Document k6pmwGr17KVaJe1VLa5RkDk60

< PAGE 1 'H MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 1914) 347-4700 EMERGENCY PHONE NUMBER (800) 888-8372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME)i IRGANOX B 225 FAMILY/CHEMICAL NAME: TETRAKIS(METHYLENE!3,5-DI-TERT-BUTYL-4-HYDR0XYHYDR0CINNAMATE) ) METHANE CAS. REG. NO. 6683-19-8 AND TRIS(2,4-DI-TERT~ BUTYLPHENYL)PHOSPHITE CAS REG. NO. 31570-04-4 AND IRGAFOS 168, 1:1 BLEND). PRODUCT TYPE: (IRGANOX 1010 ANTIOXIDANT/STABILIZER. IMPORTANT: PLEASE NOTE: REVISION 05 - SECTION X REVISED. xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X X FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR * x ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THEWIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE x x TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx HAZARD STATEMENT : xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX SECTION II-HAZARDOUS INGREDIENTS IRGANOX B 225 00 086931 CONFIDENTIAL c PAGE 2 NONE KNOWN SECTION III-PHYSICAL DATA APPEARANCE. WHITE TO OFF-WHITE POWDER. ODOR. NO DISCERNABLE ODOR. BOILING POINT. NOT DETERMINED. MELTING POINT. 110-125C IRGANOX 1010; 181-186C DECOMPOSITION TEMPERATURE. >220C. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. < 0.5`/.. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE. AT 20C, CA. 1 X 10(-12) IRGANOX 168 (MM HG) SOLUBILITY IN WATER. AT 20C, INSOLUBLE PH. NOT APPLICABLE. SPECIFIC GRAVITY: NOT DETERMINED. IRGAFOS 1010; 1 168. X 10(-10) IRGAFOS SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. >302F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER: NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. NFPA CODE. HI FI RO EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS. THE PRODUCT CAN FORM AN EXPLOSIVE DUST/AIR MIXTURE. AVOID DUST FORMATION AND CONTROL IGNITION SOURCES; EMPLOY GROUND ING, VENTING AND EXPLOSION RELIEF PROVISIONS IN ACCORD WITH ACCEPTED ENGINEERING PRACTICES IN PROCESS OPERATIONS CAP ABLE OF GENERATING DUST AND/OR STATIC ELECTRICITY. IRGANOX B 225 O86930 C0NFroNTrAi PAGT 3 SECTION V-REACTIVITY DATA STABILITY * STABLE. INCOMPATIBILITY. STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND PHOSPHORUS OXIDES. HAZARDOUS POLYMERIZATION. WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE. DERMAL, INGESTION, AND INHALATION. THRESHOLD LIMIT VALUE. NONE ESTABLISHED. ORAL LD50: (RATS) >5000 MG/KG FOR BOTH COMPONENTS INTRAPERITONEAL LD50. (RATS) >2000 MG/KG FOR IRGAFOS 168 SKIN IRRITATION. (RABBITS) NONE (DRAIZE SCORE 0/8) FOR BOTH COMPONENTS EYE IRRITATION. (RABBITS) NONE (DRAIZE SCORE 0/110) FOR BOTH COMPONENTS SENSITIZATION. (GUINEA PIGS) NO SENSITIZATION OBSERVED FOR IRGAFOS 168. RIPT (HUMANS) NOT A PRIMARY IRRITANT AND NO EVIDENCE OF SENSITIZATION UNDER THE CONDITIONS OF THE STUDY FOR IRGANOX 1010. INHALATION LC50. (RATS) >A6MG/L AIR FOR A 1-HOUR DUST EXPOSURE TO IRGANOX 1010. IRGAFOS 168 NOT TESTED. TERATOGENICITY. (RATS AND MICE) NO TERATOGENIC EFFECTS (IRGANOX 1010). (RABBITS) NO EVIDENCE OF TERATOGENICITY (IRGAFOS 168). MUTAGENICITY. IRGANOX 1010. AMES TEST. NEGATIVE DOMINANT LETHAL (MICE). NO EVIDENCE OF A DOMINANT LETHAL EFFECT. NUCLEUS ANOMALY TEST (CHINESE HAMSTERS). NEGATIVE. CHROMOSOME STUDIES IN SOMATIC CELLS (CHINESE HAMSTERS). NEGATIVE. IRGAFOS 168. AMES TEST. NEGATIVE CHROMOSOME STUDY, SPERMATOGONIA/SPERMATOCYTES (MOUSE). NO EVIDENCE OF MUTAGENICITY. SISTER CHROMATID EXCHANGE STUDY (CHINESE HAMSTER). NEGATIVE. SACCHAROMYCES CEREVISIAE MP-1. NEGATIVE IRGANOX B 225 D0 086933 confidential PAGE A CHROMOSOME STUDY IN SOMATIC CELLS (CHINESE HAMSTER)> NEGATIVE. DOMINANT LETHAL STUDY (MOUSE)i NEGATIVE. NEUROTOXICITY: WHITE LEGHORN STRAIN: NO SIGNS OF NEUROTOXICITY FOR IRGAFOS 168. SIGNS AND SYMPTOMS OF EXPOSURE-ACUTE: NO IDENTIFIED HEALTH EFFECTS. