Document jyOy3XOVKnMwqzGMXyQJ1ORdR

m-Tr,^ t:. irrvr.lirx1 - LIA105O3 > HWPOfldl FOR A nSttXS HBJBCT 0> IB XraWWtfTIOB Bnomt w b w p cofcTnoe un> m wag guamm t o wn an ac t amm It la a imnl pndlM to rtfw to Inert oat to mcttn !> ' orputle plfoiU} itentgr ebito lead, nl V**^ i Im cbronato ooi other* riyrtmt the group of reactive placets, cad auoh aeterlals so tltoalun dlMdto, Iran o Uh o bA utwdtr plgneata ityruat Um pno of noo-reactive pl^eete. The tom reactive yip--to boo mnllj rtftmd to tin rhenlcel nwtintjr bitwM the pi ipint sad tb* organic vehicle with abide tt boa boos ooogtouadad* aapoelally oilaj ad tbo formation of aatalaoap-llho --pound* boa baas aaas aa tbs prlaaiy foes of raaettoo. tba propoaod project trauld etudy tba reactive plpaanta with roapaet to tba latairaoetloo batatas yalats }tb tba ra> etive plgnaet* tad tba aetal eubetrata to which they have baoa applied. Zb s recent paper bp tbta raaaoreb group (paper entitled *hactive toatlaga* given by Hr. Kronatain st Portbaoat Aeglenal Owroelan Oonfareoea, S.A.C.S., la Beaton, October 7, 1958.) wuye aad saana hsao baas Dm for etudylng tba thenlcal change* which occur as s atasZ StffMa to whleh rhaalnal costlapa ban baas applied. It wan ahowa, for laataaca, that a phogpbatlacd ataal eurface eaa ebsapa rhaal nelly after tba application of s point booed eo s reactive pl^airt, auob aa tine ehrcaate; oad It la aanaed that rad laod would react la a alsllar saaaar. Bereby, satsl of tba pi punt baoosaa port of tbo pboapboto coating aadameetb tba applied point, for a--pie a pboepbetlsed ataal eurface Alcb la a epectroenelyalo did aot cootola aay aloe, contained 3'5S$ tlae after tba application aad reacrral of tba point, The J.JH aloe could oaly bora aaUrad fros tba tlae ebrosata la tba polst. Xt la apporaat that euch a reectloo could be at beala practical laportaaoe If it could ba aotobllabcd that la tba aaoa aaaaar a rad laod prlaer would Introduce laod lsto tba coated aurfaoa to further lahlblt tba aurfaea ocrroaloo. Aa laart plpaaat would aot ba able to do thlo. Tba raaaoo wfey tba reported toot bad baao applied to a protracted, or pboapbatlMd aurfaoa, waa la tba fact that It la coaler to rtai eueb a prrtraataaat aad analyte it for lta coapooeate. Tba Method which baa bcea uaad by tbia roaearcb (roup to detenelae whether or aot aa latarraactleo baa occurred betweea aa applied ooetlag aad lta eubetrata eoealata of ebaaleally dlaeolvl&g tba eurface treataeat aad aaslytlac tba raaultlag aolutloo by aalaaloo apcctroaeopy* Ala baa baas deaerlbad la a . paper by Dr. Kronetain, flheldon Kaaa and J. %. Was Dias entitled "ft>oephatltlac Peactiono on Steel*, which baa bean published In a aagatlna `Paint aad Yaraleh Production6, Pol. 17, Bo. 12, Boeanbar 1957. further facta to tbla bind of analytical work hare bean gives la a paper entitled 'studying Organic CoatInga-Oalng Zafrared toflectloa Spietrua and btlaalon Spectroaeopy* by Dr. Kroaetela. thl* paper baa beea publlabed ta *falat aad Vemleh Production*, Pol. ^ Bo. 1, January / Since It la poealble to analyte aa applied aad stripped pboepbatlaatloa, it la alao poealble to atudy tba change# watch occur at tba aotal'palat latcrfaoa, due to tba application of tba reactive N 246.01 , v imv* 4- . i* i-j . LI A10504 . *' 9UP**t la a dlsperelea la as organic tU(U< Aa napli of a palat fora Aiek baa baaa studied vltb respect to Iti laurwMttoa vltb a itMl mrfaee la tba we*b-primr oa bar* ataal. Sara, tba alae o^rehrcaate aad tba phosphoric acid dissolved la tba point tvawlt la tba foraaUoa of aa Irci* tine-phosphate coating oa tba tool. It la tba faallag of tba undersigned that elallar reactions occur la tba eaaa of nd land primer appUeatloaa also, aad they algbt occur alao abac a baalc load carbonate palat would bo applied dirofftlr to a ataal aurfaaa. tba propooad project would etudr tba folloul^t <1) tba Interna ctlon of reartln