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In-House Labeling 1985 December 16 Page 6
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received
A. B. Plecka, Vernon Works
. i 0 1^3d
C. M. Reilly, Vidalia Works
J. A. Mlllect, Warrick Operations
PATRICK R. ATKINS
Marcia Dalrymple, Washington Office
J. A. Thompson, Wenatchee Works
J. D. Generous, American Powdered Metals, Conover, NO
J. D. Draper, American Powdered Metals, North Haven, CT
K. R. Lally, Buckeye Molding, New Vienna, OH
C. R. Seltzer, HC Products, Princeville, IL
M. E. Sigler, Kessler Premium Castings, El Paso, TX
J. Jackson, Pep Industries, Nashville, TN
W. R. Waymire, Rea Magnet Wire, Buena Vista, VA
W. J. Schilling, Rea Magnet Wire, Lafayette, IN
D. L. Handy, Rea Magnet Wire, Laurinburg, NC
H. P. Otis, Rea Magnet Wire, Ft. Wayne, IN
J. Liggett, Stolle Corporation, Sidney, OH
J. Nichols, Tifton Aluminum, Delhi, LA
R. B. Reeves, Tlfon Aluminum, Tifton, GA
R. D. Johnson, Vanexco, Vancouver, WA
J. R. Archibald, Pittsburgh - 6 P. Sr Atkinsr Pittsburgh - 7 * H. D. Belk, M.D., Pittsburgh - 6 T. B. Bonney, Pittsburgh - 6 J. W. Brust, Pittsburgh - 16 J. Damiano, Pittsburgh - 6 L. Delf, Pittsburgh - 6 B. D. DInman, M.D., Pittsburgh - 30 R. P. Eaganhouse, Pittsburgh - Annex 1 L. M. Fratto, Pittsburgh - 14 D. E. Huddleston, Pittsburgh - 6 J. McMahon, Pittsburgh - 16 R. Sharkey - Pittsburgh - 6
729585 0002
FROM R. M. JAMES F. W. HECKER PITTSBURGH OFFICE
T0 SEE DISTRIBUTION
1985 December 16
RE: Ref:
ALCOA IN-HOUSE LABELING PROGRAM - OSHA HAZARD COMMUNICATION STANDARD (21 CFR 1910.1200) R. M. James' Letter of 1985 July 23 Entitled "In-House Labeling Program"__________________________________________________________________________________________
The Alcoa in-house hazardous materials labeling program is now complete. A national agreement with Standard Register will be issued and distributed to the field in the immediate future. A local agreement should be issued by you subsequent to receiving the national agreement for meeting your label requirements.
Enclosed with this correspondence is a sample of the proper ordering form (Attachment A) to be used by your Procurement personnel. Local Hazardous Materials Coordinators are responsible for providing the Procurement personnel with their label requirements, which include:
1. label number 2. name of the material 3. appropriate MSDS number for the material 4. vendor stock number (to complete the proper vendor stock number
for "D - DANGER," "C - CAUTION," or "P - UNPRINTED," reference Attachment B below) 5. quantity of labels required.
There have been 47 different label formats developed (see Attachment B). These assure that the proper hazard warnings etc., are given for the material. For mixtures containing more than one hazardous material, the more severe hazard warning shall be employed. If materials are found that do not have an appropriate format, contact R. M. James in Pittsburgh for creation of a new format. Reference Attachment C for an index of hazardous materials and the applicable label format.
This program pertains to hazardous materials stored in Alcoa containers. Portable containers must be labeled directly. The only exception to this is portable containers used by the same individual within the same work shift. Stationary containers can either be directly labeled or the label information can be contained in or accompany a batch ticket, process flow sheet, etc. For stationary containers, we suggest that direct container labeling be restricted to truly hazardous situations (e.g., flammables, combustibles, explosives, corrosives, etc.).
While labeling requirements pertain to plant chemicals, as well as quality control samples, hazardous chemicals used in laboratories should also be covered.
