Document kkB8vG69gD0r612e3NM4L8O

AR2RG -- O74 ASFTFUFDYANSDUMCMOAMRPYONOEFNETNSV-I1R9O9N1MENTAL EFFECTS OF LIGHT WATER BRAND IEsTsuesTA00N 000C 000E 0 Identity: A mixture containing perfluorooctanesulfonate, which may also be rOecftearnreesdutlofoansicPFacOiSd,) (FCC-A9S5#, o2r79a5s-3a9-c3o)m.ponent of FC-203. (1- Remarks: is FC-203. CuTrhreen3t Minpfroormdautcitoinoninldoticnautemsbeitriswaasminxotturneotoefd.1.T34h%e tPeFsOtSs,am3p5le% dSiueltthoynleenfeoagmleyrc,ol3b%utysloedtihuerm,o3ct7y.l8s5u%lfawtaet,er0,.12%0%soedtihuymlelnaeurgyllycsoull,fa2te.,66an%d 0.05% tolyltriazole. cThhaerafcotlelorwiiznegd csounmcmenatrryataipopnlsioefs tiompaurmiitxiteusr.eDwaittha imnacyomnpoltetaeclcyurately reflect toxicity or degradation of the fluorochemical component of the test sample. ReSwrs 000000 Degradability [Study -- TVae(source)1] BOD: TrotComaAmyRep ET cob Pe SotGeman Te ____ Aquatic toxicity - [Study 7 Vale(sowrce) | [Mieotox | [EC 632mg (Ger] manAmyRepor) | [__ ECw| 2500mgl (German AmyRepor) | [ActivatedSludge Inhibition ______| Noneat1,000mgL3M) | `Algae (Chlorella pyrenoidosa and No effectat<1,000 mg/L (3M) -- [APlhgoarem(iSdcieunmeidneusnmdautsusmu)bspicatus) | (Waterries Daphniamagna) | : 000812 4224E-hhhrr SSSttWaaIttiiGccEEECCeC,| 48-hr Static ECs. 31.6 mg/L (German A Report) 29mglGM) 1,600 mg/L (3M) Eastern Oyster Embryo-larvae (Crassostrea Virginica) | 48-hr Static ECs. 47 mg/L (3M) Grass Shrimp Shr Sic (Palaemonetes pugio) lCp|STOmgLEM| Shr Static LC|7_5_0mgLem| Zebrafish (Brachydaniorerio) 48-hr Static LC, [1,053 mg/L (German A Report) [Scud (Gammaris 48-hr fasciatusE) h SStEatiicc CLoC]|--T_1,A634 m0g/L 0(GemrmangLReEportw) || Rainbow trout (Oncorhyncusmykiss) 96-hr Static LCs 1,300 mg/L (3M) 96-hr Continuous Flow LCs "400 mg/L (3M) `Common mummichog (Fundulus heteroclitus) 96-hr Static LCs 2,500 mg/L (3M) * Any study marked with "3M" as the source includes studies done at the request of 3M by labs other than the 3M Environmental Lab. D0 ATAQUA0 LITY 000000 Reliability: These studies have been assigned Klimish rankings = 4. Values are from a summary list only. OTHER Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 Last changed: 6/27/00 000813 Technical Report Summary am To: Patent & Technical Communications Services -- 201.20-12 Raport Summmausrtbyo typawiten, Guidelines a on vars side 9pot3pinted on Bo idesof Apr,Sand we copies 0 P 8 TCS. ont J = Fo rrr 5 as ERagkedr0 B |a-le a Howell a RD. ET e295n86c4 Persemer| l;Eayironmental Engineering & Rollution Control... OL_.089 JEE&PC_ EPP_Re ansdDeevaelr opc meh nt ---- Raoywdoris RE Environm Effects of LICHT WATER Brand AFFF and Components! == (demand, BOD, chemical oxygen demand, COD. LIGHT WATER, aqueous foam, FC-203, FC-206, ethylene glycol, butyl Carbitol, sodium laurylsulfate, Duponol, sodium dodecylsulfate, sodium octylsulfate, L-4640, triethanolamine, urea, Triton X-305, foamer, filmer, surfactant, tolyltriazole, environmental effects, toxicity, Daphnia toxicity, Microtox, algal toxicity, fish toxicity, degradability, biochemical oxygen Prefect Objective & Roport ABWEact 1c.oTmopoandednttos tuhseekdnionwtlheedpgreodbuacstes.of2.enTvoiriodnemennttatloexfifceccotmsopofnLeIntGsHTanWdAtToEcoRrrberlaatnedcaoqmupeoonuesnftilamnfdoprrmoidngucftotaomxisacintidest.he requirements have been noted. Where sulficient data on the toxicity and degradabty of individual components were This technical report includes a summary of environmental effects data on 3M's products and the components used in them. The data was taken from the literatureand from previous studiesby the 3M Environmental LaboratorTyhe. data for each component and each product have been evaluatedfor completeness and accuracy and additional testing available, the data were evaluated and recommendations regarding inclusion of the component in future products have been made. |An attempt was made to correlate the toxicity of FC-203 to the toxicity of its components by taking info consideration the ccoonmcpeontnreanttiocnonocfeinntdriavtiidouanlicn otmhepopnroedrusct,.mWahjiolrecpornoidbuucttotroxsic0itpyrcooduulcdtn0oxtKbceAycaorncolubslivleelyvce1odrreblaattehd tfo thie ttohexeicfirtoyaam,ned, obaumtthuyylliaeCtnaiarboginltysoclosTMlh.,otuaolnlddyterDniuaapzboolnleoel,bTMestotdeMiruEcmo(rorsceotldyaiitsiuuomlnalbateuer,tywlasenuedlnfaDctIeo-)wm.aptCoeonrm.epFnoutrntaehnnedtrpstroolxidkiueclcyytttotoecxsiotcniitntrigiebso.futceolmepsosnteonptrsodauncdt ptorxoidcuictyt are FoF Ty [Soca errr P7i4tDotRpeisnat and Omvlopmant TFaRctTorry EorxFandmeRnetpo MaMAnNaugteamcetnutrnSguMmary 3 REOnIcRieneceoinrogdfinvention TD OpeneportandSumman --_-- Closed Repor-OpenSummary |CEhramrical 9 cTeocwh.. Spervoijcest 3 omen 0LNoEw GhericiasiRnepoorse 000814 Contents HL IPUIDOBE conmssssosmsmesssssmmsstsmtsaitssiisstmsissssismsms 2 111. GONGFEl COMMONS .rcverrrsmssssmsssssss J -------- V. EnvironmentalEHects LErature SBarth ........wwmmermmmsmmssmssions 9 + 1.Ethylene GIYCol (RM 3017) ..occccvcmmisssssssssssssssssssssssssssssssssssssssssssssssssssss 10 2. Butyl Carbitol (RMBBB7) verses. 12 3. Duponol (RM 3021); Duponol ME Dry Surfactant (Sodium Lauryl Sulfate) ...... 14 4. Tolyltriazole (RM 27513; Corrosion InhibitorTolyltriazole Technical Grade) ..... 16 5. FOAMET (FMA115) oss: 18 6. FIIMer (FM-3820 OF FC-95) .cvrrrrrsrerrmsssssssssssssssss 18 7. Na-octylsulfate (RM 32067 OF RM 55040) ........rrrrmsnmssr 19 SOIWHIHAD IBY cusmmmmibnnmommmmmmsmmmnsnmnsn 20, 0 FOROS commimnmumnsissmmmmmrmmnsrmsmsn Ti 10. VW160390 (FC-203 without Tolyltriazole RM 27513) ...c...errrrrree 23 $1PODDBOE, cnmnmprmgummmmmmmmmmismmmmsmmsssssssens 2h 1B. FORPECR snemmmrmmmssmmrsmmsmmmmmsmmsssssmsenn 85 EFORCE cummins 38 14. FC-20BCF onrsnsmsvmsisssssssssses 28 15. L-4640 (NOW FORMEN) .crrvrrrrrrrrerrrsrssnssssssssssssssssnss 28 16. WHCOIaL 7093 (RM 45666) ....r.rvcervrerrrrrsnrssnsrssssssssnss 27 VL, THGHAEIRIANG scons 2 1B IHR commssmmsmmmmnmsnmm---- 20 19.THON X-305 cocvvrvvrrrsrsssnsssssssssssssssssssssssssssssssssssssssssssssssssssssns. 30 1- . 