Document jqx9aYeQM8Y6pDqo7pn4L5XO

t . ! ,* 1 ' ** > - [*' * V \* -- *. \? ` ? ' * W7V. ./ ! .;> ^ : # | *j -A-r - **'v . /, , . ' /; ' 1 :'v 1 .' - j *M4 ' V' ' ' * *' - ,, . - 1 ``V., '* /, /'V, 7. t '\ 1 ,' '* * y` r * t ' '' | `` i . ' *' X I"! ; , ai : ^' '> V -Z *,! _ , ^ '**,1 r / S'* ;-V'-, ;;. \ '* j, * v *i V'-'**-' "! . ' :. Published by ./ {:. , t< ' ^.,*4' *`l ' J* U . '* -r'O Manufacturing Chemists' Association, Inc. 1825 Connecticut Avenue,' N.W. -' } w- r K *'- -it p'-i, * * rS^47' Washington 9, D.C. U ^ J ^ , o > IMPORTANT Mail the Record Card Now When you receive Manual L-l, please fill out and mail the post card provided below. A record of holders will make possible the correct distribution of supplements or notices, if any, which may be issued before the next edition is printed. MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1825 Connecticut Avenue, N. W. WASHINGTON 9, D. C. For your future reference, record here the nam and address you have given below. Date........................................................................... MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1825 Connecticut Avenue, N. W. WASHINGTON 9, D. C. Gentlemen: I have a copy of the MCA Manual L-t, "Guide to Precautionary Labeling of Hazardous Chemicals"--Sixth Edition--1961. Please send me any supple ments or notices relating thereto. I should like to be advised when a new edition is printed. Name......... ........................................................................................ Address............................................................................................... PLEASE MAIL RECORD CARD NOW GUIDE TO PRECAUTIONARY LABELING OF HAZARDOUS CHEMICALS STAMP HERE MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1825 CONNECTICUT AVENUE, -N. W. WASHINGTON 9, D. C. MANUAL L-1 Sixth Edition -- 1961 PRICE: $2.00 Published by MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1825 CONNECTICUT AVENUE, N. W,, WASHINGTON 9, 0. C. 990f-0 040367 The information, recommendations, and illustrative labels contained in Manual L-l have been compiled from sources believed to be reliable and to represent the best current opinion on the subject. No warranty, guarantee, or representation is made by the Association as to the abso lute correctness or sufficiency of any information, recommendation, or illustrative labels herein, and the Manufacturing Chemists' Association, Inc. assumes no responsibility in connection therewith; nor can it be assumed that all necessary warnings and precautionary measures are contained in this Guide, or that other or additional measures may not be required under particular or exceptional conditions or circumstances. O Copyright 1945, 1946, 1949, 1953, 1956, 1961 by Manufacturing Chemists' Association, Inc. ADOPTED ...... .1945 REVISED ...........................1946 SECOND REVISION 1949 THIRD REVISION 1953 FOURTH REVISION ____ 1956 FIFTH REVISION 1961 (SIXTH EDITION) Contents PAGE MCA PrecautionaryLabelingActivity--A Review .................................. 5 Introduction ............................................................................................ 7 Definitions .............................................................................................. 9 PARTI Preparation of Precautionary Labels General Principles ................................................................................. 3 2 Preparation of Labels ............................................................................ 13 Example of Label Preparation ............................................................... 16 Table l Selection ofPrecautionaryStatements .................................... 20-21 Labels for Small Commercial Packages..................................-............. 22 Labels for Samples and for New Products for Investigational Use.... 23 Container Handling and Storage ...................................................... 24 PART II Illustrative Labels for Haxardous Chemicals Preface ................................................................................................... 29 Product Labels ........................................................................................ 30 MCA Chemical Safety Data Sheets .................................................... 95 PART III Illustrative Labels for Pesticides Preface ....................... Product Labels ............................................................. 3 ^7 MCA PRECAUTIONARY LABELING ACTIVITY A Review Accidental experience and willful experiment led man early to recognize the hazards which typify some substances. In 1450, Scotland enacted one of the first statutes governing product hazard. The Court Apothecary then ruled "that all persons are forbidden under the pain of treason to bring home poisons for any use by which Christian man or woman can take harm." From such beginnings came today's laws and regulations covering the identification of hazardous substances. One of the earliest United States statutes in the chemical field was the Federal Caustic Poison Act (1927). It covered twelve caustic or corrosive substances in certain concentrations, in containers "suitable for household use." Interpretation and enforcement was by the Food f\ and Drug Administration. In its simplest terms, packages of the speci fied materials were required by law to carry labels containing the word "POISON" in particular type size along with an "antidote" statement. The year 1932 saw the introduction into Congress of a Volatile Poisons Bill. A first draft contained a general definition of hazardous materials. A subsequent one followed the earlier plan of listing specific chemicals. The second draft authorized the Surgeon General to enlarge the list after investigation. While these bills did not become law, they marked a sharp acceleration in the evolution of precautionary labeling and its recognition by statutory requirement in the United States. With I this came renewed awareness of responsibility by producers and by industry groups such as the Manufacturing Chemists' Association, Inc. t i From such group activity came the Chemical Products Agreement Committee appointed by the Surgeon General. The work of this group evolved the voluntary "Surgeon General's Agreements" entered into hy the U.S. chemical industry in 1934-35. The texts of the precautionary labels to be used on specific products were agreed upon and made a part of executed agreements. These continued in effect and were honored by industry until 1952. The Surgeon General then agreed to their replace ment by broader and more widely applicable practices formulated through the continued work of MCA and its Labels and Precautionary Information Committee. The Manufacturing Chemists' Association, Inc., and its members, had early recognized the place of precautionary labeling in relations both with its customers and with stale and federal governments. There were 5 040368 040369 numerous strong reasons for taking the initiative in this phase of chemical marketing. The industry had an outstanding safety record in its manufacturing units. The Association believed this safety record could be projected to the plants and homes of its customers to their mutual benefit. There was always the shadow of litigation that faces any producer as the result of real or fancied injury by a product. Chemical manufacturers had already seen the possible alternative of federal and state legislation which might or might not be wisely framed. MCA chose the path of self-correction. In 1944 it convened a confer ence on a chemical precautionary labeling code. Attended by over ninety member representatives, it resulted in the formation of the Labels and Precautionary Information Committee of the Association. This committee continues as the group longest active in this endeavor. One of its earliest concerns was the compilation of a manual on precau tionary labeling practices for chemicals. First issued in March 1945, Manual L-l of the MCA LAPI Committee has become a widely recognized text on this subject. n 6 MANUAL L-1 PRECAUTIONARY LABELING OF HAZARDOUS CHEMICALS introduction Many products present no hazard in normal handling and storage. For these products, no precautionary statements are necessary on the label. The development of new chemical products, and the introduction of chemical processes into ever-widening fields, have accentuated the need for furnishing appropriate information in those cases where there are hazards requiring special precautions. Precautionary information should, so far as is practicable, reach every person using, handling, or storing hazardous substances. The most practical means of disseminating this information appears to be by precautionary labels, affixed to containers of hazardous sub stances, bearing appropriate precautionary statements expressed as simply and briefly as possible. Such label information, however, cannot take the place of the education of personnel regarding product hazards and the use of safety clothing and equipment. This education is, and must remain, the direct responsibility of their employers. The wording on precautionary labels cannot be expected to cover complete information as to the properties of a material nor the complete details of its proper handling under all conditions. Such information may be found in the producers' technical bulletins or in the Manufacturing Chemists' Association's Chemical Safety Data Sheets. To achieve uniform and adequate labeling of hazardous substances, the Labels and Precautionary Information (LAP!) Committee of the Manufacturing Chemists' Association, Inc. (MCA) offers Manual L-l 7 040370 os n guide in preparing preen ut ion nry IiiIjcI lexis, i'nrt I sets forth general principles. Part 11 presents precautionary texts selected to illustrate the application of these principles to the major types of hazards encountered. Part III presents precautionary texts illustrating the labeling of a group of substances used in the pesticide (economic poison) field. The labeling of radio-active materials is a complex problem outside the scope of this Guide. In preparing precautionary labels for such materials, it is suggested that reference be made to the series of hand books published by the United States Department of Commerce, National Bureau of Standards, covering the safe handling of radio active materials. The Surgeon General of the United States Public Health Service has discontinued the labeling agreements entered into some years ago with the manufacturers of a few specific chemicals. This was done be cause today adequate precautionary labels are in general use by the producers. The United States Public Health Service has approved the principles of precautionary labeling developed by MCA and continues its interest in this field in cooperation with the Association. It is felt that cooperation on the present broad basis will best serve the purpose intended when the earlier more specific agreements were made. This Guide will be found extremely useful in the preparaH n of precautionary text for any hazardous chemical even th ugh the General Principles and illustrative texts were designed originally for hazardous chemicals intended for industrial users. The pr cauti nary texts as presented in this Guide should be used in addition to, or in combination with any specific wording re quired by law. Since individual statutes, regulations, or ordi nances may require that particular information be included in a label, that certain information be displayed in a particular manO ner, or that a specific label be affixed to a container, the use of the General Principles or the illustrative texts in this Guide will not necessarily insure compliance with such laws. The specific requir ments of each such law and regulations issued thereunder must be observed in order to insure compliance. Such laws include th fed ral Hazardous Substances Labeling Act and similar state and municipal legislation; the Federal Insecticide, Fungicide, and R dentietd Act and similar state legislation; Interstate Commerce Commission R gulations for Transportation of Expl sives and Other Dangerous Articles; and thers. 8 DEFINITIONS Laws making precautionary iabeling mandatory mark the evolution of labeling from its earliest beginnings. Complementary to the develop ment of such codes has been the definition of terms used in specifying such labeling. This part of the development has received extensive study by the MCA Labels and Precautionary Information Committee, This has resulted in the following definitions encompassing the modes in which substances are hazardous and the types of materials which exhibit such behavior. Combustible Liquid--Any liquid which gives off flammable vapors, above 80F. to and including 150F., as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning oils. Corrosive (Physiological)--A substance which in contact with living tissue causes destruction of the tissue by chemical action. This term shall not refer to action on inanimate surfaces. Dust--Solid particles generated by handling, crushing, grinding, rapid impact, detonation, or decrepitation of organic or inorganic materials such as rock, ore, metal, coal, wood, grain, etc. Dusts do not diffuse in air but settle under the influence of gravity. Economic Poison (Pesticide)--(1) Any substance or mixture of sub stances intended for preventing, destroying, repelling, or mitigating any insects, rodents, nematodes, fungi, weeds, or other forms of plant or animat life or viruses, except viruses on or in living man or other animals, and (2) any substance or mixture of substances intended for use as a plant regulator, defoliant or desiccant. Extremely Flammable Liquid--Any liquid which gives off flammable vapors, at or below a temperature of 20F., as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning oils. Flammable Liquid--Any liquid which gives ofl flammable vapors, above 20F. to and including 80F., as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning oils. Fume--Solid particles generated by condensation from the gaseous state, generally after volatilization from molten metals, etc., and often accompanied by a chemical reaction such as oxidation. Fumes floccu late and sometimes coalesce. 9 Gas--A normally formless fluid which occupies the space of enclosure and which can be changed to the liquid or solid state by the effect of increased pressure or decreased temperature or both. A gas diffuses. Hazard us Substance--Any substance or mixture of substances which is (1) toxic; (2) corrosive; (3) an irritant; (4) a strong sensitizer; (5f flammable, or which (6) generates pressure through decomposition, heat, or other means, if such substance or mixture of substances may cause substantial personal injury or substantial illness during or as a direct result of any customary or reasonably anticipated handling or use. Irritant (Physiol gical)--Any substance which on immediate, prolonged, or repealed contact with normal living tissue will induce a local inflam matory reaction. Mist--Suspended liquid droplets generated by condensation from the gaseous to the liquid state or by breaking up a liquid into a dispersed slate, such as by splashing, foaming, or atomizing. Mixture--A physical commingling of two or more substances which may or may not bear a fixed proportion to one another and which have not reacted chemically with one another. Oxidizing Mat rial--A substance that yields oxygen readily to stimu late the combustion of organic matter. Pesticide--Same as Economic Poison Poison--Any substance or mixture of substances which falls within any of the following categories:1 (1) Produces death within 14 days in half or more than half of a group of 10 or more laboratory white rats each weighing between 200 and 300 grams, at a single dose of 50 milligrams or less per kilogram of body weight, when orally administered; or (2) produces death within 14 days in half or more than half of a group of 10 or more laboratory white rats each weighing between 200 and 300 grams, when inhaled continuously for a period of one hour or less at an atmospheric con centration of 200 parts per million or less by volume of gas or vapor or 2 milligrams or less per liter of mist, fume or dust, provided such con centration is likely to lie encountered by man when the substances are used in any reasonably foreseeable manner; or (31 produces death nilhin 14 days in half or more llum Imlf of a group of 10 or noire 10 CMA 040371 mMdts tested in a dosage of 200 milligrams or less per kilogram at hody weight, when administered liy continuous contact with the hare skin for 24 hours or less. If available data on human experience with any substanc in the above-named concentrations indicate results different from those obtained on animafs, tbe human data shall take precedence in any classification of a substance as poisonous. Sensitizer--A substance which will cause on normal living tissue through an allergic or photodynamic process a hyper-sensitivity which becomes evident on reapplication of the same substance. Toxic Substance--A substance which has the inherent capacity to pro duce personal injury or illness to man through ingestion, inhalation, or absorption through any body surface. Vapor--The gaseous form of a substance which is normally in the solid or liquid stale. A vapor diffuses. 11 I n 040372 PART I Preparation of Precautionary Labels Genera/ Principles The following General Principles serve as a guide in the prepara tion of precautionary labels for hazardous substances. (1) Each hazardous substance presents a distinct problem and must be treated individually in the light of its own characteristics. Conclu sions regarding the hazards of a product cannot safely be drawn either from the properties of the materials from which it is formed or by analogies based upon chemical structure. Mixtures of two or more chemicals may have properties that vary in kind or degree from those of the individual components. Any precautionary label for mixtures should be hased on the prop erties of the finished product. Impurities may contribute hazardous properties and should not be overlooked. (2) All statements on precautionary labels should be brief, accurate, and expressed in simple, easily understood terms. (3) Precautionary labeling should be used only when and to the extent necessary. The language should be practical, not based alone upon the inherent properties of a product, but directed toward the avoid ance of hazards resulting from such use, handling, and storage as may reasonably be anticipated. The use of precautionary labels for relatively harmless products, or the use of unnecessary words, will develop a disregard for labels and defeat their purpose as surely as will failure to give adequate notice of hazards. (4) On labels for different products, uniformity in language to indicate the same hazards and same degree of hazard is most desirable in order to gain greater understanding through standardization. (5) The following subject matter should be considered for inclusion on a precautionary label: A. Name of Product. B. Signal Word designating degree of hazard--DANGER!, WARNING!, or CAUTION! 