0 ALCOA
SF4S63 ( V M-ee)
729585 0003
In-House Labeling 1985 December 16 Page 2 If anyone has questions concerning implementation of the above program, please do not hesitate to contact R. M. James (ext. 2881) or F. W. Hecker (ext. 4386). R. M. JAMES F. W. HECKER RMJ:wp Attachments
729585 0004
In-House Labeling 1985 December 16 Page 3
DISTRIBUTION:
Plant Procurement Managers
J. D. Boyce, Alcoa Technical Center T. W. Dodson, Arkansas Operations D. J. Phillis, Badin Works J. R. Rettinger, Cleveland Works D. C. Schlipf, Corona Works T. W. Lee, Davenport Works R. A. Topp, Fort Meade Works R. C. Mlessler, Lafayette Works B. C. Payne, Lancaster Works H. L. Gallop, Lebanon Works J. J. Hicks, Logans Ferry Works E. T. Klenske, Massena Operations J. Kuzko, Export Supply Division, New Orleans, LA C. H. Barker, Jr., Paradise Point T. A. Innes, Point Comfort Operations J. R. Pargman, Richmond Works J. R. Fry, Rockdale Works W. S. Zuber, Tennessee Operations M. D. Wooden, Vancouver Operations J. Gallagher, Vidalia Operations J. Heron, Vernon Works H. R. Sands, Warrick Operations R. D. Huber, Wenatchee Works R. L. Suter, Wenatchee Works K. Taragowski, American Powdered Metals Co., North Haven, CT M. J. Clement, Buckeye Molding Co., New Vienna, OH G. Babinsack, Halco (Mining) Inc., Pittsburgh Office - 2AC W. R. Pottgen, HC Products Company, Princeville, IL M. Brooks, Northwest Alloys, Inc., Addy, WA F. C. Burke, Rea Magnet Wire Company, Inc., Fort Wayne, IN 0. T. Smith, The Stolle Corporation, Sidney, OH E. M. Trevelyan, Tifton Aluminum Company,Inc., Tifton, GA
Hazardous Materials Control Committee Plant Coordinators
L. E. Gibson, Addy Works P. S. Bussey, ATC C. T. Nienaber, Anderson County Works L. L. Rippey, Arkansas Operations C. A. Carter, Badin Works P. C. Martin, Buckeye Molding Co., New Vienna, OH J. R. Progar, Cleveland Works J. V. Calcott, Cleveland Works J. D. Generous, American Powdered Metals, Conover, NC P. Bahner, American Powdered Metals, North Haven, CT G. R. Steinke, Corona Works M. K. Sonksen, Davenport Works A. S. Jarnagin, Tifton Aluminum Co., Tifton, GA
In-House Labeling 1985 December 16 Page 4
F. W. Eubanks, Tifton Aluminum Co., Delhi, LA F. H. Rohde, Kessler Premium Castings, El Paso, TX R. A. Topp, Fort Meade Works G. L. Gemmer, Rea Magnet/Fort Wayne, IN S. A. Kraft, Lafayette Works L. M. Crivaro, Lancaster Works R. Jacobson, Lancaster Works D. D. Korzon, Lebanon Works J. K. Garnevale, Logans Ferry Works S. M. Anderson, Massena Operations . H. W. Robinson, Mobile Works J. Wilson, Pep Industries, Nashville, TN J. Quaglia, Point Comfort Works C. H. Barker, Paradise Point W. R. Wheeler, HC Products, Princeville, II J. L. Eicher, Richmond Works G. H. Lantz, Rockdale Works R. A. Mowery, Stolle Corp., Sidney, OH H. G. Sakoian, Tennessee Operations J. A. Blessinger, Vancouver Works J. A. Blessinger, Vanexco, Vancouver, WA A. B. Piecka, Vernon Works S. M. Dean, Vidalia, LA K. P. Karsten, Warrick Operations J. A. Thompson, Wenatchee Works