000815 Environmental Effects of LIGHT WATERTM Aqueous Film Forming Foam and Components 1. Purpose The purpose of this study is to increase 3M's knowledgeof the environmental effects of pLrIoGduHcTt.WAAnTd,ERbyTMuandqeuresotuasndfiilnmgftohremsiengefffoecatms,atnodmtihneimiinzdeivtidhueaml ctohmropuognhenfotrsmuulsaetdiotnocmhaakngeetsh.e I. Background Trheipsorstteuddiyn w"aInsveusntdiegrattiaoknesnoifnTroexsipcoEnfsfeecttos taenstdinBgiodloogniecablyDtehgeraGdaabrimlaftnyAorf mFyoawhmicExhtwinagsuishing Agents in Wastewater" by Ekkehard Ising. The report, hereafter referred to as the "German Army Report", included data for 16 fire fighting materials, of which two were 3M's FC-203 and FC-206. The 16 fire extinguishing agents were categorized as: 5 multi-range foam agents 6 film-forming foam agents. 3 protein foam agents 1 film-forming fluorine-protein foam agent 1 special foam agent for deep-fry pan fires Environmental effects considered in the German Army Report were: 1. Acute toxicity to the marine photoluminescent bacterium Photobacterium phosphoreum using the Microtox system. The toxicity was expressed as EC. and ECy,, however, the exposure time is not clear from the German Army Report and may have been 10, 20, or 30 minutes. Two multi-range foam agents were considered "highly toxic". Three multi-range foam agents and 2 film forming agents were found to be "toxic". Four film-forming, all 3 protein, the film-forming fluorine-protein agent, and the deep-fry agent were considered to have "low toxicity". FC-203 and FC-206 were in the "low toxicity" category. _ 2. Algae cell multiplication inhibition test using Scenedesmus subspicatus as the test organism with an exposure time of 72 hours. Toxicity was expressed as EC ,, and ECs. All foam agents with the exception of two of the protein foam agents were "toxic" to algae. The two protein foam agents had weak toxicity to algae. Both 3M products were considered "toxic" to algae. 3. Acute toxicity to Daphnia magna after exposure for 24 hours. The toxicity was expressed as LC, and LCs, but the effect criterion was the organisms" loss of ability to swim and will be referred to as EC yo and EC, in this report. All 5 multirange foam agents, all film-forming agents except FC-206, and the deep-fry agent were toxic" to -2- 000816 Daphnia. One film-forming agent (FC-206), all three protein agents, and the film-forming fluorine-protain agent had "low toxicity" to Daphnia. FC-203: "oxicTM; FC-206: "low toxicity". 4. cArciutetreiatowxaicsitdyetaothZeabnradttihseh t(oBxricaicthyywdaansieoxrperriecs)saefdtearseLxpCo1s,uarnedfoLrC4.8 Ohonulrys.twTohe mult-range foam agents were "toxic" to fish. Three multi-range foam agents and two ffiillmm--ffoorrmmiinngg aaggeennttss,w2erpreot"ebionrdfeorlaimneagteonxtisc,iwaankdlythteoxdiec"e.p"-Wreyaakgleyntt.oxOicn"ewefirme-f4orming agent and the film-forming fluorine-protein agent were "non-toxic". FC-203 and - FC-206 were in the "weakly toxic" category. 5. Chemical Oxygen Demand (COD) and 5-day Biochemical Oxygen Demand (BOD s) of a3% solutionofthe test material in water. The ratio of BOD s to GOD was used as arating guideline, with a BOD/COD ratio of 0.5 o less considered insufficient b(iFoCc-h2e0m6i)cwalerdeegcroandsaitidoenr"e.dTinwsouffmiucliteint-lryandgeegraagednetdsbaioncdhoemniecaflilmy-.fTorhmeinrgatiaogefonrtFC-206 was 0.35. One mult-range agent and one fim forming agent (FC-203) were considered "probably insufficient" because their BOD /COD ratios were 0.55. The 9 0r.e8m9a.ining agents were all sufficient with their BOD /COD ratios ranging from 0.60 to The data from the German Army Report for the two 3M products are summarized In the table baenldowse.lTf-hceondsaitsatefnotr".thTehMeicdraottaoxa,reZecbornasfiisdhe,reCdOrDe,asaonndabBlOeDbe,ceasutssesteheeymatgorbeee "farieralysowneallblwei"th data from previous 3M studies and are considered self-consistent because the FC-206 data aro roughly half that of FC-203. M.ertEo ome| aLow Tot2t0y | `Summary of German Army Report Data Goopion | oZnubeenlow tesTote m0 | asToteao|[tWemoy Treerrm | wo,| sor0astco00 protsaetty 20o0wTotrseay | tesTote:wo | sTos o2t00 | |2Waeeak Tdooieers|| 2emm [---- _3- 000817 AForrmyt'hse aallggaalstdoaxitcaitsyhdoatwa,estsheentrisaalrlye etqwuoiviamlpeonrttatnoxticpiotiynftosrtooucrontswiodeprr.odFuicrstts,.tOheneGewromuladnexpect more tests. toxicity for However, FC-203 than for higher toxicity by FC-206, FC-203 as shown in the than by FC-206 Microtox, Zebrafish, and may not always be true. Daphnia For tehxeampphloet,ostyhnetrheetmiacyprboeceassc.omSpeocnonedn,t owuhricPhEiDs pfaorrtFicCu-l2ar0l3y tionxdiiccattoeaslgnaoe,efpfeecrthtaoptswdoisarlugpatling tshpeecsiaesmeatacsotncheonsteriantitohnesGueprtmoa1n,0A0r0mymgR/eLp.orWth,iltehetyheartewoallaflrgeaslhswpaetceiresspoencitehse PED are and such not a tlhaartgetddiaftfeesrefnrceomin1t9o7xi4ciatnydwoitulhdans'tbebeenexipmepocstseidb.lOentoeviemripfoyrttahnetelxiamcittaftioornmuwliatthitohneoPf tEhDe. data is sample used in those tests. For the Daphnia data in the German Army Report, the difference between the FC-206 and tFhCe-r2a0i3s vaaclounessidseereamblseldairfgfeewrahnecne bceontswiedeenritnhgetPheEDwadtaetracaonntdetnhteoGf ethremtawnoAfrormmyuldaattiao.nsO.urAlso, PED has a 48-hr static Daphnia magna LCs, of 1,600 mg/L. wile the German Army Report has a 24-hr static Daphnia magna EC, is 430 mg/L. The PED data is quite old (1973) and the fPoErmDuldaattiaonanofdtthheetGeestrsmaamnplAermcyandnaottabien tvheartiftihede.PTEheDredaitsaaimsatjhoercdoinfcfeenrternacteiobnewthwiecehnctahueses. death to 50% concentration of the which Daphnia test causes 50% population(LC5) and the German Army value is the of the test population to stop swimming (Effective Concentration = ECy,). The German Army value is infair agreement with recent results * which show a 48-hr static Daphnia magna EC s, of 229 mg/L. One thing that should be kept in mind when considering the toxicity data is that reproducibility tainmde.prHeocwiesvioenr,oftthoexidciiftfyetreesntcsescabnetvwareyencotnhseidoeldradbaltyaf(rcoimrclaa1bo9r7a4t)orayntdotlhaebomroartoeryreacnendtodvaetra is Amtoraenylirkaetley,douusrtporcimhaarnygiensteirnesftorsmhuolualtdiobneratthheertotxhiacintycohfaonugrecsuirnretnetstpprroodtuocctosl aonrdtewset'sspheocuileds. be concerned with having current, reliable data on our PEDs. il. General Comments The following general statements summarize the factors guiding this study. 