12 C. Affirmative Stal m nt of Hazards. D. Precautionary Measures covering actions to be followed or avoided. E. Instructions in Case of Contact or Exposure, where ad visable. (Note: Under some laws antidotes or first aid procedures are required when the word "POISON1" is used.) Instructions for the handling and storage of containers should also be considered for inclusion on the label. This is information relating to characteristics of the container as well as those of its contents, and is discussed separately under Container Handling and Storage on Page 24. (6) The inclusion of the word "POISON" and the skull and crossbones on a label should be limited to those cases where the product is a poison according to the definition appearing on Page 10, or where such use is prescribed by law. When used, this legend should be in addition to the other label warnings and should not take the place of the Signal Words DANGER!, WARNING!, and CAUTION! which are designed to show the relative degree of hazard. (7) A non-descriptive code designation or trade name should not be used as the only identification of a hazardous substance. If the complete chemical name is not shown, the label should clearly state the type of chemical, e.g., "corrosive acid", "lead c mpound". (8) Precautionary statements should be grouped together in a prominent location on the label and should be printed in easily legible type which is in contrast by typography, layout, or color with other printed matter on the label. The label should be affixed firmly to and in a conspicuous place on the container. Preparation of Labe/s In the preparation of a precautionary label, the compilation of all available relevant information on the product is a necessary first step. An adequate knowledge of the toxicity of the material (obtained from the literature or through laboratory tests) and data on physical and chemical properties, packaging, and methods of handling and use of the product are needed to make possible a description of the hazards. In the case of an established product, advantage should he taken of the experience of people involved in manufacturing, shipping, and using 13 040373 the material. All the General Principles should be kept in mind and the following information considered for inclusion on the label: A. Name of Product This is important information for the safety of handlers and users. It is preferable that the chemical name of the product he used. The recommendations of the American Chemical Society for nomenclature should he followed. Trade names may he used in addition to chemical names. A non-descriplive code designa tion or trade name should not be used as the only identification of a hazardous chemical. If the complete chemical name is not shown, the label should at least clearly state the type of chemical, e.g., "corro sive acid", "lead compound". B. Signal W rd This word is intended to draw attention to the pres ence of hazard, and to indicate the degree of severity. The Signal Words recommended are, in the order of diminishing severity of hazard: (1) DANGER! (2) WARNING) (3) CAUTIONI Degree of severity can he expressed only in relative terms. "DANGER!" is the strongest of the three words and should be used for those products presenting the most serious hazards. "CAUTIONI" is recommended for those compounds presenting the least serious hazards. "WARNING!" is intermediate between "DANGER!" and "CAUTION!" Reference to the illustrative labels in Part II of this Guide will help in the selection of the proper Signal Word. C. Statement of Hazards This statement should give notice of the hazards that are present in connection with the customary or reasonably anticipated handling or use of the product. Examples are: CAUSES BURNS VAPOR EXTREMELY HAZARDOUS Many chemical products will present more than one type of hazard, in which case, appropriate statements for each significant type should he included on the label. In general, the most serious hazard should he stated first. While any compound may he hazardous if improperly used, it is impractical to cover every possible contingency on a label. Efforts should he directed toward giving notice of the significant hazards. A minor hazard may frequently he covered clearly and briefly by an appropriate precautionary statement alone. In some cases, the total hazard of a product, while justifying one or more Precautionary Meas 14 ures, may be of such order as to require no Statement of Hazard on the label. D. Precautionary Measures These instructions are intended to sup plement the Statement of Hazards by setting forth briefly measures to be taken to avoid injury or damage from staled hazards. Examples are: Keep away from heat, sparks, and open flame. Avoid breathing dust. Precautionary Measures may be included for hazards not considered of sufficient importance to require mention in the Statement of Hazards. Statements similar to, "Do not take internally." deserve special attention. They are seldom necessary where the Precautionary Measure to be followed is obvious as, for example, when the product is labeled "POISON" or the Statement of Hazards contains the words, "MAY BE FATAL IF. SWALLOWED". On the other hand, the instruction may be desirable if ihe name, appearance, use, or other attributes of the chemical are likely to result in its being taken orally through accident or mistaken identity. E. instructions in Case of Contact or Exposure The primary pur pose of precautionary labeling is to prevent injury or damage. How ever, Instructions in Case of Contact or Exposure may be included in those instances where the results of contact or exposure are severe and immediate treatment is highly desirable, and where simple remedial measures may be taken safely by non-professional persons before medical assistance is available. Instructions should be limited to recognized first aid procedures based on simple methods and commonly available materials. Instruc tions for strictly medical treatment should be omitted except when specifically required by law or indicated by special circumstances. Because of the serious and lasting effects that may result from eye injuries, a recommendation to get medical attention should accompany any specific instructions directed to treatment of the eyes. In certain instances, simple remedial measures such as washing, or removal of clothing, may he included where they will serve to avoid serious injury following contact or exposure. All precautionary information should appear on the label as a unit and should be printed in the order given above. The labels in Barts H and HI illustrate suitable arrangements and indicate llu: relative promi 15 nence that should be given to the individual statements. Such relative prominence may be achieved in a number of ways such as by variation in type size, color, or layout of the printed material. Note: Some state laws and regulations require, on labels, the use of special or strictly defined antidotes or prescribe special ways in which these must be shown for certain hazardous substances. The require ments for any given poison may, therefore, vary greatly, and the impossi bility of showing, in the illustrative labels, antidotes which might be nationally acceptable has led to the practice of indicating only the need for an appropriate first aid or antidote statement where the "POISONskull and crossbones" legend is used. Table 1, on Pages 20 and 21, is intended as a guide in the selection of precautionary statements for labels. Listed are classifications of mate rials according to the hazardous properties most frequently encountered. Opposite each classification are given Statements of Hazard, Precaution ary Measures and, in most cases. Instructions in Case of Contact or Exposure. It is important to recognize that hazardous substances can have inherent in them more than one of such hazardous properties, and that the label wording for such products should include an appropriate combination of the pertinent statements. As each hazardous substance must be treated individually in the light of its own characteristics and customary or reasonably anticipated handling or use, there will be many instances in which the illustrative statements in Table 1 will not be applicable, either because they do not accurately express the degree of hazard or because they fail to cover the particular characteristics. In such cases, suitable statements should be chosen to fit the situation. The illustrative labels in Part 11 of this Guide may be helpful in the choice of appropriate wording. EXAMPLE OF LABEL PREPARATION To give as complete an illustration as possible of the procedure to be used in writing a precautionary label. Ethylene Chlorohydrin has been selected. A study of available physical, chemical, and toxicological data shows that this chemical presents several hazards for consideration. It is a poison, as defined in this Guide, by skin absorption and is dangerously toxic by oral ingestion and by vapor inhalation. On con tact it can cause serious damage to the eyes. There is a hazard of combustibility since the flashpoint of the liquid is 140F., which is within the range of combustibility in Class of Hazard I-C in Table 1. A special hazard of Ethylene Chlorohydrin is its ability to penetrate ordinary rubber. 16 CMA 040374 The selection of the Signal Word depends on the seriousness of the hazards and to a lesser extent on the number of hazards. In the case of Ethylene Chlorohydrin, both major hazards--its toxicity and its ac tion on the eyes--are serious and acute. Therefore, the Signal Word "DANGER!" is indicated. Since ethylene chlorohydrin is dangerous by any type of contact with the body, strong Statements of Hazard should be used. As far as possible, hazards should be listed in the order of decreasing importance. Thus, from Table 1, Classes of Hazard 111, IX, and X, appropriate State ments of Hazard are selected to describe the various hazards. From HI: VAPOR EXTREMELY HAZARDOUS VAPOR MAY BE FATAL IF INHALED From IX: EXTREMELY HAZARDOUS LIQUID ABSORBED THROUGH SKIN From X: MAY BE FATAL IF SWALLOWED For brevity and better emphasis, the above statements are combined and rearranged: EXTREMELY HAZARDOUS LIQUID AND VAPOR MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN For the major hazard of eye damage, the appropriate Statement of Hazard as selected from Table 1, Class of Hazard VI1, is modified to: CAUSES BURNS TO EYES The Statement of Hazard "COMBUSTIBLE" is not necessary (ex cept as required by law I, since the Precautionary Measure, "K ep away from heat and open flame." is considered adequate. Since ordinary rubber protective clothing, including gloves, will not eliminate the hazard of skin absorption, a special Precautionary Statement to this effect should be prepared and included. 17 040375 ^^ilcments of Precautionary Measures are selected from Table 1, Column 3, Classes of Hazard 1, 111, Vll, IX and X. From I: Keep oway from heat and open flame. From III: Do not breathe vapor. Use only with adequate ventilation. From VII: Do not get in eyes, on skin, on clothing. From IX: Do not get in eyes, on skin, on clothing. From X: Do not take internally. Special Precautionary Statement prepared to cover special hazard of material: Ordinary rubber protective clothing, including gloves, will not pre vent skin absorption. Instructions in Case of Contact or Exposure are selected from Table 1, Column 4, Class of Hazard IX: From IX: In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gel medical attention: Wash clothing before re-use. Ethylene Chlorohydrin is a poison by absorption into the body by skin contact, therefore, the "POISON-skull and crossbones" legend is used, followed by first aid instructions: POISON Call A Physician First Aid If swall wed: If conscious, make patient vomit immediately by putting finger down throat or by giving warm mustard water or salt water freely. General: Keep patient warm; if conscious, give black coffee. Note to Physician: Do not give adrenalin. 18 Thus, the completed precautionary label, combining and rearrang ing selected material according to General Principles as outlined in this Guide, will include the following components as shown below: Q Name of Product, Signal Word, 0 Statement of Hazards, 0 Precautionary Measures, 0 Instructions in Case of Contact or Exposure, 0 Poison legend and 0 First Aid Statem nt 0|ETHYLENE CHLOROHYDRrN~[ANHYDROUS OR 38/) ------[ r*xTREMEU'HAZARDOUS LIQUID AND VAPOR {MAY BE FATAL IF SWALLOWED, INHALED, OR 0------------------------ 1 ABSORBED THROUGH SKIN [causes burns to eyes Do not get in eyes, on skin, on clothing. Ordinary rubber protec! five clothing, including gloves, will not prevent skin absorption. j Do not breathe vapor. o-- { Use only with adequate ventilation, j Do not take internally. { Keep away from heat and open flame. | In case of contact, immediately remove all contaminated clothing j and flush skin or eyes with plenty of water for at least IS 0" 'l minutes; for eyes, get medical attention. Wash clothing before re-use. __ _ POISON Call A Physician L- r- First Aid 0---- If swallowed: If conscious, make patient vomit immediately by putting finger dawn throat or by giving warm mustard water or salt water freely. General: Keep patient warm; if conscious, give black coffee. Note to Physician: Do not give adrenalin. 19 ihir iKil. mi ill* In luw uiu m>l mii'ikdi.U la l>c loim^I) tc. m lln- yivt.ii iubc "ducts will be encountered that present hazards varying In kind or degree IrooinJ^^H Nets applicable to the product may be found In this Table. However, suitable Ron thereof, o> differ fisted. Appropriate Statement of hazard*. Precautionary Measures, and fnifrudiol.. | eat statements entirely, may be necessary. Case of Contact or Exposure should be prepared on the basis of the properties of the prod- | NOTE: "POtSON-skull and crossboneo" should be included if the product any uct, following the pattern and general phraseology of the following table. Parenthetical the criteria for "POISON" set forth on Page 10 or is required by law. If "POISON" wards in the table express variations in kind or degrea and are to be used where oppfi* used, add a first aid or antidote statement as required. SEE EXAMPLE OF LABEL PREPARATION BEGINNING ON PAGE IB. Clast of Haiard I. liquids Flashing at 150F. or Below (Flash paints are determined by the Tagliabue Open-Cup Method) A. Flash point 20 F. or below B. Flash point above 2Qf. to BQCF. Inclusive C. Flash point above 80F. to 150F. inclusive II. Oxidizing Materiab til. Materials Giving Vapors Ropidly Toxic or Extremely Irritating on Exposure for a Short Time or to Low Concentrations IV. Materials Giving Vapors Hazardous from Pro longed or Repeated Exposures or Exposure to High Concentrations V. Gases and Vapors Physiologically Inert VI. Materials in Dust Form Hazardous from Inhalotion or Contoct VII. Corrosives Statements of Hazard ' Precautionary Measures IMPORTANT: Select applicable statements) only. IMPORTANT: Select applicable ftatemenJ(s) only. Selection(s) to be based on actual fiazard(i) and | Sdcclion(s) to be based on octual haxard(t) and degree of hazard, in some instances, where a mild 1 degree of hazard. In some instances the omission of caution is indicated, the Statement of Hazard moy be I Precautionary Statement may be justified where the omitted and adequate information provided by the ecasure to be followed is obvious from the statement of Precautionary Measures. | Statement of Hazord. \ EXTREMELY FLAMMABLE FLAMMABLE COMBUSTIBLE* STRONG OXIDANT CONTACT WITH COMBUSTIBLE MAY CAUSE FIRE (OTHER) 1 Keep awoy from heat (sparks,) ond open flame. 1 keep container closed (ond away from heat). (he with adequate ventilation. t Store separately (away) from and avoid contoct with MATERIAL p combustible (other) materials. Avoid contamination of clothing os it becomes dangerously flammable when dry. 1 Keep container closed (and away from heat), 1 Amid contact with skin and eyes. VAPOR (EXTREMELY) HAZARDOUS (IRRITATING) HAZARDOUS LIQUID AND VAPOR (GAS UNDER PRESSURE) VAPOR POISONOUS IF INHALED VAPOR MAY BE FATAL IF INHALED [Sm NOTE oppoiit* page] Do not breathe vapor, i Do nol get in eyes, on skin, on clothing. ! Use only wilh adequate ventilation. | Keep container closed (and away from heat). Move air-line respirator or self-contained oxygen respirator available for emergency. VAPOR HARMFUL CAUSES IRRITATION OF EYES, NOSE, ANO THROAT I (lie only with adequate ventilation. 1 Avoid (prolonged or repeated) breathing (of) vopor. Avoid contact with skin, eyes, ond clothing. 1 Keep container closed (and away from heat). GAS (VAPOR) REDUCES OXYGEN AVAILABLE FOR 1 (he with adequate ventilation, BREATHING 1 Keep container closed. RELEASES HEAVY GAS (VAPOR) WHICH MAY Do not enter storage areas unless adequately CAUSE SUFFOCATION j ventilated. HAZARDOUS (HARMFUL) DUST 1 Do not breathe dust. HARMFUL IF INHALED * Avoid breathing dust. CAUSES IRRITATION OF SKIN, EYES, NOSE, AND Wash thoroughly before eating or smoking. THROAT 1 Avoid contoct with skin, eyes, and dothing. CAUSES SEVERE BURNS CAUSES BURNS MAY CAUSE BURNS \ Do nol get in eyes, on skin, on clothing. Avoid contoct with skin, eyes, ond dothing. j Avoid exposure to (concentrated) vapor. VIII. Irritants, Sensitizers IX. Materials Toxic through Skin Absorption X. Materials Toxic if Swallowed 9fl CMA 0403T6 CAUSES SKIN IRRITATION MAY CAUSE SKIN IRRITATION l Avoid (prolonged or repeated) contact with skin. Wash thoroughly after handling. | Avoid exposure to (concentrated) vapor.________ (EXTREMELY) HAZARDOUS (HARMFUL) SOLID (LIQUID ABSORPTION THROUGH SKIN MAY BE FATAL ABSORPTION THROUGH SKIN HARMFUL (RAPIDLY) ABSORBED THROUGH SKIN (See NOTE opposite page] POISONOUS IF SWALLOWED MAY BE FATAL IF SWALLOWED HARMFUL IF SWALLOWED [See NOTE opposite page] Do not get in eyes, on skin, on clothing, j Avoid contact with skin, eyes, and clothing. e-------------- ---------- -------- ----------------- f Wash thoroughly before eating or smoking. Wosh thoroughly after handling. IDo out breathe dust (vapor). Avoid breathing dust (vapor). Instructions in Cate of Contact or Exposure IMPORTANT: Select applicable ztatement(s) only. Selecfion(s) to be based on necessity for prompt action in order to ovoid serious effects. In cose of contoct, immediately Rush skin or eyes with plenty of water for (at least) 15 minutes; for eyes, get medical attention. (Wash clothing thoroughly at once.) Sweep up spillage ol once. Flush or absorb spillage with ........................... In case of contact, immediately Rush skin or eyes with plenty of water for (at least) 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. [See NOTE above] If spilled on clothing, remove and wash before re-use. In case of exposure to high concentrations, move to fresh oir. If affected by exposure, move to fresh oir. If breathing has stopped, apply artificial respiration. In cose of contact, (immediately) flush skin or eyes with plenty of water for (at feast) 15 minutes; for eyes, get medical attention. (Remove ond wash clothing before re-use.) In case of contact, immediately flush skin or eyes with plenty of water for (at least) 15 minutes; (for eyes.) get medical attention. (Remove ond wash clothing before re-use.) In case of contact, flush with (plenty of) water; (for eyes, get medical attention-.) In cose of contact, immediately (remove all contami nated clothing and) flush skin or eyes with plenty of water for (at least) 15 minutes; (for eyes.) gel medical attention. Wash clothing before re-use. [See NOTE above] (See NOTE above] 040377 Labe/s for Smalt Commercial Packages The General Principles governing the preparation of precautionary labels discussed in Part I and the illustrative labels in Part II of this Guide have been developed primarily for bulk packages of chemicals intended for industrial use. The General Principles may be applied, however, to chemicals packaged in small containers. These may include, among others, hazardous substances in retail packages intended for the ultimate consumer; highly purified chemicals intended for research, testing, or control; and chemicals intended for professional use such as in pharmacy. As stated in the General Principles on Page 12, each hazardous substance presents a distinct problem and must be treated individually in the light of its own characteristics. This same principle will apply to small containers. Small containers may present a problem of less available space for labeling purposes. Careful and selective shortening of precautionary statements for such containers may be in order if necessary to permit legibility, or if the wording on labels for the chemical in industrial packages is not applicable. Consideration should always be given to (1) the intended or reasonably anticipated handling or use of the particular product, (2) the training and experience of the expected user, and (3) the extent to which the hazard is modified by the size or type of container. The following principles are recommended for condensation of suggested label wording where necessary or advisable: (1) Retain the Signal Word; (2) Retain the Statement of Hazards, shortened if necessary to a practical equivalent; (3) Consider omission of Precautionary Measures if they are clearly indicated or implied from the Statement of Hazards or can be clearly indicated or implied by revising the Statement of Hazards; (4) Consider omission of wording relating to hazards that may be less serious because of the particular characteristics of the package, the nature of the use, and the training and experience of the user. Care must be taken to include Precautionary Measures for any additional hazard which may be present as a result of such characteristics, use, or training and experience. Care should b tak n that lab Is pr pared in accordance with the ab v principles include all information required by law. 22 Labels for Samples and for New Products for Investigational Use Samples: In general, the label for samples of a product should bear the same precautionary information that is on the commercial label, with the exception of possible differences in container instructions. If the prod uct is not in commercial production, the label for samples should be prepared in accordance with the General Principles stated on Page 12 in this Guide. New Products for Investigational Use: Chemical, physical, and toxicological data should be obtained on any product before it is distributed, so that hazardous properties can be described on the label. However, it may occasionally be necessary to make delivery of a new product for investigational use before ait of these data are obtained. For instance, the quantity available may be too small for necessary tests, or the product may have to be delivered to investigators for the purpose of obtaining the desired information. These deliveries should be made to qualified investigators only, and should be labeled as adequately as possible with the information avail able. To cover such cases (and such cases only) the following illustra tion is suggested for preparing labels to be used during the period of investigation. (NAME OR DESCRIPTION OF PRODUCT! FOR INVESTIGATIONAL USE ONLY SIGNAL WORD! STATEMENTS) OF KNOWN HAZARD(S) Appropriote precautionary measures. Appropriate instructions in case of contact or exposure. IMPORTANT) The chemical, physical, and toxicological pr perties of this product have not been fully investigated, and its handling or use may (be hazardous) (present additional hazards). Ex rcise due care. 23 CONTAINER HANDLING AND STORAGE Care should always be exercised in handling and storing containers of hazardous chemicals and in removing the contents. The Chemical Packaging Committee of the Manufacturing Chemists' Association, Inc., has recommended the general precautions given below for handling and storing certain classes of containers. Applicable phrases may be selected from these statements. These may be used either as separate labels or in combination with the precautionary labels illustrated in Part II. Where the properties of the substance require special or addi tional precautions, such instructions are indicated in some instances in conjunction with the individual label in Part II. Metal Drum Handling and Storage (far liquid* and **mi-liquid*) Keep plug up to prevent leakage. Keep drum out of sun and away from heat. Relieve internal pressure when received and at least weekly thereafter by slowly loosening plug. Retighten immediately. Drums should be grounded when being emptied. Do not drop or slide across sharp projection. Never use pressure to empty. Drum is not a pressure vessel. Keep lights, Are, and sparks away from drums. Drum must not be washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum. In case of spillage, flush with plenty of water. Glass Carb y Handling and Storage Before moving carboy be sure closure is securely fastened. Avoid rough handling or dropping. Loosen closure carefully. Keep carboy out of sun and away from heat. Never use pressure to empty. Carboy is not a pressure vessel. Completely drain carboy before returning. In case of spillage, flush with plenty of water. Wooden Barrel Handling and Storage {for liquid* and somi-liquid*) Keep barrel out of sun and away from heat. Store with bilge bung up. Never use pressure to empty. Drain completely. Keep barrel moist -shrinkage may cause leaks. In ease of spillage, flush with plenty of water. 