Document jmXxXEgbQyvKKwaYDVO4qB2KN
CCs M.Hunt/E.Gonick, Pigts., Wilm. S.J.Gorman/L.F.Andrews, Wilm. R.H.Zabel, Wilmington W.F.Spengeman/H.B.Clark, Chest.Run W, J.McClure/R.A.Hageman, Newark H.Arnoul/R.Gedd, Newark B.L.Rodowskas/R.M.Salemi, Newport W.S.Struve/A.A.Brizzolara, Newark F.F.Ehrich, Newark R.H.Wetzel/J.W.Minnich, Newport Newark, New Jersey January 31, 1969
P. D. GRAHAM Pigments - Wilmington
EXPERIMENTAL "MONASTRAL" BLUE GF (B)BT-465-D
Attached is a Research check list for. BT-465-D, in cluding information on composition, suggested uses, proper ties, material on hand, and patent status.
Submitted by; H, Matrick
APPROVED BY:
A. A. BRIZZOLARA
I. COMPOSITION
84.4% N-657 Blue G 14.9% N-873 CPC-AP
0.7% Moisture (based on BT-297-D data)
II. SUGGESTED USES
A. Paint
BT-465-D offers improved transparency and strength over BT-297-D in any system where BT-297-D is subject to crystal growth during dispersion. This appears to include virtually all paint systems where ball milling or CAB chipping is the method of dispersion. BT-465-D is also fully superior to BT-297-D in work ing properties such as mill base viscosity, gloss, and flocculation resistance.
BT-465-D offers improved tinctorial properties such as trans parency and strength over BT-417-D in most paint systems, but particularly in low work applications such as sand milling. This is because BT-465-D is readily dispersible relative to BT-417-D.
B. Plastics
BT-465-D offers dramatic improvement in heat stability in linear polyethylene vs. BT-297-D or BT-383-D. BT-417-D has not been evaluated in this application because of poor dispersibility. BT-465-D is expected to perform well in other plastics with similar solvent characteristics and/or fabricating temperatures such as non-linear polyethylene, polypropylene, acrylonitrilebutadiene-styrene and possibly `'high temperature" PVC. If the resin is too good a solvent for CPC such as in polystyrene, no advantage over BT-297-D will be evident. If the resin is too poor a solvent for CPC as in low temperature PVC, BT-297-D will perform sufficiently well. Heat stability performance of BT-465-D is
concentration dependent. At very low concentrations (o.oi phr),
heat stability is not as good as at moderate concentrations (0.1 phr). ;At high concentrations (1.0 phr), BT-297-D may suffice.
C. Inks
BT-465-D shows no advantages over BT-417-D in ball-milled nitrocellulose ink. Likewise, the former did not demonstrate any advantages over BT-297-D or BT-383-D in oleoresinous ink by 3 roll milling.
III. PROPERTIES (Chestnut Run has evaluated BT-465-D for auto motive applications under NC-69-22)
A. Acrylic Lacquer
1. Tinctorial and Working Properties
a* Sand Milling - Ret 68-322A, 68-877A
DUP050081437
N42377.01
2-
B-4804, C#68176
Brookfield Viscosity
CPS 6_ rpm 60
2100 740
Ford Cup Seconds
138
Shear/S trength Uniformity
0-10 scale**
4
Transparency Strength*
vs trans. 110+
GTNF-55-3450 1300 C#69701
550
101
8 s trans. 100
BT-417-D, 84871
300 290
85
6 standard 110-130+
BT-465-D,
600 440
107
dip flooded
full trans.
1888-22
100
Bagman Gaucre Grit Reading
BT-417-D, 97482 ST-465-D, 00399
5* 10' 15' 20'
1.0 2.5 4.0 6.0 3.0 5.0 6.0 7.0
b. CAB 2-Roll Mill Dispersion Re: 68-839
B-4804, C#68176
GTNF-55-3450 C#69701
BT-417-D,
84871 BT-465-D, .
1888-22A
Ford Cup Viscosity
48"
46"
30"
40"
Shear/Strength
Uniformity Transparency Strenc
4
s trans.
