Document jyGKr01d7x0YzYkDBJr4zrdz2

STLS E V F. R N TRENT STL Chicago 2417 Bond Street University Park, IL 60466 Tel: 708 534 5200 Fax: 708 534 5211 www.stl-inc.com VERN TRENT LABORATORIES ANALYTICAL REPORT JOB NUMBER: 2 3 3 5 0 5 Prepared For : Weston Solutions, In c . 14 0 Weston Way Building 5-2 West Chester, PA 1 9 3 8 0 - 1 4 9 9 Project Con fiden t ia 1 .Decatur - FC Ilivest igat ion 'Attention : Jai Kesari Dace : 0 1 /2 6 / 2 0 0 5 Signutu Name : Wright Title : Proj ect Manager E-Mail : rwright@stl- inc.corn This Report Contains Leaders in Cnvirnnmental Testing Date '/ is / u S STTi chi cago 2 4 1 7 Bond StreetUniversity Park, 1L 8 0 4 66 PHONE: (7 0 S) 5 3 4 - 5 2 0 0 F A X . .: (7 0 8 ) 5 3 4 - 5 2 1 1 Pages Severn Treni Laboratories, Inc. CONFIDWEENTTCIAHLEMDEISCTARTYUDRA-TFAC PINAVCEKSATGIGEATION JOB# 233505 Data Summary................................................................ 1 Chain of Custody..........................................................26 Case Narrative..............................................................32 Raw Data.......................................................................34 STL Chicago is part of Severn Trent Laboratories, Inc. '!' S A M P L E I N F O R M A T I O N Date: 01/26/2005 Job Number.: 233505 Customer...: Weston SoLutions, Inc. Attn...... : Jai Kesari Project Number........ : 20004891 Customer Project ID___ : CONFIDENTIAL DECATUR Project D e s c r i p t i o n . T: Confidential Decatur - FC Investigation Laboratory Sample ID 233505-1 238505-2 233505-3 233505-4 233505"5 233505-6 233505-7 233505-8 233505-9 233505-10 233505-11 233505-12 233505-13 233505-14 233505-15 233505-16 233505-17 .... .Customer.. : Sample ID' DEKG-SB-01B-0-0150 DEKG-SB-001B-0-0200 DLOI-SB-31 OR-0-0000 DLOI-SB-31OR-0-0005 DLOI -lSB-310R-0-0020 DLOI-SB-310R-0-0050 DLOI-SB-31 OR-0-0370 DLOI-SB-226R-0-0000 DLOI-SB-226R-0-0005 DLOI-SB-226R-0-0020 DLOI-SB-226R-0-0050 DLOI-SB-226R-0-0180 DLOI-SB-226L--0000 DLOI-SB-226L-0-0005 DLOI-SB-226L-0-0020 DLOI-SB-226L-0-0D50 DLOI-SB-226L-0-0170 .. . Sample Matrix Soi l Soil Soil Soil Soi l Soil Soi L Soi l Soil soi 1 Soi l soi l Soil Soil Soil Soi L soi l ".[Jgte -.."Ti Sampled.'. . Sampled 01/12/2005 12:00 01/12/2005 12:40 01/12/2005 13:55 01/12/2005 14:50 01/13/2005 08:20 01/12/2005 14:25 01/12/2005 16:35 01/11/2005 08:00 01/11/2005 08:10 01/11/2005 08:15 01/11/2005 08:20 01/11/2005 09:10 01/11/2005 10:05 01/11/2005 10:20 01/11/2005 09:45 01/11/2005 09:50 01/11/2005 10:40 " Received .:. Received 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 Page 1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Wunber: 233505 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: DBKG-SB-0Q1B-0-0150 Date S a i l e d ...... :01/12/2005 Time Sarrpled...... :12:00 Sanale Matrix..... :Soi L TEST MEIROD:: ' PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon <Soils> TOC Average Duplicates, Solid LABORATORY TEST RESULTS .PROJECT : CONFIDENTIAL DECATUR Laboratory Sample ID: 233505-1 Date Received...... : 01/15/2D5 Time Received....... : 09:00 Date:01/26/2005 A7TW: Jai (Cesari . SAMPLE RESULT a: FLAGS 5QD HDL 79 RL Dl LiftION UNITS' :b a t c h DT DATE/TIME l e c h ; 310 1 mg/Kg 140108 01/17/05 1427 c Ls * [n Description = Dry Wgt. Page 2 I 1 STL Chicago STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 233505 CUSTOMER: Weston Solutions, Inc. Customer Sample ]D: DBKG-SB-001B-0-0200 Date Sampled...... :01/12/2005 Time Sampled...... :12:40 Sample Matrix..... :Soi l TEST METHOD PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils} TOC Average Duplicates, Solid LABORATORT TEST RESULTS . .PROJECT: CONFIDENTIAL.DECATUR. Laboratory Sample ID: 233505-2 Date Received........ :01/15/2005 Time Received.*,....: 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT . G FLAGS . 570 73 RL 280 DILUTION UNITS BATCH DT OATE/TIME T.ECH 1 mg/Kg IA0108 01/17/05 1447 'els STL Chicago * In Description = Dry Ugt. Page 3 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233505 CUSTOMER: Weston Solutions, Inc; Customer Sample ID: DLOI-SB-31R-0-0000 Date Sampled...... :01/12/2005 Time Sampled...... :13:55 Sample Matrix..... :Sai l Tes t m e t h o d Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon {Soils) TOC Average Duplicates, Solid ADORATORI TEST RESULTS PROJECT CONFIDENT IAL'DECTR Laboratory Sample ID: 233505-3 Date Received...... : 01/15/2005 Time Received...... : 09:00 Date:01/26/20G5 -.W--J.ltj*-- Jai !Kesari SAMPLE RESULT 13000 FLASS HDL 530 2100 DILUTION; UNITS BATCH OT DATE/TIME' TECH mg/Kg 140127 01/21/05 1726 m m STL Chicago * In Description = Dry Ugt. Page 4 STL Chicago is part of Severn Trent Laboratories, 3nc. Job Number: 233505 CUSTOMER: Weston Solutions, Inc. Customer Sanple ID: DLOI-SB-3iOR-O-0005 Date Sampled...... :01/12/2005 Time Sampled...... :14:50 Sample Matrix..... :Soil TEST METHOD; PARAMETER/TEST DESCRIPTION LLoyd Kahn Total Organic Carbon CSciLs) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CQNF1DEMTIAL DECATUR . Laboratory Sample iD: 2335(35-4 Date Received........ :01/15/2005 Time Received........ :09:00 Date:01/26/2005 ATTR: Jai Kesari SAMPLE RESULT o; FLAGS 2200 MDL 110 ' RL 430 DILUTION UNITS BATCH DT DATE/T3 ME TECH 1 mg/Kg 140108 01/17/05 1522 els ! i STL Chicago is part of Severn Trent Laboratories, Enc. Job Number: 233505 CUSTOMER: Weston Solutions, Enc. Customer Sample ID: DLQ]-SB-31QR-0-0020 Date Sampled...... :01/13/2005 Time Sampled...... :08:20 Sample Matrix..... :Soil TEST METHOD PARAMETE R/TE 5.T C ESCRI PTIOtJ -. Lloyd Kahn [Total Organic Carbon (Soils) ;TOC Average Duplicates, Solid so LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR' ' Laboratory Sample 10: 233505-5 Date Received........ :01/15/2005 Time Received........ :09:00 Bate:0V26/Zl}D5 ATTN: Jai Kesari i j j SAMPLE- RESULT Q FLAJS 1500 MOL 90 . ;SL 35D D ELUT EON 1 UNITS': BATCH DT DATE/TIM TECH f mg/Kg 140117 01/19/05 18 56[rm j i | j j i 1 j i J __________________________________________________________________________________________________________ * En Description = Dry Ugt, Page 6 ______________ i_____ STL Chicago STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233505 ;CUSTOMER: Weston Solutions,!Inc, Customer Sanple 1C: DLQI-SB-310R-G-QQ50 Date Sampled...... :01/12/2005 Time Sampled...... :14:25 S a m p l e M a t r i x ...... : Soil TEST METHOD Lloyd Kahn PARAMETER/TEST.DESCRIPTION: ! Total Organic Carbon LSoilsJ TOC Average Duplicates, Solid LABORATORY TEST RESULTS . PROJECT; CONFIDENTIAL.PECATR Laboratory Sample ID: 233505-6 Date Received........ :01/15/2005 Time Received...----- :09:00 Date:D1/26/2Q05 ATTN: Jai Kesari SAMPLE RESULT' R A G S 660 MOT 63 RL DILUTION UNITS- CATCH DT DATE/HHE TECH 25D 1 mg/Kg 140117 01/19/D5 1941 rnm * [n Description = Dry Ugt. Page 7 i STL Chicago is part of Severn Trent Laboratories, Inc, Job Nunber: 233505 CUSTOMER: Weston Solutions, Inc. / Customer Sample ID: DL01-SB-310R-0-037Q Date Sampled.......:01/12/2005 Time Sampled.......:16:35 Sample Matrix..... :Soil TEST METHCO Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid 00 LABORATORY TEST RESULTS PROJECT:- CONFIDENTIAL DECATUR Laboratory Sample ID: 233505-7 Date Received....... : 01/15/2005 Time Received....... : 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT- Q FLAGS 350 MDL 68 fit DILUTION UNITS. BATCH d t !; o a t e /t j m e TECH 260 ma/Kg 140117 :01/19/05 1957 rnm STL Chicago * In Description = Dry Wgt. Page 8 STL Chicago is part of Severn Trent Laboratories, Inc. Job Hunber: 233505 : CUSTOMER: Weston Solutions,- Inc. Customer Sample D: DLOI-SEJ-226R-0-QQ00 Date Sampled..... : 01/11/2005 Time Samp led..... : 03:00 Sample Matrix.... : Sol L . TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon iSoiIs) TOC Average Dtpli cates, Solid LABORATORY TEST RESULTS PROJECT:' CONFIDENTIAL DECATUR Laboratory Sample ID: 233505-3 Date Received...... : 01/15/2005 Time Received___ 09:00 Date:01/26/2005 ATTN: Jai (Cesari SAMPLE RESULT <3 FLAGS 20000 W)L-; 400 ' ftt 1600 DILUTION UH ITS BATCH ;DT DATE/TIME TECH 1 mg/Kg 140117 01/19/05 2035 rnm * In Description = Dry tfgt. ' Page 9 ___________ KTT riiif': STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233505 C U S I O M E R : :Wes to n Soluti o n s , Inc. Customer Sample ID: DLOJ-SB-22R-0-OQ05 Date Sampled...... :01 /t 1/2005 Time Sampled.......:05: tQ Sample Matrix..... :Soil TEST METHOD Lloyd Kahn PARAME TER/TEST:O ESCRIP H O N Total Organic Carbon (Soils! TOC Average Duplicates, Solid LABORATORY TEST RESULTS :PROJECT ::COMFIDENT 1At DECATUR Laboratory Sample ID: 233505-9 Date Received....... : 01/15/2005 Time Received....... : 09:00 Date:01/26/2005 ATTN: Jai Kc-sari SAMPLE RESULT 'ftt FLAGS: 5200 MOL 20 0 RL DILUTION BATCH [DT DATE /T (H E TECH S00 mg/Kg 140117 01/19/05 2052 * In Description = Dry Ugt. Page 10 STL Chicago is part of Severn Treni Laboratories, Ine. * In Description = Dry tfgt. Page 11 STL Chicago is part of Severn Trent Laboratories, Inc, Job Number: 233505 CUSTOMER: Weston Solutions, Enc.' Customer Sample ID: DL0I-SB-226R-5-0050 Date Sampled...... :01/11/2005 Time Sampled...... :03:20 Sample Matrix..... :Soi l TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid <N LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR. Laboratory Sample ID: 233505*tl Date Received........ :01/15/2005 Time Received........ :09:00 Date:01/26/2005 ATTN: Jai Kesari .SAMPLE RESULT. ta FLAGS 1600 MDL. 120 RL .ClLUT IOU /UNITS BATCH DT DATE/T1ME TECH 460 1 mg/Kg 140117 01/19/05 2128 rnm i i STL Chicago * In Description = Dry Wgt. Page 12 STL Chicago is part af Severn Trent Laboratori es, Irvc. Job Number: 233505 CUSTOMER: Heston Solutions, Inc, Customer Sample ID: DLQI-SB-226R-O-01SO Date Sampled...... :01/11/2005 Time Sampled...... :09:10 Sample Matrix..... :Sai l LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL DECATUR Laboratory Sample ID: 33505-12 Date Received........ :01/15/2005 Time Received........ :09:00 Date :01/26/2005 ATTN: Jai (Cesari . . STL Chicago STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233505 CUSTOMER: Weston Solutions, Inc. . Customer Sample ID: DLOl-SB-226L-G-0000 Date Sampled.......:01/11/2005 Time Sampled.......:10:05 Sample Matrix......:Soil TEST METHCO Lloyd Kahn PARAMETER/TEST DESCR[PTJ0M Total Organic Carbon CSoflsJ TOC Average Duplicates, Solid LABORATORY TEST RESULTS - : PROJECT: CONFIDENTIAL DECATUR . Laboratory Sample ID: 233505-13 Date Received....... : 01/15/2005 Time Received....... : 09:00 Date:01/26/2005 ATTU: Jai (Cesari i i 5 SAMPLE RESULT 32000 FLAGS: HDL 610 rl: 2400 DILUTION UNITS BATCH RT DATE/TIHE :TECH mg/Kg 140117 01/19/05 Z Z I S ^ m m STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233505 CUSTOMER: Weston Solutions, Enc. Customer Sample ID: DLOI-S&-226L-0-0005 Date Sampled...... :01/11/2005 Time Sampled...... :10:20 Sample Matrix..... :Sai l LABORATORY TEST RESULTS PROJECT: CONF!OEMTlAL DECATUR Laboratory Sample ID: 233505-14 Date Received........ :01/15/2005 Time Received........ :09:00 Date:01/26/2005 ATTN: Jaf Kesaci m _1 H STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233505 CUSTOMER : Heston Solutions, Inc. Customer Sample ED: DL0I-SE-226L'Q-O020 Date Sampled...... :01/11/2005 Time Sampled...... :09:45 Sample Matrix..... :Soi l TEST METHOD Lloyd Kahn PAfiAMETER/TEST.D E S C R ]PTION Total Organic Carbon <Soils> TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233505-15 Date Received........ :01/15/2005 Time Received........ :09:00 Date:D1/26/2005 ATtN: Jai -Kesari SAMPLE RESULT Q.,FLAGS 4100 :MDl 200 RL, 790 DliUTIOK UNITS BATCH DT DATE/TIME TECH ..... .. u_____ mg/Kg !14 P117 01/19/05 2257 rr/n ' In Description = Dry Wgt. Page 16 ot* STL Chicago is part o-f Severn Trent Laboratories, Jnc. Job Number: 233505 ; CUSTOMER: Weston Solutions, Inc. Custodier Sample ID: DLQt-SB-226L-Q-0050 Date Sampled...... :01/11/2005 Time Sampled...... :09:50 Sample Matrix..... :Soil TEST METHOD ! PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid r- LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233505-16 Date Received........ :01/15/2005 Time Received........ :09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT ' Ct FLAGS15 DO MOL' 83 .: : :.RL 330 [SDILUTION UNITS BATCH DT 0ATE/TIME TECH 1 mg/Kg 140117 01/19/05 2309 rnm STL Chicago * In Destri pt ion = Dry tfgt. Page 17 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233505 CUSTOMER: Weston Solutions, Inc. Customer Sample IS: DLI-5B-22L-Q-0170 Date Sampled..... 01/11/2005 Time Sampled..... 10:40 Sample Matrix.... Soi l TEST: METHCO Lloyd Kahn PARAHETER/TEST DESCRIPTION Total Organic Carbon tSoiIs} TOC Average Duplicates, Solid co LAEORATOR TEST RESULTS PROJECT: CONFiDENTE A L :DECATUR Laboratory Sample ID: 233505-17 Date Received....... : 01/15/2005 Time Received....... : 09:00 Oate:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT 1100 FLAGS KOL. 91 RL DILUTION UNITS BATCH ^DT DATE/TIME TECH: 350 mg/Kg 140117 01/19/05 2322 rnm STL Chicago n Description = Dry Wgt. Page 18 STL Chicago is pari of Sevcrn Treni Laboratories, ine. Job Number: 233505 LABORATORY CHRONICLE Date: 01/26/2005 CUSTOMER : Weston Solutions, Inc. Lab ID: 233505-1 METHOD Lloyd Kahn Client ID: DEKG-5B-001B-0-Q15Q DESCRIPTION Total Organic Carbon (Soils) Lab ID: 233505-2 Client ID: DBKG-SB-01B-0-0200 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233505-3 Client ID: DLOI-SB-310R-0-0D00 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-4 Client ID: DLOI-SB-310R-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-5 Client ID: DLOI-SB-31R-0-Q020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-6 Client ID: DL0I-SB-310R-0-0050 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233505-7 Client ID: DLOJ-SB-31DR--0370 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-8 client ID: DLOI-SB-226R-0-0000 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (Sails) Lab ID: 233505-9 Client ID: DLOI-SB-226R-0-0005 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-10 Client ID: DLOI-SB-226R-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-11 client ID: DLOISB-226R-0-0050 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233505-12 Client ID: DLOI-SB-226R-0-0180 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233505-13 Client ID: DLOI-SB-226L-0-0000 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233505-14 Client ID: DLOI-SB-226L-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-15 Client ID: DLOI-SB-226L-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kbsari Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140108 140108 01/17/2005 1427 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140108 14010S 01/17/2005 1447 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1726 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140108 140108 01/17/2005 1522 DILUTION Date Recvd: 01/15/2005 SampLe Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 1856 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 1941 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 1957 DILUTION Date Recvd: 01/15/2005 SampLe Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2035 DILUTION Date Recvd: 01/15/2005 SampLe Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2052 DILUTION Date Recvd: 01/15/2005 SampLe Date: 01/11/2005 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2109 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2128 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2141 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2215 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2234 DILUTION Date Recvd: 01/15/2005 SampLe Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2257 DILUTION STL Chicago Page 19 19 STL Chicago is port of Severn Trent Laboratories, Inc. Job Nimber: 233505 LABORATORY CHRONICLE Dato: 01/26/2005 CUSTOMER: Weston Solutions,'Inc. Lab ID: 233505-16 Client ID: DLOI-SB-226L-0-0050 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233505-17 Client ID: DLOI-SB-226L-0-0170 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT :.CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2309 Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2322 DILUTION DILUTION STL Chicago Page 20 20 Job Number.: 233505 .CUSTOMER: Westn Slut ions, Inc. QUALITY CONTROL RESULTS Report Date.: 01/23/2005 ;!;Project confidential :PEPA-TR: . . . .:!AT.TN.: !Jat !ksarfii;! :jest Method .v w'iH vj lipyd Kahn ; Methd Description..; Total 0rganic Carbon.(Soils) :.P.aramctcr... ngariic carbon,-' Tbtv itOCT! =i cote.,- ,TAneasLt.y.Cet,d1e,;.;^:!:.;^Tt:C'.-. QC Lab ID Reagent Uni ts ICV 140108-002 I04LSTTC2 m 140108-003 LCS 140108-004 I0FSTLK3 LCD 140108u005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 140108-015 I04LSTTC2 mg/Kg CCB 140108-016 mg/Kg QC Result QC Result 1908.82 32.00 U 5097.22 5582.97 5097.22 2248.15 32.00 U True Value 2000.00 4780.00 4780.00 2000.00 Orig. Value QC Calc. F * Limi ts Date Time LOTL I 202.37 171.24 U 107 U 117 9 112 % 85-115 % 53-140 % 53-140 R 30 % 85-115 01/17/2005 1144 01/17/2005 1148 01/17/2005 1213 01/17/2005 1220 01/17/2005 1612 01/17/2005 1616 PMTaeerstath-moMdeetDtehroe.ds,c:riptio'r:ni+.;Z'.ToLrlobgtyaadnlKicoa;rChg'naa'rnbiocn,caTrboot*n.<(TSOoCii)s!')-.!......... . PEaqutciphm',1.e,nt Cde. :.-.'.:S.:''T.'10C44..1..'':17'- . ;!::;!:::!/::!:::!T::ensa:tt:y:esot-t.f-e... tfhojfcfl:':;'.:. ::.- QC Lab ID Reagent units CCV 140117-018 IQ4LSTTC2 CCB 140117-019 1CV 140117-002 I04LSTTC2 ICB 140117-003 LCS 140117-004 I00FSTLK3 LCD 140117-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg CCV 140117-018 I04LSTTC2 mg/Kg CCB 140117-019 mg/Kg QC Result QC Result 1968.55 32.00 u 2125.68 32.00 u 4802.14 4465.78 4802.14 2078.20 32.00 U True Value 2000.00 2000.Q0 4780.00 4780.00 2000.00 Orig. Value QC Cale. F * Limits Date Time 98 106 188.93 216.04 U 100 U 93 7 104 % 85-115 % 85-115 % 53-140 % 53-140 R 30 % 85-115 01/19/2005 0006 01/19/2005 0009 01/19/2005 1830 01/19/2005 1833 01/19/2005 1843 01/19/2005 1850 01/19/2005 2248 01/19/2005 2251 ; es-t. Method...... Tlyd kahn :i:!-!-;- : : .:Method Description.;:::fpt:a'l:.Organic ;:.:Crbdn:(Soils) Parameter,.', : lrganib. Eqrbon,.TOt.; (TOC) -.-''Batch.,,. L . V , :140127 'Equipment! Cod. :: Analyst.*.: rhm.:.:.:;:;.:ttt:.:Od*, :I0C:.!,:.!.. QC Lab ID Reagent Units ICV 140127-002 I04LSTTC2 ICB 140127-003 LCS 140127-004 I00FSTLK3 LCD 140127-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 140127-018 I04LSTTC2 CCB 140127-019 CCV 140127-018 I04LSTTC2 CCB 140127-019 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 2033.16 32.00 U 4013.62 4204.36 4013.62 1994.52 32.00 2052.63 32.00 U u True Value 2000.00 4780.00 4780.00 2000.00 2000.00 Orig. Value QC cale. F * Limi ts Date Time 102 197.68 165.70 U 84 U 88 5 100 103 % 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 01/21/2005 1643 01/21/2005 1646 01/21/2005 1654 01/21/2005 1700 01/21/2005 1942 01/21/2005 1945 01/21/2005 2133 01/21/2005 2136 !Test! Method. : Method DescrptTohi:! Ttl Organi c Carbon (Soi U ) Parameter!; ;!.-, QC Lab ID MS 233505-2 MSD 233505-2 Reagent Uni ts I04LSTTC2 mg/Kg I04LSTTC2 mg/Kg QC Result 1765.01 1790.34 QC Result 1765.01 T410SEquipment'icddia:.;,,v *TQC4 ' Analyst.'.' : C U ' :!::: Test :Dbde ::.T.Q!V2. : True Value 2000.00 2000.00 Orig. Value 565.42 565.42 QC C Le. F * Limita Date Time 90 94 4.3 % 53-140 01/17/2005 1504 % 53-140 01/17/2005 1512 R 30 Page 21 * %=% REC, R~RRD, A=ABS Diff., D=% Diff. STL Chicago 21 Jab Number,: 233505 ^csYMf: Ueftfon Solutions,:Inc. QUALITY CONTROL RESULTS Report Date.: 01/28/2005 '.PROJECT!:WFNTitli !DECATUR . . ;;a t t n :i :Jh.t .iiesari . TSt MetH ad /: Lloyd Kahn. Method Description. !TtM; =rgani c :Carbon-<Sils) . p.riimeter.v :;.TOC:':Ave rage Dupli cat es :: QC Lab ID MS 233505-5 MSD 233505"5 Reagent Units I04LSTTC2 mg/Kg IQ4LSTTC2 mg/ Kg QC Result 3764.38 3134.89 QC Result 3764.38 i-140117' . Eqd ifWiftit Code::. TOCV ' Analyste,-; rrtft Test-code.::: o o a v 2:; True va Lue 2000.00 2000.00 rig. Value 1480.19 1480.19 QC cale. F * Limits Date Time 74 % 53-140 01/19/2005 1925 96 % 53-140 01/19/2005 1932 8 STL Cliicaeo Page 22 * %=% REC, R=RPD, A=AB5 Diff., D=% Dlff* 22 DUAL 1 \ S S U R A II C E H E I H REF ERE!ICES A N D N O T E S Report Date: 01/26/2005 REPORT COMMENTS 1) ALL pages of this report are integral parts of the analytical data. Therefore, this report shouLd be reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting limits are adjusted for sample.size used, dilutions and moisture content if applicable, 4) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 4DCFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt. GLossary of flags, qualifiers and abbreviations (any nunber of which may appear in the report) inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated limit, < Not detected at or above the reporting Limit. J Result is less than the RL, but greater than or equal to the method detection Limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MDL. S ResuLt was determined by the Method of Standard Additions. F AFCEE: Result is Less than the RL, but greater than or equaL to the methoddetection limit. Inorganic Flags (Flag Column) ICV,CCV,ICB,CCB,ISA,ISB,CRI,CRA,MRL: Instrument related QC exceed the upper or lower controL Limits. * LCB, LCD, MD: Batch QC exceeds the upper or Lower control Limits. + MSA correlation coefficient is less than 0.995. 