1. The primary purpose of the environmental effects data isfor internal use in evaluating formulations and ingredients and regulatory authorities. Therefore, not any intended for submission testing should be done to governmental using low-cost, . non-GLP methods. An exception may be data for the new foamer (L-4640) which may need to be submitted for the European PMN currently underway. 1 DErnavftirRoeSpyosrttefmrsotmoErnevpieraotStyhsetDemasphLnaibaortaetsotsryfodraFteCd-2M0a3rcahnd10V,W11969013.3W0e. Thhaevepraeslkiemidnary ~~ results from EnviroSystems on the rest of the samples were acceptable. -a- 000818 2. The German Army Army is presently performs using the its own testing and evaluation scheme no authority used in the other report than the German cited above. Tahpeprleicfaobrlee, otnhleyretoisthneo Gneeremdatno cAhromoysetesatlsacbohreamteor.y,Intsetsetapdr,otteosctolm,eotfhtoedstssapnedcisepsecies should be chosensothat test results can be used in as many countries as possible. 3. W`hferormethpeoslsiitbelrea,tudraetoar ofnrotmheraewnvmiartoenrmiaelntsaulppelfifeercstsinoofrcdoemrtpoonreendtusceshtoeusltidnbgecoosbttsaiannedd time. 4. The National Institute of Occupational Safety and Health relative toxicity of the components and the formulations (NIOSH) terminologyfor will be used in the the dRiespcoursts,itohneoyfatroexigceneeffreacltlsy. aWchcielpettehdesinettheerUmsS.weTrhee ntooxtiucisteydanindtchoerGreesrpmoandniAngrmtyerms are: Concentration Acutely Toxic to Test Population NIOcoSH Terminology <1 mgiL 1-10 moll 10-100 mgiL 100 - 1,000 mg/L. >1,000 mg/L "Highly Toxic" "Moderately Toxic" "Slightly Toxic "Practically Non-Toxic" Insignificant Toxicity" 5. The LIGHT WATER AFFF formulations and components considered are: 1. Ethylene Glycol (RM 3017) 2. Butyl Carbitol (RM 8887) 3. Duponol ME (RM 3021) 4. Tolyltriazole (RM 27513) 5. Foamer (FM-4115) 6. Filmer (FM-3820 = FC-95) - 7. Na-octylsulfate (RM 32067 or RM 55040) 8. 9. FDlC--w2a0t3er (RD 199) 10. VW160390 (FC-203 without Tolyitriazole RM 27513) 11. FC-203CE (same as FC-203C) 12. FC-206CE 1143.. FFCC--220063CCFF se, .5- 000819 15. L-4640 16. Witcolate 7093 (RM 45666) 17. Triethanolamine 18. Urea 19. Triton X-305 Items 1 to 10 are froma list given to Eric Reiner by Wim Vanneste 3/12/90. Items 11 10 13 were given to the author by Wim Vanneste 2/5/91. Items 14 10 16 were given to the author by Roger Alm (2/4/91). IV. Conclusions and Recommendations In order to correlate the toxicity of the product to the toxicity of individual components, the component concentration Is taken into consideration. In the table below, the toxicity to Daphniaof the pure components are given in the third column. The fifth column contains estimated toxicities based on product formulation. This is the toxicity which would be expected `when the component is diluted inwater to the same concentration as in the product. For example, one would expect that since the toxicity of pure butyl Carbitol is about 700 mg/L, the toxicity of a solution made of 35% butyl Carbitol and 65%waterwould have a toxicityof about 2,000. Some interesting observations can be made from these numbers. First, even though tolyltriazole is quite toxic, it is present at low concentration in the product and when diluted in the product it probably does not contribute substantially to product toxicity. However, this analysis does not exonerate tolyltriazole as a major contributor to product toxicity. Second, the cloonwtersitbuntuomrsbetorspriondtuhcetftifotxhicciotyl:ubmuntyilnCdaircbaitteoclo,mpDounpeonntoslwhMiEch(dwioldlecbyelstuhlefamtoes),t tlhikeelfyoamer, and the filmer. Unfortunately, there is not a single component which stands out with a numberin the fifth column which is substantially lower than all the rest. This may mean that thera is a synergistic effect between components. -6- 000820 Summary of Recent Daphnia Toxicity Data fom Name parr] = myc pe (RM 8887) em To reiume)r 6 iFuem2e 0 F009) TTpe SEE Er) Too 2a 100) Zeasam "wwe wan 93-56) sree OR 2noox aso oo oon ze 134% on ite oR on Fratyr or Proaty 2300 Prony 000 Proattoyt an CE Test =) Probably Pratott a DFonm "oo a FT Yo + rom 0-4) x Wo ywemeroxe some) - x The important conclusion from these Daphnia results is that a more complete set of toxicity data is needed, especially for algae. The table below summarizes the additional data needed to complete the environmental effects database on our products and their ingredients. Additional tests are indicated with an X. 2 Preliminary results from EnviroSystems, March 10, 1991. 7. | 000821 Summary of Additional Testing ee CR eAr s Team xx < BHYEhSemme x x x Tmwi xx xx Erme xx xxx 6 FFimeer -roso x x :- Tam RL Shussou x x xxx a + rom {RD196) x > SpEeNmSrEeSs x x x x o ERm xx rome xx oro xxxx x rower xxxxxx veo xx m nds xxxxxx a - wow oreo xxxxxx To =w. 7 . w [SS ---- "8 000822 V. Environmental Effects Literature Search Data from previous 3M Environmental Laboratory Studies and from the literature are `summarized in this section. Toxicity data noted by "AQUIRE" were obtained from a search of the USEPA AQUIRE database on Feb. 12, 1991. Included as part of the reference for the data from AQUIRE are the date of publication of the original journal article and the review code established by a group of EPA reviewers. The reviewers have ranked toxicity data from the literature by the following scale: 1. Meets all review criteria. 2. Procedures generally satisfactory. 3. Insufficient in some area of the test methodology or test report. 