Document jmmjLRB2wdrRx4K2R9npqeaX9

UA. DEPARTMENT OF LASOR Oeeupetionel Sihty md HMHh AdUMiMion y i* * r ^ ' '--ty QMS N*. 44.RIMT MATERIAL SAFETY DATA SHEET February, 1977 Itoquktd undar UtOt Safety and Haalth RafUtadon* lor SMp Rapatrin*. SMpbuddina, and SMpbraaklns (29 CFR 1919,1919, 1917) MAMUAACTUMCAt NAMC PPG Industries, Inc. SECTION 1 , CMCROCNCV TCLCPMONC NO. (412) 434-3131 ^ne"^t^V^^'nter^lTtsKirg^. PA 15222:.___ _____ CMCMICAL NAMC AMO tVMOMVM* j^TAAOC NAMC AMO>V*yYM woVynlnWvclladMennteV Chloride. Vlnvlldene Chloride Mono __ Chlorinated Hydrocarbon_______________ 1_____ -CHfJgle_________________________ SECTION II . HAZARDOUS INGREDIENTS faints. encamvATivta. a soLvunt % TLV (AIN alloyi awe awanic ooatipw* PIOMCMT* RASCMCTAL TLV S <U*tad CATALYST ALLOW VKHICLK SOLVENT* AOOITIVU OTNCM METALLIC COATtNM FILL** MCTAL run coATiMAQw com ruix OTHSea - . ./r *1 V MAIANOOUK Mummss OF OIHSR UMNO*. tOtJM, OR A*RS VinylIdene Chloride 1' % TLV (IMttl 100 10 ppn -' SECTION III PHYSICAL DATA ROIUNO POINT (V.) VAPOR PRf**UA (MM M*.) g 88.9 495 PCCIPIC ORAVITV (H|OsD PCRCCNT.'viopA'TILS bvvoluMnJ\ > VAPOR OCNSITV |AIR>|) 3.34 SOLUBILITY IN WATfR g 20C ___0_,04X appcaranccamoooor clear, colorless llauld. sweet oddr 1.213 100 1 SECTION IV FIRE AND EXPLOSION HAZARD DATA rm5iH0 pFoiifciMpuliTnpen rup) mm-- tkYXiljWOUI*HINO MODI* , rsCO?, dry chemical. water spray, foam --iAt pjri:prktinr proccdurc* breathing apparatus; water -spray my be ii^eri to-cowl wmljanflnt UNUSUAL na( ANO KxrUOttOM HAZARDS rP,--r-o- Jducts of c---o--m-- busttbn Include toxic and corrosive PAQt (1) (ContlmMd m i Mb) Form OSHA-20 Ha*. May It SL 07457: SECTION V - HEALTH HAZARD DATA THf r 5HOLD LIMIT VALUE 10 parts per million (ppm) - volume/volume ACGIH - 1976)__ f :ts of overexposure aspect Carcinogen in experimental laboratory animals - See Attached Sheet EMERGENCY AND FIRST AID PROCEDURES See Attached Sheet SECTION VI * REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID Ignition sources, direct sunlight, excessive heat STABLE X* exposure to atmospheric oxygen. INCOMPATABILITY (Mtltfith to ovoid) Contamination with water, free radical initiators; copper, aluminum and their alley HAZARDOUS DECOMPOSITION PROOUCTS ExpTosvve peroxides, hydrogen chloride. HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR (SNOmONI TO AVOID Txposure to atmospheric oxygen. *Exposure of uninhibited or inhibitor-depleted monomer to oxygen may form explosnive peroxides. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED _-Evacuate spill area: remove source* nf ignition*. wary Rlf-rnntainaH hrarthing apparatus; ventilate area to below explosive limits; dike large spills. Small spills can be removed with absorbent material such as sand or vermlculite. WASTE DISPOSAL METHOD _ Large dilced Quantities should be pumped to salvage tanks for reclamation OIL disposal by waste disposal contractor. For small quantities, absorb as indicated Above, then sweep up absorbent material and place in closed containers for dis- SECTION VIII SPECIAL PROTECTION INFORMATION "respiratory protection (Specify type) _____________________ ________________________ - __See Attached Sheet... VENTILATION i ilocal exhaust 5UTT c cut to maintain concentration below TO ppm. MECHANICAL /Gfmttol) SPECIAL OTHER PROTECTIVE GLOVES 1 EYE PROWnONChemical ,,Neopreneunless full far.emece respirator* s OTPMrEo*tPeRcOtTivCCeTIVc^olHVncTto Drevent skin contact. safe+y worn. QOggleS, SECTION IX - SPECIAL PRECAUTIONS Keepaway fromtaskoeunricnehsanodrliniggnaintdiosnto;rainvgoi.d. con.tam.ina.t.ion w.i.t.h oxygen, moisture or cSatotraelyitniccTomool,ufditriyesptlacvee.f_ip_-_ft_a_t_e_n__a_i__u_n_a_e_r__in__e_r_t_i_w__s_p_h_f_e_r_e___ih__d__ry__a_duipm__e_n_t_.-_-_--_-_-OTDHoERnPoRtECsAtUoTrIOeNSmaterial longer than 4 months. PAGE (2) * NOTE: Do not add reclaimed material to fresh material. If PO *>. contaminated. FormOSHA-20 r*>. Mayra SL 074578 ABDENDUM TO MATERIAL SAFETY DATA SHEET ON VINYLIDENE CHLORIDE (FEBRUARY 1977) Section V - Health Hazard Data Effects of Overexposure: Acute - Overexposure to vapor can lead to anesthesia, irrational behavior, drunkenness, and if continued, unconsciousness and ultimately, death. Liquid vinylidene chloride is irritating to the eyes and skin. The inhibitor can cause local skin irritation or burns unless washed off thoroughly. Since the odor threshold lies between 500 and 1000 ppm, the odor of vinylidene chloride is not an adequate warning to prevent overexposure. Chronic - In recent preliminary animal studies, it has been reported that vinylIdene chloride in concentrations higher than the present ACGIH threshold limit value (TLV) of 10 ppm may be carcinogenic to some species of experimental laboratory animals via inhalation. Although these findings are preliminary and incomplete, it is suggested that air concentrations of vinylidene chloride in the work area be maintained below 10 ppm at all times. It Is also recomnended that the 8-hour time weighted average (TWA) be maintained as far below 10 ppm as practical. Chronic exposure to low concentrations of vinylIdene chloride can result in Injury to the liver and kidneys. Emergency and First Aid Procedures: Inhalation Overexposure - Remove to fresh air. If not breathing, give artificial respiration, preferable mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. Eye or skin contact - Inmediately flush with plenty of water (soap and water for skin) for at least 15 minutes. If irritation occurs, consult a physician. Wash contaminated clothing before reuse. Section VIII - Special Protection Information Respiratory protection: Wear NIOSH/MESA - approved non-air purifying respiratory protection where concentrations cannot be maintained below 10 ppm. Establish a respiratory protection program in accordance with the minimum requirements of 29 CFR 3 1910.134 (May 28, 1975). SL 7457g