4 MS, MSD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control Limits are not applicable. E SD: Serial dilution exceeds the control limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting limit or had a negative instrument reading lower than the absoLute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or lower control limits. W AS(GFAA) Post-digestion spike was outside 85-115% control limitsorganic Qualifiers (Q Column) U Analyte was not detected at or above the stated limit. ND Compound not detected. J Result is an estimated value below the reporting limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. V The chromatographic response resembLes a typical fuel pattern. Z The chromatographic response does not resemble a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value beLow the reporting Limit ora tentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting Limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or lowercontrol limits, EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample, p Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a diLution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery l"s not calculated. H ManuaLLy integrated compound. P The lower of the two values is reported when the % difference between the results of two DC columns is Page 23 .D U A L I T Y A S S U R A N C E ...M E T H 0 D S REFERENCES A '.oi:/^/2p5 '..:..- greater than 25%, Abbreviations AS Post Digestion Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation analysis of A1 or D1 C2 Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CRI Low Level Standard Check - ICP CV CaliIbration Verification Standard Dil Fac Dilution Factor - Secondary dilution analysis D1 Dilution 1 D2 Dilution 2 D3 Dilution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Low Level DSM Distilled Standard Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial Calibration ICB Initial Calibration Blank ICV Initial Calibration Verification 1DL Instrument Detection Limit ISA interference Check Sample A - ICAP 1SB Interference Check Sample B - ICAP Job No. The first six digits of the sample ID which refers to a specific client, project and sample group Lab ID An B number unique laboratory identification LCD Laboratory CohtroL Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIME) PDS Post Digestion Spike (ICAP) RA Re-anatysfs of originaL A1 Re-anaLysis of Dl A2 Re-analysis of D2 A3 Re-anaLysis of D3 RD Re-extraction of dilution RE Re-extraction of original RC Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 24 STL Cliicago 24 Q U A L I T Y A S S U R A N C E;S M E T H O D S R '.t':F E R E N C ; ;S ;'A N D ..N 0 T E S ' Report Pate: 01/26/2005 RTW Retention Time Window sample ID A 9 digit number unique for each sample, the first six digits are referred as the job number SCB Seeded Control Blank SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL) UCB Unseeded Control Blank SSV Second Source Verification Standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCQP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS G1 Gelex Check standard Range 0-1 G2 Gelex Check Standard Range 1-10 G3 Gelex Check standard Range 10-100 G4 Gelex Check standard Range 100-1000 Note 1: The Post spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used, EX. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note Z: The MD calculates an absolute difference (A) when the sample concentration is less than 5 times the reporting limit. The control Limit is represented as +/- the RL. ctt :-- Page Z5 if t CHAIN OF CUSTODY STL Chicago 26 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 2 3 3 5 S" / of PROJECT INFORMATION Client: W eston Solutions, Inc. 1400 W eston Way, Bldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: Lkesarit weston solutions.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: E. Caldwell, B. McCanless 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # \ Client DBKG DBKG DLOl DLOl DLOl DLOl DLOl SaSmBple SB SB SB SB SB SB Identification 001B 0 0150 301001RB 31 OR 0200 00000050 31 OR 3311 OORR 0020 00307500 Collection Date 12-Jan-0 5 12-Jan-0 5 12-Jan-05 12-Jan-05 13-Jan-05 12-Jan-05 12-Jan-05 Collection Time 12:00 1123::4505 14:50 184:2:205 16:35 Sac z o'OOS. *CmO-r Sample Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL Comments CHAIN OF CUSTODY Relinqujslye^d B y r Date y f/ Cooler ID No.: Tim e RecFeeivdeEdxBy: y< r5 F Cooler Temp. {CJ: Date Time fi/Mr fS/lorfir / O trtv o PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY/ ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE of PROJECT INFORMATION Client: W eston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19330 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari em ail: i.kesari(>we sto risoluti ons.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED 1 Sampler: E. Caldwell, B. McCanless 256-552-6189 P.O. #: Quotation #: ____________ SAMPLE ANALYSIS ExyLIMS # Client Sample identification | DLOI SB 226R 0 0000 DLOl SB 226R 0 0005 . 1 DLOI SB 2 2 6 R 0 0020 :: 12 \l - iS - : ife : n DLOI DLOI DLOI DLOI DLOI :: DLOI DLOI SB SB SB SB SB SB SB 226R 226R 226L 226L 226L 226L 226L 0 0050 0 0180 0 0000 0 0005 0 0020 0 0050 0 0170 Collection Date 11 -Jan -05 11-Jan-05 H-Jan-05 11-Jan-05 11-Jan-Q 5 11-Jan-05 11-Jan-05 =1 1-Jan-05 11-Jan-05 11-Jan-05 CHAIN OF CUSTODY Cooler ID No.: Collection Time 8:00 8:10 8:15 8:20 9:10 10:05 10:20 9:45 9:50 10:40 Composite No. of Containers TOC 4 Q. EI -Q oE X X X X X X X X X X i_ Sample Matrix 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 ! SOIL 1 SOIL Cooler Temp. (C): I________ Comments [X X X X X X X X X X _J_! PROJECT REQUIREMENTS Results Deadline: Rei injiAH^ff^pky: Date Time 7* Received By: Fed Ex u~ Date Time // S - tfio o Laboratory Report Options: Sample Results Only Add Case Narrative Add QuaJity Control Summary Add Calibration Summary Add Raw Data Other: Sampie Lot#: STL Chicago Internal Sample Custody Transfer Record Client: U > Sample No. i- n i-tn Analysis /wc (Us Relinquished by: - Received by: Date Time X jj 1 : i-n-'*' /-~ck 0 Comments CHI-22-11-001/C-inS rpjsckl Job Sample Receipt Checklist Report Job Humber.: 233505 Location.: 57222 Check List Number.: 1 Description.: Customer Job ID.... : Job Check List Date.; 01/15/2005 Project Number,.- 20004391 Project Description.: Confidential Decatur - FC Investigation Customer...... : Weston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report,.: 01/2B/2005 Project Manager.... : rcw Chain-of-Custody Present?......................... Y Were samples dropped off at or picked up by STL?.. N Custody seal on shipping container?............... Y ...If "yes", custody seal intact?................. Y Custody seals on sample containers?.,T.,*,,...... N ...If "yes", custody seal intact?...... .......... SampLes iced?................................ Y Temperature of cooler acceptable? (4 deg C +/- 2). Y 3.1 Samples received intact (good condition)?..........Y Volatile samples acceptable? (no headspace),...... Correct containers used?.......................... Y Adequate sample volume provided?.................. Y Samples preserved correctly?... ......... Y Samples received within holding-time?............. Y Agreement between coc and sample Labels?......... Y Radioactivity at or beLow background levels?..... Y A sample Discrepancy Report (SDR) was needed?.___ N If samples were shipped was there an air bill #?.. Y Sample Custodian Signature/Date................... Y Page 1 STL Chicago 30 Express U S A ir b li TMwuFilnstdtaf!ra 3 U f i H c b 4 f l f i f i 5 D t From . Osta / / / v ' / o - r SeSBiSSsBaH Sendar'a Nbotb ~T 7 t A . . Pv { A j tf j.1. PtoiB ' L 2 : C / % X Cocnwnv a - 4^ ' O Cs I ____/ A-1 C -- v______ ^ 4a B q u e s s P a c k q g t S e t v i n^FadfePrioriiiitVBrni^t; (~f FaifeStandardOvenigf* P I fsd&fiHtOwniflh^' NtaUvmHxriv* *-- * rtHwn" L J fatto matolttwrimwH n at asmJ-ai lfteaaam tgimlBk in ifiB' KtiiiltULHim--rtu-It1gT iFNiiain idlni &uMtEi nxMmpttraiw^wsS-a--w--r--- Express Fret|t*Arwice Adqiii**MrwHiitiicaitiw. AJdW38 M O O Ctr f e / . <r-rx-L Y..v ^ Slats / T ^ ?i ^^ 2IP ^ 7 ***!-- **>*f 3 T# Bwipwirfa Name_____ j A / V A ^ t ^ -- / Z y g g-<~ "C .A i s / J ' Plwiw j. *- V *4'A Y Company />1 L. A A ^2 W 7' /x>^AlfAlJedu enmlapnsitatm_dina_t a_f m__P O_. i_m _i _o r _E D_. 3_F ^- t a t a wb /W i' tanqMS ^KttastataUii nqijtaftdSr. totali. !tatFHbi*ta*km 5V J39L_ Z ^ V 7..WAj- .-A .' '^j. A / < / Stata L ap z O H C Dmsy D 5 Packaging -tam*-** rT FedB f fed & ft* * Q (W 6 JSSSSKSk**,* H Fase* Tuba S f o lt o ' *6 SpecialHmdbriQ ItaM*Fadgcaddmitatatto*! 'SfliKWMiw r-| HOUWeatofey i i at Faift location ,--L j)HafOwtLffeeDtdfEcnatWntMcrafa&Pitat* _. M* ThfrtisHbnutrtwatsttaactraicMtw n Bootal.~i jnp \ n 0 va? aOmwariikyiaitotfmitl.xHfes 1n'------ DI > i IvM i, 'TMl 1 l l . TjlWTOttjttakknrta!Drytin-amabt-iipilifarkT.prrfa!V 1~1 Carsp aircraft tMy Paynent affla? aarM EK Jkd No.wCotSt&rd Fatato. S, Recipient 0 TTwiFarly 0 OrwftCafd Q OA^rf-.P-Sy.y taflafrw- . skjrwflr*JI , ...... aiaiO M B ti m luwO ^n) tW la fiim ta ii from srrt wsikinf slsiiw. Baljonr?VtMraprWhJI>aMw cBrr.-tiDtl*jMiJHC.lrBo-FPserdt^rIl4.i3iC-.C.i&Sll1S2W33-.iMVrcFrtMTl'L'd-'i:^ WAP.H*1* <n CASE NARRATIVE STL Chicago Wet Chemistry Case Narrative Client: Weston Solutions, Inc. Job#: 233505 DateRec'd: 01/15/05 This narrative covers the analysis of the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analysed for TOC in duplicate by furnace combustion and nondacisidpiefrisciavteioinnftroarreedmdoevteecitnioorngaonnica cDaorbhormn,aannndPdhroyeinngix. 8N0o00coTrrOeCctiaonnawlyasserm, aadfete,rtherefore, for moisture content. The average ofthe sample bums is reported. 2. The method-recommended holding time of 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. 5. The LCSs were within acceptance limits. 6. The matrix QC done on samples 233505-2 and 5 was within acceptance limits. Wet Chemistry Section Manager STL Chicago Date 33 RAW DATA *** RUN LOG *** L X Tt'C I L> m ) 1/24/05 16:28 s Total Organic Carbon (Soils) Method Code.*; TOCS Batch Code...: 140106 status...... RPT Batch Date...: 01/24/05 Batch Time...: 1538 User Name.......:els QC Code......... :TOCS Calc Code....... :TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code----: TEST CODE TTTTTTTTTTTTT 0OOO00OCCCIII c ccC C c C S S sC C C 2 3 4 A A A 2 A sS S VVV V 2A 234 2 2 SAMPLE: Grp Pos sample id Di luti on TEST POS Date / Time 1234567111222 78 90 12 11 ___ICALJ05A5TTC1_ 0 12 ___ICVJ04LSTTC2_ 1/17/05 1144 0 13 ,,__ MB__ 1/17/05 1148 0 14 ___LCS_I00FSTLK3_3 1/17/05 1213 0 15 16 17 LCD IQ0FSTLK3 3 233477 1 S Z33477_2_$___ 1/17/05 1220 0 1/17/05 1232 1/17/05 1323 0 0 18 233477_3_S___. 