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FILE NAME: Warning Labels (WL) DATE: 1946 DOC#: WL012 DOCUMENT DESCRIPTION: MCA Guide for the Preparation of Warning Labels for Hazardous Chemicals STATE OF PEN N SYLVA N IA C I T Y O F P H I L A D E L P H I A , to wit: N O W C O M E S J A K E L A U G H L I N , who after being duly sworn, makes oath as follows: 1. I am a paralegal employed by the Locks Law Firm o f Philadelphia, Pennsylvania. 2. O n Novem ber 18, 2014 I traveled to the Othmer Library o f Chem ical History, located at 315 Chestnut Avenue, Philadelphia, Pennsylvania. 3. W hile at the library, I reproduced the following publications: Warning Labels, 1946, Pages 1-63 4. These digital images were captured from the original publications housed at the archival section o f the Othmer Library o f Chemical History. The original publications are the property o f the Othmer Library o f Chem ical History, and were returned to their custody following their reproduction. Each o f these documents is over 20 years old and were found at a library o f chemical history, where they would be expected to be maintained. I declare under penalty o f perjury under the laws o f the State o f Pennsylvania that the foregoing is true and correct. Executed this 19th day o f November, 2014. NOTARY: Subscribed and sworn to this 19th day ofN ovem b er, 2014, before me, the undersigned, a notary public in and for the C ity o f Philadelphia and State o f Pennsylvania, and as witnessed by my hand and official seal. /> M y commission expires the 20 Notary Signature and # COMMONWEALTH OF PENNSYLVANIA NOTARIAL SEAL INIECE D. GOSHA, Notary Public City of Philadelphia, Phila. County My Commission Expires June 14,2016  I * 48 Manual L -1 PART I M ANUAL L -l--A GUIDE FOR TH E PREPARATION OF WARNING LABEI-S FOR HAZARDOUS CHEMICALS Adopted 1945 Revised April 1946 The development o f new chemical products and the introduction of chemical processes into ever widening fields has accentuated the need for furnhhm g appropriate information in those casefl where special precautions are necessary Many chemicals present no hazards in normal handling and storage and for these products no precautionary labels are necessary The education o f employees regarding chemical hazards is, and must remain, the direct respon sibility of their employers. However, such hazards are not confined to employees alone, and infor mation concerning them should, so fa r as practicable, icach every person using, transporting, nr storing chemicals The most practical means for the seller to disseminate this information appear* to be by labelB affixed to containers of hazardous chemicals, bearing appropriate precautionary statements and instructions stated as simply and briefly as circumstances permit. In the interest of uniformity and more adequate labeling o f chemical products, the Manufac turing Chemists' Association has prepared this Manual for the benefit and guidance of its members. A senes of definitions is included in Schedule 1 In order that the terms used may be clearly under stood hi addition to the general recommendations contained herein, the M CA has prepared sug gested labels for specific products. These have been printed aa Manual I.-2, which will be supple mented from time to time as additional recommended labels are developed A precautionary label does not take the place o f safety equipment such as suitable goggles, airline respirators, gas masks, clothing, shoes, etc Individual statutes, regulations or ordinances may require that particular information be included on a label or that a specific label be affixed to a container In each case, the requirements of these laws should also be studied The warning labels suggested in tins Manual should be used in addition to, or m combination with, any label leqimert by law * * Federal statutes include Interstate Commerce Commission Regulations fo r Tw ispoi-taticn of Explosives and Ocher Dangerous A rticles Supt of Documente, G ovt Printing 0 trice, W ashington, D . C Federal Caustic Poison A ct and regulations. Food and B u g Adm lm stiaUon, Federal Sccuiity Agency, Washington, D C, Federal Insecticide A c t of 1910 and legulatlona A gricultural M arketing Administration, V S Department of Agriculture, Washington, D C Federal Food, D rug Bnd Cosmetic A ct and regulations' Food and D rug Administration, Federal Security Agency, W ashington, D . C. Related statutes of the 48 States and the D istrict of Columbia include Cuuatic A cid, Pharmacy, Poison, ond Insecticide A cts. AUG 1 51948. W CHEMISTS' CLUB ------------L lfifM W ---------- WARNING LABELS PART 1 A G U ID E FOR THE P R EP A RA TIO N OP W A R N IN G LABELS FOR H AZA RDO U S CHEMICALS PART 2 ILLUSTRATIVE W ARN IN G LABELS FOR H AZARDOUS C H E M IC A LS THEOTHMER LIBRARYOF CHEMICAL HISTORY CHEMICAL HERITAGE FOUNDATION a V IllS H IB IT M ANU FACTU RING CHEMISTS' A SSO C IA T IO N OP THE UNITED STATES 6 0 * W o o d w a r d B i d a - * W a s h i n g t o n 5 , D. C. C#yleM tees by Maw<cturt*s CHamMl' AiltdSfkfl 4f Mis UtUfaS Ite' .he Unii! PREPARATION OF PRECAUTIONARY LABELS Manual L 1 The basic considerations in the preparation of a precaulioiuty label for any chemical product (including mixtures) aie, 1) Determination of the hazards present in the particular chemical product 2) Selection of appropriate statements for each significant hazard inherent in the product. 3) Arrangement of statements in the order of emphasis desired The most frequently encountered hazards have been classified by the M CA into 10 types as listed m Schedule 2 Set opposite each class are statements illustrating characteristic precautions usually required for that type of hazard. Many chemical products will have more than one type o f hazard, m which case appropriate statements for each significant type should be included on the label Most chemical products con tain impurities When these are present in haimful quantities, appropriate warnings and precau tionary measures should be included on the labels A b each chemical product must be treated individually, there will be many instances in which the illustrative statements will not be applicable either because>they do not accurately express the degree of hazard or because they fail to cover the particular characteristics fn such cases, suitable statements should be selected from Schedule 3 This Schedule presents a more comprehensive list of statement arranged in columnar form and grouped aa follows* A Signal Word B Hazards C Precautionary Measures D Instructions m Case of Accident Column A-- The degree of hazard can be expressed only In relative terms The purpose is two-fold to indicate to the reader the comparative seriousness of the danger involved in handling a given product and to call attention to the precautionary instructions which should immediately follow The " signal words'' recommended are, in the order of dimin ishing severity of hazard, (1) D A N G E R , (2) W A R N IN G , (3) C A U T IO N Example: W AR N IN G ! Column B --From thi9 column should be selected the phrase (or phrases) that most accu rately describes the principal hazard This is placed on the same line as the "signal word " Example. W ARNING! FLAM M ABLE If other significant hazards are present, they should be tabulated under the principal hazard. Column C --The appropriate statement of " precautionary measures*' should be chosen fiom Column C and should follow on subsequent lines Example: W ARNING' FLAMM ABLE Keep away from heat and open flame. Keep container closed Use with adequate ventilation Avoid prolonged breathing of vapor Avoid prolonged or repeated contact with skin 3 Manual L 1 GENERAL PRINCIPLES In the preparation of any precautionaiy label the following principles should first be con sidered. 1) Each chemical product (including mixtures) presents a distinct problem and must be treated individually, m the light of its own characteristics 2) Extreme care should be exercised in the choice of terminology Statements should be brief and simple 8) On labels for different products, uniformity m language to indicate the same hazards ( is most desirable In order to gain greater understanding through standardization. 4) Precautionary statements must be accurate, selectively chosen, and expressed in clearly defined terms. To be effective they should be used only when and to the extent necessary Labeling o f a relatively harmless product so aa to indicate that it is hazard ous, as well as the failure to give adequate notice of a hazard, will develop a disregard for labels and defeat their purpose For example, if the word "P O ISO N " is to retain its usefulness on a label, it should be applied exclusively to those fffoducta (I) which are poisons according to a definite toxicity standard*, or (2) with which it is associated through common usage, or (3) for whtch its use is prescribed by law In all other cases the relative degree of the hazard can be better indicated by the use of signal words such as "D A N G E R " to cover extremely acnous hazards, " W ARNING'' to cover less serious hazards, and "CAU TIO N'' to cover minor hazards, together with a descriptive statement of the hazard 5) Chemical names should be those recommended by the American Chemical Society. 