120+
8
vs trans.
100
10
standard
110
10
transparent
100
2. Humidity Resistance
The humidity resistance in High Gloss "Lucite", by CAB dispersion, using Semi-Works material which had been washed to
2100, 5000, and 8000 ohms, respectively, showed all three samples to be markedly superior to BT-417-D. The latter is considered to be acceptable. However, it is recommended that BT-465-D be washed to 5000 ohms routinely as in process (B).
3. Outdoor Durability
Series 68409 - Ball milled - 6 Mos. Exposure
25 A1
75 A1 90 A1 __5 ...
75 color 25 color 10 color 95
BT-465-D, 187584F (dry blend) 10 9.5 9 6
BT-417-D, 84871
88
86
BT-297-D, PS-98150
9 9.5 10 10
Strengths are rough estimates. comparison of spray vs. pour? at = strength, rating is 10? at
low pour strength rating approaches 0.
DUP050081438
-3Series 68411 - CAB Dispersion - 6 Months
BT-465-D/ 1875-83B (dry blend)
BT-417-D, TS-84871 BT-297-D, PS-98150
90 Al 10
6
6 7
25 Al 75
9
8 6
--Jbrint 95
5 5 6
Series 68411 - Sand Milled - 6 Months
BT-465--D (dry blend) BT-417--D* TS-84871 BT-297-D, PS-98150
90 A1 10
7 7 7
25 A1 75
8 8 9
__5 95 Tint
6 5 6
Series 68430 - CAB Dispersion - 3 Months
BT-465-D, 1888-22A BT-417-P, TS-84871
BT-297-P* PS-98150
75 A1
25 8
10 8
25 Al
75 7 9 9.5
_5 95
Tint
6
6
8
Series 68430 - Sand Milled - 3 Months
BT-465-D, 1888-22A BT-417-P, TS-84871
75 Al
25 9
10
25 Al
75 10 10
5 95
Tint
9
8
B. Thermosetting Acrylic Enamel
1. Tinctorial and Working Properties
a. Sand Milling Ret 68-323
B-4804,68176 GTNF-55-3450
C#69701
BT-417-P, TS-84871
BT-465-D/ 1888-22A
Brookfield Viscosity
CPS 6 rpm 60 6100 850
500 120
100 30
400 130
#4 Ford Cu p 63" 19"
Shear/Strength Uniformity 1 8
Trans
parency Strength
equal
98
s.trans. 93
14" 6 standard 100
20" dip flooded full trans.
94
b. Ball Milled Reii 68-111
GTNF-55-3450 1700 190
35"
8.5 s.opaque ca ?
C#69701
BT-417-D.
75 70
23"
6
standard std.
TS-84871
BT-465-P
300 142.5 30" dip flooded trans.
ca =
1875-88B,(dry blend)
II
i
DUP050081439
4
2. Outdoor Durability
Series 68410 (TAE-2) Sand Mill - 6 Months
BT-465-D, 1875-77E {dry blend)
BT-417-D, TS-84871 BT-297-D, PS-98150
90 Al
10 6 6 6
25. Al
75 10
10 10
_5 95
Tint
8
7
7
Series 68411 (TAE-3) Ball Mill - 6 Months
BT-465-D, 1875-77C (dry blend) BT-417-D, TS-84871 ' BT-297-D# PS-98150
90 Al 10
5 6 7
25 Al 75
9 8 8
_5. Tint 95
7
7 7
Series 68430 - TAE-3 - Sand Mill
BT-465-D, 1888-22A BT-417-D, TS-84871 BT-297-D, PS-98150
75 Al 25 " '
9 10 10
25 Al 75
10
10 10
95 Tint
8.
9 9
C. Plastics - Polyethylene
1. Heat Stability
Re: NC-67-22 Alathon 7050
450 500
600F .