1/17/05 1357 0 19 233423_1_S___ 1/17/05 1411 0 1 10 233505 1 s 1/17/05 1427 0 1 11 1 12 1 13 233505_2_S___ 2335 05_2_S_MSm IQ4LSTTC2J1 233505_2_S_MSD_I04LSTTC2J1 1/17/05 1447 1/17/05 1504 1/17/05 1512 0 0 0 1 14 1 15 1 16 233505_4_S___ ___CCV_I04LSTTC2_ __ CCB__ 1/17/05 1522 1/17/05 1612 0 1/17/05 1616 0 0 TT talliron -- Page 1 *** QC Summary *** <V2 ) Total Organic Carbon (Soils) Method code..: TOCS Batch Code...: 140103 Status...... : RPT Batch Date...: 01/24/05 Batch Time...: 1538 User Name....: els 0C Code....... : TOCS CaLc Code..... : TOCS Location Code..: 57222 Grp Strip SampLe 10 Pos Test ResuLt Khoun Originai 1 2 ___ICV_l04LSTTC2i_ 1 TOC 190S.82 2000 1 3 ___M 8 _ 1 TOC "2.80 1 4 ___ LCS_IOOFSTLK3_3 1 TOC 5097.22 4780 '2.80 1 5 ___LC DJ DD F S T L I G J 1 TOC 5582.97 4760 -2.60 1 12 233505_2^S_MS_I04LSTTC2_11 5 TOCAV2 1765.01 2000 565.42 1 13 233505_2_S_MSD_I04LSTTC2_11 5 TOCAV2 1790.34 2000 565.42 1 15 CCV I04LSTTC2 1 TOC 2248.15 2000 1 16 ___CCB__ 1 TOC "2.68 Report Date: 1/24/05 16:28 Equipment Code.: OC4 import Code____: Alternate QC Res 95 F QC Rea F 5097.22 1765.01 107 117 90 94 112 9 4.3 S T l .f'hiOflOn Page 1 IK *** RAU TEST DATA *** (VS ) Total Organic Carbon (Soi Ls) Method Code,,: TOCS Batch Code... : 140103 Status...... : RPT Batch Date.. : 01/24/05 Batch Time.. : 1538 User Name... : cls SAMPLE: Grp Po$ sample ID 11 ICAL I05ASTTC1 12 ICV IQ4LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 233477 1 S 1 7 233477 2 S 1 S 233477 3 S 1 9 233423 1 S 1 10 233505 1 S 1 11 233505 2 s 1 12 233505 2 S MS I04LSTTC2 11 1 13 233505 2 S MSP I04LSTTC2 11 1 14 233505 4 S 1 15 CCV ID4LSTTC2 1 16 CCS QC Code....... : TOCS CaLc Code___ ,_ : TOCS Location Code.. : 57222 Dilution TOC mg/Kg T0C2 mg/Kg Report Date: 1/24/05 16:26 Equipment code.: T0C4 Import Code..,.: TQC3 mg/Kg TOC4 mg/Kg TOCAV2 mg/Kg 1908.82 -2.80 5097.22 5582.97 534233.00 537137.50 445746.67 334031.75 1175628.67 518404.50 52242.50 50974.67 545.15 459.77 398.37 732.48 1765.01 1790.34 2033.46 2320.59 2248.15 -2.88 535685,25 389889.21 847016.5B 51608.58 502.46 565.42 1765.01 1790.34 2177.03 STL Chicago Page 1 37 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method code..: TOCS Batch Code-..: 140108 Status___ RPT Batch Date...: 01/24/05 Batch Time,..: 1538 User Name....: els SAMPLE: Grp Poh Sample ID 11 ICAL I05ASTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I00F5TLK3 3 15 LCD I00FSTL.K3 3 1 6 233477 1 S 1 7 233477 2 s 1 8 233477 3 S 1 9 233423 1 S 1 10 23355 1 S 1 11 233505, 2 S 1 12 233505 2 S MS I4LSTTC2 11 1 13 233505 2 S MSD I04LSTTC2 11 1 14 233505 4 S 1 15 CCV I4LSTTC2, 1 16 CCB QC code........ : TOCS Calc Code.,----: TOCS Location Code..: 57222 Dilution TCAV3 mg/Kg TQCAV4 mg/Kg Report Date: 1/24/05 16:28 Equipment Code.: TOC4 Import Code----: T0CR1 ug TOCR2 ug T0CR3 ug 95.4410 -0.4487 128.9597 166.9308 160.2699 133.7240 352.6886 31.3455 24.8041 27.8063 133.0821 137.1404 86.2185 112.4076 -0.4610 214.8550 133.6127 207.3618 76,4620 38.5285 51.7864 118.8140 STL Chicago Page 38 ** RAW TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code?,-: TOCS Batch Code...: 140108 Status..... .; RPT Batch Date...: 01/24/05 Batch Time...: 1538 User Name____: els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I04LSTTC2 13 . MB 14 LCS I00FSTUC3 3 15 LCD I00FSTLK3 3 1 6 233477 1 S 1 7 233477 2 s 1 B 233477 3 S 1 9 233423 1 S 1 10 233505 1 S 1 11 233505 2 s 1 12 233505 2 S MS I04LSTTC2 11 1 13 233505 2 S MSD J04LSTTC2 11 1 14 233505 4 S 1 15 CCV I04LSTTC2 1 16 CCB QC Code........ : TOCS Calc Code*.----: TOCS Location Code..: 57222 Dilution TOCR4 ug UT1 g Report Date: 1/24/05 16:28 Equipment Code.: TOC4 Import Code....: UT2 WT3 WT4 ggg 0.05 0.16 0.0253 0.0299 0.0003 0.0003 0.0003 0.0006 0.0455 0.0698 0.0754 0.0766 0.0424 0.05 0.16 0.0004 0.0004 0.0004 0.0015 0.0838 0.0707 0*0512 STL Chicago Page 3 39 *** RAW TEST DATA (V2 > TotaL Organic Carbch [Soils) Method Code., : TOCS Batch Code... : 140108 Status...... : RPT Batch Date.. : 01/24/05 Batch Time.. : 1538 User Name... : els SAMPLE: Grp Poa Sample ID 11 ]CAL 05ASTTC1 12 ICV 104LSTTC2 13 MB 14 LCS I0FSTLK3 3 15 LCD I0FSTLK3 3 1 6 233477 1 S 1 7 233477 2 S 1 8 233477 3 S 1 9 233423 1 S 1 10 233505 1 S 1 11 233505 2 S 1 12 233505 2 S MS I04LSTTC2 11 1 13 233505 2 S MSD I04LSTTC2 11 1 14 233505 4 S 1 15 CCV I04LSTTC2 1 16 ___CCB QC Code....... : TOCS Calc Code..... : TOCS Location code..: 57222 Dilution DLFAC N/A TCS mg/Kg Report Date; 1/24/05 16:28 Equipment Code.: TOC4 import Code..-.: TCS2 mg/Kg TCSAV2 mg/Kg TICS ttig/Kg 3.2000 1.0000 6.3241 5.3512 457.1429 457.1429 457.1429 152.3810 2.4749 2.2776 2.1220 2.0888 3.4188 3.2000 1.0000 STL Chicago Page 4 40 Calibration Report Print Date/Time: 2005/01/17 11:33:08 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8,538e+04 Y Intercept (b): 436425 r-squared: 0,99800 Standard ID Y X Expected Measured Message Date& Raw Data ug C ug C Time 0 ugram C -4530 0.000 5,165 No Sample Det 01/17/2005 09:53 IQugramC 1085240 10.000 7.599 01/17/2005 10:15 20 ugram C 1870210 20.000 16.794 01/17/2005 10:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210.740 01/17/200511:07 300 ugram C 26478564 300.000 305.025 01/17/200511:15 400 ugram C 33682344 400.000 389.401 01/17/2005 11:32 STL Chicago 41 Multiple Analysis Report Sample ID 0 ugram C lQugramC 20 ugram C 40 ugram C . ...... . 80 u g r a m C 120 ugram C 200 u g r a m C* ..... . 300 ugram C 400 ugram C I C V ........................ ICB-MB DCS L C D ................. 233477-1 233477-1 233477-2 . . ,. ...... 233477-2 233477-2 2 3 3 4 7 7 - 3 ........... 233477 -3 2 3 3 4 7 7 "3 2 3 3 4 7 7 - 3 ........... 233423-1 233423-1 2 3 3 5 0 5 - 1 ........... 233505-1 233505-2 2 3 3 5 0 5 - 2 ........... 233505-2ms 233505-2msd 2 3 3 5 0 5 - 4 ........... 233505-4 ccv C C B ................. Print Date/Time; 2005/01/19 1 8 i 15:36 Result Std. Dev* RSD Mode ALT -4530 1085240 1870210 . 3806480. 7357282 11114689 .18428840* 26478564 33682344 . 95 *4410, -0,4487 128.9597 *166.9308, 160.2699 214*8550 *686,1457. 133.7240 133,6127 .857,1482. -0.0662 352,6886 *207.3618* 31.3455 76.4620 , 24,8041. 38.5285 27.8063 . 51.7864. 133.0821 137.1404 . 86*2185, 118*8140 112.4076 . -0.4610. TC TC TC . ..TC TC TC . . .TC TC TC . .-TC TC TC , , -TC TC TC . , -TC TC TC . . ,TC TC TC , , ,TC TC TC , , -TC TC TC , ..TC TC TC . . *TC TC TC * . .TC STL Chicago 42 Detailed Analysis Report Print Date/Time: 2005/01/19 18:15:40 Sample ID: 0 u g r a m C Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -4530 Last Message: Mo Sample Detected Mode : TC Filename: 01170950 Timestamp: 01/17/2005 09:53 Sample Type: TC Standard Beginning Baseline 1.599 Ending Baseline 1.545 Integration Time 12 0 Sample ID: lQugramC Method: boat Cal* Curve: SOILCURVE Operator ID: CAROL Rep # ppm c ug C 1 Raw Data 1085240 Mode: Filename: Timestamp: Sample Type: TC 01171011 01/17/2005 10:15 TC Standard Beginning Baseline 1*440 Ending Baseline 2*438 Integration Time 206 Sample ID: 20 u g r a m C Method: boat Cal* Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 Raw Data 1670210 Mode: Filename: Timestamp: Sample Type: TC 01171021 01/17/2005 10:26 TC Standard Beginning Baseline 1*456 Ending Baseline 2*455 Integration Time 224 Sample ID: 40 u g r a m C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 Raw Data 3806480 Mode: TC Filename : 01171029 Timestamp : 01/17/2005 10:34 Sample Type : TC Standard Beginning Baseline 1*457 Ending Baseline 2*456 Integration Time 251 Sample ID: 80 u g r a m C Method: boat Cal * C urve: SOILCURVE O perator ID: CAROL Rep # ppm C ug C Raw Data 7357282 Mode: TC Filename: 01171040 Timestamp: 01/17/2005 10:45 Sample Type: TC Standard Beginning Baseline 1.463 Ending Baseline 2*462 Integration Time 278 STL Chicago 43 Sample ID: Method: Cal. Curve: Operator ID; 120 ugram boat SOILCURVE CAROL C Rep # ppm C ug C 1 Raw Data 11114689 Sample ID: Method: Cal. Curve : O p erator ID: 200 ugram boat SOILCURVE CAROL C Rep ff ppm C ug C 1 Raw Data 18428840 3111 I11111 Sample ID: 300 u g r a m C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 Raw Data 26478564 Sample ID: 400 u g r a m C Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 Raw Data 33682344 Sample ID: ICV Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep # ppm C ug c Raw Data 1 95.4410 95.4410 8584908 Sample ID: ICB-MB STL Chicago Mode : TC Filename: 01171052 Timestamp: 01/17/2005 10:58 Sample Type: TC Standard Beginning Baseline 1.454 Ending Baseline 2.454 Integration Time 304 Mode: TC Filename: 01171101 Timestamp: 01/17/2005 11:07 Sample Type : TC Standard Beginning Baseline 1.590 Ending Baseline 2. 588 Integration Time 325 Mode : Filename : Timestamp: Sample Type: TC 01171109 01/17/2005 11:15 TC Standard Beginning Baseline 1.898 Ending Baseline 2.898 Integration Time 340 Mode: Filename : Timestamp: Sample Type TC 01171125 01/17/2005 11:32 TC Standard Beginning Baseline 1.576 Ending Baseline 2.576 Integration Time 411 Mode : Filename : Timestamp: Sample Type TC 01171137 01/17/2005 11:44? Cal. Verification Beginning Baseline 1.716 Ending Baseline 2.713 Integration Time 276 Mode : TC 44 Method: boat Cal * C urve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0-4487 -0.4487 -12541 Last Message: No Sample Detected Filename : 01171145 Timestamp: 01/17/200 Sample Type: Sample Beginning Baseline 1,812 Ending Baseline 1,667 Integration Time 120 Sample ID: LCS Method: boat Cal, Curve: SOILCURVE Operator I D : CAROL Rep # ppm C ug C Raw Data 1 128.9597 128,9597 11035982 Mode: TC Filename: 01171208 Timestamp: 01/17/200 Sample Type: Samp1e Beginning Baseline 1,853 Ending Baseline 2.852 Integration Time 283 Sample ID: Method: Cal, Curve : Operator ID LCD boat SOILCURVE CAROL Rep ti ppm C ug C Raw Data 1 166,9308 166,9308 14277843 Mode: Filename : Timestamp: Sample Type: TC 01171214 01/17/2005 Sample Beginning Baseline 2,008 Ending Baseline 3,007 Integration Time 293 Sample ID: 233477-1 Method: boat Cal* Curve: SOILCURVE Operator ID: CAROL \ \ \ Rep # ppm c ug C R^w Data \ 1 160.2 699 160.2 699 13 7X>9161 Sample ID: 233477-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL \\ ^ Rep # ppm C ug C Raw Data 1 214.8550 214.8550 18369476 Mode : Filename : Timestamp: Sample Type: TC 01171227 01/17/200 Sample ( Beginning Baseline 1.707 Ending Baseline 2,705 Integration Time 271 Mode: TC Filename : 01171238 Timestamp: 01/17/2005 12:44 Sample Type: Sample \ eginning Ending Integration B kseline Baseline Time . 