pigment dlaporalaao la aalactad wahlelaa vltb a clean, bare, atoal auifaaa (*) tba anna aa leally prtreated (3) tba aaae oa surfaces wblcb bare a coattag of aa oxide or bgrdroxlde or a alight fora of net. this latarraaetloe la (a) to ba oatabUabad and emlysed; and (b) lta affect on the stability or eorcoelon resistance of tba natal aurfaaa la to ba sta&led. X* tba stadias to *V, eo^tntln stadias on ateol aurfaoea art to be aada alao aad oa aurfaeaa wblcb ara pelated will a wblcb doea not contain aqr reactive pigMtrta. Aa tba faterreactloa la farther studied aad eatabllabad a donation will ban to ba taken up; that la, la tba latarraectlco; as laorgule oo^ewd only, or ban certain organic aadl* biewa cbmloolly a port of tba land-iron capiases or the also*Iran refill--a on the rirfidj tbat, for laataaea, land la oapabla of faming a grant nuaber of ecnplesaa vltb tosrgaalc aad vltb organic group# la known la tba Utnmtun. fbe project la planning to uee aueb aalacted organic nblelaa with the reectln plgaenta aa out ba ejected to contribute to the fomatlon of octal ecnplexec with the ateol, alualam or nagncilm oirfase. The orgaalca la the emplane, wblcb are being fomad directly on the eteel aurface, mold be different fren the heavier palat flla wblcb la being fomed on tap of the reaction ooatlag Am to tbc drying of the paint Itself. fbat a rticnlnal fometteo oa a ateol aurfaee eaa ban oocslderable Influence on tba atablllty of tba aurfaee was studied sons yeara ago by this research pop In tba case of aurface treetniata cn nagoealun natal surfaces. Tbe results were reported In two papers to the Amrices Cbmleal Society, wblcb were later published la "faint aad Varnish Production", ("birfoce Amiability of Inhibitor* la Prolactin Ooetlng fty*tm" fart ! PIchrome Treatmnt of Magaaelm Surfaces, by Max Kroorula aad Joeepb 0. Pettorioo, la Vol. k6, be. IP, Anvent ir 19&i Part 12 Cbrcnate Plguecitatloa of Organic OoeiLom, by Max Iroaeteln aad |. P. fcaaterle, lx Vol. U, *. 13, Decanter 1^6). In tbeee paper* the effect of ehimetee aa tbs r> actm plgMBt me^udled. Tbe propoeed project would study to dt( extent other grape of reactlv* pi guest* can produce Inhibitor layers on the natal aurface aad bow aueb aodifleatloos stand vp under ej^oeurt M nolsturs aad ehenlcal affaeta. mwww LIAX0505 N4& J'.'Wg' s"Sv "i:-; *TT-'3K^iVV^'^ W^?: > 9m pwywri vert would b eurM out Is tho Burfaoo twtolop bbontn7 of tho Hmurcti Utliloa, Oollip of feCl&Mrlac, Bov York tfaivoroltjr, uolor tho dlrootloa of Dr. Mu Kmotola m pnjwt tlnctor. ftli UtontoiY U oov looatod la Braoarch BuUAlag Bo. 2, *01 Moot K>}th Btraot, Bov York jk, Bov Yarkj tout It la onhohilod to too roloootod la Boooareh BtUdl* Bo. J, BOw Boou Blpnagr oad fordbaa Loadloc Hood, Bov York 60, Bov York* la ttoo roll of 1999. Yho projvot diroctor would too oaolotod tojr q d o fulVtlao rtioulol or CtooBloul Bn<li>oor (Boooarato dido) aad addltloaal otudoat OMlotoaov aa It aldbt too nplnd. Yho parutlao aorrlooo of aa uoolotaat iow> oelootlot would too wood la tho ooardlaotleu aad rooordli* of tho votfe. Yho oalooloa opoctroaaal/aoo would too doao Jotatl/ with Kr. J. Z. Vfea Wo* at tho ATBllod feoctrochauleal Xaborutorloo, Xac. la Oloa Book, Bov dtofoor. 1999 Boopoctfully adfeadttad. /a/ Max Kraotoia Soulor Buoaroh Blostlot // camruo*-----------------Aooocloto Doaa Blrootor, BMoardh Dlrlsloa In Tort MnnUgr OBlXttfl Of pylHutll Cblrnlt7 fclofct*, Mr Tort 53, Mr Tort opgf acapo (1 TM Mfl>) Mtrim h>ct Btnetor (00 tf tin) kmnk Aid* (1005 tin*) tutiBt tnlitue*, oo r*yiir*4i 1,800.00 4,000.00 938*80 (72D hrs/l.JO/far.) A**l*tnt Ai|liMia| Mwtlit (205 of tin*) M*ctealcf iimftw, m rofilroA. 1/M40 200.00 $6,000.00 Or*rt--<1 (575 of MltrU*) M*t*rUl* nl Oappll-- IrporU, photofnphl* wart O.A.S.Z. (2-55 of w m) filUot talMlo* Oandatle*, tml 10,000.00 4.500.00 2,000.00 000.00 000.00 540.00 000.00 $16,500.00 M Of, 1959 * 1 :