Document k6d9GaqmjG9L1rwey5wYqo5kD

jJm. ?V^y I Shell MATERIAL SAFETY DATA S736: I* f5) MSDS NUMBER t r 7 2Q1 / *5 I PAGE 1 24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL' 713-241-4819 iCJT HE A.71- -1 f|ft On 2 \ A\ 3 1 REACTIVITY 1 'j3 'iHAZARD RAT,NG k. tTME AS,T - ,P E,S-;i5RHET. . MODERATE - 2 For acute and chronic health effects refer to the discussion in Section III /be safe\ READ OUR PRODUCT iAFETT INFORMATION . AND i rass rr ON j \ IHOOOXCOTY;WlAJJil''.r|. S / SECTION 1 PRODUCT ^ NEODENE (R) 6/12 ALPHA OLEFIN BLEND NAME Q gy yg CHEMICAL wHEXENE-1 . DODECENE-1 NAME V ^FAMILY1 ^ LINEAR ALPHA OLEFIN SECTION II-A NO. PRODUCT/INGREDIENT COMPOSITION P NEODENE 6/12 ALPHA OLEFIN BLEND 1 ce 2 C 12 CAS NUMBER MIXTURE 592-41-6 1.12-41-4 PERCENT 100 20-50 50-80 SECTION II-B NO- ACUTE ORAL LD50 P NONE ESTABLISHED 1 >5.6 G/KG - RAT 2 >5.0 ML/KG - RAT 3 NONE ESTABLISHED ACUTE TOXICITY DATA ACUTE DERMAL LD50 >2.0 G/KG - RABBIT >2.0 ML/KG - RABBIT ACUTE INHALATION LC50 NOT AVAILABLE NOT AVAILABLE SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT PRODUCT IS IRRITATING TO THE EYES- SKIN CONTACT PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED LIOUID CONTACT CAN RESULT IN DEFATTING AND DRYING OF THE SKIN WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS. INHALATION PRODUCT IS PRESUMED TO HAVE A LOW ORDER OF ACUTE INHALATION TOXICITY. INGESTION PRODUCT IS PRESUMED TO BE SLIGHTLY TOXIC, BUT INGESTION MAY RESULT IN VOMITING; ASPIRATION (BREATHING) OF VDMITUS INTO THE LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES MAY RESULT IN A5PIRAT ION PNEUMONITIS- SAL 000009974 PRODUCT NAME: NEODENE(R) 6/12 ALPHA OLEFIN BLEND Q g 1^ y g MSOS 7,291 PAGE 2 SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. ASPIRATION PNEUMONITIS MAY BE EVIDENCED BY COUGHING ANP CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR. LABORED BREATHING AGw.AVATED MEOICAL CONDITIONS PREEXISTING SKIN AND EYE DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV OCCUPATIONAL EXPOSURE LIMITS OSHA NO. PEL/TWA PEL/CEILING TLV/TWA ACGXH TLV/STEL P- SHELL INTERNAL STANDARD - 100 PPM OTHER SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING OR SHOES UNTIL THOROUGHLY DECONTAMINATED. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. 2NQESTION JOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY. KEEP HEAD BELOW HIPS TO PREVENT A_. IRATION OF L20UJD INTO THE LUNGS. GET MEDICAL ATTENTION. NOTE TO PHYSICIAN NOTE TO THE PHYSICIAN: IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED. EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX. CONVULSIONS DR UNCONSCIOUSNESS OCCUR BEFORE EMESIS. GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. SECTION VI NONE IDENTIFIED. SUPPLEMENTAL HEALTH INFORMATION SECTION VII BOILING POINT: 145-419 (DEG F) MELTING POINT: -33 DEG F (DEG F) PHYSICAL DATA SPECIFIC GRAVITY: 0.735 (H20*1) 60 DEG. F SOLUBILITY; (IN WATER) INSOLUBLE SAL 000009975 Tfife VAPOR PRESSURE: 3.0 P (MM HG) 100 DEG. F VAPOR DENSITY: 4.86 (AIR=1 ) PRODUCT NAME: NEOOENE(R) 6/12 ALPHA OLEFIN BLEND EVAPORATION RATE (N-BUTYL ACETATE 1): NOT AVAILABLE APPEARANCE AND ODOR: COLORLESS LIQUID. MILD HYDROCARBON ODOR. MSDS PAGE LB/GAL . 11 7,29 ` 3 GS 773 SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: -14 DEG. F C SET AF LASH) FLAMMABLE LIMITS /% VOLUME IN AIR LOWER: 1 UPPER: 8 EXTINGUISHING MEDIA WATER FOG OR FOAM TO FIGHT LARGE FIRES. DRY CHEMICAL OR C02 EXT INGUIS^ERS ON SMALL FIRES. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WARNING. FLAMMABLE. CLEAR FIRE AREA OF UNPROTECTED PERSONNEL- DO NOT ENTER CONFINED FIRE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS . COOL FIRE CONTAINERS WITH WATER. SPACE EXPOSED UNUSUAL FIRE AND EXPLOSION HAZARDS CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO DIRECT FLAME CONTAC" SHOULD BE COOLED WITH LARGE QUANTITIES OFWATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT, SPARKS. FLAME AND CONTACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. PROTECTIVE CLOTHING AVOID CONTACT WITH EYES. WEAR SAFETY GLASSES OR GOGGLES AS APPROPRIATE. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICAL RESISTANT GLOVES AND OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR EMERGENCY USE. EYE WASH FOUNTAINS SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES WARNING. FLAMMABLE. ELIMINATE ALL IGNITION SOURCES- HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. *** LARGE SPILLS ** EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL- WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. IF `VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS; CONTAIN RUN-OFF. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT .SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. SAL 000009976 CrS773PRODUCT NAME: NEODENE(R) 6/12 ALPHA OLEFIN BLEND MSDS PAGE 7,291 4 FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE: DISPOSE OF FLUSH SOLUTIONS AS ABOVE. SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS: SEAL TIGHTLY FOR PROPER DISPOSAL. SECTION XIX SPECIAL PRECAUTIONS KEEP LIQUID AND VAPOR AWAY FROM HEAT. SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIOUID PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS. CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION PRIOR TO USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM THE HANDLING SITE; FLASH-FIRE CAN RESULT. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE (ONLY) WITH ADEQUATE VENTILATION. CONTAINERS. EVEN THOSE THAT HAVE BEEN EMPTIED. CAN CONTAIN EXPLOSIVE VAPORS- DO NOT CUT, DRILL. GRIND. WELD OR PERFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. 00 NOT PRESSUR12E DRUM CONTAINERS TO EMPTY THEM. STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EQUIPMENT. BOND AND GROUND TRANSFER CONTAINERS AND EQUIPMENT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING. SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. SECTION XIII TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FLAMMABLE LIQUID D.O.T. PROPER SHIPPING NAME: PETROLEUM OIL, N.O.S. SR REQUIREMENTS: l ID NUMBER NA 1270. SECTION XIV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III. SECTION 313, THE ENVIRONMENTAL DATA SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. SECTION XV STATE REGULATORY INFORMATION SAL 000009977 PRODUCT NAME: NEDDENE(R) 6/1? ALPHA OLEFZN BLEND NSDS PAGE 7,281 S THIS INFORMATION IS BEING SYSTEMATICALLY ADDED TO OUR MSDS. IT HAS PREVIOUSLY BEEN PROVIDED TO YOU IN VARIOUS WAYS. INCLUDING THE MSDS. THE NEW MSDS FORMAT IS INTENDED TO PROVIDE THE USER WITH THE I NFORMATI ON IN A MORE CONVENIENT MANNER. G S7 78 SECTION XVI SPECIAL NOTES SEE ENVIRONMENTAL DATA SHEET FOR WASTE DISPOSAL AND OTHER ENVIRONMENTAL INFORMATION THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT HOWEVER. SHELL MAKES NO WARRANTY. EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RE5ULT5 TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:JUNE A3, 1&90 BE SAFE READ OUR PRODUCT SAFETY INFORMATION ...AND PASS IT ON (PRODUCT LIABILITY LAW REQUIRES IT) d. C. WILLETT SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210 000009978 SAL A Shell ENVIRONMENTAL DATA SHEET S?US (9-8?) EDS NUMBER 7,291 PAGE 1 PRODUCT )NEODENE(R) 6/12 ALPHA OLEFIN BLEND PRODUCT k CODE f 31337 G S7 73 SECTION I NO. PRODUCT/COMPOSITION COMPONENT P NEODENE 6/12 ALPHA OLEFIN BLEND 1 C6 2 C12 CAS NUMBER MIXTURE 592-41-6 112-41-4 PERCENT 100 20-50 50-80 SECTION II NO. EHS RQ (LBS) (-1) SARA TITLE III INFORMATION EHS TPQ (LBS) ( "2 ) SEC 313 (-3) 313 CATEGORY ( *4 ) P 311/312 CATEGORIES (*5 ) H- 1 . P-3 nnTNDTFC----------------------------- 1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 -2 * THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302 *3 * TOXIC CHEMICAL, SEC 313 *4 * CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM "5 = HAZARD CATEGORY FOR SARA SEC. 311/3T2 REPORTING HEALTH H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD H-2 = DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 = FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD P-5 = REACTIVE HAZARD SECTION III ENVIRONMENTAL RELEASE INFORMATION KEEP OUT OF SURFACE WATERS, SEWERS, AND WATERWAYS ENTERING OR LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO THE GENERAL PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR. SECTION IV RCRA INFORMATION UNDER EPA - RCRA (40 CFR 261.21), IF THIS PRODUCT BECOMES A WASTE MATERIAL, IT WOULD BE IGNITABLE HAZARDOUS WASTE. HAZARDOUS WASTE NUMBER DO01. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. SAL 000009979 PRODUCT NAME: NEODENE(R) 6/12 ALPHA OLEFIN BLEND G S77S EDS FACE 7,291 2 INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER. SHELL MAKES NO WARRANTY. EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NQ RESPONSIBILITY FDR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED;JUNE 13, 1990 .............................................. SHELL OIL COMPANY ENVIRONMENTAL AFFAIRS P. 0. BOX 4320 HOUSTON. TX 77210 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241-2252 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461 CHEMTREC: (800) 424-9300 SAL 000009980