BT-465-D, 1875-8E (dry blend)
9
8.5 7.5
BT-297-D, 1875-8G
8 6 4 3.5
Re: NC-67-14 - Alathon 7040
BT-465-D, 1859-89D (dry blend)
10
10
10
9
BT-297-D, PS 98150
8 7 54
D. Specific Gravity: 1.88
IV. MATERIAL OH HAND
BT-465-D, lot 00399 (38 lbs.) prepared in the Newark SemiWorks by wet blending is available for trade sampling. A 25 lb.
sample has been transferred to Sales. An additional 10 lbs, are being retained by Research.
V. PATENT STATUS
A composition of matter patent on 0-CPC with CPC-AF has been applied for (patent application 1702K).
DUP050081440
C'?'/5'
MAKING INSTRUCTIONS; BATCH Ul
>.V. 2QO, 202, 204, 210, 240, 2-6v 1' >, 2641
CO 20 CODE BT-46.5-0
PKO.
* E$T. WOT. $T0. HRS.
2327
j .b 5. TIME
C.V.
M
________
1 __.______' _________' __ P.V._______________________ ___
PROCESSES
APPROVED 1
(B BT-465-D () (I
( > FV/K 2-6-69 ( ) HM jd?~j~h'3 ( ) RG 2-10-6.
(1 TYPED BY
(>
EQUIPMENT
SV 1
12
NAMEt
"MONASTRAL" BLUE GF
Ru n 2" (+100 G) w a t e r in t o V-
20Pu mp in t h r u
me s h s c r e e n
"
$TooI
`
" if .
USE LBS,
NON-BLEEDING
M CODE
AO LB
873-A 350_
*
3
Pu mp , in
t h r-uj-~20
me s h s c r e e n
, ~~
" 1^
1
657-A 2000
"5-- Fl o o d t o
" & s t ir 15 min
5" DO NOT STOP AGITATOR
S 200 202 4 1 go" 92^
( 6084GV (5446Gi
204 210 240 261 264 88" Fn 72" 85" 82"
(5174GV (59770^ 1'3182G)(7395G) (3624G )
V
St a r t
-Fin
Op t r
__
.
*
| 1
; V
V
* DUP050081441
CO 20 CODE BT-465-0
-4
EST. WOT,
2327
PKO. _
LBS. `
REMARKS
PROCESSING INSTRUCTIONS: GATCH Ut
PROCESSES
(B) BT-465-0
APPROVED
EWK 2-6-66 HM , 2-6-ti
RG 2-10-6
TYPED BY
FC 2-24-69
MAKING NOTES
NAME.
,,MO^IASTRAL,, BLUE GF
______________________ .
__________________
NON-BLEEPING
INSTRUCTIONS
-PRESSING-
RECORD
v at
DATE
t ime
RELEASED BY
PRESS
12
NO, OF CAKES 3X36
PRESS
Wit h
w as h TO 5000
TEST AFTER 3
26 3X40
90 2X48
ag it at io n
OHMS 35- /b"F WATER
HOURS
LOAD
ON 6 CARS
.# '
PRESSLOAO STARTED CAKES USED
WATER ON HRS, WASHED
OHMS HRS, WASHED OHMS HRS. WASHED OHMS CAKE CONDITION NO. CARS LOADED
EXPLAIN LOSSES
1ST
2ND __3RP__ 4TH _iX
a mp l e s
>ELIVER TO
' ' ' :.
-Oft# 16 HRS a t 220F "T"
*. ' .
SAMPLED BY
-ORYING-
RELEASED BY
; LUMP - OK - ' WET - SALTS - CONTAMINATE ,
V- ADDITIONAL DRYING HOURS REOUIREO
MPLES LIVER TO
,L 7 HSP .066 RP SCREEN3500 RPM
<. TEMP.
