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Material Safety Data Sheet
May be used to comply with OSHA's Hazara Communication Standard. .*9 CFR 1910.1200. Standard must be consulted tor specific requirements.
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1^4287 Yellow
U.S. Department of Labor
Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 1218-0072
Nora; Blank spaces are not permitted. M any Hem is not applicable, or no information is available, the space must be marked to indicate that.
Section I
Manufacturer's Name
HARWICH CHEMICAL CORPORATION
Address (Number, Street. City, State, and ZIP Code)
60 South Seiberling Street
Akron, OH
n
44305
Emergency Telephone Number
(216) 798-9300
Telephone Number lor Information
Same
Date Prepared
August 5, 1988
Signature of Preparer (optional)
i>
Section II -- Hazardous Ingredients/tdentity Information
Hazardous Components (Specific Chemical Identity; Common Name(s)) OSHA PEL `
Titanium Dioxide CAS #13463-67-7
15mg/mJ
Iron Oxide CAS #1309-37-1 **Lead (as Pb) **Chrcmate (as Cr)
10mcr/m3 . 05mg/mJ
lmg/rn
1
ACGIH TLV
*5mg/mJ *5nw/m3 .15mg/m3 . 5mg/m3
Other Limits Recommended
% (optional)
>1
>1 . 4 5mg/mJ STEL >1
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*TLV for respirable nuisance dust. Not likely in product form.
**Contained in Cl Pigment Yellow 34, Cl #77603, CAS #1344-37-2.
%
Section III -- Physical/Chemical Characteristics
lioiling Point
N/A
Vapor Pressure (mm Hg.)
N/A
Vapor Density (AIR 1) Solubility in Water
N/A
Appearance and Odor
Section IV -- Rre and Explosion Hazard Data
Flash Point (Method Used)
N/A
Extinguishing Media
C02r dry chemical, water spray
Special Fire Fighting Procedures
Specific Gravity (H2O - 1)
calculated
Melting Pont
Evaporation Rate (Butyl Acetate - 1)
Flammable Limits
N/A
LEL
2.42 N/D N/A
UEL
cool fire exposed surfaces and to protect fire fighting personnel. .
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Unusual Fire and Explosion Hazards
Fire conditions produce HC1. In the presence of heat and organic matter, lead chromate
can cause an oxidation reaction resulting in fire.
(Reproduce locally)
=Not Appl icable
N/D = not Determined
OSHA 174, Sept. 1985
VAB.0001071922
Section V
stability
Reactivity Data
Unstable
I Bonnot
above 200C to avoid possible release of HC1
Stable
X
i ncompatlbility (Mar(iariaIs to Avoid) Strong oxidi
h^^dou^0pc>mpo9ition or Byproducts
(toxic and corrosive). Ignition sources
Hazardous Polymerization
May Occur Will Not Occur
Conditions to Avoid
None known X
Section VI Health Hazard Data
Routo(8) of Entry:
Inhalation?
Not 1:
Skin?
fealth HazardsJAqute and ChronicJL .....
.. .
..
.,
Acute: If dusty may irritate the eyes, skin and respiratory tract
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Refer to the OSHA Standard Vinyl Chloride 29CFR.1910 for a full discussion of possible
health effects'.--Chronic:--prolonged overexposure may cause lead yui-soniny involving-- delayed effects in the blood, gastrointestinal, nervous and reproductory systems.
Carcinogenicity:
Lead Chromate
NTP?
Snsnect
IARC Monographs?
Suspect
OSHA Regulated?
No
Lead chromate is an ACGIH suspect carcinogen. Sligiansratnyd Ssyymspttoemms osf ExoS^lead poisoning are fatigue, disturbance of sleep and constipation
With more severe exposure; colic, anemia and nueritis. Generally Aggravated by Exposure Respiratory and skin disorders aggravated by dust*
ency and First Aid Procedures.
Inhalation: Move to fresh air,
artificial respiration if necessary, call a doctor.
byes: Flit
s," call a due Lai.--Skin:--Wash willi
Ingestion; Induce vomiting, call a doctor
Section VII -- Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled
prevent additional discharge of material* Recover spilled material and place in a
suitable container for recycle or disposal* Depending on the quantity spilled, notifica
tion of the National Response Center (800-424-8802) may be necessary
/aste Disposal Method
Dispose of in accordance with all Federal, State and Local regulations.
Lead chromate
pigments are a hazardous waste on the basis of EP Toxicity. Test waste mixture for EP
Precautions to Be Taken in Handling and Storing
Do not store near flame or neat. Refer to the OSHA Standard mentioned in Section VI
Heated material may cause thermal burns.
Other Precautions
None
Section VIII -- Control Measures
Respiratory Protection (Specify Typo)
TT.d^ a ntosh/MSHA approved respirator above PEL or TLV.
Ventilation
Local Exhaust
To maintain PEL & TLV
Special
None
^TMiT^PEL TLV
Protective Gloves
Imnervious
Other Protective Clothing or Equipment
None
Work/Hygienic Practices
..
Wash before eating or smoking.
0mt$one ______i____________________________________________________
Eye Protection
Safety glasses
*
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