4. Abstract or foreign paper with data in limited format. The complete contents of the AQUIRE database for eachchemical is not given in this report because the database includes many obscure species of litle interest (opossum shrimp, Indian catfish, snakehead catfish, oysters, clams, sponges and many others) and data which is considered by the EPA reviewers to be of questionable value. Additional degradability and toxicity data have been taken from the Handbook of Environmental Data on Organic Chemicals by Karel Verschueren (Nostrand Reinhold, New York, 1983). These are referenced by page number in the Handbook followed by the date of the original reference. There are many cases in which the same data appeared on AQUIRE and in Verschueren but only the AQUIRE reference is given because it includes the EPA quality rating of the original reference. Raw material suppliers were identified from the 3M PRISM database and suppliers were contacted and asked for any environmental data they have. Unfortunately, environmental data was not generally available from raw material suppliers. And, the suppliers were slow in sending the limited data do have. The source and reliability of the literature datawas taken into consideration in the environmental assessment of the components and the recommendationsforfurther testing. RIenpfoorrmtatFioornmafotr:each component or formulation is organized as follows: _ Formulation or component name and RM number Chemical Abstracts Service (CAS) Number Vendors Degradability data from the literature or from previous 3M assessments Aquatic Toxicity data from the literature or from previous 3M assessments Environmental Assessment Recommendations for Additional Testing - -9- 000823 Detailed information for components and formulations are given in the same order as in the list above. 1. Ethylene Glycol (RM 3017) CAS#107-21-1 `Vendors: Chemtech, Ashland Chemical, Dow Chemical, Texaco Chemical, Olin, Shell Of, Union Carbide, Textile Chemical, Ashland Chemical, Unocal Degradability: Theoretical Oxygen Demand (ThOD) BOD, BOD, Bi BOD, BOD, co-p BOD,/COD Ratio BOD,/COD Ratio 1.29 g/g (Verschueren p646) 0.440.22 g/g (avg of 12 citations from Verschueren p 646) 0.52 gig (Env. Lab. Req. #1940) 01..6179 gg//gg ((EVnevr.scLhaube.rReenqp. 6#4169;401)953) 0.92 g/g (Verschuerenp 646; 1953) 1.14 g/g (Env. Lab. Req. #1940) 1.000.08 g/g (avg of 3 citations from Verschueren p 646) 1.02 g/g (Env. Lab. Req. #1940) 1.2420.04 g/g (avg of 3 citations from Verschueren p 646) 1.28 g/g (Env. Lab Req. #1940) 0.4 (Env. Lab Req. #1940) 0.8 (Env. Lab Req. #1940) Toxicity:* Green Alga (Scenedesmus quadricauda) - 7-day Static Popul. Growth Inhib. 10,000 mg/L (AQUIRE 2; 1980) 8-day static Popul. Growth Inhib. 10,000 mg/L (AQUIRE 2; 1978) 33M Environmental Lab work done in Dec. 1973. 4 The toxicity data are a partial isting of 38 tests on 16 species from the EPA AQUIRE database. --- 5 Population Growth Inhibition: Change in cell number of algal species including pre-exponential lag rate effects. -10- 000824 Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth inhib. Bacteria (Pseudomonas putida) Algae (Microcystis aeruginosa) Protozoa (Uronema parduczi) Water flea (Daphnia magna) 48-hr Static ECs, 24-hr Static LCy 24-hr Static LC, 48-r Static LCs, Brine shrimp (Artemia salina) 24-r Static LCs, 24-hr Static LC, Fathead Minnow (Pimephales promelas) 24-hr Static LC, 48-hr Static LC, 96-hr Static LC, . 96-hr Static LCq, Bluegill Sunfish (Lepomis macrochirus) 96-hr Static LC, 10,000 mg/L (AQUIRE 2; 1980) 2,000 mg/L (AQUIRE 2; 1978) >10,000 mg/L. (Verschueren p 647) 2,000 mg/L (Verschueren p 647) >10,000 mg/L (Verschueren p 647) 1,000 mg/L (EnviroSystems 1991) 10,000 mg/L (AQUIRE 2; 1977) 10,000 mg/L (AQUIRE 3; 1983) 10,000 mg/L. (AQUIRE 3; 1983) So 20,000 mg/L. (AQUIRE 2; 1974) 20,000 mg/L (AQUIRE 3; 1983) 10,000 mg/L (AQUIRE 3; 1983) 10,000 mg/L (AQUIRE 3; 1983) 10,000 mg/L (AQUIRE 3; 1983) 49,000 mg/L, 53,000 mg, & 57,000 mg/L (AQUIRE 2; 1983) 10,000 mg/L (AQUIRE 2; 1968) Rain9b6o-whrTrSotuatti(cSLaClqmo gairdner) 41,000 mg/L (AQUIRE 2; 1980) Common Shrimp (Crangon crangon) 48-hr Renewal LCs 100,000 mg/L (AQUIRE 2; 1974) 96-hr Renewal LCs 50,000 mg/L (AQUIRE 2; 1974) Goldfish (Carassius auratus) 96-hr Static LCs 5,000 mg/L (AQUIRE 2; 1979) Guppy (Poecilia reticulata) - 7-day Renewal LC, 49,300 mg/L (AQUIRE 3; 1981) 6 Acute Daphnid toxicity testing done by EnviroSystems for 3M. Test resus dated March 10, 1991. S11 000825 EnEvtihyrloennmeegnltyacollAshsaessisnsmiegnnitf:icant toxicity and a high BOD/COD ratio. Even though itis present in high concentration in the product, it probably does not contribute substantially to product toxicity. gional Testing: None. 2. Butyl Carbitol (RM 8887) CAS# 112-345 (Diethylene Glycol Monobutyl Ether) `Synandovenndoyrs:mBustyl Dioxitol (Cain Chemical), Poly-Solv DB (Olin Corporation), Glycol Ether DB (Oxychem), Butyl Carbitol (Union Carbide Corporation - Linde Div.), Butyl Dioxitol (Shell Oil Company), Dowanol DB (Dow Ghemical), Ektasolve-DB (Eastman Chemical Products, Inc.) - Degradability: ThoD BOD, BOD,, BOD,s BOD, cop BODy/COD Ratio BOD,/COD Ratio Toxicity Bacteria (Pseudomonas putida) 2.17 g/g (calculated) 0.25 (Verschueren p 524) 0.69 g/g (Env. Lab." Req. #1940) 1.45 g/g (Env. Lab. Req. #1940) 1.61 g/g (Env. Lab. Req. #1940) 1.56 g/g (Env. Lab. Req. #1940) 2.08 (Verschueren p 524) 1.83 g/g (Env. Lab. Req. #1940) 0.12 (Verschueren p 524) 0.37 (Env. Lab. Req. #1940) 0.85 (Env. Lab. Req. #1940) - 255 mg/L (Verschueren p 524) 7 3M Environmental Lab work done in Dec. 1973. " 8 The toxicity data are a partial listing of 15 tests on 10 species from the EPA AQUIRE database. S12- 000826 Green Algae (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib. 1,000 mg/L (AQUIRE 2; 1980) 8-day Static Popul. Growth Inhib. 1,000 mg/L (AQUIRE 2; 1978) Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. 53 mg/L (AQUIRE 2; 1978) Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. 73 mg/L (AQUIRE 2; 1980) Protozoa (Uronema parducz) 420 mg/L (Verschueren p 524) : Protozoa (Chilomonasparamecium) 48-hr Popul. Growth Inhib. 2,774 mg/L (AQUIRE 4; 1980) Water Flea (Daphnia magna) 48-hr Static ECy, 708 mg/L (EnviroSystems 1991) 24-hr Static LCs, 2,850 mg/L-(AQUIRE 2; 1977) Bluegill Sunfish (Lepomis macrochirus) 96-hr Static LCy, 1,300 mg/L (AQUIRE 2; 1977) Goldfish (Carassius auratus) 24-hr Static LCs, 2,700 mg/L (AQUIRE 2; 1979) Guppy (Poecilia reticulata) : 7-day Renewal LCs, Silver ide (Leuciscus idus) Static LCyy Inland Silverside (Menidia berylina) - 96-hr Static LCqy 1,150 mg/L (AQUIRE 3; 1981) 1,805 mg/L and 2,304 mg/L. (AQUIRE 3; 1978) 2,000 mg/L. (AQUIRE 2; 1977) EnBvOiDrodnamteansthaolwAsssfeaisrlsymheingth:degradability. The literature data show this material to have insignificant toxicity to fish and Daphnia. The two freshwater green algae values from AQUIRE are consistent and indicate that butyl Carbitol is practically non-toxic to green algae. There is considerably more toxicity shown to blue-green algae, however. We should Bhave a sample)of butylCarbfiionatol tTeesstteidngf:or algal toxicity to be sure of ts toxic effects. Algae and Microtox. -13- ..00 0827 3. Duponol ME Dry Surfactant (RM 3021; Sodium Lauryl Sulfate) CA#S 151-21-3 (Sodium Dodecylsulfate CHy(CH;),,0SO,Na) Vendor; Dupont' ThOD BOD Toxicity: Green Algae (Chlorella sp) Static Popul. Growth inhib. Green Algae (Chlorella vulgaris) | 72-hr Static Growth Inhibition' Green Algae (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib. 8-day Renewal Growth Inhibition Flagellate Euglenoid (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Renewal Popul. Growth Inhib. Bacteria (Pseudomonasputida) Cell Multiplication Inhibition Protozoa (Uronema parducz Cell Multiplication Inhibition 2.03 g/g (calculated) Swisher" reports that "linear primary alkyl sulfates have long been recognized as extremely rapid in primary biodegradation, often disappearing in less than a day" and cites approximately 100 references `which show degradation rates of80 to 100% within a few hoursordays. 