Document mBezaM31pK4Km7YjJg19OQr5g

AR X26 _ O84 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (DAPHNIA MAGNA) IEsTsuesTANCE 00000000 Identity: rMeifxetrurreedctoontaasinPiFnOgSp,erFfCl-u9o5r,ooocrtaansesaulcfoomnpaotenewnhticohf FmCa-y30a1ls7o. b(e1Octanesulfonic acid) (CAS# 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-3017 produced in Antwerp, Belgium. Current information indicates FCw3a0t1e7r,is2a1%mixettuhryeloenfe gl0y.c6o7l%,P1F.O3S3,%2H0yd%rodixeytfhyolaemneer,gl1yc%olsboudtiylumetohcetry,l 5su5l.f4at1e%, a0n.d5%0.p0ol5y%oxtyoleytlhtryalieznolee.monooctylphenyl ether, 0.04% sodium lauryl sulfate, cThhaerafcotlelrowiiznegd csounmcmenatrryataipopnlsioesftiompaumriitxiteusr.e Dwaittah imnacyomnpoltetaeclcyurately reflect toxicity of the fluorochemical component of the test sample. METHOD: 000000000 Method: OECD Guideline 202 Type: Acute static GLP: No Yearcompleted: 1995 Species: Daphnia magna ASnuaplpyltiiecra:l Imno-nhiotuosreincugl:turTeesm,pemraaitnutraien,epdHa,tcAoSncdulc-tDivEiTtDy,, aDnuldutdhi,ssMolNved oxygen. Exposure period: 48-hours Test organism age: <24 hours old TSteasttisctoincdalitmieotnhs:ods: LCs, values calculated using a computer program. Dilution water: Dechlorinated City of Duluth, MN tap water post carbon filter, aerated for 24 hours prior to use. Dilution water chemistry: Hardness: 50 mg/L as CaCOy Alkalinity: 46 mg/L as CaCOs Conductivity: 127- 143 ymhosicm . TpHo:c: 71..682mglL _ Lighting: Cool-white fluorescent lights. A daily photoperiod of 16 hours light Santdoc8khaonudrstedsatrksowlaustimoanipnrteapianreadttihorno:ugThhouettteshte mtaetsetriinaglpweraisoda.dded directly 0 the dilutionwater on a weight/volume basis and mixed by mechanical stirring at ambient lab temperature. 002816 Exposure vessels: 250 mL beakers with 200 mL test solution. NNuummbbeerrooffdraepplhinciatdess:pe4r replicate: 5 WNautmebrecrhoefmicsotnrcyendturraitnigontsh:e sotnuedyp:lus a blank control pH range (0-48 hours): 7.9~8.2 (control exposure) 7.87.9 (1000 mg/L exposure) Temperature range (0-48 hours): 20.1-20.6 C Conduct1i2v7i--ty1r3a9npgmeh(o0s-/48cmho(ucrosnt)r:ol exposure) Dissol1v4e2d --ox1y4g3epnmrhaonsg/ecm(0(-41800h0oumrgs/)L: exposure) 8.18.8 mglL (control exposure) 7.789 mglL (1000 mg/L exposure) R0 eswts 00000 Nominal concentrations: Blank control and 1000 mg/L. Element values: 24-hour ECs = >1000 mg/L 4488--hhoouurr ENCOsEoC= =>11000000 mmgg//LL.. Element values based on nominal concentrations. RSuebmsatraknsc:eTReestmianrgkwsafsielcdo. ndTuhcetveadlouensthreepmoirxtteudraepapslydetosctrhiabtemdixitnutrheeaTnedstnot the fluorochemical proportion alone. conclusions 0000 ThohuertNesot OsbusbsetravnecdeE4f8f-echtouCronEcCesnotrwaatsiodne(teNrOmEiCn)edwtaosb1e0>0100m0g0lLm.g/L. The 48Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 pataQuALTY 000000 Reliability: Kiimisch ranking = 2. This study meets the criteria for quality ~ testing. However, sample purity was not property characterized and the study__ lsoalcuktsiaonnalytical confirmation of the amount of fluorochemical proportion in REFERENCES ~~ 0000000000 002817 TDihviissitoens,t wDualsutcho,nMduNctaetdthbeyrAeSqculesCtoropfotrhaeti3oMn,CDoumlputahnyE,nvLiarbonRmeeqntuaelstTensutminbger N3188, 1995. O0 THE0 R 0000000000 Last changed: 6/26/00. 