24 Cylinder Handling and Storage Keep cylinder out of sun and away from beat. Never drop cylinders. Keep cylinders locked vertically to prevent falling and/or dropping. Be sure connections are light. ICC Regulations prohibit refilling cylinder without permission of owner. Have air line respirator or self-contained oxygen respirator available for emergency. Aerosol Containers The term "aerosol container" is generally applied to a container which holds its contents under pressure and is equipped with a dis pensing nozzle designed to release the container's contents through a very small orifice. While a true aerosol is a mist or spray of fine parti cles or droplets suspended in air, aerosol type containers are used for packaging and dispensing many products which do not form true aerosols' on release. Thus, there are aerosol products dispensed as depositing sprays (paints or insecticides) or as semi-liquid froths (whipping cream or shaving lather). In all cases, aerosol containers require more care in handling and storage than similar unpressurized containers, and particularly require protection from elevated tempera tures. When the contents are released as an aerosol or fine spray, there may be greater flammability or inhalation hazard than would be pre sented by the same product in other types of packaging and use. The Chemical Specialties Manufacturers Association suggests the following precautionary text for the pressure hazard presented by a metal aerosol container: WARNING! Contents under pressure. Do not puncture. Exposure to heat or prolonged exposure to sun may cause bursting. Do not throw into fire or incinerator. NOTE: Additional requisite cautions for statements as to hazards to persons and property, the safe dischatae of contents, etc. will depend upon the particular product. Appropriate modification of the above text may he required for an aerosol container made of a noil-metallic material. Also, additional precautionary labeling may be needed to warn against hazards presented by the contents of an aerosol container after release. Special test pro cedures developed by the Chemical Specialties Manufacturers Associa tion are used in determining the flammability hazards of products in aerosol containers. 25 040379 MANUAL L-l -- SIXTH EDITION 1961 In this new edition of Manual L-i, certain illustrative label texts have been added to illustrate specific new material types- Other texts which appeared in the 5th Edition have been revised in order to recog nize new information concerning tbe products' properties, or in con sideration of revised Container Handling and Storage precautions as set forth on Page 24. Finally, some texts have been deleted since the labeling principles which they illustrated are adequately illustrated by other texts in this Guide. The fact that a label text formerly used in Manual L-l is deleted from this edition does not imply that the material no longer requires precautionary labeling. Furthermore, the omission of a label text for a particular product does not indicate that the product does not require precautionary labeling. Individual statues, regulations, or ordinances may require that particular information be included in a label or that a specific label be affixed to a container. In each case, the requirements of such laws should be studied. PART II Acrolein Benzidine Hydrochloride Benzidine Sulfate Benzoyl Peroxide Beryllium Oxide Powder Butyllithium (normal) Calcium Cyanide Decaborane Iliborane Dichlorobenzene (ortho) Ethyl Acrylate Isopropylamine ADDED Lead Oxide (Red Lead) Methyl Acrylate Methylaniines, Anhydrous Methylamines, Aqueous Solutions Pentahorane Phosphorus Pentasulfide Potassium Dichromate Titanium Trichloride, Anhydrous Tolylene Diisocyanate Vanadium Tetrachloride Vinyl Acetate Zirconium Metal Powder LABELS REVISED Acetaldehyde Q Acetic Acid, Glacial Acetic Anhydride Acetyl Chloride Acrylonitrile Ally) Alcohol Allyl Chloride Aluminum Chloride, Anhydrous Ammonium Hydroxide iso-Amy! Acetate (now Amyl Acetate, Mixed Isomers) Aniline Antimony Trichloride Barium Chloride Benzyl Chloride Bromine Butadiene (now Butadiene, Inhibited) Butyl Alcohol (normal or secondary) n-Butylamine (now Butylamine, normal) Butyraldehyde Caustic Potash Caustic Soda Chlorine Chlorosulfonic Acid Chromic Acid [Chromium Trioxidc) (now Chromium Trioxide [Chromic Acid]) Cresol (Cresylic Acid) Cyanides, Inorganic Cycluhexane Continued Next Page 26 PART II--Continued LABELS REVISED Ibicliloroelhylcnc Dichloroethyl Ether Diethylamirie Diclhylenetriatnine [Uimethylamine, Anhydrous Dimethyl Sulfate Bioxane (1,4-Diethylene Dioxide) Ethyl Acetate ! Ethylene Chlorohydrin (Anhydrous or 38%) Ethylene Dichloride Ethylene Oxide , Formaldehyde Solution (Hydrochloric Acid (Muriatic Acid) Hydrocyanic Acid Hydrogen Chloride, Anhydrous Hydrogen Peroxide 7.4% Hydrogen Peroxide (stronger than 7.4% I hut not exceeding 52%) Hydrogen Sulfide ! Lead Monoxide (Litharge) Mercuric Chloride (Mercury Bichloride) I Methanol ; Methyl Bromide | Methyl Chloride Methyl Ethyl Ketone Methyl Methacrylate Monomer Methyl Morpholine | Mixed Acid (Sulfuric and Nitric) Morpholine Muriatic Acid I Naphthylamine (alpha) Paraformaldehyde Phenol Phosphoric Acid Phosphoric Anhydride (now Phosphorus Pentoxide) Phosphorus Phosphorus Penlacliloride Phtlialic Anhydride Potassium Hydroxide iso-Propyi Ether (now Isopropyl Ether) Pyridine Silver Nitrate Sodium Cyanide Sodium Fluoride Sodium Hydrosulfite Sodium Hydroxide Sodium Orthosilicate Sodium Sesquisilicate, Anhydrous Sodium Sulfhydrate Sodium Suliide Sulfur Chloride Sulfur Bichloride Sulfuryl Chloride Tar Acids Thiouyl Chloride Toluene (Toluol) Toluidine (ortho or nieta) Toluidine (para) Vinyl Acetate Xylene (Xylol) Ammonia, Anhydrous (Barium Nitrate Benzidine 1,2-Dichloroelhane Di-iso-Butyl Ketone ' Dimethylanilinc I Dipropyl Ketone I Ethyl Formate * Ethylene Dihromide Ethylene Glycol Monomethyl Ether I Mesityl Oxide Methyl Amyl Acetate Methyl Atnyl Alcohol Methyl n-Amyl Ketone , Methyl iso-Butyl Ketone LABELS DELETED Methyl Cyclohexanol Methyl Cyclohexanone Methyl iso-Propyl Ketone Methylene Chloride Nitrogen Dioxide Nilrophenol Pentachlorophenol Petroleum Naphthas and Solvents, Industrial Phenelidine (ortho or para) iso-Propyl Acetate Propylene Chlorohydrin Sodium Fluosilicate Telrachlorophcnol Trichlorophenol PART III LABELS ADDED 3-(alpha-Acetonylfurfuryl) 4-hydroxycoumarin and Sodium Salt Allyl Alcohol 2 Cat hoinethoxy-1 melhylvinyl Dimethylphosphalc and Beta Isomer 2-Chloroallyl Diethyldithiocarhamate alpha-Chloro-N,N-dialiylacetamide ],l-his(Chlorophcnyl) - 2,2,2-trichloroclhanol 1,2 Dihroino-3-chloropropane Continued Next Page 27 040380 PART III--Continued LABELS ADDED Dichloropropene Dichloropropanc Mixture Diethyl Diphenyl Dichloroelhane Dodine Hexaethyl Tetraphosphate Maleic Hydrazide, Diethanolamine Salt 1-Naphthyl N-Methylcarbamate Penlachloroniirobenzene Phorate Round N-Trichloromethylthiophthalimide LABELS REVISED Acrylonitrile Arsenicals, Liquid (Weed Killers) now Arsenical Weed Killers, Organic Calcium Arsenate Calcium Cyanide Chloranil Cyanides, Inorganic Dichlone Dichloroethyl Ether Ethylene Dibromide Ethylene Dichloride Formaldehyde Solutions (5% and over) Hydrocyanic Acid Lead Arsenate Malathion Methyl Bromide Nicotine Sulfate Parathion Paris Green Sodium Fluoride Sodium Fluosilicate Tetraethyl Pyrophosphate Thallium Sulfate Toxaphene Zinc Araenite Antu Aramite LABELS DELETED Barium Fluosilicate Glyodin O 28 PART II Illustrative Labels for Hazardous Chemicals The precautionary labels in this section have been prepared to demonstrate the practical application of the General Principles in Part I to a number of chemical products intended for industrial use. The user should familiarize himself with Part I before adapting any of the label statements contained in Part II to his products. The chemicals were selected to illustrate labeling for the major types of hazards com monly encountered. Consequently, the listing covers only relatively few of the hazardous chemicals for which precautionary labels are necessary. In many cases, these labels would be applicable to other products having the same hazards, and examples of this are listed by appropriate cross references. The labels are based on the properties of the named chemicals; the presence of other substances, including impurities, may alter these prop erties and necessitate additional or different precautionary information. General information regarding the handling and storage of con tainers is not included on these labels. This subject is discussed under the beading, "Container Handling and Storage", beginning on Page 24. First aid treatment is given for a few products only. Such informa tion may be desirable on other products. Where "clothing" is men tioned in first aid instructions, it should be understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions because of special hazards arising from absorption of the chemical by leather. The notation, "MCA Chemical Safety Data Sheet available", appear ing with certain labels in this section, refers to Data Sheets published by the Manufacturing Chemists* Association, Inc. These publications con tain detailed information on the chemical, physical, and toxicological properties of the product, as well as information on shipping containers, labeling, storage, handling, and protective equipment. Prices and a complete list of available Chemical Safety Data Sheets may be obtained directly from the Manufacturing Chemists' Association, Inc. (See Pages 95 and 96 for complete listing of Chemical Safety Data Sheets now available.) The labeling of radio-active materials is a complex problem outside the scope of this Guide. In preparing precautionary labels for such 29 materials, it is suggested that references be made to the series of hand books published by the U. S. Department of Commerce, National Bureau of Standards, covering the safe handling of radio-active materials. The illustrative precautionary labels suggested in Manual L-l should be used in addition to, or in combination with, any label required by law. ACETALDEHYDE DANGERI EXTREMELY FLAMMABLE MAY FORM EXPLOSIVE PEROXIDES UNDER AIR PRESSURE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. *Cool to below 68F. before opening. *Do not use air pressure to transfer. MCA Chunk'd Safety Data Sheet SD-43 available ACETIC ACID, GLACIAL DANGERI CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. Q Keep away from heat and open flame. In case of contact, immediately flush skin or eyes with plenty of o water for at least 15 minutes; for eyes, get medical attention. o <jj oo *Glacial Acetic Acid freezes at 62F., forming hard lumps which may break carboy when moved. * Store in area maintained above 62 F. *lf frozen, thaw by carefully moving carboy to warm area. MCA Chemical Safety Data Sheet SD-41 available* * Addition to "Container Handling and Storage", Pagfi 24. 30 ACETIC ACID, 80% DANGERI CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chamkal Safety Data Sheet SD-41 available ACETIC ACID, 56% -70% WARNINGI MAY CAUSE BURNS Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for ct least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Sheet SD-41 available ACETIC ACID, 28% CAUTIONI MAY CAUSE BURNS Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes,- for eyes, get medical attention. MCA Chamkal Safety Data Sheet SD-41 available 31 040382 ACETIC ANHYDRIDE DAN ERI CAUSES SEVERE BURNS VAPOR HARMFUL Do not get liquid or vapor in eyes, on skin, on clothing. Do not breathe vapor. In case of c ntact, immediately remove contaminated clothing and flush skin r eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chemical Safely Data Sheet SD-IS available ACETONE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ACETYL CHLORIDE DANGERI FLAMMABLE CAUSES SEVERE BURNS Keep away from heat, sparks, and open flame. Keep container closed. O Do not get in eyes, on skin, on clothing, g Avoid exposure to concentrated vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not allow water to get into container because of violent reaction. 32 ACROLEIN DANGERI EXTREMELY FLAMMABLE MAY BE FATAL IF INHALED LIQUID CAUSES SEVERE BURNS Keep away from heat, sparks, and open flame. Keep container closed. Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation. In case of contact, immediately remove contaminated clothing, includ ing shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash cl thing thor oughly before re-use. POISON Call A Physician First Aid If inhaled; Move patient to fresh air; if breathing becomes diffi cult, start oxygen inhalation through suitable equipment. If swallowed; If conscious, make patient vomit immediately (finger down throat or give warm mustard water or salt water freely). General: Keep patient warm; if conscious, give coffee. ACRYLONITRILE DANGERI VAPOR HAZARDOUS FLAMMABLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation. Keep away from heat, sparks, and open flame. Keep container closed. POISON First Aid (In addition, INCLUDE the some First Aid and Antidote as recommended for CYANIDES, INORGANIC shown on Page SI.) MCA Chemical Safety Data Sheet SD-31 available 33 ALLYL ALCOHOL DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN FLAMMABLE Do not get in eyes, on skin, on clothing. Do not breathe vapor. Do not take internally. Keep away from heat, sparks, and open flame. Keep container closed. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON Call A Physician First Aid ALLYL CHLORIDE DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL Keep away from heat, sparks, and open flame. Keep container closed. Q Use only with adequate ventilation. Do not get in eyes, on skin, on clothing. Do not breathe vapor. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. te e o ^ o 34 ALUMINUM CHLORIDE, ANHYDROUS WARNINGI MAY CONTAIN GAS UNDER PRESSURE CONTACT WITH WATER OR MOIST AIR LIBERATES HYDROCHLORIC ACID GAS CAUSES BURNS Loosen closure cautiously before opening. Avoid contact with eyes, skin, or clothing. Keep container tightly closed. In case of contact, immediately flush skin or eyes with plenty of water .for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safely Data Sheet SD-62 available AMMONIA, AQUASame label as AMMONIUM HYDROXIDE MCA Chemical Safety Data Sheet SD-13 available AMMONIUM DICHROMATE WARNINGI FLAMMABLE harmful dust MAY CAUSE RASH OR EXTERNAL ULCERS Keep away from heat, sparks, and open flame. Keep container closed. Avoid contact with skin and eyes. Avoid breathing dust or solution spray. In case of contact, immediately flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. MCA Chemical Safety Data Sheet SD-45 available 35 AMMONIUM HYDROXIDE WARNINGI LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Loosen cl sure cautiously before opening. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. MCA. Chemical Safety Dote Sh*t SD-13 avoilobU far AQUA AMMONIA AMYL ACETATE (mixed isomers) CAUTIONI Keep away from heat and open flame. Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ANILINE DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Avoid breathing vapor. a Use only with adequate ventilation. In case of contact, immediately remove all contaminated clothing, o including shoes, and flush skin or eyes with plenty of water for at O least 15 minutes; get medical attention. Wash clothing before liJ CD re-use. POISON Call A Physician First Aid MCA Chemical Safety Data Sheet $0-17 available 36 ANISIDINE ( rth ) WARNINGI HAZARDOUS LIQUID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. Use only with adequate ventilation. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. ANISIDINE (para) WARNINGI HAZARDOUS SOLID ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Avoid breathing dust. Use only with adequate ventilation. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. ANTIMONY TRICHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR HAZARDOUS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep container closed. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chemical Safely Data Sheet $0*66 available 37 040385 ARSENIC TRIOXIDE DANGERI MAY BE FATAL IF SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. & POISON Call A Physician First Aid MCA Chemical Safety Data Shaat SO-SO availobU BARIUM CHLORIDE DANGERI MAY BE FATAL IF SWALLOWED Do not take internally. Avoid breathing dust. Wash thoroughly after handling. POISON Call A Physician First Aid If swallowed: Give Epsom salt or sodium sulfate In water. o 38 BENZENE (BENZOL) DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL Keep away from heat, sparks, and open Dame. Keep container closed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. g* POISON Call A Physician First Aid MCA Chemical Safety Data Sheet SD-2 available BENZIDINE HYDROCHLORIDE DANGERI HAZARDOUS SOLID HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN REPEATED ABSORPTION MAY RESULT IN BLADDER TUMORS Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Take hot shower after work, using plenty of soap. BENZIDINE SULFATE Same label as BENZIDINE HYDROCHLORIDE 39 CMA 0 4 0 3 8 6 BENZOYL CHLORIDE WARNING! CAUSES BURNS VAPOR IRRITATING Avoid contact with skin and eyes. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BENZOYL PEROXIDE DANGERI FLAMMABLE SOLID OXIDIZING MATERIAL HEAT, SHOCK, OR CONTACT WITH OTHER MATERIALS MAY CAUSE FIRE OR EXPLOSIVE DECOMPOSITION BEFORE USING, READ MCA CHEMICAL SAFETY DATA SHEET SD-81 Store in a cool place in original container and protect from direct sunlight. Keep away from heat, sparks, and open flame. Do not add to hot materials; do not grind or subject to frictional heat or shock--explosive decomposition may result. Prevent contamination with readily oxidizable materials and poly merization accelerators. Avoid contact with skin, eyes, and clothing. For Wet Benzoyl Peroxide change the heading to read: BENZOYL PEROXIDE (Wet) Use label appearing above for Benzoyl Peroxide inserting immediately above the line-. Store in a cool place . . . the line: Keep container closed to prevent drying out. MCA Chemical Safety Data Sheet $0-8] available 40 BENZYL CHLORIDE (Stabilized) WARNINGI CAUSES BURNS Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Sheet SD-69 available BENZYL CHLORIDE (Unstabilized) WARNINGI CAUSES BURNS CONTAMINATION MAY RESULT IN DANGEROUS PRESSURE Keep dry and handle only in suitable equipment to prevent metallic contamination. Consult manufacturer. Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Sheet SD-69 available BERYLLIUM OXIDE POWDER DANGERI HAZARDOUS DUST Do not breathe dust. Use with adequate ventilation. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Wash clothing before re-use. Keep container tightly closed. Flush container clean before discarding. Avoid spillage. If any occurs, carefully wet down and remove. POISON Call A Physician First Aid 41 BROMINE DANGERI CAUSES SEVERE BURNS VAPOR HAZARDOUS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. Wear goggles, neoprene rubber gloves, and rubber protective cloth ing when handling. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin with plenty of water for at least 15 minutes. Flush eyes for at least 30 minutes. Get medical attention in all cases. Wash clothing before re-use. if inhaled, move patient to fresh air, keep him warm and quiet until physician arrives. MCA Chemical Safely Data Shaat SD-49 available BUTADIENE (Inhibited) DANGERI EXTREMELY FLAMMABLE MAY FORM EXPLOSIVE PEROXIDES ON EXPOSURE TO AIR Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. MCA Chemical Safely Dala Sheet $D-SS available BUTYL ACETATE (normal)Same label as AMYL ACETATE (mixed isomers) Q BUTYL ALCOHOL (normal or secondary) WARNINGI LIQUID CAUSES EYE BURNS q Keep away from heat and open flame. owo Avoid contact with the eyes. -a Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. In case of contact with eyes, immediately flush with plenty of water for at least 1 5 minutes. 42 BUTYL ALCOHOL (t rtiary)Same label as ETHYL ACETATE BUTYLAMINE (normal) WARNINGI FLAMMABLE CAUSES BURNS Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. BUTYLCATECHOL (para-tertiary) WARNINGI CAUSES SKIN IRRITATION CAUSES BURNS WHEN MOIST Do not get in eyes, on skin, on clothing. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. BUTYL CHLORIDE (normal) DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 43 BUTYL ETHER (n rmal) CAUTIONI TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from heat and open flame. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. Do not allow to evaporate to near dryness. Addition of water or appropriate reducing agents will lessen peroxide formation. BUTYLLITHIUM (normal) (25% or less in hydrocarbon solvents) DANGERI EXTREMELY FLAMMABLE IGNITES ON CONTACT WITH MOIST AIR CAUSES BURNS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Handle under inert gas atmosphere in DRY equipment. Keep away from heat, sparks, and open flame. Avoid spillage and contact with moisture or combustibles. Do not get in eyes, on skin, on clothing. Wear goggles and protective clothing when handling. In case of fire, use CO fire extinguisher. In case of contact, immediately flush skin with plenty of water; for eyes, flush with plenty of water for at least 15 minutes and get pr mpt medical attention. Remove and wash clothing before re-use. BUTYRALDEHYDE (iso or normal) o DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL o .p- Keep away from heat, sparks, and open flame. o OJ Keep container closed. oo oo Use with adequate ventilation. Avoid c ntact with eyes, skin, or clothing. In case of contact, immediately remove contaminated clothing, in cluding shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing thoroughly before re-use. MCA Chemical Safety Data Sheet SD*78 available 44 CALCIUM CYANIDE DANGERI POISONOUS SOLID LIBERATES POISONOUS GAS Do not take internally. Do not breathe gas or dust. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. Keep container tightly closed and away from water or acids. Clean up spillage immediately. Keep away from feed or food products. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before re-use. POISON ^ First Aid Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. Antidote If Cyanide Gas is inhaled; Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. If Cyanide is swallowed: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. If patient is con scious, or when consciousness returns, give emetic (1 tablespoonful of salt to each glass of warm water) and repeat until vomit fluid is clear. Repeat inhalation of amyl nitrite 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. Never give anything by mouth to an unconscious person. 45 040389 CARBON DIOXIDE, SOLID ("DRY ICE") WARNING! EXTREMELY COLD (109F. below zero) CAUSES SEVERE BURNS LIBERATES HEAVY GAS WHICH MAY CAUSE SUFFOCATION Do not get on skin or hands. Do not taste. Do not put in stoppered or closed containers. Do not enter places where used or stored until adequately ventilated. CARBON DISULFIDE DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE Keep away from fire, sparks, or heated surfaces. Store in cool place and keep container closed. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin and eyes. POISON Call A Physician First Aid MCA Chemical Safety Data Sheet SD-I2 available n 46 CARBON TETRACHLORIDE DANGERI HAZARDOUS VAPOR AND LIQUID MAY BE FATAL IF INHALED OR SWALLOWED Use only with adequate ventilation. Do not breathe vapor. Avoid prolonged or repeated contact with skin. Do not take internally. ^ POISON A Call A Physician First Aid MCA Chemical Safety Data Sheet SD-3 available CAUSTIC POTASHSame label as SODIUM HYDROXIDE MCA Chemical Safety Data Sheet SD-10 available CAUSTIC SODASame label as SODIUM HYDROXIDE MCA Chemical Safety Data Sheet SD-V available CHLORAL DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR INHALATION MAY CAUSE DELAYED FATAL LUNG INJURY Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. In case of inhalation or suspicion of inhalation, move patient at once to fresh air and call a physician. Keep patient absolutely quiet and start oxygen inhalation through suitable equipment. 47 CHLORINATED DIPHENYL (MONO, Dl, or TRI) Same label as CHLORINATED NAPHTHALENE CHLORINATED DIPHENYL OXIDE (MONO, Dl, or TRI) Same label as CHLORINATED NAPHTHALENE CHLORINATED NAPHTHALENE (For TRI and HIGHER CHLORINATED NAPHTHALENES) CAUTIONI Avoid repeated contact with skin. Av id repealed inhalation of fumes and dust. CHLORINE DANGERI HAZARDOUS LIQUID AND GAS UNDER PRESSURE DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Do not breathe air containing this gas. Do not get in eyes or on skin. Do not heat cylinders. Q Have available emergency gas masks approved by U.S. Bureau of Mines for Chlorine service. o In case of exposure, move patient to fresh air, keep him warm and ^ quiet, and call a physician. U) Vo MCA Chemical Safety Data Sheet 5D-80 available O 48 CHLOROBENZENE (MONO) WARNINGI VAPOR HARMFUL Keep away from heat and open flame Use only with adequate ventilation. Avoid contact with skin and clothing. Avoid prolonged breathing of vapor. CHLOROFORM WARNINGI VAPOR HARMFUL Use only with adequate ventilation. Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROPHENOL (MONOCHLOROPHENOL) ( rtho, meta, or para) -- Same label as CRESOL CHLOROSULFONIC ACID DANGER! CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not allow water to get into container because of violent reaction. MCA Chamical Safely Data SHmI SD-33 available CHLOROTOLUENE (MONO) CAUTIONI VAPOR HARMFUL Keep away from heat and open flame. Use with adequate ventilation. Avoid prolonged breathing of vapor. 49 040391 CHROMIUM TRIOXIDE (CHROMIC ACID) DANGER! STRONG OXIDANT CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE MAY CAUSE BURNS OR EXTERNAL ULCERS Keep container closed. Do not get in eyes, on skin, on clothing. Do not breathe dust or mist from solutions. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before refuse. Use fresh clothing daily. Take hot shower after work, using plenty of soap. MCA Chemical Safety Data Sheet SD-44 available CREOSOTE OIL (COAL TAR CREOSOTE) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repealed contact with skin. Avoid prolonged breathing of vapor. Use with adequate ventilation. CRESOL (CRESYLIC ACID) DANGERI HAZARDOUS LIQUID RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chemical Safety Data Sheet SD-4B available 50 CYANIDES, INORGANIC (Excluding HYDROCYANIC ACID and CALCIUM CYANIDE) (NAME Of CYANIDE) DANGERI POISONOUS SOLID CONTACT WITH ACID LIBERATES POISONOUS GAS Do not breathe gas or dust. Do not take internally. Avoid contact with eyes and skin. Wash thoroughly after handling. Keep container closed and away from acids. Store in a dry place. Keep away from feed and foodstuffs. In case of contact with eyes, flush with plenty of water for at least 15 minutes and get medical attention. POISON First Aid Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. Antidote If Gas is inhaled: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. If swallowed: Break an amyl nitrite pearl in a cloth and hold {ightly under nose for 15 seconds. If patient is conscious, or when con sciousness returns, give emetic (1 tablespoonful of salt to each glass of warm water) and repeat until vomit fluid is clear. Repeat inhalation of amyl nitrite 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. Never give anything by mouth to an unconscious person. MCA Chemical Safety Data Sheet SD-30 available far SODIUM CYANIDE 51 040392 CYCLOHEXANE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. MCA Chemical Safety Data Sheet SD-61 available CYCLOHEXANOL CAUTIONI VAPOR. HARMFUL Use nly with adequate ventilation. Avoid prolonged breathing of vapor. * Avoid prolonged or repeated contact with skin. CYCLOHEXANONE CAUTIONI VAPOR HARMFUL Keep away from heat and open flame. Use only with adequate ventilation. O Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 52 DECABORANE DANGERI HAZARDOUS SOLID AND VAPOR POISONOUS IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN FORMS SHOCK-SENSITIVE MIXTURES WITH CERTAIN OTHER MATERIALS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Always wear a self-contained breathing apparatus or full-face air line respirator when using this chemical. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep from contact with oxidizing materials, highly oxygenated or halogenated solvents, organic compounds containing reducible functional groups, or aqueous ammonia. In case of contact, immediately wash skin with soap and plenty of water. Flush eyes with water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. * POISON Call A Physician First Aid Move patient to fresh air; keep him warm and quiet. If swallowed: If conscious, give a tablespoonful of salt in a glass of warm water and repeat until vomit fluid is clear. Note to physician: Treat symptomatically. Symptoms may be delayed up to 48 hours after suspected exposure. Allow rest; keep under observation. Administration of methocarbamol or other muscle relaxants may be helpful immediately following exposure and in absence of symptoms. 53 040393 DIBORANE DANGERI EXTREMELY FLAMMABLE GAS UNDER PRESSURE EXTREMELY IRRITATING IF INHALED REACTS VIOLENTLY WITH OXIDIZING MATERIALS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Keep away from heal, sparks, and open flame. Do no! breathe gas. Use only with adequate ventilation. Have available emergency self-contained breathing apparatus, or full-face air-line respirator when using this chemical. Keep from contact with oxidizing materials. Note: This gas deadens the sense of smell. Do not depend on odor to detect presence of gas. POISON Call A Physician First Aid Move patient to fresh air; keep him warm and quiet. Note to physician: Treat as irritant gas. Administration of oxygen and br nchodilators may be helpful. DICHLOROBENZENE (ortho) CAUTIONI VAPOR IRRITATING Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. If liquid gets in eyes, immediately flush thoroughly with plenty of water. MCA Chemical Safety Pata Sheet SD-54 available 54 DICHLOROETHYLENE WARNINGI FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. DICHLOROETHYL ETHER DANGERI MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN Do not get on skin or clothing. Do not breathe vapor. Use only with adequate ventilation. Do not take internally. In case of contact, immediately remove contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes. Wash clothing before re-use. POISON g* Call A Physician First Aid 2,4-DICHLOROPHENOL WARNINGI CAUSES BURNS Avoid contact with eyes, skin, and clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. 55 040394 DIETHYLAMINE -- Same label as METHYLAMINES, AQUEOUS SOLUTIONS MCA Chemical Safely Data Sheet SD-S7 available far METHYLAMINES DIETHYLENETRIAMINE DANGERI CAUSES SEVERE EYE AND SKIN BURNS Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated breathing of vapor. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes; for eyes, get prompt medical attention. Remove contaminated clothing, including shoes. Wash clothing before re-use; discard contaminated shoes. MCA Chemical Safety Data Sheet SD-76 available ' DIMETHYLAMINE, ANHYDROUS DANGERI EXTREMELY FLAMMABLE HAZARDOUS LIQUID AND VAPOR UNDER PRESSURE LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Keep away from heat, sparks, and open flame. Use only with adequate ventilation. Do not breathe vapor. Do n t get in eyes, on skin, on clothing. In case f contact, immediately flush skin or eyes with plenty of water f r at least 15 minutes. Wash clothing before re-use. Call physician at once in case of burns, especially to eyes, nose, and throat, or if patient is unconscious. Have air-line respirator or self-contained oxygen respirator available for emergency. MCA Chvmical Safety Data Shunt SD-57 availabl* for METHYLAMINES 56 DIMETHYL SULFATE DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. Wear goggles and rubber gloves when handling. In case of spillage, cover immediately with-dry soda ash. POISON Call A Physician First Aid Start treatment immediately. Eyes: Flush with water for at least 15 minutes. Skin: Remove all contaminated clothing and flush skin with water for at least 15 minutes. Inhalation; If breathing becomes difficult, start oxygen inhalation through suitable equipment. MCA Chemical Safely Data Sh**t SD-19 availabl* DIOXANE (1,4-DIETHYLENE DIOXIDE) WARNINGI FLAMMABLE VAPOR HARMFUL TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. Do not allow to evaporate to near dryness. Addition of water or appropriate reducing agent will lessen peroxide formation. 57 040395 ETHYL ACETATE WARNINGI FLAMMABLE Keep away from heat, fparks, and open flame. Keep container dosed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. MCA ctwmical Safety Data Shea! $D-5t available ETHYL ACRYLATE (Inhibited with...................... ) WARNINGI FLAMMABLE VAPOR HARMFUL MAY IRRITATE SKIN AND EYES Keep away from heat, sparks, and open flame. Keep container dosed. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash contaminated clothing before refuse. MCA Chemical Safety Data Sheet SD-7V available n ETHYL BROMIDE WARNINGI VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged breathing of vapor. Keep container closed, out of sun, and away from heat. 58 ETHYL CHLORIDE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Use with adequate ventilation. Keep container closed, out of sun, and away from heat. MCA Chemical Safety Data Shift SD-50 available ETHYL ETHER DANGERI EXTREMELY FLAMMABLE HIGHLY VOLATILE TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from heat, sparks, and open flame. Keep container tightly dosed. Do not allow to evaporate to near dryness. Addition f water or appropriate reducing agent will lessen peroxide formation. MCA Chemical Safvty Data Shoal SD-29 available 59 040396 ETHYLENE CHLOROHYDRIN (ANHYDROUS or 38/o) DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN CAUSES BURNS TO EYES Do not get in eye*, on skin, on clothing. Ordinary rubber protec tive clothing, including gloves, will not prevent skin absorption. Do not breathe vapor. Use only with adequate ventilation. Do not take internally. Keep away from heat and open flame. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON g* Call A Physician First Aid If swallowed: If conscious, make patient vomit immediately by putting Anger down throat or by giving warm mustard water or salt water freely. General: Keep patient warm; if conscious, give black coffee. Note to Physician; Do not give adrenalin. ETHYLENEDIAMINE Q DANGERI CAUSES SEVERE EYE AND SKIN BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Keep away from heat and open flame. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes; for eyes, get prompt medical attention. Remove contaminated clothing, including shoes. Wash clothing before re-use; discard contaminated shoes. `This product freezes at approximately 50F, ' Addition to "Container Handling and Storage", Pogo 24. 60 ETHYLENE DICHLORIDE WARNINGI FLAMMABLE VAPOR HARMFUL Keep away from heat, sparks, and open flame. Keep container dosed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MCA Chemical Safely Data Sheet SD-18 available ETHYLENE OXIDE DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL MAY CAUSE BURNS Keep away from heat, sparks, and open flame. Keep container closed. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Discard contaminated shoes. MCA Chemical Safety Data Shed SD-3S available 61 FORMALDEHYDE SOLUTION WARNINGI CAUSES IRRITATION OF SKIN, EYES, NOSE, AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. POISON * Call A Physician First Aid If swall wed: Give a tablespoonfui of salt in a glass of warm water and repeat until vomit fluid is clear. Give milk or white of egg beaten with water. MCA Chemical Safety Data Sheet SD-1 available FORMIC ACID Same label as HYDROCHLORIC ACID HYDROCHLORIC ACID WARNINGI CAUSES BURNS q Avoid contact with skin and eyes, g Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water > for at least 15 minutes; for eyes, get medical attention. o MCA Chemical Safety Data Sheet SMf available -J 62 HYDROCYANIC ACID DANGERI EXTREMELY HAZARDOUS LIQUID AND GAS EXTREMELY FLAMMABLE MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN USE ONLY IN A CLOSED SYSTEM. Keep away from heat, sparks, and open flame. Do not take internally. Do not breathe gas. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before re-use. POISON &> First Aid Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. Antidote If Cyanide Gas is inhaled: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. If Cyanide is swallowed: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. If patient is conscious, or when consciousness returns, give emetic (1 tablespoonful of salt to each glass of warm water) and repeat until vomit fluid is clear. Repeat inhalation of amyl nitrite 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. Never give anything by mouth to an unconscious pers n. MCA Chemical Safety Data Shvat SD-67 availabl* 63 HYDROFLUORIC ACID, ANHYDROUS DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not get in eyes, on skin, on clothing. Do not breathe vapor. Store out of sun and away from direct heat. UNLOAD ONLY IN ACCORDANCE WITH PRACTICE RECOMMENDED IN MANUFACTURING CHEMISTS' ASSOCIATION, INC. MANUAL H-10. Read also MCA Chemical Safety Data Sheet SD-25. First Aid, In Case of Contact or Suspicion of Contact. Always have on hand a supply of Magnesia paste (magnesium oxide and glycerin). Skin: Immediately flush with large quantities of cold water until all acid is removed (up to 3-4 hours or until medical attention is obtained), paying particular attention to skin under nails. In case medical attention is delayed, apply a mixture of glycerin with either magnesium oxide or milk of magnesia. Get medical atten tion. Remove and wash clothing before re-use. Eyes: Immediately flush with cool water for 15-30 minutes; Prompt medical attention is absolutely necessary. MCA Chemical Safety Data Sheet SD*25 available HYDROFLUORIC ACID, AQUEOUS DANGERI HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE (In addition to above Statement*, alto include balance at precautionary label recommended for HYDROFLUORIC ACID. ANHYDROUS) MCA Chemical Safely Data Sheet SD-25 available HYDROGEN CHLORIDE, ANHYDROUS DANGERI HAZARDOUS LIQUID AND GAS UNDER PRESSURE CAUSES BURNS EXTREMELY IRRITATING Do not breathe gas. Do not get in eyes or on skin. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. `NOTE: Suck-back Into Cylinder May Cause Explosion. Under no circumstances should the cylinder delivery tube be inserted in a liquid or gas without a vacuum break or other protective apparatus in the line to prevent suck-back. MCA Chamical Softly Data Shaal SD-39 available HYDROGEN PEROXIDE 7.4% CAUTIONI STRONG OXIDANT Avoid contact with skin and eyes--wear rubber gloves and goggles. Avoid contamination from any source, including metals, dust, and organic materials. Such contamination may cause rapid decom position, generation of large quantities of oxygen gas, and high pressures. * Store in original closed container. `Be sure that the container vent is working satisfactorily. *Do not add any other product to this container. `When empty, rinse thoroughly with clean water. MCA Chemical Safety Data Sheet $D53 Supplement! A & B available CMA 0 4 0 3 9 8 Addition to "Container Handling and Storage", Page 24. 64 I 65 HYDROGEN PEROXIDE (stronger than 7.4% but not exceeding 52%) CAUTIONI STRONG OXIDANT Avoid c ntact with skin and eyes--wear rubber gloves and goggles. Avoid contact with combustible materials. Drying of this concentrated product on clothing or combustible materials may cause fire. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing at once. Avoid contamination from any source, including metals, dust, and organic materials. Such contamination may cause rapid decom position, generation of large quantities of oxygen gas, and high pressures. * Store in original closed container. *Be sure that the container vent is working satisfactorily. *Do not add any other product to this container. 'When empty, rinse thoroughly with clean water. MCA Chemical Safety Data Sheet SD-S3 Supplements All available HYDROGEN PEROXIDE, HIGH STRENGTH ( v r 52%) DANGERI POWERFUL OXIDANT CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Wear goggles, rubber gloves, protective outer clothing, and heavy rubber shoes. Keep from contact with combustible materials. Spills on clothing or combustible materials will cause fire. Flush spillage with water. Keep from contamination from any source, including metals, dust, and organic materials. Such contamination can cause rapid decomposition, generation of high pressures or formation of explosive mixtures. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes. GET MEDICAL ATTENTION. Wash clothing promptly and thoroughly. * HANDLING INSTRUCTIONS Do Not Open Unless You Have Been Properly Instructed. Store in original closed container. Store container in a cool, clean place. Keep drum in upright position. Do not roll drum on side. Wash leakage with water. Put nothing else in this container. When Empty, Drain And Flush Container Thoroughly With Clean Water . . . Replace Bungs Securely. MCA Chemical Safety Pata Shoot SD-53 Supplements ABB available CMA 0 4 0 3 9 9 * Addition to "Container Handling and Storage'*, Page 34. 66 * Addition to "Container Handling and Storage", Pago 24. 