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MICROBICS MICROTOXS TOXICITY TEST TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may alsobe referredto as PFOS, FC-95, or as a component of FC-603F. (1Octanesulfonicacid)(CAS # 2795-39-3). Remarks: The 3M producton lotnumber was 501. The testsample isFC603F. Currentinformatioinndicatesitisa mixtureof0.5% PFOS, 7% diethyleneglycolbutylether,82.95% water,2% acrylifcoamer,4% Alkylether sulfate1,.45% Xanthan gum, 1.4% calciumacetate,0.07% N-(3Chloroallyl)hexaminiucmhloride0,.5% tdethanolamine,0.05% sodium hydroxide,0.03% cis-1-(3-Chioroallyl)-3,5,7-td1a-zaaz-oniaadamantane chloridea,nd 0.05% tolytriazole. The followingsummary applies to a mixture with incompletely characterizedconcentrations of impurities.Data may not accurately reflectthe toxicityof the fluorochemical component of the testsample. METHOD: Method: MicrobicsMicrotoxO "BASIC" Procedure Test type: Staticacute GLP: No Year Completed: 1994 Species: Photobacteriumphosphoreum Analyticalmonitoring:pH and osmoticcondition. Exposure period: 30-minutes Statisticamlethods: EC50 valuescalculatebdy statisticlailnearegression program providedforMicrotoxV Test organism source: Microbics'Reagent, LotAM025 Test conditions: Diluent: MilliporMeilli-QTwmater Test temperature: Not noted. Stock and testsolutionpreparation: A 2000 mg/L primarystock solutonwas prepared by dissolvin2g00 mg testsubstance in100 mL MilliporMeilli-O@wmater. The pH ofthestocksolutionwas 6.7.An osmoticadjustmentwas made using200 mg NaCi dissolvedin10 mL stocksolution.Appearance oftestsoluflonwsas noted as "clearand colodess".Alltestsolutionswere made by proportionadlilutions. Exposure vessels: 4 mL cuveftes. Number of replicates:two Number of concentrations: Four plusa blankcontrol Element basis: Percentlightloss RESULTS Nominal concentrations:Blank control1,25,250, 500, and 1000 mg/L Element value: 5-minuteECro = 480 (450 - 510) mg/L 15-minuteEC5o = 390 (370 - 420) mg/L 30-minuteEC5o = 340 (320 - 350) mg/L Element valuesbased on nominal concentrations. Remarks: Testingwas conducted on a mixtureas describedinthe Test Substance Remarks field.The values reportedapplytothatmixtureand not the fluorochemicalproportionalone. CONCLUSIONS The FC-603F 30-minute EC50 forPhotobacterium phosphoreum was determined tobe 340 mg/L witha 95% confidenceintervaolf 320 to350 mg/L. Submitter: 3M Company, Environmental Laboratory,P.O. Box 33331, St. Paul,MN, 55133 DATA QUALITY ReliabilityK:limischranking= 2.This studymeets the criterifaorquality testing.However, sample puritywas notpropedy characterizedand the study lacksanalyticaclonfirmationofthe amount offluorochemicalproportioninthe solution. REFERENCES Thisstudywas conducted by the 3M Company, EnvironmentalLaboratory, St.Paul,MN, Lab Request number Ml 655, 1994. OTHER Last changed: 6/26/00. 3M ENVIRONMENTAL LABORATORY Page I of Microtox Test Data Summary LF;LM1655 Date:5/20/94 Analyst:JM2 SAMPLE: FC-603F (Lot#501) Sample Conc. % ReducfionInBioluminescence (mg/L) 5 min 15 min 30 min 125 is 24 25 250 35 39 43 500 50 55 59 ---1000--l---68 --- ---73---- ...ZZ... EC50 480 mg/L 390 mgtl 340 mg/L (95% C.I.) (450-510) (370-420) (320-350) @m 10620 1 -0 -owo Sample Descriptlon Lab Request No. (C EnvironmentalLab - Work eet Page , -N,,\-\c,( A - -,\ \ 'L-4 't Date: Analyst: -V c of ri%A L" ct @C"N c Qc -,;cZc), c c,:\,r.-, ------------ 14 IC re :@ik t@e Ufa itt m (4 ttit, 7, @L@c.AtI., ul Wk 1g5 eonna. ruLsess, en arg TRY : ; 3 SHOE EL vga Vranas ge Sdn hele % F;A A RL i EN ad s Tt r ei hebdr Cp gn dE oly Ciba RAN SRE Ci EE 1 ai SLCSEHRTALAEE SAE ona Woe a] RR CeI Sa IS 0SelEREe ER .a NE NT a aR ase ER oO CE SEEE AES, EN, TreadiEi R oe IELRRSeSRN 2 Er mS SL me Tesi Boe mss ran Qs 37Ti. STR0TAN Lal HY i fa rE 3 Freer pogpd 5 oh sid J a i Fat Soles RShah iAiaeins LBtonho h8 eCl ORSE SlEeidenBshR Cdheps BioSlAipRnEagEge Eavmeen sdale ad ii el doD l ning an Meas es Eomae lie SAE roi Sh EL aE SE onl :a en seiBeltreper ic whRh FxIER Gras aims atus Bin rdGeidery AR so i eoh2 . 18 nin ; 2 oi " Fh Emr puns dno miss SOD . enim e ETO da bos CoRR : tHE EE cr RSET RE Th : wad 23 : SseBn R 42 he se Pr i COREBee (a waa SE SREE REn E he a Ogr thele Oe nd de Baa HRS pha ee Mae en en Gi EEE Hay ior GUE 0 Di ceoCmEAREfEiRndiWsEsEBE5 GEIRB neLSnR g ......... 3 1tql' ILI" 4'v