210
F
*
PLEA , . / WITHOUT MIXING
PLES ' 1 tNV + 1 Ht CAN '
TVER TO
CTL
ll PMtVl
NO. CARS PULLED SAMPLED BY
-GRINDING-
SCREEN MAX. TEMP.
.
EXPLAIN LOSSES
DATE MIXED --
SAMPLED BY
i
LUMP WGT. RELEASED BY
RPM op
'' 1
'
RELEASED BY
--------'
DUP050081442
t7
(B) BT-465-D
St a n d a r d Fo r mu l a No t e s
Th e "B" p r o c e s s is w r it t e n f o r c o s t in g . No p l a n t p r o d u c t io n h a s b e e n ma d e t o -
d a t e o n t h is p r o c e s s . It r e p l a c e s t h e "A" p r o c e s s a n d d if f e r s a s f o l l o w s ;
1. Fil t r a t io n in a w a s h p r e s s is s u b s t it u t e d f o r c e n t e r f e e d p r e s s in g . Th e
PRODUCT IS PRESS WASHED TO 5000 OHMS TO ENSURE GOOD HUMIDITY RESISTANCE IN
AUTOMOTIVE FINISHES.
2. TO OBTAIN SATISFACTORY PRESS BURDENS FOR MULTIPLE PRESSLOADS, THE BATCH s u e is in c r e a s ed f r o m 2100 t o 2327#*BG(N657-A) an d CPC-AF (N-873-A) ar e in c r e a s e d f r o m 1785 t o 2000# a n d 315 t o 350# r e s p e c t iv e l y t o a c c o mo d a t e
THE INCREASE IN BATCH SUE.
3. Va t s 240, 261 a n d 264 a r e a d d e d a s a l t e r n a t e s t r ik e v a t s .
4. HSP WITH .066*' SCREEN REPLACES HSP, 'WITH 3/32" SCREEN, TO ENSURE OPTIMUM
PRODUCT PERFORMANCE IN PLASTICS AND SAND MILLED PAINT APPLICATIONS.
Th e c a l c u l a t e d c o mp o s it io n a n d g o a l y ie l d f o l l o w s ;
Co mp o n e n t
Ac c o u n t Po u n d s - .
% An h y d
$auLas_
An h y d
Go a l
tiil-CL
Ca l c u l a t e d ; Co mp o s it io n
PBGCSH (N-657-A) PBZFAH (N-873-A)
Mo is t u r e
2000(2) 350( 1),
98.2 99.2
1964 347
An h y d
2311 16
2327#
84.4 14.9
.7 100.Q
Re f e r e n c e s ;
1. N-657 a n d N-873, if d r ie d a r e a s s u meo t o ..r e t a in 0,8$ mo is t u r e . 2. N-657 IS ASSUMED TO CONTAIN 1.0$ WATER SOLUBLE SALTS WHICH WILL BE WASHED
OUT DURING PROCESSING.
3. Mo is t u r e c o n t en t o f BT-297-D, PS-98150; 0.7$ /
Sig n e d ; Ap p r o v e d :
E.W.Ko s l o s k Y H.Ma t r ic k R.Ge d o
H.Ar n o u l
2-6-69 2-7-69 2-8-69
2-10-69
EWKj f c
!
! I
1
\ ' t i f
i i.
|,
i
DUP050081443
CS-PC-59B _________
RAW MATERIAL CARD___________
UG: 20 'CODE (B ) BT-465-0 : ( ) EST. WT. 2327
LBS.
NAME; "MONAS I KAL." BLUE GF
DATE:2-6-69
N-C0DE
LBS, BASIS
NAME
N-657-A
.2000 ioosf PBGCSH
N-873-A
350 Too% PBZFAH
,
f
J !
tt
REPLACE PROCESS ORIGINAL PROCESS
Jfi. j s a re'/P/Me/v'r#
!> ' *.
r ' i */
DUP050081444
New Jersey Office Supply Co,
F ilin g Specialists
40l Frielirighuysen Ave., Newark, N . J.
i
|
DUP050081445