67 040400 HYDROGEN SULFIDE DANGERI POISONOUS LIQUID AND GAS UNDER PRESSURE FLAMMABLE BEFORE USING, READ MCA CHEMICAL SAFETY DATA SHEET SD-36 Do not breathe gas. Keep away from heat, sparks, and open flame--may form explosive mixture with air, NOTE: This gas deadens the sense of smell. D not depend on odor to detect presence of gas. POISON g* Call A Physician First Aid Carry patient to fresh air. If patient has stopped breathing, apply artificial respiration imme diately. Keep patient warm. MCA Chemical Safety Data Shaat SD-36 available ISOPROPYLAMINE DANGERI EXTREMELY FLAMMABLE VAPOR EXTREMELY HAZARDOUS LIQUID CAUSES BURNS Keep away from heat, sparks, and open flame. Keep container closed. Do not breathe vapor. Use only with adequate ventilation. Do not get in eyes, on skin, on clothing. In case of contact, immediately remove contaminated clothing, in cluding shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chtmical Safety Data Sheet SD~72 available 68 ISOPROPYL ETHER-Sam lab I as ETHYL ETHER LEAD ACETATE WARNINGI HARMFUL DUST Avoid breathing dust. Wash thoroughly before eating or smoking. Keep away from feed or food products. LEAD MONOXIDE (LITHARGE) Same label as LEAD ACETATE MCA Chemical Safety Data Sheet SD-64 available for LEAD OXIDES LEAD OXIDE (RED LEAD)Same label as LEAD ACETATE MCA Chemical Safety Data Sheet SD-64 available MALEIC ANHYDRIDE WARNINGI CAUSES BURNS Avoid contact with skin, eyes, and clothing. Avoid exposure to concentrated vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MERCURIC CHLORIDE (MERCURY BICHLORIDE) DANGERI HARMFUL DUST MAY BE FATAL IF SWALLOWED Do not breathe dust or vapor. Avoid contact with eyes or prolonged contact with skin. Keep away from feed or food products. Wash thoroughly before eating or smoking. Use fresh clothing daily. Take hot shower after work, using plenty of soap. POISON Call A Physician First Aid 69 040401 METHANOL DANGER! FLAMMABLE VAPOR HARMFUL MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED CANNOT BE MADE NONPOISONOUS Keep away from heat, sparks, and open flame. Keep container closed. Av id prolonged or repeated breathing of vapor. Use only with adequate ventilation. g* POISON .* Call A physician First Aid If swallowed: Give a tablespoonful of salt in a glass of warm water and repeat until vomit fluid is clear. Give two teaspoonfuls of baking soda in a glass of water. Have patient lie down and keep warm. Cover eyes to exclude light. METHANOL MIXTURES For products containing mothanol in proportion sufficient to create hazard because of mothanol content, uio applicable statements as above, with addition ofi CONTAINS OVER..................... % OF METHANOL The word "FLAMMABLE" may be omitted from the Statement of Hazards if the product has a flash point above 80 F. MCA Chemical Safety Data Sheet SD-22 available n 70 METHYL ACRYLATE (Inhibited with...................... ) WARNING! FLAMMABLE VAPOR HARMFUL MAY IRRITATE SKIN AND EYES Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash contaminated clothing before re-use. MCA Chemical Safety Data Sheet SD-79 available METHYLAMINES, ANHYDROUS-- Same label as DIMETHYLAMINE, ANHYDROUS MCA Chemical Safely Data Sheet SD-83 available far ETHYL ACETATE METHYLAMINES, AQUEOUS SOLUTIONS DANGERI EXTREMELY FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chvmical Saftty Data Sht SD-57 available 71 040402 METHYL BROMIDE DANGERI VAPOR EXTREMELY HAZARDOUS HIGHLY VOLATILE CAUSES BURNS Do not breathe vapor. D not get in eyes, on skin, on clothing. Keep away from heat. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin thoroughly with soap and water; for eyes, flush with plenty of water for at least IS minutes; get medical attention. Do not re-use shoes or clothing until free from all contamination. g* POISON Call A Physician First Aid ; Remove patient to fresh air. Keep lying down and warm. Use artificial respiration if breathing has stopped. Get IMMEDIATE medical attention. Use oxygen inhalator only at the direction of a physician. On Can Label Add: IMPORTANT! The contents of this can afe under pressure. Do not use ordinary can opener. Special handling equipment is available. Contact <"*** equipment and proper use. MCA Chvmical Safvty Data Shot SD-35 available ................ for information on 72 METHYL CHLORIDE WARNINGI FLAMMABLE LIQUID AND GAS UNDER PRESSURE VAPOR HARMFUL Keep away from heat, sparks, and open flame. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin. MCA Chemical Safely Data Sheet $0-40 available METHYL ETHYL KETONESame label as ETHYL ACETATE MCA Chemical Safety Data Sheet 5D*83 available METHYL METHACRYLATE MONOMER WARNINGI FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin, eyes, and clothing. METHYL MORPHOLINE WARNINGI HAZARDOUS LIQUID AND VAPOR MAY CAUSE SKIN IRRITATION FLAMMABLE Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. Keep away from heat, sparks, and open flame. Keep container closed. 73 MIXED ACID (SULFURIC and NITRIC) DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING SPILLAGE MAY CAUSE FIRE OR LIBERATE DANGEROUS GAS Do not breathe vapor. D not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. MCA Safaty Data Shitl SD-65 available MONO-COMPOUNDS -- See alt motive chemical name, e.g., CHLOROPHENOL for MONOCHLOROPHENOL MORPHOLINE WARNING! CAUSES EYE BURNS Q MAY CAUSE SKIN IRRITATION ABSORPTION THROUGH SKIN HARMFUL Do not get in eyes, o Avoid c ntact with skin or clothing, o Keep away from heat and open flame. w In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove contaminated clothing and wash before re-use. MURIATIC ACID Same label as HYDROCHLORIC ACID MCA Chemical Safaty Data Sheet SD-39 availabla for HYDROCHLORIC ACID 74 NAPHTHYLAMINE (alpha) (containing b taNAPHTHYLAMINE) Same label as NAPHTHYLAMINE (beta) MCA Chamical Safely Data Shea! SD-32 availabla for BETANAPHTHYLAMINE NAPHTHYLAMINE (beta) WARNINGI HARMFUL DUST AND VAPOR REPEATED ABSORPTION MAY RESULT IN BLADDER TUMORS Use only with adequate ventilation. Avoid breathing dust or vapor. Avoid contact with skin. Wear fresh clothing daily. Take hot shower after work, using plenty of soap. MCA Chemical Safety Data Sheet SD-32 available NITRIC ACID DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING SPILLAGE MAY CAUSE FIRE OR LIBERATE DANGEROUS GAS Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. MCA Chemical Safaty Data Sheet SD-5 available 75 040404 NITROANIUNE ( rth , m ta, or para) DANGERI HAZARDOUS SOLID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Avoid breathing dust or vapor. Use only with adequate ventilation. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. Wash clothing before re-use. NITROBENZENE - Same label as ANILINE MCA Chemical Safely Data Sheet 5D-2I available OLEUM (FUMING SULFURIC ACID) DANGERI CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. D not add water to contents while in a container because of violent reaction. MCA Chamical Safety Data Sheet SD-20 available far SULFURIC ACID OXALIC ACID WARNINGI HARMFUL IF SWALLOWED CAUSES SKIN IRRITATION Avoid breathing dust. Avoid contact with skin and eyes. Do not take internally. Keep away from feed or food products. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. 76 PARAFORMALDEHYDE WARNINGI CAUSES IRRITATION OF SKIN, EYES, NOSE, AND THROAT Avoid prolonged or repeated contact. Avoid breathing dust or prolonged breathing of vapor. Use with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. * POISON g* Call a Physician Immediately First Aid If swallowed: Give a tablespoonful of salt in a glass of warm water and repeat until vomit fluid is clear. Give milk, or white of ' egg beaten with water. MCA Chemical Safety Data Sheet 5D-6 available PARALDEHYDE CAUTIONI VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Keep away from heat and open flame. Do not take internally. "Solidifies at about 54F. (12C.) and may break container. "Store in a moderately warm place. * Addition to "Container Handling and Storage", Page 24, 77 040405 PENTABORANE DANGERI POISONOUS IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN EXTREMELY FLAMMABLE LIQUID UNDER PRESSURE FORMS SHOCK-SENSITIVE MIXTURES WITH CERTAIN OTHER MATERIALS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Always wear self-contained breathing apparatus or full-face air-Une respirator when using this chemical. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat, sparks, and open flame. Keep from contact with oxidizing materials, highly oxygenated or hal genated solvents, and organic compounds containing reducible functional groups. > In case of c ntact, immediately wash skin with soap and plenty of water. Flush eyes with plenty of water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. POISON g* Call A Physician First Aid Move patient to fresh air; keep him warm and quiet. Note to physician: Treat symptomatically. Symptoms may be delayed up to 48 hours after suspected exposure. Allow rest; keep under observation. Administration of methocarbamol or other O muscle relaxants may be helpful immediately following exposure g and in absence of symptoms. 78 PERCHLORIC ACID DANGERI STRONG OXIDANT CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR EXPLOSION, ESPECIALLY IF HEATED CAUSES SEVERE BURNS Keep container closed and away from heat. Store separately from, and avoid contact with, dehydrating agents and other materials. Do not get in eyes, on skin, on clothing. In case of spillage, flush with plenty of water and remove contam inated articles. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chamical Safety Data Sheet SD-II available PERCHLOROETHYLENE (TETRACHLOROETHYLENE) Same label as TRICHLOROETHYLENE MCA Chemical Safely Data Sheet SD-34 available PHENOL DANGERI HAZARDOUS LIQUID OR SOLID RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. "A* POISON Call A Physician First Aid MCA Chemical Safety Data Sheet $0-4 available 79 PHENYLENEDIAMfNE (m ta or para) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. PHOSPHORIC ACID CAUTIONI CAUSES SKIN IRRITATION Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Sheet SD-70 available PHOSPHORUS, White or Yellow (For Wet Shipments) DANGERI CAUSES SEVERE BURNS Contents packed under water and will ignite if water is removed. Do not get on skin or in eyes. Wear heavy rubber gloves and goggles or face shield. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet until medical attention is obtained. 4- POISON Call A Physician First Aid MCA Chemical Safety Data Sheet SD-16 availabU n o o o cn 80 PHOSPHORUS OXYCHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY IRRITATING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. In case of spillage, flood carefully with LARGE VOLUME of water and provide adequate ventilation. Do not add water to contents while in a container because of violent reaction. *Do not open unless you have been properly instructed. *Do not use this container for any other product. MCA Chamical Safely Data Sheet SD-26 available PHOSPHORUS PENTACHLORIDE WARNINGI HAZARDOUS DUST CAUSES BURNS Do not breathe dust. Do not get on skin or in eyes. Wear rubber gloves and goggles. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Open container carefully. Do not add water to contents while in a container because of violent reaction. * Addition to "Container Handling and Storage", Page 24. 81 PHOSPHORUS PENTASULFIDE WARNINGI HARMFUL DUST CONTACT WITH WATER OR ACID SLOWLY LIBERATES POISONOUS AND FLAMMABLE HYDROGEN SULFIDE GAS Avoid breathing dust or evolved gas. Avoid contact with skin, eyes, and clothing. Use only with adequate ventilation. Keep container tightly closed. Avoid friction or rough handling because of fire hazard. fires with Carbon Dioxide or Sand. Smother MCA Chemical Safely Data Sheet $0-71 available PHOSPHORUS PENTOXIDE (PHOSPHORIC ANHYDRIDE) WARNINGI CAUSES BURNS Avoid contact with skin and eyes. Wear rubber gloves and goggles. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Open container carefully. Do not add water to contents while in a container because of violent reaction. MCA Chvmical Safety Data Shaal SD-ll available O o o o -J 82 PHOSPHORUS TRICHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY IRRITATING CONTACT WITH WATER MAY CAUSE FLASH FIRE Do not get in eyes, on skin, on clothing. Do not breathe vapor. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. In case of spillage, flood carefully with LARGE VOLUME f water and provide adequate ventilation. Do not add water to contents while in a container because of violent reaction and possible flash fire. *Do not open unless you have been properly instructed. * Do not clean or re-use this container. MCA Chemical $sfty Data Shtst SD-27 available PHTHALIC ANHYDRIDE (SOLID) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid breathing dust. MCA Chemical Safety Data Sheet &D-61 available POTASSIUM DICHROMATESame label as SODIUM DICHROMATE MCA Chemical Safety Data Sheet SD-46 available * Addition to "Container Handling and Storage", Page 24, 83 040408 POTASSIUM HYDROXIDESam label as SODIUM HYDROXIDE MCA Chemical Safely Data Sheet SD-IQ available for CAUSTIC POTASH PROPYLENE Sam label as ETHYL CHLORIDE MCA Chemical Safety Data Shut 5D-59 available PYRIDINE WARNINGI FLAMMABLE VAPOR HARMFUL Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. SILVER NITRATE WARNINGI MAY CAUSE BURNS Avoid contact with skin and eyes. In case of contact, flush skin or eyes with water for at least 15 minutes,- for eyes, get medical attention. & POISON g* Call A Physician First Aid 84 SODIUM METAL DANGERI REACTS VIOLENTLY WITH WATER LIBERATING AND IGNITING HYDROGEN MAY CAUSE BURNS Keep from any possible contact with water. Keep container tightly closed. Do not get in eyes or on skin. Wear goggles and DRY gloves when handling. In case of fire, smother with DRY SODA ASH--NEVER USE WATER OR CHEMICAL FIRE EXTINGUISHERS. Dispose of SODIUM by burning carefully in an open fire. First Aid Skin; Remove SODIUM and flush affected area with water. Eyes: IMMEDIATELY flush eyes with plenty of water for 15 minutes. Get medical attention. MCA Chemical Safely Data Shot SD-47 available SODIUM CHLORATE WARNINGI STRONG OXIDANT CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE Clothing and vegetation contaminated with chlorate or its solutions are DANGEROUSLY FLAMMABLE. Remove cl thing and wash thor oughly with water. Keep persons and animals off treated areas. Spillage may cause Fires. Do not get on floor. Sweep up and remove immediately. When not in use, keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. MCA Chemical Safety Data Sheet SD*42 available SODIUM CYANIDESame label as CYANIDES, INORGANIC MCA Chemical Safely Data Sheet $D-30 available 85 SODIUM DICHROMATE WARNING! HARMFUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS Keep container closed. Avoid contact with skin and eyes. Avoid breathing dust or solution spray. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Use fresh clothing daily. Take hot shower after work, using plenty of soap. MCA Chemical Safety Data Sheet SIMA available SODIUM FLUORIDE WARNINGI MAY BE FATAL IF SWALLOWED Avoid breathing dust. Wash thoroughly after handling. Clean up spillage. SODIUM HYDROSULFITE CAUTIONI MAY IGNITE IF ALLOWED TO BECOME DAMP Keep container tightly closed. Use only dry, dean utensils in handling. Q Store in a cool, dry place. ^ In case of fire, smother with SODA ASH, DRY SAND, or CARBON o DIOXIDE. Dispose of by flushing away with a LARGE VOLUME of o water under adequate ventilation, o 10 86 SODIUM HYDROXIDE DANGER! CAUSES SEVERE BURNS TO SKIN AND EYES Do not get in eyes, on skin, on clothing. Do not take internally. When handling, wear goggles or face shield. While making solu tions, add slowly to surface of solution to avoid violent spattering. In case of contact, immediately flush skin with plenty of water,- for eyes, flush with plenty of water for at least 15 minutes and get medical attention. MCA Chemical Safety Data Sheet SD-9 available for CAUSTIC SODA SODIUM ORTHOSILICATE WARNINGI CAUSES SEVERE BURNS TO SKIN AND EYES Avoid contact with skin, eyes, and clothing. Do not take internally. When handling, wear goggles or face shield. While making solu tions, add slowly to surface of solution to avoid violent spattering. In case of contact, immediately flush skin with plenty of water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. SODIUM SESQUISILICATE, ANHYDROUSSame label as SODIUM ORTHOSILICATE SODIUM SULFHYDRATE -- Same label as SODIUM SULFIDE 87 SODIUM SULFIDE (Containing 35% or more combined water) DANGERI CONTACT WITH ACID LIBERATES POISONOUS GAS BURNS SKIN AND EYES Do not breathe dust or gas. Do not get in eyes, on skin, on clothing. Keep container closed and away from acid and heat. Sweep up spillage. Do not Rush to sewer which may contain acid. In case of c ntact, immediately flush skin or eyes with plenty of water for at least IS minutes,- for eyes, get medical attention. Remove and wash clothing before re-use. STYRENE MONOMER CAUTIONI VAPOR HARMFUL Keep away from heat and open flame. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin, MCA Chemical Safety Data Sheet SD-37 available o SULFUR CHLORIDE $ WARNINGI CAUSES BURNS o VAPOR IRRITATING Avoid contact with eyes, skin, and clothing. 1-1 In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not all w water to get into container because of violent reaction. MCA Chemical Safety Data Sheet SD-77 available far SULFUR CHLORIDES SULFUR DICHLORIDE Same label as SULFUR CHLORIDE MCA Chemical Safety Data Sheet SD-77 available far SULFUR CHLORIDES 88 SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. MCA Chemical Safvly Data Sheet SD-20 available SULFURYL CHLORIDESame label as SULFUR CHLORIDE TAR ACIDS-- Same label as CRESOL TETRACHLOROETHANE DANGERI VAPOR EXTREMELY HAZARDOUS Use only in completely enclosed system. Do not breathe vapor. Do not get in eyes, on skin, on clothing. Do not lake internally. POISON ^ Call A Physician First Aid MCA Chemical Safety Data Sheet $D~34 available TETRACHLOROETHYLENE (PERCHLOROETHYLENE) Same label as TRICHLOROETHYLENE MCA Chemical Safely Data Sheet SD-24 available for PERCHLOROETHYLENE 89 TETRAETHYLENEPENTAMINE Same label as DIETHYLENETRIAMINE THIONYL CHLORIDE Same label as SULFUR CHLORIDE TITANIUM TRICHLORIDE, ANHYDROUS DANGERI SOLID MAY IGNITE SPONTANEOUSLY IN AIR VAPOR CAUSES IRRITATION OF SKIN, EYES, NOSE, AND THROAT DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Keep away from heal, sparks, and open flame. Do not get in eyes, on skin, on clothing. Do not breathe vapor or dust. Keep container closed; open container carefully and only in dry oxygen-free or inert atmosphere. Wear rubber gloves and face shield or safety goggles. In case f contact, immediately remove from skin with dry cloth fol lowed by flushing with plenty of water for at least 15 minufes; for eyes, flush with plenty of water for'at least 15 minutes; get medical attention. Remove contaminated clothing and wash before re-use. O TOLUENE (TOLUOL) o WARNING! FLAMMABLE O VAPOR HARMFUL Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. MCA Chemical Safety Data Sheet 5D-63 available 90 TOLUIDINE ( rtho or m ta) DANGERI HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Use only with adequate ventilation. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. Wash clothing before re-use. MCA Chemical Safety Data Sheet SD-82 available TOLUIDINE (para)-Same label as NITROANILINE MCA Chemical Safety Data Sheet SD-82 available TOLYLENE DIISOCYANATE DANGERI HAZARDOUS LIQUID AND VAPOR CAUSES BURNS Keep container closed. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. MCA Chemical Safety Data Shaat SD-73 availabla TRICHLOROETHYLENE WARNINGI VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MCA Chamical Safely Data Shaat SD-14 availabla 91 TRIETHYLENETETRAMINE Sam label as DIETHYLENETRIAMINE TRIMETHYLAMINE, ANHYDROUSSam label as DIMETHYLAMINE, ANHYDROUS MCA Chemical Safety Data Shaat SD-57 available far METHYLAMINES rg VINYL ACETATE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. MCA Chemical Safety Data Shaat SD-75 available TRIMETHYLCYCLOHEXANOL Sam label as CYCLOHEXANOL VANADIUM TETRACHLORIDE DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR ABSORPTION THROUGH SKIN MAY BE FATAL CAUSES SEVERE BURNS MAY CONTAIN GAS UNDER PRESSURE DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Open container carefully and only in dry oxygen-free or inert atmosphere. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Q Do not take internally. Wear rubber gloves and face shield or safety goggles. In case of contact, immediately remove from skin with dry cloth fol lowed by flushing with plenty of water for at least 15 minutes; for eyes, flush with plenty of water for at least 15 minutes; get medical attention. Remove contaminated clothing and wash before re-use. POISON Call A Physician First Aid 92 VINYL CHLORIDE DANGERI EXTREMELY FLAMMABLE LIQUID AND GAS UNDER PRESSURE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. MCA Chemical Safety Data Sheet SD-56 available XYLENE (XYLOL) WARNINGI FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. XYLIDINES -- Same label as TOLUIDINE (ortho or meta) 93 040412 040413 ZINC CHLORIDE (Granular, Fused, or S luti n) WARNING! MAY CAUSE SEVERE SKIN IRRITATION Avoid contact with skin or eyes. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. ZIRCONIUM METAL POWDER (Minimum 25% Wafer) DANGER! FLAMMABLE SOLID MAY EXPLODE IF WATER CONTENT IS 10% OR BELOW Keep wet in storage--dry powder may be ignited by friction, static electricity, or heat. DO NOT ATTEMPT TO LOOSEN OR REMOVE MATERIAL FROM CON TAINER WITH ANY TOOL. Keep away from heat, sparks, and open flame. Keep from freezing. In case of spillage, keep wet and remove carefully. In case of fire, smother with foam-type fire extinguisher or sand. Do not use carbon tetrachloride, CO: extinguishers or water. Wear goggles or face shield and fire-retardant clothing when handling. 