6) The use of a non-desenptivc code designation or trade name as the only identification v of a hazardous chemical should be avoided If for any reason, it is undesirable to ' show the chemical name, or i f the chemical name is so complex as to be meaningless except to the trained chemist, the label should state the type of chemical, e g , "eorpo- slvc acid," " lead compound " 7) The following subject matter should be considered for inclusion on a precautionary label: 1 Chemical name 2 "Signal word" (D A N G ER -W A R N IN G -CA U T IO N ) designating degree of hazard (Column A, Schedule 3) 3 Affirmative statement o f " hazard" (Column B, Schedule 3) 4 "Precautionary measures" covering actions to be followed or avoided (Column C, Schedule 3) 5. "Instructions m case of accident," where advisable (Column D, Schedule 3) 8) Warning labels should be printed in easily legible type, which is in contrast by typog raphy, layout, or color with any other punted matter on the label and should be placed conspicuously on containers Legibility may be preserved with e suitable piotective coating * To provide piactieal working standard fo r labeling purposes 1P O ISO N ' u defined m Schedule 1 at this Manual to include only Chemicals capable o f causing acute effect* b y mgeet/on and inhalation the principal mode* of entry into the body Thi* definition excludes chemical capable of causing injuries a* a result of skin absorption or o f chronic ovpoaure by inhalation, because the vanabfe actions and effects o f chemical with the chnracleruiiei preclude a piaetlcal means o f m easuring thir hazards. 2 M unlintnni Chcmim' AvxxiJrion oi ihe United Soto ________________ MbU*! H .Schedule 1 D E F IN IT IO N S Flammable Liq uid12*--An inflammable ' liquid is any hyoid which gives off inflammable vapor9 (as determined by flash point from Tagllabue'a open-tup tenter, as used for test of burning oils) at or below a temperature of 80* F Extremely Flammable Liquid' --An extremely flammable liquid is a liquid which gives off flammable vapors (as determined by flash point from Taghabue's open-cup tester, as used for teat of burning oils) at or below a temperature of 20" F Corrosive*-- (Physiological)-- A corrosive is &n agent which in contact with living tissue will cause more or leas severe destruction o f tissue by chemical action. Irritant7-- (Physiological)--An irritant is an agent which m contact with living tissue will induce either immediately or after prolonged or repeated contact a more or less severe local tissue reaction not leading directly to destruction of tiseue. Sensiftzer*-- (Physiological)--A sensitizer is a material which as ordinarily handled does not necessarily cause any discernible reaction in living tissue but which after initial or re peated contact with the tissue of some individuals may, at a later date, produce a prompt inflammatory reaction on contact, even in minute amounts, with the tissue of the same individuals. Duets --Solid particles generated by handling, crushing, grinding, rapid impact, detonation and decrepitation of organic or inorganic materials such as rock, ore, metal, cool, wood, grain, etc. Dusts do not tend to flocculate except under electrostatic force; they do not diffuse m air but settle under the influence of gravity Fum e3--Solid particles generated by condensation from the gaseous state, generally after volatili zation from molten metals, e tc, and often accompanied by a chemical reaction such as oxidation. Fumes flocculate and aometimea coalesce. Afists*-- Suspended liquid droplets generated by condensation from the gaseous to the liquid state or by breaking up a liquid into a dispersed state, such as by splashing, foaming, and atomizing. Gases *--Normally formless fluids which occupy the space of enclosure and which can be changed to the liquid or solid state only by the combined effect of Increased pressure and decreased temperature. Gases diffuse Vapors ' --The gaseous form o f substances which are normally in the solid or liquid state and which can be changed to these 3tateB either by increasing the pressure or decreasing the the temperature alone. Vapors diffuse. P oison 7--Poison means a substance which, when taken by mouth in amounts of 60 grains (4 grams) or less, or when inhaled m concentrations of less than 200 parts per million by volume in the air, rapidly (within 6 or 10 minutes) jeopardizes life by other than mechani cal or physical action Mote This definition of ``Poison'' 1 based on practical considerations only, >8 an aid m determining, generally, when the word "Poison" should he included on a warning label See General Principles 4 Mixture 5--A physical commingling of two or more substances which may or may not bear a fixed proportion to one another and which have not reacted chemically with one another 1I C C dRfimtlon W hile the term `'inflammable'' is used by the IC C , the prefe-red form "flammable'' Is used in this Manual 2 M C A definition s A s defined In Chaptoe I I " Engineering Control of the A ir Contamination o f the W oik ing Environment' ' (Allen D Brandt, D S c ) page 198, ' M anual o f Industrial H ygien e," U S P H S , 5 Mn.l L-l Mmuliciuiini QitnjiKi Aumisikia cJ ,k> Un.ird Som Column D--When it is advisable to Include Instructions in case of accident, the appropriate statements may be selected from this column Instructions in case of accident to indi viduals arc valuable hut should be limited to recognized first aid procedures based upon simple methods and commonly available materials Instructions for strictly medical treat ment should be omitted except when specifically required by Jaw Because o f the serious and lasting effects that may result from eye injuries, & recommendation to obtain medical attention should accompany any specific instruction directed to the treatment of the eyes If the statements from Schedule 3 fail to meet the exact needs, they should be modified to suit In the example shown, toluene, no phrase from this column appears to be necessary While every compound carries some hazard, if improperly used, it is impractical to cover every possible contingency on a label Efforts should be directed toward naming the serious hazards, and warning against such abuses and accidents as are likely to be encountered under norma) con ditions. There are scarcely any means o f measuring in absolute terms the relative seriousness of hazards, and the recommendations in Schedule 8 only contemplate their division into two or three degrees of intensity It follows that of two compounds one may be less hazardous than the other and yet may carry the 9ame warnings and cautions Instructions for handling and storage of containers should be included where conditions indi cate their need These instructions should take into consideration both the characteristics of the chemical product and the limitations of the type or types of container m which it is packed Schedule 4 presents suggested labels for samples of experimental products for which full data regarding hazards are not yet known Schedule 5 illustrates the application of caution statements to three specific products In the case of toluene, the statements used are similar to those given in Schedule 2 for a compound or mixture having hazards in classifications I-B and IV The second example, aqueous hydrofluoric acid, represents a very special case where the particular hazards require modification of the stand ard statements. The third example is that of a label for a proprietary compound or mixture 4 Muvftauiint Q kiuish Ausciu.oa ol tbe UnuM Sam Xl.mial LI V Gases and Vapors PhyaioiogicaUy Inert CAUTION! VAPOR REDUCES AVAILABLE FOR ING Use with adequate ventilation. Keep container closed. OXYGEN BREATH VI. Harmful Dusts. CAUTION! HARM FUL DUST Avoid repeated breathing or skin contact. Wash thoroughly before eating or smoking Keep away from feed or food products VII Skin Irritants--Corrosive, D AN GER!CAUSES SEVERE BURNS Do not get in eyes Do not get on skin Do not get on clothing In case of contact, immediately flush skm or eyes with plenty of water, for eyes, get medical attention. Remove and wash cloth ing before re-use V III Materials Causing- Skin Irritations after Repeated or Continued Contact CAUTION! MAY CAUSE SKIN IRRITA TION Avoid prolonged or repeated contact. IX . Materials Toxic through Vapor Inhala tions or Skin Absorption. WARNING l ABSORBED THROUGH SKIN VAPOR HAZARDOUS Avoid contact with skin or clothing Avoid breathing vapor In case of exposure, remove to fresh air Immediately wash with soap and plenty of water Remove and wash clothing before re-uae X Toxic if Taken Internally Applies to ma terials covered by statutory definition of poison " liable to be destructive of human adults in doses of 60 grains or less (4 gma )" or to any material toxic in amounts likely to be taken internally through easily anticipated errors. POISON If not covered by regulation or definition (see Gen ersl Principles 4) s typical Isbel might resd DANGER! MAY BE FATAL IF SWALLOWED Do not take internally 7 Hjnnul] LI ____ _____________ MinufKimmi CKt/riiu ^tKKUHMi of 1)1 Uftlirt ton Schedule 2 CLASSIFICATION O F HAZARDS Class Typical Label I Flammable Liquids and Oxidizing Agents which Support Combustion (Flash points for liquids are determined by Taghabue'a Open-Cup Method). A Flash point 20 F or below. DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame Keep container closed B. Flash point above^O" to 80* F in clusive. W ARNING! FLAMMABLE. Keep away from heat and open flame. Keep container closed . 