Document kVeovqYJLvYEmKqyY4xL0rjE
PYRANOLTM COMPOSITIONS
* GE Specification - 1488, 1467, 1470, A13B3B. (1497 = A13B3B), A50P5.. # ASTM 0 2283 Type (_), Annual Book of Standards, Vol . 10.03. 1242, 1254, 1260 - AroclorTM PCB mixtures - Monsanto Chemical T3 4CB - tri- & tetra-ch1orobenzenes - Hooker Chemical Sn44 - tin tetraphenyl - Hooker Chemica1(1944-1957),
Metal 4 Thermite Corp EDDC - epoxide dicyclo-dlepoxy carboxylate - ERL 4221, Union Carbide 4
CY-179, Ciba-Geigy
PITTSFIELD. MA
1932-NOV 1944 1 488*
60S 1260 40% T3C8
NOV 1944-APR 1952 1467
60% 1260 40% T3CB 0.125% Sn<*4
APR 1952-MAR 1963 1 470
45% 1260 40% T3CB 15% T4CB 0.125% Sn*4
MAR 1963-APR 1972 A13B3B (3)# 45% 1260
40% T3CB 15% T4CB 0.125% EDDC
APR 1972-NQV 1973 A13B382 (FI 45% 1254 40% T3CB 15% T4CB 0.125% EDOC
NOV 1973-FE3 1974 A50P559
65% 1254 23% T3CB 12% T4CB 0 .125% EDDC
JAN 1974-END A13B3B3 (G) 60% 1254
40% T3C3 0.125% EDDC
1953 - 1963 1470
45% 1260 40% T3C8 15% T3CB 0.125% Sn*4
1970 - 1972 A50P559 65% 1254 23% T3CB 12% T3C8
0.125% EDDC
ROME. GA
1963 - 1965 A13B3B (B1 45% 1260 40% T3CB 15% T4CB 0.125% EDDC
1965 - 1970 A50P524 (Cl
80% 1242 13% T3C8
7% T4CB ' 0.125% EDDC
1972 - 1974 A13B3B2 (FI
45% 1254 40% T3C8 15% T4C8 0.125% EDDC
NOV 1973 -- FEB 1974 A50P559 65% 1254 23% T3CB 12% T4C8
0.125% EDDC
SEP 1969 - OCT 1970 A13B3B (B1
45% 1260 40% T3CB 15% T4CB ' 0.125% EDDC
MAR 1974-END A50P570
40% 1254 60% T3CB 0.125% EDDC
HICKORY, NC 4 SHREVEPORT. LA Pyranol - never used
/3800B
tor 12-29-87
(JLil* 000654
WATER PCB-00048190
Designation: D 2233 - 88
Standard Specification for CHLORINATED AROMATIC HYDROCARBONS (ASKARELS) FOR CAPACITORS'
-Jtid b bunt undo tbf (tin) designation h 1)11. the aninbet ttnmtrlirtely fottowtng the ilesi^nillotl Indicates tW 'ipioet #dojnioo 01, In the c*.e of rcuiiion. the yea, of leaf reitiioo A numbci in paicnlhcses indnates the jeer of H*
I hu specification rovers synthetic nontihle electiical insulating liquids of the nsted aromatic hydrocarbon type known katcls, which arc used as an electrical iling and crxding medium in capacitors, rpecificalion includes liquids that were imsly available and are still in use in istus ' Inurlalion systems incorporating these ,els and celluhtsic or other otganic matemay, when arced, produce gaseous mixt that are moderately flammable. I Ask arcLs covered by this specification are
nr types as follows. 1 I Type A Biphenyl that has been chlo-
ird to a content rtf 42 weight %. I 1 Typt B Biphenyl that has been chloUed to a chlorine content of 54 weight %. ) 1 Type C- A mixture of approximately
3> type 1)2213 B and 25 % trichlorobenr.
(14 1'ypr /)--I he same as Type A, exce|H >l lire higher boiling homologs have been re ived to a maximum level of 0.4 %.