50 mg/L (AQUIRE 4; 1980) 0.05 mg/L (AQUIRE 4) 0.02 mg/L (AQUIRE 2; 1980) 0.02 mg/L (AQUIRE 2; 1978) 40 mg/L (AQUIRE 2;) 7 mg/L (AQUIRE 2; 1978) 280 mg/L (Verschueren p 793; 1980) 0.75 mg/L (Verschueren p 793; 1980) _ 9 Phone: 302-774-1000. 2/15/91: will send information. 10 Swisher, 807-811. R. D.SurfactantBiodeg2nrdead.dMaracetlDeikkoer:nNe.w York, 1987, p 466, 11 The toxicity data are a partial listing of the 409 tests on 49 species from in the EPA AQUIRE database. 12 Growth Inhibition: Measurable change in length and/or weight. 14- 000828 Water flea (Daphnia magna) 48-hr Static ECs, 24-hr Static LC4 23.39.0mmgg//LL(E(nAvQiUrIoRSyEs2t;em1s87179)91) 24-r Static LCyy 48-hr Static LCs . 77..20,21.01.0m, &g12(.a0vg(AofQU8;IAREQU3;IR1E9823;) 48-hr Static LCs 5.0109.852)mg/L (avg of 3; AQUIRE 3; 1983) 48-hr Flow-through LC, 1.8 mg/L (AQUIRE 2; 1981) Fathead Minnow (Pimephales promlas) 24-hrStatic LCs 48-hrStatic LCy 7.48 8.5 mg/L (AQUIRE 3; 1963) 6.6 &7.3 mg/L (AQUIRE 3; 1983) 96-hr Static LCs, 6.6 & 6.9 mg/L (AQUIRE 3; 1983) Bluegill (Lepomis macrochirus) So 96-hr Flow-through LCq, 4.5 mg/L (AQUIRE 2; 1981) Mummichog (Fundulus heterociitus) 96-hr Static LCs, 2.1 mg/L (AQUIRE 2) Sheepshead Minnow (Cyprinodon variegatus) 24-hr Static LCy, 48-hr Static LC, 10.0 mg/L (AQUIRE 2) 9.0 mg/L (AQUIRE 2) : 96-hr Static LC, 9.0 mg/L (AQUIRE 2) High-ayes Medaka (Oryzias latipes) 6-hr Renewal LCs, 24-hr Renewal LC, 67 mg/L (AQUIRE 2) 46 mg/L (AQUIRE 2) _ 48-hr Renewal LCy, 46 mg/L (AQUIRE 2) Brine Shrimp (Artemia salina) 24-hr Static LC, 3.6 mg/L (AQUIRE 2; 1974) Atlantic Silverside (Menidia menidia) 96-hr Static LC, 2.8 mg/L (AQUIRE 2; 1982) Killfish (Fundulus similis) 24-4 48-hr Static Static LCs LCy 4.7 4.7 mg/L mg/L (AQUIRE (AQUIRE 2) 2) - 96-hr Static LCs 4.5 mg/L (AQUIRE 2) Rainbow Trout (Salmo gairdner) 48-hr Flow-through LCs 96-hr Flow-through LCs 5.95 mg/L (Verschueren p 793; 1977) 4.62 mg/L (Verschueren p 793; 1977) 10-day Flow-through LCs 2.85 mg/L (Verschueren p 793; 1977) 15 000829 Zebrafish (Brachydanio rerio) 48-hr Flow-through LCs, 96-hr Flow-through LC, 8.81 mg/L (Verschueren p 793; 1977) 7.97 mg/L (Verschueren p 793; 1977) 10-day Flow-through LC, 7.97 mg/L (Verschueren p 793; 1977) Flagfish (Gordanella floridae) 48-hr Flow-through LC, 96-hr Flow-through LC, 10.0 mg/L (Verschueren p 793; 1977) 8.10 mg/L (Verschueren p 793; 1977) 10-day Flow-through LCs, 6.90 mg/L (Verschueren p 793; 1977) EnLvitierroatnumreendtaatalAisnsdiecsastemsefnatir;ly low toxicity to bacteria and although no actual BOD test data are available, this material should be obtained by our should be own BOD readily tests. degraded by microorganisms. A BOD value d`Tahtias amagtreereisalweisllmwoidtehraltiteelryattuorxeidcattoafwishhi,cDhapgihvneisa,usancdonafligdaeen.cOeuirn tmhoesctonrtercaecnttDlaabpohrnaitoaryt'esst `work on this material. testing is warranted. Because there is sufficient fish toxicity data from the literature, no fish Because of the algal toxicity shown in the literature data, algae testing should be done. aEdvveenrstehoeufgfhectthsiwsilmlatbeerimailniismatolxiifcittoisapvaasrsieetdytohfraoquugahtiacwoarsgtaenwiastmesr, titrreeaatdmielnytdseygsrtaedmesorainfda Wsiegnisfhiocaunltdnduomsboemreofsmtuidcireosoringawnhiiscmhsoaurrepprroedsuecnttisinpaasnsaetusratlhrwoaugtheatro mdoedgerlawdaesitterwaapitdelry. `twroeualtdmebnetasysismtuelmatainodn tofheamneaatusruarlebtohdeytoofxiwcatefefrecutssinogf tahneamqoudaerli'usmefsftlouecnkte.dAwniotthhfeirshs.tTuhdiys would give us a. n understandionaling oTfetshteindge.gradation in a river, pond, or lake. : BOD, COD, and Microtox. 4. Tolyltriazole (RM 27513; Corrosion Inhibitor Tolyltriazole Technical Grade) CAS#29385-43-1 CHiN, cr - A N SyMenthoyaln-n1dHv-yeBnedm nozorstsr:iazole -16- | 000830 Methylbenzotriazole Cobratec TT-100 (PMC, Inc.TM) Preventol CI7-100 (Mobay Corp.) Degradability: BOD Toxicity: Water Flea (Daphnia magna) 48-r Static ECs, Bluegill Sunfish 96-hr LCs Rainbow Trout 96-hr LCop Fathead Minnow 96-hr LCs Add1iH-tBiednoaztonatrafiolarzoalseim(iCleaHrNcso)mpound: CAS Number: 95-14-7 Synonyms: 1,2.3-Benzotriazole Aziminobenzene Benzene Azimide * Benzotriazole i Bluegill sunfish (Lepomis macrochirus) Static 24-hr Stress Rainbow Trout (Salmo gairdnen) Static 24-hr Stress Sea Lamprey (Petromyzon marinus) Static 24-hr Stress Chinook Salmon (Oncorhynchus tshawytscha) Static 24-hr Mortality <60% ThOD (Mobay Corp.) 19 mg/L (EnviroSystems 1991) 31.0 mg/L (Mobay Corp. and PMC) 21.4 mg/L (Mobay Corp. and PMC) 25.5 mg/L (Mobay Corp. and PMC) Qu W 5 mg/L (AQUIRE 3; 1957) 5 mg/L (AQUIRE 3; 1957) 5 mg/L (AQUIRE 3; 1957) 10 mg/L (AQUIRE 3; 1969) 13 PMC Specialities Group, Inc. Technical Bulletin 3200. Contact: Bill Mautlewicz (513-242-3300). 