11 Flammable Solids and Oxidizing Agents as Classified by the ICC CAUTION! EXPOSURE MAY CAUSE FIRE OR CREATE FIRE HAZARD Keep away from heat and open flame Keep container closed. In case of contact, immediately flush with plenty of water, remove and wash clothing before re-use III Vapors Immediately Toxic or Extremely Irritating Even on Exposure for a Short Time or to Low Concentrations. DANGER! VAPOR EXTREMELY HAZARDOUS Do not breathe vapor Do not get on akin Do not get in eyes Keep container closed and away from heat. Keep away from feed or food products Have air line respirator or gas mask ap proved by U S Bureau of Mines specifi cally for (name of chemical) available for emergency IV Vapors Hazardous from Prolonged or Repeated Exposures, or Exposure to Higher Concentrations W ARNING t VAPOR HARMFUL Uae only with adeiuate ventilation Avoid prolonged or repeated breathing of vapor Keep container closed and away from heat Minuftoiiti* eternivi AiscIjiuv) cl ihc Sui Schedule 1 LABELS FOR EXPERIMENTAL SAMPLES Manus) l-l The labeling of experimental samples of new products presents unusual problems All of the properties or possible uses of a product are seldom known. The following safeguards are therefore recommended: 1. Samples of a product already on the market should carry the same warning label as a commercial shipment 2. The following label is suggested for samples of any material that has never been in commer cial production unless (1) the material is known to be wholly innocuous, or (2) the dangers are limited to known hazards and appropriate cautions are submitted SAMPLE Name or Description of Product FOR EXPERIMENTAL USE ONLY CA U T IO N ! The chemical, physical and toxicological properties of this product have not been fully investigated and its handling or use may be naiurdous. Exercise due cere 3 The identity of the sample, indicated m parentheses above, should be as clear as possible. Wherever feasible, it should be the name of the compound or mixture, and m any case it should be the best possible identification to aid the user in knowing with what he is concerned. 4. Where there are significant known hazards they should be so indicated 5. The above label may be used m the case of old products being considered for new uses Schedule 6 SPECIMEN PRODUCT LABELS The following specimen labels illustrate the application to specific products of the principles set forth in this Manual *. Product Combining Hazards of Class I-B and IV (Schedule 2) Chemicals TOLUENE W ARNINGl FLAMM ABLE Keep away from heat and open flame Use with adequate ventilation Avoid prolonged breathing of vapor Avoid piolonged or repeated contact with skin L. M im i.'ll L -l Miimfiaurini Chemira Auocumoa ol ite Umica Sem " Schedule 3 RECOMMENDED LABEL CAUTIOUS A. Signal Words B. Hazard c. Precautionary Measure D. Instructions in Case of Accident Flamm ability Extrem ely Flammablefflosh point 20 F or below ) b .F lam m able (Hash p o i n t above 20* to 80* F Inclu sive) c Exposure May Cause Fire or Create Fire Hazard a Keep s w a y f r o m heat (sparks) and open Dame b Keep container dosed (and sway from best) Volatility a H ighly Volatile b. Volatile (Solvent or L iq u id ) a Keep out o f sun and away from heat. b Keep combiner cloueq (and ewer from heat) Inhalation a DANGERI b. W ARN ING' e. C A U T IO N ! a Vapor Extremely Hazardous b M ay be F atal if Inhaled c Vapor Harmful d Vapor Reduces O x y g e n Available tor Breathing e Harm ful Dust t Causes Irritation to Eyes, Nose and Throat. a Da not breathe vapor (or) Avoid b u ath m g vapor Li. Avoid prolonged or repeat ed breathing of vapor c Use (only) with adequate ventilation d Avoid prolonged breathing of dust Contact (n esse of exposure remove to fresh air b H ave air [ins respirator or gee outsit approved by U 3 Bureao or Mines specifi cally for (rsm e of cheml M i) available for emer gency a Corrosive Liquid b Causes (Severe) B unn e Dangerous Because (Rap idly) Absorbed Through Skin d Causes Skin Irritation e M ay Causa Skin Irritation. a. Do not get (1) in eyes, (2) on skin, (8) on clothing, b Avoid contact with (1) ryes. (2) skin, (3) clothing C. Wash thoroughly before eating or smoking Ingestion n In ease of contact (1) Immediately flush (skin or eyes) with plenty of water (for at least 16 min utes) (For eyes, get med teal attention) (2) Immediately wash with soap and plenty of water (3) Remove and wash clothing before re use. a Poison (akul) A crossbones) b M av be Fatnl if Swallowed a Dc not tako Internally, General a Strong Oxidant b Contnct with Combustible M ateuol May Cause Fire a , Keep way from feed or food pioducts b Keep dry c Store in cool piece d Keen away from enmbus tible mateitals s G et medical attention b In case of milage, flush with plenty o f water c Jo case of spillage, absorb with sand, oehes or oarth The use of any warning or other statement listed above is not pecessauly limited to the hazaid undei which it la grouped The gioupmg m e e t/ indicates tho type of hazaid to which given statements most frequently apply The small letters oie not Intended to indicate a c o n d itio n botween am uteily lettered statements in adjacent columns but rue /oi identification only The parenthetical words indicate optional statements Manual L I Mamiftaanoi Owaunt Aueomso of ihe Uicifi Sara Product Requiring Modified Cautions and F irst A id HYDROFLUORIC ACID, AQUEOUS DANGER I CORROSIVE LIQUID VAPOR HAZARDOUS CA USES SEVERE BURNS WHICH M AY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not breathe vapor Do not get m eyes, on skin, on clothing In case of contact or suspicion of contact* Immediately Rush skin with plenty of water until whiteness dis appears, paying particular attention to skin under nails Soak affected areas with crushed ice in 70% ethyl alcohol until physician arrives Flush eyes with plenty of water for at least 15 minutes In all cases get medical attention. Remove and wash clothing before re use Avoid use of greasy ointments Proprietary Product (e g . containing fluorine salts) (PROPRIETARY NAME) Contains Fluorine Compounds W ARNING! POISONOUS IF TAKEN IN T E R N A LL Y Avoid breathing dust Flush spillage to sewer with water P LM-a2nual P A R T II M A N U A L L-2 -- ILLU ST R A T IV E W ARN ING L A B E L S FO R H AZARDOUS CH EM ICA LS Adopted 1945 Revised 1946 PREFACE This Manual contains warning labels suggested by the Manufacturing Chemists' Association to cover the significant hazards inherent in a large number of industrial chemical products. These products have been selected so as to provide illustrative labels for each major type of hazardous chemical which is of commercial importance. In many cases these labels are applicable to other products which are listed only in the index with appropriate cross references. These labels do not cover impurities which may be present in the products and, except in a few instances, do not include precautionary information regarding the handling and storage of the containers. The manufacturer or packer should in each case include on his label additional warn ings to cover the hazards due to impurities which may be present in harmful quantities and, where the facts so indicate, to cover container handling and storage. Suggested first aid treatment has been included for a few products only. The omission of first aid treatment for other products should not in any case be interpreted to mean that it may not be desirable. Individual statutes, regulations or ordinances may require that particular information be included on a label or that a specific label be affixed to a container as in the case of the Interstate Commerce Commission Regulations for Transportation of Explosives and Other Dangerous Articles. In each case, the requirements of these laws should also be studied. The warning labels suggested in this Manual should be used in addition to or in combination with any label required by law. These labels have-been prepared in accordance with the procedure outlined in Part I, M .C .A . Manual L - l " A Guide for the Preparation of Warning Labels for Hazardous Chemicals." The user should familiarize himself with Manual L - l before adapting any of the label statements con tained in Manual L-2 to his products. It is anticipated that Manual L-2 will be supplemented from time to time as additional illustrative labels are suggested or revisions are made. Min4/O4/i0| ChOMKi AuaowiM of ife l/nid Sacs 12 ACETALDEHYDE DANGER1 EXTREMELY FLAM M ABLE Keep way from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Chill thoroughly before opening. CARBOV LABEL ACETIC ACID, GLACIAL DANGER! CAUSES SEVERE BURNS Do net get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. CARBO Y H A N D LIN G A N D STO RA G E Glacial Acetic A c id f r o at M * F , forming hard lumps which may break carboy whan moved. Store in area maintained above 6 2 'F , If froien, thaw by carefully moving carboy to warm area ALUMINUM DRUM LABEL ACETIC ACID, GLACIAL DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention. DRUM H A N D LIN G A N D STO RAG E Glacial Acetic Acid freeiei et 62ep, forming hard