Information copies:
H. F. Hillegass, Wenatchee Works D. P. Hooghkirk, Vernon Works S. Huey, Rea Magnet Wire, Fort Wayne E. B. Parker, Rockdale Works C. M. Reilly, Vidalia Works T. M. Engelgau, Northwest Alloys, Inc., Addy Works S. C. Smith, Davenport Works L. F. Wagner, Point Comfort Operations , 0. E. Wilkinson, Anderson County Works
Safety Managers
J. V. Calcott, Cleveland Works J. Carrothers, Vidalia Works W. M. Cochran, Tennessee Operations J. D. Duke, Richmond Works G. C. Greisbach, Rockdale Works J. Hicks, Logans Ferry Works v R. S. Howell, Lancaster Works K. Madison, Wenatchee Works A. Ness, Fort Meade Works E. T. O'Connor, Cleveland Works D. C. Olsen, Bad in Works R. R. Perdue, Northwest Alloys, Addy Works
Ln-House I.abellng 1985 December 16 Page 5
G. 0. Pratt, Davenport Works J. W. Rose, Warrick Operations I. C. Scheffler, Arkansas Operations J. A. Shockey, Point Comfort Operations R. A. Slack, Lafayette Works R. H. Snodgrass, Alcoa Technical Center G. R. Steinke, Corona Works T. L. Stuller, Wenatchee Works L. D. Tanis, Alcoa Technical Center D. L. Werner, Vancouver Operations O. E, Wilkinson, Anderson County Works P. T. Woerz, Massena Operations L. Wood, Vernon Works B. Allison, Vanexco, Vancouver, WA R. H. Batterman, ACPC, Massena Operations P. H. Bahner, American Powdered Metals, North Haven, CT F. Eubanks, Tifton Aluminum, Delhi, LA G. Gemmer, Rea Magnet Wire, Fort Wayne J. D. Generous, American Powdered Metals, Conover, NC S. B. Haman, Tifton Aluminum, Tifton, GA J. Humphrey, Algonquin Industrial, Guilford, CT J. Jackson, Pep Industries, Nashville, TN S. Jarnagin, Tifton Aluminum, Tifton, GA K. Johnson, Buckeye Molding, New Vienna, OH D. Marsh/J. Brown, Stolle Corporation, Sidney, OH R. L. Purvis, API, Pittsburgh Office W. R. Wheeler, HC Products Company, Princeville, IL
Environmental Contacts
W. A. Dunn, Alcoa Technical Center W. C. Stimmel, Addy Works 0. E. Wilkinson, Anderson County Works L. L, Rippey, Arkansas Operations C. A. Carter, Badin Works R. C. King, Cleveland Works G. R. Steinke, Corona Works G. 0. Pratt, Davenport Works R. A. Topp, Fort Meade Works S. A. Kraft, Lafayette Works L. M. Crivaro, Lancaster Works D. D. Korzon, Lebanon Works J. K. Carnevale, Logans Ferry Works D. R. Wilson, Massena Operations D. G. Applegate, Mobile Works C. H. Barker, Paradise Point J. C. Mayfield, Point Comfort Operations R. P. Graf, Richmond Works E. B. Parker, Rockdale Works C. L. Green, Rockdale Works W. S. Stroud, Tennessee Operations J. A. Blessinger, Vancouver Operations
LABEL NO.
ATTACHMENT A
PROUUCI NAME
LABELS
MSDS NO.
rVEmr
SLOCK NO.* QUANTITY
SIZE
14" x 11" 11" x 8" 8" x 6"
5" x 4"
VENDOR STOCK NO.