14 Mobay Corp. data given by Matthew Bartman 412-777-2000. L17- 000831 Coho Salmon (Oncorhynchus kisutch) Static 24-hr Mortality 10 mg/L (AQUIRE 3; 1969) Northern Squawiish (Ptychocheilus oregonensis) Ea `Static 24-hr Monretnatl;ity 10 mg/L (AQUIRE 3; 1969) While the limited ata shows that this material is moderately toxic, it is present at such low concentration (0.05%) in the product, it may have litle effect in the overall toxicity of the product. Because of the toxicity of this material, we need a complete set of data. There is no reason to repeat the fish data, however. "This material is listed on the TSCA 8(d) list and any testing done must be reported to the oUSEPA. . ---- BOD, COD, algae, and Microtox. - 5. RFoosanmeerr (FM-4115) Water Flea (Daphnia magna) 48-hr Static EC, 68 mg/L (EnviroSystems 1991) EnTvhierfoonammeenrtaslhAoswssesslisgmhtentotx;icity to Daphnia, but there is no data for the remaining environmental effects. We should have a complete set of effects data forthis material. Care sfiould be taken that the sample used in the environmental effects testing is agood representative sample which has been produced by the manufacturing method which will hbe used in the fy uture. --_ BOD, COD, fish, algas, and Microtox. 6. Filmer (FM-3820 or FC-95) . - Degradability: 80D, nil (PED) BOD, nil (PED) BOD; nil (PED) cop nil (PED) TocBODICOD 0 oo S18 000832 Water Flea (Daphnia magna) 48-hr Static ECs, 49 mg/L (EnviroSystems 1991) 4g-hr Static EC, 50 mg/L (PED) Activated Sludge Inhibitory Conc. >4,000 mg/L (PED) Fathead Minnow (Pimephales promelas) 96-hr LCs 38 mg/L (PED) Bluegill Sunfish (Lepomis macrochirus) 96-hr LCs 68 mg/L (PED) Rainbow Trout (Salmo gairdnen) 96-hr LCs 11 mg/L (PED) EnTvhierfoilnmmerenwitlallAnostsceosnstmriebnutte:to the BOD/COD ratio, so toxicity is the issue with this component. This material does show slight toxicityto fish and Daphnia. There is good agreement between previous and present Daphnia toxicity data which gives us confidence in the most recent data from EnviroSystems. We need to have a complete set of effects data for a sample representative of a recent manufacturing lot which has been produced by the manufacturing method which will be Aused in the futu"re. fiona) Texting: `Algae and Microtox. 7. Na-octylsultate (RM 32067 or RM 55040) CAS#142-31-4 Vendors: Alcolac Incorporated (Sodium Octyl Sulfate Solution); Stepan Company (POLYSTEP B-29). Degradability: ThOD 1.88 g/g (calculated) - 15 Wim Vanneste's PROFS note dated 03/12/1990 gives this RM#. 16 Alcolac: 301-355-2600. No data available. 17 Called 708-446-7500 ext. 2283: they have no data. 19- oC 000833 BOD Swisher' reports that "linear primary alkyl sulfates have long been recognized as extremely rapid in primary biodegradation, often disappearing in less than a day" and cites approximately 100 references which show degradation rates of 80 to 100% within a few hours or days. Toxicity: Australian Barnacle (Elminius modestus) 30-min Static Immobilization ECs, Water Flea (Daphnia magna) 48-hr Static EC, 3,970 mg/L (AQUIRE 2; 1976) 517 mg/L (EnviroSystems 1991) En`vAlitrhooungmhennotaBlOAsDsoersCsmOeDntd:ata are available, this material will most likely have a high BOD/COD ratio. BOD and COD data should be obtained so that we have numerical values `which have been obtained in tests comparable to those used for the remaining components. There is surprisingly litle literature data available on the aquatic toxicity of this surfactant, however for the Daphnia data it shows considerably less toxicity than the C 1, surfactant. "This surfactant is present at 3% so it may be amajor factor to toxicity of the product. Fish, algae, and Microtox toxicity data are essential to complete the assessment of this Ringredient. " Testing: BOD, COD, fish, algae, and Microtox. 8. Dl-water (RD 199) Jordy: Water Flea (Daphnia magna) ~~ >1,000 mg/L (EnviroSystems 1991) 48-hr Static EC, EWnhviilreonitmmeanytasleAesmsefsooslmieshntto:test the deionized waterfortoxicity, toxic effects have been traced to contaminated deionized water supplies in the past. The Daphnia result indicates that the supply was not contaminated and no further testing of the deionized water sample is warranted. BNonee.commefnor dAddaititonialToesntinsg: 18 Swisher, 807-811. R. D. Surfactant Biodeg2nrdea d.MdaracetlDeikkoer:nNe,w York, 1987, p 466, 19 There was 1 test given in the EPA AQUIRE database. -20- 000834 9.FC-203 BOD, BOD, cop BOD/COD Toxicity: Microtox EC, EC, Activated Sludge Inhibition Algae (Chlorella pyrenoidosa and Phormidium inundatum) _ Algae (Scenedesmus subspicatus) 72-hr Static Popul. Growth Inhib. EC, 72-hr Static Popul. Growth Inhib. ECs, Water Flea (Daphnia magna) - 24-hr Static EC, 24-hr Static ECs, 48-hr Static EC, 48-hr Static EC, 560 g/L (PED) 717 g/L (German Army Report) 1,060 g/L (PED) 1,070 g/L (PED) 1,373 g/L (German Army Report) 0.52 (PED and German Army Report) 632 mg/L (German Amy Report) 2,500 mg/L (German Army Report) none at 1,000 mg/L (PED) no effect at <1,000 mg/L (PED*') 16.9 mg/L (German Army Report) 160 mg/L (German Army Report) 31.6 mg/L (German Army Report) 430 mg/L. (German Army Report) 229 mg/L (EnviroSystems 1991) 1,600 mg/L (PED) 20 "3% application solutions" were used to obtain the BOD , and COD data in the German Army Report. The German Army values were 41,200 mg/L and 21,500 mg/L for the COD and BOD, respectively. The German Army values were multiplied by 33.3 to get the values in this report. 21 Testing done by Industrial Bio-Test Laboratory, Jan. 1974. 22 EnviroSystems is repeating this test because there was not enough variation in the FC-203 concentrations they used to develop a good standard curve. 23 Testing done by Bionomics Laboratory, Dec. 1973. 21. 000835 Eastern Oyster Embryo-larvae (Crassostrea virginica) 48-r Static ECs, Grass Shrimp (Palaemonetes pugio) 96-hr Static LCs, Fathead minnow (Pimephales promelas) 96-r Static LCs, Zebrafish (Brachydanio rerio) 48-r Static LC, 48-hr Static LCs, Scud (Gammarus fasciatus) 48-hr Static LCs, 47 mg/L (PEDTM) 510 mg/L (PED*) 750 mg/L (PED) i 1,053 mg/L (German Army Report) 1,634 mg/L (German Army Report) 1,100 mg/L (PED*) Rainbow trout (Oncorhyncus mykiss) 96-r Static LCs Rainbow trout (Oncorhyncus mykiss) 96-hr Continuous Flow LCs, Common mummichog (Fundulus heterociitus) 96-hr Static LCs, Grass Shrimp (Palaemonetes pugio) | 96-hr LCs :- 1,300 mg/L (PED) 400 mg/L (PED) 2,500 mg/L (PEDTM) 510 mg/L (PED) En1.viTrhoenfmiesnhttaoxliAcistsyedsastamefnrotm:the German Army Report agrees well with data from previous 3M studies, so no fish testing is needed. 2. The Microtox tests from the German Army Report seem reasonable, so this test should not be repeated. 3. The 24-hr EC, Daphnia toxicity from the most recent EnviroSystems work and the 48-hr EC, from the German Army Report are in fairly good agreement. However, we weren't satisfied with the concentrations used in the EnviroSystems work and they are repeating 24 Testing done by Bionomics Laboratory, July 1980. 