lumps. Store m area maintained ebova 42F. If freien, thaw by moving to warm area 12 r V L M/igfaaufia Chc Ufot S-ilu BARREL l a b e l ACETIC ACID (80%) DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor n eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BARREL BA N D U N G AN D STORAGE Keep out of sun and wy from heat. Store with bilge bung up. Never use pressure to empty. Drain completely. Keep berrel moist; shrinkage may M use leaks. In ease of spillage, flush with plenty of water. B A R R E L LABEL ACETIC A C ID (56% and 70%) W ARNING! M A Y CAU SE BURNS Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or yet with plenty of water for at least )5 minutes; for eyes, get medical attention. BARREL H A N D LIN G A N D STO RAG E (U *t tame instructions m fo r Acetic A cid 8 0% ) BARREL LABEL ACETIC ACID (28%) CAUTION! M A Y CAU SE BU RNS Avoid contact with eyes, skin, or clothing. In ease of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention BARREL H A N D LIN G A N D STO RAG E (U te tam e intlruclw m a i fo r Acetic 4cid 80% ) 13 Manu*! La Manul L-2 MflU/Kit/rint O w n m -luodiijoo ol the United Juin ACETIC ANHYDRIDE DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eye, on skin, on clothing. Do not breath vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. ACETONE DANGER1 EXTREMELY FLAM MABLE Keep away from heat and open flame. Keep container doted. Use with adequate yentilation. A vo id prolonged or repeated contact with skin. ACETONYLACETONE CAUTION! VOLATILE SOLVENT Keep away from heat and open flame. Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. Note: Contact with this material stains the skin. ACETYL CHLORIDE DANGER! FLAMMABLE CAUSES SEVERE BURNS Do not allow water to get in container. Keep away from heat and open flame. Keep container closed. Do not get in eyes, on skin, on clothing. Avoid exposure to concentrated vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical aftention. 14 c r Lo MouhPrm,t Cht ACRYLONITRILE DANGER! FLAM M ABLE POISON Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use with adequate yentilation. Keep away from heat and open flame. Keep container dosed. L-: ( t # POISON # FIRST A ID TREATM ENT Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately end C A L L A PH YSIC IAN . If patient is conscious and breathing. I II) Break an amyl nitrite pearl in a cloth and hold lightly over the nose for not more than 15*20 seconds. Repeat every 5 minutes for 25 minute* ?f recovery is not forthcoming. l (2) If this product has been S W A L L O W E D , give patient one pint of 1 % Sodium Thiosulfate solution (or soapy water or mustard water) by mouth every 15 minutes until vomiting occurs. If patient has stopped breathing: G ive artificial respiration until breathing starts. Break an amyl pitrite pearl in a cloth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes or until breathing starts. If patient Is unconscious but breathing: Break an amyl nitrite pearl in a doth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if recovery is not forthcoming. Give oxygen from an inhalator. Never give anything by mouth to an unconscious person. In all cases r keep patient quiet and warm until a physician arrives. t i IS I ALLYL ALCOHOL DANGER! RAPIDLY ABSO RBED THROUGH SK IN VAPOR EXTREMELY HAZARDOUS FLAMMABLE Do not get In eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention Remove and wash clothing before re-use. Do not take internally. ALLYL CHLORIDE DANGER! HARMFUL AND FLAMMABLE Do not get in eyes, on skm, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. VAPOR carboy label A M M O N IA , AQUA W ARNING! LIQUID CA U SE S BURNS VAPOR EX TREM ELY IRRITATIN G Avoid breathing vapor. Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. CARBO Y H A N D LIN G A N D STORAGE Refer* moving carboy bo ure cloture li teeuraly Loosen clenwe carefully. Keep out of sun and away from heat. Mover w e pressure to empty. Completely dram e*rboy before returning. In case o f (pillage, flush with plenty o f water. fastened. ( I ( LU a d Uie United Sain AM M O N IA, AQUA W ARNING! LIQUID CAU SES BURNS VAPOR EXTREM ELY IRRITATING Avoid breathing vapor. Avoid contact with eyes, skin, or clothing. In case of contacf, immediately flush skin or yes with plenty of water for at least 15 minutes; for eyes, get medical attention. DRUM H A N D LIN G A N D 5T0RAG E Keep plug up to provent leakage. Keep drum out of $un and away from haat. Before removing plug, loosen slowly to relieve pressure. Never use pressure to empty. Keep lights, fire and sparks away from drum openings. Drum must not be washed out or used for other purposes. Replace plug after each withdrawal and return with empty (n case o f spillage, flush with plenty of water. drum. CYLINDER LAB EL AM M O N IA, ANHYDROUS W ARNINGS HAZARDO U S LIQUID AN D VAPOR UNDER PRESSURE LIQUID CAU SES BURNS VAPOR EXTREM ELY IRRITATIN G Do not breathe vapor. Do not get in eyes, on skin, on clothing, in case of contact, immediately flush skin and eyes with plenty of water for at feast IS minutes. Call a physician at once in case of burrs, especially to the eyes, nose and threat, or if the victim is unconscious. c y l in d e r h a n d l in g a n d s t o r a g e Keep away from heat. D o not flora in sunlight. Never drop cylinders. Be sure connections ere tight. Never refill cylinder. I C C Regulations prohibit refilling without permission of owner H ave gas mask approved by U. S. Bureau of Mines specifically hr ammonia service available for emergency. 17 Minuiwturini ChuiuHi Auoqkiob of eke Uaacd Soie L-2 A M M O N IU M BICHROMATE W ARNING! FLAM MABLE HARMFUL OUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP A W A Y FR O M HEAT, SPARKS, A N D FL A M E KEEP C O N TAIN ER C LO SED , Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not fake infernally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes: for eyes, get medical attention Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. AM YL ACETATE CAU TIONI VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ANILINE DANGER! RAPID LY ABSO RBED VAPOR HAZARDOUS THROUGH S K IN # POISON # Do not get on skin, on clothing. Avoid breathing vapor. Use with adequate ventilation. In case o f contact, Immediately flush skin with plenty of water. Remove and wash clothing before re-use. 10 Manual L-2 o-ANISIDINE W ARNING! HAZARDOUS LIQUID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor. p-ANISIDINE W ARNING! HAZARDO U S SO LID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing dust or vapor ANTIM O N Y TRICHLORIDE DANGER1 CAU SES SEVERE BURNS I VAPOR HAZARDOUS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. Keep container closed. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes: for eyes, get medical attention Remove and wash clothing before re-use. A R O M A T IC INDUSTRIAL SOLVENT ( F o r oli>enti having an in itia l boiling po in t not below 100 C. fin d ' h avin g a fla sh po in t 8 0 *P . o r B E L O W , Tngliabue O p en C u p M ethod at specified by Interstate Com m erce Com m ittiotu) W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. Mtnul L.2 bltnuhwjiin Quain Auogttia ol (lit Uoucd Su ARO M ATIC INDUSTRIAL SOLVENT (For tolvenit having on initial bailing point not below 100nC, and having a lath point A B O V E 80*F., Taglubue Open Cup Method a tpectfied by Interkite Commerce CammUsion) CAUTION! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ARSENIC TRICHLORIDE DANGERl CORROSIVE LIQUID VAPOR EXTREMELY HAZARDOUS % POISON Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep container closed. in case of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medieal attention. Remove and wash clothing before re-use. BARIUM NITRATE CAUTION! STRONG O XIDAN T CONTACT W ITH CO M BUSTIBLE M A T ER IA L M A Y CAU SE FIRE Keep container closed and away from combustible material and heat. Sweep up and carefully remove spiled material Avoid repeated contact with skin. D o not take internally. 20 ( 1( MtouUqurlat Oieaitti Auoctuiea o< (he Ui Suit L -i BARIUM OXIDE CAUTION! M AY CAU SE SK IN IRRITATION Avoid contact with skin. Keep away from feed or food products. Do not take internally. BARIUM PEROXIDE CAUTION! STRONG OXIDANT CONTACT WITH CO M BUSTIBLE M ATERIAL M AY CA U SE FIRE Keep container closed and away from combustible material and heat. Sweep up and carefully remove spiled material. Avoid contact with skin. Do not take internally. BENZENE (BENZOL) DANGER! EXTREMELY FLAMMABLE VAPOR H ARM FUL -- POISON Keep away from heat and open flame. Keep container closed. Use with adequate ventilation Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. BENZIDINE W ARN IN G ! H AZAR DO U S SOLID A N D VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid breathing dust or vapor. Avoid contact with skin. In case of contact, immediately wesh with soap and plenty of water. 