comment 0 F. Low Temperature Temperatures remain safely above the ducttle/bdttle Comment Q <5 Quantity of Fternmabte/Unetebte Material In Process Comment 0 H, Corrosion and Erosion Corrosion rates below 0 5 mrrVyr WITH nsK of pitting and/or Comment I Leakage Joints and Padung Leakage of Aammabtes/combustiblas is Insignificant Comment 0 j Use of Feed Equipment DOES NOT exist in the plant with tha Process Unit Comment Penalty was taken m exothermic reaction Hie No penalty taken here. K. Hot Oil Heat Exchange System Process does not use a hot oil exchange system, or tha hot oil Is not above rfs boiling point Comment 0 L Rotating Equipment Other targe, high speed muting equipment with significant Comment 0 JFIS-r SyaHM v2 I - 4WHI Pnni Data' 1/22/97, Work File C,\WINDOWS\ProflkiVu23960l1Desktop\Fel7denwlCA2 97 -6 Gas Turbina (replace new) xls MF OataFile'C'\WtNDOWS1PrOfllea1u239601tDesktop\Fai7danw\FE17_DAT XLS Do A 037057 CON5TDFNTTAL LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Proem Control Credit Factor IC1) ) Emergency Power Automatic switch to emergency power for CRITICAL SERVICES Comment: 0 b) Cooling No credit (Fedor*1.0) Comment: 0 c) Explosion Control No credit (Factor*1.0) Comment: 0 d) Emergency Shutdown Vibration detectors which initiate e shutdown (Factor*0.96) Comment: 0 e) Computer Control Computer with "fall-safe' logic end at least one of the Comment: 0 f) Inert Gas No credit (Factor*1.0) Comment: 0 g) Operating Instructions/Procedures 1. Startup, 2. Routine Shutdown, 3. Normal operating conditions, 4. Turndown operating conditions, Comment. 0 h) Reective Chemical Review Reactive Chemical program is a continuing part of operations Comment. Annual refresher training for ell plant employees. i) Other Process Hazard Analysis Management Of Change Review (Fac*or*O.B8) Comment: 0 Material laolation Credit Factor <C2) e) Remote Control Valves Remotely operated valves can isolate equipment or piping in Comment: 0 b) Dump/Blowdown Process employs an emergency blowdown tank that it vented Comment. 0 c) Drainage 0 Comment 0 d) Interlock Process is provided with an interlock system which prevents Comment. 0 Fire Protection Credit Factor (C3) a) leak Detection No credit (Factor*!.0) Comment. 0 b) Structural Steel No credit (Factor*!.0) Comment' 0 c) Fire Water Supply Firefighting water can be supplied for 4 hours at less than 100 Comment. O d) Special Systems No credit (Factor*!.0) Comment: 0 e) Sprinkler Systems No credit (Factor* 1.0) Comment: 0 f) Water Curtains No credit (Factor*!.0) Comment. - g) Foam No credit (Factor*! .0) Comment - h) Hand Extinguishers/Monitors The process is protected by monitor guns (Factor*,97) Comment. - I) Cable Protection No credit (Factor* 1.0) Comment: - [FtE-7 6y*nm Vw*2.6 Prin! Date. 1/23/87, Work File: C:\WINDOWS\Profile5kj239601\Desktop\Fei7denw\CA2 87 - 6 Gas Turtiine (replece new).xts MF DetaFile:C:VWINDOWS\Pro(iles\u239601\Dektop'Fei7denw\FEI7_DAT.XL$ D0 A 037058 CONFTDFNTTAl. ^7 FIRE & EXPLOSION INDEX ARfiA/COUNTRY DIVISION ISSTOn------------ EaTE------------ North America SITE Louisiana manufacturing unit Plaquemlne PROCESS UNIT 1/6/97 Plaquemlne PREPARED BY: Chlor-Alkall 2 Gas Turbina APPROVED BY: (Superintend**) 3-PA&Z TUZ-"Ul BUILDING John Dlzor REVIEWED BY: (Manegefiiant) Gretchen C. Leblanc REVIEWED BY: (Technology Center) 3601 REVIEWED BY: (Scffty A Lots Prevention) MATERIALS IN PROCESS UNIT Buck Bailey Methane and Air STATE OF OPERATION BASIC MATERIALS) FOR MATERIAL FACTOR m_DE*K)N JC_*TAKTVF NORMAL OPERATION ___AWTPQWW Methane MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 *F (6C 21 1. General Process Hazards Penalty Fee- Penalty Factor Range tor Used (1) Base Factor................................................................................................. A Exothermic Chemical Reactions 1.00 0.30 to 1.25 1.00 1.00 B. Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer D. Enclosed or Indoor Process Units E Access F. Drainage and Spill Control 0.25 to 1.05 0.25 to 0.90 0.20 to 0.35 0 oallons 0.25 to 0.50 0.00 0.00 0.00 0.00 General Process Hazards Factor (FI)........................................................................... 2.00 2. Special Process Hazards Base Factor............................................................................ .................... 1.00 A Toxic Material(s) B. Sub-Atmospheric Pressure (< 500 mm Hg) C Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.20 to 0.80 0.50 1 Tank Farms Storage Flammable Liquids 2, Process Upset or Purge Failure 3. Always in Flammable Range D. Dust Explosion (See Table 3) 0.50 0.30 0 80 0.25 to 2.00 E. Pressure (See Figure 2) F. Low Temperature G. Quantity of Flammable/Unstable Material Deratinq Pressure 35 psiq Relief Settino 0 Dsio 0 20 to 0.30 Quantity 1 lb He 21.500 BTU/lb 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids In Storage. Dust in Process (See Figure 5) H. Corrosion and Erosion 1. Leakage Joints and Packing 0.10 to 0.75 O.IOtol.SO 1.00 0.20 0.00 0.00 0.00 0.60 0.00 0.29 0,00 0.00 0.00 0.00 0.10 0.00 J. Use of Fired Equipment (See Figure 6) K, Hot Oil Heat Exchange System (See Table 5) 0.15 to 1.15 L. Rotating Equipment 0.50 Special Process Hazards Factor (F2)............................. .............................................. Process Unit Hazards Factor (FI x F2) * F3.............................................................. 0.00 0.00 0.50 2.89 6.78 Fire and Explosion Index (F3 x MF * F&EI).................................................................. 121 (1) For no penalty use 0.00. Print Date: W?39S9/3PesktP'Fai7denw'CA2 97 *7 <9as Turbine (replace spare).xls MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fel7denw\FEI7_DAT.XLS 00 A 037059 C0NFJ05NTTA1 LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a- Emergency Power b Cooling C. Explosion Control d. Emergency Shutdown ft. Computer Control Credit Factor Range o.ee 0.97 to 0.99 0.84 to 0.88 0.96 to 0 99 0.93 to 0.99 Credit Factor Used (2) 0.98 1.00 1,00 0.96 0.93 Feature t. Inert Gas 9- Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.98 0.91 to 0.98 Credit Factor Used (2) 1.00 0.95 0.91 0.98 Cl Value (3) | 0.741 | 2. Material Isolation Credit Factor (C2) Feature a. Remote Control Valves b Dump/Blowdown Credit Factor Range 0.96 to 0 98 0.96 to 0.98 Credit Factor Used (2) 0,98 0 98 Feature c. Drainage d. Interlock C2 Value (3) | 0.941 | 3 Fire Protection Credit Factor (C3) Feature 8. Leak Detection b. Structural Steel c. Fire Water Supply d Special Systems e Sprinkler Systems Credit