25 Testing done by Bionomics Laboratory, Aug. 1979. 26 Testing done by Bionomics Laboratory, Dec. 1973. 27 Formerly Salmo gairdneri. 28 No mortality or abnormal effects at this concentration. 29 Testing done by Bionomics Laboratory, Aug. 1979. 22. : 000836 this work. be due to The large difference formulation changes between German or changes in the Army value toxicity test and the protocol 1973 PED value may but this cannot be verified. t4e.sAtisngwiitshotfhkenfoowanmecromapnodsiftiilmoenr,awnde fnreoemdatoknboewcnarmefaunluftahacttutrhiensgalmotp.le submitted for 5. Since toxicity to algae was of concem in the German Army Report, the algae data is Aprobably the moy st important.ional Testing; BOD, COD, and algae. 10. VW160390 (FC-203 without Tolyltriazole RM 27513) Toxicity: Water Flea (Daphnia magna) 48-r Static ECs 165 mg/L (EnviroSystems 1991) En1.viSirnocnemethnetaolnlAyssdiefsfsermeenncte.between this material and FC-203 is tolyltriazole, testing this material along with FC-203 seems like a good way to determine the effect of tolyltriazole. For the recent Daphnia data, there is little difference between FC-203 and VW160390 and the effect of tolyltriazole cannot be seen. In fact, the toxicity of FC-203 was slightly less than the toxicity of VW160390 in the recent EnviroSystems work. Since EnviroSystems is repeating the Daphnia for these two samples, we will have to wait until EnviroSystems has completed these tests before making an evaluation. | 2. A Microtox and fish toxicity test should be done on this material and the results compared to the FC-203 results to seeif there is a measurable effect caused by tolyltriazole in the product. RBeOcDo,mmaelgnadea,tfiisohn, safnodr AMdidcriottiooxn.alTesting: - 30 EnviroSystems is repeating this test because there was not enough variation in the concentrations they used to develop a good standard curve. .23- 000837 11. FC-203CE Degradabilty: BOD, BOD, BOD, cop 91 g/L (PED) 400 g/L (PED) 680 g/L. (PED) 762 g/L (PED) . BOD,,/COD ratio Total Organic Carbon (TOC) OECD Method 301E Tosi: 0.89 (PED) 220 giL (PED) 88-90% biodegradability in14da2ys (PED) Algae (Selenastrum capricornutum) >1,000 mg/L (PED) 95-hr ICs OECD Activated Sludge Respiration none at 1,000 mg/L. Inhibition Test 209 Water Flea (Daphnia magna) >1,000 mg/L. (PED) 48-hr Static LC, Microtox (Photobacterium phosphoreum) Exposure: ECs 5 min. 370 mg/L 1350mmiinn. 226300 mmgg//LL. Killfish (Fundulus heterocitus) 96-hr Continuous Flow LCs, 1,400 mg/L (PED) Fathead Minnow (Pimephales promelas) 96-hr Continuous Flow LCs, 2,000 mg/L (PED) Emi 96-hr Static LC, . . >1,000 mg/L (PED) - The environmental effects data for FC-203CE is fairly complete. The PED data shows lower toxicity to Daphnia than is shown by FC-203 in the German Army Report and from the recent tests by EnviroSystems. Daphnia testing should be done BaHgainforassur"ance in our PoEnD.a Testing: Algae and Daphnia. 24- 000838 12. FC-206CE Degradability: BOD, BOD, BOD, cop BOD,/COD ratio Total Organic Carbon (TOC) OECD Method 301E Tosi: 46 g/L (PED) 260 g/L (PED) 470 g/L (PED) 402 g/L (PED) . 1.2 (PED) 130 g/L (PED) 89-92% biodegradability in 14 days (PED) Algae (Selenastrum capricornutum) 95-r ICs OECD Activated Sludge Respiration Inhibition Test 209 Water Flea (Daphnia magna) 48-hr Static LCs Microtox (Photobacterium phosphoreum) Exposure: 5 min. 15 min. 30min Killfish (Fundulus heteroclitus) 96-hr Continuous Flow LCs Fathead Minnow (Pimephales promelas) 96-hr Continuous Flow LCs, 96-hrStatic LCs >1,000 mg/L (PED) none at 1,000 mg/L >1,000 mg/L (PED) Cy, 650 mg/L 4500 mg/L. 4200 mg/L 2,000 mg/L (PED) 2,000 mg/L (PED) >1,000 mg/L (PED) EnvironmentalAssessment: . - The environmental effects data for FC-203CE is fairly complete. `Again, the PED" data showsi low toxicitoy to Daphnia which shouldbeverified. `Algae and Daphnia. _25- 000839 13. FC-203CF EnNvoirenovnimreonntmeanltAaslseefsfsecmtesndta:ta for this product are available and a complete set of environmental effects data should be obtained. a " ional Testing: BOD, COD, algae, Daphnia, fish, and Microtox. 14. FC-206CF EnNvoiernovnimreonntmaenltAaslseefsfsemctesndta:ta for this product are available and a complete set of environmental effects data should be obtained. A 0 gional Testing: BOD, COD, algae, Daphnia, fish, and Microtox. - 15. 14640 (New Foamer) Testing is currently underway for a European PMN by NOTOX Laboratories: 1. Daphnia toxicity study (C2 EEC test method). 2. Fish toxicity (C1 method) using Zebra fish (Brachydanio rerio). 3. Modified Sturm test (C5) for ready biodegradability. All testing for the European PMN is being done by GLP. `The following environmental effects data are from several 3M technical reports which are compiled in the report "Environmental Data and Information in Support of the PMN for Certain-Chemical Substances Designated as L-4640", June 20, 1880. i D ge BOD, <0.038 g/g BOD, <0.0380/g BOD, <0.0389/g cop 0.41g/g - Tos`iT,heoretical Oxygen Demand 0.75g/g Acute Effect on Microbial Respiration Water Flea (Daphnia magna) 48-hr Static Cy Fathead Minnow (Pimephales promelas) 96-hr Static LCs, 8% reduction in rate of oxygen depletion at 1,000 mg/L 100 mg/L and 111 mg/L 158 mg/L and 166 mg/L 26 000840 Envi Assessment; Because of the importance of this material to future products, a full set of environmental effects data is needed. The environmental effects data not included in the PMN work or in the previous studies should be obtained: algae and Microtox. BAlgeaecanod Mmicmroteoxf.nordAddaititonialToestninsg: 16. Witcolate 7093 (RM 45666) CAS#73665-23-2 Witco Corporation (713-433-7281) has no ecotox information available. Witcolate 7093 is 55% water, 45% C6-C10 ethoxylated sulfate. They recommended Swisher for biodegradation information. Ld No information on EPA AQUIRE database nor in Verschueren. EnNvoirefofnemctesndtaatlaAsissaevsasilmaebnlet.:Testing depends on the likelihood that this material will be used Bin future products. yonal Testing: COD, BOD, algae, fish, Daphnia, and Microtox. 17. Triethanolamine CAS#102-71-6 Degradability* ThOD BOD, BOD,, BOD, BOD, 2049/9 nil 0.02 g/g with standard seed 0.17 g/g adapted sewage 0.039/g 0.029/g nil with std. diluted sewage 0.059/g 0.13g/g 31 All degradability data are from Verschueren p 1150-1. 