Document kadL8JdLRE46yDVRa7LOR2RQy
UTMU&HCOiaOl E. I. d u Po n t d e Ne mo u r s & Co mp a n y
Wil min g t o n , De l aw a r e 19898
CHEMICALS AND PIGMENTS DEPARTMENT JACKSON LABORATORY
July 12. 1983
B. S. WEIS C&P B-17202
1984 TECHNOLOGY SUMMARY
Attached is the draft of the Colored Pigment Summary. This is very similar in content to the previous summary, with changes reflecting CR&DD's changed format, as well as new information on R&D programs. The Business Center has reviewed the write-up.
A note of explantion on the data presented in Table I. The R&D expense for 1979. 80 and 81 includes actual IEB expense plus ~36% of the MTE expense for those years. The 36% figure is an estimate of programs that could have been classified MDV; 1982 numbers are actual expense.
Manpower this year includes all allocations. The big Change in manpower in 1981 reflects a jump in allocated manpower from 5 in 1980 to 13 in 1981.
I feel that use of total manpower distorts the manpower trends picture, but that's the way CR&DD wants it.
PAW/jrag 0300G
4
P. A. WRIEDE
Business Mission - Harvest
Manage quinacridone in a strengthen node and Krolor in a sustain mode, while managing remaining products in a harvest mode. Improve cash flow by reducing costs and maintain an assured supply of quality pigment to F&FP.
Role of Technology
Superior quinacridone process and product technology is the key factor in maintaining Du Pont's competitive leadership in quinacridones. The quinacridone segment is Du Pont's strength in Colored Pigments.
Evaluation
Technology Position
Opposite Competition
1983
198?
1993
Summary
Product
Quinacridones
+
+
+ Superior products
for automotive finishes
and plastics.
Inorganics 0 0 0 Conventional inorganics competitive in all
areas. Krolor - superior for plastics
applications.
Copper Phthalocyanine 0
0 0 CPC blues are generally equal to competition.
Other Organics 0
0 0 Competitive products for ink and consumer paints, but product line is narrower than
competition's.
Process
0 0 0 Low cost producer of quinacridone crude. Some copper phthalocyanine and other
organic processes are not cost competitive.
'fil
DU P050146136
Patent Position
Du Pont's current competitive advantage in the quinacridone business is a direct result of past strong patent position on process and product technology.
Critical quinacridone patents on crude synthesis and solid solution products have expired in the last several years, allowing competition, especially Bayer, to introduce products that had been unique to Du Pont. Patent protection continues through the late 1980's on important treating agents and quinacridone gold products. No strong patent protection exists for other product lines with the exception of silica coated lead chromates (Krolor) where product and process patent protection exists through the mid-80's. Competition is marketing Krolor-type products, which we feel infringe our basic patents.
Key Technologies
Quinacridone
p
o
nS
0, g H 0)
r4
to 0 to >1 + 0) a C CO H 0 Pt to 44
33 CQ a Q
P to
A O O
0 K
crude synthesis Finishing Technology Product Properties
HI M HO H A A A A HO H
DUP050146137
Competitive Technical Activity
State of the Art
Research in Colored Pigments at Du Pont and major competition is generally aimed at modifying and improving existing products to meet the performance needs of changing end-use industries. European pigments manufacturers have also been successful in research aimed at developing completely new pigment chemical types (as judged by patent activity) especially in the yellow, orange, red color areas. Du Pont currently does not have a major technical
effort aimed at new pigment development.
Major Activity
Du Pont Assessment
s Bayer has developed a production unit (Bushey Park, S.C.) utilizing Du Pont guinacridone synthesis technology to produce unique red products.
e Du Pont production scale should continue to yield better economics.
Bayer and Sun are actively developing quinacridone solid solution products which had previously
been unique to Du Pont.
e Du Pont technical expertise in quinacridone product development and
strong ties with Fabrics & Finishes Department will
maintain our lead in new product development.
Conclusion
Du Pont Vs strength in Colored Pigments resides in the quinacri done segment of the business. Our large scale production facility based on intermediate synthesis of dihydroquinacridone and our backward integration to dimethylsuccinate (a Petrochemicals Department by-product) combine to make us the low cost producer of crude quinacridone. The requirement for high temperature operation and sophisticated solvent recovery make it difficult for competitors to duplicate our economics without significant investment. Bayer has installed a production facility based on our technology to produce products formerly unique to Du Pont.
Improved product introductions are key to maintaining a competitive advantage. Our technical expertise in quinacridone product development and our close ties to the critical automotive industry through Fabrics & Finishes Department should allow us to continue our product superiority.
DUP050146138
Du Pont is generally equal to competition in product technology in nonquinacridone segments of the business. However, our multiplant configuration and low capacity utilization result in process cost disadvantages in these segments vs. competition. Research Strategy and Programs (19821
Research emphasis will be placed on maintenance of our quinacridone competitive position through improved product development to respond to new automotive finishes technology and to expand quinacridone penetration into high value plastics markets. Development of improved products in nonquinacridone business segments will be minimized over the next several years.
Manufacturing technical programs are aimed at upgrading existing product technology to improve operating reliability and product quality and reproducibility. Success in these programs will allow future operation of the Colored Pigments business in a more cost effective manner to improve profitability and competitive position.
