Document jmg4mG3d7v8oZZBBbm1KgoKdk

Technical Service Report Report No. 431-81-804-8 To From Date E. L. SoneS C. B. Herrin April 8, 1981 Conoco Inc. Research and Development Department Analytical Research Section Ponca City, Oklahoma CC........... '1 THIS DOC 1!i,.' ; 11 i . .. AND THE PhOf-Cn fy (ji L'. : : 1 !: ; Subject PURGEABLE PRIORITY POLLUTANTS IN SAMPLE VOA 4236-93-13 LCCP 002 ANALYTICAL NUMBER 16998 Conclusion The following priority pollutants were found: 1) methylene chloride 2) chlo roform 3) 1,2 dichloroethane 4) benzene 5) toluene 6) ethyl benzene 1 PPb 0.. 9 ppb 3 ppb 244 ppb 60 ppb 2 ppb. Other components found in "significant" amounts were butane and hexane and butanol and hexanol. Expcrimental The sample was run on the Finnigan 0WA-30 GC/MS/DS using a Tekmar L.SC-2 automatic purge-and-trap apparatus. The conditions were; Sample Concentrator Purge gas Purge time Desorption time Desorption temperature Sample size Internal standards G.l s Ch r oma t og r a ph Carrier Column Oven temperature program Mass Spectrometer Scan 40-250 amu in 4 sec 1000 'n'.o'.is collected. He @ 40 roft/min 12 min 4 min L80C 5 ml 1,4 dich1orobutane and bromochloromethane. He @ 20 mH/min 6 ft, 17o SP 1000 on Carbopak B 30C for 4 min initial hold then 8D-/min up to 180C then hold for 120 min. SAL 0000881 Technical Service Report No. 631-81-804-8 Page 2 The sample was removed from the cold room and allowed to come to room temperature before it was run. Methanolic solutions of the internal standards were injected into a syringe containing 5 mfi- of sample. Cal ibration was accomplished by dosing boiled-and-sparged Milli-Q water with the internal standards and a blend of EPA Consent Decree volatile standards prepared by Radian Corp. and purchased from Regis Chemical Co. This dosed water was run under the same conditions as the sample, and the data obtained were fed into two of the OWA system libraries. The data from the sample were run through the OWA system automatic quan tification program which employed the two libraries in the reverse search mode. The standard blend did not contain any compounds more volatile than methylene chloride, so a manual search was performed for the five gaseous priority pollutants. None were detected. Discussion of Results The sample contained non-priority pollutant components which appeared to be in excess of 10 ppb. These components were forward searched using the NBS library and an automatic search routine. Good matches with ref erence spectra were obtained for the compounds listed in the Conclusion section. Xylenes were not detected. The automatic quantification pro gram gave hits for trichloroethylene and tetrnchloroethylene. These may have been false positives. The spectra were not good enough to make a positive identification. The automatic system also gave a false negative for methylene chloride. The methylene chloride value was calculated manua1ly. C-t & He>rnM C. B. Herrin Research Group Supervisor Gas Chromatography Group Analytical Research Section BW At tachments Copies to FK I:'.AS bib. SAL 0000138127 ; <>Oo I aajHidNoo Noriisinoov X :GS -91 rS/92/*: 0:2s o 'i? nj nwv oezf ni nwy ot? woud muds noat/T ON 869+ 31cJWVS ~1W Q d^UA 30d0d WOO l'S/9S/C VOA 500 dOOO omv-:3aow inw/ u.j Ndo a(i ;-bs i aVL-j ' 3UOH TNI a:3Si;vdAn ?>o ON b9S CINV C -C6--9CCt' :S1N3WN03 NE10 IS A3VNV 33d :.