94 CHEMICAL SAFETY DATA SHEETS Acetaldehyde ..... ..... ....................................... ....... -................... ..................... --SD-43 Acetic Acid ................ SD-41 Acetic Anhydride ...... SD-15 Acetylene ...... --.................................--......... -.......................... ..........-..............- SD-7 Acrylonitrile --. ....................................... ................................................... _........ SD-31 Aluminum Chloride, Anhydrous ............. ...................................................... .. SD-62 Ammonia, Anhydrous .................................................................. ............................ SD-8 Ammonia, Aqua ................................................................ ............... ............ ........ SD 13 Ammonium Dichromate _.... --............................... .................--.... -..................... SD-4S Ammonium Hydroxide ................ SD-13 Aniline ...................................................................................... --.............. ............ SD-17 Antimony Trichloride, Anhydrous......................................... ..... ........ _................SD-66 Arsenic Trioxide .......... .............................................................................. ............ SD-60 Benzene ................................ -......... ............... -............ -....... ...... ................ --.... ..... SD-2 Benzoyl Peroxide ........................._......................................................... ................. SD-81 Benzyl Chloride .............................................................. ......... ..................................SD-69 Belanaphlhylamine ................................................................................ ........... ....... SD-32 Bromine ................................ .....-....... -...... .............................................................. SD-49 Butadiene .................................... ........................................... ..................... ........... SD-55 Butyraldehyde ............................................................. ................... --......................SD-78 Calcium Carbide --.................. SD-23 Carbon Disulfide ..... ...... .................. .................................................... ................SD-12 Carbon Tetrachloride ................................................ --............ ... ........... ............... SD-3 Caustic Potash (Potassium Hydroxide) ........ ..................... ..... ............... ...... ..... SD-10 Caustic Soda (Sodium Hydroxide) ........... ... ............. ......... ............. .... ............SD-9 Chlorine ...... SD-80 Chlorosulfonic Acid ................................... SD-33 Chromium Trioxide (Chromic Acid) ..................................... ........... --...... ..........SD-44 Cresol ....... -- .................................. ..... ...............................................---..................SD-4B Cyclohexane ................................. --.................. ........ -.................. .......................... SD-68 Dichlorobenzene (Ortho) ........................-................. -.................. ....... -............. SD-54 Diethylenetriamine .................................. - ..........................SD-76 Dimethyl Sulfate .............................................................................. SD-19 Ethyl Acetate .......................... SD-51 Ethyl Acrylate .................................................................................... *.......... ........ SI) 79 Ethyl Chloride ......................................................................................................... SI) 50 Ethyl Ether .................................... SD-29 Ethylene Dichloride ........................ SD-18 Ethylene Oxide ................................................................................. SD-38 Formaldehyde ................ .......................... ........................ SD-1 Hydrochloric Acid ................................................................................................. SD-39 Hydrocyanic Acid .......... SD-67 Hydrofluoric Acid, Anhydrous, Aqueous ............................... SD-25 Hydrogen Chloride, Anhydrous .................................................... ..................... -- SD-39 Hydrogen Peroxide................................................... .......................SD-53 Sup. A and B Hydrogen Sulfide .................... SD-36 Isopropylamine ........ SD-72 Continued Next Page 95 040414 CHEMICAL SAFETY DATA SHEETS (Continued from Page 95) Lead Oxides ............. ...................................................................... ............ ............. SD-64 Methanol ...... ....................... ....................................................... ..... .......... ....... ..... SD-22 Melhylamines ............................... SD-57 Methyl Acrylate ....................................................................................... SD-79 Methyl Bromide ........... SD-3S Methyl Chloride .......... ............ ............... ................. ................... .......................... SD-40 Methyl Ethyl Ketone ------------------------ ------ --------------- --------------- ------------------ SD-83 Mixed Acid ________________ __ __ ______________________ _________ ___ _ 5D 65 Naphthalene _____ ________ _________ ,,_______ _____ ___ __ _____ ____ _____ SD-58 Nitric Acid ___ _____ ___ __ ___________ _______ _______ ___ _____________ ___ SD-5 Nitrobenzene ______ ____ __________ ___________ ____________ ___ _______ ___ $D-21 Paraformaldehyde ........................... ......... ..... ......... .................. ........ ............... . SD-6 Perchloric Acid Solution_________ _______ _______ ______ ____ __ _______ ____SD-11 Perchloroethylene ..... SD-24 Phenol .................................. ............... ......................... ... .......... ..... ........................ SD*4 Phosphoric Acid ......... ........... ............. ......... ................. ....... ........... ......................SD-70 Phosphorus, Elemental ................ ................ ................................ ............ ............. SD-16 Phosphorus Oxychloride ................................................................... ........ ............. SD-26 Phosphorus Pentasulfide ............................................................................................SD-71 Phosphorus Pentoxide (Phosphoric Anhydride) ..................................... ........... SD-28 Phosphorus Trichloride ........... ....................... ............... ....... ........ ............. ........... SD-27 Phthalic Anhydride .......... .............. ..... ................... .............. ................... ............. SD-61 Potassium Dichromate ................... SD-46 Potassium Hydroxide (Caustic Potash) ________ _____ SD-10 Propylene ........... ..... ......... ........... .............................. ....... .............. ............ SD 59 Sodium Chlorate .................................. SD-42 Sodium Cyanide ......................................................................................................... SD-30 Sodium Dichromate ...................................................... SD-46 Sodium, Metallic ............................................................... ............. _____........ SD-47 Sodium Hydroxide (Caustic Soda) ............................... ................. ................ ...... SD-9 Styrene Monomer .............................. SD-37 Sulfur ................................................................................ .............. ...................... SI) 74 Sulfur Chlorides ......................................................................................................... SD-77 Sulfur Dioxide .................................................................................................... SD-52 O Sulfuric Acid ............................................................................................................. SD-20 Tetrachloroethane .......... SD-34 Toluene ......................... Tolylene Diisocyanate ....................................................................................... SD-63 SD-73 Toluidine ......... SD-82 Trichloroethylene ....................................................................................................... SD-I4 Vinyl Acetate ...............................................................................................................SD-75 Vinyl Chloride ....................................................................... SD-56 96 PART III Illustrative Labels for Pesticides This section contains suggested precautionary texts for a group of hazardous chemicals commonly used as, or in the formulation of, in secticides, fungicides, rodenticides, herbicides, nematocides, plant regu lators, defoliants, and desiccants. The term "Pesticid " is used in this Guide to indicate these products but the term "Economic P is n" is synonymous. Wording is based on the General Principles set forth in Part I. Careful study should be given to Part I and the special con siderations discussed below before any suggested wording is used for a pesticide. These labels have been selected for illustrative purposes only, and the listings do not purport to cover all pesticides for which precautionary labeling is necessary. Omission of a label for any par ticular product should not be interpreted to mean that such pr duct requires no precautionary label. The principles in Part I apply primarily to the labeling of hazardous chemicals intended for industrial consumption, some of which are also used as, or for processing into forms of, pesticides intended for home, farm, or other ultimate consumer use. Labels for such packages of pesticides require consideration of additional factors since they will be handled, stored, and used differently from those intended for indus trial consumption. Pesticide labels should include warnings not only of hazards to man, but also of hazards to domestic animals, useful inverte brates, and desirable vegetation. The usual legally-required ingredient statement may make unnecessary a separate showing of chemical identi fication of hazardous components on labels using code or nondescriptive names. A producer or distributor of a pesticide should be familiar with all pertinent laws,' regulations, and interpretations affecting these products, including those of the federal government, states, territories, and other political subdivisions; and with any applicable statutes, ordinances, or regulations affecting labeling in general. Statements suggested in Part III should be used in addition to, or in combination with, any other wording required by law. Each suggested precautionary text in this section applies to a commercial chemical or to an indicated concentration range of a chemi cal. Many pesticides are marketed in a variety of formulations contain ing different concentrations or combinations of their ingredients. Formulati ns f two or more constituents may have properties that 97 040415 vary in kind or degree from those f the constituents. In all cases, the precauti nary statements should be based on the properties of the finished formulation. it has not been practical to propose statements for all special pack ages, extraordinary uses, or other unusual circumstances surrounding individual products. Each statement is designed for the normal and customary use of a particular product when packaged for sale as a pesticide. Each labeler of a pesticide should recognize that his product must be treated individually, in the light of its own char* acteristics, including, among others, concentration and grade, pack age sizes and types, channels of distribution, normal storage and transportation conditions, intended consumers, and intended uses. The label statements in Part III are confined mainly to measures necessary to prevent injury to man and domestic animals arising out of the ordinary handling, storage, or use of a pesticide. Additional state ments may be indicated by the particular form or manner in which a product is sold or the circumstances surrounding its use. There also may be other hazards to man or animals which can arise only from specific uses for which directions are given in the labeling. Frequently a pesticide may also be hazardous to useful invertebrates or useful vegetation, or by reason of residues on edible vegetation. The omission of reference to any of these hazards from any text in Part HI does not imply that they may be disregarded. As a rule, such statements are properly incorporated in directions for use. By way of illustration, notes directed to the foregoing appear in connection with some of the illustrative labels. Even though they may be separated from the principal warnings, they should, nevertheless, be prominently displayed. Examples: Do not apply within................. days of harvest. Avoid use during flowering and pollination periods. Do not consume or market fruits or vegetables until residue is removed. Do not use this powder on drainboards, shelves or other places where contact with food is likely. Do not allow spray to come in contact with garden plants. For protection of fish and wildlife, avoid contamination of streams, lakes, or ponds. The Federal Insecticide, Fungicide, and Bodenticide Act and most state acts require the "POISON - skull and crossbones" legend and 98 an antidote on all "Economic Poisons" deemed "highly toxic to man". The definition of "Poison" in Part I of this Guide is similar to the definition of "highly toxic to man" in the regulations under the fed eral act. The products in this section have been classified according to the "highly toxic to man" definition. Other states, while not following the federal act on the definition of "highly toxic to man", require the "POISON - skull and crossbones" legend and antidote on all substances which are defined as "Poisons" in their poison laws. The term "Poison" has been commonly understood by the layman to mean toxic by oral intake only. The controlling criteria should con sider oral intake, inhalation, and skin absorption. To clarify the use of the term, labels on packages of pesticides "highly toxic to man" should specify the modes of entry into the body by which the product is poisonous. Examples: POISONOUS IF SWALLOWED POISONOUS BY SKIN CONTACT MAY BE POISONOUS IF INHALED POISONOUS IF SWALLOWED OR ABSORBED THROUGH SKIN It is not intended that the word "POISON" should take the place of a signal word. One of the signal words "DANGERI" or "WARNING!" will be applicable when a product is a "Poison". The selection of the appropriate word will depend not only on the degree of toxicity of the product, but more particularly on the risk of injury presented under normal conditions of handling or use. The word "POISON" (or its derivatives) should be reserved exclusively for those products coming within the definitions of the federal act as "highly toxic to man" except where it may be required by other laws or regulations. For products that are less toxic, statements like the following are preferred: MAY BE FATAL IF SWALLOWED HARMFUL IF INHALED OR SWALLOWED First aid in case of contact is given for a few products only. The Federal Insecticide, Fungicide, and Rodenticide Act and most state acts require a statement of an antidote on all "Econ mic Poisons" deemed "highly toxic to man". The term "antidote" is defined in the federal act as "a practical immediate treatment in case of poisoning and includes first aid treatment" and the regulations state that "the antidote statement shall include direction to call a physician immedi ately". Some state laws and regulations require, on labels, the use oi special or strictly defined antidotes or prescribe special ways in which these must be shown for certain chemicals. The requirements for any 99 040416 given pesticide may, therefore, vary greatly and the impossibility of showing, in the illustrative labels, antidotes which might be nationally acceptable has led to the practice of indicating only the need for an appropriate antidote statement where the "POISON-skull and crossbones" legend is used. Such information may be desirable on other products. Where "clothing" is mentioned in first aid instructions, it should be understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions because of special hazards arising from absorption of the chemical by leather. An important principle of good labeling is to avoid the indis criminate use of precautionary statements since this tends to detract from the importance which should be given to the vital warnings. Common sense indicates certain fundamental precautions in the handling of nearly all household and farm supplies and a label statement cannot substitute for it. Phrases such as "Avoid contamination of feed and foodstuffs." and "Do not take internally." should be necessary only where the inherently high toxicity of the product, special use of the material, size of the package, likelihood of mistaken identity, or actual use experience strongly indicates their need. 3-(alpha-ACETONYLFURFURYL)4-HYDROXYCOUMARIN and SODIUM SALT 1. Over 3.0%: WARNINGI If swallowed by humans, domestic animals, or pets, this material may reduce the clotting ability of the blood and cause bleeding. Q In such case, intravenous and oral administration of Vitamin K combined with blood transfusions are indicated as in the case of hemorrhage caused by overdoses of bishydroxycoumarin. Keep away from humans, domestic animals, and pets. POISON & (Antidote) SI#: Directions for lire should include a statement directing placement of baits so os to protect children, pets, and domestic animals. (continued on next page) 100 2. 3-(a!pha-ACETONYlFURFURYL)-4-HYDROXYCOUMARIN and SODIUM SALT (0.1% to 3.0% inch): CAUTIONI If swallowed by humans, domestic animals, or pets, this material may reduce the clotting ability of the blood and cause bleeding. In such case, intravenous and oral administration of Vitamin K combined with blood transfusions are indicated as in the case of hemorrhage caused by overdoses of bishydroxycoumarin. Keep away from humans, domestic animals, and pets. Not*: Directions lor Use should include a statement directing placement of baits so as to protect children, pets, and domestic animals. 3. Finished Baits: Directions for Use should include a statement directing placement of baits so as to protect children, pets, and domestic animals. ACRYLONITRILE DANGERI POISONOUS IF INHALED FLAMMABLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. Keep away from heat, sparks, and open flame. Keep container closed. Sr POISON (Antidote) Note: Directions for Use should include instructions for appropriate respiratory protection. 101 040417 ALDRIN 1. ALDRIN Technical and Formulations (60% and over): WARNING) POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist or powder. Wash thoroughly with soap and water after handling and before eating or smoking. Do not use indoors without adequate ventilation. Use clean clothing daily. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON & (Antidote) 2. Formulations (10% to 60%); WARNINGI HAZARDOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist or dust. Wash thoroughly with soap and water after handling and before eating or smoking. Use clean clothing daily. In case f contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. O Not*: Directions for Use should include instructions for appropriate respiratory protection and the use of clean synthetic rubber gloves during commercial or prolonged exposure in spray-mixing and loading operations. Labels should bear a statement relative to pro tection of persons and animals in treated and adjacent areas. (continued on next page) 102 3. ALDRIN Formulations (less than 10%): CAUTIONl HARMFUL BY SKIN CONTACT, INHALATION, OR SWALLOWING Avoid contact with skin and eyes. Avoid breathing spray mist or dust. Wash with soap and water after handling and before eating or smoking. Avoid contamination of feed and foodstuffs. Note: Directions for Use should include instructions for appropriate respiratory protection. Labels should bear a statement relative to protection of persons and animals in treated and adjacent areas. ALLYL ALCOHOL DANGER! EXTREMELY HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Do not breathe vapor. Do not take internally. Keep away from heat and open flame. Keep container closed. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON (Antidote) Not*: Directions for Use should include instructions for adequate ventilation or respiratory protection, as well as the use of neoprene gloves and goggles, when product is being handled. If product exhibits Tag. Open-Cup flash point of 80F. or less, appropriate flammability statements must be added. ANTIMONY POTASSIUM TARTRATE (TARTAR EMETIC) WARNINGI MAY BE FATAL IF SWALLOWED Avoid breathing dust. Wash thoroughly after handling. 103 040418 ARSENICAL WEED KILLERS, INORGANIC 1. 