Document jmpKDNykXwa9v8JMMm7RYnnrN

{ U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Approved OMB No. 44-R13B7 Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shjpbreaking (29 CFR 1915, 1916, 1917) MANUFACTURER'S NAME Cabot Corporation SECTION 1 EMERGENCY TELEPHONE NO. address fSumher, Street. Cilr. State, and ZIP Code) 125 High Street. Boston. Mass. 0 2110 CHEMICAL NAME AND SYNONYMS Silicon Dioxide. Silica CHEMICAL FAMILY TRADE NAME AND SVNONVMS a CAB-O-SIL FORMULA Oxide__________________ ___________________________________________ ________________________________________________________________________ SECTION II HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES. & SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS R'GMents None BASE METAL TLV % (Unit*) CATALYST VEHICLE solvents ADDITIVES OTHERS Nnnp None Nnnp ,N, nnft ALLOVS NnnP METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX Nnn * OTHERS HAZARDOUS MIXTURES OF 0~HER LIQUIDS, SOLIDS, OR GASES TLV % (Unltl) SECTION III - PHYSICAL DATA BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-J) solubility in water Negligible N.A. N. A. N.A. SPECIFIC GRAVITY (HaO=l) PERCENT. VOLATILE BY VOLUME <%) EVAPORATION RATE ( =D appearance and odor Fine White Powder. Odorless 2.2 N.A. N.A. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) EXTINGUISHING MEDIA N.A. ,,N.A. . SPECIAL FIRE FIGHTING PROCEDURES N.A, . flammable limits N A___ Lai Uel NoneUNUSUAL FIRE AND EXPLOSION HAZARDS ,, 00 085944 - confidential \ PAGE (1) (Continued on reverse side) Form OSHA-20 Rav. May 72 threshold limit value SECTION V - HEALTH HAZARD DATA 20 jjppgf . 8 hour time weighted average EFFECTS OF OVEREXPOSURE " _____________________ Non-hazardous - Temporary Discomfort------ EMERGENCY AND FIRST AID PROCEDURES SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE INCOMPATability (Materials to avoid) X None None HAZARDOUS DECOMPOSITION PRODUCTS ________________________________Nnnp HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR COf DJTIONS TO AVOID X None SECTION VII SPILL OR *,EAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep up or use vacuum cleaner____________ WASTE DISPOSAL METHOD ------------------Ron Hire wasf.ft M gpnsal as for ordinary wastes such as paper, wood, sand etc. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY protection (Specify type) M-S-A Dustfoe 77 is sufficient VENTILATION LOCAL EXHAUST Helpful but not essential SPECIAL mechanical (General) OTHER PROTECTIVE GLOVES Not necessary OTHER PROTECTIVE EQUIPMENT EYE PROTECTION ,_ _ _ . Normal Good Safety Practic SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Drv..powdered materials can build static electrical charges when subjected to friction. Proper precautions, when using CAB-O-SIL in theother precautions presence uf flammable or explosive liquids, should -------------------------be taken to prevent accidents. PAGE (2) GP 0 >30.540 DO 085945 CONFIDENTIAL 'jyyw ii'" 'WBjjjwaww F rm OSHA-20 Rv. Miy 72 wp MATERIAL SAFETY DATA SHEET BER CHEMICALS MSDSNO. 121.1 7 ST. PAUL STREET BALTIMORE. MARYLAND 21202 (301) 783-1120 I. PRODUCT IDENTIFICATION TRADE NAME: Cadmium Pure Yellow and Yellow Orange; CADMOLITH* Yellow and Yellow Orange SYNONYMS: Cadmium-Zinc Sulfide: Pure and Lithopone ______________ Color Index Pigment Yellow 37, C.IJ77199 (PURE); Color Index Pigment Yellow 35, C.IJ77117 (CADMOLITH) II. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT CAS. NO. % PEL TLV Cadmium Sulfide (Pure) Barium Sulfate Zinc Sulfide 1306-23-6 7727-43-7 1314-98-3 27-100 0-65 0-25 0.2 mg/cu.m, (as Cd) 0.05 mg/cu.m, (as Cd) (TWA) 0 6 mg/cu.m, (as Cd) (Ceiling) Not established. Not established. Cadmium and cadmium compounds are listed as an undifferentiated group in IARC and Third Annual NTP Report as carcinogenic to animals, but with only limited and conflicting evidence of carcinogenicity to humans. This listing does not imply any adverse effect of -- cadmium pigments on human health. It III. PHYSICAL DATA Rs IILLIIMNGO PPOOIINNTT, T70iAOmmmmUHOfii: gCgdos'CubZliNmSesSuinblaimbseesnacet 1o1f8a5ir*Cat MELTING POINT Ba S04 r-> 1580 C SPECIFIC GRAVITY (HaO 1): cADMOLITHS =7.5 - 4.6 VAPOR PRESSURE: N. A, N, VAPOR DENSITY (AIR si): N. A. SOL. IN HsO % BY WT: Insoluble % VOLATILES BY WT: N. A. EVAPORATION RATE: N. A. APPEARANCE/ODOR: Fine yellow or orange odorless powder pH (10%, slurry): 6.0-7.5 IV. FIRE AND EXPLOSION DATA FLASH POINT: Not Combustible AUTOIGNITION TEMPERATURE: Not Ignitable FLAMMABLE LIMITS IN AIN, % BY VOL.: LOWER: N. A. UPPER: N. A. EXTINGUISHING MEDIA: None required. SPECIAL PINE FIGHTING CEDURES: None required. DO 085946 C0NFTD5NTTA( UNUSUAL FIRE AND EXPLOSION If heated to temperatures above 800*C in air, these materials decompose to form toxic fume.