659 \ 2.659 313 Sample. ID: Method: Mode: Filename TC 01171247 STL Chieggo 45 C a l . Curve : SOIIiCURVE Operator ID : CAROL Rep # 1 ppm \ ug C \ 352.6886 \\352.6886 Raw Data 30137324 Timestamp: 01/17/2005/13:57 Sample Type: Sample V/ Beginning Baseline 5.481 Ending Baseline 6.478 Integration Time 267 Sample ID: Method: Cal. Curve: Operator ID: 233477-3\ boat \ SOILCURVE \ CAROL Rep # ppm C ug C Raw Data 1 207.3618 207.3618 1\7729732 Mode : Filename : Timestamp: Sample Type TC 01171358 01/17/2005 Sample 14:03 Beginning Baseline 3.365 Ending Baseline 4.361 Integration Time 278 Sample ID: Method: Cal. Curve: Operator ID: 233423-1 boat SOILCURVE CAROL Rep # ppm C ug C 1 31.3455 31.3455 \ Raw Data \ 2701957 \ Mode: TC Filename: 01171406 Timestamp: 01/17/2005( 14:11 Sample Type: Sample Beginning Baseline 2.295 Ending Baseline 3.290 Integration Time 226 Sample ID: 233423-1 Method: boat Cal. Curve: SOILCURVE Oper a t or ID: CAROL Rep # ppm C ug C Raw Data 1 76.4620 76.4620 6553877 Mode: TC Filename: 01171416 Timestamp: 01/17/2005 Lple Type: S ample 14:22 Beginni] Baseline 1.917 Ending Baseline 2.916 Integration Time 268 Sample ID: 233505-1 Method: boat Cal. Curve: SOILCURVE O p erator ID: CAROL Rep # ppm C ug C Raw Data 1 24.8041 24.8041 2143469 Mode : Filename : Timestamp: Sample Type TC 01171422 01/17/200 Sample Beginning Baseline 2.270 Ending Baseline 3.267 Integration Time 212 Sample ID: Method: Cal. Curve : O p erator ID: 233505-1 boat SOILCURVE CAROL Mode : Filename : Timestamp: Sample Type TC 01171432 01/17/2005 Sample 14:37 STL Chicago 46 Rep # 1 " w ' V ppm C ug C Raw Data 38 *5285 38.5285 3315215 Sample ID: 233505-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 27.8063 27.8063 2399788 sample ID: 233505-2 Method: boat Cal. Curve: SOILCURVE O p erator ID: CAROL Rep # ppm C ug C Raw Data 1 51.7864 51.7864 4447142 Sample ID: 2 3 3 5 0 5 -2ms Method: boat Cal, Curve: SOILCURVE operator ID: CAROL Rep # ppm C ug C Raw Data 1 133.0821 133.0821 11387942 Sample ID: 233505-2msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 137.1404 137.1404 11734428 Sample ID: 233505-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 86.2185 86.2185 7386855 STL Chicago Beginning Baseline 1.977 Ending Baseline 2.975 Integration Time 256 Mode : Filename: Timestamp: Sample Type TC 01171442 01/17/200/ Sample ( 14:47 Beginning Baseline 1.773 Ending Baseline 2.772 Integration Time 239 Mode: Filename: Timestamp: Sample Type: TC 01171452 01/17/2005 Sample 14:58 Beginning Baseline 1.841 Ending Baseline 2.837 Integration Time 351 Mode: Filename: Timestamp: Sample Type: TC x " " "'.^ 01171459 f ..) 01/17/2003 15:04 Sample \ / Beginning Baseline 4.591 Ending Baseline 5,584 Integration Time 251 Mode: TC Filename: 01171507^ \ Timestamp: 01/17/2005 15:12 Sample Type: Sample J / Beginning Baseline 4.957 Ending Baseline 5,945 Integration Time 264 Mode: Filename: Timestamp : Sample Type: TC 01171517 01/17/20(05 Sample l _____ 15:22 Beginning Baseline 1.883 Ending Baseline 2.831 Integration Time 261 47 Sample ID: 233505-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 118.8140 118.8140 10169767 Last Message: Endpoint Timeout Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ration ppm C ug C Raw Data 1 112.4076 112.4076 10033468 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.4610 -0.4610 -13598 Last Message: No Sample Detected Mode: TC Filename: 01171545 Timestamp: 01/17/2005 Sample Type: Sample 15:54 Beginning Baseline 0.478 Ending Baseline 2.678 Integration Time 480 Mode: Filename: Timestamp : Sample Type: TC 01171559 01/17/20' 5 16:12/ C a l . Veri f icatin Beginning Ending Integ Baseline 1.623 Baseline 2.622 Time 369 Mode : TC Filename: 01171614 Timestamp: 01/17/20 Sample Type: Sample 16 6 Beginning Baseline 2.096 Ending Baseline 1.889 Integration Time 120 ST L C hicago PaoeNo.: ...... 1 2 1 TOC in S o ils Book No.. Method: Lloyd Kahn Instrument Phoenix 8000 (TQC4`i LafaNat Batch: / V ft / Calculation*; Date of Standard Curve; / //& / f ~ TOC (mg/kg) = ug C /grams sample Book# 'J -? Pacts# / ^ / MS, MSO Known Cone, (mg/kg) 100 ug C I gram* sample MS, MSD Observed (mg/kg) = ug C l grams sample MStM SD R, * (observed ma/ka - ava, sample result (mo/kgll x100 known concentration in mg/kg Standard TraceablHtv: (Nat*: Working Standards are prepared dally fromthe noted Stock Solutions.) Stock I (Curve) T o k : # S T T ^ - f Stock il (CV/CCV) g O V ^ 7 T C '<?_ LCS Source \ ? c > * r s T ^ ^ l c s True Value V 9 jpau,,^Acceptance Range T ' 3 - / Y ^ - Sam ple ID: Sam ple W eight (g) ug C '0 o /& q O .J - H& ip J L t& H. ) _______ X O O_____ &JL l e j H 0 T ti/ 1 * 0 uJL 'L & J L . Y "" uob ' 7FTD ~TW T FT ~ ji---- 7. / .'O C L ^ y f l O x i. ! a a a C) ^ c? (7 0 M fy - o n * ^ ff a 0 0 3 h , oooH --y 0. -- _ - 2 r ! i - 6 - 7 - h ' & Q OO C/^ v i/ - 'i d , o ,c?o Y y ?v ?7 .-7 7 % > f p T f^ k 1 7 5 ?. 7 z ~ .-J.i 7 / 2 9 f, Z ... 'X ^'.^P " C om m ente: a -c iV / y ?^ ^ ir-j .... Analyst Date: / - _Prep Analyst / Y / ________ ____________ Date: f / ( % . ( ? T y jyC^-- ' / t^-py Reviewed bvf / C f y j /'Afl T l f Y l ...... V ' " t - l. ........... D a t e : ' ...... 7 /cw-22-ii-o*sra-os/oi , 49 J STMTOeLCthCiondh:iScoaLigllosoyd Kahn 122 Page No.:,. 5211Book No.: Instrument: Phoenix flOOO <TQC4) LabNet Batch: i Date of Standard Curve: i f j 7! C 7 - : TOC (mg/kg) s> ug C / grams sample Book# ' b j m i Pane ' t L I MS, MSD Known Cone, (mg/kg) 100 ug C / grams sample MS, MSD Observed (mg/kg) ug C / grams sample' MS, MSD Rec. * fobserved m g /kflj- eyg, sample re W tt'fmo/kglT x 100 known concentration in mg/kg Standard Traceability: (Note: W orking Standi Sht prepared daily from the noted Stock Solutions.) Stock l (Curve) m Stock II (ICV/CCV), LCS True Value. Acceptance RanQe, Sample ID: lV i '> - i Sample Weight (fl) - : ugC ' C lc .3 / v^ / r ^ Comments: t cUa - - /. --i _ -2 , ... - 0 ,Q C )( s .& oy :O f ,1- o. rr 3 iT oo 2 0 p 7 C ll. fo c .. " -V "70 . rt-y r 7 O ,,& & 0 . jl? . jip '* - \S 0 T .^ _ 1I 7t 5P0 r . 0 / f 1 r i) i ,,2- "( Y , 3 ij [ iw Y .W M % o. o f y f / '2~- , o <r v: .. n .o w Vo $ n O'- ! 0 f/lr^ fC r' ' (JL^./C?:. . ^ :....' .. , ... _ _ XNX _ ....... . -, X .: .. n- ..... ......'wi-1.^:fJv--u.",,.- \i '^..W+K-j-'1' y*- . - 7 7 .. f/;-: _-r'.:^V-V-VA-:;-- -,. .... ..... th:; . - ^ . - Y '7-...,:-" '< ,'V '."' . ........- ...- . \ ' ..^ V Prep Analyst:* ---- .Date: / ,//? Analyst: Date: 7 f Y j i , ' K ( ........ Datar"/ sr CHl-22Lif49m-0W01 r~'liir*nn,n Aft LX IOCS *** RUN LOG *** <vz > 1/24/05 17:12 Total Organic Carbon (Soi^s) Method Code..: TOCS Batch Code...: 140117 Status..... .: RAW Batch Date.. .: 01/24/05 Batch Time.. .: 1637 User Name. ; rnm QC Code...... : TOCS Calc Code.... : TOCS Location Code.. 57222 Equipment Code* Import Code.*,. TEST CODE TT T TTT TTT TT TT cO 0 0 O O 0 O C C I I 1 c c cC C C c s S S C c C s s2 3 4 A A A 2 A S VVV V 2A 234 2 2 SAMPLE: Grp Roe Sample ID Di Lotion TEST POS Date / Time 12 3 4 5 67 1 1 122 2 789 0 12 11 ___ ICAL_l04LSTTC1i_ 1/17/05 0000 0 12 ICV I04LSTTC2 1/19/05 1B30 0 13 ___ICB__ 1/19/05 1B33 0 14 ___ L C S J Q O F S T L K 3 J 5 1/19/05 1843 0 15 LCD I00FSTLK3 3 1/19/05 1850 0 16 233505_5_S___ 1/19/05 1856 0 17 233505_5_S__MS_I04LSTTC2_6 1/19/05 1925 0 1 fi 233505_5_Sj1SD_I04L5TTC2m0 1/19/05 1932 0 19 233505_6_S___ 1/19/05 1941 0 1 10 233505_7_S___ 1/19/05 1957 0 1n 233505_S_S___ 1/19/05 2035 0 1 12 233505_9_S___ 1/19/05 2052 0 1 13 2335Q5J0_S___ 1/19/05 2109 0 1 14 233505J VS,__ 1/19/05 2128 0 1 15 233505_12_S___ 1/19/05 2141 0 1 1 2 3 3 5 0 5 J 3 S ___ 1/19/05 2215 0 1 17 233505 14 S 1/19/05 2234 0 1 1 ,__ CCV_I04LSTTC2_ 1/19/05 2248 0 1 19 ___CCB__ 1/19/05 2251 0 1 20 233505_15_S___ 1/19/05 2257 0 1 21 233505_16_S___ 1/19/05 2309 0 1 22 233505_17_s___ 1/19/05 2322 0 1 23 233506_VS___ 1/19/05 2341 0 1 24 233506 2 S 1/19/05 2352 0 1 25 ___CCV_I04LSTTC2_ 1/19/05 0006 0 1 26 CCB 1/19/05 0009 0 STL Chicago Pago 1 -- 51 *** ac summary *** <VZ ) Total organic carbon (Soils) Report Date: 1/24/05 17:12 Method Code..: TOCS Batch Code...: 140117 Status...... : RAW Batch Date...: 01/24/05 Batch Time...: 1637 User Name :rnm QC Code........ : TOCS Calc Code...... : TOCS Location Code..: 57222 Equipment Code.: Import Code....: Grp Smp Sample ID Pos Test Result Known Original Alternate QC Res F QC Res F 12 13 14 15 17 ___ICV_IQ4LSTTC2_ 1CB ___LC SJ 00 F S T L K 3 J LCD IO0FSTLK3 3 233505_5_S_MSJ 04LSITC2^6 1 TOC 2125.68 1 TOC -2.31 1 TOC 4802.14 1 TOC 4465.78 5 TQCAV2 3764.38 2000 4780 4780 2000 106 -2.31 -2.31 1480.19 4B2.14 100 93 74 7 1 8 233505_5_S_MSDJ04LSTTC2_6 1 18 CCV I04LSTTC2 1 19 ___CCB__ 1 25 ___CCV_I04LSTTC2_ 5 TOCAV2 3134.89 1 TOC 2078.20 1 TOC 3.14 1 TOD 1968.55 2000 2000 2000 1480.19 3764.38 104 98 8 1 26 ,,__ CCB__ 1 TOC 3.80 STL Chicago .. -- Page 1 52 *** RAW TEST DATA *** CV2 ) Total Drganic carbon <SoiU) Method code.. TOCS Batch Zode,,,. 1401 17 Status RAW Batch Date...: 01/24/05 Batch Time.: 1637 User Name.... : rnm SAMPLE Grp Pos Sample ID 11 ICAL IQ4LSTTC1 12 ICV I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 233505 5 S 1 7 233505 5 S MS I04LSTTC2 6 1 8 233505 5 S MSD 04LSTTC2 1 9 233505 6 S 1 10 233505 7 S 1 11 233505 S S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11 S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 IS CCV IQ4LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV J04LSTTC2 1 26 ___CCB__ QC Code....... : TOCS Calc Code..... : TOCS Location Code..: 57222 Di Lution TOC mg/Kg TQC2 mg/Kg Report Date: 1/24/05 17:12 Equipment Code.: Import Code___ : T0C3 mg/Kg TOC4 mg/Kg TDAV2 mg/Kg 2125*68 2.31 4802.14 4465.78 1533.73 3764*38 3134.89 680.30 490.15 19674.39 5484.53 1714.66 13B3.B9 659.43 30439.31 5254.46 2078.20 -3.14 4116.25 1611.45 1153.37 20934.94 5999.47 1968,55 -3.80 1421.65 645.13 214.25 20938.65 4977.54 2256.91 1777.87 849.82 3373S.10 5792.24 4125.66 1419.15 1075.65 27492.02 5682.64 1480.19 3764.38 3134.89 662.74 352.20 20306.52 5231.03 1985.79 1580.88 754.62 32088.71 5523*35 4120.95 1515.30 1114.51 24213.48 5841.06 STL Chicago Page 1 53 *** RAU TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140117 Status...--- : RAW Batch Date...: 01/24/05 Batch Time...: 1637 User Name____ : m m SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTC1 12 ICV I04LSTTC2 13 ICB 14 LCS I0FSTLK3 3 15 LCD IOOFSTLK3 3 1 6 233505 5 S 1 7 233505 5 S MS IQ4LSTTC2 6 1 8 233505 5 S MSD IQ4LSTTC2 6 1 9 233505 6 S 1 10 233505 7 S 1 11 233505 8 S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11 S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 18 CCV I4LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I04LSTTC2 1 26 ___CCB__ QC Code........ : TOCS Cale Code......: TOCS Location Code..: 57222 Dilution T0CAV3 mg/Kg T0CAV4 mg/Kg Report Date: 1/24/05 17:12 Equipment Code.: Import Code---- : T0CR1 ug T0CR2 ug T0CR3 ug 106.284Q -0.3704 130.1381 105.8390 84.9377 233.0150 182.1373 45.2399 30.6343 2D6.5811 144.2431 64.8140 47.6058 38.7084 304.3931 173.3973 103.9098 -0.5022 97.5551 82.5063 61.9362 142.3576 77.3931 98.4275 -0.6080 84.1619 61.4859 18.9826 314.0798 117.9677 105.6234 94.7606 39.9417 232.7929 166.2374 112.2180 101.4690 63.5711 137.4601 249.4678 STIChicago Page 2 54 *** RAW TEST DATA (V2 ) Total Organic Carbon (Soils) Method code.. TOCS Batch Code... 140117 Status...... RAW Batch Date-,: 01/24/05 Batch Time... : 1637 User Name___ : rnm SAMPLE: Grp Pos sample ID 11 ICAL IQALSTTCI 12 ICV I04L5TTC2 13 1CB 14 LCS 00FSTLK3 3 15 LCD I00F5TLK3 3 1 6 233505 5 s 1 7 233505 5 S MS 104LSTTC2 6 1 8 233505 5 S MSD I4LSTTC2 6 1 9 233505 6 S 1 10 233505 7 s 1 11 233505 8 S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11 S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 18 CCV I04LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I04LSTTC2 1 26 CCB Ctc Code... TOCS Calc Code. Tt.. : TOCS Location Code..: 57222 D i lution TQCR4 ua WT1 Q Report Date: 1/24/05 17:12 Equipment Code.: Import Code___ : WT2 WT3 UT4 999 0.05 0.16 0.0271 0.0237 0.0552 0.0619 0,0581 0.0665 0.0625 0.0105 0.0263 0.037B 0.0344 0,0587 0.0100 0.0330 0.05 0.16 0.0237 0.0512 0.0537 0.6B 0.0129 0.05 0.16 0.0592 0.0953 0.0886 0.0150 0.0237 0.0468 0.0533 0.0470 0.0069 0.0287 0,0272 0.0715 0.0591 0.0050 0.0439 STL Chicago Page 3 SS *** RAW TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code*. TOCS Retch Code__ 140117 status...... RAW Hatch Date__; 01/24/05 Retch Time__? 