\n (.'dillWOAS 00d003 :33dU!V3 ooo CIC6*& -O O.IJ'dvAS 'OV ^ . ; i- i-1' ic NO 'JNKNUlJ': SA;-,pi..Ir. CllMNI ITA T'lUN GWA REVERSE SEARCH STATUS RhRL'R T THE I N IERNAI. STANDARD AREA HAS A DIFFERENCE OF. -100 PERCEIMi Of THE LAST STANDARD INTERNAL STANDARD FOUND FOR LIBRARY: l.I OR ARY V1 CONFOUNDS QUANTITATED BY INTERNAL STANDARD USING PARAMETERS IN 5. IJjRARYUi Rl I T.R I EXPECTED BES 1 ENTRY HO SCAN SCAN FIT L J BNARY PEAKS UR I TV ENTRY MO FOUND PEAKS QUANT SATURA` r KS a < 1. ,? J. L 215 993 6/2 14 1 ll F44 24 7 998 LSI I3 OSS 258 964 307 i. 0 13 l 1 0 o NUMBLY OF COMPOUNDS IDENTIFIED 0 DATA PKGCLSSiNC OF G 1.9313 COMPLETED ON 4/06/01 19.33:17 SAL 000088129 :'1WN'('Ji '! 1YLGET ODnPL'UND AN/'L.'ol- luamt iiation report fill* DATA- St. 73 3 3 T 1 03/36/31 IS: 34 00 SAMPLE LCCF002 SUDMiT i/O BY: ELS ANALYST C13 H AMOUNT-AREA (HGHTJ R REF. AMNT / iREF AREA HGhT ) x REfP FACT) PESP. FAC. FROM LIBRARY ENTRY NO NAME 1 HROMDCHLGROMETHANE <INTERNAL STANDARD) 3 CHLORGMETHANE 3 01OHLDRGDIFLUORQMETHANE 4 HR' 300METHANE 3 VINYL CHLORIDE 6 CHLOROETHANE 7 METHYLENE CHLORIDE 3 IP, ICHLOHOFLUORQMETHAME 9 l-DICHLGROETHYLENt: 10 1.1-DICHLOROETHANE :i J TRANS-1,2-DICHLOROETHYLENE 13. CHLOROFORM 13 1, 3--DICHL0RETHANE 14 1,1,I-TRICHLOROETHANE ID CARBON TETRACHLORIDE 16 BF.OMGDICHL.OROMETHANE NO H/L SCAN TIME REF RRT MF.TH ILL 215 14.31 1 3 . 000 A BB FT i FOUND 3 ml v FOUND ! FOUND 3 NG I FOUND ALL FOUND NO : F OUND 0 NO. FOUND Npv found 1 ; ACT FOUND ; ; FOUND ; j 247 1 6 40 1 1. 149 A 1?U i 9- 258 17: 25 41 !. 200 A BB HL ' POUND i i i r POUND LIN FOUND ARF.A(HGHT) AMOUNT 138019. 100. OOO UC/L 7.1 UT 96. 05 3155. 797 0. 347 UG/L. 2. 264 UG/L. 0. 21 3. .14 ",AL 000SB.I30 : ;-jP-l i GAN TAF- CT: I C CNT'GUND ANAL. , 3 1 5 GUAnTITA'" 1 Oh REPORT FILE: GL?3 i O f A- 01. ?3J 3. f I Od.'26/Si 15: CM: 00 SAMPLE: L.CCP002 SUBMITTED BY. ELS ANALYST- CBH AMOUNT "AREA < HGHT > * REF. AMNT/( REF. AREA ' MGHT ) REBP. FAC. FROM LIBRARY ENTRY RESP.FACT! no name 1 1/A~DICHLOROBUTANE <INTERNAL STANDARD) P 1; 2--DICHLQR0PR0PAME TRANS-1, 3-D! CHLOROPROFEME 4 TR I CIIL GR OETHYLENE 3 BENZENE 6 CIS-1 . 3-DICHLDROPROPENE 7 1. ; , 2-TRICHLOROETHANE 3 DID20M0CHL0R0METHANE 9 BROMOFORM .5 0 1,1,2, 2-TETRACHLOROETHYLENE 11 1 < 1/2/ 2-TETRACHL0R0ETHANE 1.2 TOLUENE A3 CHLOROBENZENE :. * ETHYLBENZENE NO r-i / e SC AN T1I ME REF RR 7 ME:th 1 55 440 29: 42 1 .1. 000 A BB NOT FOUND uJ NOT FOUND A 30 \ ) */0t3o 30.3 21: 4 a 331 22- 2t !. 0 734 A BE < 0 752 A BB J NOT FOUND ; M . ` FOUND met FOUND 5v- r FOUND 1. 0 L i 431 29 06 1 o. 980 A BB \ ` NC T FOUND i o 7 3 4/6 32 OB l -'.I.- i FOUND i " , 636 42: 36 O CD M 1 1. A BB .1 J 44 5 A BB AREASHGHT) AMOUNT 72ITT 328818 140. coo NG/ML 31 4 1 1008. 2065130. 0. 267 NG / ML. 0. 06 243. 561 NG/ML 54. 65 86. 267352. 5914 o. 025 NG/ML. 0. 0 ! 59. 535 NG/ML 13. 36 0 C- , 306 NG/ML 0. 52 OOOOBBl31 s&t- i SAMPLE 0UAN1 I TAT I UN CJv.'A RE Vi.-.iR SL SEARCH STAUiti RFTiLiR ir it. i H LLR, ;AL b ' . AR D AREA HAS A DIFFERENCE OF. PERCENT nr : i in la? INTERNAL STANDARD FOUND FOR LIBRARY:LIBRARYV? TANDARD COMPOUNDS QUANT FI ATKO DY INTERNAL STANDARD USING PARAMETERS IN I.J0RARYV2 R L.P OFT EXPECTED BEST ENTRY NCI. SCAN SCAN FIT LIBRARY PEAKS PUR ITY ENTRY NO. FOUND PEAKS QUANT SATUhQ' PEAKS J 438 4 '10 989 476 1 1 1 0 L*. 321 323 993 6 4 1 J 0 5 32=? 331 1000 483 5 1 1 o 10 429 431 921 33 10 1 1 o A` C->- 47 5 476 996 641 12 1 3 0 14 634 635 997 198 14 1 J 0 number OF COMPOUNDS IDENTIFIED 6 DATA PROCESSING OF GL9313 COMPLETED ON 4/06/81 20 48:27 ,0S8l32 ooo SAt-