- HAZARD: oxide, zinc oxide and sulfur dioxide. cadmium ROUTES F EXP SURE INHALATI N: V. HEALTH HAZARD INF RMATI N Prolonged Inhalation of dust may cause Irritations of respiratory tract mucosal membranes. Long term exposure to metallurgical or soluble cadmium leads to kidney dysfunction, but no chronic effects have been shown to result from exposure to insoluble cadmium pigments. SKIN CONTACT: May have a drying effect on skin. SKIN ABSORPTION: The insolubility of cadmium-zinc sulfide pigments renders any skin absorption highly unlikely, and any corresponding toxic effect highly Improbable. EYE CONTACT: Eye irritation may result from contact with dust. INGESTION: Not toxic in acute exposure in animals. For cadmium pigment: (oral, rat) LD^, For zinc sulfide: (oral, mouse) LD^, >10,000 mg/kg > 30,000 mg/kg EMERGENCY AND FIRST AID PROCEDURES EYES: Flush eyes with plenty of water to remove dust particles. If irritation persists, consult a physician. SKIN: Wash skin with water and mild soap. INHALATION: Remove to fresh air. INGESTION: Administer milk or beaten egg whites at frequent intervals. Call physician. NOTES TO PHYSICIAN: None. 6 DO 0359-47 CONFTDFNTTAl VI. REACTIVITY INF RMATI N Decomposition in acid yields volatile, flammable and toxic hydrogen sulfide gas and soluble toxic cadmium salts in solution. Thermal decomposition In air about 800*C yields toxic fumes of cadmium oxide, zinc oxide and sulfur dioxide. VII. SPILL AND LEAK PROCEDURES Avoid generating airborne dust during cleanup. Use vacuum or wet procedures. Dry sweeping should be avoided. VIII. SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS: Local exhaust, if necessary to maintain airborne concentration below the TLV level. PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: NIOSH-approved dust respirator. EYE: Safety glasses with side-shields or goggles. QL VES: Optional, to protect hands from drying effect. THER: None. IX. SPECIAL PRECAUTIONS Avoid contact with acids. Wash hands before eating and smoking. Do not smoke or eat In areas of potential contact with pigment. OO Ho r- X. HAZARDOUS MATERIAL IDENTIFICATI N SYSTEM (HMIS) HEALTH HAZARD: FLAMMABILITY HAZARD: REACTIVITY HAZARD: MAXIMUM PERSONAL PROTECTION: 2 0 1 E XI. ENVIRONMENTAL INFORMATION WASTE DISPOSAL METHOD: This product when spilled, recover as a product as much as possible, clean-up by removal of contaminated soil and place material or contaminated soil in a suitable disposal container. The contaminated soil may possess EPA hazardous waste characteristics, EP-Toxicity for 0006. Dispose of the material after testing in appropriate approved facility. This product is listed under Superfund Amendment & Reauthorization Act of 1986, Title III, Section 313, Review appropriateness of this regulation pertaining to your usage. t August 1,198T PREPARED BY: Mr. J.H. Blacker____________________________ TITLE: ______ Manager-Industrial Hygiene & Health_________ COMPANY: ______ SCM Chemicals. Inc.________________________ ADDRESS: ______ 3901 Glidden Road, Baltimore, Maryland 21226 TELEPHONE: (301) 355-3600______________________________ _ 00 085949 CONriOFNTTAI MATERIAL SAFETY DATA SHEET (USDS NO. 120.1 BBS. CHEMICALS 7 ST. PAUL STREET BALTIMORE, MARYLAND 21202 (301)783-1120 I. PRODUCT IDENTIFICATION TRADE NAME: Cadmium Pure Red and Orange; CADMOLITHe Red and Orange >YM nyms: Cadmium Sulfoselenlde: Pure and Llthopone Color Index Pigment Red 108, C.I.#77196; Color Index Pigment Orange 20, C.I.#77196 II. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT CAS. NO. PEL TLV Cadmium Sulfoselenlde Barium Sulfate 58339*34-7 7727-43-7 30-100 0-70 0.2 mg/cu.m, (as Cd) 0.05 mg/cu.m, (as Cd) (TWA) Not established Cadmium and cadmium compounds are listed as an undifferentiated group In IARC and NTP as carcinogenic to animals, but with only limited and conflicting evidence of carcinogenicity to humans. These listings are based on cadmium compounds other than the pigmentory forms. No studies have implicated cadmium pigments as carcinogenic. / III. PHYSICAL DATA BOILING POINT, 760mm HQ: Cd sublimes in absence of air at 980C MELTING POINT Cd Se 1350*C SPECIFIC GRAVITY (HaO s 1). ^'S^oUTHS^ 4.5 - 4.6 VAPOR PRESSURE: N. A. VAPOR DENSITY (AIR si): N. A. SOL. IN HaO % BY WT: Insoluble % VOLATILES BY WT: N. A. EVAPORATION RATE: N. A. APPEARANCE/ODOR: Fine red or orange odorless powder pH (10% lurry): 6.0-7.5 IV. FIRE AND EXPLOSION DATA FLASH POINT: Not Combustible AUTOIQNITION TEMPERATURE: Not Ignitable FLAMMABLE LIMITS IN AIR, % BY VOL.: LOWER: N. A. UPPER: N. A. EXTINGUISHING MEDIA: None required. SPECIAL FIRE LIGHTING E ' CEDURESi None required. 00 085950 confident tai, UNUSUAL FIRE AND EXPLOSION If heated to temperatures approaching 900 C the materials decompose in air to form toxic cadmium HAZARD: oxide, selenium dioxide and sulfur dioxide. ROUTES OF EXPOSURE INHALATI Ni V. HEALTH HAZARD IHF RMATION Prolonged Inhalation of dust may cause Irritations of respiratory tract mucosal membranes. Long term exposure to metallurgical or soluble cadmium leads to kidney dysfunction, but no chronic effects have been shown to result from exposure to cadmium pigments. SKIN CONTACT: May have a drying effect on the skin. SKIN ABSORPTION: No literature references found citing skin absorption. EYE CONTACT: Eye irritation may result from contact with dust. INOESTION: Not toxic for acute exposure in animals, (oral, rat) LDM > 10,000 mg/kg EMERGENCY AND FIRST AID PROCEDURES EYES: Flush eyes with plenty of water to remove dust particles. If irritation persists, consult a physician. SKIN: Wash skin with water and mild soap. INHALATION: Remove to fresh air. INOESTION: Administer milk or beaten egg whites at frequent intervals. Call physician. NOTES TO PHYSICIAN: None. 00 085951 confidential VI. REACTIVITY INFORMATI N Acid decomposition yields volatile, flammable and toxic hydrogen sulfide and hydrogen selenide gases and toxic cadmium salts in Csolutions. Thermal decomposition in air about 800*C yields toxic cadmium oxide fume, selenium dioxide and sulfur dioxide. VII. SPILL AND LEAK PROCEDURES Avoid generating airborne dust during cleanup. Use vacuum or wet procedures. Dry sweeping should be avoided. VIII. SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS: Local exhaust, it necessary, to maintain airborne concentration below the TLV level. S PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: NiOSH-approved dust respirator. EYE: Safety glasses with side-shields or goggles. OLOVES: Optional, to protect hands from drying effect. OTHER: None. IX. SPECIAL PRECAUTIONS Avoid contact with acids. Wash hands before eating and smoking. Do not smoke or eat in areas of potential contact with pigment. c ^0 08595;} cnftdbnttai X. HAZARD US MATERIAL IDENTIFICATION SYSTEM (HMIS) HEALTH HAZARD: FLAMMABILITY HAZARD: REACTIVITY HAZARD: MAXIMUM PERSOHAL PROTECTION: 2 0 1 E o XI. ENVIRONMENTAL INFORMATION WASTE DISPOSAL METHOD: This product when spilled, recover as a product as much as possible, clean-up by removal of contaminated soil and place material or contaminated soil in a suitable disposal container. The contaminated soil may possess EPA hazardous waste characteristics, EP-Toxicity for D006. Dispose of the material after testing In appropriate approved facility. This product is listed under Superfund Amendment & Reauthorization Act of 1986, Title III, Section 313. Review appropriateness of this regulation pertaining to your usage. o AEgust 111987 PREPARED BY: Mr. J.H. Blacker____________________________ TITLE: ______ Manager-Industrial Hygiene & Health_________ COMPANY: ______ SCM Chemicals, Inc.________________________ ADDRESS: _____ 3901 Glidden Road, Baltimore, Maryland 21226 TELEPHONE: (301) 355-3600_______________________________ DO 085953 CONFIDENTIAL