2% and over at Metallic Arsenic: WARNINGI POISONOUS IF SWALLOWED Avoid contact with skin, eyes, and clothing. Do not breathe spray mist; wear respirator. In case of contact, wash thoroughly. POISON (Antidote) 2. Less than 2% as Metallic Arsenic: WARNINGI MAY BE FATAL IF SWALLOWED Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist. Keep away from food and out of reach of children and domestic animals. In case of contact, wash thoroughly. Note: Direction, for Ue should include reference to the avoidance of spray drift to vplu able plant* and restriction of person, and animals from treated areas. BENZENE HEXACHLORIDE (See LINDANE also) 1. BENZENE HEXACHLORIDE Technical and Dry Formulations (25% and over): WARNINGI HARMFUL IF SWALLOWED n MAY CAUSE IRRITATION OF SKIN AND EYES MAY BE ABSORBED THROUGH SKIN Avoid breathing dust, vapor, or spray mist. Avoid contact with skin and eyes. Avoid contamination of feed and foodstuffs. In case of contact, wash skin with plenty of soap and water; for eyes, flush with water and get medical attention. Note; If the product is to be applied to plants that are used as food, a warning should be included in the Directions for Use to the effect that the material should not be applied where there is danger of residual odor or taste remaining in foodstuffs or edible portions of treated crops. (continued on next page) 104 2. BENZENE HEXACHLORIDE Dry Formulations (less than 25%): CAUTION! Avoid breathing dust, vapor, or spray mist. Avoid contact with skin and eyes. Avoid contamination of feed and foodstuffs. Wash thoroughly after handling. 3e Solutions or Emulsifiable Formulations: $inc various solvents which differ in toxic properties may b* used, labels should bear the precautionary information covering the combined hazards of benzene hexachloride and solvent. Note: If the product is to be applied to plants that are used os food, a warning should be Included in the Directions for Use to the effect that the material should not be applied where there is danger of residual odor or taste remaining in foodstuffs or edible portions of treated crops. CADMIUM SALTS Toxicity varies with the different products; hence, each product must be considered on its own properties. CALCIUM ARSENATE WARNINGI POISONOUS IF SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Clean up spillage. POISON ^ (Antidote) 105 040419 CALCIUM CYANIDE DANGERI POISONOUS SOLID LIBERATES POISONOUS GAS Do not take internally. Do not breathe gas or dust. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. Keep c ntainer tightly closed and away from water or acids. Clean up spillage immediately. Keep away from feed or food products. In case of contact, immediately flush skin or eyes with plenty of water f r at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before re-use. POISON (Antidote) Note; Directions lor Indoor Use should include instructions lor appropriate respiratory protection. CAPTAN CAUTIONI Avoid breathing dust or spray mist. Avoid prolonged or repeated contact with skin. Avoid contamination of feed and foodstuffs. 106 2-CARBOMETHOXY-l -METHYLVINYL DIMETHYLPHOSPHATE and BETA ISOMER 1. Technical Material and Formulations (over 2%); DANGERI POISONOUS BY SWALLOWING, INHALATION, OR SKIN CONTACT RAPIDLY ABSORBED THROUGH SKIN REPEATED EXPOSURE MAY, WITHOUT SYMPTOMS, PROGRESSIVELY INCREASE SUSCEPTIBILITY TO POISONING BY THIS PRODUCT Do not swallow or get in eyes, on skin, on clothing. Wear clean heavy rubber gloves and goggles. Wear clean water proof or freshly-laundered protective clothing (coveralls, cops, etc.). Replace gloves frequently and destroy used gloves. Wash thoroughly with soap and water after handling and before eating or smoking. Bathe immediately after work and change all clothing. In case of contact, immediately remove all contaminated clothing and wash skin with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Wash clothing before re-use. Do not breathe dust, vapor, or spray mist. Wear a mask or respirator of a type passed by U. $. Department of Agriculture for protection against this product. Do not contaminate food or feed products. Keep out of the reach of children and domestic animals. In case of spillage, wash down with large amounts of water. Decontaminate areas and equipment by washing with a strong lye solution. Empty containers are to be destroyed by burning or burying; never re-use. Stay out of smoke when burning containers. POISON First Aid Net*; For technical material and manufacturing concentrations add after statements of haiard: BEFORE USING, CONSULT MANUFACTURER FOR SAFE HANDLING INSTRUC TIONS. (continued on next page) 107 2. 2-CARBOMETHOXY-l -METHYLVINYL DIMETHYLPHOSPHATE and BETA ISOMER Formulations (2% or less): WARNINGI POISONOUS BY SWALLOWING, INHALATION, OR SKIN CONTACT RAPIDLY ABSORBED THROUGH SKIN Do not swallow or get in eyes or on skin. Wear clean rubber gloves, protective clothing, and goggles. Replace gloves frequently and destroy used gloves. Wash thoroughly with soap and water after handling and before eating or smoking. In case of contact, immediately remove all contaminated clothing and wash skin with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Do not breathe dust, vapor or spray mist. Wear a mask or respirator of a type passed by U. S. Department of Agriculture for protection against this product. D n t contaminate food or feed products. Keep out of reach of children and domestic animals. Empty containers are to be destroyed by burning or burying. Stay out of smoke when burning containers. POISON First Aid Noli: Labels should bear a statement relative to the protection of persons and animals in treated and adjacent areas. n (continued on next page) 040420 108 2-CARBOMETHOXY-1 -METHLYVINYL DIMETHYLPHOSPHATE and BETA ISOMER FIRST AID ATROPINE IS THE EMERGENCY ANTIDOTE FOR POISONING BY THIS PRODUCT Consult physician about obtaining an adequate supply of 1/100 grain atropine tablets for emergency use. CALL A PHYSICIAN IN ALL CASES OF SUSPECTED POISONING Internal: If swallowed, induce vomiting by introducing finger down throat or by giving 1 tablespoonful of salt in a glass of warm water. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON External: If spilled on skin, immediately move patient from vicinity of the insecticide, remove all contaminated clothing, and wash skin with soap and running water. If material gets into eyes, wash immediately with running water for at least 15 minutes. If warning symptoms appear: Administer two 1/100 grain atropine tablets immediately. NEVER ADMINISTER ATROPINE UNLESS WARNING SYMPTOMS APPEAR Keep patient prone and quiet. Start artificial respiration immediately if patient is not breathing. Transport the patient immediately to the nearest physician. Note to Physician: This product is a cholinesterase inhibitor. Warn ing symptoms include weakness, headache, tightness in chest, blurred vision, un-reactive pinpoint pupils, salivation, sweating, nausea, vomiting, diarrhea, and abdominal cramps. Treatment: Atropine is the specific therapeutic antagonist of choice against the parasympathetic nervous stimulation. If there are signs of parasympathetic stimulation, atropine sulfate should be injected at 10 minute intervals, in doses of 1 to 2 milligrams, until complete atropinizolion has occurred. Morphine is contraindi cated. Clear chest by postural drainage. Oxygen administration may be necessary. Observe patient continuously for 48 hours. Repeated exposure to cholinesterase inhibitors may, without warn ing, cause prolonged susceptibility to very small doses of any cholinesterase inhibitor. Allow no further exposure until time for cholinesterase regeneration has been allowed as determined by blood test. 109 040421 CARBON DISULFIDE DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE Keep away from fire, sparks, or heated surfaces. Store in co I place and keep container closed. Avoid breathing vapor. Avoid contact with skin and eyes. POISON .* (Antidote) Not*: Direction* for Ui* should inclod* instructions for adequate ventilation or respiratory protection when product is being handled. CARBON TETRACHLORIDE DANGERI HAZARDOUS VAPOR AND LIQUID MAY BE FATAL IF INHALED OR SWALLOWED Do not breathe vapor. Avoid prolonged or repeated contact with skin. Do not take internally. POISON (Antidote) Note: Directions for Use should include instructions for adequate ventilation or respiratory protection when product is being handled. Q CHLORANIL CAUTIONI Avoid breathing dust. Avoid contact with skin. no CHLORDANE 1. CHLORDANE Technical and Dry Formulations (25% and ver): CAUTIONI HARMFUL IF SWALLOWED ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Avoid breathing dust or spray mist. Avoid contamination of feed and foodstuffs. In case of contact, wash with soap and water. 2. Dry Formulations (less than 25%): CAUTIONI Avoid breathing dust. Avoid contamination of feed and foodstuffs. 3. Solutions or Emulsifiable Formulations: Since various solvents which differ in toxic properties may be used, labels should bear precautionary information covering the combined hazards of chlordane and solvent. Note: Directions for Use should include appropriate additional instructions for aerosol products or those intended to be used on animals. Special labeling for various house* hold preparations is required federally and in some states. 2-CHLOROALLYL DIETHYLDITHIOCARBAMATE 1. Dry Formulations (granular): WARNINGI MAY CAUSE EYE INJURY AND SKIN IRRITATION Do not get in eyes, on skin, on clothing. Avoid breathing dust. Do not take internally. Avoid contamination of feed and foodstuffs. In case of contact with dust, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. 2. Emulsifiable Formulations: Since various solvenfs which differ in toxic properties may be used, labels should bear precautionary information covering the combined hazards of this product ond solvent. ill alpha-CHLORO-N,N-DIALLYLACETAMIDESame labels as 2-CHLOROALLYL DIETHYLDITHIOCARBAMATE CHLOROFORM WARNINGI VAPOR HARMFUL MAY BE FATAL IF SWALLOWED Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Not*: Direction* for Uw thould include imtructioni for adequate ventilation or reipiratory protection when product I* being handled. CHLORO-IPC (iso-PROPYL-N-[3-CHLOROPHENYL] CARBAMATE) CAUTIONI HARMFUL IF SWALLOWED CHLOROPHENOL (MONOCHLOROPHENOL) Same label as CRESOL n O tf* O bO to 112 1,1 -bis(CHLOROPHENYL)-2,2,2-TRICHLOROETHANOL 1. Dry Formulations (over I0%): CAUTIONI Avoid repeated skin contact. Avoid breathing dust or spray mist. Do not take internally. Avoid contamination of feed and foodstuffs. Wash thoroughly after handling. 2. Dry Formulations (10% or less): CAUTIONI Avoid breathing dust. Avoid contamination of feed and foodstuffs. 3. Emulsifiable Formulations: Since variou* lolvents which differ in toxic properties may be used, labels should bear precautionary information covering combined hazards of this product and solvent. CHLOROPICRIN DANGERI POISONOUS IF INHALED Do not breathe vapor. I Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove a and wash clothing before re use. POISON ^ a (Antidote) Nolo: Directions for Use should include instructions for appropriate respiratory protection. f I 113 II COAL TAR CREOSOTE CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repealed contact with skin. Avoid prolonged breathing of vapor. Use with adequate ventilation. COPPER COMPOUNDS (10% and over as M tallic Copper) CAUTIONI HARMFUL IF SWALLOWED CRESOL (CRESYLIC ACID) DANGERI MAY BE FATAL BY SKIN CONTACT OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Da not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately remove all contaminated clothing, in cluding shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. n o o to OJ CYANIDES, INORGANIC (Excluding HYDROCYANIC ACID and CALCIUM CYANIDE) (NAME Of PRODUCT) DANGERI POISONOUS SOLID CONTACT WITH ACID LIBERATES POISONOUS GAS Do not breathe gas or dust. Do not take internally. Avoid contact with eyes and skin. Wash thoroughly after handling. Keep container closed and away from acids. Store in a dry place. Keep away from feed and foodstuffs. In case of contact with eyes, flush with plenty of water for at least 15 minutes and get medical attention. POISON (Antidote) Nat*; Direction! for indoor use should Include instructions for appropriate respiratory protection. CYANO(METHYLMERCURI)GUANIDINE (METHYL MERCURY DICYANDIAMIDE) Same labels as ETHYL MERCURY CHLORIDE Q 0 I 114 115 040424 2,4-D (2,4-DICHLOROPHENOXYACETIC ACID and Derivatives) 1. 2,4-0 ACID and Dry Formulations (10% and over): WARNINGI IRRITATING TO EYES, NOSE, AND THROAT Do not get in eyes. Avoid contact with skin. Avoid breathing dust. In case of contact with eyes, flush with plenty of water for at least 15 minutes and get medical attention. 2. SODIUM SALT (2,4-D Acid Equivalent 20% and over): CAUTIONI IRRITATING DUST Av id breathing dust. Avoid contact with skin and eyes. 3. Liquid Formulations of 2,4-D ESTERS: CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with eyes, skin, and clothing. 4. Liquid Formulations of 2,4-D AMINES: WARNINGI CAUSES IRRITATION OF EYES AND SKIN Do not get in eyes. Avoid contact with skin and clothing. In case of contact, flush eyes with plenty of water for at least 15 minutes and get medical attention; wash skin with plenty of soap and water. q Not*. All weed killer preparations containing 2,4-D or its derivatives ihould, when appro priate. carry adequate warning statements regarding dangers of vapor, spray or dust drift to desirable plants, the necessity of using other equipment for handling and apply ing other agricultural chemicals, and avoiding contamination of domestic or irrigation water supply. 116 DALAPON, SODIUM SALT CAUTIONI CAUSES SKIN IRRITATION Avoid contact with skin, eyes, and clothing. In case of contact, remove contaminated clothing and wash skin with plenty of soap and water,- for eyes, flush with water for 15 minutes and get medical attention. Wash clothing before re-use. DDD (D1CHLORODIPHENYL DICHLOROETHANE) Same labels as DDT DDT (DICHLORODIPHENYL TRICHLOROETHANE) 1. DDT Technical: CAUTIONI HARMFUL IF SWALLOWED ABSORBED THROUGH SKIN WHEN IN SOLUTION Avoid breathing dust or spray mist. Avoid contamination of feed and foodstuffs. 2. Dry Formulations (over 25%); CAUTIONI HARMFUL IF SWALLOWED Avoid breathing dust or spray mist. Avoid contamination of feed and foodstuffs. 3. Dry Formulations (25% or less): CAUTIONI Avoid breathing dust. Avoid contamination of feed and foodstuffs. 4. Solutions or Emulsifiable Formulations: Since various solvents which differ in toxic properties may be vied, labeli ihould bear precautionary information covering the combined hoxords of DDT and lofvent. Note: If the preparation contain, other hoxardooi ingredients, appropriate additional cau tions must be added to the foregoing. Directions for Use should include appropriate addi tional instructions for aerosol products or for products intended to be used on animals. 117 040425 1,2-DIBROMO-3-CHLOROPROPANE 1. Technical Product: WARNINGI HARMFUL. LIQUID AND VAPOR MAY BURN SKIN AND EYES CAUSES IRRITATION OF NOSE AND THROAT MAY BE ABSORBED THROUGH SKIN D not breathe vapor. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Do not take internally. In case of contact, immediately remove contaminated clothing, in cluding shoes, and wash skin with soap and water; flush eyes with plenty of water for at least 15 minutes and get medical attention. Wash clothing and air shoes thoroughly before re-use. Store away from domestic animals and dwellings and out of the reach of children. 2. Dry Formulations (20% and over): WARNINGI HARMFUL DUST AND VAPOR MAY BURN SKIN AND EYES CAUSES IRRITATION OF NOSE AND THROAT MAY BE ABSORBED THROUGH SKIN In addition to abovo StatoiiMOts. also include balanco of precautionary label recommended for Technical Product. 3. Dry Formulations (less than 20%); CAUTIONI MAY CAUSE IRRITATION OF SKIN, EYES, NOSE, AND THROAT Avoid contact with skin, eyes, and clothing. Avoid prolonged breathing of vapors or dust. Do not lake internally. Q Wash thoroughly with soap and water after handling and before eating or smoking. Keep out of the reach of children and domestic animals. 4. Solutions and EmulsiFiable Formulations: Sine* various solvents which differ in toxic properties may be used, labels should bear precautionary information covering the combined hazards of this product and solvent. 118 DICHLONE CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin, eyes, and clothing. Wash hands and face thoroughly with soap and water after handling. Store away from feed and foodstuffs. DICHLOROETHYL ETHER DANGERI MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN Do not get on skin or clothing. Do not breathe vapor. Do not take internally. In case of contact, immediately remove contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes. Wash clothing before re-use. * POISON * (Antidote) Not*: Directions for Use should include instructions for adequate ventilation or respiratory protection when product is being handled. 119 92^0^0 DICHLOROPROPENE - DICHLOROPROPANE MIXTURE WARNINGI HAZARDOUS LIQUID AND VAPOR MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN CAUSES BURNS TO SKIN AND EYES Do not get in eyes, on skin, on clothing. Wear goggles and poly ethylene gloves when handling. Do not breathe vapor. Use only with adequate ventilation. Keep away from heat and open flame. Keep container dosed. Keep out of reach of children. Do not contaminate feed and foodstuffs. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin thoroughly with soap and water; for eyes, flush with water for at least IS minutes and get medical attention. Wash clothing and air shoes thoroughly before re-use. Note: Directions for Use should include instructions for respiratory protection when the product is being handled in enclosed areas. DIELDRIN -- Same labels as ALDRIN 120 DIETHYL DIPHENYL DICHLOROETHANE (1,1 -DICHLORO-2,2>bis [ p-ETHYLPHENYL ] ETHANE) 1. Technical Product: CAUTIONI ABSORBED THROUGH SKIN WHEN IN SOLUTION In case of skin contact, wash with soap and water. Avoid breathing dust. 2. Dusts and Wettable Powders: CAUTIONI Avoid prolonged breathing of dust or spray mist. 3. Solutions and Emulsifiable Formulations: Sine* various rolvents which differ In tonic properties may bo used, labels should boar precautionary information covering the combined hazards of diethyl diphenyl dichloroethane and solvent. DINITRO-ortho-CRESOL DANGERl POISONOUS BY SWALLOWING OR SKIN CONTACT ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Avoid breathing vapor, dust, or spray mist. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with plenty of soap and water; for eyes, flush with water for at least IS minutes and get medical attention. Wash clothing before re-use. POISON (Antidote) DODINE (DODECYLGUANIDINE ACETATE) Technical Product and Dry Formulations (over 50%): CAUTIONI CAUSES EYE IRRITATION In case of c ntact with eyes, flush with plenty of water for at least 15 minutes and get medical attention. 121 040427 ENDRIN 1. ENDRIN Technical and Formulations (2.5% and over): DAN ERI POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. D not breathe spray mist or powder. Wash thoroughly with soap and water after handling and before eating or smoking. Clean up spillage. Do not use indoors without adequate ventilation. Use clean clothing daily. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. JL POISON A. (Antidote) 2. Formulations (/ess than 2.5%): WARNING! HAZARDOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist or dust. Wash thoroughly with soap and water after handling and before eat ing or smoking. Use clean clothing daily. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Not*: Direction* for Uie should include instruction* for appropriate respiratory protection and the use of dean synthetic rubber gloves during commercial or prolonged exposure in spray-mixing and loading operations. Labels should bear a statement relative to the protection of persons and animals in treated and adjacent areas. 122 ETHYL BROMIDE WARNINGI VAPOR HARMFUL Avoid prolonged breathing of vapor. Keep container closed, out of sun, and away from heat. Not*: Direction, for Uu should include instruction! for adequate ventilation or reipiratery protection when the product ii being handled. ETHYL MERCURY ACETATESame labels as ETHYL MERCURY CHLORIDE ETHYL MERCURY CHLORIDE 1. Dry Formulations (any effective concentration): DANGERI POISONOUS BY INHALATION OR SWALLOWING MAY CAUSE SKIN IRRITATION OR DELAYED CHEMICAL BURNS Do not get in eyes, on skin, on clothing. Do not breathe vapor, dust, or spray mist. In case of contact, immediately wash skin with plenty of soap and water; for eyes, flush with water for at least 15 minutes and get medical attention. If burning or blistering of skin results, get medical attention. Use clean clothing daily. 2. Solutions: POISON (Antidote) The above label may require additional Statements of Hazards for solutions since in this form the chemical may be absorbed through the skin and thus be poisonous by skin contact. Note; For certain applications, Directions for Use moy need to include more detailed in structions for safe handling of this product and materials treated with it. 123 ETHYL MERCURY PHOSPHATESam labels as ETHYL MERCURY CHLORIDE ETHYL MERCURY para-TOLUENE SULFONANILIDE Sam labels as ETHYL MERCURY CHLORIDE ETHYLENE DIBROMIDE WARNINGI HARMFUL LIQUID AND VAPOR CAUSES SKIN IRRITATION, AND BURNS ON PROLONGED CONTACT ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin with soap and plenty of water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Wash clothing and air shoes thoroughly before re-use. Not*: Directions for Use should include instructions for adequate ventilation or respiratory protection when the product it being handled. Since mixtures with hydrocarbon- or halogenated hydrocarbon-type solvents may be more hazardous* even "highly toxic", labels should bear precautionary information covering the hazards of the mixture. n ETHYLENE DICHLORIDE ^ WARNIN I FLAMMABLE oit1 VAPOR HARMFUL 4^ Keep away from heat, sparks, and open flame. ^ Keep container closed. Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. Not*: Direction* for Utt should include instruction* for adequate ventilation or respiratory protection when the product is being handled. 124 FERBAM (any ffectiv concentration) CAUTION! MAY CAUSE IRRITATION OF EYES, NOSE, THROAT, AND SKIN Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. *Keep away from fire or sparks. -For dust mixtures 50% and over, and for lower concentrations if diluent is combustible. FORMALDEHYDE SOLUTIONS (5% and over) WARNINGI CAUSES IRRITATION OF SKIN, EYES, NOSE, AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attenti n. POISON (Antidote) HEPTACHLOR WARNINGI MAY BE FATAL IF SWALLOWED Avoid breathing vapor, dust, or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, wash promptly with plenty of soap and water. Avoid contamination of feed and foodstuffs. 125 040429 HEXAETHYL TETRAPHOSPHATE Sam lab I as TETRAETHYL PYROPHOSPHATE HYDROCYANIC ACID DANGERI EXTREMELY HAZARDOUS LIQUID AND GAS EXTREMELY FLAMMABLE MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN USE ONLY IN A CLOSED SYSTEM. Keep away from heat, sparks, and open flame. Do not take internally. Do not breathe gas. Do not get in eyes, on skin, on clothing. in case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before re-use. A?A- POISON (Antidote) Not#: Direction* for Um should include instruction* for appropriate respiratory protection. HYDROXYMERCURICHLOROPHENOL (any Hective concentration) Q WARNING! POISONOUS IF INHALED OR SWALLOWED MAY CAUSE SKIN IRRITATION Avoid breathing dust. Avoid contact with skin, eyes, and clothing. In case of contact, immediately wash skin with plenty of soap and water; for eyes, flush with water for at least 15 minutes and get medical attention. POISON .$* (Antidote) Note: For certain applications. Directions for Use may need to include more detailed in* structions lor safe handling of this product and materials treated with it. 126 HYDROXYMERCURICRESOL Same label as HYDROXYMERCURICHLOROPHENOL HYDROXYMERCURINITROPHENOL Same label as HYDROXYMERCURICHLOROPHENOL HYPOCHLORITES Becaui* of the differences in properties of members of this group, each product containing them must be reviewed individually in light of its own characteristics. IPC (iso-PROPYLPHENYLCARBAMATE) Same label as CHLORO-IPC LEAD ARSENATE WARNINGI POISONOUS IF SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Clean up spillage. POISON (Antidote) 127 040430 LINDANE (See BENZENE HEXACHLORIDE als ) 1. LINDANE and Dry Formulations (25% and over): WARNINGI MAY BE FATAL IF SWALLOWED MAY BE ABSORBED THROUGH SKIN Avoid breathing dust, vapor, or spray mist. Avoid contact with skin and eyes. Avoid contamination of feed and foodstuffs. In case of contact, wash skin with plenty of soap and water; for eyes, flush with water and get medical attention. 2. Dry Formulations (less than 25%): Same label at BENZENE HEXACHLORIDE--Dry Formulations (less than 25%). 3. Solutions or Emulsifiable Formulations: See BENZENE HEXACHLORIDE MAGNESIUM ARSENATESam label as CALCIUM ARSENATE n 128 MALATHION 1. MALATHION Technical and Dry Formulations (over 50%): CAUTIONI HARMFUL IF SWALLOWED OR INHALED Avoid breathing vapor or dust. Avoid repeated or prolonged contact with skin. Wash thoroughly after handling. Wash contaminated clothing before re-use. 2. Dry Formulations (over 10% to 50% incl.): CAUTIONI MAY BE HARMFUL IF SWALLOWED Avoid prolonged breathing of spray mist or dust. Avoid repeated or prolonged contact with skin. Wash thoroughly after handling. Avoid contamination of feed and foodstuffs. Keep out of reach of children. 3. Emulsifiable Formulations: Sine* various solvunts which ditsr in toxic properties may bo used, emulsifiable liquid labels should bear precautionary information covering the combined haiards of malathion and solvent. 4. Dusts (10% or less): CAUTIONI Avoid prolonged breathing of dust. Avoid repeated or prolonged contact with skin. Wash thoroughly after handling. Avoid contamination of feed and foodstuffs. Keep out of reach of children. MALEIC HYDRAZIDE, DIETHANOLAMINE SALT CAUTIONI MAY BE HARMFUL IF SWALLOWED Avoid breathing spray mist. Avoid contact with skin, eyes, and clothing. 129 MANEB (any eff ctive concentration) -- Sam label as ZINEB MCP (2-METHYL-4-CHLOROPHENOXYACETIC ACID and Derivatives) -- Sam labels as 2,4-D METHYL BROMIDE DANGER! VAPOR EXTREMELY HAZARDOUS HIGHLY VOLATILE CAUSES BURNS Do not breathe vapor. Do not get in eyes, on skin, on clothing. Keep away from heat. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin thoroughly with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Do not re-use shoes or clothing until free from all contamination. &POISON (Antidote) IMPORTANTI The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment is available. n Contact MANU"cw*lVfor information on equipment and proper use. O 4* O Nat*: Direction* far U*e should include Instruction* for adequate ventilation or respiratory U) protection when the product is being handled. H 130 METHYL PARATHION - Sam lab Is as PARATHION METHYLENE CHLORIDE CAUTIONI Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MONOCHLOROPHENOL - Same label as CRESOL NABAM SOLUTIONS (19% and over) CAUTIONI MAY CAUSE SKIN IRRITATION MAY BE HARMFUL IF SWALLOWED Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. 1-NAPHTHYL N-METHYLCARBAMATE CAUTIONI HARMFUL IF SWALLOWED OR INHALED Do not take internally. Avoid breathing dust. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling. Wash contaminated clothing before re-use. Avoid contamination of feed and foodstuffs. 131 04043 NICOTINE SULFATE SOLUTION (40% NICOTINE) DANGERI POISONOUS IF SWALLOWED ABSORPTION THROUGH SKIN HARMFUL Do not gel in eye*, on tkin, on clothing. Wear protective clothing and goggles when handling. Do not breathe spray mist; wear respirator. Store away from food and out of reach of children and domestic animals. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. . POISON (Antidote) NICOTINE DUSTS (5% or less) CAUTIONI HARMFUL IF INHALED OR SWALLOWED Avoid exposure to dust. Avoid contact with skin and eyes. Wash thoroughly after handling. Store away from feed and foodstuffs. Not*: The pi(ctnta|i and form of nicotian prmont may call for poilon labeling under the rquirem*nti of various state taws. OVEX (p-CHLOROPHENYL p-CHLOROBENZENEg SULFONATE) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin. Avoid breathing dust or spray mist. KJ 132 PARATHION 1. PARATHION Technical: DANGERI POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN REPEATED EXPOSURE MAY, WITHOUT SYMPTOMS, BE INCREASINGLY HAZARDOUS BEFORE USING, CONSULT MANUFACTURER FOR SAFE HANDLING INSTRUCTIONS. Do not get on skin, in eyes, on clothing. Wear clean heavy rubber gloves and goggles. Wear clean water proof or freshly-laundered protective clothing (coveralls, rubber boots, cap, etc.). Destroy and replace gloves frequently. Bathe immediately after work and change all clothing. Wash clothing thoroughly with soap and hot water before re-use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water; for eyes, flush with water for 15 minutes. Do not breathe vapor or dust. Wear respirator or mask effective for parathion protection. In case of spillage, cover with an absorbent such as soda ash, lime, clay or sawdust. Sweep up and bury. Wash area thoroughly with strong lye solution. POISON First Aid (continued on next page) 133 2. PARATHION Wettable P wders and Ousts (25% r less): DANGER! POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN REPEATED EXPOSURE MAY, WITHOUT SYMPTOMS, BE INCREASINGLY HAZARDOUS Do not get on skin, on clothing. Wear clean heavy rubber gloves and clean waterproof or freshlylaundered protective clothing (coveralls, cap, etc.). Destroy and replace gloves frequently. Wash thoroughly with soap and warm water before eating or smoking. Bathe immediately after work and change all clothing. Wash clothing thoroughly with soap and hot water before re-use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water. Do not breathe dust, vapor, or spray mist. Wear mask or respirator of a type passed by the U. S. Depart ment of Agriculture for parathion protection. Airplane pilots should wear full-face canister-type mask. If handled indoors, provide mechanical exhaust ventilation. Do not store near food or feed products. q Keep out of reach of children and domestic animals. Bury spillage; clean up area with strong lye solution. Burn or bury containers; never re-use. Stay out of smoke when burning containers. POISON First Aid 040433 3. Solutions or Emulsifiable Formulations; Since various solvents which differ in toxic properties may be used, labels should bear precautionary information covering the combined hazards of parathion and solvent. Note: labels should bear a statement relative to the protection of persons and animals in treated and adjacent areas. 134 (continued on next page) PARATHION FIRST AID ATROPINE IS AN ANTIDOTE--CONSULT PHYSICIAN FOR EMERGENCY SUPPLY CALL A PHYSICIAN AT ONCE IN ALL CASES OF SUSPECTED PARATHION POISONING If symptoms or signs of poisoning include blurred vision, abdominal cramps, and tightness in the chest, do not wait fra doctor but give two atropine tablets (each 1/100 gr.) at once. Move patient immediately from the area where parathion is present. Remove contaminated clothing and wash the skin clean with plenty of soap and water to remove all traces of parathion. If swallowed, induce vomiting by giving salty or soapy warm water. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON Physician's Note: This product is a cholinesterase inhibitor. Warn ing symptoms include weakness, headache, tightness in the chest, blurred vision, non-reactive pin-point pupils, salivation, sweating, nausea, vomiting, diarrhea, and abdominal cramps. Treatment: Give atropine, preferably by injection, grains 1/100 three or more tablets at once and parenterally or orally every hour until pupils dilate. Thirty or more tablets may be required in 24 hours. Never give morphine. Clear chest by postural drainage. Artificial respiration or oxygen administration may be necessary. Observe patient continuously 48 hours. Repeated exposure to cholinesterase inhibitors may, without warning, cause prolonged susceptibility to very small doses of any cholinesterase inhibitor. Allow no further exposure until time for cholinesterase regenera tion has been allowed as determined by blood tests. PARIS GREENSame label as CALCIUM ARSENATE 135 040434 PENTACHLORONITROBENZENE 1. PENTACHLORONITROBENZENE Technical and Dust Formulations: CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of dust. Wash thoroughly after handling. 2. Wettable Powders: CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of dust or spray mist. Wash thoroughly after handling. 3. Liquid Formulations: Since vorloul solvents which differ In toxic properties may be used, label* ihould bear precautionary information covering the combined haxardt of pentachloronitroben. tint and lolvent. PENTACHLOROPHENOL 1. PENTACHLOROPHENOL Technical: WARNINGI HARMFUL DUST Avoid breathing dust. Avoid contact with skin, eyes, and clothing. Do not take internally. q In case of contact with dry material or its solution, immediately wash skin with soap and plenty of water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. (continued an n*xt pagt) 136 2. PENTACHLOROPHENOL Oil S lotions: WARNINGI CAUSES SKIN IRRITATION ABSORPTION THROUGH SKIN HARMFUL Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. Do not take internally. In case of contact, immediately wash skin with soap and plenty of warm water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. PHENOL (CARBOLIC ACID) DANGER! MAY BE FATAL BY SKIN CONTACT OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. g?POISON (Antidote) PHENOTHIAZINE CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. In case of contact, wash skin with soap and plenty of water; for eyes, flush with water and get medical attention. 137 PHENYL MERCURY ACETATE 1. Dry Formulations: Same label at HYDROXYMERCURICHLOROPHENOL 2. Solutions: Same labels as PHENYL MERCURY OLEATE PHENYL MERCURY OLEATE (Oil Solutions or Oil-Water Emulsions) 1. 1.0% and over: DANGERI POISONOUS BY SWALLOWING OR SKIN CONTACT MAY CAUSE SKIN IRRITATION OR DELAYED CHEMICAL BURNS ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Do not breathe spray mist. In case of contact, immediately remove all contaminated clothing and flush skin or eye* with plenty of water for at least 15 minutes; for eyes, get medical attention. If burning or blistering of skin results, get medical attention. Wash' clothing before re-use. g?POISON (Antidote) Not*: For certain applications. Directions for Use may need to include more detailed in structions for safe handling of this product and materials treated with it. Q (continued on next page) 2. PHENYL MERCURY OLEATE (Less than 1.0% and over 0.1 %): WARNINGI POISONOUS IF SWALLOWED MAY CAUSE SKIN IRRITATION OR DELAYED CHEMICAL BURNS Avoid contact with skin, eyes and clothing. Avoid breathing spray mist. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. If burning or blistering of skin results, get medical attention. Wash clothing before re-use. g*POISON (Antidote) 3. 0.1% or less: CAUTION! HARMFUL IF SWALLOWED MAY CAUSE SKIN IRRITATION OR DELAYED CHEMICAL BURNS Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist. In case of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. If burning or blistering of skin results, get medical attention. Nolo: For certain application!. Direction! for Uie may need to include more detailed initroctioni for af handling of this product and maloriolt trootod with it. 040435 138 139 0 4 0436 PHORATE (O,0-DIETHYL-S-ETHYLTHIOMETHYLPHOSPHORODITHIOATE) (any effective concentration) DANGERI POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN REPEATED INHALATION OR SKIN CONTACT MAY, WITHOUT SYMPTOMS, PROGRESSIVELY INCREASE SUSCEPTIBILITY TO PHORATE POISONING D not get on sltlti, In eyes, on clothing. Wear clean heavy rubber gloves and goggles. Wear clean water proof or freshly-laundered protective clothing (coveralls, cap, etc.). Destroy and replace gloves frequently. Wash thoroughly with soap and warm water before eating or smoking. Bathe immediately after work and change all clothing. Wash clothing thoroughly with soap and hot water before re-use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Do not breathe dust or vapor. Wear mask or respirator of a type passed by the U. S. Depart ment of Agriculture for phorate protection. If handled indoors, provide mechanical exhaust ventilation. D not store near food or feed products. Keep out of reach of children and domestic animals. Bury spillage; wash area thoroughly with a solution containing 1 lb. soda ash per gallon of water, to which a water-soluble wetting agent has been added. Empty containers are to be destroyed by burning or burying; n never re-use. Stay out of smoke when burning containers. POISON * First Aid (Same First Aid as for Parathion) Not*: For certain application*. Direction* for Use may n**d to Include more detailed instruction* for tafe handling of this product and material* treated with it. Label* *houtd also bear statement* relative to the protection of persons and animals in treated and adjacent areas. 140 POTASSIUM CYANATE CAUTIONI Avoid breathing dust or spray mist. Avoid prolonged or repeated contact with skin. Wash thoroughly after spraying. RONNEL (0,0-DIMETHYL 0-2,4,5-TRICHLOROPHENYL PHOSPHOROTHIOATE) 1. Dry Formulations (10% to 30% incf.): CAUTIONI HARMFUL IF SWALLOWED Avoid prolonged breathing of dust or spray mist. Avoid prolonged or repeated contact with skin. Wash thoroughly with soap and water after handling and before eating or smoking. Avoid contamination of feed, foodstuffs, and water supplies. Keep out of the reach of children, 2. Solutions or Emulsiflablo Formulations; Sine* various solvents which diffnr in toxic propnrtins may bn usnd, labels should bear precautionary Information covering the combined hazards of rannel and solvent. SODIUM CHLORATE WARNING! STRONG OXIDANT CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE Clothing and vegetation contaminated with chlorate or its solutions are DANGEROUSLY FLAMMABLE. Remove clothing and wash thoroughly with water. Keep persons and animals off treated areas. Spillage may cause fires. Do not get on floor. Sweep up and remove immediately. When not in use keep tightly closed in original metal container. Keep away fr m fire. Store separately from flammable material. 141 SODIUM FLUORIDE WARNINGI MAY BE FATAL IF SWALLOWED Avoid breathing dust. Wash thoroughly after handling. Clean up spillage. SODIUM FLUOSILICATE CAUTIONI HARMFUL IF SWALLOWED Avoid prolonged breathing of dust or spray mist. Avoid contamination of feed and foodstuffs. Keep away from children and domestic animals. Clean up spillage. SODIUM TRICHLOROACETATE WARNINGI IRRITATING TO SKIN AND EYES MAY CAUSE BURNS . Do n t get in eyes. Avoid contact with skin and clothing. Avoid breathing spray mist. In case of contact, immediately flush skin or eyes with plenty of O water for at least 15 minutes; for eyes, get medical attention, y Remove contaminated clothing and wash before re-use. STRYCHNINE and STRYCHNINE SALTS (any effective concentration) DANGERI POISONOUS IF SWALLOWED Do not breathe dust. Wash thoroughly after handling and before eating or smoking. Store away from and do not contaminate feed and foodstuffs. Keep children, pets, and domestic animals away; especially from baited areas. POISON A* (Antidote) 2,4,5-T (2,4,5-TRICHLOROPHENOXYACETIC ACID and Derivatives) ~ Same labels as 2,4-D TETRACHLOROPHENOL Same labels as PENTACHLOROPHENOL 040437 142 143 CMA 0 4 0 4 3 8 T^AETHYL PYROPHOSPHATE (any effective concentration) DANGERI POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN REPEATED EXPOSURE MAY, WITHOUT SYMPTOMS, BE INCREASINGLY HAZARDOUS Do not get in eyes, on skin, on clothing. Wear clean heavy rubber gloves and goggles. Wear clean water proof or freshly-laundered protective clothing Icoveralls, cap, etc.). Replace gloves frequently and destroy used gloves. Wash thoroughly with soap and warm water before eating or smoking. Bathe immediately after work and change all clothing. Wash clothing thoroughly with soap and hot water before re-use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Do n t breathe dust, vapor, or spray mist. Wear mask or respirator of a type passed by the U. S. Depart ment of Agriculture for tetraethyl pyrophosphate protection. Airplane pilots should wear full-face canister-type mask. If handled indoors provide mechanical exhaust ventilation. Do not store near food or feed products. Keep out of reach of children and domestic animals. Bury spillage; clean up area with strong lye solution. Burn or bury containers; never re-use. Stay out of smoke when burning containers. POISON First Aid (Same First Aid as for Parathion) Nat*; Labels should b*ar a itat*m*nt relative to lb* protection of perrons and animals in treated and adjacent areas. 144 THALLIUM SULFATE (any ff ctiv c nc ntration) DANGERI CUMULATIVE POISON ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Wash thoroughly after handling and before eating or smoking. Store away from and do not contaminate feed and foodstuffs. Keep children, pets and domestic animals away, especially from baited areas. Burn all pests killed. g*POISON (Antidote) THIOCYANATES Because of th* differences in properties of members of this group, each product containing them must be reviewed individually In light of its own characteristics. THIRAM (any effective concentration) CAUTIONI MAY CAUSE IRRITATION OF EYES, NOSE, THROAT, AND SKIN HARMFUL IF INHALED OR SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. Note: For certain applications. Directions for Us* may need to include more detailed In structions for the safe handling of this product and materials treated with it. 145 040439 TOXAPHENE 1. Dry Formulations (25% and over): WARNINGI MAY BE FATAL IF SWALLOWED MAY BE HARMFUL BY SKIN ABSORPTION Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. 2. Dry Formulations (less than 25%); CAUTIONI HARMFUL IF SWALLOWED Avoid prolonged breathing of dust or spray mist. Avoid contact with skin, eyes, and clothing. Wash th roughly after handling. 3. Solutions or Emulsiflable Formulations: Sines various solvents which differ in toxic properties may be used/ labels should bear the precautionary Information covering the combined hazards of toxaphene and solvent. N-TRICHLOROMETHYLTHIOPHTHAL1MIDE -- Same label as CAPTAN o TRICHLOROPHENOL (all isomers) CAUTIONI MAY CAUSE SKIN IRRITATION % Avoid prolonged or repeated contact with skin. Do not take internally. 146 WARFARIN Same labels as 3*(alpha-ACETONYLFURFURYL)-4HYDROXYCOUMARIN and SODIUM SALT ZINC ARSENITE - Same label as CALCIUM ARSENATE ZINC PHOSPHIDE FORMULATIONS (10% and ver) WARNINGI POISONOUS IF SWALLOWED Do not breathe dust or vapor. Wash thoroughly after handling and before eating or smoking. Store away from and do not contaminate feed and fo dstuffs. Keep children, pets, and domestic animals away; especially from baited areas. POISON (Antidote) ZINEB (any effective concentrationJ CAUTIONI MAY CAUSE IRRITATION OF EYES, NOSE, THROAT, AND SKIN MAY BE HARMFUL IF INHALED OR SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, flush skin or eyes with plenty get medical attention. *Keep away from fire or sparks. f water; for eyes, For dull mixture, 5C% and over, qno' for lower concentration! if diluent it tonbuiliU*. ZIRAM (any effective concentration) -- Same label as ZINEB 147