Nrn* I--These statements arc merely descriptions
ihe materials currently in common use and are not
r ruled as pa/I of this rprcifiralion, which is Iwsrtl on
physical and chemical properties prescrilied in fa-
I
Nor* 2 Current governmental regulations pro
's! Ihe manufacture and sak of polychlorinated W-
'cnyh (sslarcHI I his method is being maintained for
tornce ol those uni'
-e si>11 in service.
It nf 3 - I or inhu
jn IX. It's in mineral oils.
088 Test Method for .Saybolt Viscosity1
1)92 Test Method for flash and Fire Poinb
by Cleveland Open Cup1
D97 Test Method for Pour Point of Petroktm
Oils'
0664 Test Method for Neutralization Nunr
ber by Potentiometric Titration'
0 877 lest Method for Dielectric Breakdow*
Voltage of Insulating Liquids Using l)edl Tlertrodcs'
12 923 Methods of Sampling Electrical InstiUf
ing 1 squids' 0924 Test Methrxl for A-C Ixess Charactei*
lies and Relative Permittivity (Diekctrir
Constant) of Flexlriral Insulating liquid**
0 974 I est Method for Neutralization Numbo by Color lndicator Titration'
01169 Test Method for Specific Resistant* (Resistivity)of Electiical Insulating liriukk'
DI218 Test Method for Refractive Index itJ Rcfraclive Dispersion of I lydrocarlron lit) uidd
DI533 Test Methods for Water in Insulstiq I iquids (Karl Fischer Reaction Method)'
01810 l est Method for Specific Gravity J | Askarels'
01820 Test Mcthorl for Hydrolyzable CW rine Compounds in Chlorinated Aromatic |
llydtocatlxrns (Askazcls)1 01821 Test Method fgr Inorganic ChlofirJt! |
in Askarels'
11 hh tprcifn^lkkn W ymlet the jviixfklion of A*Tf M C
miller l> J / on f kdiHal |rnul*M#f I iqukfa */xJ
8*4i
iKr flirrt l mfon5ihiTil)r of
1)2 T 01 on
.......nmt Im II. f9A6 Pub<KhJ MW
.I
D 2233
Ohr uumoj
01903 T est Method for Coefficient of Thetmal Fxpansion of Electiical Insulating Liq ride with lesser amounts of combuslible gases.
uids of Petroleum Origin, and Askarels' 01936 T est Method for Thermal Stability of
Chlorinated Aromatic I lydrocatbons (Askarels)'
4. Octal! Requirements
4.1 Askarels for use in capacitors shall con form lo Ihe requiiements prescribed in Table I.
02129 T esl Method for Color of Chlorinated
Aromatic Hydrocarbons (Askarels)' D4059 Methcd Tor Analysis of Polychlorin
Not* 4--Since October 1971 askarel produced in the United Stiles for use in capacitors has conformed
lo Type D as ihown in Table I. Materials previously available are still in use In the field.
ated Biphenyls in Insulating Liquids by Gits Chromatography'
3. Definition 3.1 nskarrl--a generic Irrm for a group of
Not* 5--These materials sometimes contain addi tives whose presence may interfere with Ihe chemical
tests prescribed In Table I. Unless it is known that no additives are present, results of Ihe chemical tests may he misleading.
synthetic, firc-rtsislanl, chlorinated aromatic hy 5. Sam|*lhf and Teat Methods
drocarbons used as electrical insulating liquids. They have a property under arcing conditions
such that any gases produced will consist pre dominantly of noncombuslihle hydrogen chlo-
5.1 The material shall be sampled In accord
ance with Melhodj O 923 and tests shall be conducted in accordance with the methods of test listed In Table i.
TV American Soclrlyfor Trifbtf a*2 W(V(fWl toket M prirtwr re^*ecf*rg (V wSAy rf wry pans rtylll osorrteJ Sr
(wwrrtwl Nrtll any Ifna wnalnv2ii (Mi rlmuiord Vent of (Ml tiarrAaeJ Or e nprnty a2rtrr7(ka Jelerrnburtlon of IV pJlAry 4 my mt /rolml rlghll, onj the riih of hfrtngrotm/ of rock rlgklr. arc rrretrotjr their own rryKr(l(%.
