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344
CHAPTER 13
1952 Guide
Table 8. Approximate Air Requirements for Theoretically Perfect Combustion of Fuels*
Ttpe OF
Fuel
Air Requires fob Perfect Combustion
Lin per Lb Fuel
Cu Ft per Unit^ Fuel
AppboxiPreci-
Per Cent
Exceptions
Solid Btu per lb X 0.00073 Btu per lb X 0.0097
3
Liquid Btu per lb X 0.00071 Btu per lb X 0.0094
3
Gas Btu per lb X 0.00067 Btu per cu ft X .0.0089 . 5,
`
Fuels containing more than-30%
. water Results low for
gasoline and kerosene Gases of. 300 Btu per. cu ft or
_ less
.: a Values in table taken from page 276 of Gaseous Fuels, 1648, published by American Gas Association. k Units for solid and liquid fuels in pounds, for gas in cubic feet.
2. Fuel Oil (Pounds air per gallon): Commercial Standard No. 1, 102.6; No. 2, 105.5; No. 5, 112; No. 6, 114.2.
3. Gaseous Fuels (Cubic feet of air per cubic foot): Natural, 10.0; Mixed Natural and Manufactured, 8.0; Manufactured, 4.7, Propane, 23.8, Butane, 31.0.
..COMBUSTION EFFICIENCY FROM THE FLUE GAS ANALYSIS
Excess Air
A commonly employed index of efficiency of combustion is the relation existing between the amount of air theoretically required for perfect com bustion and the amount of air actually supplied. Since the difference between air supplied for combustion and theoretical air required is charac terized as excess air, its percentage may be calculated by use of the follow
ing equation, .
-( -)>Percent excess air
Air supplied -- Theoretical air X 100
Theoretical air
(5)
` The amount of dry air supplied per pound of fuel burned may be obtained from Equation 6 which has reasonable precision for most solid and liquid fuels. Values for C02, CO and Nt are percentages by volume from the flue gas analysis, and C is the weight of: carbon burned per pound of fuel, cor rected: for carbon in the ash.
3.04Nt %; _ Pounds.dry air supplied per pound of fuel X (CO, + CO) x
(6)
Because excess air calculations are almost invariably made from Orsat analysis results, and theoretical air requirements are not always known, another convenient method of expressing the relation of Equation 5 is as
follows:-
. 100(0, -CO/2) Percent excess air = ^ x 0 264 _ (0j _ c0/2)
: (7>
As measurement standards for gaseous fuels are almost universally ex
pressed in cubic,feet, Equation 8 may be employed for computing excess
air on a percentage basis for gases.21
;
Percent excess air =
---. X 100 --
CO, .
A
(8)
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Fuels and Combustion
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Table 9. Approximate Maximum Theoretical CO, Values, and 1 CO, Values for Various Fuels with Different Percentages of' ` Excess Air
i,!
Type of Fuel
- Maximum
Theoretical or
Ultimate
Percent COs
COPercent
s at Given Excess
Air Values
20% '
. 40%
60% ' `
Coke Anthracite Bituminous Coal
No. 1 and 2 Fuel Oil
.
21.0 20.2
17.5: . 16.8
15.0 ' 14.4
:. 43.0 ' f 12.6
18.2
15.1
12.9
11.3
15.0
. 12.3
10.5
9.1,
No. 6 Fuel Oil Natural Gas Carburetted Water Gas Coke Oven Gas
,;
16.5
12.1
13.6 11.6 '10.1
9.9
8.4; .
7.3
17.2
.14.2
. 12:1
10.6
11.2 9.2 7.8 6.8
Mixed Gas (Natural and Carbu. retted Water Gas)
Propane Gas (Commercial) Butane Gas (Commercial)
15.3
13.9 . 14.1 1
12.5 11.4 il.6"
. 10.5 9.6 9:8 '
. 9.1 8.4
- 8.5
where
U = ultimate carbon, dioxide, percent of flue gases resulting from perfect com
bustion.
-.'
CO, " carbon dioxide content of flue gases, percent.
P = dry products from perfect combustion, cubic feet per cubic: foot of gas burned.
-4 -- air theoretically required for complete combustion,- -'cubic-feet-per-cubic foot of gas burned.
As the ratio of P/A is approximately 0.9 for most city gases, a value of P
90 may be substituted: for 100 in Equation s for rough calculation.
Carbon-hydrogen ratios of different fuels vary considerably, 'hence the
maximum or ultimate CO, attainable also varies. Where they are un
known, theoretical maximum CO, values may be calculated from a flue gas
analysis by use of Equation 9.
;.
Maximum theoretical % CO, = % COs i Aue gas sample.X 1Q0V
) / O, in same sampleX
"V
0.21
'
Approximate maximum CO2 values for perfect combustion' of . several common types of fuel are shown in Table 9 , together with values of'CO, that will be attained with different amounts of excess air. Dearable values
attained Photic depend upon the fuel, the method of Airing, and
other considerations. In general, fuels burned in suspension, such as gas,
Pn, and pulverized coal, can be burned with a lower amount of excess air
than fuels burned on grates.
'
To produce heat efficiently by burning any common: fuel. a number of
baac requirements must be met: (1) adequate heat absorbing surface of proper shape and construction is necessary in the appliance, (2) heat transler surfaces must be clean, (3) a minimum amount, of excess air must be present, (4) air employed for combustion and combustible gases must be properly mixed, and (5) flue gas losses must be reduced to a safe minimum.
If insufficient heating surface is employed, or if heat transfer surfaces are covered, with soot, ash, or scale,' flue losses will generally be excessive