1637 User Name. ... : rnm SAMPLE: Grp Pos Sample ID 11 ICAL IQ4LSTTC1 12 ICV IQ4LSTC2 13 ICB 14 LCS J00FSTLK3 3 15 LCD ID0FSTLK3 3 1 6 233505 5 S 1 7 233505 5 S MS I04LSTTC2 6 1 8 233505 5 S MSD IQ4LSTTC2 6 1 9 233505 6 S 1 10 233505 7 S 1 11 233505 8 S 1 12 233505 9 S 1 13 233505 10 s 1 14 233505 11 s 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 18 CCV I04LSTTC2 1 19 CCE 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I04LSTTC2 1 26 ___CCB QC Code... ___ : TOCS naie Trtria. ___ ; TOCS Location Code..: 57222 Di lut ion DLFAC N/A TCS mg/Kg Report Date: 1/24/05 17:12 Equipment code.: TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.9041 6.7511 2.7972 2.5848 2.7539 1.977B 2.1178 12.5490 6.4000 3.7825 3.6488 3.0274 18.9349 5.1864 3.2000 1-0000 6.2868 2.6080 2.8369 27.1186 5.6338 3.2000 1.0000 RTT, Chicapn Page 4 Calibration Report Print Date/Time: 2005/01/20 0:12:11 Cal. Curve ID : Created: Calibration Factor Y Intercept (b): r-squared: SOILCURVE 01/17/2005 (m) : 8. 538e+04 436425 0,99 800 11:33 Standard ID 0 ugram C lOugramC 20 ugram C 40 ugram C 80 u g r a m C 120 ugram C 200 ugram C 300 ugram C 400 ugram C Y Raw Data "453 0 1085240 1870210 3806480 7357282 11114689 18428840 26478564 33682344 X Expected ug C 0 *000 10.000 20.000 40.000 80.000 120.000 200.000 300.000 400.000 Measured Message ug C -5.165 No Sample Det 7.599 16.794 39.473 81,062 125.072 210.740 305.025 389.401 Date & Time 01/17/2005 09:53 01/17/2005 10:15 01/17/2005 10:26 01/17/2005 10:34 01/17/2005 10:45 01/17/2005 10:58 01/17/2005 11:07 01/17/2005 11:15 01/17/2005 11:32 STL Chicago 57 Multiple Analysis Report Print Date/Time: 2005/01/20 0:11:54 Sample ID Result Std. Dev, RSD Mode ALT ICV 106*2840 ICB -0,3704 LCS 130.1381 L C D ...................................... 105*8390* * * 233505-5 84*9377 233505-5 84*1619 233505-5 M S .............................233*0150.** 233505-5 MSD 182.1373 233505-6 45.2399 2 3 3 5 0 5 - 6 ............................... 61.4 959. .- 233505-7 30.6343 233505-7 18*9826 2 3 3 5 0 5 - 9 ............................... 1049.2341*** 233505-8 206.5811 233505-8 314.0798 2 3 3 5 0 5 - 9 ................................ 144*2431. ** 233505-9 117.9677 233505-10 64.8140 2 3 3 5 0 5 - 1 0 ............................... 105.6234, , , 233505-11 47.6058 233505-11 94.7606 2 3 3 5 0 5 - 1 2 .............................. 38.7084,,, 233505-12 39.9417 233505-13 1049.7812 2 3 3 5 0 5 - 1 3 ............................... 551*7590.** 233505-13 304.3931 233505-13 232.7929 2 3 3 5 0 5 - 1 4 ............................... 173.3973,.. 233505-14 166,2374 CCV 103.9098 C C B ...................................... -0.5022... 233505 -15 97*5551 233505-15 112.2180 2 3 3 5 0 5 - 1 6 .............................. 82*5063.** 233505-16 101.4690 233505-17 61.9362 2 3 3 5 0 5 - 1 7 ............................. 63,5711,.. 233506- 1 675.8541 233506-1 142.3576 2 3 3 5 0 6 - 1 ................................ 137.4601*** 233506-2 77*3931 233506-2 249.4678 C C V ...................................... 98.4275, ., CCB -0,6080 TC TC TC . , . , .TC TC TC ** * * *TC TC TC .. ...TC TC TC ** . . .TC TC TC .* .**TC TC TC .. ***TC TC TC .. . . .TC TC TC ** *.*TC TC TC .. *.*TC TC TC ,, ...TC TC TC *. . ..TC TC TC ,. . , .TC TC TC .. * * *TC TC TC . . . . .TC TC STL Chicago Detailed Analysis Report Print Date/Time: 2005/01/20 0:11:56 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 106 *2840 106.2840 9510653 Mode: TC Filename: 01191825 ^ Timestamp: 01/19/200^18:30^ Sample Type : Cal. Verification Beginning Baseline 2.423 Ending Baseline 3.420 Integration Time 261 Sample ID: ICB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.3704 -0.3704 -5861 Last Message: No Sample Detected Mode: TC Filename: 01191831 Timestamp: 01/19/200 Sample Type: Sample Beginning Baseline 2.002 Ending Baseline 1.962 Integration Time 120 Sample ID: LCS Method; boat Cal. Curve: SOILCURVE Operator ID : CAROL Rep # ppm C ug C Raw Data 1 130. 1381 130.1381 11136586 Mode : Filename : Timestamp : T00C111/ 19 19 8/ 23 800a _ 18 :43 Sample Type : Sample Beginning Baseline 1.891 Ending B a s el 2. i8n8e8 Integration T2i83me Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator id : CAROL Rep # ppm C ug C Raw Data 1 105.8390 105.8390 9062003 Mode: Filename: Timestamp : T00C111/19198/2405 0 5 (l8 i5 0 y Sample Type : Sample Beginning Baseline 2.069 Ending Baseline 3.069 Integration Time 264 Sample ID: 233505-5 Method: boat Cal. Curve: SOILCURVE operator ID: CAROL Rep # ppm C ug C Raw Data 1 84.9377 84.9377 7277504 Mode; Filename: Timestamp: Sample Type: TC 01191851 01/19/2005/18:56^ Sample v Beginning Baseline 2.927 Ending Baseline 3.925 Integration Time 244 STL Chicago 59 Sample ID: 233505-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 84.1619 84 *1619 72112 69 Sample ID: 233505-5 MS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 233.0150 233.0150 19919928 Sample ID: Method: Cal. Curve : Operator ID: 233505-5 MSD boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 182.1373 182.1373 15576131 Sample ID: Method: Cal. Curve : Operator ID 233505-6 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 45,2399 45,2399 3888216 Sample ID: 233505-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm c ug C Raw Data 1 61.4859 61,4859 5275257 Sample ID: 233505-7 STL Chicago Mode: Filename: TC 01191857 Timestamp: 01/19/2005 Sample Type: Sample 19:02 Beginning Baseline 2.603 Ending Baseline 3.600 Integration Time 243 Mode : Filename : Timestamp: Sample Type: TC 01191919 01/19/2005\19:25 Sample Beginning Baseline 1.848 Ending Baseline 2,848 Integration Time 379 Mode: Filename ; Timestamp: Sample Type TC 01191927 01/19/2005X19:32 Sample Beginning Baseline 2,608 Ending Baseline 3.606 Integration Time 282 Mode : Filename : Timestamp: Sample Type: TC 01191937 01/19/200 Sample Beginning Baseline 2,121 Ending Baseline 3.120 Integration Time 241 Mode: TC Filename: 01191945 Timestamp: 01/19/2005 Sample Type: Sample 19:50 Beginning Baseline 1.844 Ending Baseline 2,842 Integration Time 253 Mode : TC 60 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 30,6343 30.6343 Raw Data 2641238 Sample ID: Method: Cal. Curve : Operator ID: 233505-7 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 18.9826 18.9826 1646448 Sample ID: Method: Cal. Curve: Operator ID: 233505-8 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 1049.2341 1049.2341 89606408 Last Message: Over-range Sample ID: Method: Cal. Curve: Operator ID 233505-8 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 206,5811 206.5811 17663076 Sample ID: Method: Cal. Curve : Operator ID: 233505-8 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 314,0798 314.0798 26841016 Sample ID: Method: 233505-9 boat Filename: 01191953 Timestamp: 0 1 / 1 9 /20Q5... 19 :57 Sample Type: Sample ~~ Beginning Baseline 2,012 Ending Baseline 3 .Oil Integration Time 230 Mode: Filename : Timestamp: Sample Type: TC 01192007 01/19/2005 Sample 20:12 Beginning Baseline 1.486 Ending Baseline 2.484 Integration Time 204 Mode : Filename : Timestamp: Sample Type: TC 01192017 01/19/200^ 2 Sample Beginning Baseline 1.686 Ending Baseline 2,728 Integratu Time 480 Mode: Filename : Timestamp : Sample Type: TC 01192030 01/19/200^20:35 Sample --- Beginning Baseline 2,915 Ending Baseline 3.913 Integration Time 278 Mode : Filename: Timestamp : Sample Type TC 01192038 01/19/2005 Sample 20:44 Beginning Baseline 2.163 Ending Baseline 3.160 Integration Time 311 Mode: Filename : TC 01192047 Cal * Curve ; SOILCURVE Operator ID : CAROL Rep tt ppm C ug C Raw Data 1 144.2431 144.2431 12340832 Sample ID: 233505-9 Method: boat 2058 Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 117.9677 117.9677 10097516 Sample ID: Method: Cal. Curve : Operator ID 233505-10 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 64.8140 64.8140 5559399 Sample ID: Method: Cal. Curve: Operator ID; 233505-10 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 105.6234 105.6234 9043590 Sample ID: Method: Cal. Curve : Operator ID: 233505-11 boat SOILCURVE CAROL Rep tt ppm C ug C Raw Data 1 47.6058 47.6058 4090212 Sample ID: Method: Cal, Curve : Operator ID 233505-11 boat SOILCURVE CAROL STL Chicago Timestamp: 01/19/20oC p"r52^ Sample Type : Sample Beginning Baseline 2.327 Ending Baseline 3.323 Integration Time 261 Mode: Filename: TC 0119 Timestamp: 01/19/2005 21;04 Sample Type: Sample Beginning Baseline 1.660 Ending Baseline 2.660 Integration Time 319 Mode : TC Filename : 01192105 ^ r r' Timestamp : 01/19/200^21:09' Sample Type : Sample Beginning Baseline 2.165 Ending Baseline 3.160 Integration Time 238 Mode; Filename: Timestamp: Sample Type: TC 01192110 01/19/2005 Sample 21:15 Beginning Baseline 2.147 Ending Baseline 3.145 Integration Time 266 Mode: Filename : Timestamp: Sample Type: TC 01192124 01/19/2005: 21:2; Sample Beginning Baseline 1.546 Ending Baseline 2.542 Integration Time 233 Mode : Filename : Timestamp: Sample Type TC 01192129 01/19/2005 21:34 Sample A7 Rep # 1 ppm C 94.7606 ug C Raw Data 94.7606 8116156 Beginning Baseline 1.939 Ending Baseline 2.938 Integration Time 263 Sample ID: 233505-12 Method: boat Cal. Curve : SGILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 38.7084 38.7084 3330582 Mode : Filename: Timestamp: Sample Type: TC 01192136 01/19/2005' Sample 1:41 Beginning Baseline 1.820 Ending Baseline 2.818 Integration Time 234 Sample ID: Method: Cal. Curve: Operator ID 233505-12 boat SOILCURVE CAROL Rep # 1 ppm C 39.9417 ug C Raw Data 39.9417 3435879 Mode : Filename: Timestamp: Sample Type: TC 01192143 01/19/2005 Sample 21:48 Beginning Baseline 1.684 Ending Baseline 2.682 Integration Time 237 Sample""ID-t.,...._ 233505-13 Method: boat C a l . Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 1049.7812 1049,7812 89 65312 8 Last^Message: Over-range Mode : Filename: Timestamp: Sample Type: TC 01192154 01/19/2005 Sample 22:01 "Beginning Ending B a s2e.1i9i5i i e - B"a"^s-e3l.