DUP050146139
Kev Issues
Can we be successful in process improvement program to achieve cost reduction goals of Colored Pigments business?
e Hill we successfully maintain our quinacridone competitive position through new product development programs?
Summary Data
1983 (F) HP $MM
R&D
15
2.9
MT 9 1.6
Total
24
4.5
1984 (FI MP &MM
14 2.7
8 1.4
22 4.1
R&D % S+T
Total % S+T
2.5
2.1 3.2
eo
(*>
Cost Reduction
Existing Process New Process
Capacity
Existing Product improvement
New Product
Regulations
Research Objectives (%)
1982 (A)
1983 IF!
1984 (FI
17 29 34
-- -
72 71 66 11 -
--
PAW/jrag 03006
DUP050146140
p
p> rt
H 9 tt
C <H rt O
p
rH
co H M
Pp
P
p Pi
0 0. O'
Or
p a <g
41 8
ao ap u
ac a ft *
ns aS
rt
X p o >n
rH O' CO a ch
Of
ft p a ft rt
p ft** P
p p
JQ P
P
XJ rH
rH <W
3 PO
o
P <P
3 ao
oa
<p
"POP o
ppP
Po
O
ft p
H
tt 00 P
o
tt CO P
>
JO cc P rH p
XS co p
H
rH O' JQ P o
rH O' .0
p
rH "rH
V ft
rH -fH
p
XS
1
in
p^
p PH
X ip in p
a
t* co p O tt
OOP
p
o> o
Po
o a> o
t-t
rH rH O Hi 01
CO rH u
XI o mn
N
oiinn
pa o <v ft. a -O p o Po p' O. P a ft u ON pO
P p <U tt aO oa V P tt
oa iH p GO p ft Oi to a M pP X) d 0i rl o a
P s u p tt * 3 rH
os * ' rH O' > H rH -rH tt
ttl OU rH
o N01
E xpenditures E xpenditures
1984
SI o in CM H
O*
rt
OO rt
OB 00
1983
o w CO tt* N <*
0
oU
O
to 0
ft: rt p P
0pp
pa 1 o O' P 8Pa i
P O* tt i P
fttt
1 X3 P P P P .rH ft
oa>
ft
voo
p
S iH wp
Oa'
rH *0 ft rO <0 o O
1 tt
P <o 3 to ft
O O' 0 P 01 0 tt 01
tt P o O P P
P 0 V tt p
^ e p a 14 tt P rH p
3 Pi tt
p 3 P <H rH O 0
rH 01 P
a p 0 >i o > 0 O tt iH O 01 >1 tt tt 0 O
rat
o
uv tt
a
x
a rt 0 > b ft
- * i-t o a p
0Oi TJ r-t >
>O
P eO
PO eo
P
Oa xs
tt
pe
o ft
P
a. 8
P O P <o o q o *p p s o
C <P
pOi PO
>
a
pVHWPb fPat
> -H i-i O
rH *P0
O P
P V
Pi-H rt
>
Q
oP
Pi O eca
Pi rt ft to
A
p(0.
o no
g to
Oft 13 <P
>
ih
o
*ph
eit j Q pp
aa
O CH tt to
U a-rt
ft e o
Pi O O tt rH O
8 O <P P
HpUDWOOl
p
3o
Pi
0
teo
tt
p o
P
O O
PH
Pa
a, *
DUP050146141
#os wj
r0*0
H&
\0o0 tmr* oHn
in 00
0rHi
G*O* 0H1
r> 00
0rH1
osi i-i
(M CO
p0V rlr
a
to
O(N <Hf ONl 0VoO1 0r-Vl
N
Or-l CHM
0> (M
CM O CM CO 10 CM Ot VO rH CM
rH O 00 CD CM en 01 10 rH *
o10 a10
OCtHoO 0(N>
00 r0v
Ut 00
in
Hm
O oo 00
iHn oiornS oo m go
tn
*H*
O 0
rm* H
o 10 10 N H
10 rH M1 N rH CM
oH oN CNM i<0nW0 oN
5oM
W
M o
Q u8 05
ss M
u o 2
10 fO l vo l I
PJ I VVOO I I
#
tn
VO I VO I
I
+ n
I VVOO I
I
CaMt i r~ i
I NC-> rH-l
I
t0oV
I
toov
r~ C4,
I
r tino
rCO rol I
rirno
OCO Vr4O I
H
4 a
0 nw
44
0
9o
X
sft
-a
a0
> U 44
C 01
a 0e
tg
a X
0X
ww
to 0 05
r*v H
'
a
0 >r
u
o
9
o
a
aft
0
a 0 a 4->
43 C Pi 006 0 Oi 0
H WX WX
W <M a
H
* c 0 wj-
M
0
_9
ao
ft
a
nM
0a
43
wG
44
U 8 ft
008
H
ft
X
0
X
WWW
0)
rH
<D
to
w 0 > H 44 O 0 -r43 O
Q a
44 0
c o *H 44 P 43 rl *4 44 O H
Q
a m
0
o
O
uw
C5 04 w
O0
h e> O
44 C O O 1-1 M
P 44 0
o w
X0 *X
9
0
W2
44
W1 1
o
u
44
a
0 8 0
> o M Oi 6 1-4
44 O P 0) o M
ft
4s4
Cv c
rl rl
<4 44
0W
ft rl
0M
oU
tfl 44 O P O o 44 ft
9a
2
R egulation**
DUP050146142