2i w *" 1 MmuAnvnnc Uieiutu Aiwcmiop al he Ueud Som CARBOY LABEL BENZOYL CHLORIDE W ARNING] CAU SES BURNS VAPOR IRRITATIN G Avoid contact with item or eye. Avoid breathing vapor. in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. C A R B O Y H A N D LIN G A N D STO RAG E Bator moving carboy be iur cloture It ucuroty fastened. Loosen cloture carefully. Keep out o f sun and away from heat. Never use pressure to empty. ; Completely drain carboy before returning In case of spillage, flush with plenty o f water. CARBOY LABEL BENZYL CHLORIDE W ARNING! CA U SES BURNS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. In case of contact with liquid, immediately wash skin with soap and plenty of water; flush eyes with weter for at least )5 minutes and get medical * attention. Do not transfer to ordinary metal containers without first adding stabilizer. Get instructions from manufacturer. flRl/Af LABEL BENZYL CHLORIDE W ARNING! CA U SES BURNS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor, in case of contact with liquid, immediately wash skin with soap and plenty of water; flush eyes with weter for at least 15 minutes and get medical attention The Benzyl Chloride in this drum contains e stabilizer. Before transferring, get instructions from manufacturer. 22 r / QM Aitcam ii ibe Uonci Sana BROMINE DANGER! CAUSES SEVERE BURNS Do not get on skin or in eyes. Do not breathe vapor. in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet with crushed ice in 7 0 % ethyl alcohol until physician arrives. BUTYL ACETATE (normal) CAU TIO N I VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (normal or secondary) CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (tertiary) W ARNING! FLAM MABLE Keep away from heat end open flame. Keep container closed. U se w ith ad eq u ate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 23 Manu) L-3 M in uti I.-2 Muuiiamm Cbcffutfa ioa of iSc Uautd Su m BUTYLAMINE (normal) W ARNING: FLAM M ABLE M A Y CAU SE SK IN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at feast 15 minutes; for eyes, get medical attention. p-tert. BUTYLCATECHOL W ARNING! CA U SES SK IN IRRITATION CA U SES BU RN S W HEN MOIST Do not get in eyes, on skin, on clothing. In case of contact, immediately wash slnn with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. BUTYL CHLORIDE (normal) DANGER! EXTREMELY FLAMMARLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. BUTYL ETHER (normal) W ARNING] VO LATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin C A U T IO N : Dry ethers tend to form explosive peroxides. Do not use materia) if it liberates iodine from acidified aqueous iodide solutions 24 C (' ' ` o Cfctiaitt M iniai CALCIUM CYANIDE DANGER! LIBER A TES POISONOUS G AS Avoid breathing gas or dust. Avoid contact with skin. Keep away from acids. Store away from feed or food products. Keep container tightly closed and dry. p o iso n FIRST A ID TREATM ENT (V e am Jin t aid treatment at recommended fo r inorganic Cyantdet) CARBON DISULFIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE ^ POISON ^ Keep away from fire, sparks, or heated surfaces. Store in cool place and keep container closed, Avoid breathing vapor. Avoid contact with skin. CARBON TETRACHLORIDE W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLORINATED NAPHTHALENE Avoid repeated contact with skin. Avoid repeated inhalation of the fumes and dust. 25 Mtnui H CAUSTIC SO DA (SODIUM HYDROXIDE) W ARNING! CAUSTIC SO D A IS CORROSIVE BURNS SKIN AND EYES Avoid contact with body Of clothing. Do not take internally. P R E C A U T IO N S When handling Sodium Hydroxide wear goggles or face shield and avoid all contact with skin. While making solutions, add Sodium Hydroxide slowly to surface of solution to avoid violent Spattering In Case of accidental contact with skin, immediately flush affected parts with water and wash with vinegar. For eyes, flush freely with water for at least 15 minutes and get medical attention. m TH E C.4SE O F P R O P R IE T A R Y COMPOUNDS CONTAINING CAVSTIC A LK A LI: l ) Name of Product W ARN IN G I CO NTAINS CA U ST IC A L K A L I W HICH IS C O R R O SIV E BURNS SKIN A N D EYES Avoid contact with body or clothing. Do not take internally. P R E C A U T IO N S (V * e tame precaution* at fo r Sodium H ydroxide, H lbllllllU ng nam e o f product for Sodium H ydroxide.) CHLOROBENZENE, M O NO W ARNING! VAPOR HARM FUL Use with adequate ventilation. Avoid contact with skin or clothing. Avoid prolonged breathing of vapor. ni dw Udntd Saia M iaut CHLOROFORM W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROTOLUENE, M O NO CAUTION! VAPOR HARM FUL Use with adequate ventilation. Avoid prolonged breathing of vapor. CHROMIC ACID W ARN IN G ! CO NTACT W ITH CO M BUSTIBLE M A T E R IA L M A Y CA U SE FIRE CAUSES SEVERE BURNS KEEP C O N T A IN ER CLOSED. Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. COAL TAR CREOSOTE (CREOSOTE OIL) CAUTION! M A Y CAU SE SK IN IRRITATION Use only with adequate ventilation. U Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of vapor. Manual L-2 Mtnv/iaunni Oicmla AunriuioA nf die (failed Sato CYANIDES, INORGANIC (excluding Liquid Hydrocyanic Aetd and Calcium Cyanide) Name of Product DANGER! CONTACT W ITH A CID POISONOUS G A S L IB E R A T E S Avoid breathing gas or dust. Avoid contact with skin. Keep away from feed or food products. Keep container closed and store in a dry place. ^ POISON ^ FIRST A ID TREATM ENT Carry patient to fresh air, Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately and C A L L A P H YSIC IAN . If patient is conscious and breathing: (1) Break an amyl nitrite pearl in a cloth and hold lightly over the nose for not more than 15-20 seconds. Repeat every 5 minutes for 25 minute* if recovery is not forthcoming. (2) If this product has been S W A L L O W E D give patient one pint of 1 % Sodium Thiosulfate solution (or soapy water or mustard water) by mouth every 15 minutes until vomiting occurs. (Eliminate this for liquid HCN }. If patient has stopped breathing; Give artificial respiration until breathing starts. Break an amyl nitrite pearl in a cloth and hold lightly over nose for not mora than 20 sec* onds, repeating overy 5 minutes for 25 minutes or until breathing starts. If patient is unconscious but breathing: Break an amyl nitrite pearl in a cloth and hold lightly ovor nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if recovery is not forthcoming. Give oxygen from an mhalator. Never give anything by mouth to an unconscious person In all eases keep patient quiet and warm until a physician arrives. 28 ( I ( I C 0 t- o Chemin, Amoouim </ the toned Sum CRESOL (CRESYLIC ACID) DANGERI RAPID LY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get on slcin or in eyes. Do net breathe vapor. Do net take internally. In ease of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-usa. CYCLOHEXANE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. CYCLOHEXANOL CAUTION! VAPOR HARM FUL Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. DICHLOROETHYLENE W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 29 Manual L-2 Mtnu/scianoi AuoaUiofl o d,c tfa/icd Satei DICHLOROETHYL ETHER W ARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take Internally. DICHLOROPHENOL (F or nil itom erlo dichUirophenols) W ARNING! M A Y CA U SE BURNS Avoid contact with sltm. Avoid breathing vapor. Do not take internally. In case of contact, immediately wash with soap and plenty of water. DIETHYLAMINE DANGER! EXTREMELY FLAMMABLE M AY CAU SE S K IN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes. In ease of contact, immediately flush skin or eyes wifh plenty of water for at least 15 minutes,* for eyes, gat medical attention. 30 {aWicwciat Chnuiii Autamaa et tir Danni Sam Manual L.J D IO X A N E (1,4-DIETHYLENE DIOXIDE) W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. C A U T IO N ! Dry ethers tend to form explosive peroxides. Do not use material if it liberates Iodine from acidified aqueous iodide solutions. ETHYL ACETATE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ETHYL BROMIDE W ARNING! VAPOR HARMFUL Use with adequate ventilation Avoid prolonged breathing of vapor. Keep out of sun and away from heat. Keep container closed. ETHYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. U$e With ad eq uate ventilation Keep container closed, out of sun and away from heat. Manual L- Mmaf.cwnlni Qumnq AiianMiaa ai rkt UautJ Suis ETHYLENE CHLOROHYDRIN DANGERS RAPIDLY A BSO RBED THROUGH SK IN VAPOR EXTREMELY HAZARDOUS Do not gat on skin or clothing. Do not breaths vapor. Do not taka internally. In case of contact, immediately wash with soap and . plenty of water; remove ana wash clothing before re-use. POISON ^ FIRST A ID TREATM ENT If swallowed, make patient vomit immediately (finger down throat) or giva warm mustard water or salt water freely. General: Keep patient warm; if conscious give black coffee. Call physician. Note: Do not give adrenalin. ETHYLENE DIBROMIDE W ARNING! VAPO R HARM FUL Avoid breathing vapor. Avoid contact with eyes, skin, or clothing, 1n ease of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. Do not take internally. ETHYLENE DICHLORIDE W ARNING! FLAM M ABLE VOLATILE SOLVENT VAPOR HARMFUL Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 32 ( I I uC Muiuiiogun* Chtmiu Altounina at ibt (.mod taie* Xinaol L-Z ETHYLENE GLYCOL MONOMETHYL ETHER CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ETHYL ETHER DANGER! EXTREMELY FLAMMABLE HIG H LY VOLATILE Keep away from heat and open flame. Keep container tightly closed. C A U T IO N ! Dry ethers tend to form explosive peroxides. D o not use material if it liberates iodine from acidified aqueous iodide solutions. ETHYL FORMATE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of yapor. ETHYL METHACRYLATE MONOMER W ARNINGI FLAMMABLE Keap away from heat and open flama. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin or clothing. 33 Minuti L -J chi Henni Sexes FORMALDEHYDE W ARNING! CAU SES IR RIT ATIO N OF SKIN, EYES, NOSE AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. POISON ^ CALL A PH YSICIAN AT ONCE FIRST A ID InternaNy: Give milk freely, or one glassful of water containing I table spoonful of ammonium acetate. Produce vomiting with a pint or more of warm salt water (I cupful per quart) or warm soapy water. Repeat three times. Follow with milk end raw eggs. BARREL LABEL FORMIC A CID W ARNING! CA U SES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BARREL H A N D LIN G A N D STO RA G E Keep out of sun and away from heat. Store with bilge bung up. Never use pressure to empty. Drain completely Keep berrel moist; shrinkage m ay cause leaks In case of spillage, flush wtfh plenty o f wafer. 34 oG Chcnli of the UsmH Saia CARBOY LABEL FORMIC ACID W ARNING! CAU SES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case o f contact, Im m ediately flush skin o r eyes w ith plenty o f w ater fo r a t least 15 minutes; for eyes, get medical attention CARBO Y H A N D U N G A N D STORAGE Before moving carboy be sure closure Is securely fastened Keep out of sun and away from heat N e var use pressure to empty Completely drain carboy before returning In case of spillage, flush with plenty of water. CARBOY LABEL HYDROCHLORIC ACID W ARNINGI CAUSES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention CARBO Y H A N 01IN G AN D STORAGE Before moving carboy, be sure closure Is securely fastened. Loosen closure carefully. Keep out of sun and away from heat Ne ve r use pressure to empty. Completely drain carboy before returning In case of spillege, flush with plenty of water. 35 Manual 12 [ ^ 1 j ' j > i j I I 1 I t Mhu*l L-t Mvtuiinoclai CbtiDtKi Atuouion HYDROCYANIC ACID, LIQUID DANGER! PO ISON G AS Do not breathe gas, Avoid contact with stein. Do not drop container. Keep cool and away from open flame. # POISON # FIRST A ID TREATM ENT (Vie tame first atd treatment its recommended for inorganic Cyanide) HYDROGEN PEROXIDE (stronger than 25 volume and not exceeding 130 volume) CAUTION! STRONG O XIDANT Avoid contact with eyas or skin-- wear goggles and rubber gloves. Avoid contact with combustible materials. Drying of this concentrated product on clothing or other combustible materials may cause fire. In case of contact, Immediately flush slun or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid decomposition, generation of farge quantities of oxygen gas, and high pressures. CO N TAIN ER H A N D LIN G A N D STORAGE Store in original dosed container. K t i p out of run and away from heat. 1 sure that the container vent rs working satisfactorily. D o not ad d any other product to this container W han empty, rinse thoroughly with dean water. 36 i I ( ! t ( O (J MMu/icnir.ai Qtcmint HYDROGEN PEROXIDE (25 volume) CAUTION! STRONG OXIDANT Avoid contaet with eyes or skin-wear goggles and rubber gloves. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid de composition, generation of large quantities of oxygen gas, and high pressures CO N TA IN ER H A N D LIN G A N D STORAGE ' S to re in origins) d o s e d container Be sure that the container vent is working satisfactorily. Do not add any other product to this container W h e n empty, rime thoroughly with clean watar. MiniiaJ L 2 HYDROFLUORIC ACID, AQUEOUS DANGER! CORROSIVE LIQUID VAPOR HAZARDOUS CA U SES SEVERE BU RNS W HICH M A Y NOT BE IM M ED IATELY PAINFUL OR VISIBLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. In ease of contact or suspicion of contact: Immediately flush skin with plenty of water until whiteness disappears, paying particular attention to jkm under nails. Soak affected areas with crushed ice n 7 0 % ethyl alcohol until physician arrives Flush eyes wHh plenty of water for at least 15 minutes In all cases get medical attention Remove and wadi clothing before re-use. Avoid use of greasy ointments. 37 Maaual L- ofikeCJautd Sat LEAD ACETATE W ARNING! HARM FUL DUST Avoid breathing dust. W ear dust mask approved by U. S. Bureau of Mines for this purpose. W ash thoroughly before eating or smoking. Keep away from feed or food produets. MALEIC ANHYDRIDE W ARNING! CAU SES BURNS Avoid contact with eyes, skin, or clothing Avoid exposure to concentrated vapor In case of contact, immediately flush skin or eyes with plenty of water for at (east 15 minutes; for eyes, get medieal attention. MERCURY BICHLORIDE (MERCURIC CHLORIDE) DANGER! M A Y BE FATAL IF SW ALLOW ED POISON Do not breathe dust. Keep away from feed or food products. W ash thoroughly before eating or smoking. Use fresh clothing daily. Take hot shower after work using plenty of soap. METHYL n-AMYL KETONE CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin sa ( I Cln.itd METHYL BROMIDE DANGER! HIGHLY VOLATILE CAUSES BURNS VAPOR EXTREMELY HAZARDOUS Keep away from heat. Keep container closed. Avoid breathing vapor. Avoid contact with skin, eyes, or clothing. ON CAN LABEL ADD: # POISON # <?S FIRST. A ID Remove to fresh air. Keep lying down and warm. Use artificial respiration if breathing has stopped. Get immediate medical attention. Oxygen mhalator should be used only at the direction of a physician. C A U T IO N 1 The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment Is available. Contact ( . _ ) for Name of Manufacturer information on equipment and proper use. METHYLENE CHLORIDE CAUTION! VOLATILE SOLVENT Ueo with adequate ventilation. Avoid prolonged' or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 3? Marniti hi nf ih linieri Sarti METHYL ETHYL KETONE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. U$e with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. METHYL METHACRYLATE MONOMER W ARNING) FLAM M ABLE M A V CAU SE SK IN IRRITATIO N Keep away from heat and open flame. Keep container closed. Usa with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin or clothing. METHYL iso-PROPYL KETONE W ARNING! FLAM M ABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 40 ( i j 1 j O O Otcnuio Awu<ie6 ih< Lnnri Sam Manali L-2 C ^ ltB O y LABEL MIXED ACID (Sulfuric and Nitric) DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITRO US G A S POISONING Do not breathe vapor. Do not get in eyas, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention c a r b o y h a n d l in g a n d st o r a g e Before moving carboy bo turo datura U ttcurobf iattentd Loosen cloture carefully. Keep out o f sun and away from heat. N ever use pressure to empty. Completely drain carboy before returning. In cast of spillage, flush with plenty of water. (U n der l C . C . Regulation! carboy are perm U nble hipping container fo r m ixed acid containing n o( mare than 17% N itric Avid and at feast w a te r .) ORUiU LA B E L MIXED ACID (Sulfuric and Nitric) DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITROUS G A S POISONING Do not breathe vapor. Do rot gat in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of sun and away from heat. Relieve internal pressure when received and at least weekly thereafter by slowly loosening plug. Ret'ghten Immediately. Never use pressure to empty Keep lights, fire and sparks away from drum openings. Drum must not be washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum. In case of spillage, flush with plenty of water. 41 Manual L-J Miu/tniln| Oku AtlMNivi) uf th* Uniicd Suie MORPHOLINE W ARNING! HAZARDO U S LIQ UID AN D VAPOR M A Y CAU SE SK IN IRRITATION Use with adequate ventilation. Avoid exposure to vapor. Avoid confect with slim or eyes. b-NAPHTHYLAMINE CAUTION! CONTENTS HARM FU L REPEATED ABSORPTION IN BL A D D E R TU M O RS MAY RESULT Avoid breathing dust or vapor. Avoid contact with skin. Do not take internally. t.A R B O Y LABEL DANGER! NITRIC ACID CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CA U SE N ITRO U S G A S POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of wafer for at least 15 minutes! get medical attention. C A R BO Y H A N D LIN G A N D STORAGE Before moving carboy bo sure cloture Is securely foster*! Looser closure carefully Keep out of sun end away from heat Never use pressure to empty Completely drain carboy before returning In case of spillage, flush with plenty of water 42 ! ; ( * ^ J United Sait Manu' DRUM LABEL DANGER! NITRIC ACID CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS M A Y CAU SE NITROUS G A S PO ISONING Do not braatha vapor. Do not get in eyes, on skin, on clothing. In ease of contact, immediately flush skin or ayes with plenty of water for at least 15 minutes; get medical attention. DRUM H A N D LIN G A N D STORAGE Keep plug up to prevent leaU gs. Keep drum out at tun end away from heat. Relieve internal pressure when received and et least weekly thereafter by slowly loosening plug Retlghten Immediately Never use pressure to empty Keep light!, fire and sparks away from drum openings. Drum must not ba washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum In ease of spillage, flush with plenty of water. m-NITROANILINE W ARNING! HARM UL BECAUSE ABSORBED THROUGH SKIN Avoid contact with skm. Avoid breathing dust. In case of contact, immediately wash thoroughly with soap and plenty of water; remove and wash clothing before re-use. NITROPHENOL, M O N O W ARNING! M A Y BE ABSORBED THROUGH Avoid breathing dust. Avoid contact with skin. In case of contact, immediately wash with soap and plenty of water. S K IN 43 Marnili L-l Mmuhautlfti Chmim Auaiumn U ii< Uniirl iuici DRfJM LABEL OLEUM DANGER! CAUSES SEVERE BURNS Avoid breathing vapor. Do not get in eyas, on skin, on clothing, in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. Do not add water to contents while in a container because of violent reaction. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of tun in d away from heel. Relieve internal pretture when received end et least weekly thereafter b y tlowJy loosening plug. Retighten Immediately. Never use pressure to empty. Keep lights, fire end sparks away from drum openings. Drum must not be washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum. In case ot spillage, flush with plenty of water. I , j r'\ , ^ \^J \ J OXALIC ACID W ARN IN G ! H ARM FUL IF T A K E N IN T ERN A LLY CAU SES SK IN IRRITATIO N Avoid breathing dust. Avoid contact with skin. in casa of contact, immediately flush with plenty of water. Do not take internally. Keep away from feed or food products. PARALDEHYDE CAUTION! VAPO R HARM FU L Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Do not take internally. Solidifies at about 54 r. (I2 `C.) and may break container. Store in a moderately Wttftn place. Oo Manulidurini Oit iim<4 Suie PENTACHLOROPHENOL W ARNINGI HARM FUL DUST Avoid breathing dust. Avoid contact with skin or clothing. In case of contact with dry materiel or its solution, wash at once with soap and plenty of water. Do not take internaly. M inu ti L 2 PENTACHLOROPHENOL, OIL SOLUTIONS OF CAUTIONI CA U SES SK IN IRRITATION ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid eontaet with skin or clothing. In ease of contact with skin, wash at once with plenty of soap and warm water. Do not take Internally. See instructions for use before handling. PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (F or solvents having a flash paint 2 0 ' F , or B E L O W , Tngllabue O pen Cup Method at specified by interstate Com m erce Com m ission) Name of Product DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 45 Manu! L- Minili* PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (F o r solvent having a /lath point A B O V E 2 0P . but not above 800 F ., Tagiiabue O pen C u p M ethod ns specified b f Interstate Com m erce Com m ission) Name of Product W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PETROLEUM NAPHTHAS A N D SOLVENTS, INDUSTRIAL (F or solventi having a fla ih point A B O V E 6 0 F ., Tagiiabue O pen Cup M ethod a* sp e cifie d b y in te n ta te C o m m e rce C o m m issio n ) Name of Product CAUTION! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. p-PHENETIDINE CAUTION! H AZAR DO U S LIQ U ID AN D VAPO R ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor 46 ( i i i, OO o Ml^[0.ncn Cktt UaicW Saia DANCER! PHENOL RAPIDLY ABSORBED THROUGH CAUSES SEVERE BURNS POISON ^ S K IN Do not get on skin or in eyes. Avoid breathing vapor. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use, p-PHENYLENEDIAMINE CAUTION! M A Y CAU SE SK IN IRRITATION Avoid breathing or contact with dust. CARBOY LABEL PHOSPHORIC ACID CAUTION! CA U SES SK IN IR RIT ATIO N Avoid contact with skin or eyes, in cate of contact, immediately flush skin or eyes with plenty of water for at least 16 minutes; for eyes, get medical attention. C ARBO Y H A N D LIN G A N D STORAGE Before moving carboy be sure closure is securely fastened. Loosen closure carefully Keep out of sun and away from heat. Never use pressure to empty Completely drain carboy before returning. In cate of spillage, flush with plenty of woter, 47 Manul I 2 PHOSPHORIC ANHYDRIDE W ARNING! CA U SES BURNS Avoid contact with skin or eyes. When using, protect eyes with goggles and wear rubber gloves. In ease of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. Open carafglly. PHOSPHORUS DANGER! CAUSES SEVERE BURNS ^ POISON Contents packed under water and will ignite if water is removed. Keep drum out of sun and away from heat. Do not get on skin or in eyes. Protect eyes with goggles or face shield and wear heavy rubber gloves. In ease of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet until medical attention is obtained. PHOSPHORUS PENTACHLORIDE W ARNINGI H AZARDO U S DUST CAUSES BURNS Do not breathe dust. Do not get on skin or in eyes. Protect eyes with goggles and wear rubber gloves. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. Open carefully. 49 { O O Manual l-l PHOSPHORUS OXYCHLORIDE DANGER] CAUSES SEVERE BURNS VAPOR EXTREM ELY IRRITATIN G Do not breathe vapor. Do not get on skin or in eyes. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. CONfAiNER HAN0UN6 AND SrORASE D o not open unless you have been instructed in the proper manner, Never use pressure to empty Do not use this container for any other product In ease of spillage, flood carefully with L A R G E V O L U M E of water end provide adequate ventilation iso-PROPYL ACETATE W ARNING! FLAM MABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PYRIDINE W ARNING! FLAM MABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. 49 SAMPLE* i i Name or Description of Product FOR EXPERIM ENTAL USE ONLY C A U T IO N ! The chemical, physical and toxicological properties of this product have not been fully investigated and its handling or use may be hazardous. Exercise due care. *St*e M .C .A . Manual H . SILVER NITRATE W ARNING! CA U SES BU RNS POISON ^ Stains skin. Do not gat on skin or in eyes. in case of contact with eyes, get medical attention. SODIUM CHLORATE W ARNING! CONTACT W ITH COMBUSTIBLE M A T E R IA L M A Y CA U SE FIRE All clothing contaminated with chlorates s D A N G E R O U SL Y FLA M M A B LE . Remove and wash thoroughly with water. Do not get on floor. Spillage may cause fires with combustible material. Sweep up and remove Immediately. When not in use keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. FOR PACKAGES O F AGRICULTURAL CH LORATES, ADD: Keep Animals O ff Freshly Treated Areas T he label m u st be se cure ly affixed to th e exterior o f each package. Litho graphed or tram fer label are preferred. 50 1 i l Oo Mu>uI*cftflA| Owmias Austin Manuil L 2 SODIUM BICHROMATE W ARNING! HARM FUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP C O N TAIN ER CLOSED. Avoid breathing dust or solution spray. Avoid contact with skin or eyes. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. SODIUM FLUORIDE W ARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust. Rush spillage to sewer with water. IR THE CASE O F PR O PRIET ARY COMPOUNDS W HERE FORM ULA DISCLOSURE IS N OT MADE ON TH E LABEL, Name of Product Contains Fluorine Compounds W ARN IN G ! PO ISO NO U S IF TA K E N Avoid breathing dust. Flush spilage to sewer with water. IN T E R N A L L Y N O T E , A ll inorganic fluo rine co m p o und to ld fo r in tectktdal use which are acutely to xic to mnn ih o u ld be colored. SODIUM HYDROSULFITE CA U TIO N I SUBJECT TO FIRE IF ALLOW ED TO BECOME DAMP Keep container tightly closed. Use only dry, clean utensils in handling Store in a cool, dry place. 51 Mm u U Miiuhauimf CkcauBt Anoclsrion of the United Sacci SODIUM SULFIDE (Granular] DANGER! CONTACT W ITH A C ID LIBER A TES POISONOUS G A S BURNS SKIN AND EYES FLAMMABLE EXPOSURE M A Y CAU SE FIRE OR CREATE FIRE H A ZA R D Avoid breathing dust. Avoid contact with skin and eyes. Keep container closed and away from acids, com* bustible materia! and heat. Sweep up spillage. Do not flush to sewer which may contain acid. STYRENE M O NO M ER W ARNING! VAPOR H A RM FU L Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. DRUM LABEL SULFUR CHLORIDE DANGER! CAUSES BURNS VAPOR IRRITATIN G Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. DRU M H A N D LIN G A N D ST O RA G E Keep plug up to prevent leakage. Keep drum out or sun end away from heat. RaFlav# internal pressure when received and et least weekly thereafter by slowly lessening plug ReKghten immediately Never use pressure to empty Keep lights, fire and sparks away from drum openings Drum must not ba washed out or used for other purposes Replace plug after each withdrawal and return with empty drum In case of spillage, flush with L A R G E V O L U M E of wafer. S2 ( . o MiuifKiM,e| Qiaid United CARBO Y LABEL SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do net get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. CARBO Y H A N D LIN G A N D STORAGE Before moving carboy be sure closure is securely fastened. Loosen closure carefully. Keep out o f sun end away from heat, Naver use pressure to empty. Completely drein carboy before returning. In case of spillege, flush with plenty o f water _____________________ DRUM LABEL SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not get n eyes, on skin, on clothing, in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gat medical attention. Do not add water to contents white in a container because of violent reaction. DRUM H A N D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out of sun end away from heat Relieve internal pressure whan received end et least weekly theraaftar by slowly loosening plug. Retighten Immediately. Never use pressure to empty. Keep lights, the and sparks away from drum openings. Drum must not be washed out or used for other purposes. Raplace plug after each withdrawal and return with empty drum. In case of spillage, flush with plenty of water. 