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC: NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN. EMERGENCY AND FIRST AID PROCEDURES-EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN: WASH WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION: IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION< REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER: WASH CONTAMINATED CLOTHING PRIOR TO REUSE. SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES: SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. THOROUGHLY FLUSH RESIDUE WITH WATER. WASTE DISPOSAL METHODS: INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-COD: 2.38 G COD/G IRGANOX 1010 FISH TOXICITY: IRGANOX 1010: ZEBRA FISH, LC50 96 H: >100 PPM IRGAFOS 168: ZEBRA FISH, LC50 96 H: 4.05 PPM GOLDEN ORFE, LC50 96 H: 42 PPM RAINBOW TROUT, LC50 96 H: 49 PPM CARP, LC50 96 H: 66 PPM CATFISH, LC50 96 H: 70 PPM BLUEGILL, LC50 96 H: 84 PPM INVERTEBRATE TOXICITY: DAPHNIA MAGNA, EC50 24 H: >86 PPM FOR IRGANOX 1010 ________________________ SECTION VIII-SPECIAL PROTECTION INFORMATION _ VENTILATION: USE LOCAL EXHAUST. PROTECTIVE GLOVES: WEAR GLOVES AS A STANDARD HANDLING PROCEDURE. IRGANOX B 225 086934 CONFTDPNTTAI PAGE 5 EYE PROTECTIONi WEAR SAFETY GLASSES OR GOGGLES TO PROTECT AGAINST DUST PARTICLES. RESPIRATORY PROTECTIONi USE NIOSH APPROVED DUST MASK, IF REQUIRED. OTHER PROTECTIVE EQUIPMENTi WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HMIS CODEi HEALTH . 1 FIRE . I REACTIVITY 0 HANDLING PRECAUTIONSt IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, HANDLE WITH CARE AND AVOID UNNECESSARY PERSONAL CONTACT. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST. USE ONLY WITH ADEQUATE VENTILATION . FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENE: WASH THOROUGHLY AFTER HANDLING. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION CDOT) 49 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASS: NONE. DOT NUMBER: NONE. RCRA STATUS: NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). CERCLA STATUS: NOT LISTED. SARA/TITLE III - TOXIC CHEMICALS LIST: THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 313 (40 CFR 372). TSCA INVENTORY STATUS: CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING : CHEMICAL NAME : TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE CAS NUMBER = 31570-04-4 IRGANOX B 225 TMNF7DFNtFA|. PAGE 6 XXX `<i CHEMICAL NAME TETRAKIS(METHYLENE(3,5-DI-TERT-BUTYL-4-HYDR0 OXYHYDROCINNAMATE)} METHANE CAS NUMBER 6683-19-8 XXX CHEMICAL NAME . PENTAERYTHRITOL TRIS ESTER WITH 3-(3,5~DI-TE RT-BUTYL-4-HYDR0XYPHENYL)PROPIONIC ACID CAS NUMBER i 84633-54-5 PERCENT < IMPURITY XXX PENNSYLVANIA RIGHT-TO-KNOW ACT: THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME CAS NUMBER COMMON NAME COMMENTS CHEMICAL NAME CAS NUMBER COMMON NAME COMMENTS PHENOL, 2,4-BIS(1,1-DIMETHYLETHYL)-, PHOSPHI TE (3:1) 31570-04-4 TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE; IRGAFOS 168 NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. XXX BENZENEPROPANOIC ACID, 3,5-BISC1,1-DIMETHYLE THYL)-4-HYDROXY-, 2,2-BIS((3-(3,5-BISC1,1-DI METHYL ETHYL)-4-HYDR0XYPHENYL}-l-0X0PR0P0XY)M ETHYL}-1,3-PROPANEDIYL ESTER 6683-19-8 TETRAKIS(METHYLENEC3,5-DI-TERT-BUTYL-4-HYDR0 XYHYDROCINNAMATE)JMETHANE; 3,5-DI-TERT-BUTYL-4-H YDROXYHYDROCINNAMIC ACID, NEOPENTANETETRAYL ESTE R; PENTAERYTHRITOL TETRAKIS(3,5-DI-TERT-BUTYL-4HYDROXYHYDROCINNAMATE); IRGANOX 1010 NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. xxx ISSUE DATE: 04/05/90 REVISION: 07C ISSUED BY: B. SCHWEMMER FOR FURTHER INFORMATION, PLEASE CONTACT: BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. IRGANOX B 225 D0 086936 CONFIDENTIAL