IV, ttmrjarj b rohfeet lo rrrlrlewt ol wry (hr, hr the myMjttt, trchmlcol committee ni mrut be rrrtrrccd erery fee frori
nil ro, rrriled either rmforored or aSldrer rare rwtrmna, me kirkrd eitherfor rrrlrioer of (Xli ttaroiarj or for mdJUionei
kreeomdt onj thoteld hr oJoreteedlo ASTki HroJfoorlm Toler foffwKwfJ tHR nrortr#
nMiUrrartim #f
tJ tK*
lUfvnjJbl* frrAnfcW fwnwi/ttf*. wAJch ppm mop otitnd. tfppmfkrl thot ^rr rtmnMtKi IUh mrt rvc^vtVf/a^ Ktorkngppn thoml4
wmkt porn
known to thp A5TA4 CtwJflff m 5/iwAnA' )9)4 flwco St., tkMmdrlpAkm, to, tP/Of.
WATER_PCB-00048191
ijft) D 2233
Doalgnatlorr: O 2283 - 88
GCP 000656
Standard Specification for
CHLORINATED AROMATIC HYDROCARBONS (ASKARELS) FOR TRANSFORMERS'
Tim NirwUrd w hsaxt) under the died dni|ruilioe D 221); the Hynttet itmntdiitdjf foAow|n| the (M|nalion Indinks the ycir of rifirurf tdofrikm of, in the ewe of nWon, the yew of Iasi rrrWon. A vmbtr in partnlhocf Indicifa the year of last rtsfprtnni. A. aopeiicitpt epsilon {) JrxJkftrr n editodal chanft tirxe (he hkft revkion ot reap)KOal.
I. Scop*
1.1 This specification coven synthetic non flammable electrical insulating liquids of the chlorinated aromatic hydrocarbon-type known is askarets, which are used as an insulating and cooling medium in liquid-filled transformers. This specification includes liquids that were previously available and are still in use in ipparitus.
1.2 Askarels covered by this specification are of various types, having components in weight percent in accordance with Table I.
Nor* I--The components and the respective per-
cralage* given ate descriptive of the materials cur-
Itally In common use and are not Intended as part of
tfcts specification, which is based on physical and
tbcmtctl properties.
'
Nor* I- types A through f) are PCB type aa-
tareti previously available and still In use tn the field,
kecently Type It, a non PCB askaiel. was introduced
Ml retrofit and replacement.
Nora 1 -- Current governmental regulations pro
Whit the manufseture and sale of polychlorinated
Wphenyla (PC'Bi) llili method serves as a reference
fct alt askarets, PCB and non-PCB.
I Applicable Documents
2.1 ASl'M Standards:
D8 Test Method for Sayboll Viscosity'
D92 Test Method for Hash and fire Points by
Cleveland Open Cup1
D97 Tesl Method Tor Pour Point of Petroleum
Oil,'
D445 Test Method for Kinematic Viscosity of
Transparent -nd Ojxacpie l.iiguids (and Hie
Calculatin'
nainic Viu osily)'
flhCi test K'.
f...
.li, -1i -- M.......
her by Potentiometric Titration'
' D877 Test Method for Dielectric breakdown
Voltage of Insulating Liquids Using Disk
Electrodes'
D923 Melhotls of Sampling Electrical Insulaf-
ing l iquids'
D924 Lest Method for A-C l.oss Characteriv
tics and Relative Permittivity (Dielectric
Constant) of Electrical Insulating liquids'
D974 Test Method for Neutralization Num
ber by Color-Indicator Titration'
DII69 Test Method for Specific Resistance
(Resislivity)of F.lectrical Insulating Liquids'
DI2I8 l est Method Tor Refractive Index and
Refractive Dispersion of llydnxarbon liq
uids'
DI5J3 Test Method for Water in Insulating
liquids (Karl Fischer Reaction Method)'
D 1701 l est Method for Scavenger Content of
Askarels*
Dl 810 Test Method for Specific Gravity of
Askarels'
DI82I Test Method for Inorganic Chlorides
in Askarels1
.