53 M in a i L-2 Manual L-a 'C Chtsum Altoat Vttiifi Sora SULFUR DIOXIDE (Under Pressure) W ARNING! EXTREM ELY IR RIT A TIN G G A S A N D LIQ U ID Avoid breathing gas. Do not drop cylinder. Do not allow cylinder temperature to reach I30'F. TETRACHLOROETHANE DANCER! VAPOR EXTREMELY HAZARDOUS VOLATILE LIQUID POISON ^ Use only in completely enclosed system. Do not breathe vapor. D o not get on skin or clothing. Do not take internally. TETRACHLOROETHYLENE (PERCHLORETHYLENE) W A RN IN G l VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. TOLUENE (TOLUOL) W ARNING! FLAM MABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 54 ( ! i O O ! *dai Chtiaixi Auodauoa Manaal L-2 m-TOLUIDINE W ARNINGl HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SK IN Avoid contact with skin and clothing. D o not breathe vapor Use with adequate ventilation. In ease of contact, immediately wash thoroughly with soap and plenty of water; remove and wash clothing before re-use. TRICHLOROETHYLENE W ARNINO! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor Avoid prolonged or repeated contact with skin. D o not take Internally. TRICHLOROPHENOL (F or all isom eric Trichora phenols) CAUTION! M A Y CAU SE SK IN IRRITATION Avoid prolonged or repeated contact. Do not take internally. VINYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor 55 MtRQ) L-2 Minljctu(if| Cbcffliui AuedKian oi ih Uwiri Sum XYLENE (XYLOL) W ARNING! FLAM M ABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation, Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ZINC CHLORIDE (Granular, Fused or Solution) CAUTION! M A Y CAU SE SK IN IRRITATIO N Avoid prolonged or repeated contact. 54 ( ( o o u o M i^ .aun n i Cherniy. ou,! of chc Uonrt Sutn M aruil L-t MANUAL L>2 INDEX M any o f the product lifted in th u index do not appear specifically m the Jn6el listings. T h e labels applicable to tuch products are indicated by the crott-referen ce " i./.n." (sam e label a i-- ) . Acetaldehyde Acetic Acid Glacial Carboy Drum 80% 5 6 % and 7 0 % 28% Acetic Anhyride Acetone Acetonylacetone Acetyl Chloride Acrylonitrile Aliyl Alcohol Ally! Chloride Ammonia, Anhydrous Aqua Carboy Drum Ammonium Bichromate Ammonium Hydroxide-- See Ammonia, Aqua Amyl Acetate Aniline O'Armidine p-Anisidine Antimony Trichloride Aromatic Industrial Solvent Arsenic Trichloride . -- B-- Barium Hydroxide-- s.la. Barium Oxide Barium Nitrate Barium Oxide Barium Peroxide Benzene . 57 12 12 . 12 _ 13 (3 13 14 14 14 14 15 16 16 . 16 17 18 16-17 . 18 . 18 19 19 19 19-20 20 21 20 21 21 21 Minai] L*2 Mmufutufifn Chnitu Auomiton ol rt* fiutd Suif Benzidine 21 Benzol-- See Benzene . . 21 Benzoyl Chloride 22 Benzyl Chloride Carboy 22 Drum 22 Bichloride of Mereury-r-See Mercury Bichloride 36 Bichromates-- See Sodium Bichromate 51 Bromine 23 Butyl Acetate (Normal) 23 Butyl Alcohol Normal or Secondary 23 Tertiary 23 Butylamine (Normal) 24 P'tert, Butylcatechol 24 Butyl Chloride (Normal) 24 Butyl Ether (Normal) 24 Butylidene Acetone-- s.I.a. Butyl Acetate 23 Butyraldhyde-- s.I.a. Ethyl Acetate ' 31 -- C-- Calcium Cyanide 25 Carbon Disulfide 25 Carbon Tetrachloride 25 Caustic Potash-- s 1a. Caustic Soda 26 Caustic Soda 26 Chlorinated Diphenyl-- s.I.a. Chlorinated Naphthalene 25 Chlorinated Diphenyl Oxide-- s.I.a, Chlorinated Naphthalene 25 Chlorinated Naphthalene . 25 Chlorobenzene, Mono 26 Chloroform 26 Chlorophenol, Mono, Ortho, Meta, or Para-- s.I.a. Phenol 47 Chlorotoluene, Mono 27 Chromates and Bichromates of Sodium end Potassium See Sodium Bichromate 51 Chromic Acid 27 Coal Ter Creosote 27 Corrosive Sublimate-- See Mercury Bichloride 38 Creosote O il- S e e Coal Tar Creosote 27 Cresol 29 Cresylic Acid-- See Cresol 29 Cyanides, Inorganic 28 Cyclohexane 29 5 Go * (\ K'iiuf Cyelohexanol Cyclohexanone-- s.l a. Cyelohexanol -- D-- Diacetone Alcohol-- s.I.a. Ethyl Acetate Dichloroethylene Dichloroethyl Ether Dichlorophenol Diethylamine f,4-Diefhylene Dioxide-- See Dioxane Diethylenetriemine-- s.I.a. Morpholine Diisobutyl Ketone-- s.I.a. Butyl Acetate Dimethylanilme-- s.I.a. Aniline Dioxane Dipropyl Ketone-- $.l.a. Butyl Acetate ---CE-- Ethyl Acetate Ethyl Acetoacetate-- s.I.a. Butyl Acetate Ethyl Bromide Ethyl Butanol-- s.I.a. Butyl Acetate Z-Ethyibutyl Acetate-- s.I.a. Butyl Acetate 2*Ethylbutyra!dehyde-- s.l.a. Ethyl Acetate Ethyl Chloride Ethylene Chlorohydrin Ethylenediamine-- s.I.a. Morpholine Ethylene Dibromide Ethylene Dichloride Ethylene Glycol Monomethyl Ether Ethyl Ether Ethyl Formate 2-Ethyihexanol-- s.I.a. Butyl Acetate 2-Ethylhexyl Acetate-- s l.a. Butyl Acetate Ethyl Methacrylate Monomer Formaldehyde Formic Acid Barrel Carboy -- F-- 59 Mmul L 2 29 29 31 29 30 30 30 31 42 23 18 31 23 31 23 31 23 23 3t 31 32 42 32 32 33 33 33 23 23 33 34 34 _ 35 M tQ ua l uiiauntif Chemin, itrinn ni At tlcied $! -- G-- Glycol Diacetate-- *J.a Butyl Acetate Glycol Diformate-- s.I.a. Butyl Acetate -- H-- Heptanoi-2-- j.l a. Butyl Acetate Hexanol-- s.I.a. Butyl Acetate Hydrochloric Acid . Hydrocyanic Acid, Liquid Hydrofluoric Acid Aqueous Hydrogen Peroxide Stronger than 25 volume andnot exceeding 25 Volume 130 volume Industrial Petroleum Naphthas and Solvents See Petroleum Naphthas and Solvents, Industrial Industrial Solvent, Aromatic Inorganic Cyanides (See Cyanides, Inorgenic) Isophorone-- s l.a. Butyl Acetate Lead Acetate Litharge-- s.l a. LeadAcetate -- M-- Maleic Anhydride Mercuric Chloride-- SeeMercury Bichloride Mercury Bichloride Mesityl Oxide-- s.La. Butyl Acetate Methyl Acetoacetate-- s l.a. Butyl Acetate Methyl Amyl Acetate-- *.La. Methyl n-Amyl Ketone Methyl Amyl Alcohol-- s.I.a. Methyl n-Amyl Ketone Methyl n-Amyl Ketone Methyl Bromide Methyl iso-Butyl Ketone-- sJ.a. Methyl Ethyl Ketone Methyl Cyclohexanol-- s.I.a. Cyclohexanol Methyl Cyclohexanone-- s.La. Cyclohexanol Methylene Chloride Methyl Ethyl Ketone 0 23 23 23 23 35 35 37 36 37 45-46 19-20 28 23 38 38 38 38 38 23 23 38 38 38 3? 40 2? 29 39 40 ( ( GO o O rafa Manual L 2 Methyl Methacrylate Monomer _ Methyl Morpholine-- s.I.a. Morpholine Methyl iso-Propyl Ketone Mixed Acid (Sulfuric and Nitric) Carboy Drum Monochlorobenzene-- See Chlorobenzene, Mono Monochlorophenol-- s.I.a. Phenol Monochlorotoluene-- See Chlorotoluene, Mono Mononitrophenol-- See Nitrophenol, M ono Morpholine Muriatic Acid -- See Hydrochloric Acid -- N-- Naphthas, Industrial Petroleum, and Solvents See Petroleum Naphthas and Solvents a-Naphlhylamine (containing 5 % b-Napbthylamine) s.I.a. b-Naphthylamine b-NaphthyUmine . ~ Nitric Acid Carboy Drum m-Nrtroamfine p-Nitroaniline-- s La. m-Ntroaniline Nitrobenzene-- s i a. Aniline m -Ntro-p-Anisdine-- s.l.a. m-Nitroaniline p-Nitro-e-Toluidine-- s.I.a. m-Nitroaniline Nitrophenol, M ono -- O-- Oil of Vitriol-- See Sulfuric Acid Oil Solutions of Pentachlorophenol-- See Pentachlorophenol, O il Solutions of Oleum Oxalic Acid -- P-- Paraldohyde Pentachlorophenol Oil Solutions of Perchlorethylene-- See Tetrachloroethylene 40 42 40 41 41 26 47 27 43 42 35 45-46 42 42 42 43 _ 43 43 18 43 43 43 53 45 44 44 44 45 45 54 Mu>ul L-$ of (he Unite Petroleum Naphthas and Solvents, Industrial o-Phenetidine-- s l.a, p-Phenetidine p-Phenetidine Phenol p-Phenyknediamine Phosphoric Acid Phosphoric Anhydride Phosphorus Phosphorus Oxychloride Phosphorus Pentachloride Phosphorus Trichloride-- sj.a. Phosphorus Oxychloride Potassium Chlorate-- s ia . Sodium Chlorate Potassium Chromate and Bichromate-- See Sodium Bichromate Potassium Hydroxide-- s.I.a. Caustic Soda iso-Propyl Acetate Propylene Chlorohydrin-- s.I.a. Ethylene Chlorohydrm isopropyl Ether-- s.I.a. Ethyl Ether Pyridine . . 45-46 46 46 47 47 47 48 48 49 48 49 50 51 26 49 32 33 49 -- s-- Sample-- Label tor Experimental Products Silver Nitrate Sodium Chlorate Sodium Bichromate Sodium Fluoride Sodium Hydrosulfte Sodium Hydroxide-- See Caustic Soda Sodium Orthosilicate-- s.I.a. Caustic Soda Sodium Sesquisiiicat^--s.I.a. Caustic Soda Sodium Sufftiydrate-- s.l a. Sodium Sulfide Sodium Sulfide (Granular) Solvents Aromatic Industrial Industrial Petroleum Naphthas and Solvents Styrene Monomer . Sulfur Chloride Sulfur Dichlorlde-- s.I.a. Sulfur Chloride Sulfur Dioxide Sulfuric Acid Carboy Drum Sulfuryl Chloride-- s.I.a. Sulfur Chloride 50 50 50 51 51 51 26 26 26 52 52 19-20 45-46 52 52 52 54 53 53 52 62 G iG ! ion of eh Unirai Sisifi M tn u n l L-2 Tar Acids-- s.I.a. Cresol Tetrechioroethane Tetrachloroethylene Tetrachlorophanol-- s.I.a. Pentachlorophenol Tetraethylenepentamme-- sia . Morpholine Thionyl Chloride-- sJ.a. Sulfur Chloride Toluene m-Toluidine o-Toluidine-- s.I.a. m-Toluidine p-Toluidine-- s.I.a. m-Toluidine Toluol-- See Toluene _ Trlchloroethykne Trichlorophenol Triethyknetetramine-- s.I.a. Morpholine . Trimethylcydohexanof-- s.I.a. 8utyl Acetate -- V-- Vinyl Chloride -- X-- Xylene Xylidines-- tJ.a. m-Toluidin* Xylol-- See Xylene -- z-- Zinc Chloride (Granular, Fused or Solution) 29 54 54 45 42 52 54 55 _ 55 55 54 55 55 42 23 55 56 55 56 56 Includine U l Mid U t, U tupelM hy Clwailtte AMxclaltoB at ih* Unltod SUWi Ml Woodwtld Dullilot WniMapton 5 D C. HRINTbO IN V I A 63