Factor Range 0.94 to 0 98 0.95 to 0.98 0.94 to 0,97 0 91 0,74 to 0.97 Credit Factor Used (2) 1.00 1 00 0.97 1.00 1.00 Feature f. Water Curtains 9 Foam h. Hand Extinguishers/Monitors i Cable Protection C3 Value (3) | 0.941 | Loss Control Credit Factor * Cl x C2 x C3 (3) | 0.656 | Credit Factor Range 0 91 to 0.97 0.98 Credit Factor Used (2) 1.00 0.98 Credit Factor Range 0.97 to 0.98 0,92 to 0.97 0.93 to 0.98 0 94 to 0.98 Credit Factor Used (2) 1.00 1.00 0.97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F&EI).......... (See Front) 121 2. Radius of Exposure................................... (F>*m 7) 3. Area of Exposure.................................................................... 102 32,679 4 Value of Area of Exposure 1968 Dollars.............................. 5. Damage Factor....................................................... iflsuTM ) 0.77 6. Base Maximum Probable Property Damage - (Base MPPD) [4 x 5]... 7 Loss Control Credit Factor ........................(See Above) 0.66 8. Actual Maximum Probable Property Damage * (Actual MPPD) [6x7] 9. Maximum Probable Days Outage - (MPDO) in*.TM) 12 10. Business Interruption - (Bl).................................................... ft q.fl. SMM SMM SMM ays .......... SMM 2.00 1.54 1.01 0.48 1 1 1 (2) For no credit factor enter 1.00 (3) Product of all factors used Refer to "Fire & Explosion Index Hazard Classification Guide" (Form *471-00001) for details Print D^k1^^c^ filft1^(i)^^i,^^^^P;/^sktop\Fei7denw\CA2 97 - 7 Gas Turbine (replace spare).xls MF DataFile:C:\WINDOWS\Profiles\u239601\Desktop\Fei7denw\FEI7_DAT.XLS 00 A 037060 oonftdfnttai FIRE & EXPLOSION INDEX - DATA AND COMMENTS Material Factor Materiel l From Database Material Name Methane Baee Material Fader-21 Adjusted Material Fader 21 Heat of Combustton (BTUflb) 21500 Nh - 1 WM Nr-0 Flash Point ("F) * Gas Belling Point fF) * -266 Procase Unit Temperature (*F) -1667 Exotherm Temperate** (*F) - 666.6 Autoignltion Tamparater* (*F) * 660 6 Data For User Specified Material General Process Hatarda A. Exothermic Chmical Rsaetions REACTOR with CRlTICAL-TO-CONTROl EXOTHERM (Panalty-1.00) Comment 0 6, Endothermic Processes Process Unit is e REACTOR, but NO ENDOTHERM occurs > Penilty-0 Comment 0 C Material Handling and Transfer None of the fo!lowing situations apply (Penalty-0) Comment 0 0 Enclosed or Indoor Process Unita Process is NOT ENCLOSED (Penalty-0) Commant 0 E Access Access detemxned adequate ter emergency equipment (Panetty-O) Comment 0 F Drainage end Spill Control Diking end drainage which meets ali cntena (see help) (Penalty-0) Comment 0 Special Process Hazards A. Toxic Matenal(s) Equals two tenths of the Nh B Sub-Atmosphenc Pressure (< 500 mm Hg) Greater than $00 mmHg (Penaty-Q) Comment 0 C Operation in or Near Flammable Range Process that is by nature ALWAYS m or near the flammabte Comment 0 D. Dust Explosion Process does not include dusts (Penalty-0) Comment 0 E Pressure Commant 0 F Low Temperature Temperatures remain safely above the ductiie/bnttte Comment 0 G Quantity of Ftemmable/Unstabte Material In Process Comment 0 H. Corrosion and Erosion Corrosion rates below 0 5 mnYyr WITH nsk of pitting end/or Comment 1 Leakage * Joints and Peeking Leakage of fterrvnables/cenibustibtes Is insignrficent