-i1n9e4 Integration Time 403 Sample ID: Method: Cal. Curve: Operator ID: 233505-13 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 551,7590 551.7590 47133388 Mode: TC Filename: 01192202 "^-- --..Timestamp: 01/19/2005 Sample,_.3?ype: Sample 22:08 Beginning Baseline 2.805 Ending " ---Integration Baseline T i m e .. 3.804 327 Sample ID: 233505-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode : Filename : Timestamp: Sample Type: TC 01192209 0l/l9/2005/'22:15 Sample , STL Chicago Rep # ppm C 1 304.3931 ug C Raw Data 304.3931 26013986 Sample ID: 233505-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 232,7929 232,7929 Raw Data 19900968 Sample ID: Method: Cal. Curve: Operator ID: 233505-14 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 173.3973 173.3973 14829940 Sample ID: Method: Cal. Curve: Operator ID 233505-14 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 166.2374 166.2374 14218644 Sample ID: Method: Cal, Curve : Operator ID CCV boat SOILCURVE CAROL Rep # ppm C ug C 1 103,9098 103.9098 Raw Data 9307950 Sample ID: Method: Cal, Curve : Operator ID: CCB boat SOILCURVE CAROL Rep ff ppm C ug C Raw Data 1 -0,5022 -0.5022 -17112 STL Chicago Beginning Baseline 2.542 Ending Baseline 3.540 Integration Time 307 Mode: TC Filename: 01192217 Timestamp: 01/19/2005 22:22 Sample Type: Sample Beginning Baseline 2.278 Ending Baseline 3.277 Integration Time 298 Mode : Filename : Timestamp: Sample Type: TC 01192226 01/19/200 Sample Beginning Baseline 1.880 Ending Baseline 2.880 Integration Time 295 Mode : Filename : Timestamp : Sample Type: TC 01192235 01/19/2005 Sample 22:40 Beginning Baseline 2.120 Ending Baseline 3.116 Integration Time 275 Mode: Filename : Timestamp: Sample Type TC 01192242 01/19/2005^22:48") Cal. Verification Beginning Baseline 1.955 Ending Baseline 2.952 Integration Time 266 Mode : Filename: Timestamp: Sample Type: TC ^ ^ 01192248 01/19/200^22:51 Sample Beginning Baseline 1.890 Ending Baseline 1.681 Integration Time 120 64 Last Message: No Sample Detected Sample ID: 233505-15 Method: boat Cal * Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 97,5551 97.5551 8354745 Sample ID: 233505-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data Baseline 1 112.2180 Time 112.2180 9606623 Sample ID: Method: Cal. Curve: Operator ID 233505-16 boat SOILCURVE CAROL Rep # 1 ppm C 82.5063 ug C Raw Data 82.5063 7069917 Sample ID: Method: Cal. Curve: Operator ID: 233505-16 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 101.4690 101.4690 8688906 Sample ID: Method: Cal, Curve: Operator ID: 233505-17 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 61.9362 61,9362 5313701 STL Chicago Mode: Filename: Timestamp: Sample Type: TC 01192252 01/19/2005^22:57') Sample --- y Beginning Baseline 2.110 Ending Baseline 3.109 Integration Time 255 Mode: TC Filename: 01192258 Timestamp: 01/19/2005 23:02 Sample Type: Sample Beginning Baseline Ending Integration 2.149 3.145 258 Mode : Filename: Timestamp : Sample Type TC 01192305 r T -- 0 1 / 1 9 / 2 0 0 ^ 2 3 :09 Sample Beginning Baseline 2.346 Ending Baseline 3.342 Integration Time 247 Mode: TC Filename: 01192311 Timestamp: 01/19/2005 Sample Type: Sample 23:16 Beginning Baseline 2,351 Ending Baseline 3.349 Integration Time 262 Mode: Filename : Timestamp: Sample Type TC 01192317 01/19/20(^5 23:2 Sample Beginning Baseline 2,265 Ending Baseline 3.261 Integration Time 239 65 Sample ID: 233505-17 Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep tt ppm C ug C Raw Data 1 63.5711 63.5711 5453285 Sample ID: ' 33506-1 Method: ^oat C a l . CU'^ve: S Operator ID: CA j Rep # ppm C ug C 1 675.8541 6^.8541 Raw Data 57728284 Sample ID: 233506-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Rw Data 1 142.3576 142.3576 121^9852 Sample ID: 2335Q6-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 137.4601 137.4601 11761723 Sample ID: 233506-2 Method: boat Cal. Curve: SOILCURVE O p erator ID: CAROL Rep # ppm C ug C Raw Data 1 77.3931 77.3931 6633365 Mode : TC Filename : 01192323 Timestamp: 01/19/2005 23:28 Sample Type : Sample Beginning Baseline 2.206 Ending Baseline 3.205 Integration Time 242 Mode : TC Filename: 01192329 Timestamp: 01/19/2005 Sample Type: Sample 23:35 Beginning Baseline 2.140 " Ending Baseline' 3.137 Integration ______ T i m e Mode: Filename: Timestamp: T00C111/19923/23060 5 (2 3 j4 1 Sample Type: Sample ) Beginning B a s e2 l. 7i3n6e Ending Baseline 3.735 Integration Time 258 Mode : TC Filename : 01192341 Timestamp: 01/19/2005 Sample Type: Sample 23:47 Beginning Baseline 2.362 Ending B a s e3 l. 3i6n2e Integration T2 7i1m e Mode: 'ilename: mestamp: pie Type: TC 01192347 ^ --- 01/19/200^ 23:52 Sample Beginning Baseline 2.411 Ending Baseline 3.409 Integration Time 246 STL Chicago 66 Sample ID: 233506-2 Method: boat \ Cal. Curve: SOILCURV^ Operator ID: CAROL \ Rep # ppm C ug C \ R a w Data 1 249 *4678 249*4678 21^24626 Sample ID: Method: Cal. Curve: Operator ID: CCV boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 98*4275 98.4275 8839886 Sample ID: CCB Method: boat Cal* Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.6080 -0*6080 -26143 Last Message: No Sample Detected Mode: TC Filename: 01192354 Timestamp: 01/20/2005 Sample Type: Sample 00 :00 Beginning Baseline 1*822 Ending Baseline 2*822 Integration Time 308 Mode: TC Fi1ename: 01200001 Timestamp: 01/20/200^._00 :06 Sample Type: Cal. Verification Beginning Baseline 2.236 Ending Baseline 3*233 Integration Time 258 Mode: Filename : Timestamp: Sample Type: TC 01200006 >--7-- 01/20/2005^ 00:09 J Sample "" ^ -- r Beginning Baseline 2.073 Ending Baseline 1.744 Integration Time 120 KTT f'h irin & ii No.;_ cNo,: n 122 i t Phoenix 8000 fTOC41 Batch:_____________ _ Curve:___ ,__ Page #_ ne noted Stock Solutions.) MTSOTeLCthCoindh:SicoLaigllosoyd Kahn Calculations: TOC {m g/kg) ug C / grams sample Page No. 123 Bo_o_k__N_o_..1^ Y V 4 ' ct- 4Instrument: phoenix_gPQCL(TQC ) LabNet Batch: M O 1.1 Date o f Standard P un/sTT.I n f C ^ _ MS, MSD Known Cone, (mg/kg) 100 ug C / grama sample Book # Page * f ---- MS, MSD Observed (mg/kg) ug C / grams sample MS, MSD Re*. fobaerved mq/ko - avo, sample result fma/koH x 100 known concentration In mg/kg Standard T racea bility; (N ote: W orking Standards are prepared daily from the noted Stock Solutions.) stock I (CurveC E O P i A S tT C 1 Stock II (ICV/CCV) t X o 4 < - S T T t 2 Sample ID: 1Samnia -* 1LCS Source ip ^ C p ^ S T ^ LCS True Valuatl~ 7 fiD u rjifa Acceptance Range 1*109.0 STL Chicago MTSOTeLCthCoIndh:iScoaLigllosoyd Kahn Page No.: ,, _ 124 B k No.: 3 . ? ^ Instrument: Phoenix 6000 fTOC4i LabNet Batch: 1 *4 0 J fT - C alculations; Date of Standard Curve: ) f f lp ? T : TOC (mg/kg) u g C / grama sample Book # MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample 3 7 if7 Paoa # f ) I MS, MSD Observed (mg/kg) ug C f grams sample MS, MSD Rec. - [observed mo/kd - avg, sample result fmo/Ko)l x 100 known concentration In mg/kg Traceability:Standard (Note: W orking Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) stock ll (iC v/C C Vi ... ' '_ ' LCS Source ID LCS True Value Acceptance Range___________________ Sample ID: Sample Weight (o) > .. Commente: * -.OM 0 -- ^ ..: ..m3 ..... - .. 0 . 0 IQr}' .. 1UAJlH|QnVTfTQC/1r->3 j j / j * " f. s^in&C -..~ - 0' :0O33ir0^- lO&l m /sn ... . CCI/: .CCS -- 15 -/ .....~/=3 c>.o<3?n "iaTnTtSS^ ; o .v , - i ' - I03.(C& .IU ..L^-iscfita. o . o 'f-: 9-705I 0 . n r n - - ,ii-9'ai&) a. 0 5 1 a Q.SOizfl ; ' O. 0 7 5 ; . 1 0 1 :`4(cTiO -b ; 7. ; .'.c . .... .. . z . .......................... / - o.osQf b3:577l" 1rv, ^. "--CT\lgA^a 5 b ' 0 : OOt MSrdSK - .... H - -, \ >*.......*-&5- 00. oO-O'a5^0T r&sltbt VC-Wil s m M 16 f Co/--... `CS' 0.I<J>- ........... V S fta fy -7V(nA?r1 Prep Analyst:^ ARnevaliyeswt:edA fJL X Date: i/^l . Pate:iim -" Olfl: : Date:' ^rri-'/S^ ''' : ' CHIt22-12-(l9Sm-0SrO1 STL Chicago AO LK T ic *** RUN LOO #** 3^ (V2 ) 1/28/05 12:56 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code__ ; 140127 Statua....... : RVWD Batch Date...: 01/24/05 Batch Time__ : 2239 User Name.... .: rnfii QC Code...... TOCS Calc code___ _ Location Code..: 57222 Equipment Code.: Import Code___ : TEST CODE TTTTTTTTTTTTT s sO O O 0 0 0 0 C C C I I I CCCCcccs CCC 234AAA 2ASSS VVV V 2A 234 2 2 SAMPLE; Grp Pos Sample ID D i lution TEST POS DBte / Time 1234 56 7 1 11222 789 0 12 11 ___ICAL__ 0 12 13 14 ___ICV_I04LSTTC2_ ___ ICB__ ___LCS_I0DFSTLK3_3 1/21/05 1643 0 1/21/05 1646 0 1/21/05 1654 0 15 16 17 18 19 1 10 LCD I00FSTLK3 3 233506_6_S___ 233505_3_S___ 233506_3_S___ 2335 06_3_S_MS_104LSTTC2_8 Z33506_3_S_MSD_IQ4LSTTC2_B 1/21/05 1700 0 1/21/05 1713 1/21/05 1726 1/21/05 1737 1/21/05 1754 0 1/21/05 1801 0 0 0 0 0 0 1 11 1 12 1 13 1 14 1 15 233506_4_S___ 233506_5_S___ 233506_7_S___ 233506 8 S 233506_9_S___ 1/21/05 1807 1/21/05 1818 1/21/05 1829 1/21/05 1843 1/21/05 1858 0 0 0 0 0 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 233506_10_S___ 233506_11_S___ ___CCV_IQ4LSTTC2_ ,___CCB__ 233506J 2 _ S ___ 233506 13 S___ 233506 14 S 233506_15_S___ 2 3 3 5 0 6 1 6 5 ___ 233506_17_S___ 233506_18__S___ 2 3 3 5 0 6 1 9 S ___ _CCVJ04LSTTC2_ Pano 1 1/21/05 1909 1/21/05 1920 1/21/05 1942 0 1/21/05 1945 0 1/21/05 1952 1/21/05 2007 1/21/05 2021 1/21/05 2033 1/21/05 2045 1/21/05 2057 1/21/05 2107 1/21/05 2120 1/21/05 2133 0 -- 0 0 0 0 0 0 0 0 0 0 STL Chicago 70 *** RUN LOG *** V2 ) 1/28/05 12:56 STL Chicago Page 2 71 *** QC summary *#* tn ) Total Organic Carbon (Soils) Report Date: 1/24/05 23:07 Method Cade,.: TOCS Batch Code...: 140127 Status...... : RAW Batch Date...: 01/24/05 Batch Time.,,: 2239 User Name____: rnm QC Code....