DI903 Test Method Tor Coefficient of Ther
mal Expansion of Electrical Insulating liq
uids of Petroleum Origin, ami Askarels*
D2I29 Test Method for Color of Chlorinated
Aromatic Hydrocarbons (Askarels)1
* I Irh lpMiflullon t* >wkr the )ufWkltoo of AS IM Com-
miller 1X2/ on FlrciricW Iiwillln| IIqqkfk and (ici and li ihc dirtcl rrtpomitrtlity of Saahcotnmlllee D) VO? on Synthetic*
Cntitl ttlilion afpfO'vtxt )n Tl, 1986 F'uMWtrd Mar 1916. Originally puMiahed mt l) 2JB3 - 64 t t M*t psohnrt lion l> 228J - 12 (198
WATER_
Wfj u 22B3
3. Dcflnlllcm
3 I fliAtffiV-- a generic Icrm for a group of synlhrlk. fire rcsislanl, chlorinated aromatic hy drocarbons used as electrical insulating liquids. They have a property under arcing conditions such that any gases produced will consist pre dominantly of noncomliustiblc hydrogen chlo ride with lesser amounts of cortthuslihle gases.
4. ISrtall Requirements 4 1 Aslrarels for use in transformers shall
conform to the requirements prescribed in Ta ble 2.
Nou 4 --If more convenient, a measurement of dissipation factor may he made by fell Method l) 924 in place of the resistivity measurement, Iheortliof considerations indicate and experiment confirms that I strong statistical correlation exists between the dissipa lion factor and resistivity. however, other factors mod ify in practice the precise relationship predicted by theory. A dissipation factor at 60 11/ and I0U*(' that ir not in excels of 15 % shall be considered satisfactory
3. Sampling ami l est Methods
5 1 The material shall Ire sampled in accord ance with Methods D923. and tests shall be conducted in accordance with the methods of lest listed in Table 2.
TABI.C I Ailxrdi C'wwfBxratl hi Weight Pmrat
C omponcnls
llesachlorobiphenyr f cniachiorohrphcnyr T licMoinbiphe ny|f Tikhlorobenrene" Tri let*a blend' The noaypropene otide'
fheposidc 1 ype compound '
Type A 60
40 0 14 to
0 12
Type 45
55
0 115 to 0 111
Type C
80 70
0115 10 0 1)5
TypeD
70 30 0 18 to
022
Type E
100
0 18 to 0 22
TypeF 45
55
0115 to 0 1)3
J |1i|vKrny| < hlnrinxlrdto a rhkwirvc conlrntiff 60 werfhl %
* P'l^Kn^ vhlsMinstrsllo chknir* (onlcnl o( 54
\)
1 (l<f*bnyt <hk^ioiledlo a chkxine content of 42 weight %
* A mialuic of itomm of Irkhloeobe nrrne
* A miaiuif of itOKKfi of lfi(hlorob<nrtn< and lelf achforobenrene.
r(Myc%dy| pStnjiltlSii
3.4 r poaycydohtsytmelhyl 5,4 tjx>*ycytk>be*an carboaylate.
*Hwi l*< 8 contains no chlorinated biphenyl*
Type O Type If
60 40
100
O il) to 0 1)3
0 tore 0 23
il' 000657
t||t) D 2203
Tiopefty
1 ADI F 2 DrtiN Rr^rlftmealifot A' hatch foe f r inline met a Type A Type B Typet Type 1) Type f Type T Type <i
Type It'
At) 1 >''
1<*I
Mcltioi1
Acidity, mg KOll/g. mu 0 014
inn
0014
0 014
0014
0014
0 014
0014
Color APIlA mac
IV)
Condition
dear
Chlorides, inorganic, ppm 0 1
150 dear 01
150 dear 05
150 clear 01
150 dear 01
150 dear 01
150 clear 01
150 dear 01
max RHifive permittivity at
) 7 to 4 0 ) 8 lo 4 3 4 4 to 4 9 4 3 to 4 6 4 7 to 4 9 4 5 to 4 9 4 ) to 4 6 4 > to 4.1
I0OT and 1 h)l< Dkkctrk breakdown volt )5 15 )5 )3 )3 35 J5 )3
age min. h V Fite point'*