Comment 0 J Use of Fired Equipment DOES NOT exist m the plant wth the Process Unit Comment Penalty was taken in exothermic reaction line No penalty taken here K. Hot Od Heel Exchange System Process does not use a hot oa exchange system, or the hot oil is not above it's boiling point Comment 0 L Rotating Equipment Other large, high speed rotating equipment wW significant Comment Q jnc-7 im v*4 a wesi Prmt Date 1/22/67, Work FUa- C'VWINDOWS\PrefttesW236601^>esktop\Fei7denwVCA2 67 7 Gas Turbine (repiece apere).xts MF DateFile C \WINDOWS\Profltee\u2366Q1\D*sktop\Fel7danw\FEI7^DAT.XLS DO A 037061 OONFTDFNTTAl LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Process Control Credit Factor IC1> a) Emergency Power Automatic switch to emergency power for CRITICAL SERVICES Comment 0 b) Cooling No credit (Factor*1.0) Comment: 0 c) Explosion Control No credit (Faetor*1.0) Comment 0 d) Emergency Shutdown Vibration detectors which Initiate a shutdown (Factor*Q96) Comment 0 e) Computer Control Computer with "faiLsofe" logic and at least one of the Comment: 0 f) Inert Gas No credit (Fector*l .0) Comment; 0 0) Operating Instructtons/Proceduras 1. Startup, 2. Routine Shutdown, 3. Normal operating conditions, 4. Turndown operating conditions, Comment: 0 h) Reactive Chemical Reviaw Reactive Chemical program Is a continuing part of operations Comment: Annual refresher training for all plant employees. 1) Other Process Hazard Analysts Management of Change Review (Faetor*0.98) Comment: 0 Material Isolation Credit Factor (C2) a) Remote Control Valves Remotely operated valves can isolate equipment or piping in Comment: 0 b) Dump/Blowdown Process employs an emergency blowdown tank that Is vented Comment- 0 c) Drainage 0 Comment 0 d) Interlock Process is provided with an interlock system which prevents Comment o Fire Protection Credit Factor (C3) a) Leak Detection No credit (Factor* 1.0) Comment. 0 b) Structural Steel No credit (Factor*1.0) Comment' o c) Fire Water Supply Firefighting water can be supplied for 4 hours at less than 100 Comment 0 d) Special Systems No credit (Factor* 1.0) Comment 0 e) Sprinkler Systems No credit (Factor*1,0) Comment: - f) Water Curtains No credit (Factor*1.0) Comment. -- g) Foam No credit (Factor*1.0) Comment: - h) Hand ExtinguishersMonttors The process is protected by monitor guns (Factor*0.97) Comment. - I) Cable Protection No credit (Factor*1.0) Comment, - fflE`7 Syvtotn Wr-z fi - Print Date. 1/22/87, Work File: C:\WINDOWS\ProfilM\u239601\Detktop\Fei7denw\CA2 97 - 7 Gat Turtelne (replace ipare).idt MF DalaFlle,C.\WINDOWS\Prolilet\u239601VDotktop\Fel7denw\FEI7_DAT.XLS OO A 037062 CONFTDFNTTAl 31 ouq UUW9VJL.IUM I CU MUM* - Reactive Chemical Revievip' ' - ' '- -.. '* ' '. i.... ..' .T` V-"' - 'i-'i; i- March'4,' 1994 O' '"-* ,0- -.-'Vi Ov, * ; i: v v* |y. ,y .V;-.^ ' y: I^VvT';. ?*?\ ~' }' : ^yj; ^ ' J-r ' >*4 vVi X^/i '-:y *" , ,* _ '" Audits and Checklists # V' y--o, v,. v l -* rw` - '. . - ' . V ,VT*- - -_v 0 ` "* 'fV'- --ii `: V, . y</V-v* f ,; ' ' ` - ^v4- * .* * .f- ,,. '..~0 .'; 0 \- Caustic ; Dow Chemical, Louisiana Operations / * m' * f .- , * j-rj1 ^ * -..ilnLii mw.hil ` V ' Mi Jfci \ -. t ' - ~1 ' f,` -T r* , Tpm W* llajvirsff -\ L ,* ` *OaZ:.; rtd^tL^i^N DO A 037064 CONFIDENTIAL -X ,i.j. .-. ...