002818 BEST COPY AVAILABLE aon | k 9 p- bs g:o - B fr reo d en ae fick STUDYTITLE ACUTE TOXICITY OF FC-3017 TO DAPHNIA S4GY1 - `OECD GUIDELINE 202 STUDYCOMPLETED December 23, 1995 TESTING FACILITY EAnSveitroCnomrenptoarlatTisonisng DDiuvilsuiiohn Du1l1l2tEha,sMtSNe5c53o05tn-r1ed7e0t1 TFeal.x NNoo.. ((21188)) 772222-24509420 STUDYIDENTIFICATIONNUMBERS ASel Study IDF 500.068 Shida Ci mpafnyiLabrReequstdN318% ani sia A . he et MLa s i ag Aik EE JiBgs <agmumetnis loorMoi.se b andi G l eb TE Ahem aie ll BEE Lc oN Lo CR By ehbib oap RR er ughip +08RR10 BEST COPY AVAILABLE - sS ios ns L0 GENERAL INFORMATION [StyoTe usomsDoPAacapipevTeoomFisacasgy.aSsrmoCrnearPoeLg wae ms | | MBuN0liE5nn5vgi1r20o3n6mEeGn3ta,l9T3e5shBmulhogeynasnd.Se1rviPcea,l Sor ay 5TS3eu3esmBnuAas.oheByAevaaecnnhd,eS,SeSWie.EsPm.ovlr,uoNnnNegn5l5210366.9, | TSeesoimnogrFsacLilbityReyny fomTel No. (612) 778-7452. Sl CoorAaseioulna Envromana I [|T rocpmmee me ve TDeusliln,g DNoNoio53n3s ,051:13TeEl aNoS:ec(o3n] 1d)S7o53n040 I Fv [[DTeefiinnigtFveiTtewDDuiercssor Daa Valation and Repo Review | onald on | Decomver2023, 199. ross | LRoecattieonnootffiRRoawnwDDaataasanndd FFinnal RReepgoort Soi Sah ony so MIRE ||TAoSelyeCarosropmoerAaldt:iDautotaynth Ecnovmirpoinemecnal_| TDeusttin,g DMN 5i580151:s3TlEaotNSoecGno1n9d)S,7e3n4s0._| Sh TRE a EE ETS n I le 0T CHAR ET LFm mcoSmRiRh E CS SEN e REY Ca R LE L SPgEh a LoadliEetl sae e rR E n E EET ERE RD hal a a le i PORE20.. . BEST COPY AVAILABLE =-- 20 OWECTIVE) c"FTooonacdmee,ntiefrroamriioDnnaep(thhNneOi4aE8C.m)1agomnfeadtihaentceffescutbsctoanncceen,trFatCi-o3n0(1ELCi)gh2tnWda4ke8rhAiqoueaobuiesrFabile Fafofremcitng Ghuiisdesltiundey2w0a2s(cOonEdCuDcte1d99a%c.conin to the ASGl study plan. reine by the Sponsor and OECD 3.0 TEST METHODS Test Subsiance. | P15rompisecrib:le wClietahtwaatmebre,rncdolosraebdlTeid, specific gravy ca 1.1 (water = | | Tecosntcecnotnrcaetnitornattieosnts:solu0ti(odnilwuatisonpwraetpearredcobnytromla)ssanaddd1i0ti0o0n mfgo/lLl.oweHdibgyh II TetOrganisms | DmSoeaucprhhcaneni:iacamHleaasgltntihraryi,nnlogenasstsiaetmhsbainoevn2t6i:nl0aebiatfermopmeraAtSuere.sok cures mainained in 1I ater of ts Hoon wae Quy HiUansnaedtilineodne.swti:UlsheGdarsamovoropatahdibssmoirsrapetippeiedcawiiinhadniadtni4oinnrdevepadlraic2a4emhsebcoeoffnc6oernmtitrh.aetitDoeisntd ot fecd during th est Diluion Water onli | Scohuermciec:al DsercahllyosrsisantiondeRCatwyDDoafaaDulPuatchk,agMe,N, ap water The most`recent TE 2 ChaarCaOci,erainsdiac:pHAotfe7s.t82t.imA,ertahteewdaoterr2h4ad pihaord1neswsionfg5m0tmnL.ts.ss i #0508 | | Exposure Chambers + 1 Type: 250-mlborosir licate gln ass beakers. whhaain) i foapdiStgiri be | uUsoe ihncefoesvt:er2e0d0m,leoxfcedpitlwuthieonn waatpeerroirmetensttasbovleurtieoant/ocnhsamwbeerr.emDudrisng the<i|] 31 Maa f[asGReapa essoa g a nl Cob eE:a EEA EoR e EELnElET AER [BFSe som