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CONOCO Material Safety Data Sheet Page MATERIAL IDENTIFICATION CONDENSATE M8DS NUMBER : GASC0065 Revision Date Date Printed i 15-Apr-92 : 15--Apr--92 MANUFACTURER/DISTRIBUTOR Conoco, Inc. P.0. Box 2197 Houston, TX 77252 PHONE NUMBERS GENERAL INFORMATION TRANSPORT EMERGENCY MEDICAL EMERGENCY : 1-(713)293-5550 : l-(800)424-9300 : l-(800)441-3637 CHEMICAL FAMILY s Petroleum Hydrocarbon TRADE NAMES / SYNONYMS Casinghead Gasoline Natural Gasoline 0202, 0230 CAS NUMBER NFPA RATINGS NPCA-HMIS RATINGS : 64741-47-5 s Health: 1 Flammability: 4 Reactivity: 0 : Health: 2 Flammability: 4 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. OSHA HAZARD DETERMINATION Hazardous Inaredients Condensate containing Hydrocarbons (Aromatic & Paraffinic) * Toluene * Xylenes * Benzene CAS Number 64741-47-5 MIXTURE 108-88-3 1330-20-7 71-43-2 * Regulated as a Toxic Chemical under Section 313 of Title III of the Superfund Amendments and Reauthorization Act Of 1986 and 40 CFR part 372. 100 >70 <15 < 12 0. 1-5 MCD 000023108 MSDS MO. GASC0065 CONOCO Material Safety Data Sheet Page PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density % Volatiles water solubility Odor Porn Color Speeifio Gravity -20 to 600 deg F 200-500 mm Hg at 68 deg F >1 (Air = 1.0) Variable Insoluble Gasoline Liquid Colorless 0.6-0.8 HAZARDOUS REACTIVITY Instability Incompatibility Decomposition Polymerization Stable. Incompatible with oxidizing materials. Avoid heat, sparks, and flame. Carbon monoxide may be formed from incomplete combustion. Polymerization will not occur. FIRE AMD EXPLOSION DATA Flash Point Method Flammable Limits LEL DEL Autoignition s As low as -50 F : PMCC in Air, % by volume x< l : 10 : As low as 450 F FIRE_ AND EXPLOSION HAZARDS Vapor forms explosive mixture with air. Vapors or gases may travel considerable distances to ignition source and flash back. Class IA Flammable Liquid (NFPA). EXTINGUISHING MEDIA Foam. Dry Chemical. C02. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential ignition. Unusual Fire and Explosion Hazards: Highly Flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including MOD 000023109 MSDS MO* GASC0065 CONOCO Material Safety Data Sheet (FIRE AND EXPLOSION DATA - Continued) respiratory protection. HEALTH HAZARD INFORMATION Acute Toxicity Data - None Available Other Toxicity Data Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. Animal studies with toluene have failed to demonstrate birth defects in rats and mice. However, toluene has been shown to cause delayed growth and extra ribs in the offspring of rats and mice at inhaled doses (266-399 ppm) that were nontoxic to the mother. Toluene has not been conclusively shown to cause adverse reproductive effects in humans. One published study on xylene reports limited data suggesting high oral doses caused an increase in malignant tumors in rats. However, other more extensive animal studies have demonstrated no evidence of carcinogenicity. Developmental toxicity was observed but only at concentrations that were maternally toxic. Xylene does not have selective toxicity for the developing fetus. Animal studies have shown that prolonged or repeated inhalation exposure to high concentrations of some petroleum distillates have caused liver tumors in mice and kidney damage/tumors in male rats. However, kidney effects were not seen in similar studies involving female rats, guinea pigs, dogs, or monkeys. Present studies indicate the kidney effects will only occur in male rats. Also, human studies do not indicate this peculiar sensitivity for kidney damage. The significance of liver tumors in exposed mice is highly speculative and not a good indicator for predicting a potential human carcinogenic hazard. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates Page MCD 000023110 M8D8 NO. GASC0065 CONOCO Material Safety Data Sheet Page (HEALTH HAZARD INFORMATION - Continued) were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to eyes, skin and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause lung damage or death. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Remember that good hygienic practices can be helpful in preventing adverse health effects; for example, exposure to material and its fumes can be minimized by using protective clothing or devices while contaminated skin should be washed. Intermittent or occasional skin contact with the material is not expected to have serious health effects as long as good personal hygiene measures, such as those outlined in this material safety data sheet, are followed. The real risk for any chemical exposure is related to the degree of exposure. CARCINOGENICITY The following components are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. Material Benzene IARC NTP OSHA AGGIE XXX X Du Pont controls the following materials as potential carcinogens : Benzene. APPLICABLE EXPOSURE LIMITS Toluene AEL * TLV PEL (Du Pont): (ACGIH) : (OSHA) : 100 ppm - 8 & 12 Hr. TWA 100 ppm, 377 mg/m3 - 8 Hr TWA STEL 150 ppm, 565 mg/m3 See Notice of Intended Changes (1991-92) 50 ppm, 147 mg/m3 - 8 Hr TWA, skin 100 ppm, 375 mg/m3 - 8 Hr TWA STEL 150 ppm, 560 mg/m3 MCD 000023111 MSDS NO. GASC0065 CONOCO Material Safety Data Sheet Page (HEALTH HAZARD INFORMATION - Continued) Xylenes AEL TLV PEL (Du Font): (ACGIH) : (OSHA) : 100 ppm - 8 Hr. TWA 150 ppm - 15 Min. TWA 100 ppm, 434 mg/m3 - 8 Hr TWA STEL 150 ppm, 651 mg/m3 100 ppm, 435 mg/m3 - 8 Hr TWA STEL 150 ppm, 655 mg/m3 Benzene AEL TLV PEL (Du Pont): (ACGIH) : (OSHA) : 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Min. TWA 10 ppm, A2; 32 mg/m3, A2 - 8 Hr TWA See Notice of Intended Changes (1991-92) 0.1 ppm, 0.3 mg/m3 - 8 hr TWA, skin, A1 1 ppm - 8 Hr. TWA 5 ppm - (Short term exposure limit) 0.5 ppm - Action level * AEL is Du Pont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. SAFETY PRECAUTIONS Avoid breathing vapors or mist. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Wash clothing after use. FIRST AID INHALATION If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician SKIN CONTACT In case of contact, immediately wash skin with soap and water. Wash contaminated clothing before reuse. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Immediately give two glasses of water. Never give anything by mouth to an unconscious person. Call a physician. MCD 000023112 K5D8 NO. GASC0065 CONOCO Material Safety Data Sheet (FIRST AID - Continued) NOTES TO PHYSICIAN Activated charcoal slurry may be administered. To prepare activated charcoal slurry, suspend 50 grams activated charcoal in 400mL water and mix thoroughly. Administer 5mL/kg, or 350mL for an average adult. Page PROTECTION INFORMATION GENERALLY APPLICABLE CONTROL MEASURES AMD PRECAUTIONS Keep away from heat, sparks and flames. Use of non-sparking and explosion-proof equipment may be necessary depending on type of operation. Ventilation: Storage and use areas should be well ventilated. Use fans or blowers in enclosed areas. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: A NIOSH/MSHA-approved, air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known or any other circumstances where air purifying respirators may not provide adequate protection. Protective Gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eye Protection: Goggles or face shield for spray/mists or if splashing is probable. Other Protective Equipment: Coveralls are recommended if splashing is probable. Launder contaminated clothing before reuse. SPILL, LEAK AND DISPOSAL INFORMATION SPILL. LEAK. OR RELEASE NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Soak up with sawdust, sand, oil dry or other absorbent material. Shovel or sweep up. MCD 000023113 MSD8 NO* GASC0065 CONOCO Material Safety Data Sheet Page (SPILL, LEAK AND DISPOSAL INFORMATION - Continued) Remove source of heat, sparks, flame, impact, friction or electricity including internal combustion engines and power tools. If equipment is used for spill cleanup, it must be explosion proof and suitable for flammable liquid an vapor. NOTE: Vapors released from the spill may create an explosive atmosphere. WASTE DISPOSAL Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Do not flush to surface water or sanitary sewer system. By itself, the liquid is expected to be a RCRA hazardous waste. SHIPPING INFORMATION DOT Proper Shipping Name s Gasoline Hazard Class e e Flammable liquid UN/NA No. e e UN 1203 DOT Labels(s) s Flammable liquid DOT Placard e e Flammable IATAZIMQ Proper Shipping Name 0 e Natural gasoline Hazard Class e e 3 (IMO 3.1) UN NO. s UN 1257 IMO/ICAO Label s Flammable liquid Packaging Group : II TDG Proper Shipping Name e Petroleum crude oil TDG Class PIN No. TDG Label TDG Placard 3.1 UN 1267 Flammable liquid Flammable STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. mod 000023114 MSDS NO. GASC0065 CONOCO Material Safety Data Sheet TITLE III HAZARD CLASSIFICATIONS Acute e e Yes Chronic s Yes Fire a Yes Reactivity No Pressure e No REGULATORY INFORMATION OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. CLEAN AIR ACT, 40 CFR 50, SECTIONS 112, 114 The material is not known to contain a Hazardous Air Pollutant. COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, & LIABILITY ACT (CERCLA/SUPERFUND), 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III (SARA) - SECTION 302/304 - Extremely Hazardous Substances, 40 CFR 355 The material is not known to contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances (40 CFR 710) and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261) This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If it is a hazardous waste, regulations 40 CFR 262-266 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, Section 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Page MCD 00002311& USDS NO. GASC0065 CONOCO Material Safety Data Sheet (REGULATORY INFORMATION - Continued) Ingredient : Petroleum Hydrocarbon Reportable Quantity : Film or sheen upon or discoloration of the water surface or adjoining shoreline. State Regulations CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") The material contains ingredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient : Benzene Toluene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following ingredient(s) found on the Pennsylvania Worker and Community Right-to-Know Act Hazardous Substance List: Ingredient CAS Registry Number Category Natural Gas Condensate 64741-47-5 Hazardous Substance Ingredient CAS Registry Number Category Benzene 71-43-2 Environmental Hazard Special Hazardous Substance Ingredient : Methylbenzene (Toluene) CAS Registry Number : 108-88-3 Category : Environmental Hazard Ingredient CAS Registry Number Category Dimethylbenzene (Xylene) 1330-20-7 Environmental Hazard Nonhazardous ingredient(s) information is withheld as trade secret in accordance with Section 11 of the Act. Foreign Regulations CANADIAN HAZARDOUS PRODUCT ACT (WHMIS) The material is a WHMIS Controlled Product. Class B Division 2 : Flammable Liquid. Class D Division 2A : Very Toxic Material. Chronic Toxic Effects. Carcinogen. Class D Division 2B : Toxic Material. Skin or Eye Irritant. Page MCD 000023116 KSD8 NO. GASC0065 CONOCO Material Safety Data Sheet (REGULATORY INFORMATION - Continued) Emergency Phone Number: 1-613-348-3616 ADDITIONAL INFORMATION AND REFERENCES Product Use: Blended for Motor Fuel Chemical Plant Feedstock Page l The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Responsibility for MSDS : MSDS Administrator, SHEA Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 End Of MSDS MCD 000023117