27-4 000841 cop BOD,COD ToryBOD ,/COD Bacteria (Pseudomonas putida) Popul. Growth Inhib. Algae (Microcystis aeruginosa) Popul. Growth Inhib. Green Alga (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib. 8-day Static Popul. Growth Inhib. 8-day Static Popul. Growth Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. Protozoa (Entosiphon sulcatum) 72-hr Static Population Growth Protozoa (Chilomonas paramecium) . 48hr Renewal Popul. Growth inhib. Protozoa (Uronema parducz) Bacteria (Pseudomonas) LC, Algae (Scenedesmus) "LC, Algae (Colpoda) LC, Water Flea (Daphnia) LC, 24-hr Static LC4, Brine Shrimp (Artemia salina) 24: Static LCs 1.50 gig nil10 0.11 0.09 >10,000 mg/L. (Verschueren p 1151) 47 mg/L (Verschueren p 1151) 1.8 mg/L (AQUIRE 2; 1980) 1.8 mg/L (AQUIRE 2; 1978) 715 mg/L (AQUIRE 2; 1978) 19 mg/L and 47 mg/L (AQUIRE 2; 1978) 56 mg/L (AQUIRE 2; 1980) 1,768 mg/L (AQUIRE 4; 1980) >10,000 mg/L. (Verschueren p 1151) 10,000 mg/L (Verschueren p 1151) 100 mg/L' (Verschueren p 1151) 160 mg/L (Verschueren p 1151) 2,500 mg/L (Verschuaren p 1151) 1,390 mg/L (AQUIRE 2; 1977) 5,600 mg/L (AQUIRE 2; 1974) - 32 The toxicity database. data are a partial listing of the 16 tests on 10 species given in the AQUIRE 33 This value is from a different reference than the previous one. 28. 000842 Goldfish (Carassius auratus) 24-hr Static LCs, 5,000 mg/L (AQUIRE 2; 1979) 24-hr LC, (85% TEA) Environmental Assessment 75,000 mg/L atpH 7 3,500 mg/L at pH 10.3 (Verschueren p 1151) This material shows insignificant toxicity to Daphnia and fish. However, it has a low BOD/COD ratio and will contribute to a low ratio in the product. In addition, it shows considerable toxicity to algae. For these reasons, it would be best not to use this material in products unless no alternative can be found or its concentration in the product will be extremely low. The literature data is essentially complete for this material. Any testing on this material must be reported to .US EPA undreerdspecetoinonblToSyCA 8(d). None. 18. Urea CAS#57-13-6 Degradability:TM Degrades abiotically: H,NCONH, + H,0 > CO, + NH, Degradation rate at 20C Degradation rate at 2'C Concentration in domestic sewage Toxicity: Bacteria (Pseudomonas putida) Popul. Growth Inhib. Green Algae (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib. 8-day Static Popul. Growth Inhib. 10.9 mg/Lhr 3.3 mg/h 2to6 mg >10,000 mg/L (Verschueren p 1178) 10,000 mg/L (AQUIRE 2; 1980) 10,000 mg/L (AQUIRE 2; 1978) 34 All degradability data are from Verschueren p 1178-9. 35 The toxicity data are a partial listing of 32 tests on 17 species from the EPA AQUIRE database. 29. ' 000843 Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. 47 mg/L (AQUIRE 2; 1978) Protozoa (Entosiphon sulcatum) 29 mg/L (AQUIRE 2; 1980) 72-hr Static Popul. Growth Inhib. Protozoa (Chilomonas paramecium) 48-hr Popul. Growth Inhib. 2,683 mg/L (AQUIRE 4; 1980) Water Flea (Daphnia) 24-hr Static LCy, 10,000 mg/L (AQUIRE 2; 1977) Creek Chub (Semotilus atromaculatus) 24-hr LC, 24-hr Cy 16,000 mg/L (AQUIRE 2; 1952) 30,000 mg/L (AQUIRE 2; 1952) EnLivtierroatnumreendtaatlaAisnsdiecsastemsetnhta;t this material shows insignificant toxicity to Daphnia, fish, and green algae. the product. Furthermore, it degrades readily and it most likely would not be a problem in sHhoowuelvderb,e ivtedriofeisedsbhyoowutroxoiwcintytteostbsliutei-tgisreteonbaelguasee,dainndthteheprloodwutcotxiactithyitgoh gcroneceenntarlagtaieons. ional Testing: None. 19. Triton X-305 CAS# 9002-93-1 (PRISM ~composition of the shows Triton X-305 to be remaining 30% not given). 70% this material with the Synonyms: Poly(oxy-1,2-ethanediyl), alpha-[4-(1,1,3,3-tetramethylbutyl)pheny]- `omega-hydroxy-polyethylene Octoxinol glycol p-1,1,3,3-tetramethylbutylphenyl ether P-tert-octylphenoxypolyethoxyathanol - VendorR:ohm & Haas Company 36 Independence Mall West, Philadelphia, PA 19105. Phone: 215-592-3000. -30- 000844 Toxicity." Bluegi2l4l-h(rLeSptaotmiicsLmCa,crochirus) 3.5 mg/L (AQUIRE 1; 1975) 24-hr Static LC,, 24-hr Static LC, 16.2 mg/L (AQUIRE 1; 1975) 1,080 mg/L (AQUIRE 1; 1975) 24-hr Flow-through LC, 96-hr Static Cy 21.08.0mgm/gL/L((AAQQUUIIRREE1;2;1917957)5) 96-hr Static LCqo 96-hr Static LCq 12.0mg/L (AQUIRE 1; 1975) 531 mg/L (AQUIRE 1; 1975) 96-hr Flow-through LC, 6-day Flow-through LCs, 10.0mg/L (AQUIRE 2; 1975) 9.6 mg/L (AQUIRE 2; 1975) The reason Static LCs, for the high values (531 mg/L)are not for the 24-hr known. Static LC , (1,080 mg/L) and for the 86-hr TbihoedevgernaddaobrilfiotryTroiftTorniXto-n30X-53(05R.ohHmowaenvderH,aatshe)yhaarsensoenddaitnagoan dtahteaasqhueaetitcotnoxtihceityaqouratic tboexliiceivtye otfhaTtritthoentXo-xi1c0i0t.y oTfriXt-on30X5-1is00lehssasthaanloXw-e1r0m0olbeeccualuasreweXi-g3h0t5tihsalnesXs-s3u0r5faacnedatchteivye. Triton Triton X-305 is not product line believed to Union to degrade biologically. Rohm Carbide (1-800-752-1827) and and will Haas has recently be transferring the sold their business `iTnhtehefonleloawrinfugtduraet.aTihs efrCoAmSAQnUuImRbeErognivtheins by Rohm and CAS number. Haas for the series is 9036-195. CAS #9036195 Toxicity:TM Rainbow Trout (Salmo gairdner) 48hr Static LC, 96-hr Static LCqo 7.2 mg/L (AQUIRE 2; 1978) 7.2 mg/L (AQUIRE 2; 1978) Marine Polychaete Worm 48-hr Static LCq (Scolelepis fuliginosa) 17.0 mg/L (avg. of 7 points) 96-hr Static LC, 13.7 mg/L (avg. of 8 points) - (AQUIRE 2; 1978) 37 The toxicity database. data are a partial listing of 13 tests on 5 species from the EPA AQUIRE 38 The toxicity database. data are a partial listing of 36 tests on 5 species from the EPA AQUIRE 31. 000845 Marine Polychaste Worm (Capitella capitata) 48-hr Static LC, 96-hr Static LC, 8.2 mg/L (avg. of 6 points) 6.0 mg/L (avg. of 8 points) Aquatic Sowbug (Idotea balthica) (AQUIRE 2; 1978) 48-hr Renewal LC, 96-hr Renewal LCq 10.0 mg/L (AQUIRE 3; 1972) 5.0 mg/L (AQUIRE 3; 1972) EnBovtihroCnAmSenntuamlAbesrsseshsamveenat:limited amount of toxicity data available which shows moderate ctooxmicpiltey.teSisnecteofTrdiattona oX-n3t0h5isismaatemraijaolrincoormdpeorniennotrdoferthteo cCoErreplraotdeuctthse,ewffeecwtisl.lonfetehde aCE products to their formulation. BOD, COD, algae, Daphnia, ish, and Microtox. - 82 000846