`1411D OR 1411C OR 141 IP 1108D OR 1108C OR 1108P 0806D or 0806C OR 0806P 05041) OR 0504C OR 0504P
(U-DANGER) (C-CAUTION) (P-UNPRINTED)
729585 0008
ATTACHMENT B LABEL FORMATS
U
2)
3) 4) 5)
6)
7)
8)
9)
10)
ID
12)
13) 14) 15) 16) 17) 18) 19)
20) 21) 22)
23) 24) 25) 26) 27) 28) 29) 30) 31) 32) 33) 34) 35) 36) 37) 38) 39) 40) 41) 42) 43) 44) 45)
46) 47)
Flammable Liquid (Irritant) - DANGER Hexane - DANGER Methanol - DANGER 1-Nitropropane - DANGER Flammable Liquid (Irritant, Carcinogen) - DANGER Flammable Gas (Compressed) - DANGER Flammable Solid (Water Reactive) - DANGER Combustible Liquid - CAUTION Combustible Liquid (Animal Carcinogen) - CAUTION Combustible Liquid (Irritant) - CAUTION Isophorone - CAUTION Combustible Liquid (Irritant, Health) - CAUTION Water Reactive - DANGER Water Reactive and Explosive - DANGER Oxidizer - DANGER Oxidizer (Irritant) - DANGER Compressed Gas (Inert) - CAUTION Compressed Gas (Oxidizer) - DANGER Compressed Gas (Oxidizer, Health) - DANGER Irritant - CAUTION Corrosive - DANGER Corrosive (Carcinogen) - DANGER Corrosive (Combustible Liquid) - DANGER Corrosive (Oxidizer) - DANGER Corrosive (Oxidizer, Explosive) - DANGER Corrosive (Compressed) - DANGER Corrosive (Sensitizer) - DANGER Cresol and Phenol - DANGER Pneumoconiosis Dust - CAUTION Pneumoconiosis Dust (Carcinogen) - CAUTION Ceramic Refractory Fibers - CAUTION Asbestos - CAUTION Carcinogen - CAUTION Carcinogen (Sensitizer) - CAUTION Carcinogen (Inhalation, Skin) - CAUTION Coal Tar Pitch Products - CAUTION Sensitizer - CAUTION Systemic Toxic - CAUTION Systemic Toxic (Irritant) - CAUTION Glycol Ether - Cellosolve and Cellosolve Acetate - CAUTION Butyl Cellosolve - CAUTION Lubricants - UNPRINTED Lubricants (Skin Carcinogen) - CAUTION "Regulated Hazardous" Material - UNPRINTED Flammable Liquid (Irritant which contains cellosolve, cellosolve acetate) - DANGER
Carcinogen (Irritant) - CAUTION Carcinogen (Flammable, Irritant) - DANGER
729585 0009
ATTACHMENT C HAZARDOUS MATERIALS INDEX
Substance
Acetic anhydride Acetone Acetylene Acrylic acid Alumina Aluminum Aluminum chloride Aluminum dross Aluminum fluoride Aluminum granules Aluminum - lithium alloys Aluminum powder Alkylamine Ammonium bifluoride Ammonium hydroxide Anhydrous ammonia Argon Asbestos
Label No.
21 I 6
23 44 44 21 13 44 14 44 14 27 21 21 26 17 32
Bauxite Bayer liquor Benzene Benzoic acid Beryllium and its compounds Boric acid Brown mud Butyl cellosolve
44 21
5 20 30 20 20 41
729585 0010
Substance
Cadmium Calcium aluminate Calcium carbonate Calcium fluoride Calcium hydroxide Calcium metal Calcium oxide Carbon dioxide Carbon tetrachloride Cell demister eutectic Cell dropout box material Cellosolve Cellosolve acetate Ceramic refractory fibers Cesium Chlorine Chlorodifluoromethane Chloroform Chromic acid Chromium Citric acid Coal tar pitch Cobalt Cold ramming paste Copper Cresol Crushed bath Cryolite Crystalline silica Cyclohexanone
Label No.
30 20 44 44 21
7 21 17 35 21 21 40 40 31 44 19 17 33 24 44 20 36 29 36 44 28 44 44 29 10
2 729585 0011
Substance
Dlacetone alcohol DichlorodIfluromethane Dimethyl ketone DOP
Electric calcined anthracite Ethane Ethanol Ethyl acetate Ethyl benzene Ethylene glycol
Fluorotrichloromethane Fluosilicic acid Formaldehyde Formic acid Furfural
Gallium and its oxides Gasoline Glacial acetic acid Glycerin Glycerol
Label No
10 17
1 33
44 6 1 1 1
44
17 21 34 23 10
44 47 23 44 44
3
729585 0012
Substance
HaIon 1301 Helium Hexachlorbenzene Hexane Hexylene glycol Hi flash naphtha Hot ramming paste Hydrazine Hydrochloric acid Hydrochloric acid gas Hydrofluoric acid Hydrogen
Inhibtor in Logan's Ferry paste Insoluble hexavalent chromium Iron and its oxides Isobutyl alcohol Isophorone Isopropyl alcohol
Kerosene
Lead and its compounds Liquid propane Lithium aluminate Lithium carbonate Lithium chloride Lithium metal
Label No.