font point, mu. *( Rtfi active index. 25*C
nonelo nonelo none lo none to none to none In nonelo none lo boiling boiling boiling boiling boiling botling boiling boiling
32 44 >0 10 4 42 - 38 20
1 61)0 In 1 6068 14 1 6146 t< 1 616) lo 1 6240
1 6060 )i 1 6110 1<> I 5)60 to
1 6154
1 6088
1 AIM
1 619)
lo
1 6070
1 6120
1.3780
1 6260
gniiti.ity lOO'C. 5 V/ mil. d c* min. 0 cm 100 X 10' 100 x 10' 100 X to* 100 X 10' 100 X 10 100 x 10' 100 x 10' 100 X 10"
Scavenger content. 4: Fhenoaypropcne oode
PsepoMde type com pound
Specific gravity. 13 3/ )5 5`C
0 18 to 0 22
1 360 to 1 368
it 115 to 0 115
1 160 to 1 371
0 111 to 0 1)5
1 411 lo t 415
0 II lo 0 22
1 111 lo 1 528
0 18 to It 22
1 381 to 1.191
0 115 to 0 1)5
1 51) lo 1.511
0 115 lo 0 115
1 50110 1517
0 10 to 0 23
1 181 lo 1 192
Viscosity. Sayboll IJniver
sal. * at )) 8"C
potrn
52 lo 36
41 to 43
50 to 55
56 lo 61
82 to 92
19 to 4)
49 lo 48
11 to 4|
CocfTKirnl of thermal n pansion.* cm'/cm'*( 00007
Water content mat. ppm 30
7 0007 50
0 0007 10
00007 50
00007 K)
0 000) VI
0 0007 10
(7 007 W
[7 97<l
|) 66')
P 7W vi'Uat p mj P 97* p *77
0 91
l>97
pin
p ip D pn
P HU
l> *8
P |9t
pm
* When testing for Tire point. pseudo Hath may be observed: It differs noticeably from the flash obtained ft
cofabustibte miioiib and ti not Indicative of a fire harard * See Note 4 r Ihoe are approximate values included for Information only. * These drsi|nation rtfrv to the methods teferented in Section 2. * Hon P( l contains no chlorinated bipbenyh
rtf A meekan Sac iciyfor Tttllng
Wafrria/i faigf no position rr tprrtlng the *alldity of any potmi rights trile-
comer lion mith any iirm mentioned in this standard Users of !%l standardmr esprrstly tsdrlsed iXo# determination of the roll
if any such patent rights, and ihr rhk of Infringement of nr<h rights, art entirely their o*n responsibility.
nit standard Is tubfeeI to reilston ot any lime be the responsible tethnkaf committee and mutt bo terieu-ed terryfire .1. and f not reitseJ. either reappeared or withdrawn. Your comment! are Inrked eitherfor trillion of iMr standard 0* for esddttu Standards and should be addressed to A STM Hnirfpwlni tone comments will rrcWve rartful consideration at a meeting of rr^onslbte technical rommltter. which you may attend. Ifyoufed that four comments hair not received a fair hearing you sh< osake your 1lews knonn to the A5 TM Committee on Standards, 1916 Mare St., Philadelphia, pa. I9I0J.
WATER PCB-00048193
ASKARELTRADE NAMES
AROCIOR ASBES70L CLOPHEN CHLOREXTOL CHLORINOL CLORPHEN DIACLOR DK, INCLOR, FENCLOR DYKANOL ELEMEX EUCAREL HYVOL INERTEEN KANECHLOR N-3 . NO-FLAMOL PHENOCLOR PYDRAUL PYROCLOR PYRALENE PYRANOL --, SAF-T-KUHL SANTOTHERM THERMINOL
^Generic Name for PCB
SESO PROPRIETARY INFORMATION
MONSANTO CO. AMERICAN CORP, BAYER (GERMANY) ALLIS CHALMERS SPRAGUE JARD SANGAMO ELECT. CAFFARO (ITALY) CORNELL DUB I LIER MCGRAW EDISON
AEROVOX WESTINGHOUSE HOUSE MITSUBISHI (JAPAN) NIAGARA TRANSFORMER WAGNER ELECTRIC PRODELEC (FRANCE)
PRODELEC (FRMflCE) GENERAL ELECTRIC KUHUMAN ELECTRIC MITSUBISHI (JAPAN)
RDP/CE/040184 (3,
GCP 000658
WATER PCB-00048194