tCom e BOEspa onsorsuid m 102 Noss RHIEeTNRRRORAaSn| i Sa Ra De f ples e STEER PR a ah Ek SERGE Ue b ER hh GpBRE Wer i [ | | | cEanldepuotianttons BEST COPY AVAILABLE CAoevCenoToAotStcDuoatan a To somes Duration: 48 h. fuorescent lamps. Temperature: 20C. cthoousnetetdhaitmdmiodbinloitzesdwiamndwidtehaidn t1e5stsoercgoanndissamfse(riemxmpoobsiulriezecdhoarmgbaenrissmwserweere 2enthly agitated). Did not remove any daphnids (om the exposure chambers | tcWoeanrtdmeuircntacithvieiomtniy:s,isrppyeH:c,ifai(c1n)dcAoDLnOde,utc(i3ivnttdiyualtypi.oHn.t-eatmnopdaelrDahOtau.rrdenA,ellsasnd,deta(lek)ramliaitnnaiettsyit,onsspewceifriec || made according to APHA methods (1989). | Formal calculations no needed due to ack of effect J 40 RESULTS | Test Substance Toxicity (Pertinent data are in |24hEC, > 1000 mg/L. Table 1) HEC >1000 mpl. "E 48h NOEC: 1000 mg/L. p 2 ee get aey LP i gnCA OA RERE SORTER a geIR Bl a ik o Tn sm iCoe m LSCR ORb N SEE Co pal RE ie CEkReRnR BalSoEBBiEELhLs R L EToao R AEE aRShs Sot a Ee LR it a Sse ah A ER Tr St sci Rl s ae Ss ae RT Ee re RMOcneDeT9e REBe e22 : BEST COPY AVAILABLE | EArComrmrorisAS Duh ey orsoo Ranges of Water Chemistry Parameters Total hardness (as CaCO, mg/L): 50. Alkalinity (as CaCO, mg/L): 46. Temperature (C): 20.1-20.6. L_ DO (mg/L): 71.7-8.9. pH: 1.82820. | Specifc conducriviny umhosiomy:127.183. 5.0 TEST QaiQC Ee c"Toensttroolrgeaxnpiossmurdeeamdi,stimnmootbibleimzeodreorthraanpp1e0d%.in | 0% dead, immobilized or rapped. | fheermilnoawteisotn DmuOstcobnecaentrlaeatsiton60at%teosft the air saturation value at test temperature. | "8T5he%loofwetshte DaiOr scaotnucreatnitornatviaolnuemeaats2u0r,e0dCw.as | "Test duration must be 48 h. "The test duration was 48 h. eRsetf.erence substia}nce (sodiim chloride) toxicity|cAShealr'issiunpdahteeRdarwefDeraenicePtaocxkiacigtey.tet control Wi 6.0 REFERENCES Ri | YAmaerricwandPWubelicsHteaoltvAesorci,aWtaonsi(nAgPoHnA),.D1.98C9..Standard Methods SoErLthAeEExSaEmination of :3 =| OGuiderlinesgforoaTreEsctoiinngoomfizcCChoemoiipcearlaost.ioOnnEaCnDd DPeubvleilcoaptimoenntInOfoErCmDat)i,on 1C9e8n1t/e1r9,9W3.asOhiCngDon, D.C+. | | "175 So aRRki w a CSLe OTR E . E RSUE RETUe NETeeFRRERPlS STCR pYheRnRna Lhee e SR S21D 13B35 b Sponi sor: c3MCom omcoA al SE SR AERRS s RR iE t hi . h L S bLiE eyt3 ITREESTER SR i SGlaaaHaTeeel A aCoElmE es A o2oI LlEET a R R T eaa R RE RI EEL E RTpT oir gros etnies reer detaiingn Pi o i gE ee i refiSoon"Rusl a d TEAR RAE fa 00Ri8ae3 SPIEOB BEST COPY AVAILABLE |...0... - EnvironmentalTesting Division ASCH StudyTors010068 TABLE 1. tAocDuatephtnoxiiacimtaygonfaFC-3017 Light Water Aqueous Film Forming Foam L TCootocSnui>bminoen [Te Percerenintpeangdse E`FCFOERCRTEASNPODNNDOI-NEGF9F5E%CTCOCNOFNICDEENNTCREATIINOTNESRVWAILTSH [EcmanoeeTT _ 95% Conidae minal] ng ER eSeRE naadR s ie fs 3 SEpAi pad i Fo5neRhidE a eRASE ERSE E E a les vSe E f SRoREEi R Reel.eaeit Uo o sromeR rtorComm CSRR GHEIRE 04 SpanoSey 1 Sd REhc SLe LG DYER Bie LOR SHEER hr in Sgaslemi a oe:HR ae a il Ea SH bot oe a Beil he oBEnE iv:ic imE a R ET nO SC LOR y O FY ure e URE