17 17 35
2 20 10 36 22 21 26 21
6
21 33 44
1 11
1
9
38 6
20 20 44
7
4
729585 0013
Substance
Label No.
Magnesium aluminate spinel Magnesium and its oxides Manganese MEK Mercury Methane Methanol 4-raethyl-2-pentanol Methylene chloride Methylene diisocyanate MIBK Microcrystalline silica
44 44 44
1 38
6 3 10 46 37 1 29
ML-501 ML-502 ML-503 ML-504 ML-505 ML-507 ML-508 ML-510 ML-512 ML-514 ML-516 ML-522 ML-523 ML-526 ML-541 ML-544 ML-550 ML-554 ML-560 ML-561
42 42 42 42 42 42 42 42 42 42 42 43 (need to check source) 42 42 20 42 42 42 42 42 42
5
729585 0014
Substance
ML-562 ML-563 ML-564 ML-565 ML-567 ML-570 ML-575 ML-586 ML-587 ML-589 ML-594 ML-605 ML-606 ML-624 ML-625 ML-650 ML-666 ML-667 ML-669 ML-670 ML-672 ML-673 ML-677 ML-679 ML-680 ML-682 ML-686 ML-751 ML-752 ML-833 ML-834 ML-844 ML-847
Label No.
42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 or 43 (need to check source) 42 42 or 43 (need to check source) 42 42 42 42 42 42 42 42 42 42
6
729585 0015
Substance
ML-916 ML-921 ML-924 ML-925 ML-928 ML-931 ML-935 Mobil Mist Lube
n-butanol n-butyl acetate Nickel and certain nickel compounds Nitric acid Nitrocellulose Nitrogen 1- nitropropane 2- nitropropane
Oxalic acid Oxygen
PCBs Pentane Pentoxone Perchloric acid Perchloroethylene Petroleum coke Phenol Phosphoric acid Potassium hydroxide Propylene glycol methyl ether
7
Label No.
42 12 42 42 42 42 42 42
1 1 34 24 1 17 4 5
21 18
35 6
10 25 46 44 28 21 21
1
729585 0016
Substance
PL-101 PL-106 PL-107 PL-109 PL-111 PL-113 PL-122 PL-132 PL-133 PL-135 PL-141 PL-143 PL-145 PL-148 PL-151 PL-153 PL-160 PL-161 PL-207 PL-208 PL-228 PL-229 PL-232 PL-239 PL-242 PL-260 PL-265 PL-270 PL-280 PL-289 PL-295 PL-330 PL-333
Label No
42 42 42 43 (need to check source) 42 42 42 42 42 42 42 42 20 10 42
9 42 42 42 42 42 10 42 or 43 (need to check source) 42 42 42 42 42 42 42 42 42 10
10
8
729585 0017
Substance
PL-334 PL-348 PL-361 PL-372 PL-380 PL-408 PL-448
Sialon Silicon Silicon tetrachloride Soderberg briquettes Sodium acetate Sodium carbonate,anhydrous Sodium dichromate Sodium hydroxide Sodium hypochlorite Sodium metal Sodium silicate Spent caustic Spent potlining Stearic acid Stoddard solvent Sulfur dioxide Sulfuric acid
Label No.
42 9
42 42 42 42 42
44 44 21 (26) 36 44 20 16 21 21
7 21 21 20 44 10 26 21
9 729585 0018
Substance
Tin Titanium and its oxide Titanium tetrachloride Toluene Toluene dllsocyanate (TDI) 1,1,1-trichloroethane Trichloroethylene Trisodlum phosphate Turpentine Type 100 solvent Type 150 solvent
Used motor oils
VMP-naphtha
Xylene
Zinc Zirconium Zirconium tetrachloride
Label No.
44 44 21 (26)
1 37 39 39 44
1 10 10
43
1
1
44 44 21
10
729585 0019
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