--- : TOCS Calc Code..... : TOCS Location Code..: 57222 Equipment code.: Import Code----: Grp Smp SampLe ID Po$ Test Result Known Original Alternate QC Res F QC Res F 1 2 ___ICV_I04LSTTC2_ 1 TOC 2033.16 2000 102 1 3 ___ICB__ 1 TOC -3,55 1 4 ___LCS_IO0FSTLK3_3 1 TOC 4013.62 4780 -3.55 84 15 19 LCD I0FSTLK3 5 233506_3_S_MS_I04LSTTC2_8 1 TOC 1 TOC 4204.36 9686.34 4780 2000 -3.55 5566.22 4013.62 88 92 5 -- 1 10 233 506_3_S_MSD_104LSTTC2_8 5 TQCAV2 9686.34 1 TOC 9583.28 2000 2000 4978.99 5566.22 9686.34 92 97 18.9 5 T0CAV2 9583.28 2000 4978.99 9686.34 97 18.9 1 18 :__ CCV_I04LSTTC2_ 1 TOC 1994.52 2000 100 1 19 ___CCB__ 1 TOC -3,98 1 28 CCV I04LSTTC2 1 TOC 2052.63 2000 103 1 29 ___CCB__ 1 TOC -3.33 STL Chicago nage 1 72 AAA RAU TEST PATA AA* (V2 ) Total Organic carbon Soils) Method Code.. : TOCS Batch Code... : 140127 Status...... : RAW Batch Date.. : 01/24/05 Batch Tme.. : 2239 User Name,r. : rnm SAMPLE: Grp Pos Sample IP 11 ICAL 12 ICV I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I0FSTLK3 3 1 6 233506 6 S 1 7 233505 3 S 1 8 233506 3 S 1 9 233506 3 S MS I041STTC2 8 1 10 233506 3 S MSD I04LSTTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 8 S 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 11 S 1 18 ccv I04LSTTC2 1 19 CCB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 28 CCV I04LSTTC2 1 29 ___CCE__ QC Code....... : TOCS Cale Code..,... : TOCS Location Code,. : 57222 Piluticn TOC mg/Kg TOC2 mg/Kg Report Pate: 1/24/05 23:07 Equipment Code.: Import Code___ : TOC3 mg/Kg TOC4 mg/K T0CAV2 mg/Kg 2033.16 3.55 4013,62 4204.36 29617.40 15624.60 5566.22 9686.34 9583.28 1519.47 786,08 5113.65 2005.07 1921.46 1168.77 23659.B4 1994.52 -3.98 11049.30 3014.50 1979.26 1409.13 578.72 5986.11 571.29 983.29 2052.63 -3.33 24872,29 10795.43 4391,76 762.24 418.61 4046,57 1693.53 1864.13 1006.59 26215.18 10499.02 1928,52 2226.09 1335.91 319.53 5356.64 762.67 575.74 27244.85 13210.01 4978.99 9686.34 9583.2B 1140.86 602.35 4580.11 1849.30 11809827.,6880 24937.51 10774.16 2471.51 2102,68 1372.52 449.12 5671.38 666.98 779.51 STL Chicago Page 1 *** RAW TEST DATA *** CV2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140127 Status.RAW Batch Date...; 01/24/05 Batch Time...: 2239 User Name___ : rnm SAMPLE: Grp Pos Sample id 11 ICAL 12 lev I04LSTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3_3 1 6 233506 6 S 1 7 233505 3 S 1 8 233506 3 S 1 9 233506 3 S MS I04LSTTC2 8 1 10 233506 3 S NSD I04LSTTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 8 S 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 11 S 1 IS CCV I04LSTTC2 1 19 CCB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 28 CCV I04LSTTC2 1 29 CCB QC Code........: TOCS Calc Code..... : TOCS Location Code..; 57222 Dilution TCAV3 mg/Kg TQCAV4 mg/Kg Report Date: 1/24/05 23:07 Equipment Code.: Import Code____: T0CR1 ug T0CR2 ug T0CR3 ug 101.6581 -0.5634 103.9527 129.9146 213.2453 201.5574 59.0019 189.8522 202.2072 31.7570 33.6442 207.1029 102.8601 113.9303 66.1523 257.8923 99.7258 -0.6372 155.7952 206.4931 94-6084 72.7111 29.5145 150.8500 23.1942 32.5469 102.6316 -0.5323 161.6699 68.0112 95.3011 23.0196 23.5676 150.5324 100.9346 94.BB41 78.2121 133.6974 36.0920 79.8409 117.7600 84.4298 28,2141 137.1299 44.0822 36.5594 STL Chicago -.. -- Page 2 Id *** RAU TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code Batch Code. statua...r. TOCS 140127 RAU Batch Date.., 01/24/05 Batch Time.., 2239 User Name___ .: rnm SAMPLE: Grp Pos Sample ID 11 ICAL 12 ICV I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I0FSTLK 3 1 6 233506 6 S 1 7 233505 3 S 1 S 233506 3 S 1 9 233506 3 S MS I04LSTC2 8 1 10 233506 3 S MSD I04LSTTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 8 S 1 15 233506 9 S 1 16 233506 10 $ 1 17 233506 11 S 1 IS CCV I04LSTTC2 1 19 CCB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 28 CCV I04LSTTC2 1 29 CCB oc code.. .... ,7 TOCS Cale Code ..... : TOCS Locat ion Code..: 57222 Di luti on TQCR4 us UT1 g Report Date; 1/24/05 23:07 Equipment Code.: import Code___ : UT2 WT3 9g 0.05 0.16 0.0259 0.0309 0.0072 0.0129 0.0106 0.0196 0.0211 0.0209 0.042B 0.0405 0.0513 0.0619 0.0566 0.0109 0.05 0.16 0.0141 0.0685 0.0478 0.0516 0.0510 0.0252 0.0406 0.0331 0.05 0.16 0.0065 0.0063 0.0217 0.0302 0.0563 0.0372 0.0596 .0SQ9 0.0777 0.0051 0.0082 0.0414 0.0529 0.0632 0.0883 0.0256 0.0578 0.0635 STL Chicago Page 3 1*\ *** RAU TEST DATA *** <V2 ) Total Organic carbon (SoiLs) Method Code..: TOCS Batch Code...: 140127 Status.... .RAW Batch Date...: 01/24/05 Batch Time...: 2239 User Name :rnm SAMPLE: Grp Pos 111 1 2 3 14 15 11 6 7 11 1 1 1 9 9111102 1 13 1 14 1 15 1 16 1 17 1 18 1 1 2109 1 21 1 22 1 23 1 24 1 25 1 2 1 27 1 28 1 29 Sample ID ICAL ___ICV_104 LSTTC2_ ___ ICB__ ___ LCS_I0FSTLK3_3 ___LCD IOOFSTLK:3_3 2335Q" S,___ 233505" 3" s___ 2335 06_3_S___ 233506_3_S MS I04LSTTC2 8 233506 3 S"MSD I04LSTTC2_8 233506TM4~S~ ^ 233506_5_S___ 233506 7_S___ 233506^8 S___ 233506~9~S 233506_10_S___ 233506_11 S___ CCV I04LSTTC2 ___ CCB^_ 233506_12_S___ 233506 13_S___ 233506J 4 _ S ___ 233506 15 S__ 233506" 16^5___ 233506 17 S___ 233506^1S"s___ 233506^19" s___ ___ C C V J 0 4 L S T T C 2 _ ccb" GC Code........ : TOCS Calc Code......: TOCS Location Code..: 57222 Dilution DLFAC N/A CS mg/Kg Report Date: 1/24/05 23:07 Equipment Code.: Import Code____ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 31..02000000 6.1776 5.1780 23.3577 16.6667 9.9071 8.1633 7.5829 6.2622 3.2291 4.1184 2.8855 2.8369 22.03.0802070 31..02000000 14.3498 2.9117 3.1778 2.7875 2.2972 6.2992 3.2520 3.3126 31..02000000 STL Chicago ---- Page 4 7A Calibration Report Print Date/Time; 2005/01/21 21:37:01 Cal, Curve I D : Created: Calibration Factor Y Intercept (b): rTMsquared: SQILCURVE 01/17/2005 (m) : Q 538e+04 436425 0.99800 11:33 Standard ID 0 ugram C lOugramC 20 ugram C 40 ugram C 80 u g r a m C 120 ugram C 200 ugram C 300 ugram C 400 ugram C Y Raw Data -4530 1085240 1870210 3806480 7357282 11114689 18428840 26478564 33682344 X Expected ug C 0.000 10.000 20.000 40,000 80,000 120.000 200.000 300,000 400.000 Measured Message ug C -5.165 No Sample Det 7.599 16.794 39,473 81,062 125.072 210.740 305,025 389.401 Date & Time 01/17/2005 01/17/2005 01/17/2005 01/17/2005 01/17/2005 01/17/2005 01/17/2005 01/17/2005 01/17/2005 09:53 10:15 10:26 10:34 10:45 10:58 11:07 11:15 11:32 STL Chicago 77 Multiple Analysis Report Print Date/Time: 2005/01/21 21:39:44 Sample ID Result Std. Dev, RSD Mode ALT ICV 101,6581 ICB -0,5684 LCS 103,9527 L C D ........................... . 233506-6 474,9272 233506-6 213,2453 233506-6 ............................... 161,6699,,, 233505-3 233505-3 201,5574 68,0112 233506-3 ............................... 59,0019. .. 233506-3 95,3011 233506-3 MS 189,8522 233506-3 M S D ................. ......... 202,2072. . . 233506-4 31.7570 233506-4 23.0196 2 3 3 5 0 6 - 5 ............................... 33.6442 ... 233506-5 23.5676 233506-7 207.1029 2 3 3 5 0 6 - 7 ............................... 150.5324,,, 233506-8 102.6601 233506-8 100,9346 233506-9 ...................... ........ 118,9383.. . 233506-9 94,8841 233506-10 66.1523 2 3 3 5 0 6 - 1 0 ..................... ........ 78.2121... 233506-11 257.8923 233506-11 413.2112 2 3 3 5 0 6 - 1 1 ..................... ccv ........ 133,6974... 99,7258 CCB -0,6372 233506 - 1 2 .................... ,........ 155,7952. . . 233506-12 86.0920 233506-13 206.4931 233506-13 ..................... ........ 79,8409... 233506-14 94.6084 233506-14 117,7600 2 3 3 5 0 6 - 1 5 ..................... ........ 72.7111... 233506-15 84,4298 233506-16 29.5145 233506 - 1 6 .................... ......... 28,2141. . . 233506-17 150.8500 233506-17 137.1299 233506-18 .................... ......... 23.1942 ... 233506-18 44.0822 233506-19 32.5469 233506-19 .................... ......... 36.5594, . . CCV 102.6316 CCB -0.5328 TC TC TC .. .TC TC TC . . .TC TC TC .. .TC TC TC . . -TC TC TC ,, ,TC TC TC . . .TC TC TC . . .TC TC TC - , ,TC TC TC . . ,TC TC TC . . .TC TC TC . . .TC TC TC . . .TC TC TC ., ,TC TC TC , . .TC TC TC , , ,TC TC TC S'I L Chicago 70 Detailed Analysis Report Print Date/Time: 2005/01/21 21:39:46 Sample ID: Method: Cal. Curve: Operator ID: ICV boat SOILCURVE CAROL Rep # ppm C 1 101.6581 ug C 101.6581 Raw Data 9115704 Mode: Filename: Timestamp: Sample Type: TC 01211635 01/21/2 QCLl 6;43 ) Cal. VerificaUiUn Beginning Baseline 2.178 Ending Baseline 3.174 Integration Time 346 Sample ID: ICB Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.5684 -0.5684 -22765 Last Message : No Sample Detected Mode : Filename: Timestamp: Sample Type: TC 01211643 01/21/200^ 16:46 Sample --- Beginning Baseline 2.887 Ending Baseline 2.559 Integration Time 120 Sample ID: Method: Cal. Curve: Operator ID: LCS boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 103.9527 103.9527 8900951 Mode: TC Filename: 01211649 Timestamp: 01/2l/200jl6 :54\ Sample Type : Sample --- Beginning Baseline 2.377 Ending Baseline 3.376 Integration Time 263 Sample ID: Method: Cal. Curve : Operator ID LCD boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 129.9146 129.9146 11117508 Mode : Filename: Timestamp : Sample Type TC 01211654 01/21/2005 'f7~:Q0 Sample ^ --" Beginning Baseline 2.703 Ending Baseline 3.699 Integration Time 273 Sample ID: Method: Cal. Curve: Operator ID: boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 474.9272 474.9272 40573712 Mode: TC Filename: 01211700 Timestamp: 01/21/2005(^17:061 ample Type: Sample Beginning Baseline 3.059 Hindi Baseline 4.057 Integration Time STL Chicago 70 Sample ID: 233506-6 Method: boat \ Cal. Curve: SOILCURVE Operator ID: CAROL \ Rep # ppm C 1 213.2453 ug ^ Raw Data \ 2 13. 2453\ 18232048 Mode: TC Filename : Timestamp: 01211707 0l/2l/204jT7TT^ Sample Type: Sample Beginning Baseline 3,593 Ending Baseline 4.591 Integration Time 333 Sample ID: 233506-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug c 1 161.6699 161 *6699 Raw Data 13828681 Mode : Filename: Timestamp: Sample Type TC \ 01211715 0l/2 l/2Q G5f IT^TsTN Sample Beginning Baseline 3.184 Ending Baseline 4,179 Integration Time 259 Sample ID: Method: Cal, Curve : Operator ID 233505-3 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 201.5574 201.5574 17234164 Mode : Filename : Timestamp: Sample Type TC 01211720 ^ 01/21/200^^17:26 Sample Beginning Baseline 2.823 Ending Baseline 3,821 Integration Time 294 Sample ID: 233505-3 Method: boat Cal Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 68.0112 68,0112 5832365 Mode : Filename : Timestamp : Sample Type TC 01211727 01/21/2005 Sample 17:31 Beginning Baseline 3.022 Ending Baseline 4.016 Integration Time 231 Sample ID: 233506-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data^ 1 59.0019 59.0019 5063184 Mode: TC Filename: 01211733 Timestamp: 01/21/200 Sample Type: Sample Beginning Baseline 2,674 Ending Baseline 3.668 Integration Time 244 Sample ID: 233506-3 N Mode: TC STL Chicago 80 Sample I D T ^ ^ 3 3 5 0 6 - 1 1 Method: bo^l Ca l . Carve: SOT^CURVl Operator ID: CAROL Rep # ppm C 1 413,2112 \ug C \, 413^112 \ Sample ID: Method: Cal. Curve : Operator ID 233506-11 boat SOILCURVE CAROL \ Raw Data 35304576 \ \ Rep # ppm C ug c Raw Da 1 133.6974 133.6974 11440474 Sample ID: Method: Cal * Curve : Operator ID: CCV boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 99-7258 99.7258 8950736 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.6372 -0.6372 -28635 Last Message: No Sample Detected Sample ID: 233506-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 155,7952 155.7952 Mode : TC Filename: 01211922 Timestamp: 01/21/2005 Sample Type: Sample 19:28 BeglTming, Ending B a s e l i n e ^ ^ ^ ' BHCs!Ce`l'1ine 2 *600 97 Integration Time 328 Mode: Filename: Timestamp: Sample Type: TC 01211929 01/21/2005 Sample 19:34 Beginning Baseline 2.947 Ending Baseline 3,947 Integration Time 254 Mode : Filename : Timestamp: Sample Type TC 01211936 _ 0 1 / 2 1 / 2 0 0 1 ^ 19 : 42j] Cal VerificJaLln Beginning Baseline 2.293 Ending Baseline 3.292 Integration Time 310 Mode: Filename : Timestamp: Sample Type: TC 01211943 01/21/2 005^19:45^ Sample Beginning Baseline 2.685 Ending Baseline 2.279 Integration Time 120 Integration Time 266 STL Chicago SI